13-07-2025

1001CJA106219250006 JA

PART-1 : PHYSICS

SECTION-I

1) Mandy stands on a weighing scale inside a lift (elevator) that accelerates vertically upwards as
shown in the diagram below. The forces on Mandy are her weight W and the reaction force from the

scale R. The reading of the scale is :

(A) R + W
(B) W
(C) R
(D) R – W

2) Sixteen beads of equal mass in a light string are placed on a smooth inclined plane of inclination
sin–1(1/3) such that some of them lie along the incline whereas the rest hang over the top of the
plane. If acceleration of each bead is g/2, the arrangement of beads is that-

(A) 12 hang vertically

(B) 10 lie along inclined plane
(C) 8 lie along inclined plane
(D) 10 hang vertically

3) These questions consist of two statements each, printed as Assertion and Reason.
While answering these Questions you are required to choose any one of the following four
responses.
Assertion : No work is done by a force on a object when the point of application of the force does
not move.
Reason : A small block of mass m is kept on a rough inclined surface of inclination α fixed in an
elevator. The elevator goes up with a uniform velocity u and the block does not slide on the wedge.
Then the work done by the force of friction on the block in time t will be mg ut sin2 α.

(A) If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.
(B) If both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.
(C) If Assertion is True but the Reason is False.
(D) If both Assertion & Reason are false.

4) A point moves along a circle having a radius 20 cm with a constant tangential acceleration 5
cm/s2. How much time is needed after motion begins for the normal acceleration of the point to be
equal to tangential acceleration?

(A) 1 s
(B) 2 s
(C) 3 s
(D) 4 s

5) The upper end of the string of a simple pendulum is fixed to a vertical z-axis, and set in motion
such that the bob moves along a horizontal circular path of radius 2 m, parallel to the xy plane, 5 m
above the origin as shown. The bob has a speed of 3m/s. The string breaks when the bob is vertically
above the x-axis, and it lands on the xy plane at a point (x, y), then-

(A) x = 2m
(B) x > 2m
(C) y = 2m
(D) y = 5m

6) A block of mass 2kg is placed on wedge having an angle 37° with horizontal. Wedge rotates about
an axis as shown with angular velocity 5 rad/s. If block just start accelerating upward w.r.t. wedge
with acceleration of 1 m/s2 at the given instant find friction force acting on block. (Distance of block
is 1m at the given instant.)

(A) 16 N
(B) 8 N
(C) 26 N
(D) 38 N

7) A force is applied on the body of mass 2 kg which varies with displacement of body according to
the given graph. If initial speed is 2 m/s, find the final speed of the body :-

(A) 8 m/s
(B) 12 m/s
(C) 4 m/s
(D) 10 m/s

8) A block of mass m is placed on horizontal surface having coefficients of static friction as µs and
coefficient of kinetic friction as µk. A force F is acting at an angle θ (< 90°) to horizontal as shown in

figure and N is the normal reaction by ground surface.

List-I : Condition List-II : Friction force

(P) If block is moving in + x-direction (1) μkΝ

If block is moving in –x-direction (initial

(Q) (2) – μkN
velocity in –x direction)

(R) If block is on the verge of moving (3) – F cos θ

(S) If block is at rest (F is less than in part R) (4) – μs mg

(A) (P) - 2; (Q) - 1; (R) - 3 ; (S) - 4
(B) (P) - 1; (Q) - 2; (R) - 3 ; (S) - 4
(C) (P) - 2; (Q) - 1; (R) - 4 ; (S) - 4
(D) (P) - 2; (Q) - 1; (R) - 3 ; (S) - 3

9)

The potential energy of a body is given by :

U = 40 + 6x2 – 7xy + 8y2 + 32z where U is in joule and x, y, z in meter. Deduce the x, y and z
components of the force (in newton) on the body when it is in position (–2, 0, +5) :-
(A) Fx = –32; Fy = –14; Fz = 24
(B) Fx = –14; Fy = –32; Fz = 24
(C) Fx = 24; Fy = –32; Fz = –14
(D) Fx = 24; Fy = –14; Fz = –32

10) A block of mass m = 2kg is moved slowly from bottom to top of the hill as shown with the
tangential force F. If the coefficient of friction between block and hill is 0.5, then work done by the

force will be :-

(A) mgh

(B)
mgh
(C) 2 mgh
(D) Can't be calculated

11) Find the work done by tension on 1 kg block when the 4kg block moves down by 1m after the
system is released. All surfaces are frictionless & strings are ideal :- (g = 10 m/s2)

(A) 25 J
(B) 50J
(C) 100 J
(D) None of these
12) A particle is moving in the vertical plane. It is attached at one end of a string of length ℓ whose
other end is fixed. The velocity at the lowest point is u. The tension in the string is and velocity of
the particle is at any position. Then, which of the following quantity will remain constant ?

(A)
(B) kinetic energy
(C) Gravitational potential energy
(D)

13) Block A is in equilibrium. Now block A given velocity in downward direction.

Maximum normal reaction on block B is :-

(A) 3mg
(B) 4mg

(C)

(D) 2mg

14) Statement-1: A car moves along a road with uniform speed. The path of car lies in vertical
plane and is shown in figure. The radius of curvature(R) of the path is same everywhere. If the car
does not loose contact with road at the highest point, it can travel the shown path without loosing
contact with road anywhere else. Statement-2: For car to loose contact with road, the normal
reaction between car and road should be zero.

(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
(B)
Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.

15) A block of mass 6kg is initially at rest. A force starts acting on the block, power delivered by the
force is shown in figure. Speed of object when its displacement is 2m is :-

(A) 4 m/s
(B) 8 m/s
(C) 2 m/s
(D) 6 m/s

16) A block of mass m is attached with a massless spring of force constant k. The block is placed
over a rough inclined surface for which the coefficient of friction is μ = 3/4. The minimum value of M
required to move the block up the plane is : (Neglect mass of string and pulley and friction in pulley)

(A)
m

(B)
m
(C) 2 m

(D)
m

17) A body is thrown with the velocity of 10 m/s at an angle of 45º to the horizontal. The radius of

curvature of its trajectory in t = sec after the body begins to move is :

(A) 0 m
(B) 2.5 m
(C) 5 m
(D) None of these

18) A block of mass m is given initial speed 'u' over a wedge of mass 9m which is initially at rest. All
surfaces are smooth. Choose the incorrect statement. (Block never leaves contact with the wedge
during its upward journey).

(A)
Maximum height reached by the block is .

(B)
Final speed of the wedge (when block returns to the lowest position) is .

(C)
Final speed of the block (when block returns to the lowest position) is .
(D) Final speed of the block (when block returns to the lowest position) is towards right direction.

19) In a vertical plane inside a smooth hollow thin tube a block of same mass as that of tube is
released as shown in figure. When it is slightly disturbed it moves towards right. By the time the
block reaches the right end of the tube, displacement of the tube will be (where ‘R’ is mean radius of

tube). Assume that the tube remains in vertical plane.

(A)

(B)

(C)

(D) R

20) A hollow right circular cone is fixed with its axis vertical and vertex down. A particle is
describing circular motion in contact with the smooth inside surface of the cone in a horizontal plane
at a height h above the vertex. Its velocity is

(A)
(B)

(C)

(D)

SECTION-II

1) A tractor A is used to hoist the heavy body B with a pulley system as shown in figure. If the tractor
has a velocity 25 km/hr towards right, find velocity (in km/hr) of the body B.
2) A tennis ball is hit from a height h = 6m above the level ground at an angle A = 45° towards a
wall that is at a horizontal distance D = 15 m. The ball hits the wall after 2 seconds. At what height

above the ground does the ball hit the wall (in m)?

3) Two identical particles A & B of mass m = 2 kg is connected at the end of the spring (K= 50 N /m)
and placed on a smooth horizontal surface. Now, force F = 10 N and 2 F are applied on the particles
in opposite direction as shown in figure. Initially spring is in natural length. Simultaneously particle
A receives an impulse towards B which imparts speed v0 to it, find v0 in m/s for which length of
elongation is two times the length of compression in the spring during subsequent motion?

4) A rod of length L and mass M is located along the x-axis with ends at x = 0 and x = L. This rod
has a special property such that if we make a cut at any arbitrary x = a coordinate and consider the
rod between x = 0 and x = a, the centre of mass of this portion of the rod is located at a/4. If the

linear mass density λ(x) of the rod as a function of x is given as Find the value of
100n.

5) Consider no friction anywhere. Consider pulleys and string to be ideal. The system is released
from rest. At any instant, the velocity of B is found to be . The velocity of block C at given
instant is found to be m/s. The value of (x + y) is _____ .
 PART-2 : CHEMISTRY

SECTION-I

1) Select the INCORRECT statement for molecule ABnL2 where :-

A = Central atom
n = Number of monovalent atom B
L = Lone pair of electron on central atom

(A) Molecule will be planar and non-polar if n = 4

(B) Molecule will be planar and polar if n = 3
(C) Molecule will be non-planar and non-polar if n = 3
(D) Molecule will be planar and polar if n = 2

2) Four orders are given according to their mentioned property.

Which of the following order is CORRECT?

(A) o-hydroxy benzaldehyde > p-hydroxy benzaldehyde : B.P.

(B) Water > Acetic acid : Molar entropy change of vaporization
(C) HF > H2O : Heat of vaporisation
(D) Fumaric acid > Maleic acid : acidic nature

3) Assertion (A) : Among the two O-H bonds in H2O molecule, the energy required to break the first
O–H bond and the other O–H bond is the same.
Reason (R) : This is because the electronic environment around oxygen is the same even after
breakage of one O–H bond.

(A) A and R both are true, and R is correct explanation of A.

(B) A and R both are true, but R is not the correct explanation of A.
(C) A is true but R is false.
(D) A and R both are false.

4) Which of the following order is CORRECT :-

(A) S > Se > Te > O : First Electron affinity

(B) < < < < : Hydration energy
(C) > > CO : Bond order of C–O Bond
(D) NaF > KF > RbF > CsF > LiF : Lattice energy

5) Which of the following order is CORRECT

(A) HF < HCl < HI < HBr : Acidic strength

(B) HF > HCl < HBr < HI : Bond length of H–X
(C) < < < : Cl – O Bond length
(D) HClO4 < HClO3 < HClO2 < HClO : Acidic strength

6) Which of the following order is INCORRECT :-

(A) H2O2 > O3 > O2 (O–O bond length)

(B) < (N–O bond order)
(C) O2F2 > H2O2 (O–O bond length)
(D) N2O > N2 (N–N bond length)

7) Number of statements which are correct.

(a) Graphite is elemental form of carbon
(b) White phosphorous is molecular solid
(c) Graphite is used as high temperature lubricant
(d) Hybridization of carbon in diamond and graphite is sp3,sp2 respectively
(e) C – C bond length in graphite is higher than diamond

(A) 2
(B) 3
(C) 4
(D) 5

8) In which of the following species hybridised d-orbital(s) participate in bond formation ?

(A) SO2Cl2
(B) XeOF4
(C)
(D) XeO3

9)

Matching List

List-I (Molecule) List-II (Properties)

(P) Marshall's acid (H2S2O8) (1) Ionic bond present

(Q) Tripolyphosphoric acid (H5P3O10) (2) Cyclic with six membered ring

(R) Blue vitriol (CuSO4.5H2O) (3) Contains peroxy linkage

(S) Cynuric trichloride (C3N3Cl3) (4) Contains "X–O–X" linkage

(A) P→2, Q→1, R→4, S→3
(B) P→3, Q→4, R→1, S→2
(C) P→4, Q→1, R→2, S→3
(D) P→4, Q→3, R→2, S→1

10) Select the INCORRECT match(s)?

 Total number of shared oxygen in
Salt/silicate
anionic part of Salt/silicate

(a) Be3Al2(Si6O18) 6

(b) Zn3(Si2O7) 1

(c) Sodium tetrapolyphosphate 4

(d) Sodium trimetaborate 3

(A) a
(B) b
(C) c
(D) d

11) Which of the following is NOT correct according to given property?

(A) B(OH)3 > B(OMe)3 : Boiling point

(B) C3H8 > C3F8 : Boiling point
(C) o-dichlrobenzene > m-dichlorobenezene : Boiling point
(D) H2 > He : Boiling point

12) In which of the following set all the orbitals have at least one common nodal plane.

(A) px , dxy , dyz

(B) py , dxz , dyz
(C) pz, dxz dyz

(D) , ,

13) The electronegativity difference between N and F is greater than that between N and H yet the
dipole moment of NH3(1.5 D) is larger than that of NF3 (0.2 D).This is because

In NH3 the atomic dipole and bond dipole are in the opposite directions where as in NF3 these
(A)
are in the same direction
(B) In NH3 as well as in NF3 the atomic dipole and bond dipole are in the same direction.
In NH3 the atomic dipole and bond dipole are in the same direction whereas in NF3 these are in
(C)
opposite directions.
(D) In NH3 as well as in NF3 the atomic dipole and bond dipole are in opposite directions

14) If species MH2 have bent shape then choose the INCORRECT statement -

(A) MH2 will be polar

(B) MH2 will be planar.
(C) Octet of 'M' should be completed
(D) 'M' can have at least four valence electrons

15) Arrange the following compounds in increasing order of their dipole moment :
CCl4 , CH4 , CH2Cl2 , CH3Cl and CHCl3

(A) CH4 = CCl4 < CH3Cl < CH2Cl2 < CHCl3

(B) CH4 = CCl4 < CH2Cl2 < CH3Cl < CHCl3
(C) CCl4 = CH4 < CH2Cl2 < CHCl3 < CH3Cl
(D) CCl4 = CH4 < CHCl3 < CH2Cl2 < CH3Cl

16) Select the CORRECT order sequence(s)

C–C bond length : CH2 = CH2 >

(A)

(B) Order of dipole moment : HF < HCl

(C) Boiling point : AsH3 > NH3
(D) Bond length (S = O) : SO2 > SO3

17) Which of the following statement is INCORRECT?

(A) Homoatomic polynuclear molecules can never have permanent dipole.

(B) Hetero atomic polynuclear molecules can be non-polar.
The magnitude of average potential energy of two rotating dipole, separated by distance r, is
(C)
proportional to
(D) The dipole-induced dipole interaction energy is independent of the temperature

18) Consider a molecule 'MX3' which have three pπ–dπ bonds and pyramidal structure. Then select the
INCORRECT statement -
[M and 'X' belongs to 'p' block, consider no co-ordinate bond is present in molecule]

(A) central atom is hypervalent

(B) molecule is non polar
(C) 'X' uses It's 'p' orbital for π bond formation
(D) hybridisation of 'M' is sp3

19) Which of the following is correctly represented by their mentioned property.

(A) CrO3, ZnO, PbO2, Al2O3 (Amphoteric oxide)

(B) Cr2O3, Mn2O7, V2O5, Na2O (Basic oxides)
(C) CO2, N2O5, SO3, Cl2O7, (Acidic oxides)
(D) CO, N2O, NO, NO2 (Neutral oxides)

20) Which of the following is INCORRECT order for indicated bond length ?

(A) dN–N in N2H4 > dN–N in N2F4

(B) dN–N in NH2–NH2 > dN–N in

(C) dSi–Cl in SiClF3 > dSi–Cl in SiClH3
(D) dS–X in SOCl2 > dS–X in SOF2 (X = Halogen)

SECTION-II

1) For Tetrathionic acid number of S-S bonds = x

Number of σ bonds = y
Basicity of this acid = z
{count double bond to be only one bond}

calculate the value of x + 2y +

2) Calculate number of e– in Pd(z = 46) which have value of quantum number which satisfies the
equation n × ℓ – m = 0

3) If 'X' represents number of species within which London forces work and 'Y' represents species
when which London forces does not work among the following molecules.

Then is
C2H3OH(ℓ), Xe(ℓ), H2O(ℓ), CH3Cl(ℓ), NH3(ℓ), HClO3(ℓ)

4) How many of the following bond angle order(s) is/are correct ?

(i) NH3 > NF3
(ii) PH3 > PF3
(iii) H2O > F2O
(iv) OCℓ2 > SCl2
(v) Cl2O > F2O

5) From the following list, find the number of species which do not contain "X–O–X" linkage, where X
is central atom (B/S/P).
H3P3O9, H2S2O5, H2S2O8, H2SO5, Na2[B4O5(OH)4]. 8H2O, P4O10, [B2O4(OH)4]–2

PART-3 : MATHEMATICS

SECTION-I

1) Let a1, a2, ..... an be the terms of a G.P. whose common ratio is r. Let Sk denotes the sum of first k

terms of the G.P. then the value of in terms of Sm–1 and Sm is

(A) r Sm–1 Sm

(B)
(C)

(D) Sm-1 Sm

2) If k be the minimum value of expression (cos2 α – 2cos α )sec2 β + 9cosec2 β + 5sec2 β where α∈

[0, π] and β∈ , then k is

(A) 20
(B) 25
(C) 24
(D) 29

3) Assertion (A) : a + b + c + d + e = 8 and a2 + b2 + c2 + d2 + e2 = 16, where a, b, c, d are positive

real numbers, then .

Reason (R) :

(A) Both A and R are correct and R is the correct explanation of A

(B) Both A and R are correct but R is NOT the correct explanation of A
(C) A is correct but R is not correct
(D) A is not correct but R is correct

4) If then a1, a2, a3, a4 are in :-

(where a1, a2, a3, a4 are non-zero)

(A) A.P.
(B) G.P.
(C) H.P.
(D) None of these

5) Number of solution of the cos4 2α + 2 sin2 2α = 17 (cos α + sin α)8, α ∈ (0, 2π) is

(A) 10
(B) 6
(C) 4
(D) 2

6) The number of solutions of = –1 in (0, π) – is

(A) 0
(B) 1
(C) 2
(D) 4

7) If the value of α ∈ [0, 2π] such that the inequality sin + sin(α + x) ≥ 0 is true ∀ x ∈ R , is

equal to (where p and q are relatively prime positive integers), then the value of (p + q) is

(A) 3
(B) 5
(C) 7
(D) 9

8) If f(x) = 2 sin2 θ + 4 cos (x + θ) sin x sin θ + cos (2x + 2θ) then value of f2 (x) + f2 is

(A) 0
(B) 1
(C) –1
(D) x2

9) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

The number of solutions of 3[sinx + cosx] – 2[sin3x + cos3x] = 8 in x

(A) (I) 4
∈ [0, π] is

The number of solution(s) of sin4x – cos2x sinx + 2sin2x + sinx = 0

(B) (II) 5
in x ∈ [0,3π] is (are)

The number of ordered pairs which satisfy the equation

(C) (III) 0
x2 + 2xsin(xy) + 1 = 0 is (where y ∈ [0,2π])

The number of values of θ which satisfy the equation

(D) (IV) 2
sin3θ – sinθ = 4cos2θ – 2 ∀ θ ∈ [0, 2π] is
(A) (A) – II, (B) – IV, (C) – I, (D) – III
(B) (A) – III, (B) – II, (C) – IV, (D) – I
(C) (A) – I, (B) – II, (C) – III, (D) – IV
(D) (A) – III, (B) – I, (C) – IV, (D) – II

10) If f(x) = tan x + tan2 x tan 2x and g(n) = , then g(2013) – tan (22014) is equal to

(A) 0
(B) tan1
(C) –tan1
(D) 1

11) Let and then a2 +

c2 is equal to

(A)
(B)
(C)
(D)

12)

If in a right angled triangle ABC, and is finite, then tan(A – B) is equal to

(A)

(B)

(C)

(D)
–

13) If f(x) = x2 + ax + b where a, b ∈ R and f(f(x)) = 0 has roots 1 and 2. If k be the value of f(x) at x
= 0, then k is

(A)

(B) 2

(C)

(D) –2

14) Consider the equation x4 – ax3 – bx2 – cx – d = 0, a, b, c, d ∈ I+, a ≥ b ≥ c ≥ d then, the number of
integral solutions are

(A) 0
(B) 4
(C) 2
(D) None of these

15) Statement-I : If px2 + qx + r = 0 is quadratic equation (p, q, r ∈ R) such that its roots are α, β
and p + q + r < 0, p – q + r < 0 and r > 0, then [α] + [β] = – 1, (where [.] denotes the greatest
integer function)
Statement-II : If for any two real numbers a and b, polynomial f(x) is such that f(a) f(b) < 0, ⇒ f(x)
has at least one real root lying in (a, b).

(A) Both Statement-I and Statement-II are true

(B) Both Statement-I and Statement-II are false
(C) Statement-I is true but Statement-II is false
(D) Statement-I is false but Statement-II is true

16) Let x be then x is equal to :

(A) 10
(B) 8
(C) 4
(D) 2

17) lf (1 + 3 + 5 + ........ + p) + (1 + 3 + 5 + ........ + q) = (1 + 3 + 5 + ....... + r) where each set of

parentheses contains the sum of consecutive odd integers as shown, the smallest possible value of p
+ q + r, (where p > 6) is

(A) 12
(B) 21
(C) 45
(D) 54

18) Number of integers satisfying the inequalities

, is

(A) 5
(B) 6
(C) 7
(D) 8

19) The number of all polynomial whose coefficients are either 1 or –1 , that have only real roots are
:

(A) 6
(B) 8
(C) 10
(D) 12

20) If in triangle ABC, ∠C = 45° then value of sin2A + sin2B lies in the interval :-

(A) [0, 1]
(B) (0, 1)

(C)

(D) None of these

SECTION-II
1) If and tan α tan 2α + tan 2α tan 4α + tan 4α tan α = –k, then the value of k is :

2) Given that for a, b, c, d ∈ R, (where ac ≠ bd) if a sec(200°) – c tan(200°) = d and b sec(200°) + d

tan(200°) = c then cosec 200° then the value of p is

3) The number of solution in the interval [0, π] of the equation sin3 x⋅cos3 x = 0 is

4) Given that α, β, γ are the roots of cubic equation x3 – 3x2 + 2x + = 0. The value of α4 + β4 + γ4 is
equal to _________ .

5) If , where n ≥ 1, then is equal to _______

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C D B B A C B D D B A A B D C A C D C A

SECTION-II

Q. 21 22 23 24 25
A. 4 1 6 75 32

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C B D A C C C B B C B C C C D D A B C C

SECTION-II

Q. 46 47 48 49 50
A. 26 8 3 4 4

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B B A C C B C B D C B D C A A D B B D C

SECTION-II

Q. 71 72 73 74 75
A. 7 2 3 9 7
 SOLUTIONS

PART-1 : PHYSICS

1)

Reaction force from scale is the reading of scale.

2)

Correct answer is (D)

3)

Assertion-1 : displacement is zero

w.p = 0

f = mg sinα

s = ut + at2
= ut

4)

or

5) For x direction
u = 0, ax = 0, ∴ sx = 0; , xf = 2
For y direction u = 3, ay = 0, t = 1
∴syt = 3 ⇒ yf – yi = 3
For z direction:

u = 0, a2 = 10, s2 = 5, 5 = (10)t2 ⇒ t = 1
6)
50cos37 – 20sin37 – fr = 2 × 1
40 – 12 – fr = 2
fr = 26 N

7)

Area under F – s curve gives the change in kinetic energy.

8) In static condition =–
In static = &
In Kinetic case acts opp. to direction of relation velocity.

9)

Given U = 40 + 6x2 – 7xy + 8y2 + 32z

Then Fx = = – 12x + 7y = + 24N

[Putting x = – 2, y = 0]

Fy = = 7x – 16y = – 14N
[Putting x = –2, y = 0]

Fz = = –32N

10) By WET WF + Wfr + Wg = ΔKE

WF + µmgh – mgh = 0 – 0

WF = mgh + =
 11)
–2T + 4g = 4a T – gsin30° = 2a

Thus, ∴ W= × 2 = 25 J

12)

The tension vector is always normal to velocity vector. Hence is always zero.

⇒ A is correct choice.

13)

By W.E.T.

+ mgx =

max. comp x =
kx =2mg

14)
as θ↓ cos θ N so tendency of loosing contact is minimum at maximum value of θ.

15)

Area of power displacement graph

= m(v3 – u3)
16) Mgh =

⇒
kh = mg sinθ + mmg cosθ

17)

18) mu = 10 mv

v1 & v2 → Actual velocities of wedge & block respectively.

v1 + v2 = u ...(1)
mu = 9mu1 – mu2
⇒ u = 9(u – v2) – v2
⇒ u = 9u – 10v2

(Maximum speed of the block)

 (Maximum speed of the wedge)

19) Since there is no ext. force on system

m (R – x) + m (–x) = 0
x = R/2.

Alternate : Let the tube displaced by x towards left, then ;

mx = m (R – x) ⇒ x = .

20)

21)

22)
 At 45° ux = uy =
Displacement in y-direction after two second

(2) –
= 15 –20
H = –5
Height from ground = 6 – 5 =1

23)

v0 = 6 m/s

24)

Correct answer is (75)

25) Applying conservation of momentum along horizontal direction

PART-2 : CHEMISTRY

26) If n = 4
AB4L2 like XeF4 planar , sp3d2
If n = 3
AB3L2 like ClF3 planar , sp3d
If n = 2
AB2L2 like H2O planar , sp3

27) o-hydroxy benzaldehyde < p-hydroxy benzaldehyde : B.P.

HF < H2O : Heat of vaporisation
Fumaric acid < Maleic acid : acidic nature

28) Energy require to break two OH bond successively will be different.

29) will have highest hydration energy

•
• Lattice energy ∝

30) • HI is strongest acid with longest bond length

• Bond length ∝

31) due to % p increases for O – F bond & % s increases for O–O bond.

32) The correct answer is option (C)

33) XeOF4 has sp3d hybridisation.

34) CuSO4.5H2O has ionic bond between Cu+2 &

35) Sodium tetrapoly phosphate

Na6P4O13

Anionic part has three oxygen shared in total.

36) Boiling point of o-dichlorobenzene > m-dichlorobenzene

37) pz, dxz, dyz have common xy nodal plane

38)

39) → For this structure to be Bent there should be at least one Lone pair.
Or

→ so it can have 4 valence e– or 6 valence electrons

40) The correct answer is option (D)

41)

42) O3 has µ ≠ 0 (Homo atomic poly nuclear)

43)

44) CrO3, NO2 are acidic oxides Cr2O3 is amphoteric oxide.

45)
Due to F atom % p increases in Si – F bond & % s increases in Si – Cl bond.

46)

47)
Only s orbital will satisy the following equation
1s2, 2s2, 3s2, 4s2, Total 8e– s.

48) Even polar molecule show London forces of attraction.

 49)

(i),(iii),(iv),(v) are correct

50) H2S2O8, [B2O4 (OH)4]–2 H2SO5 have peroxy linkage H2S2O5 does not have any X – O – X
linkage.

PART-3 : MATHEMATICS

51)

52) k = cos2α – 2cosα+ 5 + sec2β +9cosec2β

k = ((cosα–1)2 + 4 × (1 + tan2 β) + 9 (1 + cot2 β)
k = ((cosα–1)2 + 4 + 9) + [[(cosα–1)2+4)tan2β + 90cos2β]
and use A.M. ≥ G.M. after putting α = 0

kmin. = (4+ 9) + = 13 + 12 = 25

53)

64 + e2 – 16e ≤ 64 – 4e2
5e2 – 16e ≤ 0

0≤e≤

54) ....(1)

....(2)
∴ From (1) and (2),

we get
∴ a1, a2, a3, a4 are in H.P.

55) Let sin2α = t

(1 – t2)2 + 2t2 = 17(1 + t)4
8t4 + 34t3 + 51t2 + 34t + 8 = 0

Let
8x2 + 34x + 35 = 0
(2x + 5) (4x + 7) = 0

sin2α = (4 soln)

56) Let

⇒ t2 = 1 ⇒ 3t2 + 2t – 1 = 0 ⇒ t = –1,

57)

Now for x ∈ R hence (i) will be true.

if
possible k = –1

58) f(x) = 2 sin2 θ + 4 cos (x + θ) sin x sinθ + cos (2x + 2θ)

= 2 sin2 θ + cos (2x + 2θ) + 2 cos (x + θ) cos (x – θ) – 2 cos2 (x + θ)
= 2 sin2 θ + 2 cos2 (x + θ) – 1 + 2 cos2 x – 2 sin2 θ – 2 cos2 (x + θ)
= cos 2x

59) (A) 3[sinx + cosx] – 2[sin3x + cos3x] = 8

3[sinx+cosx] – 2[(sinx + cosx)3
– 3sinxcosx(sinx + cosx)] = 8 ...(1)
We know
(sinx + cosx)2 = 1 + 2sinxcosx
 ⇒ sinxcosx =
Now put sinx + cosx = t in equation (1)

Now Do your self

(B) sin4x – cos2xsinx + 2sin2x + sinx = 0
⇒ sin4x + 2sin2x + sinx[1 – cos2x] = 0
⇒ sin4x + 2sin2x + sin3x = 0
⇒ sin2x[sin2x + 2 + sinx] = 0
⇒ sinx = 0
(C) x2 + 2xsin(xy) + 1 = 0
⇒ x2 + 1 = –2xsin(xy)

⇒ x + = –2sin(xy)
L.H.S. R.H.S
∈ (–∞, –2] ∪ [2, ∞) ∈ [–2, 2]
so equality can be established if
L.H.S. = R.H.S. = 2 or –2
If L.H.S. = R.H.S. = 2
⇒ x = 1 & –siny = 2

⇒ siny = –1 ⇒
similarly for x = –1

⇒ siny = 1 ⇒
(D) sin3θ – sinθ = 2[2cos2θ – 1]
⇒ 2cos2θsinθ = 2cos2θ
⇒ cos2θ[sinθ – 1] = 0
⇒ cos2θ = 0 or sinθ = 1

60) tan(2x–x)=
⇒tanx + tan2x tan2x = tan2x – tanx
f(x) = tan2x–tanx

g(n) =
g(n) = tan (2n+1)–tan1
g(2013)–tan(22014)= – tan1

61) (b + a cos θ)2 = 1 – a2 sin2 θ

(d + c cos θ)2 = 1 – c2 sin2 θ
(b + a cos θ)2 (d + c cos θ)2 = (–ac sin2 θ)2
(1 – a2 sin2 θ) (1 – c2 sin2 θ) = a2c2 sin4 θ
⇒ (a2 + c2) sin2 θ = 1
62)

is real

63) f(f(1)) = 0 ⇒ f(1 + a + b) = 0

f(f(2)) = 0 ⇒ f(4 + 2a + b) = 0
∴ 1 + a + b and 4 + 2a + b are roots of f(x)
∴ 3a + 2b + 5 = –a
⇒ 4a + 2b + 5 = 0 ...(1)
(a + b + 1)(2a + b + 4) = b

⇒ (a + b + 1) = b ⇒ (a + b + 1) =b
⇒ 3a + 3b + 3 = 2b
∴ f(0) = b
⇒ b = –3a – 3 ....(2)
From equation (1), we get
4a + 2(–3a – 3) + 5 = 0

⇒ –2a – 1 = 0 ⇒ a = –

∴ b = –3 –3=– , f(0) = b =

64) Suppose m is an integer root of x4 – ax3 – bx2 – cx – d = 0 as d ≠ 0

⇒m≠0
(I) m > 0
m4 – am3 – bm2 – cm = d
⇒ d = m(m3 – am2 – bm – c)
⇒d≥m
Also, m4 – am3 = bm2 + cm + d
m3(m – a) = bm2 + cm + d
⇒ m > a ⇒ contradiction
(II) m < 0
m = –n
⇒ n4 + an3 – bn2 + cn – d = 0
n4 + n2(an – b) + (cn – d) > 0
So, contradiction
Hence, equation has no integral solution

65) Given equation is px2 + qx + r = 0

Let, f(x) = px2 + qx + r
f(0) = r > 0
f(1) = p + q + r < 0
f(–1) = p – q + r < 0
Hence, one root lies in (–1, 0) and the other in (0, 1)
∴ [α] = – 1 and [β] = 0
⇒ [α] + [β] = – 1

66) Let a =
a – b = x, a3 – b3 = 20, ab = 2
x3 = (a – b)3 = a3 – b3 – 3ab(a – b) = 20 – 6x
⇒ x3 + 6x – 20 = 0
⇒ x = 2 is only one real solution.

67) We know that 1 + 3 + 5 + ......... + (2k – 1) = k2

Thus, the given equation can be written as

⇒ (p + 1)2 + (q + 1)2 = (r + 1)2
Therefore, (p + 1, q + 1, r + 1) forms a Pythagorean triplet, AS p > 6, p + 1 > 7.
The first Pythagorean triplet containing a number > 7 is (6, 8, 10).
∴ We may take p + 1 = 8, q + 1 = 6, r + 1 = 10
⇒ p + q + r = 21

68)

put log3 x – 1 = t2 log3 x = t2 + 1

2|t| – 3(1 + t2) + 4 > 0
2|t| – 3 – 3t2 + 4 > 0
3t2 – 3|t| + |t| – 1 < 0

x ∈ [3, 9) ⇒ 6 integers i.e. 3, 4, 5, 6, 7, 8

69)

If a polynomial a0xn + a1xn–1 + .......... + an is such a polynomial.

We can assume a0 = 1. Let r1, r2, .........rn are its roots
⇒ =

⇒ AM ≥ GM ⇒
a1, a2 = ±1, we must have a2 = –1, and n ≤ 3
⇒ Polynomials are
±(x – 1), ±(x + 1), ±(x2 + x – 1), ±(x2 – x – 1), ±(x3 + x2 – x –1), ±(x3 – x2 – x + 1)

70) Δ = sin2 A + sin2 (135° – A) = 1 + sin2A – sin2(45° – A)

= 1 + sin45° × sin (2A – 45°) = 1 + .sin (2A – 45°)

=Δ< and Δ >
0 < A < 135°
0 < 2A < 270°
–45° < 2A – 45° < 225°

⇒ .

71) cos (α + 2α + 4α) = cosα cos 2α cos 4α – sinα sin 2α cos 4α

– sinα cos 2α sin 4α – cosα sin 2α sin 4α
⇒ cos 7α = cosα cos2α cos4α (1 – tanα tan 2α – tan2α tan4α – tan4α tanα)
⇒ tanα tan2α + tan2α + tan 4α + tan 4α tan

α= ; where 7α = 2π

= –7

72) ..........(1)

..........(2)
a = d cos(200°) + c sin (200°) ..........(3)
b = c cos (200°) – d sin (200°) ..........(4)
∴ a2 + b2 = c2+ d2
∴ (a2 + b2 + c2 + d2) = 2(c2 + d2)
ac = dc cos (200°) + c2 sin (200°)
Also bd = cd cos(200°) – d2 sin (200°)
____________________________
ac – bd = (c2 + d2) sin (200°)

So
∴ p=2

73) Use sin3 x =

Equation becomes sin 4x = 0

x=

74) ∵ x3 – 3x2 + 2x + =0
∴ Σα = 3
Σαβ = 2

Σαβγ =
∵ Σα2 = (Σα)2 – 2 Σαβ
=9–4
=5

∴ α3 = 3α2 – 2α

∴ α4 = 3α3 – 2α2 – α = 7α2

= 35 – 20 – 6
=9

75) , find R1, R2, ..........., R20 it will be a telescopic

sum