02-07-2025

7101CJA101001250008 JA

PHYSICS

SECTION - I (i)

1) A stone is projected on an incline plane which is inclined at an angle 'α' with horizontal. It has
found that the stone strikes the inclined plane perpendicularly. Initial velocity of projection is at an
angle 'β' with inclined plane. Select the CORRECT alternatives.

If velocity of projection is double then angle at which stone strikes the incline plane remains
(A)
same.
(B) Distance of particle from point of projection never decreases with time for above condition.
If angle of projection is change keeping angle of incline same. still the stone can strike incline
(C)
plane perpendicularly by adjusting speed of projection.

(D)
The of flight on incline plane is

2) A person, standing on a vertical cliff a height 'h' above a lake, wants to jump into the lake but
notices a rock just at the surface level with its furthest edge s distance from the shore. The person
realizes that with a running start it will be possible to just clear the rock, so that person steps back
from the edge a distance 'd' and starting from rest, runs at an acceleration that varies in time
according to ax = bt and then leaves the cliff horizontally. The person just clears the rock. You may

neglect air resistance.

(A)
Time when the person reaches the edge of the cliff

(B)
Time when the person reaches the edge of the cliff

(C)
The distance 's' is

(D)
The distance 's' is
3) An ant is scampering on a paper with velocity 10m/s. Now you begin to pull the paper with
velocity 10 m/s along x-axis as shown in figure. Coordinate system has origin fixed to ground as
shown in figure. The initially position of ant is (0,0). Select the correct alternative (s)

(A) Velocity of ant in ground frame is m/s

(B) Position vector of ant with respect to ground after 3 sec. is m.
o
(C) In ground frame, velocity vector of ant is at an angle θ < 37
(D) In ground frame velocity vector of ant is at an angle θ < 37o .

4) A cylindrical pipe of radius r is rolling towards a frog sitting on the horizontal ground. Centre of
the pipe is moving with a constant velocity v. To sabe itself, the frog jumps off an passes over the
pipe touching it only at the top. Denoting air-time of the frog by T, horizontal range of the jump by R
and acceleration due to gravity by g, which of the following conclusions can you make?

(A)

(B)

(C)

(D)

5) A boy takes 60 min to swim across a river, if his goal is to minimize time; and takes 180 min, if his
goal is to minimize to zero the distance that he is carried downstream. In both these attempts, the
body swims with the same speed relative to the river current. Which of the following statements can
be true?

(A) He can swim relative to water faster than the river current.
(B) He cannot swim relative to water faster than the river current.
(C) If width of river is km, speed of river current is 4 km/h.
(D) If he cross a km wide river in min, he will be carried km downstream.

6) Particle A moves with a constant speed 2 m/s on a circular path of radius 4 m whereas particle B
moves along a straight line through the centre of the circular path always maintaining a constant
distance 4 m from the particle A. Which of the following conclusions can be drawn?

(A) Maximum speed of B is 4 m/s.

(B) Maximum acceleration of B is 2 m/s2.
(C) During one revolution of A, distance travelled by B is 32 m.
(D) Modulus of velocity of a particle relative to the other is a constant.

SECTION - I (ii)

1) A gun is hidden under an inclined roof of angle of inclination 30° with horizontal as shown. L =
m and its initial velocity is 20 m/s. What can be the maximum range (approximate) of the gun on

the level ground? The roof is long enough.

(A) 36 m
(B) 40 m
(C) 32 m
(D) 44 m

2) A rod always remains in contact with a cylinder as shown. The angular velocity of rod at given

moment is :

(A) 2 rad/s

(B)
rad/s
(C) 3 rad/s
(D) 4 rad/s

3) A projectile is projected at an angle of elevation . After t seconds, it appears to have an angle of

elevation as seen from the point of projection. Which of the following are incorrect:

(A) the y-coordinate of the position of the projectile at time t is , where v is the
velocity of projection
the x-coordinate of the position of projectile at time t is , where v is the velocity of
(B)
projection

(C)
, where v is the velocity of projection

(D)
velocity of projection is

4) In the arrangement of rigid links of equal length , they can freely rotate about the joined ends as
shown in the figure. If the end U is pulled horizontally with constant speed 20 m/s, find the approx.

speed of end P when the angle SUT is 90°.

(A) 5 m/s
(B) 10 m/s
(C) 7.1 m/s
(D) 14.12 m/s

5) An insect start moving along a rope with velocity V relative to rope. One end of rop is fixed to a
point A, and other end (initially at a distance L from fix point A) is pulled with speed U. After how
much time later insect reaches the other end of rope (insect start motion from point A, rope follow
hooks law)

(A)

(B)

(C)

(D)

6) A new kind of braking can reduce speed but cannot stop completely. A car installed with this kind
of brake is
running 10 m/s when brakes are applied. As a result velocity decreases with time according to
equation v=10e–2t.
Which of the following figures correctly represents variation in velocity and acceleration of the car
with time during
braking?

(A)
(B)

(C)

(D)

SECTION - II

1) The velocity of a particle traveling in a straight line is given by v(t) = 5 – 6e–t/2 m/s, where time t is
in seconds and t ≥ 0. If the particle is observed at x = 7m at the instant t = 0, its position x is

expressed as function of time Find numerical value of .

2) A particle A is thrown with initial velocity 5 m/s along a frictionless inclined plane of inclination β.
Another particle B is thrown with initial velocity 10 m/s at an angle α with the horizontal at the same
moment when A is thrown and from same position as that of A. Both the particle meet again on the

inclined plane. The value of is

3) A particle starts moving with initial velocity of 3m/s along x-axis from origin. Its acceleration is
varying with position (x) in parabolic nature with vertex at the origin as shown in figure. A tangent
to the graph is drawn at The tangent makes an angle of 60° with the x-axis. At this
position the velocity of particle is the value of k is

4) A ball is thrown from ground at an angle θ with horizontal and with an initial speed u0. For the
resulting projectile motion, the magnitude of average velocity of the ball up to the point when it hits
the ground for the first time is V1. After hitting the ground, ball rebounds at the same angle θ but
with a reduced speed of u0/α. Its motion continues for a long time as shown in figure. If the
magnitude of average velocity of the ball for entire duration of motion is 0.8 V1, the value of α is

_________ .

5) A particle is projected from a stationary trolley. After projection, the trolley moves with a velocity
. For an observer on the trolley, the direction of the particle is as shown in the figure while
for the observer on the ground, the ball rises vertically. The maximum height reached by the ball
from the trolley is h metre. The value of h will be ____

6) A particle of mass 0.5 kg is projected horizontally in air with initial velocity of 9 m/s. During the
motion of the particle in air a constant air drag of magnitude 5N acts on it opposite to its
instantaneous direction of motion. Find its speed (in m/s) when its direction of motion makes an
angle of 30° with the horizontal, (given g = 10 m/s2)

CHEMISTRY

SECTION - I (i)

1) Which statement(s) is/are correct ?

(A) Polarising power refers to cation.
(B) Polarisability refers to anion.
(C) Small cation is more efficient to polarise anion.
(D) Molecules in which cation having pseudo inert gas configuration are more covalent.

2) Choose the correct order(s) for the given properties.

(A) MgSO4 < SrSO4 < BaSO4 : Thermal stability order

(B) BeC2O4 < CaC2O4 < BaC2O4 : Solubility in water
(C) LiCl > NaCl > KCl : Melting point order
(D) BeF2 > CaF2 > SrF2 : Covalent character order

3) Which statement (s) is /are correct about hybridization ?

(A) In hybridisation orbitals take part.

(B) In hybridisation electrons take part.
(C) In hybridisation fully filled, half filled or empty orbitals can take part.
(D) Hybridised orbitals only contains bond pair electron.

4) If 'y' is the internuclear axis then which overlaping results π bond

(A) dxy – dxy

(B) px – pz
(C) dxz – dxz
(D) py – py

5) Most ionic compounds have :

(A) high melting points and low boiling points

(B) high melting points and nondirectional bonds
(C) high solubilities in polar solvents and low solubilities in nonpolar solvents
(D) three-dimentional network structures, and are good conductors of electricity in the molten state

6) Choose the correct order for the given properties.

(A) NaF < MgF2 < AlF3 : covalent character order.

(B) NaF < MgF2 < AlF3 : melting point order
(C) NaF < MgF2 < AlF3 : lattice energy order
(D) NaF > MgF2 > AlF3 : order of polarising power of cation.

SECTION - I (ii)

1) Anionic part of which of the following is planar :-

(A) Cl2O6(s)
(B) N2O5(s)
(C) PCl5(s)
(D) None of these

2) Which of the following is correct order of σ-bond strength ?

(I) 2s – 2s
(II) 2s – 2p
(III) 2p – 2p
(IV) 3s – 3s

(A) I > II > III > IV

(B) III > II > I > IV
(C) IV > I > II > III
(D) III > I > II > IV

3) How many lone pairs in ?

(A) 3
(B) 2
(C) 6
(D) 9

4) Which of the following order is correct for thermal stability ?

(A) MgCO3 < CaCO3 < BeCO3

(B) BeCO3 < MgCO3 < CaCO3
(C) MgCO3 < BeCO3 < CaCO3
(D) CaCO3 < MgCO3 < BeCO3

5) Atomic orbitals involved in hybridization of SF6 molecule are :-

(A) 3s, 3px, 3py, 3pz,

(B) 3s, 3px, 3py, 3pz,

(C) 4s, 4px, 4py, 4pz, , 3dxy

(D) 3s, 3px, 3py, 3dxy, 3dyz, 3dxz

6) Which of the following order is incorrect ?

(A) Ionic character : MCl < MCl2 < MCl3

(B) Solubility in water : LiOH < NaOH < KOH < RbOH < CsOH
(C) Solubility in water : BeSO4 > MgSO4 > CaSO4 > SrSO4 > BaSO4
(D) Covalent character : LiF < LiCl < LiBr < LiI

SECTION - II
1) What is the maximum number of atoms lie in the same plane in the structure of methylene
sulphur tetrafluoride (H2CSF4)?

2) No of molecules which are non-linear among the following molecules will be

3) Find the number of planar molecule

(a) BF3 (b) BCl3 (c) CO32– (d) SO3
(e) NH3 (f) NCl3 (g) PCl3 (h) XeF4

4) The number of species from the following which have square pyramidal structure is
PF5, BrF4– , IF5; BrF5, XeOF4, ICl4–

5) How many of the following are correct orders of property indicated against it ?
(i) I– > Br– > Cl– > F– (order of polarizability)
(ii) Li+ > Na+ > K+ > Cs+ (order of polarising power)
+ 2+ 3+
(iii) Li > Mg > Al (order of polarising power)
(iv) LiI > NaI > KI (order of ionic character)

6) Among the following compounds, the number of compounds having greater magnitude of
lattice energy than RbBr, are
NaCl, KF, RbCl, CsBr, NaBr, KCl, CsI, RbI.

MATHS

SECTION - I (i)

1)

If the roots of the equation x3 + px2 + qx - 1 = 0 form an increasing G.P., where p, q ∈ R, then

(A) p + q = 0
(B) p ∈
(C) one of the roots is unity
(D) One root is smaller than 1 and one root is greater than 1

2) Let set P = {letters of the word ASSOCIATIVE} and Q = {letters of the word ASCERTAIN}. If
universal set is the set of all alphabets, then which of the following is/are true?

(A) n (P - Q) = 2
(B) n (Q - P) = 2
(C) n
(D)
3) In a plane, let A be the set of rectangles, B be the set of squares, C be the set of cyclic
quadrilaterals and D be the set of isosceles trapeziums. The which of the following is/are always
true?

(A) C - A = ϕ
(B) B - D = ϕ
(C) A ∩ C = C
(D) (A ∩ D) ∩ C = A

4) Let Tk denotes kth term of a harmonic progression. If Tp = q (q + p) and Tq = p (p + q) where p >

1, q >1, then

(A) Tp + q = pq
(B) Tpq = p + q
(C) Tp + q > Tpq
(D) Tpq > Tp + q

5) If tn be the nth term of the series 1 + 3 + 7 + 15 +......, then

(A) t5 + 1 = 32
7
(B) t7 = 2 – 1
10
(C) t10 = 2 – 1
50
(D) t100 = 2 + 1

6) a, b, c are the first three terms of a geometric series. If the H.M. of a and b is 12 and that of b
and c is 36 then which of the following hold(s) good?

(A) Sum of the first term and common ratio of the G.P. is 11.
(B) Sum of the first five terms of the G.P. is 948.
If the value of the first term and common ratio of the given G.P. is taken as the first term and
(C)
common difference of an A.P. then 8th term of this A.P. is 29.
(D) The numbers 648 is one of the terms of the G.P.

SECTION - I (ii)

1) Let [x3 + x2 + x +1] = [x3 + x2 + 1] + x where [.] denotes the greatest integer function. The
number of solutions of the equation ([x])2 = 2-|[x]| is

(A) 1
(B) 0
(C) 3
(D) 2

2) Let p, q, r ∈ R+ and 27 pqr = (p + q + r)3 and 3p + 4q + 5r = 12 then p3 + q4 + r5 is equal to

(A) 3
(B) 6
(C) 2
(D) 1

3)

Let three positive integers a, b, c be in an increasing G.P. and b - a is a perfect cube of an integer. If
log6 a + log6 b + log6 c = 6 then a + b + c =

(A) 189
(B) 198
(C) 178
(D) 179

4) Let S be the set of integers which are divisible by 5 and let T be the set of integers which are
divisible by 7. The numbers of positive integers less than 1000 which are not in (S⋃T) is

(A) 684
(B) 685
(C) 686
(D) 687

5) If a + b + c = 1, ab + bc + ca = 2 and abc = 3, then a4 + b4 + c4 =

(A) 5
(B) 12
(C) 14
(D) 13

6) A.M. of numbers p and q exceeds their G.M. by 2. The number of ordered pairs (p,q) of integers
such that 0 < p < q < 1000 is

(A) 28
(B) 29
(C) 30
(D) 31

SECTION - II

1) The expression is equal to 'k'. The sum of the digits of 'k' is

(where denotes 0.11111.... )

2) Let a, b (a > b) are the two solutions of the equation

 , then the value of (a - 2b) is

3) The sum of all possible values of 'm' for which x2 + 2xy + 2x + my - 3 can be resolved into two
linear factors is

4) If then [S] =
([.] denotes greatest integer function)

5) Let a, b ∈ R and ab ≠ 1. If 6a2 + 20a + 15 = 0 and 15b2 + 20b + 6 = 0 then

ab2 - 9 (ab + 1)3 = kb3, where k is some constant. The value of (6k - 2014) is

6) Let and Q (y) = - 4y2 + 4y + . If there exists a unique pair of real numbers
(x, y) such that P (x) Q (y) = 20, then the value of 3x + 8y is
 ANSWER KEYS

PHYSICS

SECTION - I (i)

Q. 1 2 3 4 5 6
A. A,B,D A,C A,B,C A,D A,C,D A,B,C,D

SECTION - I (ii)

Q. 7 8 9 10 11 12
A. B A C C A B

SECTION - II

Q. 13 14 15 16 17 18
A. 0.00 3.00 9.00 4.00 9.00 6.00

CHEMISTRY

SECTION - I (i)

Q. 19 20 21 22 23 24
A. A,B,C,D A,D A,C A B,C,D A,B,C

SECTION - I (ii)

Q. 25 26 27 28 29 30
A. B B D B A A

SECTION - II

Q. 31 32 33 34 35 36
A. 6.00 7.00 5.00 3.00 2.00 5.00

MATHS

SECTION - I (i)

Q. 37 38 39 40 41 42
A. A,C,D A,B,C,D B,D A,B,C A,B,C A,C,D

SECTION - I (ii)

Q. 43 44 45 46 47 48
A. D A A C D B
 SECTION - II

Q. 49 50 51 52 53 54
A. 9.00 8.00 4.00 1.00 1.00 3.00
 SOLUTIONS

PHYSICS

1)

2)

3)

tanθ =
4)

g≥r

⇒
or,
R = uxT

5)

h = Vb,w t1, h = (Vb,w cosθ) t2

cosθ =

Vb,w =

Vw = Vb,w sinθ =

6)

t = 0, t = 4π

Motion of B is
SHM of amplitude = 8m

t = 0, t = 4π.
amax = w2A
vmax = wA

7)
Maximum height for incline plane

sin2 (θ – α) = 3/80

sin (θ – α) =
by small angle approximation
θ – α = 11°
θ = α + 11°
θ = 41°

&
= 40sin82°
R = 40 (Because sin82 = 0.99)

8) w =

=
= 2 rad/s

9)

10)

11)

I.f.:-

solving we get,

⇒
12)

13)

V(t) = 5 – 6e–t/2
x(t) = kt + ℓe–t/2 + m
at t = 0
x (0) = 7
7=0+ℓ+m ......(i)

v(t) = k – ⇐
k=5

⇐
Putting Value of ℓ in eqn (i)
m = –5

14)
uB cos(α + β) = uA

cos(α + β) =

α+β=

15)
 16)
Total time taken = t1 + t 2 + t 3 + ..............

= + ..........

Total time =
Total displacement = v1t1 + v2t2 +...........

On solving

<v> =

17)

18)
Let at certain moment its direction of motion makes an angle with the vertical as shown.

When

CHEMISTRY

19) Factual according to Fajan's Rule.

20)
(A) Thermal stability order : MgSO4 < SrSO4 < BaSO4
(B) Solubility in water : BeC2O4 > BaC2O4 > CaC2O4
(C) Melting point order : NaCl > KCl > LiCl
(D) Covalent character order : BeF2 > CaF2 > SrF2

21) It is the orbital that undergo hybridisation and not the electrons. For example, for orbitals
of nitrogen atom belonging to valency shell when hybridise to form four
hybrid orbitals, one of which has two electrons (as before) and other three have one electron
each. It is not necessary that only half filled orbitals participate in hybridisation. In some
cases, even filled orbitals of valence shell take part in hybridisation.

22) If y is internuclear axis then

dxy – dxy π
px – pz –
dxz – dxz δ
py – py s

23)

→ High melting and boiling point

→ non-directional nature
→ High solubility in polar solvent
→ Good conductors of electricity in molten state

24)

(A) Covalent character ∝ charge on cation

(B) Melting point ∝ Lattice energy

(C) Lattice energy ∝

25)

26) (I) 2s – 2s
(II) 2s – 2p
(III) 2p – 2p
(IV) 3s – 3s
III > II > I > IV

27)
3 on each I
3×3=9

28) For poly atomic anion

Thermal stability ∝ size of cation
Order of size of Cation - Be2+ < Mg2+ < Ca2+ < K+
Thermal stability order BeCO3 < MgCO3 < CaCO3 < KCO3

29) Hybridisation of 'S' in SF6 is sp3d2

(3s + 3px + 3py + 3pz + )

30) Ionic character ∝

As positive oxidation state increases or, size of cation decreases, polarizing power of cation
increases hence, the correct order of ionic character is :
MCl > MCl2 > MCl3

31)
2H + 2 axial F + 1C + 1S lie in the same plane.

32) Except and COS all are non-linear.

33) (a, b, c, d, h)

34)

PF5
sp3d (0 lone pair)
Trigonal bipyramidal

BrF4– ,
sp3d2 (2 lone pair)
 square planar

IF5
sp3d2 (1 lone pair)

square pyramidal
BrF5
sp3d2 (1 lone pair)

square pyramidal
XeOF4
sp3d2 (1 lone pair)

square pyramidal
–
ICl 4
3 2
sp d (2 lone pair)

square planar

35)

2 (i, ii)

36) NaCl, KF, RbCl, NaBr, KCl.

MATHS

37) Let roots be , a, ar, where a > 0 & r > 1.

 , , a3 = 1 ⇒ a = 1 ⇒ '1' is a root.
⇒1+p+q-1=0⇒p+q=0

Also, ⇒

∴ ⇒ - p - 1 > 2 ⇒ p <- 3.

∵ r > 1 ⇒ smaller root = < 1 and largest root = r > 1.

38) P = {A, S, O, C, I , T, V, E}
Q = {A, S, C, E, R, T, I, N}
P ∩ Q = {A, S, C, I, E, T}
∴ n (P ∩ Q) = 6
P - Q = {O, V}
∴ n (P - Q) = 2
Q - P = {R, N}
∴ n (Q - P) = 2
Also, n (P' ⋃ Q') = n ((P ∩ Q)') = 26-6 = 20
n ((P-Q) ⋃ (Q - P)) = 2 + 2 = 4
∴ n ((P - Q) ⋃ (Q - P))' = 26 - 4 = 2

39) All cyclic quadrilaterals are not necessarily rectangles. So, C - A is not necessarily ϕ. All
squares are trapeziums. So, B ⊂ D. Hence B - D = ϕ. Clearly, A ⊂ C.
All rectangles are cyclic quadrilaterals,
So, A ∩ C = A
Also, A ⊂ D. So, (A ⋃ D) = A. Hence (A ⋃ D) ∩ C = A

40) If a is first term and 'd' is common difference of corresponding A.P. then

x + (p -1) d = , x + (q -1) d =

(i) - (ii) gives d = . substituting values of x & d.

We get, Tp+q =

41) Since first order differences are in G.P. with c.r. = 2

so, tn = a (2)n + b
t1 = 2a + b = 1 & t2 = 4a + b = 3
⇒ a = 1, b = -1
⇒ tn = 2n - 1
⇒ t5 = 25 - 1, t7= 27 - 1, t10 = 210 - 1, t100 = 2100 - 1.

42) If 'r' is the common ratio of the G.P. then and

⇒ r = 3, a = 8.
⇒ a + r = 11,
t8 of A.P. = a = 7r = 2g.
648 = 8 (3)n-1 ⇒ 3n-1 = 81 ⇒n = 5

43) If [x3 + x2 + x +1] = [x3 + x2 +1] + x then 'x' must be an integer

⇒ [x] = x & ([x])2 = 2- |[x]| ⇒ x2 = 2 -|x|
x ≥ 0 : x2 + x - 2 = 0 ⇒ x = - 2, 1
x < 0 : x2 - x - 2 = 0 ⇒ x = 2, -1
Only acceptable values are x = -1,1.

44) Given, = pqr ⇒ A. M. = G.M. for p, q, r

⇒p= q=r
∴ 3p + 4q + 5r = 12
⇒ 3p + 4p + 5p = 12
⇒ p = 1, q = 1, r = 1
⇒ p3 + q4 + r5 = 3

45) log6 (abc) = 6 ⇒ abc = 66.

Let and c = br, where r = common ratio

⇒ b = 36 and
⇒ r = 2, 3, 4, 6, 9, 12, 18

Also, b - a = 36 is a perfect cube.

⇒ r = 4 ⇒ a + b +c = 9+ 36 + 144 = 189

46) For positive integers less than 1000,

n (s) = 199, n (T) = 142, n (S∩T) = 28
⇒ n (S⋃T) = n (S) + n (T) - n (S∩T) = 199 + 142 - 28 = 313.
⇒ n (S⋃T) = 999 - 313 = 686

47) (a + b + c)2 = a2 + b2 + c2 + 2 (ab + bc + ca)

⇒ 12 = a2 + b2 + c2 + 2 (2) ⇒ a2 + b2 + c2 = -3
Now, (a2 + b2 + c2) 2 = a4 + b4 + c4 + 2 (a2b2 + b2c2 + c2a2)
⇒ 9 = a4 + b4 + c4 + 2 [(ab + bc + ca)2 - 2abc(a + b + c)]
⇒ 9 = a4 + b4 + c4 + 2 [(2)2 - 2 x 3 x 1]
⇒ a4 + b4 + c4 = 13

48)
⇒
= 2 (∵ p < q)
So, possible pairs (12, 32), (22, 42), (32, 52), ...... (292, 312)

49) Expression =

=
= 81.

50) ⇒
put,
⇒ y2 -12y + 27 = 0
⇒ y = 3, 9
⇒
⇒ x = 4, 16
⇒ a = 16, b = 4
⇒ a - 2b = 8

51) Let x2 + (2y + 2) x + my - 3 = 0

Now, (y +1)2 - (my - 3) = y2 + (2 - m) y + 4 must be perfect square.

∴ (2 - m)2 - 16 = 0
⇒ m = -2 or, m = 6

52) ⇒
53) ∴ 6a2 + 20a + 15 = 0 and 15b2 + 20b + 6 = 0

⇒ a, are the roots of the equation 6x2 + 20x + 15 = 0

Now, ab2 – 9 (ab + 1)3 =

⇒k=
⇒ 6k - 2014 = 1.

54) =-

⇒ Pmax =

Q (y) = -4y2 + 4y + =

⇒ Qmax =

Now, Pmax x Qmax =

so, (x, y)
⇒ 3x + 8y = 3