07-12-2025

1001CJA106219250015 JA

PART-1 : PHYSICS

SECTION-I (i)

1) Three cylindrical shells of mass M and radius R are pushed to the right by a force F on a smooth
horizontal surface as shown. A simple pendulum of mass m and length ℓ is suspended from top of the
upper shell. Cylinders are massive while pendulum is light. The shells always remain together as
shown without losing contact with one another. The pendulum undergoes small oscillation.

(A)
The minimum time period of oscillation is .

(B)
The minimum time period of oscillation is .

(C)
The maximum time period of oscillation is .

(D)
The maximum time period of oscillation is .

2) A long thin capillary tube of radius r is dipped vertically into a liquid of density ρ and surface
tension σ. The liquid wets the tube partially, making a contact angle θ (where 0° < θ < 90°). The rise
of the liquid column is h. Consider the following four independent modifications made to the system.
Which of the above modifications will necessarily decrease the height of the liquid column compared
to the original height h ?

(A) The tube radius is halved.

(B) The liquid is heated so that its surface tension decreased by 20 %.
The tube is replaced by one with a hydrophobic coating such that the new contact angle
(C)
becomes θ' = 120°.

(D)
The experiment is repeated in an elevator accelerating upward with acceleration .

3) A ray of light is incident grazingly on face AB of a right angled prism as shown. It emerges out of
face AC, as shown, e = Angle of emergence. Refractive indices of different media have been shown
in the diagram. Choose the correct alternatives.
(A)
(B)
(C)

If the ray just fails to emerge out of the face AC of the prism, for , angle of refraction
(D)
at face AB is

4) Following are the graphs of angle of deviation versus angle of incidence.

(a) (b) (c)

Based on the above graphs, mark the correct options.

(A) Graph-a may be a part of the graph for ray of light that travels from denser to rarer medium.
Graph-b may be for ray of light that is totally internally reflected from a denser to rarer medium
(B)
boundary.
(C) Graph-c may be a part of the graph for ray of light that travels from rarer to denser medium.
(D) Graph-b may be a part of the graph for ray of light that is reflected from a plane mirror.

5) The values of for final rays to be parallel to the principal axis are: (focal lenghts of the
lenses are written above the respective lenses in the given figure)

(A)
(B)
(C)
(D) None of these

6)

A particle of mass m is attached to one end of a mass-less spring of force constant k, lying on a
frictionless horizontal plane. The other end of the spring is fixed. The particle starts moving
horizontally from its equilibrium position at time t = 0 with an initial velocity u0. When the speed of
the particle is 0.5 u0, it collides elastically with a rigid wall. After this collision :-

(A) the speed of the particle when it returns to its equilibrium position is u0
the time at which the particle passes through the equilibrium position for the first time is t =
(B)

(C)
the time at which the maximum compression of the spring occurs is
the time at which the particle passes through the equilibrium position for the second time is
(D)

SECTION-I (ii)

1) List-I contains four distinct thermodynamic scenarios. List-II contains five calculated values.
Match the scenario in List-I with the single correct numerical or algebraic result in List-II. Each

scenario in List-I maps to exactly one option in List-II. (Take : J/mol-k, ℓn2 = 0.7,

List-II
List-I
(Calculated
(Thermodynamic Scenario)
Result)

An irreversible heat engine (efficiency η = 0.8 × ηCarnot)

operates between 600 K and 300 K. It absorbs 1000 J of heat.
The work output W from this engine is used to drive a
(I) (P) 5.83
reversible (Carnot) refrigerator operating between 250 K and
300 K. Calculate the total heat Qdumped (in J) rejected into the
300 K reservoir by both the engine and the refrigerator.

Two identical blocks (mass m, specific heat C) are at initial

temperatures T1 = 300 K and T2 = 500 K. They are brought
(II) into thermal contact in an isolated system and reach a final (Q) 3000
common temperature. Calculate the total change in entropy
ΔSuniv (in J/k) for this irreversible process. (mC = 1000).
 A Carnot heat pump maintains a room at 27°C when the
outside temperature is –3°C. The heat loss from the room to
(III) (R) 64.5
the outside is 20 kW. Calculate the minimum electrical power
Pin (in kW) required to operate the pump.

One mole of an ideal gas undergoes an irreversible free

adiabatic expansion into a vacuum, doubling its volume (Vf =
(IV) (S) 2.0
2Vi). Calculate the total change in universal entropy ΔSuniv (in
J/k) for this process.

(T) 18
(A) I → Q;II → R;III → S;IV → P
(B) I → Q;II → S;III → P;IV → S
(C) I → R;II → Q;III → S;IV → P
(D) I → Q;II → S;III → P;IV → R

2) Match oscillations of List-I to angular frequencies of List-II. (Assume π2 = 10, U0 = 10 J, m = 10

kg, a = 2m)

List-I List-II

A bead slides without friction on a vertical

(I) hoop of radius R = 1m. For small oscillations (P) rad/s
near lowest point.

Oscillation frequency for small oscillations

(II) of a liquid column of length ℓ = 1m each in a (Q) rad/s
U-tube.

Particle of mass 10 kg in a 1D potential

(III) (R) rad/s
energy , small oscillations
near a minima.

For a mass m = 10 kg attached to two

(IV) identical springs k = 200 N/m each in (S) rad/s
parallel.

(T) rad/s
(A) I → Q;II → Q;III → P;IV → R
(B) I → T;II → S;III → P;IV → R
(C) I → Q;II → R;III → P;IV → S
(D) I → Q;II → S;III → P;IV → Q

3) Match the ratio of frequencies in horizontal and vertical directions (fV/fH) in list-II to the lissazious
figure in list-I.

List-I List-II
 (I) (P)

(II) (Q)

(III) (R)

(IV) (S)

(T)

(A) I → T;II → Q;III → P;IV → S

(B) I → R;II → T;III → Q;IV → R
(C) I → T;II → Q;III → R;IV → S
(D) I → T;II → R;III → Q;IV → R

4) A bird in air is diving vertically over a tank with speed 5 cm s–1. Base of tank is silvered. A fish in
–1
the tank is rising upward along the same line with speed 2 cm s The water level is falling at rate of

2 cm s–1. (Take : µwater = 4/3)

List–I List–II

(P) Speed of fish as seen by the bird directly (1) 8

Speed of the image of fish formed after

(Q) (2) 6
reflection into the mirror as seen by the bird
 Speed of bird relative to the fish looking
(R) (3) 3
upwards

Speed of image of bird relative to the fish

(S) (4) 4
looking downwards in the mirror

(5) 0
(A) P → 1;Q → 5;R → 4;S → 3
(B) P → 2;Q → 3;R → 4;S → 5
(C) P → 2;Q → 5;R → 1;S → 3
(D) P → 2;Q → 3;R → 1;S → 4

SECTION-II

1) A thin convex lens (focal length f = 20 cm) is fixed. An object is placed 30 cm in front of it. A plane
mirror is placed 50 cm from the lens on the other side. The mirror begins to move away from the
lens with a constant velocity of 10 mm/s. Find the speed (in mm/s) of the final image (formed after
refraction, reflection, and a second refraction) at the instant the mirror is 50 cm from the lens.

2) A thermally insulated cylinder is divided into two parts by a massless, conducting piston. The
cylinder is 1.0m long. Initially, the piston is at the center, with 2 moles of Helium at 300K on one
side and 1 mole of Hydrogen at 600 K on the other. The piston is released and is allowed to move
freely to a new equilibrium position. Find the final distance (in cm) of the piston from the end that
originally contained the Helium.

3) A thin equiconvex lens (refractive index µg = 1.5) is placed on a horizontal plane mirror. The
space between the lens and the mirror is filled with water (µw = 4/3). The focal length of the entire
combination (acting as a mirror) is found to be 18 cm. Find the radius of curvature (in cm) of the
lens surfaces.

4) A bead of mass m slides without friction on a rigid smooth circular hoop of radius R = 0.60 m. The
hoop rotates about a vertical diameter with angular speed Ω. The bead rests at a nonzero
equilibrium polar angle θ. For Ω = 4.85 rad/s find the angular frequency ω (in rad/s) of small
oscillations about that nonzero equilibrium (use g = 10 m/s2)

5) A tank of uniform cross-sectional area A = 1.00 m2 is filled with water to an initial height H0 =
1.00 m. At the bottom is a small circular hole of area a = 0.010 m2. A point object lies on the tank
bottom and is viewed from above through the water surface. Find the time taken (in sec) when
apparent depth becomes 0.50 m. (The refractive index of water is n = 1.33. Take g = 10 m/s2.)

6) A U-tube manometer contains an incompressible liquid of density ρ. A piston of mass m and area
A is placed on the left arm. On the right arm, the tube opens to the atmosphere. A small oscillation of
the piston causes SHM of the liquid column. Neglecting the mass of liquid as compared to the mass
of the piston. Find the angular frequency (in rad/s) for given values : ρ = 900, A = 4 × 10–4, m =
0.25.
7) The bottom of a container is made of an equi-convex lens. The focal length of the lens in air is 60
cm. Now its lower surface is silvered. The refractive index of the material of the lens is 1.5. Water is
filled in the container to a depth 30 cm. When an object is placed at a distance x cm above the water
surface on the principle axis of lens, the final image of the object coincides with the object. Find the

value of x. (given µwater = 4/3)

8) A point object is kept at a distance of 2m from origin on x-axis. A quarter cylinder of radius R = 30
cm and refractive index µ = 1.5 having its axis ⊥, to plane of paper is placed between the object and
the parabolic reflector at a distance of 130 cm from origin as shown in figure. The position of the
image (in cm) after reflection from the parabolic reflector y2 = 2x.

PART-2 : CHEMISTRY

SECTION-I (i)

1) For Hydrogen atom,

Where
Which is/are correct option :

(A)

(B)

(C)

Distance between 2nd radial nodes and 1st radial nodes is equal to 0.529
(D)

2) Which of the following statement(s) is (are) correct regarding the root mean square speed (Urms)
and average translational kinetic energy (εav) of molecules in a sample of an ideal gas ?

(A) Urms is doubled, when its temperature is increased four times

(B) εav at a given temperature does not depend on its molecular mass
(C) Urms is inversely proportional to the square root of its molecular mass
(D) εav is doubled when its temperature is increased four times

3) The correct statement(s) regarding given compounds is/are (P)

(Q) (R)

(S) (T)

(A) P and Q have different boiling points

(B) Q and R have different boiling points
(C) P and S have different boiling points
(D) Q, R and T are the same compound

4) Circle represents most basic nitrogen in these molecule. Which of the following is correct
representation ?

(A)

(B)

(C)

(D)

5) Which of the following compounds show following two properties :

(I) Oxidation states of all underlined atom is same in given compound
(II) Oxidation states of all oxygen atoms is same in given compound

(A) H2S2O5
(B) H2S2O6
(C) C3O2
(D) H2S2O8

6) Choose the correct option(s) :

(where d = internuclear distance)

(A) dP–C in PF4(CH3) < dP–C in PF3(CH3)2

(B) dP–F(e) in PF4(CH3) < dP–F(e) in PF3(CH3)2
(C) dP–F(a) < dP–F(e) in PF4(CH3)
(D) dP–C in PF3(CH3)2 < dP–C in PF2(CH3)3

SECTION-I (ii)

1) Match the items of List-I with those of List-II :

List-I List-II

Thomoson's Model of Electron are present in extra

(P) (1)
Atom nuclear region.

Rutherford's Model of
(Q) (2) Atom is neutral
Atom

Positive charge is concentrated in

(R) Bohr Model of Atom (3)
the nucleus.

Sommerfeld Model of Positive charge is uniformly

(S) (4)
Atom distributed.

(5) Stationary energy orbits.

The correct match is :
(A) P → 2,4;Q → 1,2,3;R → 3,5;S → 1,5
(B) P → 1,2,3;Q → 3,4,5;R → 1,2,3,4;S → 1,5
(C) P → 3,4,5;Q → 1,2,5;R → 1,5;S → 2,4
(D) P → 1,3;Q → 2,4;R → 1,4,5;S → 2,3

2) 10 mole of an ideal gas is filled in container A, fitted with a massless, frictionless piston, which is
in equilibrium position initially as shown in diagram. With container ‘A’ of cross sectional area 100
dm2, two more empty containers B and C are connected through the stop cocks as shown. Stop cock
I was opened for considerable time and then closed. Thereafter, stop cock II is opened for
considerable time and then closed.
(All containers are maintained at constant temperature)
 List-I List-II

(P) Final number of moles of gas in container B are (1)

(Q) Final number of moles of gas in container C are (2)

The ratio of height of piston after closing stop cock I

(R) (3)
and after closing the stop cock II is

The ratio of mean free path of molecules in container

(S) (4)
C and that in container B is

(5)

The correct match is :

(A) P → 4;Q → 1;R → 2;S → 3
(B) P → 3;Q → 4;R → 1;S → 2
(C) P → 1;Q → 2;R → 3;S → 4
(D) P → 2;Q → 3;R → 4;S → 1

3)

List-I List-II

(P) (1) Optically inactive

(Q) (2) Meso

(R) Anisole (3) Cannot show resonance

(S) (4) More acidic than water

 (5) DOU < 4

Match the correct code :

(A) P → 1;Q → 2;R → 4;S → 5
(B) P → 4;Q → 2;R → 1;S → 5
(C) P → 1;Q → 2;R → 3;S → 4
(D) P → 2;Q → 1;R → 5;S → 4

4) In a hypothetical world :

List-I List-II

n = 1 to ∞, ℓ = 0 to (n+1) , m = –ℓ to zero to (ℓ + 1),

(P) (1) 8
ms = , , ,
number of electrons having (n + ℓ) value 2 for Z = 52

n = 1 to ∞, ℓ = 0 to (n+1) , m = –ℓ to zero to (ℓ + 1),

(Q) (2) 24
ms = , , ,
number of electrons having |m| = 1 and 'ℓ < 2' for Z = 52

n = 1 to ∞, ℓ = 0 to (n+1) , m = –ℓ to zero to (ℓ + 1),

ms = ,
(R) (3) 16

number of electrons for which for Z = 52 [ℓ

≠ 0, m ≠ 0]

n = 1 to ∞, ℓ = 0 to (n+1) , m = –ℓ to zero to (ℓ + 1),

(S) (4) 2
ms = ,
number of electrons for which ℓ + m = 0 for Z = 52

(5) 14
Choose the correct option :
(A) P → 3;Q → 2;R → 5;S → 4
(B) P → 2;Q → 3;R → 4;S → 5
(C) P → 2;Q → 3;R → 5;S → 4
(D) P → 1;Q → 2;R → 3;S → 4

SECTION-II

1) The time period of revolution of the electron in ground state of H-atom is two times the time
period of the electron in first excited state of certain hydrogen like atom (atomic number Z). The
separation energy (minimum energy to remove electron from atom/ion) of electron (in ev) in third
excited level of hydrogen like atom is :
[Given that ground state energy of electron in H-atom = –13.6 eV]
2) 20.928 g of an element (M) is heated with NaOH and NaNO3 to produce Na2MO2 and NH3.
Ammonia produced is absorbed in 100 mL of 1 N H2SO4. Excess of the acid is back titrated with
NaOH solution and required 80 mL of 0.25 M NaOH solution up to the equivalence point. What is
the mass (in 'g') of hydrogen gas produced when 20 moles of 'M' is treated with excess of NaOH ?
[Atomic mass : Cr = 52; Zn = 65.4; Fe = 56; Cu = 63.5; Ni = 28; H = 1]

3) The number of compounds shows geometrical isomers:

(1) (2) (3)

(4) (5) (6)

(7) (8) (9)

4) Number of monochloro derivatives of methyl cycloheptane is x and number of fractions obtained

during fractions distillation of all the monochloro derivatives of methylcyclohexane is y than give
value of x – y

5) In how many options given below the value of Keq > 1

(i)

(ii)

(iii) CH≡CH + NaNH2

(iv)

(v)

(vi)

(vii)
(viii)

6) The number of molecules or ions in which atleast two tetrahedral units directly connected by a
common oxy-linkage.
S3O9 , , , Na2B4O7.10H2O , H2S2O6 , N2O3 (sym) , P4O10 , H2S2O7 ,
H2S3O6 , dimethyl ether

7) How many of the following statement is/are correct :

(A) Total number of oxygen shared per tetrahedron in Fe9Si9O27 is 2
(B) Total number of oxygen shared in 3 membered cyclic silicate and 4-membered single chain
silicate are not same
(C) Number of oxygen shared per tetrahedral in CaMn4Si5O15 and Al2(OH)4Si2O5 is same
(D) The general formula for phylo silicate is
(E) Total number of unshared oxygen atom in chain of 3 tetrahedron silicate is 8

8) Consider Palladium (Pd) and its electronic configuration

Number of unpaired electrons = x
Number of empty orbitals in outermost occupied shell = y
Number of completely filled orbitals having n – ℓ > 1 = z
Calculate value of x + y + z

PART-3 : MATHEMATICS

SECTION-I (i)

1) The equation ax2 – 6xy + y2 + bx + cy + d = 0 represents pair of lines whose slopes are m and m2,
if angle between the lines is θ, then (a > 0)

(A)

(B)

(C)

(D)

2) Consider an ellipse E :

Normal is drawn at a point P on E to intersect x and y axis at A and B respectively then locus of
(A)
circumcentre of ΔOAB is 4x2 + y2 = 9 (where O is the origin)
 Normal is drawn at a point P on E to intersect x and y axis at A and B respectively then locus of
(B)
circumcentre of ΔOAB is x2 + 9y2 = 4 (where O is the origin)

(C) Area of quadrilateral formed by foci and end points of minor axes of the given ellipse is sq.
units
If a tangent is drawn at P on E to intersect the x-axis and y-axis at L and M respectively then
(D)
minimum value of LM is 6 units

3) Let P(x1, y1) be a point on the hyperbola . The tangent at point P passes through the

point (0, –b) and the normal at point P passes through the point . If e denotes the
eccentricity of the hyperbola then which of the following is/are correct ?

(A) x1 =
(B) x1 = 2a
(C) y1 = b
(D) e2 = 2

4) If x + y = k is the tangent of ellipse then value of k is

(A) 5
(B) –4
(C) –5
(D) 4

5) If A(1, 3) and C(7, 5) are two opposite vertices of a square. The equation of a side through A can
be -

(A) x + 2y = 7
(B) x – 2y + 5 = 0
(C) 2x – y + 1 = 0
(D) 2x + y = 5

6) A parabola touches straight lines x – 2y + 13 = 0 and 2x + y + 1 = 0 at points P(17, 15) and Q(2,
–5) respectively then :

(A)
Focus of parabola is
(B) Directrix of parabola is x + y – 2 = 0
(C) Focus of parabola is (5, –1)
(D) Length of latus rectum of parabola is 16

SECTION-I (ii)

1) If e1 and e2 are the roots of the equation x2 – ax + 2 = 0, then match the following list-I with list-II.
 List-I List-II

If e1 and e2 are the eccentricities of the ellipse, and

(I) (P) 5
hyperbola, respectively then the values of 'a' are

If both e1 and e2 are the eccentricities of the

(II) (Q)
hyperbolas, then values of a are

If e1 and e2 are eccentricities of hyperbola and

(III) (R)
conjugate hyperbola, then values of a are

If e1 is the eccentricity of the hyperbola for which there

exist infinite points from which perpendicular tangents
(IV) (S) 1
can be drawn and e2 is the eccentricity of the hyperbola
in which no such points exist then the values of a are

(T) 0
(A) I → P;II → Q,R;III → R;IV → P
(B) I → T;II → P;III → S;IV → R
(C) I → R;II → S;III → P;IV → T
(D) I → S;II → R;III → Q;IV → P

2) Match the following list I with list II

List - I List- II

Lines x – 2y – 6 = 0, 3x + y – 4 = 0 and λx + 4y + λ2
(I) (P) 2
= 0, are concurrent, then the value of λ is

The points (λ + 1, 1), (2λ + 1, 3) and (2λ + 2, 2λ)

(II) (Q) 4
are collinear, then the value of λ is

If line x + y – 1 – λ = 0, passing through the

(III) intersection of x–y+1 = 0 and 3x + y – 5 = 0, is (R) –1/2
perpendicular to one of them then the value of λ is

If line y – x – 1 + λ = 0 is equidistant from the

(IV) (S) –4
points (1, –2) and (3, 4), then λ is

(T) 3
(A) I → R;II → T;III → Q,R;IV → S,T
(B) I → P,S;II → P,R;III → P;IV → P
(C) I → T;II → S;III → Q;IV → R
(D) I → Q;II → Q;III → R;IV → T

3)

List-I List-II

If a,b,c and d are four non zero real numbers such that
(d + a – b)2 + (d + b – c)2 = 0 and the roots of the
(I) (P) a + b + c = 0
equation a(b – c) x2 + b(c – a)x + c(a – b) = 0 are real
and equal then
 If a,b,c are real non zero positive number such that log
(II) (Q) a,b,c are in A.P.
a, log b, log c are in A.P. then

If the equation ax2 + bx + c = 0 and x3 – 3x2 + 3x – 1

(III) (R) a,b,c are in G.P.
have a common real root then

Let a,b,c be positive real numbers such that the

(IV) (S) a,b,c are in H.P.

expression is non
negative ∀ x ∈ R then

(T) a – b – c = 4
(A) I → R;II → S;III → T;IV → Q
(B) I → P;II → Q;III → R;IV → T
(C) I → T;II → P;III → Q;IV → S
(D) I → Q,R,S;II → R;III → P;IV → Q

4)

Let an ellipse touches y = x at origin and foci F1, F2 on x = 1, x = –1 respectively. It is given that
9a2 = 40 where a is semi major axis of the ellipse

List - I List- II

(I) Number of such ellipse is/are (P) 1

(II) If e is the eccentricity of the ellipse, then 20e2–14 can be (Q) 0

(III) (R) 3
is

(IV) (S) 2
(where [.] denotes greatest integer function) is

(T) 6
(A) I → S;II → R;III → P;IV → Q
(B) I → R;II → Q;III → P;IV → S
(C) I → S;II → Q;III → R;IV → T
(D) I → T;II → R;III → S;IV → Q

SECTION-II

1) If α and β are roots of the equation x2 – 6x + 12 = 0 and the value of is ab

where a and b are natural numbers then the least value of is equal to

2) Given a, b ∈ {0, 1, 2, ....., 6}. Consider the system of equations

x + y + z = 4,
2x + y + 3z = 6,
 x + 2y + az = b
If the number of ordered pairs (a, b) so that the system of equations has unique solution is λ,
then equals

3) A variable chord of hyperbola subtends a right angle at center of hyperbola. If this

chord touches a fixed circle concentric with hyperbola, then square of radius of this circle is

4) If the length of the major axis of an ellipse is 100 and eccentricity = , then the area of the
rectangle formed by joining the vertices of latus recta of the ellipse is equal to

5) Consider four lines L1,L2,L3 and L4

L1 : passing through (2,a) and (b,3)
L2 : 3x + 4y – 5 = 0
L3 : 3x – 5y + 1 = 0
L4: 10x + ay + 9 = 0
If lines L1 and L2 are parallel and lines L3 and L4 are perpendicular then value of |a – b| is

6) For an increasing G.P. a1,a2,a3........., an, if a6 = 4a4, a9 – a7 = 192, then the value of is

7) If the locus of the point of intersection of two tangents to a parabola y2 = 4x at the points whose

ordinates have the constant ratio 4 : 1 can be expressed as (where p and q are integers in
lowest form), then (p + q) is

8) If a tangent of slope m at a point of the ellipse passes through (2a, 0) and if e denotes
the eccentricity of ellipse, then 3m2 + e2 is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. A,D B,C,D A,D A,B,D A,B,C A,D

SECTION-I (ii)

Q. 7 8 9 10
A. A A D D

SECTION-II

Q. 11 12 13 14 15 16 17 18
A. 20.00 66.66 to 66.67 24.00 3.43 to 3.48 8.20 to 8.30 5.30 to 5.40 13.50 50.00

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. B A,B,C A,D A,B,C B A,B,D

SECTION-I (ii)

Q. 25 26 27 28
A. A A B B

SECTION-II

Q. 29 30 31 32 33 34 35 36
A. 13.60 40.00 6.00 6.00 6.00 5.00 3.00 21.00

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. B,D A,C,D A,C,D A,C A,C C,D

SECTION-I (ii)

Q. 43 44 45 46
A. A B D A
 SECTION-II

Q. 47 48 49 50 51 52 53 54
A. 8.00 6.00 8.00 3750.00 0.00 2.00 29.00 1.00
 SOLUTIONS

PART-1 : PHYSICS

1)

Correct Answer is (A,D)

2)

Correct Answer is (B,C,D)

3)
From the diagram we can refer that ......(1)
Using Snell's law at AB
(2)
Using Snell's law at AC
.....(3)
From eqn. (1) we can say that .........(4)
Squaring and adding 2 and 4 we get:
.......(A)

If ray fails to emerge from AC then

If ray just fails to emerge, then .......(4)

4) Light travels from rarer to denser medium

δ=i–r

non-linear increasing function of i.

slope of tangent :
Slope of tangent increases as I increases
Hence ‘c’ is not the graph for light that travels from rarer to denser medium.

5)

d1 can take any value.

a,b,c are correct

6) Collision is elastic so energy is conserve in

given question so when it return to equilibrium, its speed is u0
by
Time period if collision not occurs T = Now time to

return for the first time at equilibrium =

=
time for option (C)

time for option (D) =

7)

Correct Answer is (A)

8)

Correct Answer is (A)

9)

Correct Answer is (D)

10)

Correct Answer is (D)

11)

Correct Answer is (20.00)

12)

Correct Answer is (66.66 to 66.67)

13)
Correct Answer is (24.00)

14)

Correct Answer is (3.43 to 3.48)

15) Tank depth H(t). Drain via orifice at bottom : Torricelli states exit speed .

Volume conservation :

Integrate :

So,
Apparent depth (object at bottom, viewed from above through air-water interface): apparent
depth happ(t) = H(t)/n for small viewing angles (vertical).

So,

16) For small oscillations, restoring force arises from hydrostatic pressure :
Pressure difference :
ΔP = ρg(2x)
Upward force on piston :
F = AΔP = 2ρgAx.
Equation of motion:

Thus,
Plug values :

= 5.31 rad/s

17) For refraction at first surface of the lens,

⇒ u = –48 cm
If the object is placed h cm above the water surface, after refraction at the water surface its

image will be formed at distance from the surface

 18)
After refraction through the quarter cylinder the emergent ray falls on the parabolic reflector
parallel to x-axis.

PART-2 : CHEMISTRY

19)

σ2 – 4σ + 3 = 0

σ=
⇒ σ = 1 and 3

20)

21)

The correct answer option is (A), (D)

22) In (A), (B) and (C) ‘N’ atoms of circle have localised lone pair which do not take part in
resonance.
In (D) double bonded nitrogen is more basic.
23)

The correct answer is option (B)

24)

The correct answer is option (A),(B),(D)

25)

Theoretical.

26) Initially : nA = 10, V = 15 × 100 = 1500 dm3

TA = 300 K,
(P) After opening valve I
PB = PA = 2R

(Q) After opening valve II

PC = PA = 2R

(R) h1 = 14

h2 = 12

(S)

27)

The correct answer option is (B)

28)

The correct answer is option (B)

29)
TH-atom = 2TH-like atom

z2 = 16
z=4
separation energy in 3rd excited level is
= E∞ – E4 = –E4

= –13.6 eV
ionization energy = +13.60 eV

30) 4M + 7NaNO + NaNO3 → 4Na2MO2 + NH3 + 2H2O

moles of NH3 formed = = 0.08

∴ moles of M used = 4 × 0.08 =

∴ At. wt. of M = 65.4
M = 65.4
So, 'M' is zinc (Zn)
Zn + 2NaOH → Na2ZnO2 + H2(g)
1 mol 1 mol
20 moles 20 moles
So, mass of H2 gas produced = 20 × 2 = 40 g.

31)

1, 3, 5,7, 8, 9, shows G.I.

32) Number of monochloro derivatives of methyl cycloheptane is

⇒ Total product = 14
Number of monochloro derivatives of methylcyclohexane is :

⇒ Total product = 12
Fraction
1 1 2 2 2
Total fraction = 8
So, x – y
 = 14 – 8 = 6

33) (iii), (iv), (v), (vi), (vii), (viii)

34)

The correct answer is 5.00

S3O9 , Na2B4O7.10H2O , P4O10 , H2S2O7 dimethyl ether

35)

The correct answer is 3.00

(A),(E),(F)

36)

The correct answer is 21.00

PART-3 : MATHEMATICS

37)

Question Explanation: Determine the correct statement(s) about the pair of

lines ax2−6xy+y2+bx+cy+d=0, given that their slopes are m and m2.
Concept: Slopes of a pair of lines.
Solution: m2+m−6=0⟹m=2 or m=−3. a=m3.
Calculation: m=2: a=8. Slopes 2,4. tanθ=2/9. tan2θ=36/77. m=−3: a=−27. Slopes −3,9.
Final Answer: B, D

38) A(3cosθ, 0) B(0, –6sinθ)

2h = 3cosθ, 2k = –6sinθ

⇒
4x2 + y2 = 9

(C) ,

&
B1(0, 2) & B2(0, –2)

(D)
L = (4secθ, 0) M = (0, 2cosecθ)
 LMmin = 6

39) The equation of tangent at P(x1, y1) is It passes through (0, –b), so 0 +
= 1 ⇒ y1 = b

Also, equation of normal at P(x1, y1) is = a2e2

It passes through , so

= a2e2 ⇒ x1 =

So,

As P(x1, y1) lies on the hyperbola = 1, so =1

⇒ = 2 ⇒ e4 = 4 ⇒ e2 = 2

40)
Given tangent x + y = k
y = –x + k
T : y = mx
T : y = –x + k
m = –1 = ±5

41) Let slope of AB be m.

Now, slope of

So, ⇒ 3m – 1 = ±(m + 3)

⇒
Hence, side through A can be

y – 3 = 2(x – 1) or

42) Point (–3, 5) will lie on directrix of parabola.

PQ will be a focal chord and equation PQ is 4x – 3y – 23 = 0
Focus S will be foot of perpendicular
drawn from (–3, 5) on 4x – 3y – 23 = 0

⇒ x = 5 & y = –1
⇒ focus S is (5, –1)
Foot of perpendicular from focus on a tangent lies on tangent at vertex
⇒ Foot of perpendicular from focus on given tangent are A(1, 7) & B(1, –3)
⇒ tangent at vertex is x = 1
⇒ directrix of parabola x = –3
⇒ Length of L.R. = 2(8) = 16

43) (I) We must have, e1 < 1 < e2

⇒ f(1) < 0
⇒1–a+2<0
⇒a>3
(II) We must have both roots greater than 1
(i) D > 0 or a2 – 4 > 0 or a ∈ (–∞, –2) ∪ (2, ∞)
(ii) 1 f(1) > 0 or 1 – a + 2 > 0 or a < 3

(iii)
Thus, we have a ∈ (2, 3)

(III) We must have

(IV) We must have

44) (I)

(II)
(III) Point of intersection of x – y + 1 = 0
and 3x + y – 5 = 0 ⇒ λ = 2
(IV) Mid-point of (1, –2) and (3, 4) will satisfy y – x – 1 + λ = 0 ⇒ λ = 2

45) (I) d + a – b = 0 and d + b – c = 0

d = b – a and d = c – b
∴ b – a = c – b ⇒ 2b = a + b ⇒ a,b,c are in A.P.
also x = 1 satisfies the 2nd equation
∴ other root is also 1
∴ product of roots = 1

∴ c(a – b) = a(b – c) ⇒ ⇒ a,b,c are in H.P.

∴ a,b,c are in A.P. and a,b,c in H.P. ⇒ a,b,c are in G.P.
(II) 2 log b = log a + log c ⇒ b2 = ac
(III) (x – 1)3 = 0 ⇒ x = 1 is the common root
hence a + b + c = 0
(IV) (a + c)2 + 4b2 – 4b(a + c) < 0 (D < 0)
2
((a + c) – 2b) < 0
⇒ a + c = 2b ⇒ a,b,c in A.P.

46) Let F1(1, β) and F2(–1, α) be the foci

image of F2 in y = x is F21
here F1, 0 and F21 are collinear

⇒ ⇒ αβ = –1

OF1 + OF2

⇒
⇒ or
F1F2 = 2ac
⇒ 4 + (α – β)2 = 4a2e2

⇒4+ and

⇒ e22 =

47) α + β = 6 αβ = 12 (α – 2)3 = α3 – 8 – 3α.2(α – 2)

2
= α(α – 6α + 12) – 8
⇒ –8 ⇒ (α – 2)24 = 88

β2 – 6β + 12 = 0 ⇒

(β – 6)8 = ⇒
⇒ 88 – 1 + 1 = 88
⇒ a = 8, b = 8

48)
unique solution a ≠ 0
ordered pair = 6 × 7

49) Let variable chord be xcosα + ysinα = p Let this chord intersect the hyperbola at A and B.
Combined equation of OA and OB :

(coefficient of x2) + (coefficient of y2) = 0

⇒
⇒ p2 = 8
∴ Line : xcosα + ysinα =
Thus touches a fixed circle x2 + y2 = 8

50) Area = (2ae)(2b2/a) = 4eb2 = 4ea2(1 – e2)

=
51)

Given m1 = m2 ⇒
⇒ 6 = 4a – 3b ......(i)

m3.m4 = –1 ⇒
⇒ a=6 ........(ii)
∴ a = 6, b = 6

52) a6 = 4a4 ⇒ ar5 = 4ar3 ⇒ r2 = 4 ⇒ r = ±2

but for increasing, r = 2
a9 – a7 = 192 ⇒ ar8 – ar6 = 192
ar6(r2 – 1) = 192
a26(3) = 192 ⇒ a = 1

53) Given
⇒ t1 = 4t2
Let point of intersection be (h, k)
∴ h = t1t2 k = t1 + t2
⇒h= ⇒ k = 5t2

∴ ⇒
∴ p + q = 25 + 4 = 29

54) passes through (2a,0)

4a2m2 = a2m2 + b2 ⇒ b2 = 3a2m2

&

3m2 = ⇒ 3m2 + e2 = 1