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0% found this document useful (0 votes)
4 views38 pages

Solution

The document contains a series of physics, chemistry, and mathematics problems, each with multiple-choice answers. It covers topics such as mechanics, thermodynamics, chemical reactions, and mathematical functions. The problems are designed for examination purposes, testing knowledge in various scientific and mathematical concepts.

Uploaded by

jotsnasonkusale
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

15-02-2026

0999DJA161151250008 JA

PART-1 : PHYSICS

SECTION-I

1) A rocket is projected straight up and explodes into three equally massive fragments just as it
reaches the top of its flight. Once of its fragment is observed to come straight down in time t1. While
other two land simultaneously at a time t2, after the burst. The height at which fragmentation occurs

is: (Assume g is constant)

(A)

(B)

(C)

(D)

2) A particle A moving with momentum p suffers a one-dimensional collision with a particle B of the
same mass but at rest. During the collision B imparts an impulse I to A. The coefficient of restitution
between A and B is

(A)

(B)

(C)

(D)

3) Moment of inertia of a thin uniform semicircular wire having mass M, radius R and centre C about
an axis passing through point O and perpendicular to its plane is :

MR2
(A)

(B)
2MR2
(C) 2MR2

(D)
2MR2

4)

A yo-yo, arranged as shown, is placed on a frictionless horizontal surface. When a force F is applied
to the string, the yo-yo:

(A) moves to the right and rotates counterclockwise


(B) moves to the left and rotates clockwise
(C) moves to the right and rotates clockwise
(D) moves to the right and does not rotate

5) Portion AB of the wedge shown in figure is rough and BC is smooth. A solid cylinder rolls without
slipping from A to B. The ratio of translational kinetic energy to rotational kinetic energy, when the

cylinder reaches point C is

(A) 3/4
(B) 5
(C) 7/5
(D) 8/3

6) If the ratio of lengths, radii and Young’s moduli of steel and brass wires in the figure are a, b and

c respectively, then the corresponding ratio of increase in their lengths is :–

(A) 2a2c/b
(B) 3a/2b2c
(C) 2ac/b2
(D) 3c/2ab2

7) The value of tension in a long thin metal wire has been changed from T1 to T2. The lengths of the
metal wire at two different values of tension T1 and T2 are ℓ1 and ℓ2 respectively. The actual length of
the metal wire is

(A)

(B)

(C)

(D)

8) A beaker of volume V is completely filled with a liquid of density . The temperature of the system
is increased by T K. Find the mass of liquid overflown if volumetric thermal expansion coefficient of
beaker is and of the liquid is thrice that of beaker.

(A) 2γVTρ

(B)

(C)

(D)

9) Two solid objects of the same mass are supplied with heat at the same rate ΔQ / Δt. The
temperature of the first object with latent heat L1 and specific heat capacity c1 changes according to
graph 1 on the diagram. The temperature of the second object with latent heat L2 and specific heat
capacity c2 changes according to graph 2 on the diagram. Based on what is shown in the graph, the
latent heats L1 and L2, and the specific heat capacities c1 and c2 in solid state obey which of the
following relationships:

(A) L1 > L2; c1 < c2;


(B) L1 < L2; c1 < c2;
(C) L1 < L2; c1 > c2;
(D) L1 > L2; c1 > c2;

10) Six identical conducting rods are joined as shown in figure. Points A and D are maintained at
temperature 200°C and 20°C respectively. The temperature of junction 'B' will be :-

(A) 120°C
(B) 140°C
(C) 100°C
(D) 80°C

11) Two highly conducting shells A and B have radius R and 2R and are concentric. Temperature of
A is maintained at 2T0 and the arrangement is kept in an encloser of temperature T0 as shown. In
steady state the temperature of B is :

(A)

(B)

(C)
(D) None of these

12) 4 mole of monoatomic gas ; 3 moles of diatomic gas and 3 moles of triatomic

gas are mixed. Equivalent γ of the mixture is :-


(A)

(B)

(C)

(D)

0 0

13) One mole of a diatomic gas undergoes a process where P , V are constants.
The translational kinetic energy of the gas when V = V0 is given by :

(A)

(B)

(C)

(D)

14) A diatomic gas of molecular weight 30 gm/mole is filled in a container at 27°C. It is moving at a
velocity 100 m/s. If it is suddenly stopped, the rise in temperature of gas is :

(A) 60/R

(B)

(C)

(D) None of these

15) The temperature-entropy diagram of a reversible engine cycle is given in the figure. Its

efficiency is :

(A)

(B)

(C)
(D)

16) A carnot engine having efficiency 40% used as refrigerator. If work done by the compressor of
gas is 100J, find heat absorbed from the body having lower temperature.

(A) 250 J
(B) 100 J
(C) 150 J
(D) None

17) A certain amount of ideal monoatomic gas undergoes process given by TV1/2 = C where T is the
temperature of the gas. The molar specific heat of the gas for the process will be given by :-

(A) R/2
(B) 3R
(C) 5R/2
(D) – R/2

18) There are two identical small holes of area of cross-section a on the opposite sides of a tank
containing a liquid of density ρ. The difference in height between the holes is h. The tank is resting
on a smooth horizontal surface. Horizontal force which will has to be applied on the tank to keep it

in equilibrium is :

(A) ghρa

(B)

(C) 2ρagh

(D)

19) A cubical sealed vessel with edge L is placed on a cart, which is moving horizontally with an
acceleration ‘a’ as shown in figure. The cube is filled with a ideal fluid having density ρ. The

pressure difference between centre and top right corner is

(A)

(B)
(C)

(D)

20) An open pan P filled with water (density ρw) is placed on a vertical rod, maintaining equilibrium.
A block of density ρ is placed on one side of the pan as shown in the figure. Water depth is more

than height of the block.

(A) Equilibrium will be maintained only if ρ < ρw.


(B) Equilibrium will be maintained only if ρ < ρw.
(C) Equilibrium will be maintained for all relations between ρ and ρw
(D) It is not possible to maintained the equilibrium

SECTION-II

1) A thin plate is placed horizontally between two flat surfaces h cm apart such that the viscosity of
liquids on the top and bottom of the plate are μ1 and μ2 respectively. Determine the position (in SI
units) of the thin plate with respect to upper surface such that the viscous resistance to uniform
motion of the thin plate is minimum. [Assume h to be very small] (μ1 = 4, μ2 = 9, h = 5 in SI units)

2) Two particles P1 and P2 are performing SHM along the same line about the same mean position.
Initially they are at their positive extreme position. If the time period of each particle is 12 sec and
the difference of their amplitudes is 12 cm then find the minimum time (in sec) after which the
separation between the particle become 6 cm.

3) Consider the given system. All string, pulleys and spring are ideal, mass M is in equilibrium.

Maximum amplitude of oscillation of block in vertical direction is . Find value of α.

4) Two thin planks moving on four identical cylinders as shown. There is no slipping at any contact
points. Calculate the ratio of angular speed of upper cylinder to lower cylinder.
5) An ideal diatomic gas is expanding according to process V ∝ T5/2. When temperature of gas is

increased from 27°C to 28°C the average time between collisions of molecules increases by .
Find value of N.

PART-2 : CHEMISTRY

SECTION-I

1) During hearing of a court case, the judge suspected that some changes in the documents had
been carried out. He asked the forensic department to check the ink used at two different places.
According to you which technique can give the best results?

(A) Column chromatography


(B) Solvent extraction
(C) Distillation
(D) Thin layer chromatography

2) Dumas method involves the determination of nitrogen content in the organic compound in form of

(A) NH3
(B) N2
(C) NaCN
(D) (NH4)2SO4

3) Which of the following is meso compound :-

(A)

(B)
(C)

(D)

4) Identify conformer of 2-methyl pentane :

(A)

(B)

(C)

(D)

5) The molecular formula of diphenylmethane

, is C3H12 ;
How many structural isomers are possible when one of the hydrogen is replaced by a chlorine atom
?

(A) 6
(B) 4
(C) 8
(D) 7

6) Decreasing order of stabilities of following carbocation is :

(A) IV > III > II > I


(B) I > II > III > IV
(C) II > IV > III > I
(D) I > III > IV > II

7) Which of the following compound is aromatic?

(A)

(B)

(C)

(D)

8) Which of following is feasible reaction

(A)
+ NaOH

(B) CH3 – C ≡ CH + NaOH


(C)

+ NaHCO3
(D) HC ≡ CH + NaNH2

9) The most strongest basic group present in amoxycillin is :

(A)

(B)

(C)

(D)

10)

In which of the following compound steric inhibition of resonance is present :

(A)

(B)

(C)
(D)

11)
Compare acidic strength of H-atoms marked.

(A) H1 > H2
(B) H2 > H1
(C) H1 = H2
(D) Cannot compare

12) Which of the following pairs of compounds is a pair of enantiomers ?

(A)

(B)

(C)

(D)

13) In an experiment of Photoelectric effect graph for KEmax of ejected photo electron v/s frequency
0

of incident light is plotted. Then threshold wavelength(λ ) of


metal is -

(A) 310 nm
(B) 400 nm
(C) 4000 nm
(D) 3100 nm

14) The de-Broglie wavelength of electron moving in 3rd excited state of He+ ion is :

(A) 4.24 π Å
(B) 1.59 π Å
(C) 2.12 π Å
(D) 1.06 π Å

15) When an electron is brought close to the nucleus of the atom from an infinite distance, the
energy of the electron-nucleus system changes such that it

(A) Increases to a smaller negative value


(B) Increases to a greater positive value
(C) Decreases to a smaller positive value
(D) Decreases to a greater negative value

16) An orbital has 1 radial node and one angular node, then orbital and its radial wavefunction
distribution are respectively:

(A)

3s &
3p &

(B)
(C)

2p &

(D)

3d &

17) The value of KP for the reaction, is 4.00 atm at 627°C. If initially
atm, atm and pure graphite = 2 mol is present. Which of the following
statement is true

(A) Reaction proceed forward more than backward to attain equilibrium


(B) Reaction proceed backward more than forward to attain equilibrium
(C) Concentration of C(s) in molarity decreases at equilibrium than initial
(D) The reaction mixtures are at equilibrium form the beginning itself

18) The equilibrium constant for the given reaction :

SO3(g) SO2(g) + O2(g) ; Kc = 4.9 × 10–2


The value of Kc for the reaction :
2SO2(g) + O2(g) 2SO3(g), will be

(A) 416
(B) 2.40 × 10–3
(C) 9.8 × 10–2
(D) 4.9 × 10–2

19) A solid XY kept in an evacuated sealed container undergoes decomposition to form a mixture of
gases X and Y at temperature T. The equilibrium pressure is 10 bar in this vessel. KP for this reaction
is :
XY(s) X(g) + Y(g)

(A) 25
(B) 5
(C) 10
(D) 100

20) 2.56gm of sulphur S8(s) is taken which is in equilibrium with its vapours according to reaction :
S8(s) S(g)
If vapours occupies 960 ml at 1atm, 300K, then degree of dissociation of S8(s) will be -
[R = 0.08 atm L / mol-K]

(A) 1/4
(B) 1/20
(C) 3/8
(D) 1/2

SECTION-II

1) 0.400 g of an organic compound (X) gave 0.376 g of AgBr in Carius method for estimation of
bromine. % of bromine in the compound (X) is_____.
Given: Molar mass AgBr = 188 g mol–1 Br = 80 g mol–1)

2) Testosterone, which is a steroidal hormone, has the following structure.

The total number of asymmetric carbon atom/s in testosterone is ______

3) How many of the following compounds will have POS (Plane of symmetry) :

(i) (ii)

(iii) (iv)

(v) (vi)
(vii) (viii)

4) Calculate change in potential energy (in eV) when an electron move from ground state to third
excited state in He+.

5) 2NOCl(g) 2NO(g) + Cl2(g)


In an experiment, 2.0 moles of NOCl was placed in a one-litre flask and the concentration of NO
after equilibrium established, was found to be 0.4 mol/L. The equilibrium constant at 30°C is ______
× 10–4.

PART-3 : MATHEMATICS

SECTION-I

1)

y intercept of common tangent of curves y2 = 256x and x2 = 32y is

(A) 32
(B) 16
(C) –32
(D) –64

2) Consider all possible permutations of the letters of the word EARTHQUAKE, then the number of
permutation containing the word RAHU is -

(A)

(B)

(C) 7!
(D) None of these

3) If the line ℓx + my + n = 0 is tangent to the circle x2 + y2 – 2ax = 0, then

(A) n2 + 2aℓn – a2m2 = 0


(B) n2 + 2aℓn + a2m2 = 0
(C) n2 – 2aℓn + a2m2 = 0
(D) a2m2 + 2aℓn – n2 = 0
4) The total number of functions

f : {1, 2, 3, 4} → {5, 6, 7, 8} such that is an odd number is

(A) 256
(B) 64
(C) 128
(D) 32

5) The number of positive integral divisors of the number


N = 1000C1 + 2.1000C2 + 3.1000C3 + ..... + 10001000C1000 is λ, then sum of the digits of λ is

(A) 7
(B) 8
(C) 6
(D) 5

6) The eccentricity of the conic (2x – 4)2 + 4y2 = (x + y + 1)2 is

(A)

(B)

(C) 2
(D)

7) Equation of the plane passing through the origin and perpendicular to the plane x + y + z = 1 and
x + 2y + z = 1 is

(A) 3x – 4y + z = 0
(B) x + 2y – 5z = 0
(C) x – 2y – 3z = 0
(D) x – z = 0

8) The angle between the pair of tangents drawn to the curve 7x2 – 12y2 = 84 from the point (1,2) is

(A)

(B) 2tan–12

(C)

(D) 2tan–13

9)
If and , then is

(A)
(B) e2
(C) 1
(D)

10) How many ways can 3 men and 4 women be arranged in a row such that no two women are
seated together ?

(A) 720
(B) 144
(C) 2880
(D) 4320

11) Locus of midpoint of chords of the circle x2 + y2 = 25, which are tangents to the circle x2 + y2 –
20x – 20y + 175 = 0 will be :

(A) (10x + 10y + x2 + y2)2 = (x2 + y2)


(B) (10x + 10y – x2 + y2)2 = 100 (x2 + y2)
(C) (10x + 10y – x2 – y2) = 25 (x2 + y2)
(D) (10x + 10y – x2 – y2)2 = 25 (x2 + y2)

12) If the term independent of x in the is 405, then k equals-

(A) 2, – 2
(B) 3, – 3
(C) 4, – 4
(D) 1, –1

13) Arithemetic Mean of observations will be

(A)

(B)

(C)

(D)

14) Ratio of variances of first n positive multiples of 5 and first n positive multiples of 10 will be :
(A) 1 : 2
(B) 1 : 1
(C) 1 : 4
(D) 1 : 5

15) There are three bags X, Y and Z. Bag X contains 5 one-rupee coins and 4 five-rupee coins; Bag Y
contains 4 one-rupee coins and 5 five-rupee coins and Bag Z contains 3 one-rupee coins and 6 five-
rupee coins. A bag is selected at random and a coin drawn from it at random is found to be a one-
rupee coin. Then the probability, that it came from bag Y, is :

(A)

(B)

(C)

(D)

16) The number of ways of selection of 4 letters of the word 'PERFECT " is

(A) 15
(B) 21
(C) 25
(D) 31

17) In a group of 8 boys, two boys are brothers. In how many ways they can sit in a row if brothers
do not sit together, is

(A) 4820
(B) 1410
(C) 2830
(D) 30240

18) Number of rational terms in the expansion of is :-

(A) 17
(B) 20
(C) 102
(D) 150

19) Let z = x + iy and |z – 3| = 2|z + 1|. Then locus of z is a (x, y ∈ R)

(A) straight line with slope 2

(B)
circle with centre
(C) parabola with vertex (1, 1)

(D)
ellipse with eccentricity

20) Among the complex numbers which satisfies |z – 3 + 3i| = 3, then the complex number having
least positive argument is

(A) 3
(B) 3i
(C) –3i
(D) None of these

SECTION-II

1) Suppose F1 & F2 are the foci of the ellipse 4x2 + 9y2 = 36. P is point on the ellipse such that |PF1| :
|PF2| = 2 : 1, then area of ΔPF1F2 is :-

2) If N denotes the number of four digit natural numbers formed by using only even digits. Then
is

3) Number of integral values of n for which the quantity (n + i)4 is real

4) Let f : R → R and f(x) = x3 + x2 + x – 36, then solution for x of equation f(x) = f–1(x), is :

5) Number of points where f(x) = |(2x – 1).(3x – 3)x.(x – 1).(x – 2)| is not differentiable
ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D B B A B B A B B B C D B A C C D C B B

SECTION-II

Q. 21 22 23 24 25
A. 2 2 4 4 2

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D B D D B A D D A A B B B C D B A A A D

SECTION-II

Q. 46 47 48 49 50
A. 40 6 4 102 125

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C B A C A B D C A B D B C C A C D A B C

SECTION-II

Q. 71 72 73 74 75
A. 4 4 3 3 1
SOLUTIONS

PART-1 : PHYSICS

1)

By momentum conservation principle


V3 = V2 = V
2Vcosθ = V1

–h = –V1t1 –

⇒ = (2νcosθ)t1 + .......(i)

Now, –h = (V cosθ)t2 –

h = (–V cosθ)t2 + .....(i)


From (I) & (II)

h=

2)

For A
– J = ΔP
– J = Pf – Pi

– J = Pf – P

for B
I = ΔP

3)
IC = MR2

x= =

∴ ICM = IC – Mx2 = MR2 –

= MR2
∴ I0 = ICM + M(R – x)2

= MR2 + MR2

0
I = MR2 =2

4)

Correct answer is (A)

5)

Correct answer is (B)

6) TS = 3mg

= yS ×

= yb ×

7)
T2ℓ1 – T2ℓ 0 = T1ℓ 2 – T1ℓ 0
(T1 – T2)ℓ 0 = T1ℓ 2 – T2ℓ 1

8) ΔVapparent = (γliquid – γbeaker)V × T


Mass = ΔVapparent × ρchanged

= (3 γ – γ)

9)

Correct answer is (B)

10)
Req = 3R

i=
TB = 200 – 60 = 140°C

11) For shell B to be in steady state


Power absorbed = Power radiated
B absorbs all radiations of A = 16 × 4πR2 T04σ
B absorbs all radiations of surrounding
= 4× 4πR2σT0
4

B radiates = 2 × 4× 4πR2σT4.
Of this 4π((2R)2 – R2)σT4 falls back on B.
Net heat radiated by B = 20πR2σT4
20 × 4πR2 T0 σ = 20πR σT
4 2 4

T=

12) fmix =

γmix =

13)

Correct answer is (B)


14) K.E. of gas converted into internal energy of gas.

mV2 =

ΔT = × (100)2 × 10–3

15)

16)

Correct answer is (C)

17)

Correct answer is (D)

18)

Net force =
on container

So equal amount of force in to be


applied on the container in Right side direction

19)

Correct answer is (B)


20)

Correct answer is (B)

21)

μ1 = 4, μ2 = 9
h=5
Let plate is x distance below upper plate.

Viscous force F =

For minimum force

Solving

22)

x1 = A1 cos (ωt)
x2 = A2 cos (ωt)
x1 – x2 = (A1 – A2) cos (ωt)
6 = 12 cos (ωt)

ωt = ⇒t= = = 2s

Alternative :

θ=

ωt =

t= = 2 sec.

23) String will slack when spring tries to compress it i.e. SHM is not possible beyond the
position for which spring gets compressed.
24)

25)

PART-2 : CHEMISTRY

26) Explaining the Question: The question asks which technique can best identify whether
different inks were used in a document.
Concept: Thin layer chromatography (TLC), Separation of mixtures, Ink analysis.
Solution:
In thin layer chromatography (TLC), a small sample of the ink is spotted on a plate coated with
adsorbent (like silica gel). When a suitable solvent moves up the plate, different components of
the ink travel at different rates, forming distinct spots. Comparison of the chromatograms from
two ink samples can reveal whether the same or different inks were used.

27) Dumas method involves the determination of nitrogen contained in the organic compound
in form of N2.
28)

29)

30) Isomers obtains are

31)

32)
33) A.S. : Acid1 > Acid2

34) N1 is pure lone pair ; N2 & O5 are delocolised lone pair large sized atom, lone pair
density is less

35)

Explanation Question: SIR Steric inhibition in resonance


Concept: This question is based on SIR
Solution:

(1)

(2)

(3)
(4) The Correct option is (1)

36) Explanation: Asking about the acidic strength of H1 and H2 atoms.


Concept: Based on acidic strength.
Solution:
Acidic strength (Ka) Stability of conjugate base
Delocalisation of charge in conjugate base.

* Negative charge of conjugate base-1 is not delocalised with group while it is

delocalised with group with vacant d-orbitals of phosphorous.


* Hence acidic strength order : H2 > H1.

37)
are mirror image and are not superimposable on each other so are enantiomers.

38) KEmax = hν – ϕ

λ0 (nm) = 400 nm

39) de-Broglie wavelength (λ) =

∵ mvr =

40) Decreases to a greater negative value

41) Explain Question : Which graph represent 1 radial node and one angular node
Concept : Schrodinger wav equation
Solution :
Number of radial node= n – l = l
1 = n - l - 1 (Given)
Number of angular node = l
l = 1 (Given)
l =1 for p- orbital
for 3p ⇒ R.N = 3 –1–1 = 1
Radial node = 1, Angular node = 1
Hence orbital is 3p.

42)
t = 0 2.5 atm 2 mol 0.5 atm

As QP < KP , so reaction proceed more forward to achieve equilibrium

43) Question Explanation:


Find value of KC by changing stoichiometry of reaction.
Concept:
This question is based on properties of KC.
Solution:

SO3(g) ⇌ SO2(g) + O2(g) ; Kc = 4.9 × 10–2 ...(1)


2SO2(g) + O2(g) ⇌ 2SO3(g), Kc ' ...(2)
by multiply equilibrium (1) with –2 to get equilibrium (2)

KC' = KC–2 = = 416

44) XY(s) X(g) + Y(g)


At eq. P P
Total pressure = 2P = 10 bar
⇒P=5
Now, KP = (PX)(PY) = P2 = 25

45) moles of S8 =

moles of sulphur = = 0.04


S8(s) 8S(g)
0.01(1–α) 8 × 0.01 × α
8 × 0.01 a = 0.04
α = 0.5

46) Question Explanation:


We need to find the % of bromine in a compound from the mass of AgBr formed in the Carius
method.

Concept:
Carius method, gravimetric estimation, stoichiometric relation between AgBr and Br.

Solution:

mole of AgBr =

mole of Br– = mole of AgBr =

mass of Br– = × 80

% of Br– = × 100 = 40%.

Final Answer: 40

47)

48)

Question Explanation:
The question asks to determine the total number of given structures that possess at
least one plane of symmetry (POS).

Concept:
A plane of symmetry (POS) is an imaginary plane that divides a molecule into two identical
mirror-image halves. The presence or absence of POS depends on molecular geometry and
the spatial arrangement of substituents.

Solution:

(i) Substituted allene:


Chiral allenes having different groups (e.g., Cl and H) on each terminal carbon are
asymmetric and hence do not possess a POS.

(ii) Trans-1,3-dichlorocyclobutane:
Has a vertical plane of symmetry passing through C-1 and C-3.
✔ POS present

(iii) Norbornane (bridged bicyclic system):


Highly symmetrical structure with multiple planes of symmetry.
✔ POS present

(iv) Trans-1,3-dimethylcyclopentane:
Asymmetric due to substituent arrangement; unlike the cis-isomer, it lacks a POS.

(v) Cis-1,2-dimethylcyclopropane:
Different spatial orientation of substituents destroys symmetry.
✘ No POS

(vi) Cyclohexane (chair conformation):


A highly symmetrical structure possessing several planes of symmetry.
✔ POS present

(vii) 1,3,5-substituted cyclohexane:


A symmetrical arrangement (Br vs Br), giving a plane of symmetry.
✔ POS present

(viii) Asymmetrically substituted cyclohexane (Br and Cl):


Different substituents break symmetry.
✘ No POS

Thus, compounds (ii), (iii), (vi), and (vii) possess at least one plane of symmetry.

Final Answer: 4

49) Question Explanation: Find the change in potential energy


Concept: Bohr model
Solution: n1 = 1
n2 = 4

Change is potential energy = ΔPE = 27.2 (2)2

= 27.2 × 4 × = 102 eV
Final Answer: 102

50) Explain Question: Find equilibrium constant

Concept: This question is based on calculation of KC

Solution:
2NOCl(g) 2NO(g) + Cl2(g)
t=0 2M - -

t=teq (2–x)M xM M

∴ [NOCl]eq = 1.6 M
[NO]eq = 0.4 M
[Cl2]eq = 0.2 M

Kc = 12.5 × 10–3
Kc = 125 × 10–4
Integer answer is 125

Final Answer: (125)

PART-3 : MATHEMATICS

51) , y = mx – 8m2

⇒ ⇒ m = –2 ⇒ y int. = –32

52) E → 2, A → 2, R → 1
T → 1, H → 1, Q → 1, U → 1, K → 1

53) A line will be tangent to a circle, if length of perpendicular drawn from centre (a, 0) upon
the line ℓx + my + n = 90 is equal to radius = a

54) ƒ(1) + ƒ(2) + ƒ(3) + ƒ(4) = an odd number


Case-I : one odd and 3 even
4
C3 × 2C1 × 23 = 64
Case-II : 3 odd and one even
4
C3 × 23 × 21 = 64
Total = 128

55) 1000C0 + 1000C1x + ..... + 1000C1000x1000 = (1 + x)1000


⇒ 1000C1 + 21000C2x + ..... + 10001000C1000x999 = 1000(1 + x)999
put x = 1
⇒ 1000C1 + 2.1000C2 + ..... + 10001000C1000
= 1000 × 2999

56)

57)

A vector along the normal to the required plane is

58)
passes through (1, 2)
2 2
(2 – m) = 12m – 7
⇒ 11m2 + 4m – 11 = 0

m1m2 = –1 ⇒
Option 3 :

= 2 tan–1

= 2 tan–1 1 =

Final Answer: The correct option is (3).

59)

60) 3! × 4! = 144

61) Equation of chord of the circle x2 + y2 = 25, whose midpoint is P(h, k)


T = S1
xh + yk – 25 = h2 + k2 – 25 ...(1)
⇒ this chord is tangent to the circle
x2 + y2 – 20x – 20y + 175 = 0
Length of perpendicular from centre
= Radius

⇒ (10h + 10k – h2 – k2)2 = 25(h2 + k2)


(10x + 10y – x2 – y2)2 = 25(x2 + y2)

62)
r=2

63)

64) Let variance of first n positive integer be

i.e. Variance of first n positive multiple of 5 will be


Var (5n) = 25σ2
Variance of first n positive multiple of 10 will be Var (10n) = 100σ2

65)

X Y Z
5 one & 4 five 4 one & 5 five 3 one & 6 five

66)

2 Alike + 2 different =
All 4 different =

∴ Total = 25

67) Let B1, B2, B3, ....... B8 are 8 boys of which B1 & B2 are brother.
Then, number of gapes among B3, B4, ....... B8 is 7.

∴ Required number of ways will be = 30240

Final Answer: Option (4)

68)
r = 0, 24, ....., 24 × 16
Total terms = 17

69)

|(x – 3) + iy| = |2(x + 1) + 2iy|


3x2 + 3y2 + 14x – 5 = 0

⇒ centre

70) The complex numbers having least positive argument is –3i

71)


⇒ a = 3, b = 2


PF1 = 2λ, PF2 = λ
2λ + λ = 6 ⇒ λ = 2
PF1 = 4, PF2 = 2

PF12 + PF22 = F1F22 ⇒ ∠F1PF2 = 90°

⇒ area

72) Four digit natural numbers _________


4 × 5 × 5 × 5 = 4 × 125
∴ N = 4 × 125

Hence

73)

4n (n2 – 1) = 0
⇒ n = 0, +1, –1 → 3 values of 'n'
74) f'(x) = 3x2 + 2x + 1 > 0 (∵ D < 0)
⇒ f(x) is increasing
∴ f(x) = f–1(x) ⇒ f(x) = x
x3 + x2 + x – 36 = x
⇒ x3 + x2 – 36 = 0
⇒x=3

75) f(x) = |(2x – 1).(3x – 3)x.(x – 1).(x – 2)|


f(x) is not differentiable at x = 2

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