21-12-2025

1001CJA101001250020 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A small hole of area a is at the bottom of a container of area A. The liquid is filled up to height h

from base. As liquid comes out then

(A)
level of liquid in container falls at rate of
magnitude of acceleration of top surface of liquid is
(B)

acceleration of top surface of liquid is

(C)

(D) None of these

2) A ball of mass "1 kg" and specific gravity is released inside the tank filled with water as
shown. Resistance offered by water to ball is 2.5 V where V is velocity of the ball. Select the correct

statement (ρm & ρw are density of ball and water respectively):-

(A) Momentum of water is zero when ball reaches steady velocity.

(B) Momentum of water is 1 kg m/s in upward direction when ball reaches steady state.
(C) Momentum of ball is 2 kg m/s in downward direction when ball reaches steady state.
 Momentum of [Ball + water] system is 2 kg m/s in downward direction when ball
(D)
reaches steady state.

3) A homogeneous disk of radius r and mass m is mounted on an axle OG of length L and negligible
mass. The axle is pivoted at the fixed point O, and the disk is constrained to roll on a horizontal floor.
Knowing that the 'disk' rotates counterclockwise at the rate ω1 about the axis OG :- Choose the

correct option(s).

(A)
The angular velocity of the disk is .

(B)
The angular velocity of the disc is .

(C)
The X component of angular momentum of disc about 'O' is .
(D) The Z component of angular momentum of disc about 'O' is zero.

4) In the figure shown a uniform rod of mass m and length ℓ is hinged. The rod is released when the

rod makes angle θ = 60° with the vertical.

(A)
The angular acceleration of the rod just after release is .

(B)
The net reaction due to the hinge just after release is .

(C)
The angular velocity of the rod at the instant it becomes vertical is .

(D)
The net reaction due to the hinge at the instant the rod becomes vertical is mg.

5) Two engines operate in series between a heat source & sink as shown in figure. Heat source
supplies 600 J to engine ε1 and has efficiency 40%. Engine ε2 has efficiency 25%. Choose the
CORRECT option/s.

(A) Work done by engine ε1 is 360J

(B) Work done by engine ε2 is 90J
(C) Efficiency of complete system is 55%
(D) Heat rejected to sink is 270 J

6) A bead slides on a fixed frictionless wire bent into a horizontal semicircle of radius R0 as shown in
figure. In addition to any normal forces exerted by the wire, the bead is subjected to an external
force that points directly away from origin and depends on distance r from the origin according to

the formula :-

(A) Given force is a central force.

(B) Given force is a conservative force.

(C)
Work done by external force as bead leaves the track is .

(D)
Speed of bead as it leaves the wire is .

SECTION-I (ii)

1)

Match the list.

List-I List-II
(P) ;f=d+e (1) and are at angle 60°
(Q) ;f=d+e (2) and are in same direction
(R) ;f= d ; d = e (3) and are opposite
(S) (4) and are perpendicular
(5) None of these
(A) P → 2;Q → 4;R → 1;S → 4
(B) P → 2;Q → 3;R → 4;S → 1
(C) P → 2;Q → 1;R → 3;S → 4
(D) P → 1;Q → 3;R → 2;S → 4

2) One mole of an ideal monoatomic gas is taken round the cyclic process ABCA as shown in figure.

List-I List-II

(P) The work done by the gas during complete cycle (1)

(Q) Heat absorbed by the gas in the path AB (2)

The minimum temperature attained by the

(R) (3) P0V0
gas during the cycle.

The maximum temperature attained by the

(S) (4) 3P0V0
gas during the cycle.

(5) 2P0V0
(A) P → 1;Q → 2;R → 3;S → 4
(B) P → 3;Q → 4;R → 2;S → 1
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 1;Q → 2;R → 4;S → 3

3) There is a square frame ABCD of 4 rods of mass m and length L each. The frame is placed in x-y
plane as shown. AC is a line in x-y plane that is taken as w-axis. z-axis is perpendicular to xy-plane
through M. M is mid point of AD. Ix, Iy, Iz, Iw are moments of inertia about x,y, z, w axes respectively.
 List-I List-II

(P) Ix (1)

(Q) Iy (2)

(R) Iz (3)

(S) Iw (4)

(5) None of these

(A) P → 4;Q → 5;R → 3;S → 2
(B) P → 1;Q → 4;R → 3;S → 4
(C) P → 4;Q → 1;R → 3;S → 4
(D) P → 1;Q → 4;R → 5;S → 2

4) A small block lies on a rough horizontal platform above its centre C as shown in figure. The plank
is moved in vertical plane such that it always remains horizontal and its centre C moves in a vertical
circle of centre O with the constant angular velocity ω. There is no relative motion between block
and the plank and the block does not lose contact with the plank anywhere. P, Q, R, S and T are
points on circular trajectory of centre C of platform. P and R lie on same horizontal level as O. Q is
the highest point on the circle and S is the lowest point on the shown circle. Match the statements in

List-I with points in List-II.

List-I List-II

Magnitude of frictional force on

(P) (1) When block is at position Pa
block is maximum

Magnitude of normal reaction

(Q) (2) When block is at position Q
on block is equal to mg

Magnitude of frictional force is

(R) (3) When block is at position R
zero

Net contact force on the block

(S) (4) When block is at position S
is directed towards the centre

(5) When block is at position T

(A) P → 1,3;Q → 2,4;R → 1,3;S → 5
(B) P → 5;Q → 1,2,3;R → 2,4;S → 4,5
(C) P → 5;Q → 1,3;R → 2,4;S → 1,2,3,4,5
(D) P → 1,3;Q → 1,3;R → 2,4;S → 4

SECTION-II

1) A student wants to determine the coefficients of static friction and kinetic friction between a box
and a plank. He places the box on the plank and gradually raises the plank. When the angle of
inclination with the horizontal reaches 30°, the block starts to slip and slides 4.0 m down the plank

in 4.0 s. If is given by , then find the value of β. (µs & µk are coefficient of static friction &
kinetic friction)

2) Figure shows a disc of radius R = 20 cm with a portion of it removed symmetrically. The removed
part is a disc of radius R/2. The removed part is now placed in contact with the larger disc as shown
in figure. Disc has uniform mass distribution. With respect to origin at centre of larger disc, find x-

coordinate of centre of mass of system (in cm).

3) A simple pendulum is suspended from a peg on a vertical wall. The pendulum is pulled away from
the wall to a horizontal position and released (see Fig.). The bob hits the wall, the restitution
coefficient being . What is the minimum number of impacts with wall after which the amplitude

becomes less than 60°? (Take : log 2 = 0.3 and log 5 = 0.7)

4) Wedge of mass M = 2m has hemispherical groove of radius as R = 9 cm as shown in figure. A

particle of mass m kept at upper extreme of groove is released from rest. Find the radius of
curvature in cm of the particle, when it reaches its lowermost point. (All surfaces are smooth)

5) A glass flask contains some mercury at room temperature. It is found that at different
temperatures the volume of air inside the flask remains the same. If the volume of mercury in the
flask is 300 cm3, then find the volume of the flask. If your answer is N (in cm3), fill value of .
[Given that coefficient of volume expansion of mercury and coefficient of linear expansion of glass
are 1.8 × 10–4 (°C)–1 and 9 × 10–6 (°C)–1 respectively]

6) Heat is supplied at a constant rate to a cube of ice which is melting at rate of 0.2 gm/sec. It melts
completely in 40 sec. What will be the rate of rise of temperature (in °C/sec) after melting is
completed? (Lf = 80 cal/gm, Sw = 1 cal/gm°C)

7) A thin rod of negligible mass and area of cross-section 4 × 10–6 m2, suspended vertically from one
end, has a length of 0.5 m at 100°C. The rod is cooled to 0°C, but prevented from contracting by
attaching a mass at the lower end. Find the energy stored in the rod. Given for the rod : Young's

modulus = 1011 N/m2, Coefficient of linear expansion 10–5 K–1 and g = 10 m/s2. If your answer is ,
fill value of X.

8) A cylinder of height h = 1m has a narrow vertical slit along its wall running up to a length ℓ =
40cm from the bottom. The width of the slit is b = 1mm. The cylinder is filled with water with the slit
closed. Find the force (in N) experienced by the vessel immediately after the slit is opened.

PART-2 : CHEMISTRY

SECTION-I (i)

1) CORRECT statement(s) among the following is / are

–
(A) Geometry of electronic arrangement in PCl6 is square bipyramidal/octahedral species.
(B) In CℓF3, two lone pairs should be placed at axial position to minimize overall repulsion
(C) CH4 and XeO4 have same shape but different hybridisation
3
(D) In SiCl4 total four Sp hybridized orbitals are available with respect to central atom.

2) Which among the following molecule(s) have peroxy linkage :-

(A) HNO4
(B) H4P2O8
(C) H2SO5
(D) HClO4

3) Which of the following is/are correct statement(s) regarding these molecules.

(i) (ii) (iii) (iv)

(A) Compound I and III are diastereomers.

(B) Compound I and II are identical.
(C) Compound III and IV are enantiomers
(D) Compound II and IV are diastereomers.

4) Which of following is/are correct order :

(A)

Acidic strength order : <

(B)

Basic strength order : <

(C)
Stability order : >

(D)
Heat of combustion : >

5) One mole each of H2(g) and O2(g) are kept in separate containers at same temperature (300K) and
same pressure (1 atm).
(σ collision diameter)

(A) Number density is same in both containers.

(B) The average speed of H2(g) is greater than that of O2(g)
(C) The collision frequency (Z11) of H2(g) is greater than that of O2(g).

(D)
The ratio of collision frequencies,

6) Which of the following statement is correct regarding real gas?

(A) Liquefaction of gas is possible only when the temperature is below its critical temperature.
(B) At critical point, the properties of liquid and gas becomes indistinguishable.
 H2(g) & He(g) always show positive deviation from ideal behaviour for all values of pressure and
(C)
temperature.
(D) The critical constants (PC, VC, TC) are same for all real gases.

SECTION-I (ii)

1)

List-I List-II

(P) Z = 23 (1) d-block

(Q) Z = 33 (2) 4th period

(R) Z = 57 (3) s-block

(S) Z = 19 (4) p-block

(5) 3rd group

Information of Both list I & II belong to long form of modern periodic table.
(A) P → 4;Q → 2;R → 5;S → 3
(B) P → 1;Q → 4;R → 5;S → 3
(C) P → 3;Q → 2;R → 4;S → 1
(D) P → 5;Q → 4;R → 1;S → 3

2) Match items of List-I and List-II

List-I List-II
(Mixture of compounds) (Separation technique)

Distillation under reduced

(P) C6H5NH2 + H2O (1)
pressure

Separation of glycerol from

(Q) (2) Steam distillation
spent-lye

(R) Chloroform + Aniline (3) Differential solvent extraction

(S) CH2Cl2 + H2O (4) Distillation

(5) Crystallization
(A) P → 5;Q → 3;R → 4;S → 2
(B) P → 2;Q → 1;R → 4;S → 3
(C) P → 3;Q → 5;R → 1;S → 4
(D) P → 4;Q → 2;R → 3;S → 5

3) At 250°C and 1 atm pressure, vapour density of following reaction mixture at equilibrium is 20.
A(g) ⇌ B(g) + C(g)
Molar mass of A, B and C are 60, 40, 20 g/mole respectively.
Match the following List for the above reaction.
 List–I List–II

(P) Kp for the given reaction × 60 (1) 48

(Q) (Degree of dissociation at 1 atm and 250°C) × 60 (2) 15

(R) (Degree of dissociation at 5 atm and 250°C) × 60 (3) 30

Vapour density of reaction mixture at 5 atm and

(S) (4) 20
250°C.

(5) 24
The correct option is:
(A) P → 2;Q → 5;R → 1;S → 4
(B) P → 4;Q → 3;R → 2;S → 5
(C) P → 3;Q → 2;R → 5;S → 1
(D) P → 1;Q → 2;R → 4;S → 3

4) [Use : R0 = first Bohr radius = 0.52 Å, = 1.73, = 2.45, hc = 1240 eV nm]

List-I List-II

De-Broglie wavelength of an electron present in 3rd orbit 1.04

(P) (1)
of He+ ions. Å

for 3rd shell of 2.89

(Q) hydrogen atom. The distance of radial node from (2)
Å

nucleus .

De-Broglie wavelength of an electron accelerated

(R) (3) 4.9 Å
through potential difference of 2V.

De-Broglie wavelength of an electron emitted from

3.12
(S) metal surface (ϕ = 2 eV) by photons of wavelength 62 (4)
Å
nm.

8.65
(5)
Å
(A) P → 1;Q → 2;R → 3;S → 4
(B) P → 3;Q → 4;R → 5;S → 2
(C) P → 2;Q → 4;R → 3;S → 1
(D) P → 2;Q → 5;R → 4;S → 3

SECTION-II

1) Find the number of Diamagnetic specie(s).

Ca+2, Sc+3, Zn+2, Fe+3, Cl–, Cu+2

2) Find the total number of correct orders among the following.

(1) Order of electron affinity : N < O < F
(2) Order of ionic radius : N–3 > O–2 > F–
(3) Order of Electronegativity : N < O < F
(4) Order of atomic radius : N > O > F
(5) Order of first ionization energy : O < N < F
(6) Order of effective nuclear charge (Zeff) ionic radii : N < O < F

3) Consider the following set of quantum number

n=4
ℓ= X
m=Y

s=+
If X and Y are maximum possible value for ℓ and m respectively,
then what will be the value of (X + Y)

4) Identify total number of stereoisomers for the following compound :

5) How many structural isomers are possible for n-pentane (C5H12).

6) The total number of contributing structure showing hyper-conjugation (involving C-H bonds) for
the following carbocation is :

7)

100 ml of H2O2 aqueous solution is oxidised by 300 ml of 1M KMnO4(aq.) in acidic medium. What
volume (in ml) of 1M KMnO4(aq) in basic medium will oxidise 100 ml of same H2O2 solution ?

8) The distance between two radial nodes is 'd' Å for the given orbital of H-atom whose wave
function is given as

Ψ=

0
where a and z are constants and ,find value of 'd' ?
[Use : a0 = 0.5 Å]

PART-3 : MATHEMATICS

SECTION-I (i)

1) If 'N' denotes number of ways in which 15 identical coins can be distributed among A, B, C, D
such that Mr. 'A' must get atleast '2' coins and Mr. D must get atleast '4' coins, then

(A) Number of divisors of '2N' are '16'

(B) Number of divisors of '2N' are '18'
(C) Number of even divisors of '2N' are '12'
(D) Number of divisors of '2N' which are divisible by 2 but not divisible by 5 are '6'

2) If = I + f, where n is an odd natural number, I is an integer and 0 < f < 1, then

(A) I is an odd integer

(B) I is an even integer
(C) (I + f) ( 1 – f) = 1

(D)

3) Let the eccentricity of the hyperbola be reciprocal to that of the ellipse x2 + 4y2 = 4. If
the hyperbola passes through a focus of the ellipse, then -

the equation of the hyperbola is

(A)

(B) a focus of the hyperbola is (2,0)

(C)
the eccentricity of the hyperbola is
(D) the equation of the hyperbola is x2 – 3y2 = 3

4) Which of the following is/are correct -

Number of words formed by letters of word 'ENGINEER' such that 'no two vowels are together'
(A)
are 240.
Number of words formed by letters of word 'COMMISSIONER' such that alike letters are
(B)
together but separated from other alike letters, are 2080.
Number of words formed by letters of word 'TERRORIST' such that 'No two R are together', are
(C)
12600.
Number of words formed by letters of word 'TERRORIST' such that 'All R's and all T's, are
(D)
separated' are 10200.
5) For trigonometric equation 1 + cos4(x) = sin3(x)

(A) No. of sol. in [0, 3π] is 2

(B) No. of sol. in [–π, 4π] is 2
(C) Sum of all sol. in [0, 3π] is 3π
(D) Sum of all sol. in [–π, 4π] is 3π

6) Seven letters, (L1, L2, L3, ..., L7) are to be placed into 7 envelopes (E1, E2, E3, ..., E7). The number of
ways in which no letter goes into its correct envelope, given that L1 goes to E2 & L2 goes to E3, is less
than or equal to

(A) 44
(B) 53
(C) 62
(D) 68

SECTION-I (ii)

1)

List-I List-II

9
(I) (P) C5
Value of is
10
(II) Value of is (Q) C4
10
(III) Value of is (R) C5
9
(IV) Value of is (S) C8
18
(T) C10
Which of the following is correct ?
(A) I → R;II → T;III → Q;IV → P
(B) I → R;II → T;III → P;IV → Q
(C) I → S;II → R;III → Q;IV → P
(D) I → Q;II → T;III → R;IV → S

2)

List-I List-II

(I) Number of natural solution of the equation x + y + z = 18 (P) 192

In a polygon the number of diagonals is 54, then the number

(II) (Q) 184
of sides of polygon is equal to

There are 15 lines terminating at a point, then the maximum 15

(III) (R) C2
number of angles formed are
 Total number of 5 digit numbers having all different digits
17
(IV) and divisible by 4 that can be formed using the digit {1, 3, 2, (S) C2
9, 6, 8}, are
12
(T) C1
Which of the following is correct ?
(A) I → S;II → T;III → P;IV → R
(B) I → R;II → T;III → P;IV → S
(C) I → S;II → T;III → R;IV → P
(D) I → R;II → Q;III → T;IV → P

3)

List-I List-II

If 2x + y + λ = 0 is a normal to circle
(I) (P) 0
x2 + y2 – 4x – 6y + 1 = 0, then |λ| is equal to

If 2x + y + λ = 0 is a normal to parabola
(II) (Q) 6
y2 = 4x, then |λ| is equal to

lf 2x + y + λ = 0 is a chord of given ellipse

(III) (R) 12
which passes through its
center, then the value of λ is equal to

If 2x + y + λ = 0 is a focal chord of hyperbola

(IV) (S) 7
, then the value of |λ| is equal to

(T) 14
Which of the following is correct ?
(A) I → S;II → T;III → P;IV → R
(B) I → Q;II → T;III → P;IV → R
(C) I → Q;II → R;III → P;IV → T
(D) I → S;II → R;III → P;IV → T

4)

List-I List-II

The system of equation 2x – y + z = 0; x – 2y + z = 0 and

(I) (P) 2
λx – y + 2z = 0 has non-trivial solutions then λ is

The number of values of c for which the lines x + y = 1, (c

(II) + 2)x + (c + 4)y = 6 and (c + 2)2x + (c + 4)2y = 36 are (Q) 3
concurrent is

If a2b3 = 32 where a & b ∈ R+, then minimum value of 2a

(III) (R) 4
+ 3b is

If (3 – tan270°) = (cot70° – 3 tan70°) k, then is equal

(IV) (S) 5
to
 (T) 10
Which of the following is correct ?
(A) I → S;II → R;III → T;IV → P
(B) I → S;II → P;III → T;IV → R
(C) I → T;II → R;III → S;IV → Q
(D) I → T;II → P;III → S;IV → R

SECTION-II

1) If = 25, = 27 & , then the value of is

2) In a jeep, there are 3 front and 3 back seats. Find the number of ways in which 6 person of
different heights can be seated so that every one sitting in front is shorter than the person directly
behind him.

3) Sum of real integral values of k for which quadratic equation (k2 + 1)x2 – (4k)x + 2 = 0 always
have exactly one root in the interval (0, 1) is

4) If N1 & N2 are absolute values of maximum & minimum values of f(x) = sin2(x) + 8cos(x) – 7

respectively. Then value of is

5) For the parabola y2 = 16x, length of a focal chord, whose one end point is (16, 16), is L2, then the
absolute value of L is

6) Let nCr – 1 + n + 1Cr – 1 + n + 2Cr – 1 + ... + 2nCr – 1 = , then is equal to

7) All the letters of the word 'HUDHUD' are written in all possible orders and these words are
written out as in a dictionary. If the rank of the word 'DUHDUH' is 'N', then sum of digits of 'N' is

8) A set contains 35 element. The number of selections of at least 18 elements is 2n, then sum of
digits of n is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. A,B C A,C,D B,C,D B,C,D A,B,C

SECTION-I (ii)

Q. 7 8 9 10
A. B B C D

SECTION-II

Q. 11 12 13 14 15 16 17 18
A. 9.00 5.00 4.00 4.00 8.00 2.00 1.00 6.40

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. A,D A,B,C A,B,C,D A,C,D A,B A,B

SECTION-I (ii)

Q. 25 26 27 28
A. B B B B

SECTION-II

Q. 29 30 31 32 33 34 35 36
A. 4.00 6.00 6.00 8.00 3.00 7.00 500.00 1.50

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. A,C,D A,C,D B,D A,C,D A,B,C,D B,C,D

SECTION-I (ii)

Q. 43 44 45 46
A. A C D B
 SECTION-II

Q. 47 48 49 50 51 52 53 54
A. 27.00 90.00 5.00 15.00 5.00 1.20 5.00 7.00
 SOLUTIONS

PART-1 : PHYSICS

1) Applying Bernoulli’s equation between P and Q

.....(i)
From equation of continuity,

Acceleration of top layer

2) In steady state [equllibrium condition]

FB + Fv = mg
5 + Fv = 10
2.5 V = 5
V = 2.0 m/s
water will rise upward to fill the space
P = MwV = (0.5)(2) = 1kg m/s
Momentum of ball will be downward
P = Mball (V) = 2kg m/s
Momentum of system will be Psystem = Pw + PBall = 1 kg m/s downward

3)

4)

(A) mg sin 60° = α

α=

(B) N2 – mg cos 60° = 0 ⇒ N2 =

mg sin 60 – N1 = m

mg – . = N1

N1 =
N= = =

(C) mg (1 – cos 60°) = =

w=

(D) N – mg =

N= mg

5)

for ε–1

Q1 = 600 – 240 = 360 J

Q2 = 360 – 90
= 270 J

6) is a central force, because direction of force is always away from the fix

point origin & work done by this force is zero in any close loop force is
conservative

Work done by the force on bead = =

7)

Correct Answer is (B)

8) Explain question : We are given a graph between pressure (P) and volume (v) for a one
mole of ideal monatomic gas. We have to match list-I with list-II.
Concept : This question is based on cyclic process graph in thermodynamic system.
Solution :

0 0 0 0
For (P) : W = (2P )(V ) = P V

0 0
For (Q) : QAB = nCV (TB–TA) = 1 × R = 3P V

For (R) : TA = , TB = = 3TA, TC = = 2TA

⇒ Minimum temperature : Tmin =

(OR Temperature will be minimum for a point which is nearest to origin)
Maximum temperature will be either on end points or in process BC.
For (S) : As for process BC :

= ⇒ P = 5P0 –

0 0
⇒ PV = 5P V – V2 But PV = RT. So RT = 5P V – V2

0
⇒ = 5P0 – (2V) = 0 ⇒ V = V

0
⇒ RTmax = 5P ⇒ Tmax =
Final answer : 2

9) ×2+ ×2

× 2 + ML2
Iz = Ix + Iy

Iw =

10)

Correct Answer is (D)

11)

µs g cos θ = g sin θ ... (i)

anet = (g sin θ – µk g cos θ) ... (ii)

... (iii)
Solve (i), (ii) & (iii)
12) Mass of removed part = , where M is the mass of disc.
Centre of mass (x-coordiante)

13) After every collision V becomes 'e' time

Vn = en.V0
when θ ≤ 60° ⇒

⇒
According to given question
Vn < V'

0
en. v <
Put V0 =

en < ;e=

14)

and

so
r = 4 cm

15)

We have
Vflask = VHg + Vair
As (ΔV)air = 0
∴ (ΔV)flask = (ΔV)Hg
∵ Cavity having same expansion co-efficient for material
∴ Vf gf ΔT = VHg γHg ΔT

∴
∴ Volume of flask = 2000 cm3
16)

...(i)
0.2 × 40 = m
m = 8 gm

...(ii)
(i) / (ii)

1=

17)

(i) The change in length due to decrease in temperature,

Δℓ1 = LαΔθ
= (0.5) (10–5) (0 – 100)
Δℓ1 = –0.5 × 10–3 m ... (i)
Negative sign implies that length is decreasing. Now let M be the mass attached to the lower
end. Then change in length due to suspension of load is

Δℓ2 = (1.25 × 10–5) M

Δℓ1 + Δℓ2 = 0
or (1.25 × 10–5) M = (0.5 × 10–3)

∴
or M = 40 kg
(ii) Energy stored :
At 0°C the natural length of the wire is less than its actual length; but since a mass is attached
at its lower end, an elastic potential energy is stored in it. This is given by

... (iii)
Here Δℓ = |Δℓ1| = Δℓ2 = 0.5 × 10–3 m
substituting the values

= 0.1 J

18) Consider an element of the slit of length dx at a depth x from the top.
Velocity of efflux at .
Force on elementary area = rate of change of momentum = (b dx ρv)v = bρdx (2gx)
∴ F (total force experienced)
 =
or F = 10–3 × 1000 × 10 × 0.4 (2 – 0.4)
= 6.40 N

PART-2 : CHEMISTRY

19)

The correct answer is option (A),(D)

20)

In HClO4 peroxy linkage is not available

21)

The correct answer is option (A,B,C,D)

22)

The correct answer is option (A,C,D)

23)

(A) {for same P & T, N* is also same}

(B)

(C) Z = uavg (N*)2

(D)

24)

(A) No liquification is possible above Tc.

(B) At liquid–vapour density become equal, so, no phase boundary between them.
(C) H₂ & He also show negative deviation at critical temperature.
(D) Critical constants depend on the nature of the gas.

25)

The correct answer is option (B)

26) The correct answer is option (B)

27)
1–α α α =1+α

(Q)
So, 60 = 40 + 40α

So,

(P)

(R)

So,

(S)

28) DBλ for free electron =

DBλ for electron in Bohr model = 2πr0 × .

29)

Fe+3, Cu+2 are paramagnetic.

30) All are correct

31) Maximum possible value

 X=3
Y = +3
∴X+Y=3+3=6

32) Number of stereoisomer = 2n = 23 = 8

n = number of stereogenic unit.

33) The correct answer is (3)

34)

The correct answer is (7)

35) gm eq. of H2O2 = gm eq. of KMnO4 (acidic)

=1×
gm eq. of H2O2 = gm eq. of KMnO4 (basic)

=1×

⇒ =1×
V = 500 ml

36) σ2 – 4σ + 3 = 0 , σ = 3 , 1
n–ℓ–1=2
ℓ=0
n=3

, (Z = 1)

r= ,

r – r1 =
⇒ 3 × a0 = 3 × 0.5 Å
⇒ 1.5 Å = d

PART-3 : MATHEMATICS

37) A + B + C + D = 15
A ≥ 2, B ≥ 0, C ≥ 0, D ≥ 4
Number of solutions = 12C3 = 220
N = 220
'2N' = 2351111
38) I + f =

Let f ′ = . Then 0 < f ′ < 1

0
I + f = nC 4n + nC1 4n – 1 + nC2 4n – 2 15 + nC3 4n – 3 + ...

0
f ′ = nC 4n – nC1 4n – 1 + nC2 4n – 2 . 15 – nC3 4n – 3 + ...
n n n n–2
∴ I + f + f ′ = 2( C0 4 + C2 4 × 15 + ...) = even integer
∵0<f+f′<2 ⇒f+f′=1 ⇒1–f=f′
Thus, I is an odd integer. Now,

1–f=f′=
(I + f) (1 – f) = (I + f) f ′ = 1

39) Given hyperbola is

ellipse is

eccentricity of ellipse =

eccentricity of hyperbola =

⇒ 3b2 = a2 ....(1)

also hyperbola passes through foci of ellipse

⇒ a2 = 3 ....(2)
from (1) & (2)
b2 = 1

equation of hyperbola is
⇒ x2 – 3y2 = 3

eccentricity of hyperbola =

focus of hyperbola =

40) (A) 3E, 2N, G, I, R

(B)
4! 5C4 4! = 2880
(C) 3R, 2T, E, O, I, S
 (D) 12600 – R'S separated
= 12600 – 5! 6C3 = 10200

41) ∵
⇒ cos4(x) = 0 & sin3(x) = 1

⇒ ;n∈I ....(1)

& ;m∈I ....(2)

(1) ∩ (2) ⇒

* Solution in [0, 3π] ⇒ ;

* Solution in [–π, 4π] ⇒ ;

42)

L3 E1

L4 E4

L5 E5

L6 E6

L7 E7
So two cases either L3 goes to E1 or does not go to E1, hence D4 + D5 = 53

43) (I) 2nCn = 10C5

(II) Coeff. of x8 in (1 + x)18
= 18C8 = 18C10
(III) Coeff. of x8 in exp. of (1 + x)10 (x – 1)10 or (1 – x2)10
= 10C4
(IV) 5C5⋅4C0 + 5C4⋅4C1 + 5C3⋅4C2 + 5C2⋅4C3 + 5C1⋅4C0
= coeff. of x5 in exp. of (1 + x)9 = 9C5

44) (I) x + y + z = 18

∴
∴ 18 – 3 = 15 Apply Beggar's
so 15 + 2C2 = 17C2
(II) ∵ nC2 = n + 54
⇒ n = 12 or n = –9 (reject)
(III)
15
C2
(IV) 1, 2, 3, 6, 8, 9
Last two digits ⇒ 12, 16, 28, 32, 36, 68, 92, 96

= (4.3.2).8 = 192

45) (I) 2x + y + λ = 0
pass through (2, 3)
∴ |λ| = 7
2
(II) Normal of y = 4x is
y – mx + am3 + 2am = 0
put m = –2 ; a = 1
⇒ y + 2x – 8 – 4 = 0
⇒ y + 2x – 12 = 0
|λ| = 12
(III) 2x + y + λ = 0 passes through (–1, 2)
∴ –2 + 2 + λ = 0
λ=0
(IV) 2x + y + λ = 0 passes through focus (7, 0) or focus (–7, 0)
∴ |λ| = 14

46) (I)
⇒ 2(–3) + (2 – λ) – 1 + 2λ = 0
–6 + 2 – λ – 1 + 2λ = 0
λ=5

(II)

⇒ C = 2, 4
(III) a, a, b, b, b
 A.M. ≥ G.M. Apply

∴
⇒ 2a + 3b ≥ 5(32)1/5
⇒ (2a + 3b)min. = 10
(IV) If (3 – tan270°) = (cot70° – 3tan70°)k

or = tan(3 × 70°) = tan210° =

47) ∵

48)

Total no. of ways =

49)
f(0).f(1) < 0
⇒ 2.[k2 + 1 – 4k + 2] < 0
⇒ k2 – 4k + 3 < 0
⇒ k ∈ (1, 3)
Now check
(I) if k = 1 then quadratic
2x2 – 4x + 2 = 0
⇒ (x – 1)2 = 0

reject
(II) if k = 3 then quadratic
5x2 – 6x + 1 = 0
⇒ (5x – 1)(x – 1) = 0
 accept

∴
integers = 2, 3
sum = 2 + 3 = 5

50) y = –cos2(x) + 8cos(x) – 6

⇒ y = –[(cos(x) – 4)2 – 16] – 6
* ymin. = –[(–1 – 4)2 – 16] – 6 = –15
* ymax. = –[(1 – 4)2 – 16] – 6 = 1
∴ N1 = 1 & N2 = 15

51)

52) nCr + nCr – 1 + ... + 2nCr – 1 =

r = 12

53) D D ........

D H ........

D U D .....
DUHDHU = 1
DUHDUH = 1

54) (35C0 + ... + 35C17) + (38C18 + ... + 35C35) = 235

2(35C18 + ... + 35C35) = 235
35
C18 + ... + 35C35 = 234