18-05-2025

5301CJA101001250003 JA

PHYSICS

SECTION-I(i)

1)

The wavelength associated with a moving particle depends upon pth power of its mass m, qth power of
its velocity v and rth power of Planck's constant h. Then, the correct set of values of p, q and r is (E =
hν, E is the energy of a wave, ν is frequency & h is planks constant)

(A) p = 1, q = –1, r = 1
(B) p = 1, q = 1, r = 1
(C) p = –1, q = –1, r = –1
(D) p = –1, q = –1, r = 1

2) Two force vectors applied on an object are shown. Their magnitudes are equal

(A)
x -component of is zero

(B)
y-component of is in positive y-direction

(C)
x-component of is in negative x-direction

(D)
is in positive x-direction

3) Which of the following operation is not possible?

(A)

(B)

(C)
(D)

4) The resultant of makes are angle with with then

(A) always
(B) if A < B
(C) if A > B
(D) if A = B

5) A bullet is fired from a gun with velocity 500 ms–1, then the maximum range is :-

(A)
(B)
(C)
(D)

6) In a new system of units force (F), momentum (P) and mass (M) are taken as fundamental physical
quantities. Find the dimensional formula of power in new system.

(A) FP2M–1
0
(B) F PM–1
(C) FPM–1
0
(D) F P2M–1

SECTION-I(ii)

1) A freely falling body travelled 35 m in last second of its journey :- (g = 10 m/s2)

(A) The height of the point of release from ground is 80 m

(B) The distance travelled in the first second is 5 m
(C) The maximum speed attained by the body is 40 m/s
(D) The maximum speed attained by the body is 20 m/s

2) Two particles are thrown from same point in same vertical plane as shown in figure

simultaneously. Then indicate the correct statement(s).

(A) Time of flight of B is less than that of A.

(B) Projection speed of B is greater than that of A.
(C) Horizontal component of velocity of B is greater than that of A.
(D) Vertical components of velocities of A and B are always equal through out the flight of A and B.

3) The four pairs of force vectors are given, which pairs of force vectors cannot be added to give a
resultant vector of magnitude 10 N?

(A) 2N, 13 N
(B) 5N, 16 N
(C) 7N, 8N
(D) 100N, 105 N

4)

For the equation x = AC sin (Bt) + D e(BCt), where x and t represent position and time respectively,
which of the following is/are CORRECT?

(A) Dimension of AC is LT–1.

(B) Dimension of B is T–1.
(C) Dimension of AC and D are same.
(D) Dimension of C is T–1.

5) Which of the following is/are true statement?

(A) A vector cannot be divided by another vector.

(B) Dot product of two vectors is a scalar.
(C) Since addition of vectors is commutative therefore vector subtraction is also commutative.
The resultant of two equal forces of magnitude F acting at a point is F if the angle between the
(D)
two forces is 120º.

6) Sometimes it is convenient to construct a system of units so that all quantities can be expressed in
terms of only one physical quantity. In one such system, dimensions of different quantities are given
in terms of a quantity X as follows: [position] = [Xα]; [speed] = [Xβ]; [acceleration] = [Xp]; [linear
momentum] = [Xq]; [force] = [Xr]. Then :-

(A) α + p = 2β
(B) p + q – r = β
(C) p – q + r = α
(D) p + q + r = β

SECTION-II

1)

The time period of oscillation of a body is given by

T=
K : Represents the kinetic energy, m mass, g acceleration due to gravity and A is unknown.
If [A] = Mx Ly Tz
Then what is the value of x + y + z.

2) Energy of a particle is 5J. If unit of length and time are doubled and unit of mass is halved then
numerical value of the energy in this new system will be 5n. Value of n is.

3) The resultant of two unit vectors is a unit vector. Then the angle between those unit vectors is (n
× 60)°.
Find n?

4) A body is allowed to fall from a height of 100 m. If the time taken for the first 50 m is t1 and for

the remaining 50 m is t2. Find

5) Velocity of a particle moving along x axis is given as, v = e(x/4) (in m/s). Find acceleration of
particle (in m/s2) when particle is at x = 0.

6) A boy throws a ball at time t = 0 with upward initial velocity = 20 m/s, from the corner of the roof
of a building, whose height above the ground is 25m. If the velocity of the ball is simply reversed
after collision from the ground (magnitude remaining same), and the 3rd collision of the ball with

the ground occurs at t = t1 sec, what is the value of t1(in second) ?

CHEMISTRY

SECTION-I(i)

1) If an electron has spin quantum number of +1/2 and magnetic quantum number of –1 it cannot be
present in .

(A) f-orbital
(B) d-orbital
(C) p-orbital
(D) s-orbital

2) In which of the following process energy is not absorbed :

(A) Na → Na+
(B) Mg → Mg+2
(C) O → O+
(D) None of these

3)

The successive ionisation energies for an element X are given below

IE1 = 410 kJ / mole
IE2 = 820 kJ / mole
IE3 = 1100 kJ / mole
IE4 = 1500 kJ / mole
IE5 = 7000 kJ / mole
Find out the number of valence electron for the atom X

(A) 4
(B) 3
(C) 5
(D) 2

4) A(g) → A+(aq) : ΔH = +X

If IE1 of A(g) is Y , then hydration energy of A+ ion is :

(Y – X)
(A)

(B)
(X – Y)
(X + Y)
(C)

X
(D)

5) Process I X(g) X–3(g)

Process II X(g) X+3(g)
Which of the following is NOT changed during both processes :

(A) Total number of protons

(B) Number of neutron
(C) Both (1) and (2)
(D) Total number of electrons

6) Which of the following elements has the highest electronegativity?

(A) Sodium
(B) Chlorine
(C) Fluorine
(D) Oxygen

SECTION-I(ii)

1) The maximum number of electron having in Zn2+ is equal to the-

(A) Atomic number of Mg

(B) 12

(C) Total number of electron in Zn which have

(D) ‘p’ electrons in Ar

2)

Which of the following is / are bridging elements

(A) P
(B) Ar
(C) Al
(D) Cl

3) The statement that is (are) CORRECT for the periodic classification of elements is :

The 2nd ionisation energies of elements along a period vary regulary with increase in
(A)
atomic number always
(B) The properties of elements are periodic function of their atomic number
(C) Non-metallic elements are lesser in number than metallic elements
(D) Electron affinity of elements decreases regularly in a group in p-block elements

4) If electronegativity of P, Q, R, S elements are respectively 0.8, 1.2, 1.0 and 2.5 then choose the
hydroxides which are basic in nature

(A) POH
(B) QOH
(C) ROH
(D) SOH

5) Out of the following which represent group of amphoteric oxides -

(A) Na2O, SnO, Al2O3

(B) SnO, SnO2
(C) PbO, PbO2, ZnO
(D) BeO, Ga2O3, Al2O3

6) Which of the following is/are correct ?

(A) For A(g) + e– —→ A¯ (g) ΔH may be negative

(B) For A¯(g) + e– —→ A2– (g) ΔH may be negative
(C) For A¯(g) + e– —→ A2– (g) ΔH must be positive
(D) For Ne(g) + e– —→ Ne¯ (g) ΔH is negative

SECTION-II

1) Find the total number of possible exchange for d4 configuration in an element.

2) The value of Zeff for K (Z = 19) is x and for Na (Z = 11) is y. The value of |x – y| is

3) Which out of the following options are incorrect ?

According to the mentioned properties.
(i) IP1 of ion M+2 > EA1 of M+3 . (IP = ionisation potential, EA = electron affinity)
(ii) S > Se > Te > O (order of EA)
(iii) Li < Be < B < C (order of electronegativity)
(iv) Mg+2 < Na+ < F– (order of ionic size)
(v) Li+ > Na+ > K+ (order of hydrated size)

4) How many of the following energy terms are involved in the transformation of

IE, ΔHsub, ΔHdiss, ΔHHE, ΔHLE

5) Find out the atomic number of element whose IUPAC name is Unnilpentium.
Fill your answer as sum of digits (excluding decimal places) till you get the single digit
answer.

6) Total number of elements in a 3rd period of modern periodic table

MATHS

SECTION-I(i)

1) The equation whose roots are the squares of the roots of the equation is -

(A)
(B)

(C)

(D)

2) If and have a common factor then 'a' is equal to

(A) 24
(B) 1
(C) 2
(D) 12

3) The quadratic = 0 has roots which are positive integers, then (a2+b2) can be equal
to

(A) 50
(B) 17
(C) 29
(D) 53

4) If the roots of the quadratic equation x2 + 6x + b = 0 are real and distinct and they differ by
atmost 4 then the least value of b is -

(A) 5
(B) 6
(C) 7
(D) 8

5) The sum of all real values of x satisfying the

equation = 1 is

(A) 3
(B) –4
(C) 6
(D) 5

6) If the roots of the equation x2 – 5x + 16 = 0 are a, b and the roots of the equation x2 + px + q = 0

are (α2 + β2) and , then-

(A) p = 1 and q = 56
(B) p = 1 and q = –56
(C) p = –1 and q = 56
(D) p = –1 and q = –56
 SECTION-I(ii)

1) If x2 – 3x – 1 = 0, then which of the following options are correct?

(A)

(B)

(C)

(D)

2) The roots of the given equation (p – q)x2 + (q – r)x + (r – p) = 0, are

(A) 1

(B)

(C)

(D)

3) If the graph of y = ax2 + bx + c is given as shown in the figure, then which of the following is/are

correct?

(A)

(B)

(C)

(D)

4) If 'x' is real and y = , then value of y can be :

(A) 1
(B) 2
(C) 3
(D)

5) If the roots of the equation are equal in magnitude and opposite in sign, then :

(A) p + q = r
(B) p + q = 2r

(C)

(D) sum of roots = 1

6) If x2 + x + 1 is a factor of ax3 + bx2 + cx + d = 0, then the real root of above equation is

(A)

(B)

(C)

(D)

SECTION-II

1) If α, β are the roots of x2 – 2kx + 6 = 0 such that α2 + β2 = 4, then the value of k2 is

2) Let and are the roots of the cubic . Find the value of .

3) Let x ∈ R then number of integers in the range of is

4) The least value of expression x2 + 9y2 + 2z2 – 4x – 6y – 4z + 10 is (x, y, z ∈ R)

5) If α and β be two roots of the equation x2 + 2x + 2 = 0, then the value of (α + 1)4 + (β + 1)4 is :

6) A survey shows that 63% of the Americans like cheese whereas 76% like apples. If x% of the
Americans like both cheese and apples, number of integral values of x is.
 ANSWER KEYS

PHYSICS

SECTION-I(i)

Q. 1 2 3 4 5 6
A. D D C C A C

SECTION-I(ii)

Q. 7 8 9 10 11 12
A. A,B,C B,C,D A,B B,C A,B,D A,B

SECTION-II

Q. 13 14 15 16 17 18
A. 3.00 2.00 2 0.41 0.25 17.00

CHEMISTRY

SECTION-I(i)

Q. 19 20 21 22 23 24
A. D D A B C C

SECTION-I(ii)

Q. 25 26 27 28 29 30
A. A,B,D A,C,D B,C A,B,C B,C,D A,C

SECTION-II

Q. 31 32 33 34 35 36
A. 6.00 0.00 1.00 3.00 6.00 8.00

MATHS

SECTION-I(i)

Q. 37 38 39 40 41 42
A. C A A A A D

SECTION-I(ii)

Q. 43 44 45 46 47 48
A. B,C,D A,C A,C A,B,C,D B,C A,D
 SECTION-II

Q. 49 50 51 52 53 54
A. 4.00 3.00 1.00 3.00 2.00 25.00
 SOLUTIONS

PHYSICS

1)

Given The dimensions of right hand side and left hand side terms should be
equal.

So,

or
Now, comparing powers M, L and T, we get
p + r = 0 (i), q + 2r = 1 (ii), – q – r = 0 (iii)
After solving, p = –1, q = –1 and r = 1.
Putting these values, we get

which is the required relation.

2)

3) can not be done.

4)

So

If A > B
 5) Components of velocity at an instant of time t of a body projected at an angle θ is
vx = u cos θ + gxt and vy = u sin θ + gyt
Here, components of velocity at t = 1 s, is
vx = u + cos 60°+ 0 [as gx = 0]
= 10 × 1/2 = 5m/s
and vy = u sin 60° + (–10) × (1)

Now, angle made by the velocity vector at time of t = 1 s

or α = 15°
Radius of curvature of the trajectory of the projected body R = v2/g cos α

7)
Given
H – H' = 35

n=4

= 5 × 16 = 80 m
v = u + gt
= 0 + 10 × 4 = 40 m/s

8)

Component of velocity in vertical direction in same (Hmax is same)

....(1)

(A) Time period

TA = TB

(B)

RB > RA
from eqn – 1

since Hmax is same

11) 1. vector cannot be divided by vector 2. Ang. displacement is scalar

3. If two for cws 'f' acting at 120° tree resultant

resultant

12) Given L = xα ...(1)

–1 β
LT = x ...(2)
–2 p
LT = x ...(3)
–1 q
MLT = x ...(4)
MLT–2 = xr ...(5)

⇒ T = xα – β
From (3)

⇒ α + p = 2β ⇒ (A)
From (4)
M = xq–β
From (5)
⇒ xq = xr
⇒ α+r–q=β ...(6)
Replacing value of 'α' in equation (6) from (A)
2β – p + r – q = β
⇒ p + q – r = β ⇒ (B)
Replacing value of 'β' in equation (6) from (A)
2α + 2r – 2q = α + p
α = p + 2q – 2r
Answer is (AB).

13)

[T] = = = =
 0
⇒ [A] = M LT2
x = 0, y = 1, T = 2
x+y+z=3

14) [E] = ML2T–2

15)

cos θ =

17) v = ex/4

a= =

x=0 a= = 0.25

18)

Ball will hit first time at

t = 5 sec
Velocity just before hitting
v = 20 – 10 × 5 ⇒ – 30 m/s
ball will again hit after

so total time before third strike = 5 + 6 + 6 = 17 sec.

CHEMISTRY

23)
 Only addition and removed of e– takes plan in both the process so proton and neutron are not
changed.

26) Bridging elements = 3rd period elements.

[Except noble gases]

28) Question Explanation: To determine which hydroxides are basic in nature,

Concept : The hydroxides that are basic in nature are those formed with elements that have
lower electronegativities. This is because elements with low electronegativity tend to form
ionic bonds, and the resulting hydroxides dissociate in water to produce OH–ions, which are
responsible for basicity.

In the given options:

A. P (electronegativity 0.8): P-O bond is likely ionic, so POH is basic.

B. Q (electronegativity 1.2): Q-O bond is likely ionic, so QOH is basic.
C. R (electronegativity 1.0): R-O bond is likely ionic, so ROH is basic.
D. S (electronegativity 2.5): S-O bond is more likely covalent. SOH is more likely to be acidic or
amphoteric.

Therefore, POH, QOH and ROH are basic. The correct answer set is 1,2 & 3.

Final Answer : option (1,2 and 3)

30) is generally negative but always positive

31)

d4, No. of unpaired e— = 4

(n = 4)

Then number of exchange =

32) Zeff(Na) = 2.2 Zeff(K) = 2.2

33)
 35) Unnilpentium atomic number = 105
↓ ↓ ↓ sum of digits = 1+ 0 + 5 = 6
1 0 5

MATHS

37)
x2 – (α2 + β2)x + α2β2 = 0
x2 – [(α + β)2 – 2αβ]x + α2β2 = 0

=0
2 2 2 2
a x – (b – 2ac)x + c = 0

38)

x2 – 11x + a and x2 – 14x + 2a

Let x – α be a common factor so
α2 – 11α + α = 0
α2 – 14a + 2a = 0

α=

=0
 α2 – 24a = 0
a = 24

40)

x2 + 6x + b
For real and distinct roots
D>0
36 – 4b > 0
9–b>0
9>b
Difference of roots ≤ 4

≤4
≤4
36 – 4b ≤ 16
5≤b
So least value of b is 5

41)
when x2 – 5x + 5 = 1
or x2 – 5x + 5 = –1, x2 + 4x – 60 = even
or x2 + 4x – 60 = 0, x2 – 5x + 5 ≠ 0

⇒
Sum of all values = 3

42) α+b = 5, αβ = 16

Roots of equation x2 + px + q = 0 are α2 + β2 and

∴ =–p

(α + β)2 – 2αβ + =–p

(5)2 – 2(16) + =–p

25 – 32 + 8 = –p
1 = – p or p = –1

=q
(25 – 32)8 = q
(–7)(8) = q
q = –56

43)
squaring squaring

⇒ ⇒

Taking cube on both sides

47)

Simplifying:

Roots are : α, –α

Product = pq – pr – qr
= pq – r (p + a)

48)

49) (α + β)2 – 2αβ = 4

4k2 – 12 = 4 ⇒ k2 = 4

51)

2x2y + 3xy + 6y = x + 2
(2y)x2 + x(3y – 1) + 2(3y – 1) = 0
(3y – 1)2 – 16y(3y – 1) ≥ 0
(3y – 1)(3y – 1 – 16y) ≥ 0

y=0

52) (x – 2)2 + (3y – 1)2 + 2(z – 1)2 + 3

for least value
x – 2 = 0 ; 3y – 1 = 0 ; z–1=0
Least value = 3

53) ∵ x2 + 2x + 2 = 0
∴ α2 + 2α + 2 = 0
⇒ α2 + 2α + 1 = –1
⇒ (α + 1)2 = –1
⇒ (α + 1)4 = (–1)2 = 1
same as, (β + 1)4 = 1
so, (α + 1)4 + (β + 1)4 = 2

54)
n(C) = 63
n(A) = 76
n(C ∪ A) = n(C) + n(A) – n(C ∩ A)
= 63 + 76 – x
= 149 – x
76 ≤ n(C ∪ A) ≤ 100
76 ≤ 149 – x ≤ 100
–100 ≤ x – 149 ≤ –76
⇒ 149 – 100 ≤ x ≤ 149 – 76
⇒ 49 ≤ x ≤ 73
integral values of x ⇒ 49, 50, …, 73
Total 25 integers