17-08-2025

1001CJA106213250009 JA

PART-1 : PHYSICS

SECTION-I (i)

1)

The moment of inertia of a cube of mass m and side a about the diagonal of one of it's face is :-

(A)

(B)

(C)

(D)

2) All three spheres are identical having radius 10 cm. There is no slipping at any point of contact.
Plank P and Q are moving in opposite direction with speed 10 and 30 cm/sec. height of
instantaneous axis of rotation of sphere A from the ground is :

(A) 20 cm
(B) 30 cm
(C) 15 cm
(D) 25 cm

3) A uniform meter stick of mass m is pivoted about a horizontal axis through its lower end O.
Initially, it is held vertical and is allowed to fall freely. Its angular velocity at the instant when it
makes an angle of 60° with the vertical is

(A)

(B)

(C)

(D)

4) A solid hemisphere of mass m is kept on smooth horizontal surface. A small ball of mass m is
released at the top with gentle push towards right. Find angle with vertical at which ball will leave

the surface of the hemisphere.

(A)
(B)

(C)

(D)

SECTION-I (ii)

1) A light rigid rod AB of length 3ℓ has a point mass m at end A and a point mass 2m at end B is kept
on a smooth horizontal surface. Point C is the center of mass of the system. Initially the system is at
rest. The mass 2m is suddenly given a velocity v0 towards right. Take Z axis to be perpendicular to
the plane of the paper.

2
(A) The minimum moment of inertia (about Z-axis), Izz of the system is 5mℓ .

(B)
The magnitude of tension in the rod in subsequent motion is .

(C)
The ratio of moment of inertia about Z-axis at points A and B,
(D) Point C remains stationary during subsequent motion.

2) Two identical heavy steel balls rotate on a smooth horizontal surface being connected to light rods
of length ℓ and 2ℓ. Their centers are at a distance of 3ℓ. At the initial moment the ball is in points A
and B, having velocities v and 2v respectively. Their collision is completely elastic.

(A) After two collisions, the ball on the left is rotating clockwise with a velocity v.

(B)
The second collision occurs at time
(C) Between first and second collision, the ball on the right rotates by an angle of 2π.
(D) The collisions occur at regular intervals of time.

3) A block 'A' of mass m1 hits horizontally the rear side of a spring (ideal) attached to a block B of
mass m2 resting on a smooth horizontal surface. If v1 and v2 be the velocities of A and B at any

instant in opposite directions, then,

 The kinetic energy of the system with respect to the centre of mass reference frame will be
(A)

The kinetic energy of the system with respect to the centre of mass reference frame will be
(B)

If block A hits the spring with a velocity 'v' and velocity of B is zero and the stiffness constant of
(C)
the spring be 'k' the maximum compression in the spring will be
If block A hits the spring with a velocity 'v' and the stiffness constant of the spring be 'k' the

(D)

maximum compression in the spring will be

SECTION-II (i)

Common Content for Question No. 1 to 2

A block of mass 'm' is attached to one end of an ideal spring of spring constant 'K'. The system is
placed on a smooth horizontal surface. Initially, the spring is unstretched and system is placed on a
smooth horizontal surface. Initially, the spring is unstretched and system is at rest. Now, other end
of spring is pulled away from block with a constant acceleration a. Given, m = 4 kg, k = 100 N/m &

a = 2 m/s2.

1) Maximum speed attained by the free end of spring, relative to a reference frame attached to the
block (in m/s) is .............

2) Maximum elongation of the spring (in m) is ______.

Common Content for Question No. 3 to 4

Consider a rod of length 2m and uniform linear mass density of this rod is given by λ = 2 kg/m. If rod
is released from horizontal position as shown figure from rest. [Hinge point is frictionless] [Take g =

10 m/s2]

3) Find the normal force exerted by the hinge just after the release.

4) Find angular acceleration of rod just after release the rod.

SECTION-II (ii)

1) A body of mass m = 4 kg starts moving with velocity Vo in a straight line is such a way that on the
body work is being done at the rate which is proportional to the square of velocity as given by P=βv2

where β = . Find the time elapsed in seconds before velocity of body is doubled.

2) A block B of mass placed on rough horizontal surface is connected with block A with
the help of string (ideal). The string passes over fixed horizontal cylinder. The coefficient of
friction between block B and ground as well as between string and cylinder is µ = 7/11. Find the

minimum mass of block A (in kg) so that block B starts sliding. (Take value of and e = 2.72)

3) Force acting on a particle in conservative field is given by If potential energy at

origin i.e., u(0, 0) = 0. Then determine u(1, 1) – u(3, 3) (in J).

4) A ring of radius a = 1 m and having mass 4 kg lies on a smooth horizontal surface. One end of
each of the two massless spring k and 2k (k = 240 N/m) are fixed to the diametrically opposite points
of ring and the other end of the two springs is attached to a block of mass m = 1kg, which lies at the
centre of the ring and in this position springs are at their natural length.

If the block is displaced by a distance a/2 along the length of springs

such that spring of spring constant k is compressed a/2 and is released then at the instant when
each spring achieves it’s natural length, the velocity of the ring (in m/s) will be

5) The following figure shows a disc of radius R = 20 cm with a portion of it removed symmetrically.
The removed part is a disc of radius R/2. The removed part is now placed in contact with the larger
disc as shown in figure. Disc has uniform mass distribution. With respect to origin as centre of larger
disc find x- coordinate of centre of mass of system (in cm).

6) A is a fixed point at a height above a perfectly inelastic smooth horizontal plane. A light
inextensible string of length has one end attached to A and other to a heavy ball. The ball is held at
the level of A with string just taut and released from rest. The speed of ball just after striking the

plane is n times m/s. Find n. (Neglect the size of the heavy ball when compared to length )

PART-2 : CHEMISTRY

SECTION-I (i)

1) A sample of protein was analysed for metal content and analysis revealed that it contained
magnesium and titanium. If these are the only metallic species present in the protein and it contains
0.004% Mg by mass and 0.006%. Ti by mass, then the minimum possible molar mass (in gm/mol) of
the protein is : [Mg = 24, Ti = 48]

(A) 6 × 105
(B) 1.5 × 105
(C) 3 × 105
(D) 24 × 105

2) Consider the given statements

(i) Isopentane and neopentane has same length of parent carbon chain according to IUPAC.

(ii) is secondary amine while is a tertiary amine.

(iii) is a secondary alcohol while is a tertiary alcohol.

(iv) and both have different functional groups

Which is not incorrect?

(A) i, ii, iii

(B) ii, iii, iv
(C) i, ii, iv
(D) i, iii, iv

3) Select the CORRECT option.

(A) NH3 > SbH3 (Boiling Point)

(B) All the oxides of Mn are either basic or amphoteric in nature
(C) Cyanuric Triazide have 12 lone pairs.
(D) H3BO3 > Bond length (B–O)

4) Select correct for H3BO3 and H3PO2 :-

(A) Both are H+ donor acid

(B) Both are OH– acceptor acid
(C) Both are tribasic acid
(D) Both are monobasic acid

SECTION-I (ii)

1) A gas mixture contains 3 mol CH4 and 2 mol SO3. Correct statement(s) is/are - (S = 32, O = 16, C
= 12)

(A) Average molar mass of the mixture is 41.6 g/mol

% change in average molar mass of the mixture if SO3 is completely dissociated in SO2 and O2 =
(B)

(C) Mass ratio of CH4 and SO3 initially present in the mixture is 1 : 10.
If 1 mol more CH4 is added in the given gaseous mixture then the new average molar mass of
(D)
the mixture is 37.33.

2) Which of the following IUPAC name(s) is/are correct?

(A)

→ 3-Ethyl-2,3-dimethyl hexane

(B)
→ Hepta-1,5-dien-3-yne

(C)
→ 2-methyl ethenylpent-1-en-3-yne

(D)
→ 2,2,3-dimethylpent-3-ene

3) Select CORRECT statement(s)

(A) Magnitude of Dipole moment of HF is greater than of H2O

(B) SF6 polygon have 8 faces , 6 vertex and 12 edges.
(C) Compound of element of group 16 with covalency 4 have folded square shape or see-saw only.
(D) BeCl2 have Diagonal Hybridization

SECTION-II (i)

Common Content for Question No. 1 to 2

Consider the given compound, answer the following question

1) Find the total number of different functional groups in the given compound?

2) The degree of unsaturation of the given compound is :

Common Content for Question No. 3 to 4

Element "A" of second period can form neutral oxides as well as acidic oxide element "A" forms a
polar compound with atom "B" (Zeff = Z) (all possible combinations)

3) The difference in degeneracy of 2nd excited state of B & number of π bonds in A2O is_____.

4) Sum of sigma bonds in AB3, BA3 and A2B4 is ______.

SECTION-II (ii)

1) 5 mole mixture of KClO3 & MgCO3 is heated strongly. If volume of total gas produced at STP is
136.2 L. The mole percentage of MgCO3 in the mixture will be - [K = 39, Cl = 35.5, Mg = 24, O = 16]

2) The vapours of organic compound was burnt in oxygen. Equal volume of both gaseous substance
were taken at same pressure and temperature. After the reaction, the system was returned to the
original condition and it turn out that its volume has not changed. The product of combustion
contain 50% CO2(g) and 50% H2O(g) by volume and no other gas. Find the molecular weight of
organic compound (in gram/mol) in question.

3) A mineral consists of an equimolar mixture of the carbonates of two bivalent metals. One metal is
present to the extent of 13.2% by weight. 2.58 g of the mineral on heating lost 1.232 g of CO2.
Calculate the % by weight of the other metal. (Nearest integer)

4) A vessel fitted with a weightless, frictionless piston of 0.025 m2 contains excess conc. of HCl. The
piston moved 1m outward when 0.075 kg iron fillings were added at 300 K. The solution left behind
was found to contain Fe(II). The approximate purity of the iron sample is. (Answer to the nearest
integer)
(R = 0.08 L-atm K–1 mol–1) (Fe - 56) (External pressure = 1 atm)

5) How many of the following sets are member of same homologous series?
(i) C2H6, C4H10, C6H12
(ii) CH3–COOH, CH3–CH2–COOH, CH3–CH2–CH2–COOH
(iii) C3H7Br, C4H9Br, C6H13Br
(iv) CH3CHO, CH3CH2CHO, CH3COCH2CH3

(v)
(vi) CH3–NH2, CH3–NH–CH3, N(CH3)3
(vii) CH2=CH2, CH3–CH=CH2, CH3–CH2–CH=CH2
(viii) CH3–OH, CH3–CH2–OH, CH3CH2CH2–CH2–OH

6) How many IUPAC names are correct for the given substituents:
(a) (b)

(c) (d)

(e) (f)

(g) (h)

(i)

PART-3 : MATHEMATICS

SECTION-I (i)

1) The complete interval of values of x in satisfying the inequations

cos [Link] 2x > and 3cos x > 1, is

(A)

(B)

(C)

(D)

2) If α, β are roots of equation P(x2 – x) + x + 5 = 0 and P1 and P2 are two values of P obtained from

, then values of is-

(A) 64514
(B) 65719
(C) 67543
(D) 61217
3) Consider the system of equations ax + y = b, bx + y = 2a, ax + by = 3ab, where a, b ∈ {0, 1, 2}.
The number of ordered pair (a, b) for which system is consistent is equal to -

(A) 0
(B) 1
(C) 2
(D) 3

4) The number of solutions of in (0,

π) is

(A) 0
(B) 1
(C) 2
(D) infinitely many

SECTION-I (ii)

1) Let a, b, c be the roots of px3 + qx2 + rx + s = 0 where p, q, r, s are non zero real numbers and a,

b, c are positive real numbers. If determinant , then

(A) value of 'D' is r3p–3

(B) minimum value of 'D' is 27s2p–2

(C) r is always greater than

(D) If 3p + q = 0 and a2 + b2 + c2 = 5, then value of 'D' is 8.

2) If then possible simplification of is/are

(A) 2cosx
(B) –2cosx
(C) 2sinx
(D) –2sinx

3) If the system of equations x – cy – bz = 0, cx – y + az = 0 and bx + ay – z = 0 has a non-zero

solution and atleast one of a, b, c is a proper fraction, then

(A) a2 + b2 + c2 < 3
(B) abc < –1
(C) abc > –1
(D) a2 + b2 + c2 > 3

SECTION-II (i)

Common Content for Question No. 1 to 2

Consider the quadratic equation f(x)= (k2 – 4)x2 – (14k + 4)x + 48 = 0 has two distinct positive
integral roots, then answer the following questions

1) The value of k is

2) Correction : Old Ans. (3.00) New Ans. (2.00)

Reason : Only 2 solutions

The number of solutions of equation f(x) = , are

Common Content for Question No. 3 to 4

A telescopic series is a series whose sum eventually only have a finite number of terms after

cancellation
Based on above information, answer the following questions.

3) If upto infinity, then the value of 36 S is

4) If and , then equals

SECTION-II (ii)

1) In a ΔABC if medians from B and C are perpendicular then the minimum value of 3(cotB + cotC)
is

2) If c < 2 and the system of equation x + y – 2z = 0, 2x + y – cz = 0 and –bx + 2by – cz = 0 has non-

trival solution then if exhaustive set of b is (m, n) then value of is

3) In the equation x5 – 5x4 + 9x3 – 9x2 + 5x – 1 = 0 if p is the sum of real roots and q is the product of
real roots then the value of (p + q) is

4) Let A1, A2, A3, ......... A11 be 11 arithmetic means and G1, G2, G3, ........ G11 be 11 geometric means
and H1, H2, H3, ........ H11 be 11 harmonic means between two positive numbers a and b. If ab = 9 and

value of is pq where p is a prime number and q is a natural number then

value of is (where [⋅] is greatest integer function).

5) If ax = bc, by = ac, cz = ab, (where a, b, c > 0 and different than unity) then value of

is

6) The value of is :
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. C D B A

SECTION-I (ii)

Q. 5 6 7
A. B,C A,C A,C

SECTION-II (i)

Q. 8 9 10 11
A. 0.40 0.16 10.00 7.50

SECTION-II (ii)

Q. 12 13 14 15 16 17
A. 8 2 34 3 5 4

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. D B C D

SECTION-I (ii)

Q. 22 23 24
A. A,B,D A,B B,C,D

SECTION-II (i)

Q. 25 26 27 28
A. 9.00 30.00 7.00 11.00

SECTION-II (ii)

Q. 29 30 31 32 33 34
A. 60 30 22 78 4 5

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 35 36 37 38
A. C A B A

SECTION-I (ii)

Q. 39 40 41
A. A,B,D B,C A,C

SECTION-II (i)

Q. 42 43 44 45
A. 4.00 3.00 3.00 3.00

SECTION-II (ii)

Q. 46 47 48 49 50 51
A. 2 5 5 5 2 6
 SOLUTIONS

PART-1 : PHYSICS

1) dI =

I=

2) Let x be the distance of axis of rotation from the top of sphere A(downward). Since angular
velocity of the top and bottom point of sphere A will be same, therefore,

∴ Distance from ground

=2R + (2R –x)
= 20 + 5 = 25 cm

3)

4)
Correct Answer is (A)

5)

Correct Answer is (B,C)

6) 1st collision at

ω2t = 2nπ

ω1t = 2mπ ⇒

2nd collision at

n' = m'

t' =

7)

(KE) of system wrt to com =

By w.e.t. in center of mass frame

Work done by all = Δke

= µ(VRelf2 – VReli2)
8) Speed attained by the free end w.r.t. the block is same as the speed attained by the block
w.r.t. free end.
Maximum speed is attached at equilibrium (w.r.t. the free end)
keeq = ma

Applying work – energy theorem, we get

9)

10)

Mass of rod = λ × 2
= 2×2
= 4 kg

α = 7.5 rad/s2
mg – N1 = macm
4g – = 4 × (1 × 7.5)
N = 40 - 30
1
N = 10 Newton
1
11) 40 × 1 = 4 × 22/3 × α

12)

Correct Answer is (8)

13)
T1 = µMBg
T2 = mg
due to friction on pull
in limiting case, when block B is about to slide

Solving equation m = 2 kg

14)

u(x, y) = –x2 –y3

u(3, 4) = –32 – 33 = –36
Therefore, u(1, 1) – u(3, 4) = –2 – (–36) = 34.

15)

Correct Answer is (3)

16) Mass will be in the direct proportion of area.

So, if m is the mass of whole disc, then will be the mass of removed disc.
 17) After collision the velocity of the ball = .

PART-2 : CHEMISTRY

18)

We have to find, minimum possible molar mass of protein :

Mass ratio of 'Mg' and 'Ti' =

Mole ratio of 'Mg' and 'Ti' =

It means, 1 mole of protein contains,
4 mole of Mg and 3 mole of Ti
4 mole of Mg = 24 × 4 = 96 g
3 mole of Ti = 3 × 48 = 144 g
Total mass of metal = (96 + 144)g = 240 g

∴ % Mass of metal =

⇒ 0.01 =
∴ Molar mass of protein = 2400000 g/mol

19)

The correct answer is option (B)

20) Mn2O7 is acidic

Cynuric Triazide is C3N3(N3)3

21) H3BO3 is monobasic Lewis acid but H3PO2 is monobasic Bronsted acid.

22)

CH4 → 1 mole
SO3 → 2 mole

(A) Mavg = = 41.6 g/mol

(B) CH4 → 3 mole

SO3 → SO2 + O2
2 mole – –
 – 2 mole 1 mole
Now in sample we have CH4, SO2 and O2

Mavg = = 34.66

% change

(C)
(D) CH4 → 4 mole
SO3 → 2 mole

Mavg = = 37.33

23)

The correct answer is option (A, B)

24) (i) µ(H2O) : 1.85 D µ(HF) : 1.78 D

(ii) octahedral geometry
(iii) Compound with 4σ bond and 1 ℓ.p. can have folded square shape or see-saw.
(iv) sp hybridization is also called Diagonal Hybridization.

25)

The correct answer is (9)

26)

The correct answer is (30)

27) B is single electronic specie (H , He+, Li+2.........etc.) preferably H

A is nitrogen, it form polar compound with B
N2O have 2π bonds
Degeneracy of B in 2nd E.S. is 9

28) AB3 : NH3 3σ bonds

BA3 : HN3 3σ bonds
A2B4 : N2H4 5σ bonds

29)
So,
Hence, x = 3

% MgCO3 = ×100 = 60 %

30)

'S' + O2 → CO2 + H2O

t = 0 V lit. V lit. 0 0
tfinal 0 0 V lit. V lit.
POAc on 'C'
V×x=V
POAc on 'H'
V × y = 2V
y=2
POAc on 'O'
(Organic compound must contain oxygen)
ZV + 2V = 2V + V
Z=1
Compound is CH2O
Hence, molar mass = 30 g/mol.

31)

Let two equimolar carbonates are ACO3 and BCO3.

Wt. of metal A = 2.58 × 0.132 = 0.34 gm
ACO3 + BCO3 → AO + BO + 2CO2
Total two moles provide 2 moles of CO2
or 60 gm provide 44 gm of CO2
Mass of required to produced 1.232 g of CO2

= 1.232 = 1.68 gm
so total wt. of cabonates = 1.68 gm
wt. of metal (A + B) = 2.58 – 1.68 = 0.90 gm
wt. of B = 0.90 – 0.34

= 0.56 gm ; % of B = × 100
= 21.70 Ans.

32) Fe + HCl → FeCl2 + H2

x mole x mole

W = 58.33
 % purity = = 77.78%

33)

ii, iii, vii, viii

34)

The correct answer is 5

PART-3 : MATHEMATICS

35) 4cosx.cos2x + 1 > 0

4cosx (2cos2x – 1) + 1 > 0
8cos3x – 4cosx + 1 > 0

Let cosx = t

∴ ∴ 1 ≥ cosx > ∴

36) Px2 + (1 – P)x + 5 = 0

P2 – 16p + 1 = 0
P1 + P2 = 16 P1P2 = 1

= ((P1 + P2)2 – 2P1P2)2 – 2

= (256 – 2)2 – 2
= 64514
37) For consistency
a2b – 3ab2 + 2a2 + b3 – ab = 0
b3 – 3ab2 + (a2 – a)b + 2a2 = 0
b=0:a=0
b = 1; 1 – 3a + a2 – a + 2a2 = 0
3a2 – 4a + 1 = 0

(3a – 1) (a – 1) = 0 ⇒ a = 1 (reject) or (reject)

b = 2 : 8 – 12a + 2a2 – 2a + 2a2 = 0
4a2 – 14a + 8 = 0
2a2 – 7a + 4 = 0
⇒ not integral solution
only one ordered pair (0,0)

38) Let a = sinx + cosecx =

= 2cosecx – cosx cotx

= a2 + 1
Hence Δ = 0 has no real solution.

39)
D = (ab + bc + ca)3
∵ a,b,c are roots of px3 + qx2 + rx + s = 0

a+b+c=

ab + bc + ca =

abc
∵ AM ≥ GM

(ab + bc + ca)3 ≥ 27a2b2c2

If 3p + q = 0 ⇒
and a2 + b2 +c2 = 5 then (a + b + c)2
= Σa2 + 2Σab
9 = 5 + 2 Σab
⇒ Σab = 2, D = 8

40)

⇒ ⇒

⇒ ⇒ 2x ∈ (π, 2π)

= 2|sinx| = 2|cosx|
= 2sinx = –2cosx

41) For non trivial solution

⇒ ⇒ 1 – 2abc – a2 – b2 – c2 = 0
⇒ a + b c + 2abc = 1 – b2 – c2 + b2c2 ⇒ (a + bc)2 = (1 – b2).(1 – c2)
2 2 2

Similarly ; (b + ac)2 = (1 – a2) (1 – b2)

(c + ab)2 = (1 – a2)(1 – b2)
So 1 – a2, 1 – b2, 1 – c2 are of same sign and atleast one in proper fraction, so all are positive.
⇒ 1 – a2 > 0, 1 – b2 > 0 ; 1 – c2 > 0 ⇒ a2 + b2 + c2 < 3 and 1 – 2abc < 3 ⇒ abc > –1

42) By solving the equation roots are

So only k = 4 is only value for positive integral roots.

43) Draw graph

44)

⇒0
36 S = 3

45) ⇒ tn = Sn – Sn – 1 = n(n + 1)

46)

tanB = tan(B1 + B2)

tanB

Similarly

47) For non-trival solution

i.e. 3bc + c – 10b = 0

48) Sum of the coefficients = 0

⇒ one root is 1
x5 – 5x4 + 9x3 – 9x2 + 5x – 1 = 0
(x – 1)(x4 – 4x3 + 5x2 – 4x + 1) = 0
(1) ⇒ x2 – 3x + 1 = 0

(2) (rejected)

real roots are

Sum (p) = =4

product (q) = =1

49) A1H11 = A2H10 = A3H9 = A4H8 = A5H7 = ab

a, G1, G2, G3, G4, ............., G10, G11, b are in G.P.
⇒ G2G10 = G4G8 = (G6)2 = ab

= (A1H11) (A2H10) (A3H9) (A4H8) (A5H7) (G10G8G6G4G2)

= (ab)5 (ab)2
= (ab)7 = (32)7 ⋅ 3 = 315 = pq

⇒ =5

50) x = logabc, y = logbac, z = logcab

Value of

51)

⇒ Tr = =