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The document contains a series of mathematical and physics problems, including functions, calculus, geometry, and mechanics. It is divided into two parts: Mathematics and Physics, with multiple-choice questions in each section. The problems range from determining properties of functions to analyzing physical systems involving forces and fields.

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0% found this document useful (0 votes)
3 views40 pages

Solution

The document contains a series of mathematical and physics problems, including functions, calculus, geometry, and mechanics. It is divided into two parts: Mathematics and Physics, with multiple-choice questions in each section. The problems range from determining properties of functions to analyzing physical systems involving forces and fields.

Uploaded by

jeerelated27
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

24-05-2026

1001CJA106216260097 JA

PART-1 : MATHEMATICS

SECTION-I

1) Let the function f : [0,1] → R be defined as

for 0 < x < 1.


Then which of the following statements is correct ?

(A)
f is strictly increasing on and strictly decreasing on .

(B)
f is strictly decreasing on and strictly increasing on .

(C)
f is strictly increasing on and strictly decreasing on

(D)
f is strictly decreasing on and strictly increasing on

2) Let such that f(1) = . Then f'(1) is equal to

(A) 0

(B)

(C)

(D) 2

3) Let where x ∈ [2, 4].


Assertion: Conclusion of L.M.V.T. holds for f(x) at an irrational value of x.
and
Reason: For any differentiable function in [a, b] there exist atleast one irrational value in (a, b) at
which conclusion of L.M.V.T. holds.

(A) Assertion is True, reason is True; reason is a correct explanation for assertion.
(B) Assertion is True, reason is True; reason is not a correct explanation for assertion.
(C) Assertion is True, reason is False
(D) Assertion is False, reason is True.
4) Let and f(0) = 2 then f(–1) is equal to

(A) 6
(B) 7
(C) 8
(D) 9

5) A person is standing at the edge of a slow moving river which is 1 km wide. He wishes to return to
the camp ground on the opposite side of the river for which he may swim to any point on the
opposite bank and then walk for the rest of the distance. The campground is 1 km away from the
point on the opposite bank directly across from where he starts to swim. If he swims at the rate of 2
km/hr and walks at the rate of 3 km/hr, the minimum time taken by him is approximately.

(A) 0.6 hr
(B) 0.7 hr
(C) 0.8 hr
(D) 0.9 hr

6) If ƒ(x) , then equation of tangent at x = 0 to the curve is given by -

(A) y = 2x + 1
(B) y = x + 3
(C) 2x + y = 1
(D) y = x + 1

7) If y2 = 2ax, a > 0 and intersect orthogonally, then 'a' equals to

(A)

(B) 2

(C)

(D) 4

8) Let ƒ(x)= xe–x(x + 1) is increasing in , where a ∈ N, then value of (a + b) is

(A) 3
(B) 1

(C)

(D) 2

9) Match the following statement in List-I with the values in List-II


List-I List-II

The number of rational points on the ellipse


(A) (I) Infinite
is

The number of integral points on the ellipse


(B) (II) 4
is

The number of rational points on the ellipse


(C) (III) 2
is

The number of integral points on the ellipse


(D) (IV) 0
is
(A) (A) – I, (B) – III, (C) – II, (D) – III
(B) (A) – I, (B) – II, (C) – I, (D) – III
(C) (A) – III, (B) – I, (C) – I, (D) – III
(D) (A) – I, (B) – II, (C) – I, (D) – IV

10) A value of c for which the Rolle's theorem holds for the function ƒ(x) = 2x3 + x2 – 4x – 2 on the

interval is

(A)

(B)

(C)

(D)

11) If x + 2y = k is a normal to y2 = 16x, then the value of 'k' is

(A) 3
(B) 6
(C) 9
(D) 12

12) If m is slope of common tangent of curves y2 = 8x and x2 = 64y then possible value of m is :

(A)

(B) 2
(C) –2

(D)

13) If radius of a cylinder is decreasing at the rate of 3m/sec and it's altitude is increasing at rate of
5m/sec, then the rate of change of volume when radius is 3m and altitude is 2m is-

(A) 3π m3/sec
(B) 78π m3/sec
(C) 9π m3/sec
(D) 21π m3/sec

14) The acute angle of intersection between the curves y = x2 and is

(A)

(B)

(C)

(D) None of these

15) Statement-1 : If p < q and px2 + 4μxy + qy2 + 4a(x + y + 1) = 0 represents pair of straight lines
for some μ ∈ R and a ≠ 0, then a ≤ p or a ≥ q
Statement-2 : The given equation has non-zero linear terms

(A) Both the statements are true and Statement 2 is correct explanation of Statement 1.
(B) Both the statements are true and Statement 2 is not the correct explanation of Statement 1.
(C) Statement 1 is true and Statement 2 is false.
(D) Statement 1 is false and Statement 2 is true.

16) is (where c is constant of integration)

(A)
+c

(B)
+c

(C)
+c
(D) None of these

17)

The integral equals (for some arbitrary constant K)


(A)

(B)

(C)

(D)

18) If , then
(where C is constant of integration)

(A)

(B)

(C)

(D)

19) Let f(x) = dx and f(0) = 0. Then f(1) is equal to

(A) loge (1 + )
loge (1 + )–
(B)

(C) log (1 + )+
e

(D) None of these

20) is equal to ________.


(where C is constant of integration)

(A)

(B)

(C)
(D)

SECTION-II

1) Through the vertex O of parabola y2 = 4x, chords OP and OQ are drawn at right angles to one
another, where P and Q are point on the parabola. If the locus of middle point of PQ is y2 = 2(x – ℓ),
then value of ℓ is

2) If ƒ(x) = x + 2x3 + 3x5 such that g(x) = ƒ–1(x) then is

3) Consider ƒ(x) = max(|x|, 2x – x2), x ∈ R. Let there are m points of discontinuity and n points of non
derivability of function y = |ƒ(|x|)|, then m + n is equal to

4) If then 10A equals to


(where C is constant of integration)

5)

If , then k.m is equal to (where C is constant of


integration)

PART-2 : PHYSICS

SECTION-I

1) If a particle is performing oscillations in x-direction about origin, having potential energy U = [Link].
Then find how time period depend on Amplitude

(A)
(B)
(C)
(D) None of these

2) A solid cylindrical wire of radius R has a current I flowing along its length. It has a long cylindrical
cavity of radius R/2 as shown. Find the magnetic field at point P (in figure).

(A)

(B)

(C)

(D)

3) A non-conducting piston of mass m and area S divides a non-conducting, closed cylinder into two
parts as shown in figure. Piston is connected with left wall of cylinder by a spring of force constant
K. Left part is evacuated and right part contains an ideal gas at pressure P. Adiabatic constant of the
gas is γ and in equilibrium length of each part is . Calculate angular frequency of small oscillations

of the piston.

(A)

(B)

(C)

(D)

4) A small particle is placed at the pole of a concave mirror and then moved along the principal axis
to a large distance. During the motion, the distance between the pole of the mirror and the image is
measured. The procedure is then repeated with a convex mirror, a concave lens and a convex lens.
The graph is plotted between image distance versus object distance. Match the curves shown in the
graph with the mirror or lens that is corresponding to it. (Curve 1 has two segments)
(A) P→1, Q→1, R→2, S→2
(B) P→1, Q→2, R→3, S→4
(C) P→1, Q→2, R→2, S→3
(D) P→3, Q→2, R→1, S→4

5) The circuit shown above shows a steady state with S open. When S is closed :-

(A) No charge/current passes through S.


(B) A steady current of 30 A flows through S.
(C) 90µC of charge flows from B to A.
(D) 120 µC of charge flows from A to B.

6) An instrument uses two mirror as shown in figure. Such instrument is built with two mirrors 20
mm apart. If the radius of curvature of the large mirror is 220 mm and the small mirror is 140 mm,
where the final image of an object at infinity will be formed from M3 ?

(A) 21 cm
(B) 31.5 cm
(C) 27.5 cm
(D) 19 cm

7) Variation of x-component of electric field with x-coordinate in a region is given in the graph. A
small electric dipole having dipole moment is placed at origin, then net force on the dipole is :
(A) P0 tan θ along positive x-axis
(B) Zero
(C) P0 tan θ along negative x-axis
(D) P0 tan θ along positive y-axis

8) A thin spherical insulating shell of radius R carries a uniformly distributed charge such that the
potential at its surface is V0. A hole with a small area α4πR2 (α<<1) is made on the shell without
affecting the rest of the shell. Which one of the following statements is correct ?

The ratio of the potential at the center of the shell to that of the point at R from center
(A)
towards the hole will be
The magnitude of electric field at the center of the shell is reduced by
(B)

The magnitude of electric field at a point, located on a line passing through the hole and shell's
(C)
center at a distance 2R from the center of the spherical shell will be reduced by
(D) The potential at the center of the shell is reduced by 2αV0

9) A particle of mass m and charge q, accelerated by a potential difference V enters a region of a


uniform transverse magnetic field B in a direction perpendicular to boundary. If d is the thickness of
the region of B, the angle θ through which the particle deviates from the initial direction on leaving
the region is given by :-(Assume that the particle comes out of the other boundary)

(A)

(B)

(C)

(D)

10) Two hemispherical shell of radius R1 and R2 and having charges Q and 2Q distributed uniformly
respectively are arranged as shown. The force of interaction between two shells is (R2 << R1) :-
(A)

(B)

(C)

(D)

11) Nickel is ferromagnetic at room temperature. At a value of H field of 5 × 105 A/m, nickel
saturates. The magnetic field B is 1.25 T. What is the magnetisation vector of nickel sample?

(A) 5 × 105 A/m


(B) +3.744 × 105 A/m
(C) 9.31 × 104 A/m
(D) 15 × 105 A/m

12) A conducting balloon of radius a is charged to a potential V0 and held at a large height above the
earth surface. The large height of the balloon from the earth ensures that charge distribution on the
surface of the balloon remains unaffected by the presence of the earth. It is earthed through a
resistance R and a valve is opened. The gas inside the balloon escapes through the valve and the size
of the balloon decreases. The rate of decreases in radius of the balloon is controlled in such a
manner that the potential of the balloon remains constant. Assume electric permittivity of the
surrounding air equal to that of free space and charge does not leak to the surrounding air. How
much heat is dissipated in the resistance R until radius of the balloon becomes half?
(A)
(B)
(C)
(D)

13) Given below are two statements :


Statement-I : The equivalent emf of two nonideal batteries connected in parallel is smaller than
either of the two emfs.
Statement-II : The equivalent internal resistance of two nonideal batteries connected in parallel is
smaller than the internal resistance of either of the two batteries.
In the light of the above statements, choose the correct answer from the options given below.

(A) Statement-I is true but Statement-II is false


(B) Both Statement-I and Statement-II are false
(C) Both Statement-I and Statement-II are true
(D) Statement-I is false but Statement-II is true

14) Two circuits (shown below) are called 'circuit A' and circuit B, The equivalent resistance
of circuit A is x and that of circuit B is y between 1 and 2.

(A) y < x

(B)
(C) xy = 2R2
(D) x – y = 2R

15) Between the plates of a parallel-plate capacitor, there is a symmetrically placed metallic plate
whose thickness takes up 60% of the capacitor gap. When that plate is absent the capacitor has a
capacity C = 20nF. The capacitor is connected to a dc voltage source of voltage =100 V. The metallic
plate is slowly extracted from gap. Find the mechanical work (in μJ) performed in the process of
plate extraction.

(A) 150
(B) 100
(C) 250
(D) 200

16) Figure shows a vertical parallel plate capacitor of plate dimension (l × b) with separation d
connected to the battery via switch (s). if switch is closed then the height between the plate to which
liquid level will rise is :- (Dielectric constant of water is k)

(A)

(B)

(C)

(D)

17) Consider a long thin conducting wire carrying a uniform current I. A particle having mass “M”
and charge “q” is released at a distance “a" from the wire with a speed vo along the direction of
current in the wire. The particle gets attracted to the wire due to magnetic force. The particle turns
around when it is at distance x from the wire. The value of x is [μ0 is vacuum permeability]
(A)

(B)

(C)

(D)

18) An uniform hemi-solid sphere is placed with flat surface on rough inclined plane as shown in
figure. If friction is large for no sliding, then the minimum angle θ at which toppling occur, is

(A)

(B) 45°

(C)

(D)

19) A bead is connected with a fixed disc of radius R by an inextensible massless string in a smooth
horizontal plane. If the bead is pushed with a velocity v0 perpendicular to the string, the bead moves

in a curve and consequently collapses on the disc. Then :

(A)
Initial angular acceleration of the particle is .
Initial angular acceleration of the particle is
(B)

(C)
Distance travelled by the particle till it collides with the disc is

(D)
Distance travelled by the particle till it collides with the disc is

20) A Uniform magnetic field exists perpendicular to the plane of a copper wire ring with a diameter
D = 2 m and diameter of cross-section d = 2 mm. Take resistivity as 10–8 Ωm. At what rate should
magnetic field change over time to have the induced current in the ring of 10 A ?
(A)

(B)

(C)

(D) None of these

SECTION-II

1) Current i = 2.5 A flows along the circular coil whose equation is given by x2 + y2 = 9 cm2 (here x
& y are in cm). If magnetic field is given by πx × 10–7 T at point (0, 0, 4 cm). State value of x.

2) A charge particle of charge q and mass m is projected in a region which contains electric and

magnetic field as shown in the figure with velocity v at an angle 45° with x direction. If ,
then net deviation in particle motion will be θ (in degree) then find the value of θ/15. (neglect the

effect of gravity)

3) A stick of length L and mass M lies on a frictionless horizontal surface on which it is free to move
in any way. A ball of mass m moving with speed v collides elastically with the stick as shown in the

figure. If after the collision the ball comes to rest, then what should be the value of ?

4) A cylinder is released from rest on a rough inclined plane. Maximum value of angle θ for which

cylinder rolls without slipping after the release is . Find (α + β).


5) In the given potentiometer arrangement, wire AB is uniform and of length 100 cm. Jockey J is
performing SHM between points P and Q on the wire AB with time period 24 seconds. Initially
jockey is at a distance of 47.5 cm from end A and moving towards P. The minimum time (in sec) after

which current in the galvanometer will be zero is :-

PART-3 : CHEMISTRY

SECTION-I

1) A gas undergoes change from state A to state B. In this process , the heat absorbed and work
done by the gas is 5 J and 8 J, respectively. Now gas is brought back to A by another process during
which 3 J of heat is evolved. In this reverse process of B to A:-

(A) 10 J of the work will be done by the surrounding on gas.


(B) 6 J of the work will be done by the surrounding on gas.
(C) 10 J of the work will be done by the gas.
(D) 6 J of the work will be done by the gas.

2) For a pseudo-first-order reaction the reaction was conducted in two different

solvents, S1​ and S2​. The rate constants k1​ and k2​ were found to follow: ln k = ln A − ​. If Ea1​ > Ea2​
and at T0​, k1​ = k2​, then:

(A) At T > T0​, k1​ > k2​.


(B) At T < T0​, k1​ > k2​.
(C) The reaction in S1​ is temperature-independent.
(D) A plot of ln(k1​ / k2​) vs 1/T will have a positive slope.

3) 3.00 mole of PCl5 kept in 1L closed reaction vessel was allowed to attain equilibrium at 380 K.
Calculate composition of the mixture at equilibrium.
PCl5(g) PCl3(g) + Cl2(g)
The incorrect option is :

(A) [PCl5] = 1.41 M


(B) [PCl3] = 1.59 M
(C) [Cl2] = 1.41 M
(D) [Cl2] = 1.59 M

4) A small amount of solid lead iodide was added to a beaker of water, which was stirred. Most of the
solid settled at the bottom of the beaker, but a little dissolved, establishing the equilibrium

The rates of the forward and reverse reactions were monitored over time, producing the graph

shown below: What happened at time t?

(A) The beaker was cooled in an ice-bath.


(B) A small amount of solid KI was added to the beaker.
(C) A small amount of solid PbI2 was removed from the beaker.
(D) A small amount of water was added to the beaker.

5) Consider the following unit cell of a metal: Also consider the following

shaded planes P and Q representing two 2D lattices. The ratio of


packing fraction of P to Q is

(A) 1.00
(B) 1.63
(C) 0.55
(D) 0.74

6) For 1 mole of oxygen gas (assuming ideal behaviour), P-V curve is given

Then for the given change, select the incorrect statement(s)

(A) For process AB, change in internal energy (ΔU) > 0


(B) For process BC, change in temperature (ΔT) > 0
(C) For process CD, heat is rejected from the system.
(D) For process DA, heat is abserbed by the system.

7) Which of the following correctly matches a crystal system with its axial lengths, interfacial angles,
and possible Bravais lattice types?

(A) A crystal system with and can have both primitive and face-
centred Bravais lattices.
(B) A crystal system with a = b = c and can have only primitive Bravais lattice.

(C) A crystal system with and can have only primitive, face-centred and
end-centred Bravais lattices.

(D) A crystal system with and can have only primitive, body-
centred and end-centred Bravais lattices.

8) Matching list

List-I List-II

(P) Pb (1) Removed as one of the impurity during distillation of Zn

(Q) Sn (2) Contain impurity of its metal oxide and removed by Polling

(R) Cu (3) Removed as oxide during cupellation of Ag/Au

(S) Ti (4) At least one of the refining technique like liquation / Van arkel method can be used.
(A) P→2,3,4 ; Q→3,4 ; R→2,4 ; S→2,4
(B) P→3,4 ; Q→1,3 ; R→2 ; S→4
(C) P→1,3,4 ; Q→2,4 ; R→2 ; S→4
(D) P→1,2,3 ; Q→2,4 ; R→2,4 ; S→2,4
9) Select the incorrect statement.

(A) Number of O–Zn–O Bond angles in [Zn(acac)2] is 6


2
(B) Both the complexes [NiCl2(NH3)2], [NiCl2(PPh3)2] are dsp hybridised
3–
(C) [Cr(ox)3] has symmetrical electronic arrangement of d-electrons
3–
(D) Number of linkage isomer of [Co(SCN)4 (NO2)2] is 12

10) A rhodium complex 'X' used for hydrogenation of alkenes, select the correct statement regarding
the complex 'X'?

(A) Coordination No = 6
(B) Shows Synergic Bonding
(C) Hybridisation is sp3d2
(D) Oxidation state of Rh is +2

11) Which of the following is INCORRECTLY matched against the indicated property ?

3– 4–
(A) [Mn(CO)4] , [Cr(CO)4] ; Isoelectronic species
2– 4–
(B) [NiF6] , [NiF6] ; for both (Δo > P)
(C) [Pt(NH3)2Cl2Br2] ; Number of stereoisomer = 6
+2
(D) Na2[Fe(CN)5NO] < [Fe(H2O)5NO] ; Number of electrons in eg orbital

12) In the extraction of copper, the reaction which does not take place in Bessemer converter is :

(A) 2CuFeS2 + O2 → Cu2S + 2FeS + SO2


(B) 2Cu2O + Cu2S → 6Cu + SO2
(C) FeO + SiO2 → FeSiO3
(D) 2FeS + 3O2 → 2FeO + 2SO2

13) Select the correct statement regarding the metallurgical process of ores ?

(A) Calamine, after roasting produces oxide ore for which carbon reduction is used.
(B) In Mac Arthur-Forrest process for argentite, O2 is passed to oxidise the Na2S formed.
(C) In calcination, impurities are removed in the form of volatile oxides.
(D) In Down's process aqueous salt electrolysis is not used as O2(g) is produced at cathode.

14) The complex [Fe(CN)6]–3 has Δoct = 3500 cm–1 .


Using the above information , identify the correct statement regarding the splitting energy and
colour of the complex. [h = 6.626 × 10–34 Js]

–20
(A) Δoct = 6.96 × 10 J ; complex appears red
–19
(B) Δoct = 6.96 × 10 J ; complex absorbs violet light and appears pale yellow
–19
(C) Δoct = 3.50 × 10 J ; complex appears green
–18
(D) Δoct = 1.05 × 10 J ; complex absorbs red light
15) Statement-I : Sodium salt of butanoic acid on heating with soda lime gives n-butane.
Statement-II : Sodalime decarboxylation reaction has carbanionic intermediate.

(A) Both Statement I and Statement II are incorrect.


(B) Statement I is correct but Statement II is incorrect.
(C) Statement I is incorrect but Statement II is correct.
(D) Both Statement I and Statement II are correct.

16) Which of the following statements is TRUE regarding the catalytic hydrogenation of Propanal
(CH3​CH2​CHO) and Propanone (CH3​COCH3​)?

(A) Propanone reduces faster because the carbonyl carbon is more electrophilic.
(B) Propanal reduces faster because it is less sterically hindered.
(C) Both reduce at the same rate as they are isomers.
(D) Catalytic hydrogenation cannot distinguish between them.

17) An alkene (X) on reductive ozonolysis gives following products.

The alkene (X) is :

(A)

(B)

(C)

(D)

18) An organic compound “P” of molecular formula C6H12O3 gives positive lodoform test but negative
Tollen’s test. When “P” is treated with dilute acid, it produces “Q”. “Q” gives positive Tollen’s test
and also iodoform test. The structure of “P” is :

(A)
(B)

(C)

(D)

19) The best reaction sequence to convert 2-methyl-1-bromopropane into 4-methyl-2-bromopentane


is :

(A) (i) Mg in ether (ii) acetaldehyde (iii) NH4Cl ; (iv) SOBr2


+
(B) (i) NaC ≡ CH in ether (ii) H3O + HgSO4 (iii) HBr, heat
(C) (i) Alcoholic KOH (ii) CH3COOOH (iii) H2 / Pt (iv) HBr, heat
(D) (i) NaC ≡ CH in ether (ii) H2, Lindlar catalyst (iii) HCl , peroxide

20) How many of reagents can carry out following transformation :

(a) Cu, 300°C (b) O3 / Zn, H2O (c) NBS (d)


Zn–Hg / HCl

(e) Jones reagent (f) KMnO4, NaOH, Δ (g) Al(OCMe3)3 ,

(h) Collin's reagent (i) (i) TsCl, (ii) DMSO, NaHCO3 , Δ (j)

(A) 6
(B) 7
(C) 8
(D) 9

SECTION-II

1) The enthalpy of vapour is 10 kcal/mole higher than liquid at 350 K and 2 atm. Under given
conditions, the difference in internal energy (in cal) of vapour and liquid will be.

2) For the first order reaction : A(g) → 2 B(g) +C(g), the half-life for decomposition of A is 3 minutes
at 300K. Calculate the time (in minutes) in which the initial pressure of A at 2 atm (at 400K) changes
to a final total pressure of 5 atm at 400K. (Given activation energy of reaction is 840R and ln2 = 0.7)

3) A sulphide ore of a metal 'M' is partially roasted such that 1/3 rd of MS is converted to MO, while
the remaining stays as MS. The mixture is then heated strongly in absence of air to yield metal 'M'
via self reduction.
Total moles of SO2 formed per mole of initial MS taken is 'x'. Find the value of '6x'

4)
Compound (X) is subjected to the sequence of reactions as shown above. Molar mass of the major
product (Y) formed is ______ gmol–1.
(Given molar mass in g mol–1 C : 12, H : 1 , O : 16)

5) (P) + EtOH
P is the major organic product. Calculate the total number of oxygen atoms in P.
ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D A C A B D B A B C C D C A B A C C B C

SECTION-II

Q. 21 22 23 24 25
A. 4 22 3 38 1

PART-2 : PHYSICS

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B B A A C B C A A A A C D C A B D C B C

SECTION-II

Q. 46 47 48 49 50
A. 36 1 4 7 10

PART-3 : CHEMISTRY

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B A C D B B B C D B B A B B C B D B A C

SECTION-II

Q. 71 72 73 74 75
A. 9300 3 3 118 1
SOLUTIONS

PART-1 : MATHEMATICS

1) x ≥ y

is max. when y = 0

x<y

is max. when y = 1

2)

let x + 1 + = t2
C=0

3)

⇒ 1 + ℓnc = ℓn8 ⇒ c = (irrational value)


S2 : is false

4)
let 4x4 – 2x3 – 3x2 – 4 = A(x4 + x3 + 1) + (Bx + C) (4x3 + 3x2)
⇒ A = –4, B = 2, C = –1

(applying by parts)

5) T = D/S ⇒

f'(x) = 0 ⇒ x = for minima


⇒ f(x) = minimum time = 0.7 hr approximately

6) = ƒ(x)
x=0 ƒ(0) = 1 ƒ'(0) = 1
7) y2 = 2ax
2yy′ = 2a xy′ + y = 0

For orthogonal ⇒ = –1 ⇒ a = x
∵ y2 = 2ax ⇒ y2 = 2a2

∵ ⇒
a=2

8) ƒ′(x)

ƒ′(x)

ƒ(x) is increasing in

9)

(A) (Rational Points)


This is an ellipse with rational coefficients.
It has at least one rational point, for example, (3, 0)
Property : If a conic with rational coefficients has at least one rational point, it has infinitely
many rational points.

(B) (Integral Points)


We look for integer solutions to 4x2 + 9y2 = 36.
possible values for x2 : 0, 1, 4, 9.
If x = 0, 9y2 = 36 ⇒ y = ±2.
Points : (0, 2), (0, –2).
If x = ±3, 9y2 = 0 ⇒ y = 0.
Points : (3, 0), (–3, 0).
Total points : 4

(C) (Rational Points)


This is x2 + 3y2 = 3.
It has rational points like ? No, is irrational.

Let's check for any (x, y) ∈ Q2. If and , then x2 + 3y2 = 3.


If a rational point exists, we can show via descent or Legendre's Theorem that X2 + 3y2 =
3Z2 has non-trivial integer solutions. Here, (0, 1) is a solution because 02 + 3(1)2 = 3.
Since it has one rational point (0, 1), it has infinitely many.

(D) (Integral Points)


We look for integer solutions to x2 + 3y2 = 3.
If y = 0, x2 = 3 (no integer solution).
If y = ±1, x2 + 3 = 3 ⇒ x = 0.
Points : (0, 1), (0, –1).
Total points : 2

10) As, ƒ(x) is a polynomial function, is continuous and differentiable for all real x.
Also ƒ(x) = (x2 – 2)(2x + 1)

and ƒ =0=ƒ

Hence by Rolle's theorem for atleast one ƒ'(x) = 0


ƒ'(x) = 0
⇒ 6x2 + 2x – 4 = 0

11)

Question Explanation:

We have to find value of k for which given line is normal of conic.

Concept:

This question is based on equation of normal.

Solution:

is normal to y2 = 16x

⇒ here ,
Equation of normal y = mx – 2am – am3
Compare

Final Answer: Option (3)

12) Let common tangent y = mx + c

c= = – 16m2 ⇒ m =

13)

v = pr2h
= 9π m3/sec

14) Question Explanation: Calculate the angle between a parabola and an ellipse at their
intersection.

Concept: Angle of Intersection of Two Curves.

Solution:

Curves: y = x2 and (Ellipse).

Substituting x2 = y into the ellipse:


Solving 16y2 + 9y – 25 = 0 . Since , y = 1 and x = 1.

Slope of at (1,1).

Slope of ellipse: .

Final Answer: Option (1)

15) px2 + 4μxy + qy2 + 4a(x + y + 1) = 0 represents pair of straight lines if


4apq + 16a2μ – 4a2p – 4a2q – 16 aμ2 = 0
⇒ 4μ2 – 4aμ + ap + aq – pq = 0
For real μ, 16a2 – 4.4(ap + aq – pq) ≥ 0
⇒ (a – p)(a – q) ≥ 0 ⇒ a ≤ p or a ≥ q

16)

17)
secx + tanx = t

secx – tanx =

2tanx = t –

2 sec2x dx =
18)

3sinx + 2 cosx = a(3 cosx + 2 sinx) + b(2cosx – 3sinx)


3a + 2b = 2

2a – 3b = 3 a=

19)

f(0) = 0, C = 0

20) Let
21)

⇒ t1t2 = –4

& k = t1 + t2
⇒ 2h = (t1 + t2)2 – 2t1t2
⇒ 2h = k2 + 8 ⇒ y2 = 2(x – 4)

22) ƒ(1) = 6
ƒ'(x) = 1 + 6x2 + 15x4
g(ƒ(x)) = x
⇒ g'(ƒ(x)).ƒ'(x) = 1

⇒ put x = 1

23)
Graph of ƒ(x)
Graph of |ƒ(|x|)|
m + n = 3 (Ans.)

24) We can write

put [Link] + 1 = t2
([Link] + 2esinx)dx = 2t dt
2esinx(x cosx + 1)dx = 2t dt

On comparing =1⇒A= Ans.

25)

PART-2 : PHYSICS

26)

27)

Here

Bnet =

Putting the value of J we get

28)

Correct Answer is (A)

29) Correct Answer is (A)


30)

Charge initially

Charge finally

for this charge arrangement to happen, 90μC charge has to flow upwards.

31) Robjective mirror = 220 mm = R1


RSecondary mirror = 140 mm = R2

Distance between two mirrors, d = 20 mm.


When object is at infinity, parallel rays falling on objective mirror on reflection would collect at
its focus at

Instead, they fall on secondary mirror at 20 mm from objective mirror u = f1 – d


⇒ u1 = 110 – 20 = 90mm

From

= 315 mm = 31.5 cm from M2

32) P0 tan θ along negative x-axis

33) Let charge on the sphere initially be Q.


and charge removed = αQ

(1)

and Vp =

VC =


(2) (EC)initial = zero
(EC)final =
⇒ Electric field increases

(3) (EP)initial =

(EP)final =

ΔEP =

(4) (VC)initial =

(VC)final =

ΔVC =

34)

Let v be the velocity of the particle. Its kinetic energy is

or v = .........(1)
The particle follows a circular path from A to B of radius r which is given by
or .........(2)
Using (1) and (2), we have

In triangle BCD, sin θ = . Therefore,

35)

Correct Answer is (A)

36)

= = 5 × 105 A/m.

37) ∴

Also,

Heat =

Heat =

38)

Correct Answer is (D)

39)
Correct Answer is (C)

40) wext + wB = uf – ui

ui =

uf =
wB = ΔQv

wext = =

41)

Correct Answer is (B)

42)
A→B

43) For toppling


44)

w=

0
Distance travelled = v t = …(i)

for θ = 0

45) i =

i=

46) Magnetic field on the axis of a circular loop

B= where R = radius of loop = 3 × 10–2 m

= 10–7 × = = (36π × 10–7 T)

47)

Correct Answer is (1)


48)

49) For rolling motion

tanθmax = 3µ

α+β=2+5=7

50) Amptitude of SHM, A = 5 cm, initial position of jockey is at A/2 and moving towards
extreme.

PART-3 : CHEMISTRY

51) State change from A to B, qAB = +5 J & WAB = –8J (work done by gas)
So ΔUAB = qAB + WAB = 5 – 8 = –3J
ΔUAB = –3J
Now gas is back brought to A from B
qBA = –3J (Heat evolved)
wBA = ?
ΔUBA = –ΔUAB
qBA + wBA = – ΔUAB
–3J + wBA = –(–3J)
wBA = 6J (work done by surrounding)

52) Concept:
Arrhenius Equation comparison, Temperature sensitivity of reactions with different activation
energies.
Solution:

ln(k1​ / k2​) = ln(A1​ / A2​) −

0
Since k1​ = k2​ at T ​, 0 = ln(A1​ / A2​) − ​ ​⟹l n(A1​ / A2​) = ​.

Substitute back: ln(k1​ / k2​) = .


Given ΔEa​ = Ea1​ − Ea2 ​> 0:
If T > T0​, (1 / T0​ − 1 / T) > 0 ⟹ ln(k1​ / k2​) > 0 ⟹ k1​ > k2​. (A) is correct.
If T < T0​, ln(k1​ / k2​) < 0 ⟹ k2​ > k1​. (B) is incorrect.
Ea​ is the measure of temperature sensitivity (slope of Arrhenius plot). Larger Ea​ means higher
sensitivity. (C) is correct.

Slope of ln(k1​ / k2​) vs 1 / T is ​. Since ΔEa​ > 0, slope is negative. (D) is incorrect.
Final Answer: Option (1 and 3)

53)

Theoretical

54) On increasing volume concentration decreases.

55) Plane P has the following arrangement of circular atoms:

Considering the smallest possible triangle in this arrangement

And Plane Q has the arrangement:


56)

Process AB → V increases T↑ ΔU > 0


Process BC v decreases T↓ ΔT < 0
Process CD P↓ T↓ ΔQ < 0
Process DA P↑ ΔQ > 0

57)

A crystal system with a = b = c and can have only primitive Bravais lattice.

58)

The correct answer is option (C)

59)

The correct answer is option (D)

60)

The correct answer is option (B)

61)

The correct answer is option (B)

62)

The correct answer is option (A)

63)

The correct answer is option (B)

64)
= (6.626 × 10–34) (3 × 1010) (3500)
≈ 6.96 × 10–19J

h = 6.626 × 10–34 Js
c = 3 × 1010 cm s–1
= 35000 cm–1

65)

We get propane, not n-butane

66)

Steric Factor: Propanal has only one bulky alkyl group attached to the carbonyl carbon,
whereas Propanone has two, making the latter more "crowded" (sterically hindered).

67)

68)

69) The correct answer is option (A)

70) (a) ✓, (b) ✕, (c) ✓, (d) ✕, (e) ✓, (f) ✓, (g) ✓, (h) ✓, (i) ✓, (j) ✓
(c) NBS → N-Bromo succinimide
→ Oxidises alcohol into Aldehyde or ketone
(g) Oppenaur oxidation
(h) Collin's Reagent → Moderate oxidising agent
→ [Py + CrO3 + CH2Cl2]

71) H2O(l) → H2O(g)


ΔH = ΔU + ΔngRT
10000 = ΔU + 1 × 2 × 350
⇒ ΔU = 9300 cal

72)

The correct answer is 3.00

73)

The correct answer is 3

74)
Molar mass of Y = 118 gm

75) Hydrolysis of Acetal and Ester, then decarboxylation of β-keto acid to give CH3CHO

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