Solution
Solution
1001CJA106216260097 JA
PART-1 : MATHEMATICS
SECTION-I
(A)
f is strictly increasing on and strictly decreasing on .
(B)
f is strictly decreasing on and strictly increasing on .
(C)
f is strictly increasing on and strictly decreasing on
(D)
f is strictly decreasing on and strictly increasing on
(A) 0
(B)
(C)
(D) 2
(A) Assertion is True, reason is True; reason is a correct explanation for assertion.
(B) Assertion is True, reason is True; reason is not a correct explanation for assertion.
(C) Assertion is True, reason is False
(D) Assertion is False, reason is True.
4) Let and f(0) = 2 then f(–1) is equal to
(A) 6
(B) 7
(C) 8
(D) 9
5) A person is standing at the edge of a slow moving river which is 1 km wide. He wishes to return to
the camp ground on the opposite side of the river for which he may swim to any point on the
opposite bank and then walk for the rest of the distance. The campground is 1 km away from the
point on the opposite bank directly across from where he starts to swim. If he swims at the rate of 2
km/hr and walks at the rate of 3 km/hr, the minimum time taken by him is approximately.
(A) 0.6 hr
(B) 0.7 hr
(C) 0.8 hr
(D) 0.9 hr
(A) y = 2x + 1
(B) y = x + 3
(C) 2x + y = 1
(D) y = x + 1
(A)
(B) 2
(C)
(D) 4
(A) 3
(B) 1
(C)
(D) 2
10) A value of c for which the Rolle's theorem holds for the function ƒ(x) = 2x3 + x2 – 4x – 2 on the
interval is
(A)
(B)
(C)
(D)
(A) 3
(B) 6
(C) 9
(D) 12
12) If m is slope of common tangent of curves y2 = 8x and x2 = 64y then possible value of m is :
(A)
(B) 2
(C) –2
(D)
–
13) If radius of a cylinder is decreasing at the rate of 3m/sec and it's altitude is increasing at rate of
5m/sec, then the rate of change of volume when radius is 3m and altitude is 2m is-
(A) 3π m3/sec
(B) 78π m3/sec
(C) 9π m3/sec
(D) 21π m3/sec
(A)
(B)
(C)
15) Statement-1 : If p < q and px2 + 4μxy + qy2 + 4a(x + y + 1) = 0 represents pair of straight lines
for some μ ∈ R and a ≠ 0, then a ≤ p or a ≥ q
Statement-2 : The given equation has non-zero linear terms
(A) Both the statements are true and Statement 2 is correct explanation of Statement 1.
(B) Both the statements are true and Statement 2 is not the correct explanation of Statement 1.
(C) Statement 1 is true and Statement 2 is false.
(D) Statement 1 is false and Statement 2 is true.
(A)
+c
(B)
+c
(C)
+c
(D) None of these
17)
(B)
(C)
(D)
18) If , then
(where C is constant of integration)
(A)
(B)
(C)
(D)
(A) loge (1 + )
loge (1 + )–
(B)
(C) log (1 + )+
e
(A)
(B)
(C)
(D)
SECTION-II
1) Through the vertex O of parabola y2 = 4x, chords OP and OQ are drawn at right angles to one
another, where P and Q are point on the parabola. If the locus of middle point of PQ is y2 = 2(x – ℓ),
then value of ℓ is
3) Consider ƒ(x) = max(|x|, 2x – x2), x ∈ R. Let there are m points of discontinuity and n points of non
derivability of function y = |ƒ(|x|)|, then m + n is equal to
5)
PART-2 : PHYSICS
SECTION-I
1) If a particle is performing oscillations in x-direction about origin, having potential energy U = [Link].
Then find how time period depend on Amplitude
(A)
(B)
(C)
(D) None of these
2) A solid cylindrical wire of radius R has a current I flowing along its length. It has a long cylindrical
cavity of radius R/2 as shown. Find the magnetic field at point P (in figure).
(A)
(B)
(C)
(D)
3) A non-conducting piston of mass m and area S divides a non-conducting, closed cylinder into two
parts as shown in figure. Piston is connected with left wall of cylinder by a spring of force constant
K. Left part is evacuated and right part contains an ideal gas at pressure P. Adiabatic constant of the
gas is γ and in equilibrium length of each part is . Calculate angular frequency of small oscillations
of the piston.
(A)
(B)
(C)
(D)
4) A small particle is placed at the pole of a concave mirror and then moved along the principal axis
to a large distance. During the motion, the distance between the pole of the mirror and the image is
measured. The procedure is then repeated with a convex mirror, a concave lens and a convex lens.
The graph is plotted between image distance versus object distance. Match the curves shown in the
graph with the mirror or lens that is corresponding to it. (Curve 1 has two segments)
(A) P→1, Q→1, R→2, S→2
(B) P→1, Q→2, R→3, S→4
(C) P→1, Q→2, R→2, S→3
(D) P→3, Q→2, R→1, S→4
5) The circuit shown above shows a steady state with S open. When S is closed :-
6) An instrument uses two mirror as shown in figure. Such instrument is built with two mirrors 20
mm apart. If the radius of curvature of the large mirror is 220 mm and the small mirror is 140 mm,
where the final image of an object at infinity will be formed from M3 ?
(A) 21 cm
(B) 31.5 cm
(C) 27.5 cm
(D) 19 cm
7) Variation of x-component of electric field with x-coordinate in a region is given in the graph. A
small electric dipole having dipole moment is placed at origin, then net force on the dipole is :
(A) P0 tan θ along positive x-axis
(B) Zero
(C) P0 tan θ along negative x-axis
(D) P0 tan θ along positive y-axis
8) A thin spherical insulating shell of radius R carries a uniformly distributed charge such that the
potential at its surface is V0. A hole with a small area α4πR2 (α<<1) is made on the shell without
affecting the rest of the shell. Which one of the following statements is correct ?
The ratio of the potential at the center of the shell to that of the point at R from center
(A)
towards the hole will be
The magnitude of electric field at the center of the shell is reduced by
(B)
The magnitude of electric field at a point, located on a line passing through the hole and shell's
(C)
center at a distance 2R from the center of the spherical shell will be reduced by
(D) The potential at the center of the shell is reduced by 2αV0
(A)
(B)
(C)
(D)
10) Two hemispherical shell of radius R1 and R2 and having charges Q and 2Q distributed uniformly
respectively are arranged as shown. The force of interaction between two shells is (R2 << R1) :-
(A)
(B)
(C)
(D)
11) Nickel is ferromagnetic at room temperature. At a value of H field of 5 × 105 A/m, nickel
saturates. The magnetic field B is 1.25 T. What is the magnetisation vector of nickel sample?
12) A conducting balloon of radius a is charged to a potential V0 and held at a large height above the
earth surface. The large height of the balloon from the earth ensures that charge distribution on the
surface of the balloon remains unaffected by the presence of the earth. It is earthed through a
resistance R and a valve is opened. The gas inside the balloon escapes through the valve and the size
of the balloon decreases. The rate of decreases in radius of the balloon is controlled in such a
manner that the potential of the balloon remains constant. Assume electric permittivity of the
surrounding air equal to that of free space and charge does not leak to the surrounding air. How
much heat is dissipated in the resistance R until radius of the balloon becomes half?
(A)
(B)
(C)
(D)
14) Two circuits (shown below) are called 'circuit A' and circuit B, The equivalent resistance
of circuit A is x and that of circuit B is y between 1 and 2.
(A) y < x
(B)
(C) xy = 2R2
(D) x – y = 2R
15) Between the plates of a parallel-plate capacitor, there is a symmetrically placed metallic plate
whose thickness takes up 60% of the capacitor gap. When that plate is absent the capacitor has a
capacity C = 20nF. The capacitor is connected to a dc voltage source of voltage =100 V. The metallic
plate is slowly extracted from gap. Find the mechanical work (in μJ) performed in the process of
plate extraction.
(A) 150
(B) 100
(C) 250
(D) 200
16) Figure shows a vertical parallel plate capacitor of plate dimension (l × b) with separation d
connected to the battery via switch (s). if switch is closed then the height between the plate to which
liquid level will rise is :- (Dielectric constant of water is k)
(A)
(B)
(C)
(D)
17) Consider a long thin conducting wire carrying a uniform current I. A particle having mass “M”
and charge “q” is released at a distance “a" from the wire with a speed vo along the direction of
current in the wire. The particle gets attracted to the wire due to magnetic force. The particle turns
around when it is at distance x from the wire. The value of x is [μ0 is vacuum permeability]
(A)
(B)
(C)
(D)
18) An uniform hemi-solid sphere is placed with flat surface on rough inclined plane as shown in
figure. If friction is large for no sliding, then the minimum angle θ at which toppling occur, is
(A)
(B) 45°
(C)
(D)
19) A bead is connected with a fixed disc of radius R by an inextensible massless string in a smooth
horizontal plane. If the bead is pushed with a velocity v0 perpendicular to the string, the bead moves
(A)
Initial angular acceleration of the particle is .
Initial angular acceleration of the particle is
(B)
(C)
Distance travelled by the particle till it collides with the disc is
(D)
Distance travelled by the particle till it collides with the disc is
20) A Uniform magnetic field exists perpendicular to the plane of a copper wire ring with a diameter
D = 2 m and diameter of cross-section d = 2 mm. Take resistivity as 10–8 Ωm. At what rate should
magnetic field change over time to have the induced current in the ring of 10 A ?
(A)
(B)
(C)
SECTION-II
1) Current i = 2.5 A flows along the circular coil whose equation is given by x2 + y2 = 9 cm2 (here x
& y are in cm). If magnetic field is given by πx × 10–7 T at point (0, 0, 4 cm). State value of x.
2) A charge particle of charge q and mass m is projected in a region which contains electric and
magnetic field as shown in the figure with velocity v at an angle 45° with x direction. If ,
then net deviation in particle motion will be θ (in degree) then find the value of θ/15. (neglect the
effect of gravity)
3) A stick of length L and mass M lies on a frictionless horizontal surface on which it is free to move
in any way. A ball of mass m moving with speed v collides elastically with the stick as shown in the
figure. If after the collision the ball comes to rest, then what should be the value of ?
4) A cylinder is released from rest on a rough inclined plane. Maximum value of angle θ for which
PART-3 : CHEMISTRY
SECTION-I
1) A gas undergoes change from state A to state B. In this process , the heat absorbed and work
done by the gas is 5 J and 8 J, respectively. Now gas is brought back to A by another process during
which 3 J of heat is evolved. In this reverse process of B to A:-
solvents, S1 and S2. The rate constants k1 and k2 were found to follow: ln k = ln A − . If Ea1 > Ea2
and at T0, k1 = k2, then:
3) 3.00 mole of PCl5 kept in 1L closed reaction vessel was allowed to attain equilibrium at 380 K.
Calculate composition of the mixture at equilibrium.
PCl5(g) PCl3(g) + Cl2(g)
The incorrect option is :
4) A small amount of solid lead iodide was added to a beaker of water, which was stirred. Most of the
solid settled at the bottom of the beaker, but a little dissolved, establishing the equilibrium
The rates of the forward and reverse reactions were monitored over time, producing the graph
5) Consider the following unit cell of a metal: Also consider the following
(A) 1.00
(B) 1.63
(C) 0.55
(D) 0.74
6) For 1 mole of oxygen gas (assuming ideal behaviour), P-V curve is given
7) Which of the following correctly matches a crystal system with its axial lengths, interfacial angles,
and possible Bravais lattice types?
(A) A crystal system with and can have both primitive and face-
centred Bravais lattices.
(B) A crystal system with a = b = c and can have only primitive Bravais lattice.
(C) A crystal system with and can have only primitive, face-centred and
end-centred Bravais lattices.
(D) A crystal system with and can have only primitive, body-
centred and end-centred Bravais lattices.
8) Matching list
List-I List-II
(Q) Sn (2) Contain impurity of its metal oxide and removed by Polling
(S) Ti (4) At least one of the refining technique like liquation / Van arkel method can be used.
(A) P→2,3,4 ; Q→3,4 ; R→2,4 ; S→2,4
(B) P→3,4 ; Q→1,3 ; R→2 ; S→4
(C) P→1,3,4 ; Q→2,4 ; R→2 ; S→4
(D) P→1,2,3 ; Q→2,4 ; R→2,4 ; S→2,4
9) Select the incorrect statement.
10) A rhodium complex 'X' used for hydrogenation of alkenes, select the correct statement regarding
the complex 'X'?
(A) Coordination No = 6
(B) Shows Synergic Bonding
(C) Hybridisation is sp3d2
(D) Oxidation state of Rh is +2
11) Which of the following is INCORRECTLY matched against the indicated property ?
3– 4–
(A) [Mn(CO)4] , [Cr(CO)4] ; Isoelectronic species
2– 4–
(B) [NiF6] , [NiF6] ; for both (Δo > P)
(C) [Pt(NH3)2Cl2Br2] ; Number of stereoisomer = 6
+2
(D) Na2[Fe(CN)5NO] < [Fe(H2O)5NO] ; Number of electrons in eg orbital
12) In the extraction of copper, the reaction which does not take place in Bessemer converter is :
13) Select the correct statement regarding the metallurgical process of ores ?
(A) Calamine, after roasting produces oxide ore for which carbon reduction is used.
(B) In Mac Arthur-Forrest process for argentite, O2 is passed to oxidise the Na2S formed.
(C) In calcination, impurities are removed in the form of volatile oxides.
(D) In Down's process aqueous salt electrolysis is not used as O2(g) is produced at cathode.
–20
(A) Δoct = 6.96 × 10 J ; complex appears red
–19
(B) Δoct = 6.96 × 10 J ; complex absorbs violet light and appears pale yellow
–19
(C) Δoct = 3.50 × 10 J ; complex appears green
–18
(D) Δoct = 1.05 × 10 J ; complex absorbs red light
15) Statement-I : Sodium salt of butanoic acid on heating with soda lime gives n-butane.
Statement-II : Sodalime decarboxylation reaction has carbanionic intermediate.
16) Which of the following statements is TRUE regarding the catalytic hydrogenation of Propanal
(CH3CH2CHO) and Propanone (CH3COCH3)?
(A) Propanone reduces faster because the carbonyl carbon is more electrophilic.
(B) Propanal reduces faster because it is less sterically hindered.
(C) Both reduce at the same rate as they are isomers.
(D) Catalytic hydrogenation cannot distinguish between them.
(A)
(B)
(C)
(D)
18) An organic compound “P” of molecular formula C6H12O3 gives positive lodoform test but negative
Tollen’s test. When “P” is treated with dilute acid, it produces “Q”. “Q” gives positive Tollen’s test
and also iodoform test. The structure of “P” is :
(A)
(B)
(C)
(D)
(h) Collin's reagent (i) (i) TsCl, (ii) DMSO, NaHCO3 , Δ (j)
(A) 6
(B) 7
(C) 8
(D) 9
SECTION-II
1) The enthalpy of vapour is 10 kcal/mole higher than liquid at 350 K and 2 atm. Under given
conditions, the difference in internal energy (in cal) of vapour and liquid will be.
2) For the first order reaction : A(g) → 2 B(g) +C(g), the half-life for decomposition of A is 3 minutes
at 300K. Calculate the time (in minutes) in which the initial pressure of A at 2 atm (at 400K) changes
to a final total pressure of 5 atm at 400K. (Given activation energy of reaction is 840R and ln2 = 0.7)
3) A sulphide ore of a metal 'M' is partially roasted such that 1/3 rd of MS is converted to MO, while
the remaining stays as MS. The mixture is then heated strongly in absence of air to yield metal 'M'
via self reduction.
Total moles of SO2 formed per mole of initial MS taken is 'x'. Find the value of '6x'
4)
Compound (X) is subjected to the sequence of reactions as shown above. Molar mass of the major
product (Y) formed is ______ gmol–1.
(Given molar mass in g mol–1 C : 12, H : 1 , O : 16)
5) (P) + EtOH
P is the major organic product. Calculate the total number of oxygen atoms in P.
ANSWER KEYS
PART-1 : MATHEMATICS
SECTION-I
Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D A C A B D B A B C C D C A B A C C B C
SECTION-II
Q. 21 22 23 24 25
A. 4 22 3 38 1
PART-2 : PHYSICS
SECTION-I
Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B B A A C B C A A A A C D C A B D C B C
SECTION-II
Q. 46 47 48 49 50
A. 36 1 4 7 10
PART-3 : CHEMISTRY
SECTION-I
Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B A C D B B B C D B B A B B C B D B A C
SECTION-II
Q. 71 72 73 74 75
A. 9300 3 3 118 1
SOLUTIONS
PART-1 : MATHEMATICS
1) x ≥ y
is max. when y = 0
x<y
is max. when y = 1
2)
let x + 1 + = t2
C=0
3)
4)
let 4x4 – 2x3 – 3x2 – 4 = A(x4 + x3 + 1) + (Bx + C) (4x3 + 3x2)
⇒ A = –4, B = 2, C = –1
(applying by parts)
5) T = D/S ⇒
6) = ƒ(x)
x=0 ƒ(0) = 1 ƒ'(0) = 1
7) y2 = 2ax
2yy′ = 2a xy′ + y = 0
For orthogonal ⇒ = –1 ⇒ a = x
∵ y2 = 2ax ⇒ y2 = 2a2
∵ ⇒
a=2
8) ƒ′(x)
ƒ′(x)
ƒ(x) is increasing in
9)
10) As, ƒ(x) is a polynomial function, is continuous and differentiable for all real x.
Also ƒ(x) = (x2 – 2)(2x + 1)
and ƒ =0=ƒ
11)
Question Explanation:
Concept:
Solution:
is normal to y2 = 16x
⇒ here ,
Equation of normal y = mx – 2am – am3
Compare
c= = – 16m2 ⇒ m =
13)
v = pr2h
= 9π m3/sec
14) Question Explanation: Calculate the angle between a parabola and an ellipse at their
intersection.
Solution:
Slope of at (1,1).
Slope of ellipse: .
16)
17)
secx + tanx = t
secx – tanx =
2tanx = t –
2 sec2x dx =
18)
2a – 3b = 3 a=
19)
f(0) = 0, C = 0
20) Let
21)
⇒ t1t2 = –4
& k = t1 + t2
⇒ 2h = (t1 + t2)2 – 2t1t2
⇒ 2h = k2 + 8 ⇒ y2 = 2(x – 4)
∵
22) ƒ(1) = 6
ƒ'(x) = 1 + 6x2 + 15x4
g(ƒ(x)) = x
⇒ g'(ƒ(x)).ƒ'(x) = 1
⇒ put x = 1
23)
Graph of ƒ(x)
Graph of |ƒ(|x|)|
m + n = 3 (Ans.)
put [Link] + 1 = t2
([Link] + 2esinx)dx = 2t dt
2esinx(x cosx + 1)dx = 2t dt
25)
PART-2 : PHYSICS
26)
27)
Here
Bnet =
28)
Charge initially
Charge finally
for this charge arrangement to happen, 90μC charge has to flow upwards.
From
∴
and charge removed = αQ
(1)
and Vp =
VC =
∴
(2) (EC)initial = zero
(EC)final =
⇒ Electric field increases
(3) (EP)initial =
(EP)final =
ΔEP =
(4) (VC)initial =
(VC)final =
ΔVC =
34)
or v = .........(1)
The particle follows a circular path from A to B of radius r which is given by
or .........(2)
Using (1) and (2), we have
35)
36)
= = 5 × 105 A/m.
37) ∴
Also,
Heat =
Heat =
38)
39)
Correct Answer is (C)
40) wext + wB = uf – ui
ui =
uf =
wB = ΔQv
wext = =
41)
42)
A→B
w=
0
Distance travelled = v t = …(i)
for θ = 0
45) i =
i=
47)
tanθmax = 3µ
α+β=2+5=7
50) Amptitude of SHM, A = 5 cm, initial position of jockey is at A/2 and moving towards
extreme.
PART-3 : CHEMISTRY
51) State change from A to B, qAB = +5 J & WAB = –8J (work done by gas)
So ΔUAB = qAB + WAB = 5 – 8 = –3J
ΔUAB = –3J
Now gas is back brought to A from B
qBA = –3J (Heat evolved)
wBA = ?
ΔUBA = –ΔUAB
qBA + wBA = – ΔUAB
–3J + wBA = –(–3J)
wBA = 6J (work done by surrounding)
52) Concept:
Arrhenius Equation comparison, Temperature sensitivity of reactions with different activation
energies.
Solution:
0
Since k1 = k2 at T , 0 = ln(A1 / A2) − ⟹l n(A1 / A2) = .
Slope of ln(k1 / k2) vs 1 / T is . Since ΔEa > 0, slope is negative. (D) is incorrect.
Final Answer: Option (1 and 3)
53)
Theoretical
57)
A crystal system with a = b = c and can have only primitive Bravais lattice.
58)
59)
60)
61)
62)
63)
64)
= (6.626 × 10–34) (3 × 1010) (3500)
≈ 6.96 × 10–19J
h = 6.626 × 10–34 Js
c = 3 × 1010 cm s–1
= 35000 cm–1
65)
66)
Steric Factor: Propanal has only one bulky alkyl group attached to the carbonyl carbon,
whereas Propanone has two, making the latter more "crowded" (sterically hindered).
67)
68)
70) (a) ✓, (b) ✕, (c) ✓, (d) ✕, (e) ✓, (f) ✓, (g) ✓, (h) ✓, (i) ✓, (j) ✓
(c) NBS → N-Bromo succinimide
→ Oxidises alcohol into Aldehyde or ketone
(g) Oppenaur oxidation
(h) Collin's Reagent → Moderate oxidising agent
→ [Py + CrO3 + CH2Cl2]
72)
73)
74)
Molar mass of Y = 118 gm
75) Hydrolysis of Acetal and Ester, then decarboxylation of β-keto acid to give CH3CHO