28-07-2024

1803CJA101003240006 JM

PART-1 : PHYSICS

SECTION-I

1) A particle moves in the x-y plane. It’s x and y coordinates vary with time t according to equations
as x = t2 + 2t and y = 2t. Possible shape of path followed by the particle is

(A) Straight line

(B) Circle
(C) Parabola
(D) More information is required to decide

2) In A standard projectile motion (ground to ground) which of the following is true.

(A) Kinetic energy first increase then decrease

(B) Kinetic energy first decrease then increase
(C) Kinetic energy remains constant
(D) It can not be predict as initial velocity is not given.

3) A ball is projected with a speed 20 m/s at an angle of 30° upwards from the horizontal plane. The
time elapsed when the speed of ball becomes minimum will be

(A) 1 sec
(B) 2 sec
(C) 3 sec
(D) 4 sec

4) Path of projectile of two particles is shown in the figure. If T1 and T2 are time of flight of particle
(1) and (2) respectively, then :-

(A) T1 > T2
(B) T1 < T2
(C) T1 = T2
(D) Can't say

5) A ball is projected at an angle of 60° to the horizontal. If ball has a velocity of 50 m/s at the
highest point then ball was projected with velocity.
(A) 50 m/s
(B) 75 m/s
(C) 100 m/s
(D) 200 m/s

6) If two bodies are projected at 30° and 60° respectively, with the same velocity, then

(A) Their ranges are same

(B) Their heights are same
(C) Their times of flight are same
(D) All of these

7) The equation of a projectile is the angle of projection is :–

(A) 30°
(B) 60°
(C) 45°
(D) none

8) At the uppermost point of a projectile its velocity and acceleration are at an angle of :–

(A) 180°
(B) 90°
(C) 60°
(D) 45°

9) A large number of bullets are fired in all directions with the same speed v. The maximum area on
the ground on which these bullets will spread is :

(A)

(B)

(C)

(D)

10)

A projectile is fired with a velocity u making an angle θ with the horizontal. What is the change in
speed from initial to highest point ?

(A) ucos θ
(B) u
(C) u sinθ
(D) u cosθ -u

11) A projectile is projected with speed of 50m/s at an angle of 37° with the horizontal. Find its
speed at highest point of its trajectory?

(A) 50m/s
(B) 30m/s
(C) 40m/s
(D) zero

12) A ball is projected with speed of 40m/s at an angle of 60° with the vertical. The maximum height
acheived by the particle is: [Take g = 10m/s2]

(A) 80m
(B) 60m
(C) 40m
(D) 20m

13) Equation of trajectory of a projectile with projection speed u and projection angle θ is -

(A)

(B)

(C)

(D)

14) A cricket ball is hit at 60° with the horizontal with kinetic energy K . The kinetic energy at the
highest point is

(A) Zero

(B)

(C)

(D)

15) A ball is projected from the ground with a speed 15 ms–1 at an angle θ with horizontal so that its
range and maximum height are equal, then 'tan θ' will be equal to

(A)
(B)

(C) 2
(D) 4

16) If Range of a projectile is 4 times the maximum height attained then angle of projection is :-

(A) 30°
(B) 60°
(C) 45°
(D) 15°

17) If speed of projectile at highest point is half of initial speed. What is the angle of projection with
horizontal?

(A) 30º
(B) 45º
(C) 60º
(D) 75º

18) A particle is projected horizontally from a tower of height 125 m. Find the horizontal distance ‘R’
from foot of tower where particle hit the ground. Speed of projection is 20 m/s.

(A) 100 m
(B) 120 m
(C) 140 m
(D) None of these

19) A particle (A) is dropped from a height and another particle (B) is thrown in horizontal direction
with speed of 5 m/sec from the same height. The correct statement is

(A) Both particles will reach at ground simultaneously

(B) Both particles will reach at ground with same speed
(C) Particle (A) will reach at ground first with respect to particle (B)
(D) Particle (B) will reach at ground first with respect to particle (A)

20) An aeroplane flying 490 m above ground level at 100 m/s, releases a block. How far on ground
will it strike:

(A) 0.1 km
(B) 1 km
(C) 2 km
(D) None

SECTION-II

1) A body is projected with speed v m/s at angle θ. The kinetic energy at the highest point is half of
the initial kinetic energy. The value of θ (in degree ) is :

2) The horizontal range is four times the maximum height attained by a projectile. The angle (in
degree) of projection is :

3) A ball is projected at an angle 53° from horizontal with speed 50 m/s. Find time of flight.

4) The time of flight of a projectile is 10s and range is 500m. Maximum height attained by it is x
meter. Find x. [g = 10 m/s2]

5) The speed of a projectile at its maximum height is half of its initial speed. The value of angle of
projection will be (In degree).

6) A ball is thrown from the top of 36 m high tower with velocity 5 m/s at an angle 37° above the
horizontal as shown. Its horizontal range (in meters) on the ground is closest to [ g = 10 m/s2]

7) A bomb is dropped on an enemy post by an aeroplane flying horizontally with a velocity of 60

kmh–1 and at a height of 490 m. At time time of dropping the bomb, If meter far away horizontally
the bomb hit the enemy post. Find n.

8) A ball is projected from the ground at an angle of 45° with the horizontal surface. It reaches
a maximum height H and returns to the ground at a range R from start. Find the ratio R/H

9) Two particle are moving with velocity and m/s respectively. Time at
which they are moving perpendicular to each other is _______ (sec.)

10) A particle is projected in xy plane with y-axis along vertical, the point of projection is origin. The
equation of the path is , where y and x are in m. Then the speed of projection in ms–1 is
:

PART-2 : CHEMISTRY

SECTION-I

1) The hybridisation of P atom in phosphate ion (PO43–) is same as in :-

–
(A) I in ICl4
2–
(B) S in SO4
(C) Xe in XeF4
3–
(D) B in BO3

2) Which of the following statements is INCORRECT regarding N2O5?

2
(A) The hybridisation of N in N2O5 is sp .
(B) The total number of lone pair electrons present on N is 2
(C) It has total 12 lone pair of electrons present
(D) It has dative bond(s)

3) In which of the following molecule, number of pπ-dπ bonds formed are two times the number of pπ-
pπ bonds?

(A)
(B)
(C) SO3
(D) XeO4

4)

The formation of molecular complex BF3–NH3 results in a change in hybridisation of boron:

(A) from sp3 to sp3d

(B) from sp2 to dsp2
(C) from sp3 to sp2
(D) from sp2 to sp3

5) In the following compound ,

, the C3 – C4 bond is of the type :

(A) sp – sp2
(B) sp3 – sp3
(C) sp3 – sp
(D) sp2 – sp3

6) In protonation of NH3 change occurs in :

(A) Hybridisation of N-atom and electronic geometry

(B) Shape of molecule and H-N-H bond angle
(C) Neither in hybridisation nor in shape of molecule
(D) Number of hybrid orbitals of N and total valence electrons

7) Which single bond dissociation energy order is incorrect ?

(A) C—C > Si—Si

(B) N—N < P—P
(C) F—F < Cl—Cl
(D) O—O > S—S

8) Hybridisation theory is unable to explain bond angle in :

(A) H2O
(B) CO2
(C) PH3
(D) NH3

9)

In which of the following bond having highest bond energy.

(A) N–N
(B) O–O
(C) F–F
(D) all having same bond energy

10)
Which marked carbon having highest electronegativity?

(A) 1
(B) 2
(C) 3
(D) all having same electronegativity

11)

The hybridisation of orbitals of N atom in are respectively.

(A) sp, sp3, sp2

(B) sp2, sp3, sp
(C) sp, sp2, sp3
(D) sp2, sp, sp3

12)

Correct order of strength of σ-bond.

(A) 1s–2p > 1s–2s

(B) 2p–2p > 1s–2s
(C) 2p–2s > 2p–2p
(D) 2p–2p > 1s–1s

13) Order of bond strength in following overlappings.

(I) 2s – 2p (σ type) (II) 2p – 2p (σ type) (III) 2pπ – 3dπ (IV) 3pπ – 3dπ

(A) (I) > (II) > (III) > (IV)

(B) (IV) > (III) > (II) > (I)
(C) (II) > (I) > (III) > (IV)
(D) (II) > (I) > (IV) > (III)

14)

The strength of sigma bonds formed by 2s-2s, 2p-2p and 2p-2s overlap has the order ?

(A) 2s-2s > 2p-2p > 2p-2s

(B) 2p-2p > 2p-2s > 2s-2s
(C) 2p-2s > 2p-2p > 2s-2s
(D) 2p-2s > 2s-2s > 2p-2p

15) In covalency :

(A) transfer of electrons takes place

(B) one atom acts as donor and other acts as acceptor
(C) the electrons are shared by only one atom
(D) equal sharing of electrons takes place between two atoms

16) In which of the following species, each C is sp hybridised ?

(A)

(B)

(C) H – C ≡ C – H
(D)

17) Identify the hyper valent compound.

(A) BCl3
(B) NOF3
(C) XeF6
(D)

18) XeO3 has

(A) one pπ-pπ & two pπ-dπ bonds

(B) three pπ-pπ bonds
(C) four pπ-dπ bonds
(D) three pπ-dπ bonds

19) Which of the following molecule all bonds are not equal.

(A) CCl4
(B) SiCl4
(C) SF4
(D)

20) If x is internuclear axis, then type of bond formed between dxz and pz orbital is :

(A) π-bond
(B) σ-bond
(C) δ-bond
(D) no bond formed

SECTION-II

1) If x is the total number of molecule is which pπ-pπ bond present and y is the total number of

molecule in which dπ-pπ bond present then find the value of from the following molecules.
HNO3 , H2SO4 , HClO4 , H2CO3 , HNO2

2) Total number of identical bond angles and number of hybrid orbitals formed by carbon in CF4 are
x and y respectively. Sum of x + y is

3) In which of the following molecules, pπ– dπ bond is not possible ?

4)

Find the total number of pπ–dπ bonds present in SO3.

5)

The total number of pπ-dπ bonds present in SO3 and H2SO4 are :

6)

Consider y-axis as inter-nuclear axis, how many of following will lead to π bond formation?
(a) py – py (b) px – px
(c) pz – pz (d) dxy – dxy
(e) dyz – dyz (f) px – dxy
(g) dxy – pz (h) dxz – dxz

7) The no. of resonating structure in are :

8)

The number of lonepair in NF3.

9) Number of such planes in CH4, which have 3 atoms in a plane is ?

10)

Total number of lone pair in XeOF4 ?

PART-3 : MATHEMATICS

SECTION-I

1) If roots of the quadratic equation x2 + 6x + b = 0 are real and distinct and they differ by at most 4
then number of possible integral values of b is

(A) 10
(B) 3
(C) 4
(D) 5

2) The least integral value of k for which (k – 2)|x|2 + 8x + k + 4 > 0 " x ∈ R, is

(A) 2
(B) 3
(C) 4
(D) 5

3) If x satisfies |x – 1| + |x – 2| + |x – 3| > 6, then

(A) 0 ≤ x ≤ 4
(B) x ≤ – 2
(C) x ≤ 0 or x ≥ 4
(D) none of these

4) Number of integers in the range of is :–

(A) 1
(B) 2
(C) 3
(D) 4

5)

If α, β are the roots of the equation ax2 + bx + c = 0 then the roots of the equation
(a + b + c)x2 – (b + 2c)x + c = 0 are

(A)

(B)

(C)

(D)

6)

If exactly one root of the equation 2kx2 – 4kx + 2k – 1 = 0 lies in [0,1), then complete range of k is-

(A) (–∞,0]
(B) (–∞,0)
(C) (0,∞)
(D) [0,∞)

7)

Let α and β be the roots of equation x2 – 6x – 2 = 0. If an = αn – βn, for n ≥ 1, then the value of
 is equal to :

(A) 3
(B) – 3
(C) 6
(D) – 6

8) , then complete set of values of x is

(A) [–1, ∞)
(B) [0, ∞)
(C) (–∞, 0) ∪ (1, ∞)
(D) (–∞, 0) ∪ [1, ∞)

9) If α, β are roots of the equation x2 + ax + 2 = 0 such that α6β5 = 32, then the value of 'a' is -

(A) –2
(B) 2
(C) –3
(D) 3

10) Which of the following graph represents the expression f(x) = a x2 + b x + c (a ≠ 0) when a > 0,
b<0&c=0?

(A)

(B)

(C)
(D)

11) If the roots of 4x2 + 5k = (5k+1)x differ by unity, then find the values of k.

(A)

(B)

(C)

(D)

12) If roots of quadratic equation ax2 + bx + c = 0 are non real and 4a + c < 2b, then which of the
following is the graph of ƒ(x) = ax2 + bx + c

(A)

(B)

(C)

(D)

13) If one root of the following equations ax2 + bx + 2 = 0 and 5x2 + x + 3 = 0 is common then the
value of 'a + b' is

(A)

(B)

(C) 3
(D) 4

14) Solution set of the inequality x + 4 > 2 is :

(A)
∪ (0, 2]

(B)

(C) (1, 2]

(D)
∪ (1, 2]

15)

If exactly one root of equation x2 + (k +1)x + 5k = 0 lies in (0,5], then minimum integral value of k is
-

(A) –4
(B) –3
(C) 0
(D) 1

16) If graph of the quadratic y = ax2 + bx + c is given below : then

(A) a < 0, b > 0, c > 0

(B) a < 0, b > 0, c < 0
(C) a < 0, b < 0, c > 0
(D) a < 0, b < 0, c < 0

17) If the equation (p2 – 3p + 2)x2 + (p – 1)2x + (p2 – 4p + 3) = 0 is satisfied for more than two
different values of x, then p is equal to -

(A) 1
(B) 2
(C) 1,2,3
(D) 2,3

18) If α, β are the roots of equation x2 + 2x + 5 = 0, then the equation whose roots are and

is -

(A) 5x2 – 9x + 4 = 0
(B) 5x2 – 8x + 4 = 0
(C) 5x2 – 10x + 4 = 0
(D) 5x2 + 9x + 4 = 0
19) Number of integral values of x satisfying is :-

(A) 0
(B) 1
(C) 3
(D) 5

20) For all x, x2 + λx + > 0 then the interval in which λ lies

(A) λ < –10

(B) –10 < λ < 4
(C) λ > 10
(D) 4 < λ < 10

SECTION-II

1) If α,β and γ are the roots of the equation x3 + 4x + 1 = 0, then (α + β)–1 + (β + γ)–1 + (γ + α)–1 is
equal to

2) If the product of the roots of the quadratic equation mx2 – 2x + (2m – 1) = 0 is 3, then the value of
|m| is

3) For a natural number n, let an = 3n – 2n. Then the value of is ______

4) Let a polynomial P(x) when divided by (x – 1), (x – 2), (x – 3) leaves remainder 4, 5, 6 respectively.
If P(x) is divided by (x – 1) (x – 2) (x – 3) and remainder is R(x), then find value of R(100).

5) Number of integral values of k for which exactly one root of the equation 5x2 + (k + 1) x + k = 0
lies in the interval (1, 3), is –

6) If x is real, then maximum value of y = is :

7) The number of real solutions of the equation x2 – 3| x | + 2 = 0, is-

8) Let x1 and x2 be the real roots of the equation x2 – kx + (k2 + 7k + 15) = 0. What is the maximum
value of (x12 + x22) ?
9) If α, β are roots of ax2 + bx + c = 0, ac ≠ 0 and are roots of x2 – 3x + 1 = 0, then is

10) If α, β be the roots of 4x2 – 16x + m = 0, m ∈ R such that α ∈ (1, 2) and β ∈ (2, 3), then number
of integral values of m is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C B A C C A B B B D C D A B D C C A A B

SECTION-II

Q. 21 22 23 24 25 26 27 28 29 30
A. 45 45 8 125 60 12 500 4 2 2

PART-2 : CHEMISTRY

SECTION-I

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. B B C D C B D C A B D A C B D C C D C A

SECTION-II

Q. 51 52 53 54 55 56 57 58 59 60
A. 15 10 2 2 4 5 4 10 10 15

PART-3 : MATHEMATICS

SECTION-I

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. C C C A D D A D C B A D D A B C A B A B

SECTION-II

Q. 81 82 83 84 85 86 87 88 89 90
A. 4 1 5 103 8 17 4 18 5 3
 SOLUTIONS

PART-1 : PHYSICS

1)

ax = 2, ay = 0, vx = 2t + 2, vy = 2
and are non-parallel and = constant

2)

Speed first decreases then increases.

3)

For minimum speed of particle the y component of velocity becomes zero

⇒ vy = 0
∴ 10 – 10t = 0 ⇒ t = 1 sec

4)

H1 = H2

u1sinθ1 = u2sinθ2
Hence T1 = T2

5)

vtop is only horizontal ⇒ vcos 60° = 50 (given)

∴ velocity of projection (v)

8)
 15)

R=H

vx = ; u cos θ =
tan θ = 4

18)

R = 20 × 5 = 100 m.

19)

As initial vertical velocity of both particles is zero.

Time to reach ground is also same

20)

⇒ t = 10s
SX = 100 × t = 100 × 10
= 1000m = 1Km

21)

⇒ | vx | = | vy | ⇒ 45°

22)

R = 4H
tanθ = 1

24)

H=

26)

–36 = 3t – 5t2 ⇒ t = 3s
Range = 4 × 3 = 12 m

27)

29) When they perpendicular

t – t2 + 20 = 0
t2 – t – 2 = 0
t = 2 sec

30)

On comparing with y = x tan θ –

tan θ = ⇒ θ = 60
2 2
2U cos θ = 2 ⇒ U = 2 m/s

PART-2 : CHEMISTRY

37)

Fact

55) SO3 → 2 pπ-dπ

H2SO4 → 2pπ-dπ total = 4

57)
 59)

By observation.

PART-3 : MATHEMATICS

61)

9 < |α – β| ≤ 4
0 < (α + β)2 – 4αβ ≤ 16
0 < 36 – 4b ≤ 16
5≤b<9
Possible integral values of b are 5, 6, 7, 8

62)

k – 2 > 0 and D ≤ 0
⇒ k > 2 and (k + 6)(k – 4) ≥ 0
⇒k≥4

63) |x – 1| + |x – 2| + |x – 3| ≥ 6
(i) If x ≤ 1 ⇒ x ≤ 0
(ii) If 1 < x < 2 ⇒ x ≤ –2, rejected
(iii) If 2 ≤ x < 3 ⇒ x ≥ 6, rejected

(iv) If x ≥ 3 ⇒ x ≥ 4

64)

65)

ax2 + b(x2 – x) + c(x2 – 2x + 1) = 0

at2 + bt + c = 0 where t = α; t = β

∴ ⇒

66) Let ƒ(x) = 2k.x2 – 4kx + 2k – 1 ...(1)

∴ ƒ(0).ƒ(1) < 0
⇒ (2k – 1)(2k – 4k + 2k – 1) < 0 put {2k = 1}
⇒ (t – 1)(–t2 + 2t – 1) < 0
⇒ (t – 1)(t – 1)2 < 0
⇒ (t – 1)3 > 0
 ⇒ t > 1 ⇒ 2k > 1

⇒k>0⇒
Check at k = 0
put in (1)

∴ x2 – x = 0 There is exactly one root in [0,1)

∴ k = 0 must be include

67) α2 – 6α – 2 = 0 & β2 – 6β – 2 = 0

72)

ƒ(–2) < 0 and D < 0

73)

⇒ ,

74) 4(4 – x2) < (x + 4)2 and x + 4 ≥ 0 & 4 – x2 ≥ 0

x∈ ∪ (0, ∞) ...(1)
x ∈ [–4, ∞) ...(2)
x ∈ [–2, 2] ...(3)
(1) ∩ (2) ∩ (3)

∪ (0, 2]

75) ƒ(0) ƒ(5) < 0

5k(25 + (k + 1)5 + 5k) < 0
or 5k(10k + 30) < 0
or k ∈ (–3,0)
∴ k=0 k = –3
x2 + x = 0 x2 – 2x – 15 = 0
⇒ x = –1,0 ⇒ (x – 5) (x + 3) = 0
⇒ x = 5, –3
so k = –3
 ∴ k ∈ [–3,0)

77) p2 – 3p + 2 = 0 & (p – 1)2 = 0 & p2 – 4p + 3 =0

⇒p=1

78)

\(\frac{{\alpha + 1}}{\alpha } = y\)

∴ \(\alpha = \frac{1}{{y - 1}}\) and hence equation is
5x2 – 8x + 4 = 0

79)

80)

Use : D < 0 ⇒
⇒ λ2 + 6λ – 40 < 0
⇒ (λ + 10)(λ – 4) < 0
⇒ λ ∈ (–10, 4)

81)

∵α+β+γ=0
⇒ Σ(α + β)–1 = Σ(–a)–1

83)

84)

P(1) = 4, P(2) = 5, P(3) = 6

P(x) = Q(x)(x – 1)(x – 2)(x – 3) + (ax2 + bx + c)
a+b+c=4
 4a + 2b + c = 5
9a + 3b + c = 6
⇒ a = 0, b = 1, c = 3
⇒ R(x) = x + 3
⇒ R(100) = 103

86)

y=1+

88)

For real roots, D ≥ 0 ⇒ k2 – 4(k2 + 7k + 15) ≥ 0

⇒ 3k2 + 28k + 60 ≤ 0
⇒ (3k + 10) (k + 6) ≤ 0 ⇒
∴ x12 + x22 = (x1 + x2)2 – 2x1x2
= k2 – 2(k2 + 7k + 15)
= – k2 – 14k – 30 = 19 – (k + 7)2
Clearly, maximum value of x12 + x22 is obtained at k = – 6.
∴ (x12 + x12)max = 19 – (– 6 + 7)2 = 18 Ans.

89)