02-11-2025

9610WJA801492250056 JA

PART 1 : PHYSICS

SECTION-I

1) A ball is thrown at an angle of 45º with the horizontal with kinetic energy E. The kinetic energy at
the highest point during the flight is :-

(A) Zero
(B) E/2
(C) E
(D) (2)1/2 E

2) For a projectile the ratio of maximum height reached to the square of flight time is

(A) 5 : 4
(B) 5 : 2
(C) 5 : 1
(D) 10 : 1

3) A boy on a trolley is sliding down on a smooth incline having inclination angle 37°. He throws a
ball perpendicular to incline such that he catches it back after time 5 sec. With what velocity was the
ball thrown by the boy relative to himself?

(A) 25 m/s
(B) 20 m/s
(C) 16 m/s
(D) 15 m/s

4) A man can swim in still water with velocity of

4 m/s and river is flowing with velocity of 3m/s. If width of river is 60 m then minimum time required
to cross the river will be :-

(A) 12 s
(B) 15 s
(C) 20 s
(D) 30 s
5) To a man walking at the rate of 3 km/h the rain appears to fall vertically. When he increases his
speed to 6 km/h it appears to meet him at an angle 45° with vertical. Find the speed of rain :-

(A)
(B)

(C)

(D)

6) A particle is moving in straight line a velocity versus time graph is shown in figure.

(A)

(B)

(C)

(D)

7) Which of the following position–time (x–t) graphs represents positive acceleration in rectilinear
motion ?
(A)

(B)

(C)

(D)

8) A block of mass m is placed at rest on a rough inclined plane of angle θ. If coefficient of friction
between the block and the inclined plane is μ, then the total force exerted by the inclined plane on
the block is :-

(A) mg
(B) μmg cosθ
(C) mg sinθ
(D) μmg tanθ

9) The ratio of the weight of a man in a stationary lift and in a lift accelerate downwards with a
uniform acceleration 'a' is 3 : 2 The acceleration of the lift is :-

(A) g/3
(B) g/2
(C) g
(D) 2g

10) What is the tension in the rope at a distance x from the end where the force is applied ?
(A)

(B)

(C)

(D)

11) An insect is at the bottom of a hemispherical bowl of radius 1m. It crawls up the bowl but starts
slipping after it is at height ‘h’ from the bottom. If the coefficient of friction between the bowl and
the insect is 0.75, then h is : (g = 10 ms–2)

(A) 0.80 m
(B) 0.60 m
(C) 0.45 m
(D) 0.20 m

12) Two cars of masses m1 and m2 are moving along the circular path of radius r1 and r2. They take
one round in the same time. The ratio of angular velocities of the two cars will be :-

(A) m1 : m2
(B) r1 : r2
(C) 1 : 1
(D) m1r1 : m2r2

13) A rod of length 1m and mass 0.5kg hinged at one end, is initially hanging vertical. The other end
is now raised slowly until it makes an angle 60° with the vertical. The required work is :( use g = 10
m/s2)

(A)

(B)

(C)

(D)

14) A conical pendulum is moving in a circle with angular velocity ω as shown. If tension in the

string is T, which of following equations are correct?

(A) T = mω2ℓ
(B) T sinθ = mω2ℓ
(C) T = mg cosθ
(D) T = mω2ℓsinθ

15) A road is banked at an angle of 30° to the horizontal for negotiating a curve of radius . At
what velocity will a car experience no friction while negotiating the curve ?

(A) 54 km/hr
(B) 72 km/hr
(C) 36 km/hr
(D) 18 km/hr

16) The kinetic energy acquired by a body of mass m in travelling some distance s, starting from rest
under the action of a constant force, is directly proportional to

(A) m°
(B) m
(C) m2
(D)

17) Two bodies of masses m1 and m2 have equal kinetic energies. If p1 and p2 are their respective
momentum, the ratio p1 : p2 is equal to :

(A) m1 : m2
(B) m2 : m1
(C)
(D)

18) If a particle of mass m is moving in a horizontal circle of radius r with a centripetal force (–k / r2),
the total energy is

(A)

(B)

(C)

(D)

19) The potential energy (in joules) function of a particle in a region of space is given as :
U = (2x2 + 3y3 + 2z)
Here x, y and z are in metres. Find the magnitude of x component of force (in newton) acting on the
particle at point P (1m, 2m, 3m).

(A) 2
(B) 3
(C) 0
(D) 4

20) A particle moves along X-axis from x = 0 to x = 1 m under the influence of a force given by F =
3x2 + 2x – 10. Work done in the process is :-

(A) + 4 J
(B) – 4 J
(C) + 8 J
(D) – 8 J

SECTION-II

1) A small block slides down from the top of hemisphere of radius R = 3 m as shown in the figure.
The height 'h' at which the block will lose contact with the surface of the sphere is ____m.
(Assume there is no friction between the block and the hemisphere)

2) A ball of mass (m) 0.5 kg is attached to the end of a string having length (L) 0.5 m. The ball is
rotated on a horizontal circular path about vertical axis. The maximum tension that the string can
bear is 324 N. The maximum possible value of angular velocity of ball (in radian/s) is :-

3) A hanging mass M is connected to a four times bigger mass by using a string-pulley arrangement,
as shown in the figure. The bigger mass is placed on a horizontal ice-slab and being pulled by 2 Mg

force. In this situation, tension in the string is for x = _____. Neglect mass of the string and
friction of the block (bigger mass) with ice slab. (Given g = acceleration due to gravity)
4) A projectile is fired at an angle 60° with horizontal. Ratio of initial K.E. to K.E when velocity
vector of projectile makes an angle 15° with velocity of projection is –

5) A force newton is applied over a particle which displaces it from its origin to the point
metre. The work done on the particle in J is

PART 2 : CHEMISTRY

SECTION-I

1) 60 gm of an organic compound containing C,H & O atoms on complete combustion gave 88gm
CO2 & 36gm H2O. The empirical formula of the organic compound is :

(A) C2HO
(B) CHO
(C) CH2O
(D) CHO2

2) A solution is made by dissolving CaBr2 in water (solvent) such that mass fraction of solute and
solvent is same in the solution. The molality of solution is: (Atomic mass Br = 80, Ca = 40)

(A) 2.5 m
(B) 55.55 m
(C) 2 m
(D) 5 m

3)

20 mL of a gaseous hydrocarbon was exploded with 120 mL of oxygen. A contraction of 60 mL was

observed, and a further contraction of 60 mL took place when KOH was added. What is the formula
of the hydrocarbon :

(A) C3H6
(B) C3H8
(C) C2H6
(D) C4H10

4) In which of the following reactions H2O2 acts as a reducing agent?

(i) H2O2 + 2H+ + 2e– 2H2O
–
(ii) H2O2 – 2e O2 + 2H+
(iii) H2O2 + 2e– 2OH–
(iv) H2O2 + 2OH– – 2e– O2 + 2H2O

(A) (i), (ii)

(B) (iii), (iv)
(C) (i), (iii)
(D) (ii), (iv)

5) A2Ox is oxidised to AO3¯ by MnO4¯ in acidic medium. If 1.5 × 10–3 mole of A2Ox requires 40 ml of
0.03M KMnO4 solution in acidic medium. Which of the following statement(s) is/are correct?

(A) The value of "x" = 1

(B) The value of "x" = 3
(C) Empirical formula of oxide is AO3.
(D) Empirical formula of oxide is A2O.

6) Given below are two statements :

Statement-I: S8 solid undergoes disproportionation reaction under alkaline conditions to form

Statement-II: can undergo disproportionation reaction under acidic condition.

In the light of the above statements, choose the most appropriate answer from the options given
below :

(A) Statement I is correct but statement II is incorrect.

(B) Statement I is incorrect but statement II is correct
(C) Both statement I and statement II are incorrect
(D) Both statement I and statement II are correct

7) The velocity of electron in the 2nd orbit of H-atom is V cm/sec. Its velocity in 5th Bohr's orbit would
be :-

(A) 5 × V cm/sec

(B)
V× cm/sec

(C)
V× cm/sec
(D) None

8) The orbital angular momentum of a p orbital electron is given as :-

(A)

(B)

(C)

(D)

9) The energy of the second Bohr orbit of the hydrogen atom is –328 KJ/Mole ; hence the energy of
4th Bohr orbit would be :-
(A) –1312 KJ mol–1
(B) –82 KJ mol–1
(C) –41 KJ mol–1
(D) –164 KJ mol–1

10) Quantum number of some electrons are given below on the basis of it, arrange them from lowest
to highest energy order:

n ℓ m s

(P) 4 1 0

(Q) 5 0 0

(R) 6 2 0

(S) 6 3 –1

(A) P < Q < R < S

(B) Q < R < P < S
(C) Q < R < S < P
(D) S < Q < R < P

11) Match the following

Column I Column II

2s, 3s, 4s, 4d

(i) (a) Bohr
(order of increasing energy)

Quantum numbers of 2s2

electrons

(ii) (b) Hund’s Rule

2p3 is and not Pauli’s

(iii) (c)
exclusion

Principle quantum number Aufbau

(iv) (d)
“n” principle

(e) Size of orbit

(A) (i) → (c), (ii) → (d), (iii) → (b), (iv) → (e)

(B) (i) → (d), (ii) → (c), (iii) → (b), (iv) → (a,e)
(C) (i) → (e), (ii) → (b), (iii) → (d), (iv) → (c,e)
(D) (i) → (c,e), (ii) → (d), (iii) → (a), (iv) → (b)

12) The kinetic energy of the electron present in the ground state of Li2+ ion is represented by :

(A)

(B)

(C)

(D)

13) Let v1 be the frequency of the series limit of the Lyman series, v2 be the frequency of the first
line of the lymen series and v3 be the frequency of the series limit of Balmer series :-

(A) v1 – v2 = v3
(B) v2 – v1 = v3

(C)
v2 = (v1 – v3)
(D) v1 + v2 = v3

14) If the radius of first Bohr orbit is x, then de Broglie wavelength of electron in 4th orbit is nearly

(A) 8πx
(B) 6πx
(C) 4πx
(D) 2πx

15) The uncertainty in position of an electron is equal to its de-broglie wavelength. The minimum
percentage error in its measurement of velocity under this circumtance will be approximately :-

(A) 4
(B) 8
(C) 22
(D) 18

16) Which of the following statements is not correct

(A) Rydberg constant and wave number have same units

(B) Lyman series of hydrogen spectrum occurs in the U.V region
(C) The angular momentum of the eletron in the ground state of hydrogen atom is equal to
(D) The radius of the first Bohr orbit of hydrogen atom is 2.116 × 10–8 cm

17) In gold foil experiment number of deflected α-particles at angle 90° is 63 than number of α-
particle deflected at 120° is :-
(A) 112
(B) 42
(C) 56
(D) 28

18)

20 mL of a mixture of CO and H2 were mixed with excess of O2 and exploded & cooled. There was a
volume contraction of 23 mL. All volume measurements corresponds to room temperature (27°C)
and one atmospheric pressure. Determine the volume ratio V1 : V2 of CO and H2 in the original
mixture

(A) 6.5 : 13.5

(B) 5 : 15
(C) 9 : 11
(D) 7 : 13

19) H2O2 is oxidised by MnO4– in acidic medium to form O2 and Mn2+. How many grams of O2 are
produced from 1.5 × 10–3 moles of MnO4– and 1.2 milligrams of H2O2 :-

(A) 1.13 × 10–3

(B) 2.5 × 10–3
(C) 7.5 × 10–4
(D) 0.35 × 10–5

20) A silver coin weighing 11.34 g was dissolved in nitric acid. When sodium chloride was added to
the solution all the silver (present as AgNO3) was precipitated as silver chloride. The weight of the
precipitated silver chloride was 14.35 g. Calculate the percentage of silver in the coin -

(A) 4.8 %
(B) 95.2 %
(C) 90 %
(D) 80 %

SECTION-II

1) A chemist wants to prepare diborane by the reaction .

If we start with 32.0 moles of each of LiH and BF3. How many moles of B2H6 can be prepared.

2) Find total number of species having magnetic moment value B.M. among following species
Fe+2, Cr, Cr+3, Ti+2, Mn+2, V+3

3) At what minimum atomic number of hydrogen like species, a transition of electron from n = 2 to n
= 1 energy level results in the emission X-rays of 300Å?
4) 100 ml of Na2S2O3 solution is divided into two equal parts A and B. A part requires 12.5 ml of 0.2
M I2 solution (acidic medium) and part B is diluted x times and 50 ml of diluted solution requires 5
ml of 0.8 M I2 solution in basic medium. What is value of x?

Acidic Basic

n-factor of I2 2 2

n-factor of Na2S2O3 1 8

5) Calculate the total number of nodes in orbital represented by wave function

PART 3 : MATHEMATICS

SECTION-I

1) If where
a, b, c, x, y, z ∈ {1, 2, 3, 4, 5, 6} and also a, b, c, x, y, z are distinct then number of matrices in A
with trace equal to 10 are :-

(A) 3(3!)2
(B) 2(3!)2
(C) (3!)2
(D) (3!)3

2) Let , Y = αI + ßX + γX2 and

If Y–1 = , then (α – ß + γ)2 is equal to ___

(A) 10
(B) 100
(C) 25
(D) 5
3) If , then tr(A3 adj(A2)), is
(where tr(A) and adj(A) denote trace and adjoint of matrix A)-

(A) 6
(B) 24
(C) 36
(D) 12

4) Let A be a 3 × 3 matrix such that adj A = and B = adj (adj A). If |A| = λ
and |(B–1)T| = μ, then the ordered pair, (|λ|, μ) is equal to :

(A)

(B)

(C)

(D) (3, 81)

5) If α and β are the roots of the equation x2 + px + 2 = 0 and and are the roots of the

equation 2x2 + 2qx + 1 = 0, then is equal to :

(A)
(9 + p2)

(B)
(9 – q2)

(C)
(9 – p2)

(D)
(9 + q2)

6) If α and β are the distinct roots of the equation x2 + (3)1/4x + 31/2 = 0, then the value of α96(α12 – 1)
+ β96(β12 – 1) is equal to :

(A) 56 × 325
(B) 56 × 324
(C) 52 × 324
(D) 28 × 325

7) Let P(x) be a polynomial with integral coefficients. If there exist two integers a and b such that
P(a) – P(b) = 1, then

(A) both a and b must be even

(B) both a and b must be odd
(C) a and b are two consecutive integers
(D) a and b must be prime

8) If the equation (x2 + 2)2 – (a + 4) (x4 + 3x2 + 2) + (a + 3) (x2 + 1)2 = 0 has atleast one real solution,
then integral value of 'a' can be-

(A) –2
(B) –1
(C) 0
(D) 1

9) If α,β,γ be the roots of the equation x3 + ax + a = 0 (where a ∈ R, a ≠ 0) satisfy

, then a is-

(A) –8
(B) –2
(C) 2
(D) 8

10) The value of is equal to

(A) 0

(B)

(C)

(D) None of these

11) There is a certain sequence of positive real numbers. Beginning from the third term, each term
of the sequence is the sum of all the previous terms. The seventh term is equal to 1000 and the first
term is equal to 1. The second term of this sequence is equal to

(A) 246

(B)

(C)

(D) 124
12) If are in H.P. and are in G.P., then

(A) 76
(B) 80
(C) 84
(D) None of these

13) Let a1,a2,......,a21 be an AP such that . If the sum of this AP is 189, then a6a16 is
equal to :

(A) 57
(B) 72
(C) 48
(D) 36

14) The number of values of θ∈(0,π) for which the system of linear equations x + 3y + 7z = 0, –x +
4y + 7z = 0 & (sin 3θ)x + (cos 2θ) y + 2z = 0 has a non-trivial solution, is :

(A) One
(B) Three
(C) Four
(D) Two

15) Consider, f(x) = where n ∈ N then which is incorrect ?

(A)

(B)

(C)

(D)

16) If and , x ≠ 0; then for all

(A) Δ1 – Δ2 = x (cos 2θ – cos 4θ)
3
(B) Δ1 + Δ2 = –2x
3
(C) Δ1 – Δ2 = –2x
3
(D) Δ1 + Δ2 = –2(x + x –1)

17) If = kλ λ ≠ 0, then k is equal to :

(A) 4 λabc
(B) –4λ2
(C) 4λ2
(D) –4λabc

18) A survey of 500 television viewers produced the following information; 285 watch football, 195
watch hockey, 115 watch basket ball, 45 watch football and basket ball, 70 watch football and
hockey, 50 watch hockey and basketball, 50 do not watch any of the three games. The number of
viewers, who watch exactly one of the three games, is :

(A) 325
(B) 310
(C) 405
(D) 372

19) Let Z be the set of integers. If and

, then the number of subsets of the set A × B, is :

(A) 218
(B) 210
(C) 215
(D) 212

20) If A = {1, 2, 3, 4, 5, 6}, then the number of subsets of A which contains atleast two elements is

(A) 63
(B) 57
(C) 58
(D) 64

SECTION-II
1) Let A is a non-zero matrix of order '2' such that A + adj A = A–1 then determinant of (2A–1) is equal
to

2) Let m and n be the numbers of real roots of the quadratic equations x2 – 12x + [x] + 31 = 0 and x2
– 5|x + 2| – 4 = 0 respectively, where [x] denotes the greatest integer ≤ x. Then m2 + mn + n2 is
equal to ____.

3) If the arithmetic mean of a1, a2.......a48 is and the arithmetic mean of b1, b2, ...... b48 is λ such that

ai + bi = 1 ∀ i = 1,2,.......48, then the value of – 4λ is equal to

4) The sum of all the elements in the set | H.C.F. of n and 2040 is 1} is equal
to _______.

5) The remainder when is divided by 5 is k then k equal to

 ANSWER KEYS

PART 1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B A B B A C D A A D D C B A C A C A D D

SECTION-II

Q. 21 22 23 24 25
A. 2 36 6 2 7

PART 2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C D B D B A B C B A B A A A B D D D A B

SECTION-II

Q. 46 47 48 49 50
A. 4 2 2 5 4

PART 3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A B B C C C C B A B B A B D B B C A C B

SECTION-II

Q. 71 72 73 74 75
A. 8 9 6 1251 4
 SOLUTIONS

PART 1 : PHYSICS

1)

Explain Question: KE at highest point of 45° projectile

Concept: Only horizontal KE remains

Solution: At highest point ; E' = (v cos 45°)2 =

Final Answer: (B)

2)

Explain Question: Ratio of max height of flight time2 for projectile

Concept: Use H and T relation

Solution: T =

and H =

Final Answer: (A)

3)

Explain Question: Trolley boy throws ball and catches after 5s

Concept: Relative motion on incline
Solution: As boy catches the ball, the ball is thrown perpendicular to inclined plane.

Final Answer: (B)

4)

Explain Question: Minimum time to cross river

Concept:
Solution:

t= = 15 sec
Final Answer: (B)
 5)

Explain Question: Rain appears vertical and at 45°

Concept: Relative velocity
Solution:

x=3

Final Answer: (A)

6)

Explain Question: Find x-t graph from v-t graph

Concept: Slope of x-t = velocity
Solution: Slope of displacement time graph is velocity.
Final Answer: (C)

7)

Explain Question: Positive acceleration in x-t graph

Concept: Concave up curve
Solution: Velocity = slope of x – t = graph.
Final Answer: (D)

8)

Explain Question: Total contact force on rough incline

Concept:
Solution: f = mg sinθ, N = mg cosθ
R=
Final Answer: (A)

9)

Explain Question: Lift weight ratio (rest vs down accel)

Concept: N = mgeff
 Solution:
Final Answer: (A)

10)

Explain Question: Tension at x in rope

Concept: Newton's 2nd law
Solution:

L —→ M

1 —→

L – x —→ (L–x) = m1

T = Ma =
Final Answer: (D)

11)

Explain Question: Max height before slip in bowl

Concept:
Solution:

Final Answer: (D)

12)

Explain Question: Two cars same time per circle

 Concept: same angular velocity

Solution:

∴
Final Answer: (C)

13)

Explain Question: Work to lift rod 60°

Concept: PE change of COM
Solution:

Final Answer: (B)

14)

Explain Question: Conical pendulum relation

Concept: Centripetal force
Solution:

Tsinθ = mω2r
⇒ T sinθ = mω2ℓsinθ (∵ r = ℓsinθ)
⇒ T = mω2ℓ
Final Answer: (A)

15)

Explain Question: Speed on 30° banked road

Concept:

Solution:
Final Answer: (C)

16)

Explain Question: KE gained under constant force

Concept: Work energy therorem
Solution:
 K.E. acquired by the body = work done on the body K.E. mv2 = Fs i.e. it does not depends
upon the mass of the body although velocity depends upon the mass

v2 ∝ [If F and s are constant]

Final Answer: (A)

17)

Explain Question: Equal KE, find momentum ratio

Concept:

Solution: P = (If E = const.) ∴ =

Final Answer: (C)

18)

Explain Question: Total energy in force

Concept:

Solution: mv2 = ∴ K.E. = mv2 =

P.E. =

∴ Total energy =
Final Answer: (A)

19) Question Explanation: Finding the x-component of force from a potential energy
function.
Concept: Force from Potential Energy (Conservative Forces)
Solution: The force is the negative derivative of the potential energy function with respect to
the position coordinate. To find the x-component of the force (Fx​), take the negative partial
derivative of the potential energy (U) with respect to x.
Calculation:
Potential Energy

x - component of force

At point
P(1m, 2m, 3m), x = 1m.
Fx = – 4(1) = – 4N
The magnitude of the x-component of force is .
Final Answer: (D)
 20)

Explain Question: Work done from x = 0 to 1

Concept: Integrate F dx

Solution:
Final Answer: (D)

21)

Explain Question: Height where block loses contact (R=3)

Concept: Energy conservation
Solution:

mg cos θ = ...(1)

cos θ =
Energy conservation

mg{R – h} = mv2 ...(2)

From (1) and (2)

mg

h= = 2m Final Answer: (2)

22)

Explain Question: Max omega of ball

Concept:
Solution:

Tsinθ=mω2 (Lsinθ) ⇒ T = mω2L

Final Answer: (36)

23)

Explain Question: Tension pulley 4M and M

Concept: Net force & accel relation

Solution: (in upward direction)

Final Answer: (6)

24)

Explain Question: KE ratio at 60° launch

Concept: Compare velocity angles

Solution: v =

∴ Kf = Ki

∴ =2
Final Answer: (2)

25)

Explain Question: Work by (5i +3j) over (2i – 1j)

Concept: Dot product
Solution: W =
= (10 – 3)J
=7J
Final Answer: (7)

PART 2 : CHEMISTRY

26) Explain Question: A combustion Reaction and gm of CO2 & H2O given, Asking formula of
compound
Concept: Write combustion reaction,
Solution:
CxHyOz + O2 → xCO2 + H2 O
60 gm 88 gm 36 gm
2 moles 2 moles
x × moles of CxHyOz = 1 × 2
y × moles of CxHyOz = 2 × 2

Final Answer: (C)

27) Explain Question: Asking molality of solution

Concept: Apply formula of molality
Solution:
Solute = CaBr2
Solvent = H2O
Same mass fraction ⇒ mass of solute = mass of solvent
= x gm (say)

Molality =

m=
Final Answer: (D)

28) Explain Question: Asking formula of hydrocarbon given volume Cantraction

Concept: Apply volume contraction
Solution:

CxHy + (x + y/4) O2 → xCO2 + H2O

t=0 20 120

t = t1 0
20x = 60
Vi – Vf = 60
y=8
Final Answer: (B)

29) Explain Question: Asking where H2O2 Act As reducing Agent

Concept: Self oxidized, reduce to other.
Solution:
H2O2 acts as reducing agent when it releases electrons (itself gets oxidised and reduces others)
i.e. in (ii) & (iv).
Final Answer: (D)

30) Explain Question: Asking about volume of x

Concept: Balance reaction or apply equivalent concept
Solution:
1.5 × 10–3 × (5 – x) × 2 = 0.03 × 5 ×
x=3
Final Answer: (D)

31) Explain Question: Asking about correct statement

Concept: Dispropertionation redox reaction
Solution:

cannot undergo disproportionation reaction as chlorine is present in it’s highest

oxidation state.
Final Answer: (A)

32) Explain Question: To find velocity of electron

Concept: Bohr model
Solution:

V2 = = V ⇒ V1 = 2V

V5 =
Final Answer: (B)

33) Explain Question: Asking orbital Angular momentum

Concept: Apply orbital angular momentum formula
Solution:

A.M. = for p e– ⇒ ℓ = 1
Final Answer: (C)

34) Explain Question: Asking energy of 4th orbit

Concept: Apply bohr Bohr Energy formula
Solution:

∴ =

E2 = –82 kJ/mol
Final Answer: (B)

35) Explain Question: Asking energy orden of given set of quantum number
Concept: Apply (n + l) rule
Solution:
Use (n + ℓ) rule
(P) n + l = 5
(Q) n + l = 5
(R) = n + l = 7
(S) n + l = 9
Final Answer: (A)

36) Explain Question: Match correct data related to electron filling.

Concept: Apply (n + l) rule
Solution:
(i) → (d) ( n + ℓ ) rule
(ii) → (c) two electron must have opposite spin
(iii) → (b) electron must be spin singly occupied
(iv) → (a, e) It was used by Bohr’s and it represent size of orbit.
Final Answer: (B)

37) Explain Question: Asking K.E of Li+2 ion

Concept: Apply bohr model principle
Solution:

Final Answer: (A)

38) Explain Question: Asking relation between V1 V2 & V3

Concept: Use Rydberg formula
Solution:

v1 = R Z2 = R (Z = 1)

v2 = R V1

V3 = R
V1 – v2 = v3
Final Answer: (A)

39)

Explain Question: Find λ for 4th orbit

Concept: Apply de-broglic equation.
Solution:
r1 = x
r4 = 16x
(∴ r ∝ n2)

also λ = ……(i) (from de Broglie equation)

and mvr = ……(ii)

from (i) and (ii)
2πr = nλ

∴ Wavelength of electron in 3rd orbit.

λ3 = = = 8πx.
Final Answer: (A)

40) Explain Question: Asking % Error in velocity

Concept: Apply uncertainity principle
Solution:

Δx · Δp =

Δp = ⇒

= 8%
Final Answer: (B)

41) Explain Question: Check which one is correct

Concept: Use bohr model formula
Solution:

radius of bohr orbit

For H, n = 1, Z = 1
Final Answer: (D)

42)

Explain Question: Asking number of α-particle deflected

Concept: No of α-partide
Solution:

No. of deflected α-particles

Final Answer: (D)

43) Explain Question: Asking volume ratio in given combustion

Concept: Balance chemical equation and apply volume contraction.
Solution:

x x/2 x

(20-x) (20-x)

Vol Cont. =
x=7
Final Answer: (D)

44) Explain Question: Asking quantity of O2 in gram

Concept: Balance Redox reaction and apply equivalent concept
Solution:
2MnO4– + 5H2O2 + 6H+ → 2Mn+2 + 8H2O + 5O2
5 mol H2O2 5 mol O2
1 mol H2O2 1 mol O2

mol of O2

× 32 wt of O2
–3
1.13 × 10 gm of O2
Final Answer: (A)

45) Explain Question: In given question Asking about % of Ag in Coin

Concept: Balance reaction apply mole concept
Solution:

143.5 gm of silver chloride would be precipitated by 108 g of silver.

or 14.35 g of silver chloride would be precipitated 10.8 g of silver.
11.34 g of silver coin contain 10.8 g of pure silver.

100 g of silver coin contain

Final Answer: (B)

46) Explain Question: Find mole of B2H6

Concept: Apply limiting reagent concept
Solution:
6LiH + 8BF3 → 6LiBF3 + B2H6
32 32 4
(L.R)
From 8 mole BF3 → 1 moles B2H6 from

∴ From 32 mole BF3 = × 32 = 4 mol

Final Answer: (4)

47) Explain Question: Asking magneti moment

Concept: Apply
Solution:

⇒ 2 unpaired e–
Fe+2 = 3d6 = 4 unpaired electron
Cr = 4s3d5 = 5 unpaired electron
Cr+3 = 3d3 = 3 unpaired electron
TC+2 = 3d2 = 2 unpaired electron
Mn+2 = 3d5 = 5 unpaired electron
V+3 = 3d2 = 2 unpaired electron
Final Answer: (2)

48) Explain Question: Asking atomic number

Concept: Apply Rydberg Formula
Solution:

Thus, Z = 2
Final Answer: (2)

49) Explain Question: Asking about value of x. by comparing solution in different medium
Concept: Apply law of equivalence
Solution:
Part A
1 × M × 50 = 2 × 12.5 × 0.2 ...(1)
Part B
8 × M1 × 50 = 2 × 5 × 0.8 ...(2)
Dividing (1) by (2) we get

∴ M is 5 times diluted.
Final Answer: (5)

50) Explain Question: Asking about node of given wave function

 Concept: Apply formula of node calculation.
Solution:

n=5
=1
m=1
orbital: 5p
Radial nodes = n - - 1
=5-1-1=3
Angular nodes = = 1
Total nodes = 4
Final Answer: (4)

PART 3 : MATHEMATICS

51) Explain Question : Distinct number of matrices find.

Concept : Permutation and combination.
Solution :
Tr(A) = a + b + c = 10 ; (a ≠ b ≠ c)
Therefore it may be (1, 3, 6), (1, 4, 5), (2, 3, 5)

number of matrices =
Final Answer : (A)

52) Explain Question : Matrix and inverse matrix in given.

Concept : A ⋅ A–1 = I
Solution :

Y.Y–1 = I
Final Answer : (B)

53) Explain Question : Given a square matrix.

Concept : A ⋅ adj = |A| I
Solution :

If

=A|A2 |⋅I
=A|A|2⋅I
|A| = 1(6–2)+1(–2)
=4–2=2
So, A3 adj (A2) = A⋅(2)2

tr(A3 adj (A2) = 4 + 8 + 12

= 24 Ans.
Option (B) is correct.
Final Answer : (B)

54) Explain Question : Adjoint of matrix A is given.

Concept : |adj A| = |A|n – 1
Solution :

C = adj A =
|C| = |adj A| = +2(0 + 4) + 1.(1 – 2) + 1.(2, 4)
= +8 – 1 + 2
|adj A| = |A|2 = 9 = 9
λ = |A| = ±3
|λ| = 3
B = adj C
|B| = |adj C| = |C|2 = 81

|(B–1)T| = |B|–1 =

(|λ|, μ) =
Final Answer : (C)

55) Explain Question : Quadratic equation is given.

Concept : Relation between roots.
Solution :
α, β are roots of x2 + px + 2 = 0
⇒ α2 + pα + 2 = 0 & β2 + pβ + 2 = 0

⇒ are roots of 2x2 + px + 1 = 0

But are roots of 2x2 + 2qx + 1 = 0

⇒ p = 2q
Also α + β = –p αβ = 2

Final Answer : (C)

56) Explain Question : Roots of quadratic equation given.

Concept : Satisfy roots in given equation and simplify.
Solution :

As,

⇒ (On squaring)
∴
⇒ (Again squaring)
∴

⇒
(Multiply by )
So,
∴

Hence,
⇒
⇒
Similarly
∴
⇒ Option (C) is correct.
Final Answer : (C)
57) Explain Question : P(x) be a polynomial with integral coefficients given.
Concept : Apply given condition.
Solution :
Let P(x) = a0xn + a1xn–1 +.....+ an-1,x + an, where a0, a1,....... an are integers.
Now, 1 = P(a) - P(b) = a0 (an - bn) + a,(an–1 - bn -1) + a2(an -2 - bn -2) +..... + an-1(a-b) = (a-b)m,
where m = a0 (an-1 + an-2 b +.....+ abn-2 + bn-1) + a1 (an-2 + an-3 b +.....+ abn-3 + bn-2) +......
+ an-2 (a + b) + an-1 is an integer.
As product of two integers is 1, either a - b = 1 and m = 1
or a - b = - 1 and m = - 1
∴ a and b must be two consecutive integers.
Final Answer : (C)

58) Explain Question : Polynomial equation in given.

Concept : Convert in quadratic equation, then simplify.
Solution :
(x2 + 2)2 – (a + 4) (x2 + 2) (x2 + 1) + (a + 3) (x2 + 1)2 = 0
Divide by (x2 + 1)2 :

let
∴ t2 – (a + 4)t + (a + 3) = 0
⇒t=1;t=a+3

for t = 1 : ⇒ x2 + 2 = x 2 + 1
Not possible

for t = a + 3 :
⇒ x2 + 2 = x2a + 3x2 + a + 3
x2(–a – 2) = a + 1

a ∈ (–2, –1]
Final Answer : (B)

59) Explain Question : Cubic equation is given.

Concept : Apply relation between roots, then solve.
Solution :

⇒
⇒ ⇒
⇒ a = –8
Final Answer : (A)

60) Explain Question : Summation of infinite series find.

Concept : Write general term and manuplate.
Solution :

Tr = = =
= 3(rr – vr + 1)

So, ⇒ Sn = 3 (v1 – vn + 1) =

So, = . Ans
Final Answer : (B)

61) Explain Question : Sequence is given.

Concept : Apply given conditions then solve.
Solution :
sequence is t1 + t2 + t3 + t4 + ........
t3 = t1 + t2 ; t7 = 1000
t1 = 1
but t7 = t1 + t2 + t3 + t4 + t5 + t6
1000 = 2(t1 + t2 + t3 + t4 + t5)
(as t6 = t1 + t2 + t3 + t4 + t6)
= 4(t1 + t2 + t3 + t4)
(t4 = t1 + t2 + t3)
= 8(t1 + t2 + t3)
1000 = 16(t1 + t2)

t1 + t2 =

⇒ t2 = –1= –1=
Final Answer : (B)

62) Explain Question : Harmonic progression is given.

Concept : Write A.P. and apply given condition.
Solution :

Clearly, will be in A.P.

Hence,

(say)
Now,

Final Answer : (A)

63) Explain Question : Summation of 20 terms find.

Concept : Write Tn of A.P. and manuplate.
Solution :

⇒ (Given)

⇒ .... (1)

Now sum of first 21 terms = (2a1 + 20d) = 189

⇒ a1 + 10d = 9 ... (2)
For equation (1) & (2) we get

a1 = 3 & d =
OR

a1 = 15 & d =
So, a6.a16 = (a1 + 5d) (a1 + 15d)
⇒ a6a16 = 72
Option (2)
Final Answer : (B)

64) Explain Question : Linear equation solution for non-trivial solution.

Concept : Solve determinant then solve trigonometry equation.
Solution :
(8 – 7 cos 2θ) – 3(–2 – 7 sin 3θ) + 7 (– cos 2θ – 4 sin 3θ) = 0
14 – 7 cos 2θ + 21 sin 3θ – 7 cos 2θ – 28 sin 3θ = 0
14 – 7 sin 3θ – 14 cos 2θ = 0
14 – 7 (3 sin θ – 4 sin3 θ) – 14 (1 – 2 sin2 θ) = 0
–21 sin θ + 28 sin3 θ + 28 sin2 θ = 0
7 sin θ [–3 + 4 sin2 θ + 4 sin θ] = 0
sin θ,
4 sin2 θ + 6 sin θ – 2 sin θ – 3 = 0
2 sin θ (2 sin θ + 3) – 1 (2 sin θ + 3) = 0

sin θ = ; sin θ =
Hence, 2 solutions in (0, π)
Final Answer : (D)

65) Explain Question : Solution of determinant find.

Concept : Apply column operation then solve.
Solution :
C3 → C3 + C2 – C1 Expand along C3

So

+......+

So, for n = 7

For n →
Final Answer : (B)

66) Explain Question : Solution of determinant find.

Concept : Expand both determinants and check.
Solution :
Δ1 = –x3
Δ2 = –x3
⇒ Δ1 + Δ2 = –2x3
Final Answer : (B)

67) Explain Question : Find value of 'k'.

Concept : Apply row operation and equate.
Solution :
LHS

R3 → R3 – R1 + 2R2

∴ k = 4λ2.
Final Answer : (C)

68) Explain Question : Set theory

Concept : n(A ∪ B ∪ C) = n(A) + n(B) + n(C) – n(A ∩ B) - n(B ∩ C) - n(A ∩ C) + n(A ∩ B ∩ C)
Solution :
n(F ∪ H ∪ B) = 500 – 50 = 450
= n(F) + n(H) + n(B) – n(F ∩ H)
– n(F ∩ B) – n(H ∩ B) + n(F ∩ H ∩ B)
⇒ 450 = 285 + 195 + 115 – 45 – 70 – 50
+ n(F ∩ H ∩ B)
⇒ n(F ∩ H ∩ B) = 20
n(Exactly one) = n(F) + n(H) + n(B) – 2 × n(F ∩ H) – 2 × n(H ∩ B) – 2 × n(F ∩ B) + 3× n(F ∩
H ∩ B)
= 285 + 195 + 115 – 2(45 + 70 + 50) + 3.20
= 325
Final Answer : (A)

69) Explain Question : Find number of subsects of A × B.

Concept : Solve both sets then use 2mn
Solution :
A = {x ∈ z : = 1}
0
= 2 ⇒ x = –2, 2, 3
A = {–2, 2, 3}
B = {x ∈ Z : –3 < 2x – 1 < 9}
B = {0, 1, 2, 3, 4}
A × B has is 15 elements so number of subsets of A × B is 215.
Final Answer : (C)

70) Explain Question : Number of subset find.

Concept : Apply given condition.
Solution :
We have, n(A) = 6
Total number of subsets of A = 26
Number of subsets of A which contains at least two elements = 26 - 7
[ Subsets of A having none or 1 element are ]
= 64 - 7= 57
Final Answer : (B)

71) Explain Question : 2 order, non-zero matrix is given.

Concept : Apply given condition.
Solution :
Pre multipy by A
A2 + [Link] A = I2
A2 + |A|.I2 = I2
A2 = (1 – |A|)I2
|A|2 = (|A| – 1)2

|A| = ±(|A| – 1)
Determinant (2A–1) = 8
Final Answer : (8)

72) Explain Question : Location of roots.

Concept : Sketch curve and apply condition.
Solution :
x2 – 12 x + [x] + 31 = 0
x2 – 12x + 31 = –[x]
(x – 6)2 – 5 = –[x]
By graph

zero point of intersection, m = 0

x2 – 5 | x + 2 | – 4 = 0
case-I : x < –2
x2 + 5x + 6 =
x = – 3, – 2 (rejected)
case-II : x ≥ –2
x2 – 5x – 14 = 0
x = 7, – 2
No. of solution (n) = 3
So m2 + mn + n2 = 9
Final Answer : (9)

73) Explain Question : Arithmetic mean is given.

Concept : Summation of series find.
Solution :

then

Final Answer : (6)

74) Explain Question : Sum of element of given set find.

Concept : According to question n should not be multiple of 2, 3, 5, 17.
Solution :

n should not be multiple of 2, 3, 5 and 17.

Sum of all n = (1+3+5+....+99)
(3 + 9 + 15 +....+99) (5 + 25 + 35 + .... + 95) (17)
=2500 867 365 17
= 1251.
Final Answer : (1251)

75) Explain Question : Remainder find.

Concept : Devisor rule.
Solution :

Final Answer : (4)