31-05-2026

1001CTM404021260006 TM

Physics

1) A co-ordinate system consisting of x-y axis, is rotated by an angle θ in anticlockwise direction in

the same plane. The unit vector along new set of axes and are respectively.

(1)
(2)
(3)
(4)

2) Velocity of ball A is given by m/s. If magnitude of velocity of ball B is double the

magnitude of velocity of and its direction parallel to , then velocity of ball B is

(1)
(2)
(3)
(4)

3) Three coplanar vectors and have magnitudes 4, 3 and 2 respectively. If the angle between

any two vectors is 120° then which of the following vector may be equal to

(1)
(2)
(3)
(4)

4) Unit vector in the direction of the resultant of vectors & is

(1)

(2)

(3)

(4)

5) A vector of magnitude 10 unit has initial point at (4, 3). Terminal point of its x-component, when
drawn from the initial point of the vector is (–4, 3). What is terminal point of the vector?

(1) (–4, –3)

(2) (–4, 3)
(3) (4,–3)
(4) (8, 0)

6) Which of the following three vectors of given magnitude can not give zero resultant :-

(1) 4, 5, 6
(2) 1.5, 2.5, 3
(3) 3.2, 4, 8
(4) 2, 2, 2

7) The resultant of the force and is . If is doubled then the resultant also doubles in
magnitude then find the angle between :-

(1)

(2)

(3)

(4)

8) The bottom of an electric pole of height 30m is situated at a distance of from you due 60°
North of East. The magnitude of the position vector of a crow sitting on the top of the pole relative to
you is

(1) 30 m
(2)
(3) 60 m
(4) 50 m

9) is perpendicular to and it is given that then angle between and will be

:-

(1) 30°
(2) 150°
(3) 120°
(4) 0°

10) The resultant of two forces, one double the other in magnitude is perpendicular to the smaller of
the two forces. The angle between two forces is :

(1) 150°
(2) 90°
(3) 60°
(4) 120°

11) For the given vector , the ratio of magnitude of its component on the x-y plane
and the component on z–axis is :-

(1) 2

(2)

(3) 1
(4) None of these

12)

If and , the vector having the same magnitude as that of and parallel to is

(1)

(2)

(3)

(4)

13)

The magnitude of two forces and are in ratio P : Q = 1 : 2. If their resultant is at an angle

, then angle between and is :

(1)

(2) 45º
(3) 30º
(4) 60º

14) A force vector applied on a mass is represented as newton and the mass
accelerates with 1m/s2. What will be the mass of the body ?

(1) kg
(2) kg
(3) 10 kg
(4) 20 kg

15) Which of the following operation is not possible?

(1)

(2)

(3)

(4)

16) A constant force acting on a particle of mass 2kg is given by . What is the work
done by given force during motion of particle from point A (1m, 1m, 0) to point B (3m, 4m, 2m) ?

(1) 5 J
(2) 2 J
(3) 4 J
(4) 6 J

17) x component of is twice of its y-component. If the magnitude of the vector is and it makes
an angle of 135° with z-axis. Then is :

(1)
(2)
(3)
(4)

18) If represent unit vectors in each case, which vector combination(s) result in a unit vector
?

(1) a, b, c
(2) a, c
(3) a, b, d
(4) only d

19) For the given figure, which of the options is incorrect :

(1)
(2)
(3)
(4)

20)

If and are two vectors such that and ,then the angle between
and is:

(1) 30°
(2) 45°
(3) 60°
(4) 90°

21) Coordinates of two adjacent vertices of a regualr hexagon are A(3,–2,1) and B(1,0, –1)

respectively. If center of the hexagon is C, Then

(1)
(2)
(3)
(4) Insufficient information

22) If P and Q are the middle points of the sides BC and CD of the parallelogram ABCD, then
is equal to

(1)

(2)

(3)

(4)

23) If ABCDEF is a regular hexagon and

, then λ is equal to

(1) 2
(2) 3
(3) 4
(4) 6

24) If bisects the angle between a and , where a is a unit vector, then

(1)

(2)

(3)

(4)

25) Let be a vector which makes an angle of 120° with a unit vector b. Then, the unit vector
along (a + b) is

(1)
(2)

(3)

(4)

26) Let u, v and w be such that |u| = 1, |v| = 2, |w| = 3. If the projection v along u is equal to that of
w along u and v, w are perpendicular to each other, then |u – v + w| equals

(1)
(2)
(3) 2
(4) 14

27) Let the cosine of angle between the vectors p and q be λ such that 2p + q = and p + 2q =
, then λ is equal to

(1)

(2)

(3)

(4)

28) If , , then vectors perpendicular to a and b is/are

(1)

(2)

(3)

(4) None of these

29) In a parallelogram ABCD, and diagonal , then ∠BAC is equal to

(1)

(2)

(3)

(4) None

30) The value of a so that the volume of parallelopiped formed by , and becomes
minimum is
(1) –3
(2) 3
(3)
(4)

Chemistry

1) Similar to the % labelling of oleum, a mixture of H3PO4 and P4O10 is labelled as (100 + x) % where
x is the maximum mass of water which can react with P4O10 present in 100 gm mixture of H3PO4 and
P4O10. If such a mixture is labelled as 127 %. Mass of P4O10 in 100 gm of mixture, is

(1) 71 gm
(2) 47 gm
(3) 83 gm
(4) 35 gm

2)
Generally commercial hydrochloric acid is prepared using above method. Where NaCl is reacted
with H2SO4 to give HCl.
Step-I : 2NaCl + H2SO4 → 2HCl + Na2SO4
In next step HCl(g) is dried using concentrated H2SO4, and then HCl(g) is collected in H2O container.
Calculate how much H2SO4 solution, containing 49% H2SO4, is required to make 1 kg HCl solution of
25% weight of HCl.

(1) 720 gm
(2) 1420 gm
(3) 685 gm
(4) 1370 gm

3) The strengths of 5.6 volume hydrogen peroxide (of density 1 g/mL) in terms of mass percentage
and molarity (M), respectively, are: (Take molar mass of hydrogen peroxide as 34 g/mol)

(1) 1.7 and 0.25

(2) 1.7 and 0.5
(3) 0.85 and 0.5
(4) 0.85 and 0.25

4) The mole fraction of solvent in an aq. solution is 0.7. The molality (in mol kg–1) of the aqueous
solution is :

(1) 13.88 mol kg–1

(2) 23.80 mol kg–1
(3) 194.44 mol kg–1
(4) 1.38 mol kg–1

5) NH3 is formed in the following steps :

50% yield
100% yield
50%
If above reaction are carried out by taking 80 g of Ca and 36 g of C then NH3(g) produced was
completely dissolved in 500 ml of water then the molar concentration of NH4OH will be:

(1) 6 M
(2) 3 M
(3) 1.5 M
(4) 1 M

6) In 100g of a sample of oleum labelled as 109%, 6g water is added. The new labelling of the oleum
sample is :

(1) 102.83%
(2) 105.83%
(3) 107.87%
(4) 110%

7) For 11.35 V H2O2 solution, the percentage strength in terms of %(w/v) is :

(1) 1.0
(2) 3.4
(3) 11.35
(4) 11.2

8) How many mililiters of 0.1 M H2SO4 must be added to 50 ml of 0.1 M NaOH to give a solution that
has a concentration of 0.05 M in H2SO4.

(1) 40 ml
(2) 50 ml
(3) 200 ml
(4) 100 ml

9) 10 ml of gaseous hydrocarbon is exploded with 100 mL O2. The residual gas on cooling is found to
measure 95 mL out of which 20 mL is absorbed by KOH and the remaining volume is absorbed by
alkaline pyrogallol. The percent of O2 gas consumed during combustion of hydrocarbon is :

(1) 10
(2) 15
(3) 25
(4) 40

10) Magnitude of volume change if 30 ml of C6H5OH (g) is

burnt with excess amount of oxygen, is

(1) 30 ml
(2) 60 ml
(3) 20 ml
(4) 10 ml

11) The conversion of oxygen to ozone 3O2 → 2O3 occurs to the extent of 15% only. The mass of
ozone that can be prepared from 67.2 L of oxygen at S.T.P. will be -

(1) 14.4 gm
(2) 96 gm
(3) 640 gm
(4) 64 gm

12)

The % by volume of C4H10 in a gaseous mixture of C4H10, CH4 and CO is 40. When 200 ml of the
mixture is burnt in excess of O2. Find volume (in ml) of CO2 produced.

(1) 220
(2) 340
(3) 440
(4) 560

13) When 500 ml CO2 gas is passed through red hot charcoal, the volume becomes 700 ml. The
volume of CO2 converted into CO is

(1) 200 ml
(2) 300 ml
(3) 350 ml
(4) 500 ml

14) In the balanced chemical reaction the sum of (a + b + c + d) is

(1) 17
(2) 19
(3) 20
(4) 24

15)
Match equivalent mass of underlined species, assume M is the required molar mass.

List - I
List - II (Equivalent masss)
(Reaction)

(I) Zn + HNO3 → Zn(NO3)2 + NH4NO3 + H2O (P)

(II) H2O2 → H2O + O2 (Q)

(III) (NH4)2Cr2O7 → N2 + Cr2O3 + H2O (R)

(IV) P4 + NaOH + H2O → PH3 + NaH2PO2 (S)

(1) I-P, II-Q, III-S, IV-R

(2) I-P, II-Q, III-S, IV-T
(3) I-R, II-P, III-S, IV-Q
(4) I-R, II-Q, III-S, IV-T

16) Consider the following reaction :

The values of x, y and z in the reaction are respectively :-

(1) 5 , 2 and 16
(2) 2 , 5 and 8
(3) 2 , 5 and 16
(4) 5 , 2 and 8

17) Which of the following groups of molecules act both as oxidising agent as well as reducing
agent?

(1) KMnO4, O3, SO3

(2) HClO4, HNO2, H2O2
(3) HNO2, SO2, H2O2
(4) HNO3, SO2, H2SO4

18) The oxidation states of the most electronegative element in the products of the reaction of BaO2
with dilute H2SO4.

(1) 0 and –1
(2) –1 and –2
(3) –2 and 0
(4) –2 and +2

19) The compound contains three elements X, Y and Z. If the oxidation state of X is +2, Y is +5 and
that of Z is –2, the possible formula for the compound is

(1) X3(YZ4)2
(2) X3(Y4Z)2
(3) XYZ2
(4) X2(YZ3)2

20) One mole of N2H4 loses ten moles of electrons to form a new compound, Y. Assuming that all the
nitrogen appears in the new compound, what is the oxidation state of nitrogen in Y?
[There is no change in the oxidation state of hydrogen]

(1) +2
(2) -2
(3) +3
(4) +4

21) If mA gram of a metal A displaces mB gram of another metal B from its salt solution and if the
equivalent weights are EA and EB respectively then equivalent weight of A can be expressed as

(1)
EA = × EB

(2)
EA =

(3)
EA = × EB

(4)
EA =

22) N2 + 3H2 ⟶ 2NH3, molecular weight of NH3 and N2 are X1 and X2 and their equivalent weight are
Y1 and Y2 respectively, then (Y1 – Y2) is :

(1) (2X1− X2)/6

(2) (X1 – X2)
(3) (3X1 – X2)
(4) (X1 – 3X2)

23)

(A) S2⊝ + 4H2O2 → + 4H2O

(B) Cl2 + H2O2 → 2HCl + O2
The true statement regarding the above reactions is :

(1) H2O2 acts as reductant in both the reactions.

(2) H2O2 acts as oxidant in reaction (A) and reductant in reaction (B).
(3) H2O2 acts as an oxidant in both the reactions.
(4) H2O2 acts as reductant in reaction (A) and oxidant in reaction (B).

24) The oxidation state of 'O' is maximum in

(1) CaOCl2
(2) OF2
(3) O2F2
(4) H2O2

25) The drain cleaner, Drainex contains small bits of aluminium (Al = 27) which reacts with caustic
soda to produce dihydrogen. What is the volume (in ml) of dihydrogen at 27°C and 1.013 bar that is
produced when 0.27 gm of aluminium reacts :

(1) 0.369
(2) 369.0
(3) 246.0
(4) 540.0

26) A mixture of hydrocarbon C2H2 , C2H4 & CH4 in mole ratio of 2 : 1 : 2 is burnt completely in the
presence of air containing 80% N2 & 20%O2 by volume. The mass of air required for the complete
combustion of the one gm of mixture is

(1)

(2)

(3)

(4)

27) The number of hydrogen atoms in 0.9 gm glucose, C6H12O6, is same as :

(1) 0.048 gm hydrazine, N2H4

(2) 0.17 gm ammonia, NH3
(3) 0.30 gm ethane, C2H6
(4) 0.03 gm hydrogen, H2

28) 48 mg of triatomic volatile substance (x3) is converted to vapour that displaces 11.2 ml of air at 1
atm and 273 K. Find the atomic weight of element x.

(1) 96
(2) 48
(3) 32
(4) 16

29) Ethanol, C2H5OH, is the substance commonly called alcohol. The density of liquid alcohol is
0.7893 g/ml at 293 K. If 1.2 mole of ethanol are needed for a particular experiment, what volume of
ethanol should be measured out?

(1) 55 ml
(2) 58 ml
(3) 70 ml
(4) 79 ml

30) Which of the following has been arranged in order of increasing oxidation number of nitrogen?

(1)
(2)
(3)
(4)

Mathematics

1)

(1) 3
(2) 6
(3) 7
(4) 8

2)

In ‘S’ be the solution set of inequality the Number of prime numbers

in a ‘S’ is

(1) 1
(2) 2
(3) 3
(4) 4

3) If
Find , where A = 81

(1) 2
(2) 1
(3) 3
(4) 0

4)

If then 2x =

(1) 1
(2) 2
(3) 3
(4) 4

5)

If |x + 1 + x2 + 2| = |x + 1| + |x2 + 2|, then

(1) x < –1
(2) x ≥ –1
(3) x <
(4) None of these

6) If ax = ay then

(1) x = y always
(2)
(3)
(4) None of these

7) Number of values of x satisfying the equation is -

(1) 5
(2) 8
(3) 0
(4) 9

8) What is the sum of all real values of x, for which

(1) 2
(2) –1
(3) 1
(4) 0

9) If a + b + c = 2, ab + bc + ca = 3 and abc = 4, then the value of is equal to

(1) 15
(2) 16
(3) 17
(4) 18

10) If x = and 'x' is represented in the form where p, q, r ∈ then find p+q+r

(1) 6
(2) 5
(3) 7
(4) 8

11) If and Then the values of is equal to.

(1) 271
(2) 360
(3) 371
(4) 390

12) Suppose R(x) is remainder when

is divided by .
Then is

(1) 2022
(2) -2022
(3) 2023
(4) -2023

13) Solve: | |x–1| + 2| ≤ 4.

(1) [–1, 3]
(2) [–1, 3)
(3) (3, –1]
(4) [1, –3]

14) The expression is equal to

(1)
(2)
(3)
(4)

15) Let 3a = 4, 4b = 5, 5c = 6, 6d = 7, 7e = 8 and 8f = 9 then product (abcdef) =

(1) 1
(2) 2
(3)
(4) 3

16) Let A and B be non-empty subsets of X such that A ⊄ B. Then :-

(1) A is a subset of B'

(2) B ⊂ A
(3) A and B are disjoint
(4) A ∩ B' ≠ ϕ

17) If , then correct statement is

(1) {3} ∈ A
(2) {3,4} ∉ A
(3) {3,4} ⊂ A
(4) {{3,4}} ⊂ A

18) Let , then the number of non empty subsets of S such that product of its
elements is non zero is

(1) 15
(2) 16
(3) 32
(4) 8

19)
The shaded region in given figure is

(1) A ∩ B ∪ C
(2) C – (A ∩ B)
(3) C – (B ∩ C)
(4) C – (A ∪ C)

20) Two finite sets have m and n elements. The number of subsets of the first set is 112 more than
that of the second set. The values of m and n are, respectively

(1) 4, 7
(2) 7, 4
(3) 4, 4
(4) 7, 7
21) How many of the following statements are correct
P : In roster form, the order in which the elements are listed is immaterial
Q : While writing a set in roster form, an element is not generally repeated.
R : The collection of five most renowned mathematicians of the world is not a set.
S : A collection of most dangerous animals of the world is a set

(1) 1
(2) 2
(3) 3
(4) 4

22) If n(A) = 20, n(P(B)) = 225 and n(A ∪ B) = 35 then n(A ∩ B) is (where n(X) represent number of
elements in set X and P(X) represents power set of X)

(1) 10
(2) 20
(3) 5
(4) 15

23) If A = {ϕ, { ϕ }, {{ ϕ }}}, then the number of proper subsets of the power set of A i.e. P(A) is

(1) 7
(2) 8
(3) 255
(4) 125

24) Number of subsets of {3, 5, 7, 9, 11, 13} are

(1) 32
(2) 62
(3) 64
(4) None of these

25) If (x, y ≥ 0, x ≠ y), then x : y

(1) 5 : 2
(2) 2 : 5
(3) 25 : 4
(4) 4 : 25

26) If then which of the following can be true

(1) a = 3, b = 11, c = 2
(2) a = 11, b = 2, c = 3
(3) a = 2, b = 3, c = 11
(4) a = 2, b = 11, c = 3

27) Let a, b, ∈ Q such that then which of the following is true?

(1)
is an integer

(2)
is irrational number
(3) is a rational number
(4) None of these

28) If A, B & C are three sets, such that A = {{}}, B = {{{}}}, C = {{{{}}}}, then which of the
following option(s) is(are) not true?

(1) A ⊆ B ⊆ C
(2) C ⊆ B ⊆ A
(3) A ⊆ C
(4) All of these

29) Let α =

then the value of α2 is

(1) 8
(2) 10
(3) 7
(4) 5

30) Number of natural solutions of the equation

is

(1) 1
(2) 2
(3) 3
(4) 4
 ANSWER KEYS

Physics

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. 2 2 2 3 1 3 4 3 2 4 2 1 4 1 3 1 3 2 4 3
Q. 21 22 23 24 25 26 27 28 29 30
A. 1 4 2 4 3 1 2 3 3 3

Chemistry

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. 1 3 2 2 3 1 2 4 3 2 1 3 1 1 3 3 3 2 1 3
Q. 51 52 53 54 55 56 57 58 59 60
A. 1 1 2 2 2 1 3 3 3 3

Mathematics

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. 3 2 3 3 2 4 1 3 4 1 3 2 1 2 2 4 4 1 3 2
Q. 81 82 83 84 85 86 87 88 89 90
A. 3 1 3 3 3 3 2 4 2 2
 SOLUTIONS

Physics

1)

2) =

3)

4) Resultant vector of A and B is

Unit vector in the direction of R is

5) (x-component)2 + (y-component)2 = 102

y - component = 6 units
it is either +y direction or —y direction.

6) Resultant of three vector can be zero if sum of magnitude of two smaller vector is less than
 of equal to the magnitude of largest vector.

7)

R2 = P2 + Q2 + 2PQcosθ ..... (1)

(2R)2 = (P)2 + (2Q)2 + 4PQ cos θ
4R2 = P2 + 4Q2 + 4pQcosθ ...(2)
4(P2 + Q2 + 2PQcosθ) = P2 + 4Q2 + 4pQcosθ
3p2 + 4pQcosθ= 0

cosθ = –

8)

OC = =

= = = 60m

9) =

θ = 30°
Angle between = 180° – 30° = 150°

10) As we know by vector Addition Law

Here we have drawn right angle triangle, as it is mentioned, resultant is perpendicular to

smaller vector.

Also, Given if , then

Angle between and is θ, a for calculating angle between vectors they should be joined tail
to tail or head to head.
Using Pythagoras theorem in above triangle
R2 + A2 = B2
R2 = B2 – A2
Now by vector addition law.
R2 = A2 + B2 + 2ABcosθ
B2 – A2 = A2 + B2 – 2ABcosθ
–2A2 = 2ABcosθ

11)
= Component in x- y plane
= Component in z-direction

|Component in x-y plane|

|Component in z-axis| = 10

∴ Ratio =

12)

Let that vector is . Then

13)

14)

15) can not be done.

16)

17)

5a2 + b2 = 50 ... (i)

cos (135) =
5a2 + 25 = 50
5a2 = 25
a=

18) Ans. (2)

(a)
(b) , vectors are forming closed polygon

(c)
(d)

19)

Use triangle Law

20)

θ = 60°

21)

22) AP = AB + BP = = ... (i)

AQ = AD + DQ = AD + = ... (ii) By eqs. (i) and

(ii), we get
23) By triangle law, AB = AD – BD, AC = AD – CD Therefore,
AB + AC + AD + AE + AF
= 3AD + (AE – BD) + (AF – CD) = 3AD
Hence, λ = 3 (∵ AE = BD, AF = CD)

24) We must have ;

Therefore,

or
or

or 315λ2 – 18λ = 0
If λ = 0, (not acceptable)

For

25)

or

Therefore, a + b =

26) We have,
Projection of v and u = Projection of w along u

⇒ ⇒ v.u = w.u ... (i)

Also, v and w are perpendicular to each other
∴ v.w = 0 ... (ii)
Now, |u – v + w| = |u| + |v| + |w|2 – 2 (u.v) – 2(v.w) + 2(u.w)
2 2 2

⇒ |u – v + w|2 = 1 + 4 + 9
⇒ |u – v + w| =

27) It is given that 2p + q =

and p + 2q =

⇒ and
Let θ be the angle between p and q then
∴ λ = cos θ =

28) Any vector perpendicular to both a and b = λ(a × b)

Now,

∴ Required vector =

29) We have, and

Let q be the ∠BAC, then

Now,
∴ |AB × AC| =

Hence,

30) Volume of the parallelopieped

 , ,

⇒ 3a2 – 1 = 0

At

∴ V is minimum at

Chemistry

31) The correct answer is option (A)

32) NaCl + H2SO4 → HCl + Na2SO4

2×
m1 = 685 gm.

33) Volume strength = 11.2 × molarity

⇒ molarity =
Assuming 1 litre solution;
mass of solution = 1000 ml × 1 g/ml = 1000 g
mass of solute = moles × molar mass
= 0.5 mol × 34 g/mol
= 17 gm.

⇒ mass% =

34)

mol kg–1

35)

Ca + 2C → CaC2 (50%)
2 3
Moles of CaC2 = 3/2 × 0.5 = 3/4
Moles of CaCN2 = 3/4
Moles of NH3 = 3/4
Molarity = 3/4 × 2 = 1.5 M

36) 100g of 109% oleum requires 9 gm of water for complete converion of SO3 into H2SO4. On
adding 6gm of water, the resulting 106g oleum is still requiring 3gm of water. Hence the new

labelling .
= 102.83%

37) Volume strength = M × 11.35

11.35 = M × 11.35
M=1

= 3.4%

38) H2SO4 + 2NaOH → Na2SO4 + 2H2O

0.1 × V 50 × 0.1 – –
0.1 × V – 2.5 5–5 2.5 5

= 0.05
0.1 V – 2.5 = 0.05 V + 0.05 × 50
(0.1 – 0.05)V = 2.5 + 2.5

V= = 100 ml

39) 10 ml 160 ml

CxHy(g) + → xCO2(g) + H2O(ℓ)

100 – 10 10 x
∵ Volume of CO2 = 10 x = 20 ⇒ x = 2

∵
∴y=2
∴ Volume of O2 consumed = 25 ml.

40)
30 ml 7 x 30 ml 6 x 30ml
Volume of reactants = 30 + 210 = 240 mL
Volume of products = 180 mL

41) Explain Question:

Identify the man of ozone produced.
Concept:
Stoichiometry.

Solution:
(A) 3O2 2O3

3 mol
= 67.2 lit = 14.4 gm

Final Answer: Option(1)

42)

80 → 4 × 80 = 320
CH4 + O2 → CO2 + 2H2O
120 – x → 120 – x

x→x
CO2 = 120 – x + 320 + x = 440 ml

43) Question Explanation:

Determine the volume of carbon dioxide (CO2) that reacted when passed over red-hot charcoal

Concept: Eudiometry

Solution:

Let x be the volume of CO2 reacted.

Initial volume: 500 ml (CO2)
Final CO2 volume:
Final CO volume: 2x ml
Total final volume equation:

Final Answer: Option (1)

44)

45)

(I) nf of HNO3 = , eq. wt. =

 (II) nf of H2O = 1, eq. wt. = M

(III) nf of (NH4)2 Cr2O7 = 6, eq. wt. =

(IV) nf of P4 = 3, eq. wt. =

46)

Question Explanation:
Balance the acidic redox reaction between permanganate and oxalate to find coefficients x,
y and z .

Concept:
Balancing redox via electron transfer.

Solution:
We use the ion-electron method for an acidic medium:

A. Oxidation half-reaction: C2O42– → 2CO2 + 2e–

B. Reduction half-reaction: MnO4– + 8H+ + 5e– → Mn2+ + 4H2O

To equalize electrons, multiply the oxidation half by 5 and the reduction half by 2, then add
them:

2MnO4– + 5C2O42– + 16H+ → 2Mn2+ + 10CO2 + 8H2O

Comparing this to the given equation:

A. x = 2
B. y = 5
C. z = 16

The water coefficient is given as z/2, and 16/2 = 8, which matches the balanced equation.

Final Answer: Correct option is (3)

47)

Compounds where oxidation state of central

atom ⇒ O.S. between min. & max.
⇓
Act as both
Oxidant, Reductant

48) Question Explanation:

Find oxidation state.

Concept:
This question is based on oxidation number.
Solution:
BaO2 + H2SO4 → H2O2 + BaSO4
Most E.N. element in the products is oxygen.
O.S. of oxygen are –2 in BaSO4 and –1 in H2O2.

Final Answer:
The correct option is (2).

49) for X3(YZ4)2, sum of oxidation no. is

50)
Each Nitrogen changes its O.N from -2 to +x

51)

Question Explanation: Find the expression for the equivalent weight of metal A based on its
displacement of metal B.
Concept: Equivalent weights react in equal proportions.
Solution:
According to the Law of Equivalence, substances react or displace each other in equal gram
equivalents.
Gram equivalents of A = Gram equivalents of B

To find the equivalent weight of , rearrange the formula:

Final Answer: Option (1)

52)

X2 X1 Molecular wt.
Y2 Y1 Equivalent wt.

53) H2O2 is getting reduced in reaction (A) and is getting oxidised in reaction (B).
So, H2O2 acts as oxidant in reaction (A) and reductant in reaction (B).
54) Explain Question:
Find in which compound, oxidation state of 'O' is maximum.

Concept:
Calculation of oxidation state.

Solution:

Final answer: Option (2)

55)

Note that: 1.013 bar = 1 atm

2Al + 2NaOH + 2H2O → 2NaAlO2 + 3H2
0.27 gm ↓

=
PV = nRT (for H2)

1 × V = × 0.01 × 0.0821 × 300

V = 0.369ℓ = 369 ml

56)

Total weight of the hydrocarbon mixture

= 112 gram
Total mole of
Mole of air required
Wt. of air required

Wt. of air required per gram of the hydrocarbon mixture

57) moles of glucose =

moles of H–atom = 5 × 10–3 × 12 = 0.06 moles
No. of H–atoms = (0.06 × NA)

(1) No. of H–atoms = = 0.006 × NA

(2) No. of H–atoms = = 0.03 × NA

(3) No. of H–atoms = = 0.06 × NA

 (4) moles of H–atoms = = 0.03 × NA

58) M.M of x3 = 2 × 48

Atomic mass of x = = 32

59) Volume of C2H5OH =

{mol. wt C2H5OH = 46}

70 ml.

60)

Mathematics

61) Explain question:

Finding the value of an algebraic expression. The given expression follows the pattern
(a2–ab+b2)(a+b). By recognizing this identify, we can simplify the multiplication to the sum of
two cubes.

Concept:
Algebraic Identify a3 + b3 = (a + b) (a2 – ab + b2).

Solution:
Let a = and .

This expression is
This matches (a2 – ab + b2) (a + b) = a3 +b3.

Value
Final answer: Option (3)

62)
63)
Subsequent rationalisation

A = 81,

64)

4x – 3x. 3-1/2 =

x=
Now 2x = 3

65) We know
If |x + y| = |x| + |y|
then x.y ≥ 0
so, from the given question, we can say
(x2 + 2) . (x + 1) ≥ 0
Since (x2 + 2) is always positive
so, (x + 1) ≥ 0
x ≥ –1

66)

(d)

67) x = 5 or |x – 5| = 1 ⇒ x = 6 or x = 4
x2 + 1 = 2x + 1
⇒ x = 0, x = 2

68)

69)
70) x = ⇒ x = 21/3 –1
p=2 q=3 r=1
p+q+r=6

71) Let

[Link] = 1

72)

= 1-x
(Put x2 = -1 to reduce till linear)
Method 2:
Put x2 = -1 assume R(x) = ax+b
see, a=-1 and b =1

73) (Reference to B.B-04, Question-01)

|x–1| + 2 ≤ 4
|x – 1| ≤ 2
When x ≥ 1
x–1≤2
x≤3
Hence, the solution is 1 ≤ x ≤ 3.
When x < 1
–(x – 1) ≤ 2
–1 ≤ x
Therefore, –1 ≤ x < 1.
Therefore, combined solution –1 ≤ x < 3.

74)

75) abcdef = log34.log45.log56.log67.log78.log89

= log39 = 2

76) A is not subset of B'

B is not subset of A.
A and B are not disjoint.
A ∩ B' is not ϕ.

77) (A) {3} ∈ A is wrong since there is no element 3 in set A

(B) {3,4} ∉ A is wrong since {3,4} ∈ A
(C) {3,4} is element of set A therefore
{3,4} is not subset of A hence wrong
(D) {{3,4}} ⊂ A correct.

78)

79) Clearly region is C – (A ∩ B)

80)

2m – 2n = 112
m = 7, 2m = 128
n = 4, 2n = 16
2m – 2n = 112

81) The Correct Answer is (C)

82) Explain Question:

Finding number of elements in (A ∪ B).

Concept:
Power set, principle of inclusion and exclusion.

Solution:
Given n(P(B)) = 225
⇒ B has 25 elements
i.e. n(B) = 25
Now n(A ∪ B) = n(A) + n(B) – n(A ∩ B)
⇒ n(A ∩ B) = 20 + 25 – 35 = 10

Final Answer: option(1)

83) No. of elements in P(A) = 23 = 8

So no. of proper subsets of P(A) = 28 – 1 = 255

84)

Number of elements in set = 6

∴ Number of subsets are = 26 = 64

85) 25 : 4

86) a = 2, b = 3, c = 11

87) is irrational number

88) All of these

89) 10

90) 2