24-05-2026

1001CJA101021260013 JA

PART-1 : MATHEMATICS

SECTION-I (i)

1) Consider f : [–1,1] → , , where [.] represents GIF, then

(A)
f is continuous at ,0,1

(B)
f is discontinuous at –1,0,

(C)
f is discontinuous at –1, ,0,
(D) f is continuous everywhere except 0

2) Let f(x) = dx. If , then f(1) is equal to

(A)

(B)

(C)

(D)

3) The value of λ for which the point (λ, 2) is the interior point of ΔABC formed by x + y = 4, 3x – 7y
= 8 and 4x – y = 31 is

(A)

(B)

(C)

(D)

4) If where λ,μ ∈ , then λ + μ is equal to

(A) 18
(B) 20
(C) 19
(D) 17

SECTION-I (ii)

1) Let f : R → R be a differentiable function satisfying . If f(0) = 1 and

f '(0) = –1, then which of the following is(are) correct ?

(A) f(|x|) is non-differentiable at one point

(B) Number of solution of the equation f(x) = f–1(x) is exactly one

(C)

(D) tan–1(f(x)) is derivable ∀ x ∈ R

2) and then
(Where C is constant of integration)

(A) I = tanx – tan–1x + C

(B) I = cot–1x + tanx + C
(C) J = tanx – secx + C

(D)

3) If LT, LN, LST and LSN denotes the lengths of tangent, normal, subtangent and subnormal
respectively of a curve y = f(x) at a point P(2009, 2010) on it then

(A)

(B)

(C)

(D)
= constant

4) The function f(x) = ax3 + bx2 + cx + d has its local minimum and maximum at x = –2 and x = 2
respectively. If 'a' is the root of the equation x2 – x – 6 = 0, then which of the following is/are true

(A) a2 + b2 = 4
(B) a2 + b2 = 8
(C) c = 24
(D) d ∈ R

5) If family of straight lines ax + by + c = 0 always passes through a fixed point , then

equation 36ax2 + 8bx + 2c = 0 has

(A) at least one root in [0,1]

(B)
at least one root in
(C) at least one root in [–1,2]

(D)
at least one root in

6) Consider f(x) = (x – 1) Identify which of the following statement(s)

is(are) correct ?

(A)

(B) f '(x) is increasing in [1,∞)

(C) f(x + 4) – f(x) > 2π, ∀ ∈ [1,∞)
(D) f(x + 4) – f(x) < 2π, ∀ ∈ [1,∞)

SECTION-III

1) If the tangent to the curve 4x3 = 27y2 at the point (3,2) meet the curve again at the point (a,b)
then (|a| + |b|) equals

2) If and (where K ∈ N), then value of K is

3) Let f be a function defined on R (set of all real numbers) such that f '(x) = 2018(x – 2019)3 (x –
2020)4(x – 2021)5 (x – 2022)6 for all x ∈ R. If g is a positive valued function defined on R such that f(x)
= ℓn(g(x)), for all x ∈ R. Then the number of points in R at which g(x) has a local minima is

4) f : R → (0,∞), f(x) is twice differentiable function such that f '(x) = x f(x) for x = 1,2,3,4 then find
minimum number of roots of the equation f(x). f "(x) = (f '(x))2 + (f (x))2

5) The fuel charges for running a train are proportional to the square of the speed generated in
km/hr and the costs Rs. 48/- per hour at 16km/hr. If the most economical speed when the fixed

charges are amount to Rs 300/- per hour is 'v' km/hr then value of is

6) If the angle between the pair of straight lines formed by joining the points of intersection of x2 +
y2 = 4 and y = 3x + c to the origin is a right angle, then is

7) If f : R → R, f(x) = 4x – cosπx; g : R → R, g(x) = x3 + 4x – cosπx. Then at x = –3 is

, then |λ| is

8) If the orthocentre of the triangle formed by the lines y = x + 1, y = 4x – 8 and y = mx + c is at

(3,–1), then m – c is

PART-2 : PHYSICS

SECTION-I (i)

1) Ring of mass “5kg” and radius 1 m is placed on a smooth incline plane. If the ring is in translatory

equilibrium find the mass of the block shown in diagram :-

(A) 3 kg
(B) 7.5 kg
(C) 10 kg
(D) This situation is not possible

2) Two uniform rods AB and CD, each of length ℓ and mass m are fixed to two gears (Which are
disc's of radius 2r and r pivoted to fixed points A and C respectively at same horizontal level) as
shown in figure. The system is in vertical plane. When rod AB is slightly rotated clockwise by a small
angle, rod CD rotates in the opposite sense (anticlockwise) by another small angle such that there is
no slipping and no dissipation of energy at the point of contact of the gears due to their teeth in
contact. Neglecting the mass of gears, find the time period of small oscillations of the system. [g is
acceleration due to gravity] [Consider cos θ = 1 – ..... neglecting higher terms]

(A)

(B)

(C)

(D)

3) A hollow spherical conductor having inner radius ‘a’ and outer radius ‘b’. A constant potential
difference is applied across inner and outer shell. Due to which current flows radially. Select the

correct statement :-

(A) Drift velocity remains constant​

(B) Drift velocity increases radially outward
(C) Drift velocity decreases radially outward
(D) Drift velocity first decreases then increases radially outward

4) An isosceles right angle triangle of side d is placed in a horizontal plane. A point charge q is
placed at a distance d vertically above from one of the corner as shown in the figure. Flux of electric
field passing through the triangle is:-

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) Two mirrors are inclined at an angle of 30°. One of the ray is incident parallel to the one of the
mirror. Then select the correct statement(s).

(A) Ray will undergo five reflections from the system

(B) Total deviation from the system will be 120°
(C) Ray will retrace it path finally
(D) Total deviation suffered by the ray will be 90°

2) In the connection shown in the figure the switch K is open and the capacitor is uncharged. Then
we close the switch and let the capacitor charge upto the maximum and open the switch again.

The values indicated by the galvanometer increases after closing the switch and then decreases
(A)
after opening the switch
Direction of current is same through the galvanometer before and after opening the switch
(B)
again
(C) After opening the switch again energy dissipation in R1 is zero
(D) After opening the switch again energy dissipation in R2 is zero

3) In the circuit shown in figure C1 = C2 = 2µF. Then at steady state charge stored in :
(A) capacitor C1 is zero
(B) capacitor C2 is zero
(C) both capacitors zero
(D) capacitor C1 is 40 µC

4) In Circuit-1 and Circuit-2 shown in the figures, R1 = 1 Ω, R2 = 2 Ω and R3 = 3 Ω. P1 and P2 are the
power dissipations in Circuit-1 and Circuit-2 when the switches S1 and S2 are in open conditions,
respectively. Q1 and Q2 are the power dissipations in Circuit-1 and Circuit-2 when the switches S1
and S2 are in closed conditions, respectively. Which of the following statement(s) is(are) correct?

(A) When a voltage source of 6 V is connected across A and B in both circuits, P1 < P2.
(B) When a constant current source of 2 Amp is connected across A and B in both circuits, P1 > P2.
(C) When a voltage source of 6 V is connected across A and B in Circuit-1, Q1 > P1.
(D) When a constant current source of 2 Amp is connected across A and B in both circuits, Q2 < Q1

5) In the circuit shown in figure :-

(A) power supplied by the battery is 200 watt

(B) current following in the circuit is 5A
 potential difference across resistance is equal to the potential difference
(C)
across resistance
(D) current in wire AB is zero

6) A conducting medium is shaped in a form of a quarter of an annulus of radii b and a (b > a) and
thickness t. Specific resistance of the medium is ρ. The correct option(s) is/are :-

Resistance between faces LMNO and PQRS is

(A)

Resistance between faces LMRS and ONQP is

(B)

Resistance between faces MRQN and LSPO is

(C)

(D) Between faces LMNO and PQRS and LMRS and ONQP, resistance is same

SECTION-III

1) A uniform L shaped rigid body AOB of mass 1kg, where AO = OB = and ∠AOB is a right
angle, is hinged to a smooth joint at Point A of the body and can swing freely in a vertical plane.
Initially, the body is released from rest with AB horizontal. The maximum kinetic energy of the body

is K Joule. The value of is :-

2) Point object O is as shown in diagram. At distance (x) an object is placed such that its final image

coincides with it. For this the value of x are n1 and n2 then find the value of .
3) A thin walled glass container is filled with water . A point source S is fixed inside water.
A thin equiconvex lens (µ = 1.5) and concave mirror are arranged with mutual separation R/2 as

shown in figure. If the distance of the source from the point A is , the separation between the
source and final image as seen by an observer at the position of S is nR/6, find n. All curved surfaces

of lens and mirror have radius of curvature R.

4) The amount of heat liberated when the switch S is shifted from position 1 to 2 is n × 10–4 J. Find n.

5) In the following circuit, switch S1 remains closed for a long time and switch S2 remains open. The
system reaches a steady state. Now we close switch S2 also, keeping S1 close. In the new steady state
the magnitude of change in charge on capacitor C2 of 2 µF is q µC. Find q.
6) Figure shows two concentric spherical shells having radii 1 m and 2 m respectively. Outer
spherical surface has charge –3.2 × 10–15 Coulomb. If inner surface is now earthed by closing the
switch then x × 10+y number of electron move towards earth, then (x + y) will be (x, y ∈ I, 0 ≤ x, y ≤

9).

7) Two identical conducting spheres of radius r separated far apart are joined through resistor R & a
switch S. Initially switch is open and one of the spheres is provided with a charge +Q0. Switch S is

closed at t = 0. If charge on sphere B at time is given by (where a & n are

constant), find the value of n.

8) If in steady state the energy stored in the capacitor (as shown in figure) is N × 10–8 J, then find the

value of N.

PART-3 : CHEMISTRY

SECTION-I (i)

1) A gas undergoes change from state A to state B. In this process , the heat absorbed and work
done by the gas is 5 J and 8 J, respectively. Now gas is brought back to A by another process during
which 3 J of heat is evolved. In this reverse process of B to A:-

(A) 10 J of the work will be done by the surrounding on gas.

(B) 6 J of the work will be done by the surrounding on gas.
(C) 10 J of the work will be done by the gas.
(D) 6 J of the work will be done by the gas.

2) Which of the following reaction is correct ?

(A)

(B)

(C)

(D)

3) In which of the following reaction hydrocarbon is formed as product-

(A)

(B)

(C)

(D)

4) Choose the option in which correct order is given according to indicated property

(A) Be < N < O < F : I.E1

(B) Be < B < N < O : Atomic radius
(C) Na < K < Rb : I.E2
(D) Tℓ > Ga > In : IE1

SECTION-I (ii)

1) Which of the following statement is INCORRECT :

(A) IUPAC name of [Co(en)3]2(SO4)3 is tris(ethane-1,2-diamine)cobalt(II) sulphate

(B) Iron(III)hexacyanidoferrate(III) has formula Fe[Fe(CN)6]
(C) Geometrical isomerism is possible in tetrahedral complex having formula [Mabcd]n±
(D) Optical isomers are mirror images that are superimposable on one another

2) In which of the following compounds, the underlined atom give monobasic acid on complete
hydrolysis ?

(A) ICl
(B) BCl3
(C) PCl3
(D) NCl3

3)
Select incorrect statement regarding product P.

(A) Product (P) on treatment with Br2/CCl4 gives meso product

(B) Product (P) on treatment with (i) B2H6/THF (ii) H2O/CH3COOH gives 1, 1-dimethyl cyclohexane
(C) Product (P) on reaction with (i) B2H6/THF (ii) H2O2, gives racemic mixture
(D) Product (P) on reaction with (i) Hg(OAc)2, H2O (ii) NaBH4, gives 1, 2-dimethylcyclohexanol

4) For the reaction sequence given below, the correct statement is/are-

(A) Product (P) can be formed when product (Q) react with Br2/CCl4
(B) Product (Q) can be formed when product (R) react with alc. KOH/Δ
(C) Iodocyclohexane can be formed when product (R) react with NaI/acetone
(D) Cyclohexa-1, 3-diene can be formed when product (P) react with EtO⊖/Δ (excess)

5) 3.00 mole of PCl5 kept in 1L closed reaction vessel was allowed to attain equilibrium at 380 K.
Calculate composition of the mixture at equilibrium.
PCl5(g) PCl3(g) + Cl2(g)

(A) [PCl5] = 1.41 M

(B) [PCl3] = 1.59 M
(C) [Cl2] = 1.41 M
(D) [Cl2] = 1.59 M

6) Consider the following 1st order reaction and the accompanying concentration time plot.
A4(g) → 4A(g)
Which of the following regarding decomposition reaction is/are correct?

[Given ln2 = 0.70, ln5 = 1.60]

(A) At 30 hr, 20% reaction is complete

(B) Half-life of the reaction is 105 hrs.
(C) Rate of decomposition of reactant decreases linearly with time.
(D) Changing initial concentration will change the time at which two curves intersect.

SECTION-III

1) Find the number of chemical species which are diamagnetic in nature.

O3, NO2, KO2, [PtCl4]2–, N2, Na2[Fe(CN)5NO]

2) If number of t2g and eg electrons are 3 and 2 respectively in hexa aqua complex of 3d series metal
ion M3+, If the atomic number of metal M is X, find the sum of digits for atomic number of X (Fill
your answer as sum of digits (excluding decimal places) till you get the single digit answer).

3) Select the species that are expected to appear colored due to absorption in the visible region. Also
determine the total number of such species :
(a) [Ti(H2O)6]Cl3
(b) [MnO4]¯
(c) [CrO4]2–
(d) [Cu(NH3)4]2+
(e) [Ni(NH3)6]2+
(f) [Zn(CN)4]2–

4) Pure gas ‘A’ was taken in a closed container at a initial pressure of 5 atm. The pressure in the
container changed due to following reactions

If the total pressure due to mixture of gases A, B, C and D was found to be 10 atm, in which partial

pressure due to gas C was 3 atm. Find KP for first equilibrium , in atm2 ?

5) In CCP unit cell, the largest sphere which may fit in a tetrahedral void has radius 100 pm, then
largest sphere which may fit in octahedral void of same unit cell without disturbing the lattice has

radius 'X' pm then find value of ? [Given, ]

6)
Number of HI consumed during the given reaction.

7)
Calculate total number of hyperconjugating structures (In which C-H bond involve) in major product-

8) The plot of log kf versus for a reversible reaction A(g) P(g) is shown.

Pre-exponential factors for the forward and backward reactions are

1015 s–1 and 1011 s–1, respectively. If the value of log K for the reaction at 500 K is 6, the value of | log
kb | at 250 K is ______.
[K = equilibrium constant of the reaction
kf = rate constant of forward reaction
kb = rate constant of backward reaction]
 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I (i)

Q. 1 2 3 4
A. B D A A

SECTION-I (ii)

Q. 5 6 7 8 9 10
A. A,C,D A,B,C,D B,C,D A,C,D A,B,C,D A,B,D

SECTION-III

Q. 11 12 13 14 15 16 17 18
A. 1 2 1 3 4 4 4 0

PART-2 : PHYSICS

SECTION-I (i)

Q. 19 20 21 22
A. B B C D

SECTION-I (ii)

Q. 23 24 25 26 27 28
A. A,C A,B,C B,D A,B,C A,C A,B

SECTION-III

Q. 29 30 31 32 33 34 35 36
A. 1 3 8 2 4 5 5 6

PART-3 : CHEMISTRY

SECTION-I (i)

Q. 37 38 39 40
A. B D B D

SECTION-I (ii)

Q. 41 42 43 44 45 46
A. A,C,D A,B A,B A,B,C,D A,B,D A,B
 SECTION-III

Q. 47 48 49 50 51 52 53 54
A. 4 8 5 9 4 5 6 5
 SOLUTIONS

PART-1 : MATHEMATICS

1)

f(–1) = ; f(–1+) = 0
discontinuous at x = –1

f(0) = 0 ; f(0+) = 0, f(0–) = –1

⇒ discontinuous at x = 0

⇒ discontinuous at

2)

Let 3 – x2 = t2
+x dx = –t dt

c=0

3)
Equation of DE is y = 2
so, point of intersection

and

4)

Put x = 1 + h

6 + λ – μ = 0 and
λ + μ = 18

5) ...(1)
Differentiate (1) w.r.t. x keeping y constant

⇒ f(x) = –x + c (Given f(0) = 1)

⇒ f(x) = –x + 1
(A) f(|x|) is not differentiable at x = 0
(B) f(x) = f–1(x) are equal ∀ x ∈ R

(C)
(D) tan–1 (f(x)) = tan–1(1 – x) is derivable ∀ x ∈ R

6)
7)

⇒ (1 – 2010) (1 + 2011) = –2009.(2011)

8) Let f(x) = ax3 + bx2 + cx + d

f(x) is min. at x = –2 and max. at x = 2
⇒ a < 0 ⇒ a2 – a – 6 = 0
a = 3, –2 (a = 3 is rejected)
f(x) = –2x3 + bx2 + cx + d
f '(x) = –6x2 + 2bx + c = –6(x2 – 4)
b = 0, c = 24, d ∈ R

9)

ax + by + c = 0 passes through
⇒ 3a + 2b + 2c = 0
Let f '(x) = 36ax2 + 8bx + 2c
f(x) = 12ax3 + 4bx2 + 2cx + d
f(x) is continuous & differentiable

f(0) = d, a+b+c+d=d

f(0) = ⇒ at least one root in

10)

⇒ f(x) is increasing function

f ''(x) > 0
⇒ f(x) is increasing function ∀ x ≥ 1

Using LMVT in [x, x+4], x ≥ 1

for c ∈ (x, x+4)

∴ f(x + 4) – f(x) < 2π ∀ x ∈ [1, ∞)

11)

12)
⇒ aby + ay2 + xy = xb + xy
⇒ k=2

13)

∴ g(x) = ef(x) ⇒ g'(x) = ef(x).f '(x) ∀ x ∈ R

⇒ g'(x) = ef(x) [2018.(x – 2019)3.(x – 2020)4.(x – 2021)5.(x – 2022)6]
∵ f '(x) changes its sign from negative to positive in the neighbourhood of x = 2021
⇒ f(x) has local minima at x = 2021
so, the number of local minima is one.

14)

Consider
H(1), H(2), H(3), H(4) = 0 by Rolle's Theorem

has atleast 3 roots in (1, 4)

15)

Fuel charges per hour = kv2 ⇒ 48 = k.162

⇒ Fuel charges per hour =

Charges per hour =

Expenses of journey =
where v = speed s = distance

maximum occures when

(∵ ax + , a, b > 0, x > 0, has minimum when ax = )

v2 = 16.100
v = 40

16) x2 + y2 – 4(1)2 = 0

(use principle of homogenisation)

 (coefficient of x2 + coeff. of y2 = 0)

17)

...(i)
–1
Again f (f(x)) = x

at x = –1, (f–1(–3))' = ...(ii)

f–1 (–1) =
f(0) = –1
but g(0) = –1
g–1(–1) = 0

(g–1(g(x)))' =

at x = 0, (g–1(g(0)))' =

...(iii)
Using equation (ii), (iii), in (i)

We get

18)
Solve line PQ & QR

Point

...(i)

∵
⇒ Slope of line QR (m) = 0
 Put value of m in equation (1)

so m – c = 0

PART-2 : PHYSICS

19)
T = mg sin θ; T = 30
a = 6 rad/sec2
acceleration of block is 6
10 m – T = 6m
m = 7.5

20) mg cos θ – mg cos2θ +

= constant

= constant

= constant

= constant

= constant
(angular SHM equation)

(angular frequency)2 =

T=

21) Explain Question:

A hollow spherical conductor carries radial current between inner radius a and outer radius b.
Check how drift velocity varies with radius.
Concept: This question is based on microscopic ohm's law
Solution:

I = nq A vd ⇒
For radial flow in a sphere:
A = 4πr2
So,

As r increases from a to b:
• Area increases
• Drift velocity decreases
Final answer: Option (3)

22)

flux =

23)

24)

Correct answer is (A,B,C)

25)

Correct answer is (B,D)

26) Case (I)
When both switches are open equivalent resistance in circuit 1

Equivalent resistance in circuit 2

For voltage source

⇒ P2 > P1 (Option (A) correct)

For constant current source
P = ι2R
P∝R
⇒ P1 > P2 (Option (B) correct)
Case-II
When switch is closed

For voltage source

(Option (C) correct)

and
For current source P ∝ R
Q1 < Q2
Final Answer : The correct option is (1),(2),(3)

27)

Correct answer is (A,C)

28)

Correct answer is (A,B)

29) Kmax = ΔU
Kmax = Uf – Ui

K = Kmax =

=
K=

30) Case (1)

x = 30 cm
Case (2)

Now Case (1)

exactly at same point

Case (2)

at same distance along the principal-axis but height is opposite.

31)
Correct answer is (8)

32)

Correct answer is (2)

33)
Initial steady state, when S1 is closed and S2 is open.

Qa = 15 × Ceq = = (15)
Final steady state, when both S1 & S2 are closed

Qb = 15 × (Ceq) = 15 × = 12 µC
change in charge on C2

= Qa – = 10 – 6 = 4 µC

34)

x+y=5

Q = 1.6 × 10–15

n= = 1 × 104
x=1
y=4

35) At any time to let charge on spheres be (Q0 – q) & q

 ∴

solving equation (i) we have

Q=

36) ΔV = 0.2 V

U=

=
= 6 × 10–8 J

PART-3 : CHEMISTRY

37) State change from A to B, qAB = +5 J & WAB = –8J (work done by gas)
So ΔUAB = qAB + WAB = 5 – 8 = –3J
ΔUAB = –3J
Now gas is back brought to A from B
qBA = –3J (Heat evolved)
wBA = ?
ΔUBA = –ΔUAB
qBA + wBA = – ΔUAB
–3J + wBA = –(–3J)
wBA = 6J (work done by surrounding)

38)

39)

40)

Question Explanation : Identify the correct given order

Concept: Periodic trends in properties

 Solution:
Option 1: IE₁ generally increases across a period, but Be > B and N > O anomaly exists; so
order Be < N < O < F is incorrect
Option 2: Atomic radius decreases across a period; correct order is Be > B > N > O, so given
order is incorrect
Option 3: IE2 does not increase down the alkali metal group; it actually decreases, so order is
incorrect
Option 4: Due to lanthanide contraction , IE of Tℓ increases. Hence, order is Tℓ > Ga > In

41) Question Explanation: Identification of incorrect statements about coordination

compounds.
Concept: IUPAC Naming and Isomerism in Complexes.
Solution: Statement 1 is wrong as the counter ion should be named "sulfate," not
"trisulphate." Statement 3 is incorrect because all four positions in a tetrahedron are adjacent,
meaning geometrical isomerism is not possible. Statement 4 is false because optical isomers
must be non-superimposable mirror images.
Correct Name: Tris(ethane-1,2-diamine)cobalt(III) sulfate.
Tetrahedral Geometry: All bond angles are 109.5°, preventing cis/trans forms.
Chirality: Optical activity requires non-superimposability.
Final Answer: Option (1, 3, and 4)

42) Question Explanation: Identifying compounds where the central atom forms a monobasic
acid.

Concept: Hydrolysis of Halides and Interhalogens.

Solution: Hydrolysis involves the reaction of a compound with water to form oxoacids. A
monobasic acid is one that releases only one H+ ion per molecule.

A. ICl: Iodine (less electronegative) forms hypoiodous acid (HOI), which is monobasic.

(HOI is monobasic)

A. BCl3: Boron forms boric acid (H3​BO3​). Although it has three -OH groups, it acts as a monobasic
Lewis acid by accepting one OH− from water.

is monobasic)

A. PCl3: Forms phosphorous acid (H3​PO3​), which is dibasic.

(Dibasic)

NCl3 forms NH3 which is a base

43)
(A)

(B)

(C) + Enantiomer

(D)

44)

(A)

(B)
(C)

(D)

45)

The correct answer is option (A), (B), (D)

46)

At 30 hr, a – x = 4x ⇒ x = ,i.e. 20% A4 decomposed.

K × 30 = ⇒ t1/2 = ≈ 105 hr

47) Total number of dimagnetic species is = 4

O3, [PtCl4]2–, N2, Na2[Fe(CN)5NO].
Total number of pagamagnetic species is = 2
NO2, KO2

48)

Explain Question:
Finding the atomic number of a metal from its d-orbital distribution.

Concept:
Crystal Field Splitting in Octahedral Complexes.

Solution:
In an octahedral complex (like hexa aqua), the d-orbitals split into levels. The
problem states there are 3 electrons in t2g and 2 electrons in eg.
This gives a total of 3 + 2 = 5 electrons in the d-subshell for the M3+ ion.
Since M3+ has a d5 configuration, the neutral metal atom M must have 3 more electrons.
Calculation:
Configuration of M3+ : [Ar]3d5
Configuration of M : [Ar]3d6 4s2
Total electrons in M = 18(Ar) + 6(d) + 2(s) = 26.

Final Answer: 8
49)

Explain Question :
Identify which d-block complexes show absorption in visible light.

Concept :
D-d transitions in partially filled d-orbitals & charge transfer phenomenon allow visible
absorption.

Solution :
• [Ti(H2O)6]3+ →Ti3+is d1 d-d transition absorbs in visible region
• [MnO4]¯→ Colour due to charge transfer → absorbs visible visible region
• [CrO4]2– → Colour due to charge transfer → absorbs in visible region
• [Cu(NH3)4]2+ → Cu2+is d9 d-d transition absorbs in visible region
2+ 2+ 8
• [Ni(NH3)6] → Ni is d d-d transition absorbs in visible region
2- 2+ 10
• [Zn(CN)4] → Zn is d no d-d transition colourless

Complexes absorbing in visible range: a, b, c,d,e → Total = 5

Final answer: Option (5)

50) Question Explanation:

Question is asking about KP for first equilibrium , in atm2

Concept:
This question is based on simultaneous equilibrium.
Solution:

PT = 10
5 – x + x + y + 2x – y + y = 10
y + 2x = 5 .......(i)
2x – y = 3 .....(ii)
y = 1, x = 2

Kp = =
Final Answer: 9

51)

52)
53)

, have 6 hyperconjugating structures

54)

Keq =

At 500 K 106 = ⇒ Kb = 103

We know log Kb = log Ab –

3 = 11 –
(Ea)b = 8 × R × 500 × 2.303

log K250 – 3 = 8 × 500 ×

log K250 = –5
|log K250| = 5