SUBJECT : CHEMISTRY
In which of following solution, liquid is solute 5 mL of 1N HCl, 20 mL of N/2 H2SO4 and 30
and solid is solvent ? mL of N/3 HNO3 are mixed together and volume
(1) Amalgam of Hg with Na made to one litre. The normality of the resulting
solutions is :-
(2) Copper Dissolved in gold
(1) N (2) N (3) N (4) N
(3) Solution of hydrogen is paladium 5 10 20 40
(4) All of these Select the incorrect statement among the
following.
10 mL concentrated H2SO4 (18 M) is diluted to
1 litre. Normality of diluted acid is :- (1) Different gases have different KH values at
the same temperature
(1) 0.18 N (2) 0.09 N
(2) The value of KH for a gas decreases with
(3) 0.36 N (4) 18 N increase of temperature
At what temperature, the molarity and molality (3) Higher the value of KH at a given pressure,
of pure water are equal :- the lower is the solubility of the gas in a
(1) 100°C (2) 277 K liquid
(3) 298 K (4) At all temperature (4) Mole fraction of a gas in the solution is
If the mole fraction of solute is 0.3 in an proportional to the partial pressure of the
aqueous solution then molality of the solution is gas over the solution
(1) 30.8 m (2) 23.8 m The solubility (in mole fraction) of a gas X in
benzene at 298K under pressure 760mmHg is
(3) 24.5 m (4) 2.8 m (Henry's law constant for the gas X at 298K is
The normality of 4% (mass/vol.) NaOH is :- 7.6×105 mm Hg)
(1) 0.1 N (2) 1.0 N (1) 1×10-4 (2) 0.1
(3) 0.05 N (4) 0.01 N (3) 1×10-2 (4) 1×10-3
Which among the following concentration terms A solution is a mixture of A and B. Mole
is independent of temperature ? fraction of A in solution phase is, xA = 0.4. Find
the mole fraction of A in vapour phase:
(1) Molarity (2) Molality
(Given : PºA = 100 mm of Hg, PºB = 200 mm of
(3) (w/v)% (4) Normality Hg)
(1) 0.4 (2) 0.8 (3) 0.25 (4) 1.2
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Solutions A, B, C and D are respectively 0.1 M The vapour pressure of the solution of two
glucose, 0.05 M NaCl, 0.05 M BaCl2 and 0.1 liquids A(pº = 80 mm) and B(pº = 120 mm) is
M AlCl3. Which one of the following pairs is found to be 100 mm when xA = 0.4. The result
isotonic? shows that
(1) A and B (2) B and C (1) solution exhibits ideal behaviour
(3) A and D (4) A and C (2) solution shows positive deviations
Which one is not equal to zero for an ideal (3) solution shows negative deviations
solution (4) solution will show positive deviations for
(1) Smix lower concentration and negative deviations
(2) Vmix for higher concentrations.
(3) If T1 , T2 and T3 are boiling points of
P = Pobserved – PRaoult
component A, component B and azeotropic
(4) Hmix mixture then which of the following relation is
Mixture of volatile components A and B has correct for a minimum boiling azeotrope :-
total vapour pressure (1) T1 < T3 (2) T2 < T3
P = 254 – 119 XA
(3) T3 < T1 (4) T3 = T2
Where XA is mol fraction of P°A in mixture.
Then values of P°A and P°B will be respectively Which of the following aqueous solutions has
(1) 254, 119 (2) 119, 254 the highest freezing point assuming solution is
very dilute?
(3) 135, 254 (4) 154, 119
(1) 0.1 M KNO3 (2) 0.2 M Na3PO4
On mixing 10mL of acetone with 40mL of
chloroform the total volume of the solution is (3) 0.25 M FeCl3 (4) 0.01 M Na2SO4
(1) < 50mL (2) > 50 mL The rise in the boiling point of a solution
containing 1.8 g of glucose in 100 g of solvent is
(3) = 50 mL (4) Can't be predicted
0.1°C. The molal elevation constant of the
solvent is :
(1) 0.01 K/m (2) 0.1 K/m
(3) 1 K/m (4) 10 K/m
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Freezing point of an aqueous solution is ( – Acetic acid exists in benzene solution in dimeric
0.186)ºC. Elevation of boiling point of the same form. In an actual experiment the Van't Hoff
solution is (Kf = 1.86°C, Kb = 0.512°). factor was found to be 0.52. The degree of
(1) 0.186°C (2) 0.0512°C association of acetic acid is
(3) 0.092°C (4) 0.02372°C (1) 0.48 (2) 0.88
When 36.0 g of a solute having the empirical (3) 0.96 (4) 0.52
formula CH2O is dissolved in 1.20 kg of water, Two solute X and Y separately dissolved in
the solution freezes at – 0.93°C. What is the water to form two solutions. Both solution have
molecular formula of the solute ? same B.P. and have same % w/w concentration.
(Kf = 1.86°C kg mol – 1) :- If Van't Hoff factor of X is more than Van't Hoff
(1) C3H6O3 (2) C2H2O2 factor of Y then-
(3) C2H4O3 (4) C2H4O2 (1) Molar mass of X and Y are equal
The size of a raw mango shrinks to a much (2) Molar mass of X is higher than Y
smaller size when kept in a concentrated salt (3) Molar mass of X is lower than Y
solution. Which one of the following processes
can explain this? (4) Both solution have same molality
(1) Dialysis (2) Diffusion
(3) Reverse osmosis (4) Osmosis
The relationship between osmotic pressures (
) at a definite temperature when
1 g glucose, 1 g urea and 1 g sucrose are
dissolved in 1 litre of water is :
(assume i = 1 for all) :
(1) (2)
(3) (4)
Assuming 100% ionisation, which of the
following has same van't Hoff factor as
K4[Fe(CN)6]?
(1) CaSO4 (2) Al2(SO4)3
(3) CaCI2 (4) AICI3
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