10-08-2025

2001CJA101021250028 JA

PHYSICS

SECTION-I

1) A particle of mass m and charge q, moving with velocity V enters Region II normal to the
boundary as shown in the figure. Region II has a uniform magnetic field B perpendicular to the plane
of the paper. The length of the Region II is L. Choose the correct choice(s)

(A)
The particle enters Region III only if its velocity V >

(B)
The particle enters Region III only if its velocity V <

(C)
For , the time spent by particle in region-II is less if V is more
(D) Time spent in Region II is same for any velocity V as long as the particle returns to Region I

2) Consider the following statements regarding a charged particle in a magnetic field. Which of the
statements are true ?

(A) Starting with zero velocity, it accelerates in a direction perpendicular to the magnetic field
(B) While deflecting in magnetic field its energy gradually increases
Only the component of magnetic field perpendicular to the direction of motion of the charged
(C)
particle is effective in deflecting it
(D) Direction of deflecting force on the moving charged particle is perpendicular to its velocity

3) A conducting rod PQ of length 8L is rotated about a point O at distance 3L from P, in a uniform

magnetic field directed into the paper. Then

(A)

(B)

(C)

(D)

4) A metal rod moves at a constant velocity in a direction perpendicular to its length. A constant
uniform magnetic field exists in space in a direction perpendicular to the rod as well as its velocity.
Select the correct statement(s) from the following

(A) The entire rod is at the same electric potential

(B) There is an electric field in the rod
(C) The electric potential is highest at the centre of the rod and decreases towards its ends
(D) The electric potential is lowest at the centre of the rod and increases towards its ends

5) The figure shows three long straight current carrying conductors. The straight parts are long and

the circular part in each case in of a complete circle. Let Ba, Bb and Bc represents the strength

of field at the centre O in the three cases, then

(A)

(B)

(C)

(D)

6) An electron moves along the line XOX' which lies in the same plane as the square loop of
conducting wire as shown. The direction of induced current, if any in the loop is

(A) Clockwise as electron moves from X to O

(B) Anticlockwise as electron moves from X to O
(C) Clockwise as electron moves from O to X'
(D) Anticlockwise as electron moves from O to X'

SECTION-II

1) A current of 30 A flows through an overhead power cable in horizontal direction. The magnitude
of magnetic field at a point 5 m below the cable is find n

2) A proton and an alpha particle are separately projected in a region where a uniform magnetic
field exists. The initial velocities are perpendicular to the direction of magnetic field. If both the
particles move around magnetic field in circles of equal radii. Find the ratio of momentum of proton

to alpha particle :

3) The magnetic field due to a current carrying circular loop of radius 3 cm at a point on the axis at a
distance of 4 cm from the centre is 2.7 μT. What will be the value of magnetic field at the centre of
the loop (in μT)

4) Three planar rings, each of radius R, are placed mutually perpendicular to each other and each
having its centre at the origin of co-ordinate system. Current I is flowing through each ring. If

magnitude of the magnetic field at the common centre is found to be equal to then what is
value of N?

5) A rectangular loop with a sliding connector of length l = 1.0m is situated in a uniform magnetic
field B = 2T perpendicular to the plane of loop. Resistance of connector is R = 2Ω. Two resistances
of 6Ω and 3Ω are connected as shown in figure. Find the external force (in Newtons) required to
keep the connector moving with a constant velocity v = 2ms–1.

6) Figure shows a conducting loop in shape of a trapezium carrying a current i = 1.5A. Find the

magnetic field B (in µT) at a point P. It is given that a = 10 cm.

 SECTION-III

1) Solenoid 2 has twice the radius and six times the number of turns per unit length as solenoid 1.
Find the ratio of the magnetic field in the interior of 2 to that in the interior of 1. Assume thin and
long ideal solenoid.

2) The magnetic flux linked with a coil satisfies the relation , where t is the
time in second. The resistance of the coil is 7Ω. Find the charge flown through the coil (in Coulombs)
from t = 0 to t = 2 seconds.

3) A 3MeV proton is moving parallel to a uniform magnetic field of 5 T. Find the force on the proton
(mass of proton = 1.6 x 10–27 kg)

4) A non-conducting circular disk record of radius R, which carries a uniformly distributed charge Q,
is rotating with constant angular speed ω. The magnetic field at the center of the disk is given by

. Find value of n.

5) An infinite uniform current carrying wire is kept along z-axis, carrrying current I0 in the direction
of the positive z-axis. OABCDEFG represents a circle (where all the points are equally spaced),

whose centre at point (4m, 0 m) and radius 4 m as shown in the figure. If in S.I.

unit, then find the value of k.

6) Six wires of current I1 = 1A, I2 = 2A, I3 = 3A, I4 = 1A, I5 = 5A and I6 = 4A cut the page
erpendicularly at the points 1, 2, 3, 4, 5 and 6 respectively as shown in the figure. If the magnitude

of the integral around the closed path is Nμ weber.m–1 , then find N

 CHEMISTRY

SECTION-I

1) Select the correct statement(s) regarding reaction of SO2 with PCl5.

(A) It is a redox reaction.

(B) One of the product is sulphuryl chloride.
(C) Both the products on addition of water produce strongly acidic solutions.
(D) Both the products have same hybridisation of central atom.

2) Which of the following is/are incorrect ?

(A) Both S8 and S6 molecules have crown shape structure.

(B) Magnetic property of S2 molecule is same as ion.

(C) Rhombic sulphur is insoluble in water but soluble in CS2.
(D) Both α and β sulphur have crown shape structure.

3) Two solutions S1 and S2 containing 0.1M NaCl(aq.) and 0.08M BaCl2(aq.) are separated by
semipermeable membrane. Which among the following statement(s) is/are correct -

(A) S1 and S2 are isotonic

(B) S1 is hypertonic and S2 is hypotonic
(C) S1 is hypotonic and S2 is hypertonic
(D) Osmosis will take place from S1 to S2

4)
But-1-ene is obtained as major product when :

(A) (G) is –F

(B)

Base is

(C)

(D) (G) is –Cl & base is [Link], Δ

5) Choose the correct statements among the following.

(A)
will react more readily than for SN2 reaction

(B)
will react more readily than for SN2 reaction

(C)

will react more readily than for SN2 reaction

(D)

will react more readily than for SN2 reaction

6) Rate of SN2 depends on :

(A) Concentration of Nucleophile

(B) Concentration of substrate
(C) Nature of leaving group
(D) Nature of solvent

SECTION-II

1) Dissolving 1.24 g of white phosphorous in boiling NaOH solution in an inert atmosphere gives a
gas Q. The amount of CuSO4 (in g) required to completely consume the gas Q is ______.
[Given : Atomic mass of H = 1, O = 16, Na = 23, P = 31, S = 32, Cu = 63]

2) How many grams of sucrose ([Link]. = 342) should be dissolved in 100 gm water in order to
produce a solution with 105°C difference between the boiling point and freezing point temperature,
at 1 atm?
(Unit: Kf = 2 [Link] mol–1 ; kb = 0.5 [Link] mol–1)

3) 560 gm, 2m Urea solution when kept at temperature which is 5°C below its freezing point, then
half of the solvent freezes out. Calculate the weight(in gm) of solvent freezes out if the same solution
is placed at temperature 15°C below its freezing point

4) How many compounds are more reactive than towards SN2 reactions ?
5)

The number of times where SN2 reaction taken place in above reaction sequence in polar aprotic
solvent

6) Product mixture.
Number of possible alkenes formed in product mixture.

SECTION-III

1) How many of following interhalogen compounds do not exist ?

IF, ICl3, ClBr3, IBr3, BrI5, BrCl3, FCl3, CIF, IF7

2) Total number of P—H bonds in cyclotetrametaphosphoric acid.

3) The number of reactions gives SO2 gas :

(a) Cu + conc. H2SO4
(b) Zn + dil. H2SO4
(c) NaI + conc. H2SO4
(d) FeS2 + O2
(e) NaHSO3 + dil. H2SO4
(f) H2SO4 + PCl5

4) How many of the following are electrophiles ?

(a) CH4 (b) H+ (c) (d) :CH2 (e) NH3

(f) BH3 (g) (h) H2O (i)

(j) SO3

5)

For the given reaction 44

4
The total number of possible products formed by tertiary carbocation of A is _______.

6) Aromatic compound.
Find value of x:

MATHEMATICS

SECTION-I

1)

The value of the integral is equal to

(A) cot–1(e–x)+c
(B) log (ex – e–x)+c
(C) tan–1 (ex) + c
(D) tan–1 (e–x)+c

2)

The volume of a cube is increasing at a rate of 9cm3/s. How fast is the surface area increasing when
the length of an edge is 10cm ?
(A) 3.6 cm2/s
(B) Less than 4 cm2/s
(C) More than 4 cm2/s
(D) 6 cm2/s

3) For the curve C : y = e2x cosx, which of the following statement(s) is/are true ?

(A) equation of the tangent where C crosses y-axis is y = 3x + 1

(B) equation of the tangent where C crosses y-axis is y = 2x + 1

(C)
number of points in where tangent on the curve C is parallel to x-axis is 4.

(D)
number of points in where tangent on the curve C is parallel to x-axis is 2.

4) The curve y – exy + x = 0 has vertical tangent at point

(A) (1,1)
(B) at no point
(C) (0,1)
(D) (1,0)

5) equals -

(A)

(B) sin2x + c
(C) – cos2x + c

(D)

6) If then, is equal to

(A) ln |x| – p(x) + c

(B) ln |x| + p(x) + c
(C) x – p(x) + c
(D) x + p(x) + c

SECTION-II

1) Let f : R → R, be a function defined by f(x) = ; where [x] is greatest integer function.

Also, g(x) = (x + 1)(x + 2)(x + 3). Now, the value of , is

2) If the slope of line through the origin which is tangent to the curve y = x3 + x + 16 is m, then the
value of m is equal to

3) If where g(x) is a rational function, c is

constant of integration then find the value of 20|g(2)|.

4) Value of

5) The value of the integral is

6) is equal to :

then value of k is-

SECTION-III

1) If

2) If f(x) is a continuous function such that f(x) ≥ 0 ∀ x ∈ [1, 12] and , then find f(9)

3) Evaluate the following integrals :

4) The slope of the tangent to the curve x = a(θ – sinθ), y = a(1 – cosθ) at point θ = π/2 is-
5)

6) Evaluate the following integrals :

 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6
A. A,C,D C,D B,C,D B A,B,D B,C

SECTION-II

Q. 7 8 9 10 11 12
A. 1.20 0.50 12.50 1.73 2.00 7.50

SECTION-III

Q. 13 14 15 16 17 18
A. 6 4 0 2 8 1

CHEMISTRY

SECTION-I

Q. 19 20 21 22 23 24
A. C,D A,B C,D A,B,C A,C,D A,B,C,D

SECTION-II

Q. 25 26 27 28 29 30
A. 2.37 to 2.41 68.40 375.00 5.00 3.00 6.00

SECTION-III

Q. 31 32 33 34 35 36
A. 3 0 4 7 5 3

MATHEMATICS

SECTION-I

Q. 37 38 39 40 41 42
A. A,C A,B B,D D A,B,C A

SECTION-II

Q. 43 44 45 46 47 48
A. 54.00 13.00 4.00 0.00 2.00 40.00
 SECTION-III

Q. 49 50 51 52 53 54
A. 1 0 2 1 0 2
 SOLUTIONS

PHYSICS

1)

Radius of circular path is mv/qB

2)

A> Magnetic field can not increase speed of a charged particle.

B> Since magnetic field never changes speed thus no change in energy
C> Since this component can make it in circular path.
D> Since motion is circular so force (centripetal force) will be perpendicular to it's velocity.

3)

EMF in a rotating rod is BωL2/2

4)

A uniform electric field develops in the rod due to magnetic force on the charges

5)

Standard formulae for magnetic field of a circular arc and finite wire

6)

By using Lenz's law

7) Magnitude of the magnetic field is given by

8)

Radius of circular path is mv/qB

9)

Concept : Biot-Savart law

At Center

10)

Vector addition of magnetic fields

11)

Motional EMF in the conductor is BLv

12)

13) B = µ0ni

14)

Charge flown = Change in flux/resistance

15)

Since angle between velocity and field is zero

16)

Standard result of magnetic field of a rotating disc

17)
 B at point P =

18)

By using Ampere's law

CHEMISTRY

19) SO2 + PCl5 → SOCl2 + POCl3

No change in oxidation number of any element. So, not a redox reaction.
SOCl2 is thionylchloride; SO2Cl2 is sulphuryl chloride.
POCl3 + H2O → H3PO4 + HCl
} strongly acidic solutions
3
Both the products have sp hybridisation of central atom.

20) → S8 has crown shape while S6 has chair shape.

→ S2 molecule is paramagnetic while ion is diamagnetic.
→ α and β sulphur have S8 molecules which have crown shape.
→ a sulphur is insoluble in water while soluble in CS2.
So option (A) and (B) is incorrect.

21)

For solution S1;

π1 = C1RT × i; C1 = 0.1 M
i = 1 + (n – 1)α;
NaCl → Na+ + Cl⊝; n = 2; α = 1 (assuming 100% dissociation)
⇒ i=2
⇒ π1 = 0.1 × RT × 2 = 0.2RT
for solution (2);
BaCl2 → Ba2+ + 2Cl⊝; n = 3; α = 1 (assuming 100% dissociation)
i=3
⇒ π2 = (0.08)RT × 3 = 0.24RT
π2 > π1 ⇒ S2 is hypertonic as compound to S1

22) Elimination reaction when leaving group is –F & follows Hoffman’s rule.
& Elimination reaction with bulky base also follows Hoffman’s rule.

23) (a) For SN2 1° RX reacts faster.

(b) For SN2 RBr reacts as faster rate as Br is better leaving group.
(c) Same reason as ‘a’.
(d) Aryl halides react slowly than RX towards nucleophilic substitution reaction.

24)

Rate of SN2 reaction depends upon :

(I) Con. of nucleophile
(II) Nature of substrate
(III) Nature of leaving group
(IV) Nature of solvent

25) Mole of P4 =
P4 + 3NaOH + 3H2O → PH3 + 3NaH2PO2
0.01 mole 0.01 mole
2PH3 + 3CuSO4 → Cu3P2 + 3H2SO4

0.01 ⇒ × 0.01

= moles

= 2.385 gm
Ans. = 2.38 or 2.39

26) ΔTf + ΔTb = 5 = (Kb + kf)m

5 = 2.5 ×

W= = 68.40

27) For the given solution ΔTf = 2 × Kf ....(A)

560gm solution contains 1 mole urea & 500gm solvent. On placing solution at temperature 5ºC
below its freezing point then

(ΔTf + 5) = ....(B)
from (A) & (B)
Kf = 5/2
ΔTf = 5
If the same solution is placed at temperature 15ºC below its freezing then
ΔTf + 15 = Kf × m
(5 + 15) =
(Wt)solvent = 125 gm
weight of solvent freezes out = (500 – 125) = 375 gm

28)

primary, allylic and benzylic bromides and iodides react faster

29)

30)
All the products are showing G.I.
∴ 6 possible alkene are formed as a product.

31) Compounds ClBr3, BrI5 and FCl3 do not exist. Because of small size the central atom than
surrounding atoms and high electronegativity
d-orbital contraction does not take place and hence participation of d-orbitals in hybridisation
is prevented

32) Total number of P—H bonds in cyclotetrametaphosphoric acid.

P—H; Bonds = 0
P—OH Bonds = 4
 33) (a) Cu + conc. H2SO4 CuSO4 + SO2 + H2O
(b) Zn + dil. H2SO4 ZnSO4 + H2
(c) NaI + H2SO4 NaHSO4 + I2 + SO2 + H2O
(d) 4FeS2 + 11O2 2Fe2O3 + 8SO2
(e) NaHSO3 + dil. H2SO4 NaHSO4 + SO2 + H2O
(f) H2SO4 + PCl5 SO2Cl2 + 2POCl3 + 2HCl

34)

7 (b, c, d, f, g, i, j)
Electron pair acceptors are electrophile so species must have vacant p or d orbitals.

35)

36) Conceptual

MATHEMATICS

37)
Let

38) Let x be the length of side, V be the volume and S be the surface area of the cube. Then
V= x3 and S = 6x2, where x is a function of time t.
39)
y = e2x = cosx
At x = 0 : y = 1
y' = 2e2x cosx + e2x (–sinx)
At x = 0 : y' = 2 ⇒ T : y – 1 = 2 (x – 0)
⇒ y = 2x + 1
for tangent parallel to axis :
y' = 0 ⇒ 2e2x cosx – e2x sinx = 0
⇒ tanx = 2

∴ 2 solution in

40) y – exy + x = 0

for vertical tangent

x = 1, y = 0

41)

Option A is correct

; – cos2x + C
or

; sin2x + C
⇒ So option (ABC)

42) = p(x) then

 = = log |x| – p(x) + c

43)

(put x – 1 = t)

44)

⇒ x1 = 2 and y1 = 26

45)

46)

As function is odd so =0

47)
48)

let

49)

50)
hence f(x) = 0
hence f(9) = 0

51)

Put
52)

53)

Using Queens
Answer

54)

Using kings and adding.