28-07-2025

2031CJA101021250001 JA

PHYSICS

SECTION-I(i)

1) All the wires on the front and the back hexagonal face of the Skelton hexagonal prism have
resistance R. All the wires along the lines joining the vertices of two hexagons have resistance 2R. A
battery is connected between P & Q. Here PZOQXY is front face and UTS RWV is back face.

(A) Current through VY and TZ is zero.

(B) Current through PZ and QX are equal in modulus
(C) Current through OS & YV are equal in modulus.

(D)
Equivalent resistance across PQ is .

2) In the circuit shown in figure, E1 and E2 are two ideal sources of unknown emfs. Some currents
are shown. Potential difference appearing across 6Ω resistance is VA - VB = 10V. Choose correct

options.

(A) The current in the 4.00 Ω. resistance between C & B is 5A.

(B) The unknown emf E1 is 36 V.
(C) The unknown emf E2 is 54 V.
(D) The resistance R is equal to 9 Ω

3) Several α particles of different speeds enter a uniform magnetic field coming and confined
into a cylindrical region. If all the α particles enter the field radially, then choose the correct
option(s).

(A) Faster is the particle, lesser is the time spent in magnetic field.
(B) Slower is the particle, lesser is the time spent in magnetic field.
(C) Slower the particle, greater is the time spent in magnetic field.

(D)
Time spent by particle which have speed v is t

4) There is an infinite current carrying wire shown in the figure. A charge q is projected with
velocity parallel to the wire from point M. After some time particle passes through the

point P with velocity . Choose the correct option(s):

(A) given velocity at P is not possible

(B) given velocity at P is possible.
(C) radius of curvature at M is greater than radius of curvature at P.
(D) Workdone by magnetic force is zero.

5) Let denote the dimensional formula of the permittivity of the cacuum and that of the
permeability of the vacuum. If M = mass, L = length, T = time and A = electric current,

(A)
(B)
(C)
(D)

6) A steady current flows through the conductor of variable cross-sectional area. Now select the

correct options.
(A) The value of current is same through the cross-section 1,2 and 3.
(B) The current density is the maximum at the cross-section (3)
(C) The drift velocity is greater at the cross-section (1)
(D) The electric field is maximum at the cross-section (3)

7) In a balanced wheat stone bridge, current in the galvanometer is zero. It remains zero when

(A) battery emf is increased

(B) all resistances are increased by 10 ohms
(C) all resistances are made five times
(D) the battery and the galvanometer are interchanged

8) In the diagram shown, in steady state

(A) Charge on 1 μF capacitor is 1 μC

(B) Charge on 2 μF capacitor is 2 μC
(C) Charge on 3 μF is zero
(D) Potential difference across 2 μF capacitor is 2 volt

SECTION-I(ii)

Common Content for Question No. 1 to 2

Three infinitely long thin wires, each carrying current I in the same direction, are in the xy-plane of
a gravity free space. The central wire is along the y-axis while the other two are along x = ±d .

1) The locus of the points for which the magnetic field B is zero is . Find n

(A) 3
(B) 6
(C) 9
(D) 12

2) If the central wire is displaced along the z-direction by a small amount and released, it
will execute simple harmonic motion. If the linear mass density of the wires is λ, then natural

frequency of oscillation is . Find n.

(A) 1
(B) 6
(C) 5
(D) 7

Common Content for Question No. 3 to 4

A wire loop carrying a current I is placed in the x-y plane as shown in figure. Radius of circle is NP =

3) If a particle with charge +Q and mass m is placed at the centre P and given a velocity v along NP

(see figure), its instantaneous acceleration is . Find n

(A) 0.11
(B) 0.12
(C) 0.18
(D) 0.20

4) If an external uniform magnetic field is applied, the torque acting on the loop due to
this field is xIa2B. Find x

(A) 0.67
(B) 0.68
(C) 0.61
(D) 0.96

SECTION-II

1) In the situation shown in figure, the switch is at position 1 for long time and now it is shifted from
position 1, to position 2 at t = 0. The current in the 3 Ω resistor at t = 3 2 seconds is found to be x

ampere. Find the value of x.

2) A capacitor is charged by using battery in four steps. 1st it is charged to voltage and

maintained for a charging time T >> RC. Then voltage is raised to without discharging the
capacitor and again maintained for time T >> RC. The process is repeated two more time to
reach voltage V0 & the capacitor is charged to final voltage V0. If in this process total energy

dissipated across resistance is where C is capacitance, find N.

3) What should be value of R (in Ω.) for which power dissipated through 'R' is maximum?

4) A conductor lies along the z axis at m and carries a fixed current of 10.0 A in the -z
direction. Magnetic field is present everywhere (x is in metres). Find
the magnitude of average power in Watt required to move the conductor at constant speed to x =
2.0 m, y = 0 in 5 x 10-3 s. Assume parallel motion along the x axis, (e-0.4 = 0.67)

5) As shown in figure, a hollow cone and a hemispherical shell are joined together. Mass of each is 2
kg and combined body is rotating about its axis with angular speed 200 rad/sec. 3 Coulomb charge is
uniformly distributed over the entire surface. Find magnetic dipole moment (in Am2) of the system if
R = 20 cm and h = 40 cm.

6) As shown in figure there is a wire in sinusoidal shape carrying a current of 1A is placed in a

uniform magnetic field of strength . [Given ]. Then find the net force (in

N) on the wire.

CHEMISTRY

SECTION-I(i)

1) Which of the following undergo disproportionation on heating?

(A) H3PO3
(B) H3PO4
(C) Na2SO3
(D) NaOCl

2)
Select the correct statement(s) about (P) ?

(A) (P) is orange coloured

(B) (P) is coloured due to ligand to metal charge transfer (LMCT)
(C) (P) on heating gives coloured gas
(D) (P) produces amphoteric substance on thermal decomposition

3) Identify the correct statements regarding phosphorus compounds :

(A) The solution of PH3 in water decomposes in present of light given red phosphorus and H2.
(B) White phosphorus on reaction with sulphuryl chloride gives S2Cl2.
(C) Hypophosphoric acid, on exposure with water gives phosphonic acid as one of the product.
(D) PCl5, a yellowish white powder, reacts with Ag(powdered) to give PCl3 and AgCl.

4) Pick the correct statements, regarding reaction of ozone :

(A) It reacts with solid KOH, to give two paramagnetic products.

(B) It reacts with solid KI in acidic medium to give a product which undergoes disporportionation.
(C) It reacts with solid iodine to give I2O5, which is used in quantitative estimation of CO.
Both conc HNO3 and ozone reacts with aq. iodine respective to give same oxidised form of
(D)
iodine.

5) In the following reaction three products [P], [Q], [R] are obtained
The approximate experimental yields of the three compounds were 64%, 33% and 3% respectively.
Choose the CORRECT option(s) among the following

(A)
R is

(B)
Q is

(C)
R is

(D)
P is

6)

(A) One of the product shows optical isomerism

 Major product contains even number of α-hydrogens (hydrogens which can involve in
(B)
hyperconjugation)
(C) One of the product shows geometrical isomerism
(D) One of the product have degree of unsaturation is 6

7) In the following reaction reactant(s) [Q] is/are

(A)

(B)
(C)

(D)

8) When P and Q treated with C₂H5OK in C₂Н5ОН

(A) P give cis-2-butene without loss of deuterium

(B) P give trans-2-butene with loss of deuterium
(C) Q give trans-2-butene without loss of deuterium
(D) Q give cis-2-butene with loss of deuterium

SECTION-I(ii)

Common Content for Question No. 1 to 2

The reaction of Cl2 gas with cold dilute and hot concentrated NaOH in water give sodium salt of two
(different) oxoacids of chlorine P and Q respectively. The Cl2 gas reacts with SO2 gas , in presence of
charcoal to give a product R. R reacts with white phosphorous to give a compound S. On hydrolysis,
S gives as oxoacid of phosphorous T.

1) P and Q, respectively, are the sodium salts of -

(A) Hypochlorus and chloric acid

(B) Hypochlorus and chlorus acid
(C) Chloric and perchloric acids
(D) Chloric and hypochlorus acids

2) R, S and T , respectively are -

(A) SO2Cl2, PCl5 and H3PO4

(B) SO2Cl2, PCl3 and H3PO3
(C) SOCl2, PCl3 and H3PO2
(D) SO2Cl2, PCl5 and H3PO4

Common Content for Question No. 3 to 4

E1 is a two-step elimination reaction involving a carbocation intermediate, favored by weak bases,

tertiary substrates, and polar protic solvents.
E2 is a one-step, concerted reaction requiring a strong base, with no carbocation formation. It’s
favored by strong bases, and the transition state requires anti-periplanar geometry.

3) Identify the [P]

(A)

(B)
(C)

(D) All of these

4) The major product of the following reaction is

(1)

(2)

(3)

(4)

(A) 1, 4
(B) 2, 3, 4
(C) 1, 2, 3
(D) All

SECTION-II
1) PCl5 is an oxidiser as well as a chlorinating agent. How many moles of P–Cl(bonds) are there in
products formed, when 1 mole of H3PO3 reacts with excess PCl5 ?

2) When ozone reacts with an oxide of chlorine (unable to get dimerised), a product (X) is formed,
which on hydrolysis, gives two products (Y) & (Z). Find the sum of Cl–O bond order in the anionic
parts of (Y) and (Z) molecules.

3) Find the number of diprotic acids in which covalent bond is present between two identical atoms.
H2S2O5, H2SO5, HNO4, H4P2O6, H3PO5, N2O4, H4P2O8, H2S2O4, H4P2O7, H2N2O2

4) If X is molecular weight of the major organic product obtained in the given reaction then what is

X /7.

5) How many of the following are polar-Aprotic solvent

H2O, CH3OH, AcOH, CS2, CCl4, THF, DMF, Dioxane

6)

If the degree of unsaturation in compound A is (x) and Number of π-bond in compound B is y. Then
find (x + y) is _____?

MATHEMATICS

SECTION-I(i)
1) The integral dx is equal to:

(A) –1/2
(B) 1/4
(C) 1/2
(D) –1/4

2) If and , then M2011 is -

(A) 101005M
(B) 101005N
(C) 102010M
(D) 102011M

3) Let {1, 2, 3}, be the 3 × 3 matrix such that

(A) M is invertible

(B)
There exists a nonzero column matrix such that

(C)
The set Where O =
(D) The matrix (M–2I) is invertible, where I is the 3 × 3 identity matrix

4) If where a, b, c N, (a > b > c ),

Then (where C is constant of integration)

(A) a + b = 39
(B) a + b = 52
(C) a + b + c = 57
(D) b – c = 8

5) If A and B are two square matrices of same order such that their product AB is a null matrix then

(A) det. A ≠ 0 ⇒ B must be a null matrix.

(B) det. B ≠ 0 ⇒ A must be a null matrix.
(C) If none of A and B are null matrices then atleast one of the two matrices must be singular.
(D) If neither det. A nor det. B is zero then the given statement is not possible.
6) Let A and B be two 3 × 3 matrices such that AB = BA. Further, if A ≠ B4 and A2 = B8, then-

(A) det (A + B4) = 0

(B) det (A + B4) ≠ 0
(C) There exist a 3 × 3 matrix C such that (A + B4)C is null matrix
(D) There exist a non zero 3 × 3 matrix C such that(A + B4)C is null matrix

7) The integral is equal to

(A)

(B)

(C)

(D)

8) If , then

(A) I is an irrational number

(B)
(C) I = 3.72
(D) I is a rational number

SECTION-I(ii)

Common Content for Question No. 1 to 2

Consider the system AX = B, where

1) Sum of elements of (adjA) B is -

(A) –1
(B) 2
(C) –2
(D) –4

2) Value of tr(XBT) is (where tr(A) denotes trace of matrix A) -

(A) 0
(B) 1
(C) 2
(D) 3

Common Content for Question No. 3 to 4

Let ƒ(x) = |sinx|, g(x) = |cosx|, (ƒ(x) + g(x)) dx, (ƒ(x) – g(x)) dx

3) Which of the following statement is incorrect ?

(A) ƒ(x) + g(x) is even function as well as periodic function

(B) ƒ(x) – g(x) is odd function as well as periodic function
(C) I1 is an even integer
(D) h(x) = I2 is an odd function

4) If ƒ(x) dx , then is

(A) 4
(B) 2

(C)

(D)

SECTION-II

1) For α, β, γ ∈ R –{0} , let & . If Tr(A) = Tr(B) then

the value of is

2) If where C is the constant of integration

and g(1) = 1 then (g'(1) + g"(1) + k) is equal to :
3) Valuate the integral sin−1 dx is __________

4) If =A

ln +D

(where D is integration constant and A, B, C ∈ I) then the value of is

5) If and A is a matrix such that A–1B = B–1 and KA–1 = 2B–1 + I where K is some
scalar then value of K is

6) If ƒ(1 – x) + ƒ(1 + x) = 2 ∀ x ∈ R. Then value of , is -

 ANSWER KEYS

PHYSICS

SECTION-I(i)

Q. 1 2 3 4 5 6 7 8
A. B,C,D A,B,C,D A,C,D A,C,D B,C A,B,D A,C,D B,C

SECTION-I(ii)

Q. 9 10 11 12
A. A A A C

SECTION-II

Q. 13 14 15 16 17 18
A. 1.38 8.00 3.00 2.97 7.00 4.00

CHEMISTRY

SECTION-I(i)

Q. 19 20 21 22 23 24 25 26
A. A,C,D A,B,D A,C,D A,D B,C,D A,B,C,D C,D A,B,C,D

SECTION-I(ii)

Q. 27 28 29 30
A. A A B C

SECTION-II

Q. 31 32 33 34 35 36
A. 12.00 3.41 to 3.42 4.00 8.00 3.00 7.00

MATHEMATICS

SECTION-I(i)

Q. 37 38 39 40 41 42 43 44
A. D A B,C B,C,D A,B,C,D A,C,D A A,B

SECTION-I(ii)

Q. 45 46 47 48
A. C A B B
 SECTION-II

Q. 49 50 51 52 53 54
A. 3.00 34.00 1.65 or 1.66 0.50 2.00 2.00
 SOLUTIONS

PHYSICS

1) Compressing the hexagonal box and folding about the line PQ, the circuit is reduced as
shown in the figure (ii).

Now, let a battery is connected between point P and Q as shown in the figure (iii) and its
equivalent is shown in the figure (iv).
Applying KVL in loop 1

2)
After redrawing the circuit.
(a) I4 = 5A
(b) From loop (1) to (1)
-8(3) + E1 - 4(e) = 0 ⇒ E1 = 36 volt
From loop (2) to (2)
+ 4(5) + 5(2) - E2 + 8(3) = 0
E2 = 54 volt
(c) From loop (3) to (3)
-2R - E1 +E2 = 0

- 36 = 9Q

3)
POAC in cyclic quadrilateral

4) Word done by magnetic force is zero.

speed = constant

I2 + I2 + I2 = a2 + b2 + 32
a2 +b2 = - 6 ⇒ not possible
RoC

Vm = Vp
Bm < Bp
rm < rp

5) Refer Class Notes

6) As current remains same for all crosssectionbut current density J = I/A changes and drift
velocity I = neAVd and electric field

7) Refer wheatstone bridge topic in your class notes.

8)
I = A1
1 μF & 3μF capacitors are shorted hence have no charge p.d. across 2μF
V = 3I - 2I
V = 1 Volt
q = cV
q = 2μC

9)
Let magnetic field is zero on line (z = 0) and x = x. Then magnetic field on this line due to
wires 1 and 2 will be along negative z-axis and due to wire 3 along positive z-axis. Thus
B1 + B2 = B3

This equation gives

10)

The components of F along x-axis will be cancelled out. Net resultant force will be
towards negative z-axis (or mean position) and will be given by

If z << d . then ; z2 +d2 = d2 and Fnet = -

Negative sign implies that Fnet is restoring in nature
Therefore,
i.e. the wire will oscillate simple harmonically.
Let a be the acceleration of wire in this position and X is the mass per unit length of this wire
then

11) Magnetic field at P due to arc of circle.

Subtending an angle of 120° at centre would be
Now, velocity of particle can be written as

12) In uniform magnetic field, force on a current loop is zero. Further, magnetic dipole
moment of the loop will be,
M = (IA)
Here, A is the area of the loop.

13)
14)

15) Maximum power transfer theorem Rext = Rin

16) -2.97 W

The field moves the conductor, and therefore the work is negative. The power is given by

17)

Moment of inertia of combined body,

 18)

y = Asinπx

CHEMISTRY

19)

(i) XeF4 + 2SF4 → Xe +

(ii) XeF6 + 3H2O → XeO3 + 6HF
(iii) 6XeF4 + 12H2O → 2XeO3 + 4Xe + 24HF + 3O2
(iv) XeF6 + H2O + F⊝ + Xe + O2 + H2 O

20)

Produdtcts are Cr2O3, N2 and H2O

21)

PCl5 is good chlorinating agent

22)

(A) O3 + KOH → KO3 + O2 + H2O

(D) HIO3
23) (A)
Because alkyl halide is 3°

(B)
2° alkyl halide and polar aprotic solvent favour SN2 reaction

(C)
2° alkyl halide and polar aprotic solvent favour SN2 reaction.

(D)
So, (B), (C), (D) are correct.

24) Basic concept of SN1 and SN2

25)

26) Product is CH2=CH–CH=CH2

value of x = 2
value of y = 4
value of z = 3

27) Cl2 + 2NaOH (dil. & cold) → NaCl + NaOCl + H2O

5Cl2 + 6NaOH (conc. & hot) → 5NaCl + NaClO3 + 3H2O

28)
29)
Total brominated products 9.
out of which four enantiomeric pair
Total 5 fractions are obtained on fractional distillation of product mixture

30) 10 intermediate free radicals

So 10 structural isomeric products are formed and total products including stereoisomers are
33.
31)

3PCL5 + H3PO3 → 3POCl3 + PCl3 + HCl

32)

O3 + ClO2 → Cl2O6 HClO3 + HClO4

–
ClO3 ⇒ B.O = 1.66
ClO4– ⇒ B.O. = 1.75
Total = 1.66 + 1.75 = 3.41 or 3.42

33)

H2S2O5
H2SO5
H2S2O4
H2N2O2

34) (i) II, III, IV, V, VI

(ii)
This reaction is SN2 reaction and it's T.S. is pentacoordinate.
Optical rotation may or may not be –14° because optical rotation is compounds natural
property.
Hence ABC are incorrect and C is correct.
 35)

End-symmetric molecule of (A)

36) x = 2, y = 5

MATHEMATICS

37) I =

38)

= 101005 M
39) |M| = –1 + 1 = 0 Þ M is singular so non-invertible

(B)

and infinite solutions exists [B] is correct.

Option (D)

⇒ [D] is wrong
Option (C) :

x+ y + z = 0
x+z=0
y=0
∴ Infinite solution
[C] is correct

40)

a = 39
b = 13 c=5 now check.

41) (A) AB = 0
pre multiply A–1
A–1AB = A–1 × 0
B=0
(B) simillarly
(C) Assume A as non singular
AB = 0
pre multiply with A–1
A–1AB = A–10
B = 0 which is contradiction
Hence A must be singular
(at least one of A or B)
(D) AB = 0
|AB| = |0| ⇒ |A| = 0 or |B| = 0

42) (A– B4) (A + B4) = 0 ...(1) ∵ AB = BA

4 4
⇒ |A – B | |A + B | = 0
Now if |A + B4| ≠ 0 ⇒ A – B4 = 0 by (1) which is not possible ∴ |A+ B4| = 0
also A – B4 is a non zero matrix
which is like matrix C for which (A + B4)C = 0
so A,C,D are correct.

43)

44)
apply king & add
esecx = t

45) C11 = 2 – 2 = 0 C21 = – 4 C31 = 2

C12 = – (4 – 3) = –1 C22 = 5 C32 = –3
C13 = – 4 – 3 = 1 C23 = 1 C33 = –1

sum of elements = –2 ⇒ option (c)

46) AX = B ⇒ X = A–1 B
= –1 –1 = –2

∴ tr (XBT) = 0 ⇒ option (A)

47) ƒ(x) + g(x) = |sinx| + |cosx| ⇒ even as well as periodic

ƒ(x) – g(x) = |sinx| – |cosx|
⇒ even as well as periodic

I2 = 0

48)

49) Tr(A) = α2 + β2 + γ2, Tr(B) = 2α + 2β + 2γ – 3

As given Tr(A) = Tr(B)
⇒ α2 + β2 + γ2, = 2α + 2β + 2γ – 3
⇒ (α – 1)2 + (β – 1)2 + (γ – 1)2 = 0
⇒α=β=γ=1

So

50)
g(1) = 1
differentiate both side

Assume g(x) ax2 + bx + c

g(1) = a + b + c = 1
substitute g(x) & g’(x) in eqn
by solving eqn

51) dx = dx
put x = sin θ
I=2 2 θ sin θ d θ + 2 (π − 2 θ) sin θ dθ
=− +

52)
Let, e–x + x e–x + cos x = t

B = 1, C = 1, A = –1

= 0.50

53) A–1B = B–1 .... (1)

(A–1B)–1 = (B–1)–1 [Taking Inverse].
B–1A = B
BB–1A = B2

A = B2 ⇒ ∴ A =

A=
Now KA–1 = 2B–1 + I
KA–1B = 2I + IB
KA–1B = 2I + B [From (1)]
KB–1 = 2I + B
KI = 2B + B2

K=2
K=2

54) ∵ ƒ(1 – x) + ƒ(1 + x) = 2

Put x = 1 – x
ƒ(x) + ƒ(2 – x) = 2