Sessio Boar Test Syllabu T. O.
Subject Class Test date
n d # s marks marks
CHEMISTR 2nd January 24,
JAN RWP 04 Ch# 10 45
Y year 2025
SECTION-A
Q1. Choose the correct option.
(17x1=17)
No Question A B C D
i. Alkyl halides are prepared by
NH3 P 2O 5 PH3 PCl3
reacting alcohols with
ii. Which of the following cannot
All can be
be obtained by the direct R-Cl R-Br R-I
prepared
reaction of alkane with X2
iii. The common name of 2- Ter. Butyl Iso. Butyl n-butyl Sec. butyl
Methyl-2-chloropropane is chloride chloride chloride chloride
iv. Primary alcohol is obtained
by treating Grignard Reagent HCHO CH3CHO CH3COCH3 CO2
with
v. Grignard reagent is reactive presence of presence of polarity of non-polar
due to the halogen atom Mg atom C-Mg bond nature
vi. Ethyl magnesium bromide
Ethane Methane Propane n-Butane
reacts with water to form
vii In primary alkyl halides, the
. halogen atom is attached to a
carbon which is further 1 2 3 4
attached to how many carbon
atoms.
viii When CO2 is made to react
. with ethyl magnesium iodide, Propanoic
Propane Propanal Propanol
followed by acid hydrolysis, acid
the product formed is
ix. Which compound shows
C2H6 C2H5Cl CH3-O-CH3 C2H5OH
hydrogen bonding
x. Which of the following is
PCl3
called Lucas chlorinating PCl5 ZnCl2+HCl All of these
reagent
xi. The alkyl group of Grignard
Carbonium
reagent Free radical Carbanion None
ion
acts as
xii. SN1 reaction is favored by bulky group
on the
carbo
small groups
n
on the
atom
non-polar carbon
attac None
solvents. attached to
hed
the halogen
to the
atom
halog
en
atom.
xiii Which of the following Alkyl
. halide is R–F R – Cl R – Br R–I
more reactive.
xiv In dihalogen derivatives, if
. two halogen atoms are
Vicinal
attached to adjacent Gem-dihalide Both None
dihalide
carbons, the compound is
known as a
xv. The active substance present Westerin Chloropicrin Chloretone None
in tear gas is
xvi Which of the following alkyl
CH3CH2CH2C
. halides is hydrolysed by SN1 CH3Cl CH3CH2CI (CH3)[Link]
I
mechanism?
xvii The best Grignard’s Reagent
. CH3MgI C2H5MgBr C3H5MgCl C2H5MgCI
with respect to reactivity is
SECTION-B
Q2. Write short answers to the following questions.
(6x2=12)
(i) How does CH3MgI react with the Cyanogen chloride and water.
(ii) Why tertiary alkyl halides do not show substitution reaction by SN2 mechanism.
(iii) How alkyl iodides are prepared.
(iv) How will you convert CH4 to CH3-COOH.
(v) How carboxylic acids are prepared using Grignard reagent?
(vi) Why Ethyl alcohol is liquid while Ethyl chloride is gas at room temperature?
SECTION-C
Q3. Write detailed answers of the following.
(8x2=16)
a) Discuss in detail the mechanism of SN2 reactions.
b) Using ethyl bromide how would you prepare
(i) primary alcohol (ii) Secondary alcohol (iii) Ter. alcohol
Q4.
a) Compare the relativity of alkyl halides. With respect to bond energy and bond polarity.
b) Complete the following reaction
4 CH3-CH2-Cl + NH3