Quizrr Chapter-Wise Test for JEE Main - 2025

Q.1

1.04 gmL−1 ) of potassium chloride,

Calculate the boiling point of a one molar aqueous solution (density =
Kb for water = 0.52 kg mol−1 . Atomic mass of K = 39, Cl = 35.5
​

(A) 107.28∘ C
(B) 103.68∘ C
(C) 101.078∘ C
(D) None of these

Q.2

The mole fraction of water in 20% aqueous solution (By weight) of H2 O2 is

​ ​

77
(A) 68 ​

68
(B) 77 ​

20
(C) 80 ​

80
(D) 20 ​

Q.3

A weak electrolyte, AB, is 5% dissociated in aqueous solution. What is the freezing point of a 0.100 molal
aqueous solution of AB ? Kf for water is 1.86 deg/molal .
​

(A) −3.8∘ C
(B) −0.1953∘ C
(C) −1.7∘ C
(D) −0.78∘ C

Q.4

Which has maximum vapour pressure

(A) HI
(B) HBr
(C) HCl
(D) HF @IITJEE_Advanced
Q.5

The molal freezing point constant for water is 1.86 K molality−1 . If 342 g of cane sugar (C12 H22 O11 )
​ ​ ​

are dissolved in 1000 g of water, the solution will freeze at

(A) −1.86∘ C
(B) 1.86∘ C
(C) −3.92∘ C
(D) 2.42∘ C

Q.6

Y g of non - volatile organic substance of molecular mass M is dissolved in 250 g benzene. Molal elevation
constant of benzene is Kb . Elevation in its boiling point is given by
​

(A) KMY ​

b ​

4 Kb Y
(B)
​

M
​

(C) K4M
bY​

(D) KMbY​

Q.7

The values of observed and calculated molecular weights of silver nitrate are 92.64 and 170 respectively. The
degree of dissociation of silver nitrate is

(A) 60%
(B) 83.5%
(C) 46.7%
(D) 60.23%

Q.8

The amount of ice that will separate on cooling a solution containing 50 g of ethylene glycol in 200 g water
to −9.3∘ C is [Kf = 1.86 K molality −1 ]
​

(A) 38.71 g
(B) 38.71 mg
(C) 42 g
(D) 42 mg

Q.9

@IITJEE_Advanced
The freezing point of aqueous solution contains 5% by mass urea, 1.0% by mass KCl and 10% by mass of
glucose is
−1
(KfH2 O = 1.86 K molality
​
​ )
(A) 290.2 K
(B) 285.5 K
(C) 269.93 K
(D) 250 K

Q.10

Elevation in b.p. of an aqueous urea solution is 0.52∘ . (Kb ​

= 0.52∘ mol−1 kg ).
Hence, mole-fraction of urea in this solution is

(A) 0.982
(B) 0.0567
(C) 0.943
(D) 0.018

Q.11

Ratio of ΔTb /Kb of 6% AB2 and 9% A2 B (AB2 and A2 B both are non-electrolytes) is 1
​ ​ ​ ​ ​ ​ mol/kg
in both cases. Hence, atomic masses of A and B are respectively:

(A) 60, 90
(B) 40, 40
(C) 40, 10
(D) 10, 40

Q.12

Osmotic pressure of insulin solution at 298 K is found to be 0.0072 atm. Hence, height of water column
due to this pressure is [ given d(Hg) = 13.6 g/mL]

(A) 0.76 cm
(B) 0.70 cm
(C) 7.4 cm
(D) 76 cm

Q.13

What is the osmolarity of a 0.20 M KCl solution?

@IITJEE_Advanced
(A) 0.10 osmol
(B) 0.20 osmol
(C) 0.30 osmol
(D) 0.40 osmol

Q.14

Total vapour pressure of mixture of 1

mol of volatile component A (PAo = 100 mmHg) and 3 mol of
​

volatile component B(PBo = 60 mmHg ) is 75 mm. For such case:

​

(A) there is positive deviation from Raoult's law

(B) boiling point has been lowered

(C) force of attraction between A and B is smaller than that between A and A or between B and B
(D) all the above statements are correct

Q.15

Which statement is true for solution of 0.020 M H2 SO4 ​ ​

(A) 2 litre of the solution contains 0.020 mole of SO2−

4 ​

(B) 2 litre of the solution contains 0.080 mole of H3 O+ ​

(C) 1 litre of the solution contains 0.020 mole H3 O+

​

(D) None of these

Q.16

25 mL of an aqueous solution of KCl was found to require 20 mL of 1 M AgNO3 solution when titrated
​

using a K2 CrO4 as indicator. Depression in freezing point of KCl solution with 100% ionization will be:
​ ​

[kf = 2.0∘ mol−1 kg and molarity = molality ]

​

(A) 5.0∘
(B) 3.2∘
(C) 1.6∘
(D) 0.8∘

Q.17

A solution containing 30gms of non-volatile solute in exactly 90 gm water has a vapour pressure of
21.85 mm Hg at 25∘ C. Further 18 gms of water is then added to the solution. The resulting solution has a
vapour pressure of 22.15 mm Hg at 25∘ C. Calculate the molecular weight of the solute

(A) 74.2
@IITJEE_Advanced
(B) 75.6
(C) 67.83
(D) 78.7

Q.18

For 0.1 M solution, the colligative property will follow the order
(A) NaCl > Na2 SO4 > Na3 PO4 ​ ​ ​ ​

(B) NaCl < Na2 SO4 < Na3 PO4 ​ ​ ​ ​

(C) NaCl > Na2 SO4 ≈ Na3 PO4 ​ ​ ​ ​

(D) NaCl < Na2 SO4 = Na3 PO4 ​ ​ ​ ​

Q.19

The freezing point of equimolal aqueous solution will be highest for

−
(A) C6 H5 NH+
​

3 Cl (aniline hydrochloride)
​ ​

(B) Ca (NO3 )2 ​ ​

(C) La (NO3 )3 ​ ​

(D) C6 H12 O6 (glucose)

​ ​ ​

Q.20

Which one of the following statements is False

(A) The correct order of osmotic pressure for 0.01 M aqueous solution of each compound is BaCl2 >
​

KCl > CH3 COOH > sucrose. ​

(B) The osmotic pressure (π) of a solution is given by the equation π = MRT where M is the molarity of
the solution.

(C) Raoult's law states that the vapour pressure of a component over a solution is proportional to its mole
fraction.

(D) Two sucrose solutions of the same molality prepared in different solvents will have the same freezing point
depression.

Q.21

Two liquids A and B form an ideal solution. when total pressure of this solution is 600 torr the amount
fraction of A in the vapour phase 0.35 and in liquid phase is 0.70. The vapour pressure of pure A is (torr)

Q.22
@IITJEE_Advanced
0.004 M Na2 SO4 is isotonic with 0.01 M glucose. Degree of dissociation of Na2 SO4 is ____ (%)
​ ​ ​ ​

Q.23

The vapour pressure of a solvent decreased by 10 mm Hg when a non volatile solute was added to the
solvent. The mole fraction of solute in solution is 0.2, and the mole fraction of the solvent if decrease in
vapour pressure is 20 mm of Hg, is x. The value of 5x is

Q.24

20 g of a binary electrolyte ( [Link]. = 100 ) is dissolved in 500 g of water. The freezing point of the
solution is −0.74∘ C, Kf = 1.86 K. molality −1 . The degree of ionisation of the electrolyte is
​

Q.25

At 40∘ C, the vapour pressure in torr, of methyl alcohol - ethyl alcohol solution is represented by the equation.
PA
P = 119XA + 135 where XA is mole fraction of methyl alcohol, then the value of LimxA →1 X
​ ​ ​ is
A
​

​
​

Q.26

Persons are medically considered to have lead poisoning if they have a concentration of greater than
10 micrograms of lead per decilitre of blood. Concentration in parts per billion is ____g

Q.27

Moles of K2 SO4 to be dissolved in 12 mol water to lower its vapour pressure by 10

​ ​ mm Hg at a
temperature at which vapour pressure of pure water is 50 mm is

Q.28

When 20 g of naphthoic acid (C11 H8 O2 ) is dissolved in 50 g of benzene (Kf

​ ​ ​ ​ = 1.72 K kg mol−1 ), a
freezing point depression of 2 K is observed. The van't Hoff factor (i) × 10 is

Q.29

The van't Hoff factor of the compound K3 Fe(CN)6 is

​ ​

Q.30

The mole fraction of a solute in carbon tetrachloride is 0.235. The molality of the solution is about ____
mol/kg

Answers & Solutions

@IITJEE_Advanced
Q.1 Answer:
101.078∘ C
Solution:

Volume of solution = 1000 ml

Mass of the solution = V × d
= 1000 mL × 1.04 g/mL = 1040 g
Amount of solute in 1000 mL solution
=1M
= 1 M× Molecular Mass = 1M × 74.5 g/mol
= 74.5 g
Mass of water = Mass of solution − Mass of
KCl = 1040 g − 74.5 g = 965.5 g
Molality of the solution = m =
Moles of solute 1 mol
Mass of solvent in kg
= (965.5/1000)kg
​ ​

= 1.0357
ΔTb [Link] ⋅ m = 2 × 0.52 K kg mol−1 × 1.0357
​ ​

= 1.078∘ C.
Boiling point of the solution
= 100∘ C + 1.078∘ C = 101.078∘ C

Q.2 Answer:
68
77
​

Solution:
80
68
Mole fraction of H2 O = 18
=
​

80 20 77
+ 34
​ ​ ​

18
​ ​

Q.3 Answer:
−0.1953∘ C
Solution:
5
Degree of dissociation, α, AB = 100 = 0.05 ​

AB → A+ + B−
No. of moles dissolved
m 0 0
​ ​ ​

No. of moles after dissociation m(1 − α)mα mα

After dissociation 0.1(1 − 0.05) 0.1 × 0.05 0.1 × 0.05
​ ​ ​ ​ ​

Total moles = Molality

= 0.1(1 − 0.05) + 0.1 × 0.05 + 0.1 × 0.05
= 0.095 + 0.005 + 0.005 = 0.105 m
ΔTf = Kf m or T0f − Tf = 1.86 K/m × 0.105 m
​ ​ ​ ​

@IITJEE_Advanced
 = 0.1953 deg
Tf = 0∘ C − 0.1953 = −0.1953∘ C
​

Q.4 Answer:
HCl
Solution:

The lower is boiling point more is vapour pressure; boiling point order,
HCl < HBr < HI < HF
HCl is the most volatile compound among all hydrogen halides. The volatility of a compound is
related to its high vapour pressure at ordinary temperature. HF due to hydrogen bonding is least
volatile, as the molecular weight increases, intermolecular forces increases due to van der Waals'
force of attraction. Thus, HI is liquid and HCl is gas with maximum vapour pressure among all
hydrogen halides.

Q.5 Answer:
−1.86∘ C
Solution:

ΔTf = 1000×K
Mw×W
f ×w
​
​

= 1000×1.86×342
342×1000
= 1.86 K ​

∴ Tf = 0 − 1.86 = −1.86∘ C
​

Q.6 Answer:
4 Kb Y
​

M
​

Solution:
1000×Kb ×Y 4 Kb Y
ΔT = 250×M
​

​ = M
​

Q.7 Answer:
83.5%
Solution:

Normal [Link]
i for AgNO3 ​= Observed [Link].
=1+α ​

170
α= 92.64
​ − 1 = 0.835 = 83.5%

Q.8 Answer:
38.71 g
Solution:

ΔT = 1000×K
W×M
f ×w ​

or 9.3 = 1000×1.86×50
62×W
​

@IITJEE_Advanced
 ∴ W = 161.29
∴ Ice separated = 200 − 161.29 = 38.71 g

Q.9 Answer:
269.93 K
Solution:

ΔTf = ΔTf for glucose +ΔTf for KCl + ΔTf

​ ​ ​ ​

for urea
= 1000×1.86×10
100×180
+ 1000×1.86×1×2
74.5×100
+ 1000×1.86×5
100×60
= 3.069∘ ​ ​ ​

∴ freezing point = 273 − 3.069 = 269.93 K

Q.10 Answer:
0.018
Solution:

ΔTb = molality ×Kb ​ ​

0.52 = m × 0.52
−1
molality = 1 mol kg
∴ urea = 1 mol
water = 1000
18
= 55.55 ​

1
mole fraction of urea 55.55 ​ = 0.018

Q.11 Answer:
40, 10
Solution:

ΔT = 1000K b w1
m 1 w2 ​ ​
​

ΔT 1000×6
Kb (AB2 ) = m1 w2 = 1
​ ​ ​

​ ​ ​

1000×6
m1 ×100
​
=1 ​

∴ m1 (AB2 ) = 60 = A + 2B
​ ​

ΔT 1000×9
Kb
(A 2 B ) = m
​
​

1 ×100
=1 ​

​
​

∴ m1 (A2 B ) = 90 = 2A + B
​ ​

∴ A = 40, B = 10

Q.12 Answer:
7.4 cm
Solution:

P = 0.0072 atm
= 0.0072 × 76 cm of Hg
= 0.0072 × 76 × 13.6 cm of mercury column
@IITJEE_Advanced
 = h × 1 of water column
h = 0.0072 × 76 × 13.6 cm
= 7.4 cm

Q.13 Answer:
0.40 osmol
Solution:

KCl ⇌ K + + Cl−
Osmosis is a colligative property and thus
0.2M = 0.4M

Q.14 Answer:
all the above statements are correct
Solution:

P = PAo XA + PBo XB
​ ​ ​ ​

= 100
4
+ 60×3
4
​ ​

= 70 mm < 75 mm (experimental)
Thus, there is positive deviation (a) true mixture is more volatile due to decrease in b.p. Thus, (b) is
true also force of attraction is decreased thus (c) is true.

Q.15 Answer:
2 litre of the solution contains 0.080 mole of H3 O+ ​

Solution:

[H3 O+ ] = 2 × 0.02 = 0.04M

​

∴ 2 litre solution contains 0.08 mole of H3 O+ ​

Q.16 Answer:
3.2∘
Solution:

M (KCl) = 20×125
= 0.8M ​

i = [1 + (y − 1)x] = 2
ΔTf = molality ×Kf × i
​

= 0.8 × 2 × 2 = 3.2∘

Q.17 Answer:
67.83
Solution:

@IITJEE_Advanced
 We have,
p∘ −21.85 30×18
21.85 ​ = 90×m for I case......(i)
​

wt. of solvent =
90 + 18 = 108 gm
∘
p −22.15 30×18
22.15 = 108×m , for II case......(ii)
​ ​

By eq. (1)
p∘ m − 21.85m = 21.85 × 6 = 131.1
By eq. (2)
p∘ m − 22.15m = 22.15 × 5 = 110.75
0.30m = 20.35
m = 20.35
0.30 = 67.83

Q.18 Answer:
NaCl < Na2 SO4 < Na3 PO4 ​ ​ ​ ​

Solution:

Colligative property in decreasing order

Na3 PO4 > Na2 SO4 > NaCl
​ ​ ​ ​

Na3 PO4 → 3Na+ + PO3−

​

4 =4 ​ ​

Na2 SO4 → 2Na+ + SO42− = 3

​ ​ ​

NaCl → Na+ + Cl− = 2

Q.19 Answer:
C6 H12 O6 (glucose)
​ ​ ​

Solution:

La (NO3 )3 will furnish four ions and thus will develop more lowering in freezing point whereas
​ ​

glucose gives only one particle and thus minimum lowering in freezing point.

Q.20 Answer:
Two sucrose solutions of the same molality prepared in different solvents will have the same freezing point
depression.
Solution:

The extent of depression in freezing point varies with the number of solute particles for a fixed
solvent only and it is a characteristic feature of the nature of solvent also. So for two different
solvents the extent of depression may vary even if the number of solute particles is dissolved.

Q.21 Answer:
—
Solution:

@IITJEE_Advanced
 Ptotal = 600 torr PA = P × XA …… (i)
​ ​ ​

(P = total pressure )
XA = mole fraction of A in vapour pressure
​

YA = mole fraction of A in liquid solution

​

PA = P0A × YA …… (ii)
​ ​ ​

PA = vapour pressure of pure A

​

from Eq. (1) and (2) P0A × YA = Ptotal × XA ​ ​ ​ ​

P0A × 0.70 = 600 × 0.35

​

0.35
P0A = 600 × 0.70
​ = 600
2
= 300 torr ​

Q.22 Answer:
—
Solution:

0.004 M Na2 SO4 solution is isotonic with ​ ​

0.01 M solution of glucose, so their osmotic pressures are equal to each other.
Osmotic pressure of 0.01 M glucose
(π)glucose = CST ​

∴ C = Concentration of solution = 0.01 M

S = Solution constant = 0.0821 L − atm/K/mol
T = Absolute temperature
∴ πglucose = 0.01 × 0.0821 × T …… (i) ​

πglucose = πN a2 S O4 ​

​ ​
​

Na2 SO4 is present in ionic state in solution

​ ​

So, Na2 SO4 ⇌ 2Na+ + SO4 2− ​ ​ ​

At t =0 1 0 0 ​ ​ ​ ​ ​

At equilibrium 1 − α 2α α
(where α is the degree of dissociation of Na2 SO4 ) ​ ​

By van't Hoff factor

(πobs )N a SO
2 4
​ ​

​ ​

(πcal )N a S O
​

2 4
​ ​

​ ​

number of particles after dissociation

= number of particles before dissociation ​

= 1−α+2α+α 1 ​

∵ (πobs )Na2 SO4 = πglucose ​

​ ​
​

0.01×0.0821×T
∴ 0.004×0.0821×T = 1+2α
1 ​ ​

10 1+2α
or 4 = 1 or 10 = 4 + 8α ​ ​

α = 10−4
8 = 0.75 ​

Percentage of α = 75%

Q.23 Answer:
—
@IITJEE_Advanced
Solution:

P∘ − Ps = Po × mole fraction of solute

​

10 = Po × 0.2
Again, 20 = Po × mole fraction of solute
Hence, n = 0.4, so, mole fraction of solvent
= 1 − 0.4 = 0.6

Q.24 Answer:
—
Solution:

ΔTf = 1000×K
​

M×W
f ×w ​

∴ 0.74 = 1000×1.86×20
M×500
⇒ M = 100 ​

Normal [Link] 100

Now, exp. [Link]. = 1 + α = 100 ​ ​

So, α = 0

Q.25 Answer:
—
Solution:
PA
P = 119XA + 135; LimxA →1 ​

​
​

XA
​

​
​

= 119 + 135 = 254

Q.26 Answer:
—
Solution:

10μg per decilitre

⇒ 10 × 10−6 g in 100 mL
∴ 109 parts ( 1 billion) has
−6
= 10×10
100 × 109 g = 100g
​

Q.27 Answer:
—
Solution:

Lowering of V.P. is colligative property

thus, i (K2 SO4 ) ​ ​
= 1 + (y − 1)x = 1 + 2x = 3
∴ If Δp ​
n1 i
p∘ = n1 i+n2 ​
​

​
​

10
50
= 3n3n
​
1
1 +12
= n1n+4
1
​
​

​
​

@IITJEE_Advanced
Q.28 Answer:
—
Solution:

Molecular weight of naphthoic acid, C11 H8 O2 is 172

​ ​ ​ g mol−1
The theoretical value of depression in freezing point
= kf × molality = 1.72 × 20×1000
​

172×50
=2K
​

observed value of colligative property

∴ Van't Hoff factor i = Theoretical value of colligative property
​

2
= 4 = 0.5
​

Q.29 Answer:
—
Solution:
3−
K3 [Fe(CN)6 ] → 3K+ + [Fe(CN)6 ]
​ ​ ​

The Vant Hoff factor (i) for a dilute solution of K3 [Fe(CN)6 ] is 4 . It dissociates to give 3 potassium
​ ​

3−
ions and 1 [Fe(CN)6 ] ​ ion.

Q.30 Answer:
—
Solution:

Let
Amount of solute = 0.235 mol;
Amount of solvent = (1 − 0.235)mol = 0.765 mol
Mass of solvent,
m = nMm = (0.765 mol) (154 g mol−1 ) = 117.81 g
​

0.235 mol −1
Molality of solution = m
n
= 117.81×10 −3 kg ≃ 2.0 mol kg
​

@IITJEE_Advanced