Solution Ph: 8795430430

2.15 An aqueous solution of 2% non-volatile

solute exerts a pressure of 1.004 bar at the 2.31 ΔTF of acetic acid, trichloroacetic acid and
normal boiling point of the solvent. What is the trifluoroacetic acid increases in the order given
molar mass of the solute? Ans= 40.16 above. Explain briefly.

2.16 Heptane and octane form an ideal solution.

At 373 K, the vapour pressures of the two liquid
components are 105.2 kPa and 46.8 kPa
respectively. What will be the vapour pressure of 2.32 Calculate ΔTF when 10 g of
a mixture of 26.0 g of heptane and 35 g of CH3CH2CHClCOOH in 250 g of water. Ka = 1.4 ×
octane? Ans=73.43 10–3, Kf = 1.86 K kg mol– Ans= 0.647

2.17 The vapour pressure of water is 12.3 kPa at 2.33 19.5 g of CH2FCOOH in 500 g of water. ΔTF
300 K. Calculate vapour pressure of 1 molal is 10 C. Calculate i and Ka 2.84x 10-3
solution of a non-volatile solute in it. Ans=12.08 2.34 VP of water is 17.535 mm Hg. Calculate VP
of water when 25 g of glucose is dissolved in 450
2.18 Calculate the mass of a non-volatile solute g of water. Ans=17.4
(molar mass 40 g mol–1) which should be
dissolved in 114 g octane to reduce its vapour 2.35 Kh for molality of methane in benzene is
pressure to 80%. Ans=10 4.27 × 105 mm Hg. Calculate the solubility of
methane under 760 mm Hg.
2.19 A solution containing 30 g of non-volatile
solute exactly in 90 g of water has a vapour 2.36 100 g of liquid A (mwt 140 g mol–1) was
pressure of 2.8 kPa at 298 K. Further, 18 g of dissolved in 1000 g of liquid B (mwt 180 g mol–
water is then added to the solution and the new 1). Vp of pure liquid B is 500 torr. Calculate vp of
vapour pressure becomes 2.9 kPa at 298 K. pure liquid A and its vp in if the total VP is 475
Calculate: Torr. Ans=280.7 ,32
(i) molar mass of the solute (ii) vapour pressure
of water at 298 K. Ans 3.53kpa and 23 g/ mol 2.38 Benzene and toluene form ideal solution.
The Vp of pure benzene and toluene are 50.71
2.20 A 5% solution (by mass) of cane sugar in mm Hg and 32.06 mm Hg. Calc mole fraction of
water has freezing point of 271K. Calculate the benzene in vapour phase if 80 g of benzene is
freezing point of 5% glucose in water if freezing mixed with 100 g of toluene. Ans=0.60
point of pure water is 273.15 K. Ans=269.07
2.39 The air is a mixtures of a number of gases.
2.21 Two elements A and B form AB2 and AB4. The major components are oxygen and nitrogen
dissolved in 20 g of benzene ), 1 g of AB2 lowers with approximate proportion of 20% is to 79% by
the freezing point by 2.3 K whereas 1.0 g of AB4 volume at 298 K. The water is in equilibrium with
lowers it by 1.3 K. The molar depression air at a pressure of 10 atm. At 298 K if the
constant for benzene is 5.1 K kg mol–1. Calculate Henry’s law constants for oxygen and nitrogen
atomic masses of A and B. Ans= at 298 K are 3.30 × 107 mm and 6.51 × 107 mm
respectively, calculate the composition of these
22 At 300 K, 36 g of glucose in a litre solution gases in water.
has OP of 4.98 bar. If OP of the solution is 1.52
bars at the same T, what is conc? 2.40 calc amount of CaCl2 (i = 2.47) dissolved in
23 Suggest the most important type of 2.5 litre of water OP is 0.75 atm at 27° C.
intermolecular attractive interaction in the Ans=3.42
following pairs.
(i) n-hexane and n-octane (ii) I2 and CCl4 2.41 calc OP when 25 mg of K2SO4 in 2 litre of
(iii) NaClO4 and water water at 25° C, assuming completely dissociated.
(iv) methanol and acetone
(v) acetonitrile (CH3CN) and acetone
(C3H6O).London, London, iondipole,dipole
dipole, dipole dipole,

2.24 arrange in increasing solubility in n-octane.

Cyclohexane, KCl, CH3OH,
Ans = [Link]<OH<CN<Cyclohexane
 Solution

15 2 % NVS Ps = 1 004bar
.
Po = 10Bbar Mut =

21
IgABz/zog Benzene
ATp 23
IgABy ATF 13 RF 5)

Ps
=

W
=
.
=
, ,

09
=

m ATF = MRF
1
1000
1 3 .

= X
x 5

ana
#10042 1004
M
= 40 4
Gy
= -

y =
E

100
16 Pr = 1052 P = 468 W = 26 W = 35 octane

42 6
heptane 2 3x + 4
6y
13x +

52yy
.

112
-
. = =

Pm PECA PB (1-2) x 0 6
y
x = 25 59
. .

= + =

=
105 2 X
2) 100
+ 468(1-2A)
glutose/life 498/c
.

22 1 5
35/112 300K
369 it =
7 =

2/100
=
.

+ ,

498
= 105.2 x 0436 + 46 8 X0 544
. .

IT = CRT

25 45 XR
336x +
= 47 9 .
+
.

IT =

=3
= 73 3 .

= 00
1 5
.
= c &Y
17 Po = 12 3 .

molality = 1 PS =

Olops CHICRCHUGH/250 Ka = 1 4x10 DTF =

S
3- Ps 0 32 KF = 186
log
.

12 &
.

. =

1X-X i
12 3
1 018Ps
=
.

=
Ka
:

Ps =
12 .
08
Ps
1 - A
0 065
2=
.

VP reduce to 80 %
Il4g octane
18 W = ] Mut = 40
1 065 326 1 86 0645
ATF Imbf x 0 x
. .

=
.

=
=

Po-Ps 2 195

100-80- 10g
x

CH2FCOOH/5009
=

·3 ATF 12 kn =
19.59
=

80
ATF = ( + 2) x m Kf
R
30g NVs/90gtO Ps Po
19 2 8 RPa = 3
+
=
.

1 =
(+2)

=
9kPa Mut
30g NVS/1089tO Ps
= 2 .

X186
1 = ( + 1) x
+
3

pswt
Po-2 8 1640 3 36 2 84x10
-

=
1
. .
:
= -

1 075
.

1+ x
86
.

=
=

56
16 Po 0 .

0 =
.

2= 0 075
.

128-ext
Po 3 5
.

by po = 17 535
.

,
Ps = 3
25g glucose /450g
(i) 3 5-2
92
129
.
.

2 9
17 535- Ps
=5x
.

⑳ PS
PO88 17 535-Ps
25 P to
=
24 16
.

m = .

Po-2 8 .

1 16
.

10055Ps
- =

Po-2 9 .
17 535 .
=

Freezing
Ps = 17 44 .

20-%
Canesugar Ts 271 5 %
glucose Ts =? =

5 105mm
kn = 4 27
.
x
solubility => P T60mm
=

If

=
T-Ts =
m

P= kn Xx
213-271
760 = 4 .
27x105xx

=X
273-Ts 3
x =
1 78x10-
Ts
.

273- 3 78
.
=

Ts = 269 .
I
36 W = 100 (MW140) + 1000 (180) P3 = 500 Ph=? TP = 475 ton

Pm = PICA + PB(1-2A)
475 = Pa x 100140 + 500 (1-2A)
100/140 + 1000/180
500C10
475 =

PEX +

Pr = 280 7 .

37 P = 50
·

7/mm W = 20 (Benzene) P = 32 06
.
W=
100gm
Pm 50 11 x
2018 32 06 (1-2B)
+
Pa PM XYA
·
.

=
80/78 + 100/92
32 06x0 52 40 9xYA
.

50 71x040 +
243
. .
.

= =

24 3 + 166 40 9 .

06
YA
.

+ . =
=

39 20 % 02 79 % N2 P= 10atm KnOz = 3 .
3 x107mm

kM2 =
6 .
51x107 min

P = kn X 202 P = Kn XRN2

02x10x760 = 3 .
3x107 xRO2 0 79x10x760
.

= 6 .
51x15x
4 6 x 10-5
Roz 5
-

9 2x10
xNc
.

= .

no i = 2 47 5 = 075 T27
Acade V= 2
.
.

IT CRT
= x x0082IX300
ST =

x 3 42
gm
=
.

41 K2Son/2 lite T 298K

St 3
25mg
= =

T= CRTi

25x103 x0 0821x298
x
.
=

174

3
5 27 10
-

= .
x