1.
Product Identification
Product Name: Acetic acid
Synonyms: Acetic acid, methane carboxylic acid; ethanoic acid
U. N. No. : 2789
Molecular Weight: 60.05
Chemical Formula: CH3COOH
Contact Information:
Gujarat Narmada Valley Fertilizers & Chemical Limited
P.O. Narmadanagar – 392015, Dist. Bharuch, Gujarat, India
Ph (02642) 247001, 247002
2. Composition/Information on Ingredients
Composition:
Name CAS # % by Weight
Acetic acid 64-19-7 100
Toxicological Data on Ingredients: Acetic acid: ORAL (LD50): Acute: 3310 mg/kg [Rat].
4960 mg/kg [Mouse]. 3530 mg/kg [Rat]. DERMAL (LD50): Acute: 1060 mg/kg [Rabbit].
VAPOR (LC50): Acute: 5620 ppm 1 hours [Mouse].
Section 3: Hazards Identification
Potential Acute Health Effects:
Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation. Hazardous in case of skin contact (corrosive, permeator), of eye contact (corrosive).
Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes,
mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may
produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of
breath. Inflammation of the eye is characterized by redness, watering, and itching. Skin
inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Potential Chronic Health Effects:
Hazardous in case of skin contact (irritant), of ingestion, of inhalation. CARCINOGENIC
EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.
Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys,
mucous membranes, skin, teeth. Repeated or prolonged exposure to the substance can produce
target organs damage. Repeated or prolonged contact with spray mist may produce chronic eye
irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce
respiratory tract irritation leading to frequent attacks of bronchial infection.
Section 4: First Aid Measures
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty
of water for at least 15 minutes. Cold water may be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold
water may be [Link] clothing before reuse. Thoroughly clean shoes before reuse. Get
medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream.
Seek immediate medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention immediately.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie,
belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing,
perform mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing
aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention if symptoms appear.
Serious Ingestion: Not available.
Section 5: Fire and Explosion Data
Flammability of the Product: Flammable.
Auto-Ignition Temperature: 463°C (865.4°F)
Flash Points: CLOSED CUP: 39°C (102.2°F). OPEN CUP: 43°C (109.4°F).
Flammable Limits: LOWER: 4% UPPER: 19.9%
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances:
Flammable in presence of open flames and sparks, of heat. Slightly flammable to flammable in
presence of oxidizing materials, of metals.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of
explosion of the product in presence of static discharge: Not available. Slightly explosive in
presence of oxidizing materials.
Fire Fighting Media and Instructions:
Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use alcohol foam, water spray or fog. Cool containing vessels with water jet in
order to prevent pressure build-up, autoignition or explosion.
Special Remarks on Fire Hazards:
Reacts with metals to produces flammable hydrogen gas. It will ignite on contact with
potassium-tert butoxide. A mixture of ammonium nitrate and acetic acid ignites when warmed,
especially if warmed.
Special Remarks on Explosion Hazards:
Acetic acid vapors may form explosive mixtures with air. Reactions between acetic acid and the
following materials are potentially explosive: 5-azidotetrazole, bromine pentafluoride, chromium
trioxide, hydrogen peroxide, potassium permanganate, sodium peroxide, and phorphorus
trichloride. Dilute acetic acid and dilute hydrogen can undergo an exothermic reaction if heated,
forming peracetic acid which is explosive at 110 degrees C. Reaction between chlorine
trifluoride and acetic acid is very violent, sometimes explosive.
Section 6: Accidental Release Measures
Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate
waste disposal container. If necessary: Neutralize the residue with a dilute solution of sodium
carbonate.
Large Spill:
Flammable liquid. Corrosive liquid. Keep away from heat. Keep away from sources of ignition.
Stop leak if without risk. If the product is in its solid form: Use a shovel to put the material into a
convenient waste disposal container. If the product is in its liquid form: Absorb with DRY earth,
sand or other non-combustible material. Do not get water inside container. Absorb with an inert
material and put the spilled material in an appropriate waste disposal. Do not touch spilled
material. Use water spray curtain to divert vapor drift. Prevent entry into sewers, basements or
confined areas; dike if needed. Call for assistance on disposal. Neutralize the residue with a
dilute solution of sodium carbonate. Be careful that the product is not present at a concentration
level above TLV. Check TLV on the MSDS and with local authorities.
Section 7: Handling and Storage
Precautions:
\Keep away from heat. Keep away from sources of ignition. Ground all equipment containing
material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.
In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical
advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep
away from incompatibles such as oxidizing agents, reducing agents, metals, acids, alkalis.
Storage:
Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep
container tightly closed and sealed until ready for use. Avoid all possible sources of ignition
(spark or flame).
Section 8: Exposure Controls/Personal Protection
Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of
vapors below their respective threshold limit value. Ensure that eyewash stations and safety
showers are proximal to the work-station location.
Personal Protection:
Splash goggles. Synthetic apron. Vapor respirator. Be sure to use an approved/certified respirator
or equivalent. Gloves (impervious).
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus
should be used to avoid inhalation of the product. Suggested protective clothing might not be
sufficient; consult a specialist BEFORE handling this product.
Exposure Limits:
TWA: 10 STEL: 15 (ppm) [Australia] TWA: 25 STEL: 27 (mg/m3) [Australia] TWA: 10 STEL:
15 (ppm) from NIOSH TWA: 25 STEL: 37 (mg/m3) from NIOSH TWA: 10 STEL: 15 (ppm)
[Canada] TWA: 26 STEL: 39 (mg/m3) [Canada] TWA: 25 STEL: 37 (mg/m3) TWA: 10 STEL:
15 (ppm) from ACGIH (TLV) [United States] [1999] TWA: 10 (ppm) from OSHA (PEL)
[United States] TWA: 25 (mg/m3) from OSHA (PEL) [United States]Consult local authorities
for acceptable exposure limits.
Section 9: Physical and Chemical Properties
Physical state and appearance: Liquid.
Odor: Pungent, vinegar-like, sour (Strong.)
Taste: Vinegar, sour (Strong.)
Molecular Weight: 60.05 g/mole
Color: Colorless. Clear (Light.)
pH (1% soln/water): 2 [Acidic.]
Boiling Point: 118.1°C (244.6°F)
Melting Point: 16.6°C (61.9°F)
Critical Temperature: 321.67°C (611°F)
Specific Gravity: 1.049 (Water = 1)
Vapor Pressure: 1.5 kPa (@ 20°C)
Vapor Density: 2.07 (Air = 1)
Volatility: Not available.
Odor Threshold: 0.48 ppm
Water/Oil Dist. Coeff.: The product is more soluble in water; log(oil/water) = -0.2
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, diethyl ether, acetone.
Solubility: Easily soluble in cold water, hot water. Soluble in diethyl ether, acetone. Miscible
with Glycerol, alcohol, Benzene, Carbon Tetrachloride. Practically insoluble in Carbon
Disulfide.
Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Heat, ignition sources, incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents, reducing agents,
metals, acids, alkalis.
Corrosivity:
Highly corrosive in presence of stainless steel(304). Slightly corrosive in presence of aluminum,
of copper. Non-corrosive in presence of stainless steel(316).
Special Remarks on Reactivity:
Reacts violently with strong oxidizing agents, acetaldehyde, and acetic anhydride. Material can
react with metals, strong bases, amines, carbonates, hydroxides, phosphates, many
oxides,cyanides, sulfides, chromic acid, nitric acid, hydrogen peroxide, carbonates. ammonium
nitrate, ammonium thiosulfate, chlorine trifluoride, chlorosulfonic acid, perchloric acid,
permanganates, xylene, oleum, potassium hydroxide, sodium hydroxide, phosphorus isocyanate,
ethylenediamine, ethylene
imine.
Special Remarks on Corrosivity: Moderate corrosive effect on bronze. No corrosion data on
brass
Polymerization: Will not occur.
Section 11: Toxicological Information
Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity to Animals:
WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A
4-HOUR EXPOSURE. Acute oral toxicity (LD50): 3310 mg/kg [Rat]. Acute dermal toxicity
(LD50): 1060 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 5620 1 hours [Mouse].
Chronic Effects on Humans:
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria
and/or yeast. May cause damage to the following organs: kidneys, mucous membranes, skin,
teeth.
Other Toxic Effects on Humans:
Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin
contact (irritant), of ingestion,Hazardous in case of skin contact (corrosive, permeator), of eye
contact (corrosive).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: May affect genetic material and may cause
reproductive effects based on animal data. No human data found.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Extremely irritating and corrosive. Causes skin irritation
(reddening and itching, inflammation). May cause blistering , tissue damage and burns. Eyes:
Extremely irritating and corrosive. Causes eye irritation, lacrimation, redness, and pain. May
cause burns, blurred vision, conjunctivitis, conjunctival and corneal destruction and permanent
injury. Inhalation: Causes severe respiratory tract irritation. Affects the sense organs (nose, ear,
eye, taste), and blood. May cause chemical pneumonitis, bronchitis, and pulmonary edema.
Severe exposure may result in lung tissue damage and corrosion (ulceration) of the mucous
membranes. Inhalation may also cause rhinitis, sneezing, coughing, oppressive feeling in the
chest or chest pain, dyspnea, wheezing, tachypnea, cyanosis, salivation, nausea, giddiness,
muscular weakness. Ingestion: Moderately toxic. Corrosive. Causes gastrointestinal tract
irritation (burning and pain of the mouth, throat, and abdomen, coughing, ulceration, bleeding,
nausea, abdomial spasms, vomiting, hematemesis, diarrhea.
May Also affect the liver (impaired liver function), behavior (convulsions, giddines, muscular
weakness), and the urinary system - kidneys (Hematuria, Albuminuria, Nephrosis, acute renal
failure, acute tubular necrosis). May also cause dyspnea or asphyxia. May also lead to shock,
coma and death. Chronic Potential Health Effects: Chronic exposure via ingestion may cause
blackening or erosion of the teeth and jaw necrosis, pharyngitis, and gastritis. It may also
behavior (similar to acute ingestion), and metabolism (weight loss). Chronic exposure via
inhalation may cause asthma and/or bronchitis with cough, phlegm, and/or shortness of breath .
It may also affect the blood (decreased leukocyte count), and urinary system (kidneys). Repeated
or prolonged skin contact may cause thickening, blackening, and cracking of the skin.
Section 12: Ecological Information
Ecotoxicity:
Ecotoxicity in water (LC50): 423 mg/l 24 hours [Fish (Goldfish)]. 88 ppm 96 hours [Fish
(fathead minnow)]. 75 ppm 96 hours [Fish (bluegill sunfish)]. >100 ppm 96 hours [Daphnia].
BOD5 and COD: BOD-5: 0.34-0.88 g oxygen/g
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term
degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the
product itself.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Correctly incinerated material will decompose to corbondioxide and water only. Landfill after
ensuring that material is no longer reactive and has been neutralised. Labels should not be
removed before cleaning the containers. Empty containers may contain hazardous residues.
Contaminated containers should not be treated as household waste. Containers should be cleaned
by appropriate method and then disposed of by landfill or incineration as appropriate. Do not
incinerate closed containers. Treat the contaminated water used for spillage control or used for
dilution or for fire fighting.
Section 14: Transport Information
DOT Classification: CLASS 3: Flammable liquid. Class 8: Corrosive material
Identification: Acetic Acid, Glacial UNNA: 2789 PG: II
Special Provisions for Transport: Not available.
Section 15: Other Regulatory Information
Federal and State Regulations:
New York release reporting list: Acetic acid Rhode Island RTK hazardous substances: Acetic
acid Pennsylvania RTK: Acetic acid Florida: Acetic acid Minnesota: Acetic acid Massachusetts
RTK: Acetic acid New Jersey: Acetic acid California Director's
List of Hazardous Subtances (8 CCR 339): Acetic acid TSCA 8(b) inventory: Acetic acid
CERCLA: Hazardous substances.:
Acetic acid: 5000 lbs. (2268 kg)
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
EINECS: This product is on the European Inventory of Existing Commercial Chemical
Substances.
Other Classifications:
WHMIS (Canada):
CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F).
CLASS E: Corrosive liquid.
DSCL (EEC):
R10- Flammable. R35- Causes severe burns. S23- Do not breathe gas/fumes/vapour/spray [***]
S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice. S45- In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible).
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 2
Reactivity: 0
Personal Protection: H
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 2
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves (impervious). Synthetic apron. Vapor respirator. Be sure to use an approved/certified
respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash
goggles.
Section 16: Other Information
A human poison by unspecified routes. Moderately explosive and fire hazard when exposed to
heat or flame. Potentially explosive reaction with 5-Azidotetrazole, Bromine Pentafluoride,
Chromium Trioxide, Hydrogen Peroxide, Potassium Permanganate, Sodium Peroxide,
Phosphorous Trichloride
The product is involatile and water soluble and will partition into the aqueous phase. The product
will leach into soil. The product is readily biodegradable. BOD5 = 51 % of ThOD (Closed bottle
test - BOD) It is biodegraded under anaerobic conditions. Product is not expected to
bioaccumulate. The product is rated slightly toxic to aquatic species. The product is involatile
and water soluble and will partition into the aqueous phase. The product will leach into soil. The
product is readily biodegradable. BOD5 = 51 % of ThOD (Closed bottle test - BOD) It is
biodegraded under anaerobic conditions. Product is not expected to bioaccumulate. The product
is rated slightly toxic to aquatic species.