24-08-2025

4001CJA101003250006 JA

PART-1 : MATHEMATICS

SECTION-I (i)

1) The value of is :

(A) 0
(B) 1
(C) 2
(D) None of these

2) The first term of an infinitely decreasing G.P. is unity and its sum is S. The sum of the squares of
the terms of the progression is -

(A)

(B)

(C)

(D) S2

3) If one root of the quadratic equation px2 + qx + r = 0 (p ≠ 0) is a surd , where p, q,

r; a, b are all rationals then the other root is -

(A)

(B)

(C)

(D)

4) Let x1, x3 are the roots of equation x2 – 8x + A = 0 and x2, x4 are the roots of equation x2 – Bx + 40
= 0. If x1, x2, x3, x4 are form an increasing A.P., then (B – A) is equal to

(A) 1
(B) 2
(C) 5
(D) 7
 SECTION-I (ii)

1) Let a1, a2, a3,........ and b1, b2, b3,........ be arithmetic progression such that a1 = 25, b1 = 75 and a100
+ b100 = 100, then -

The common difference in progression 'ai' is equal in magnitude but opposite in sign to the
(A)
common difference in progression 'bj'.
(B) an + bn = 100 for any n.
(C) (a1 + b1), (a2 + b2), (a3 + b3), ....... are in A.P.

(D)

2) If the nth term of an arithmetic progression is Tn = (a – 3)n3 + (b – 4)n2 + (a + b)n – 4, ∀ n ∈ N then

which of the following is/are true

(A) a2 + b2 = 25
(B) common difference of the AP is 7
(C) common difference of the AP is 9
(D) sum of first 10 terms of the AP is 345

3) If x,y,z > 0 and x + y + z = 9, then correct statement is (are) -

(A) Maximum value of xyz is 27

(B)
Maximum value of xy2z is

(C)
Maximum value of x2yz3 is
(D) Maximum x2y3z4 is 210.33

4) Solutions of the equation 2 log10 x –log10 (2x –75 )=2 is(are)-

(A) 50
(B) 100
(C) 150
(D) 200

5) The equation |x+2|–|x+1|+|x–1|=K, x∈R has two solutions if K is equal to

(A) 4
(B) 3/2
(C) 5/2
(D) 3

6) If the differance of the roots of the equation x2 + kx + 7 = 0 is 6, then possible values of k are:
(A) 4
(B) –4
(C) 8
(D) –8

7) Let (a – 2)x2 + (b – 3)x + (c – 4) = 0 has three distinct real roots, then

(A) a + b + c = 9
(B) a2 + b2 – c = 9
(C) a + b + 2c = 13

(D)

8) The number when simplified reduces to -

(A) a prime number

(B) an irrational number
(C) a real which is less than log3π
(D) a real which is greater than log76

SECTION-II

1) The sum, is equal to ________.

2)

The number of terms common to the two A.P.'s 3, 7, 11, ....., 407 and 2, 9, 16, ....., 709 is ______.

3) The third term of a G.P. is 2. Then the product of the first five terms, is

4) If the sum to infinity of the series is λ, then find 16λ.

5) If one root is reciprocal of the other in the equation 5x2 + 13x + k = 0, then k is equal to –

6) The number of integral values of 'n' such that the equation nx2 + (n + 1)x + (n + 2) = 0 has
rational roots only, is

PART-2 : CHEMISTRY
 SECTION-I (i)

1)

Which of the following statement(s) is/are correct?

(a) Vander waal's radius of iodine is more than its covalent radius
(b) All isoelectronic ions belong to the same period of the periodic table
(c) IE1 of N is higher than that of O while IE2 of O is higher than that of N

(d) The 1st electron gain enthalpy of Cl is negative while second is positive
(A) a, b
(B) a, b, c
(C) a, c, d
(D) a, b, c, d

2) IE2 for an element is invariably higher than IE1 because :-

(A) It is difficult to remove electron from cation

(B) The size of the cation is smaller than its atom
(C) Zeff is more for cation
(D) All the above

3)

The electrons, identified by quantum number n and ℓ :

(i) n = 3 ; ℓ = 0
(ii) n = 5 ; ℓ = 2
(iii) n = 2 ; ℓ = 1
(iv) n = 4 ; ℓ = 3
can be placed in order of increasing energy from the lowest to highest as :

(A) (iii) < (i) < (iv) < (ii)

(B) (i) < (iii) < (iv) < (ii)
(C) (ii) < (iii) < (iv) < (i)
(D) (ii) < (iv) < (i) < (iii)

4) What is the molarity of a 4.9% w/w H2SO4 solution of density 0.98 gm/ml ? (S = 32, O = 16, H = 1)

(A) 0.98 M
(B) 0.49 M
(C) 1M
(D) 0.25 M

SECTION-I (ii)

1)
In a H-like sample, electron makes transition from 4th excited state to 2nd state then.

(A) 10 different spectral lines are observed

(B) 6 different spectral lines are observed
(C) number of lines belonging to the Balmer series is 3
(D) number of lines belonging to Paschen series is 2

2)

The wave function of 3s and 3pz orbitals are given by:

where a0 = 1st Bohr radius, Z = charge number of nucleus, r = distance from nucleus.
From this, we can conclude:

(A) Total number of node is same for 3s and 3pz orbitals.

The angular nodal surface of 3pz orbital occur at
(B)

(C) The radial nodal surface of 3s and 3pz orbitals are at equal distance from nucleus.
(D) 3s electrons have greater penetrating power into the nucleus compared to 3pz electron.

3) In photoelectric effect work function of any metal is 2.5 eV. The most energetic emitted electron
are stopped by potential of 1.5 Volt, then -

(A) Energy of incident photons is 4eV

(B) Energy of incident photons is 1eV
(C) Wavelength of most energetic emitted electron is 1nm
(D) Photocurrent increases with the application of photons of high frequency

4) Identify the incorrect order(s) in the following.

(A) F– > Cl– (ionic radius)

(B) Na > Mg (ionization energy)
(C) O < N (electron affinity)
(D) F < N (electronegativity)

5) Which of the following elements is/are transuranic elements.

(A) Th (Z = 90)
(B) Rf (Z = 104)
(C) Md (Z = 101)
(D) Pm (Z = 61)
6) Consider the IE1 of the following elements, whose electronic configurations correspond to the
following :-
(P) [Ne]3s23p3 (Q) [Ne]3s23p4 (R) [Ar]4s1 (S) [Ar]4s2
The CORRECT order of ionisation energy is/are :-

(A) R > S
(B) R < S
(C) P > Q
(D) P < Q

7)

Given
2KClO3(s) —→ 2KCl(s) + 3O2(g)

490 gm of KClO3 heated with 50% yield. Which is/are correct statements ? (K = 39, Cl = 35.5)
(A) 2 mol of KCl produced
(B) 96 gm of O2 produced
(C) Mass of residue is 96 gm
(D) No residue left in this reaction.

8) For 48g glucose C6H12O6, which of the following is/are correct

(A) 3.84 ×1024 total atoms

(B) 9.6 ×1023 C atoms
(C) 1.92 ×1024 O atoms
(D) None of these

SECTION-II

1) Total number of elements which can accomodate in the 10th period of periodic table if present.

2) Consider the following given oxides

CaO , MgO , BeO , Na2O , Al2O3 , ZnO , Cr2O3 , CrO3 , N2O3 , N2O , NO , PbO
Calculate value of multiplication of X and Y.
Here X = number of acidic oxides
Y = number of basic oxides

3) The number of elements among the following, which have lower electronegativity than oxygen
atom, based on Pauling scale, is __________ .
F, Cl, Br, I, H, S, P, K, Ca

4) Two nuclides A & B are isoneutronic. Their mass no. are 76 & 77 respectively if the atomic no. of
'A; is 32, then the atomic no. of 'B' will be :-
5) The total number of unpaired e– in 24Cr is x and 29Cu is y the sum of x+y is –

6) Find the mass ( in gm) of NaOH needed to prepare 100 ml 1M NaOH solution. (At. mass Na = 23)

PART-3 : PHYSICS

SECTION-I (i)

1) A ball is thrown vertically upward. Which of the graph represent speed-time graph of ball during
its flight (air resistance neglected) :

(A)

(B)

(C)

(D)

2) Two bodies are projected from ground with equal speeds 20 m/s from the same position in same
vertical plane to have equal range but a different angle above the horizontal. If one of the angle is
30°, the sum of their maximum heights is : (assume g = 10 m/s2)

(A) 400 m
(B) 20 m
(C) 30 m
(D) 40 m

3) A man running at a speed of 5 m/s, the rain drops appear to be falling at an angle of 45° from the
vertical. If the rain drops are falling vertically downwards w.r.t. ground then velocity in m/s is
(A) 5
(B) 5√3
(C) 5√2
(D) 4

4)

A car starts from rest with an acceleration of 1 m/s2. A man who is 48 m behind the car starts with a
uniform velocity of 10 m/s. Then the minimum time after which the man will reach the car,

(A) 4 s
(B) 8 s
(C) 12 s
(D) 16 s

SECTION-I (ii)

1) A particle is moving along a straight line in such a way that its velocity versus time graph is a
parabola is time, k is constant, V is velocity) as shown in the figure. Choose the correct
option(s)

(A) acceleration of the particle is throughout the journey

(B) average acceleration of particle is 1m/s2 for the interval of first 5 sec
(C) average acceleration of particle is less than for the interval of first 5 sec
2
(D) average acceleration of particle is less than 1m/s for the interval of 5 sec to 10 sec

2) A body moving with uniform acceleration in a straight line describes 25 m in the 5th second and 33
m in 7th second.

(A) Initial velocity is 6 m/s

(B) Initial velocity is 7 m/s
(C) Acceleration is 2 m/s2
(D) Acceleration is 4 m/s2

3) The equation of trajectory of a projectile is given by y = . Then :-

(A) Minimum speed of the projectile will be 10 m/s.
(B) Speed of projection will be 20 m/s.
(C) Time of flight of the projectile will be seconds.
(D) Maximum height attained by the projectile will be 15 m.

4) Two particles are thrown from the same point in the same vertical plane, as shown in figure
simultaneously.

Then indicate the correct statements :

(A) Time of flight for B is less than that of A

(B) Projection speed of B is greater than that of A
(C) Horizontal component of velocity for B is greater than that of A
The vertical component of velocities of both A and B are always equal throughout the duration
(D)
for which both the particles in air.

5) A projectile is launched from ground with initial velocity 10ms–1 which makes 53° with vertical. If
g = 10ms–2 choose the correct option(s):

(A) Horizontal range is 9.6 m

(B) Time of flight is 1.2 sec
(C) Maximum height above ground is 3.6m
When horizontal displacement is equal to one fourth of horizontal range, particle is 1.35m
(D)
above ground.

6) Two persons A & B are situated at coordinates (300, 0)m & (0, 300)m respectively. At t = 0 they
start to move with speed 30 m/sec and 40 m/s in perpendicular directions as shown in figure. Then

choose CORRECT statement(s) :

(A) Minimum distance between A & B is 60 m.

(B) Minimum distance between A & B is 100m.

(C)
Time taken for closest approach is sec.
(D) Time taken for closest approach is 10 sec.

7) A boy in the elevator with open roof shoots a bullet in vertical upward direction from a height of
1.5 above the floor of the elevator. The initial speed of the bullet with respect to elevator is 15 m/s.
The bullet strikes the floor after 2 seconds. Then (Assuming g = 10 m/s2)

(A) Lift is moving with constant speed

(B) Lift is moving with upward acceleration of 5.75 m/s2
(C) Lift is moving with downward acceleration of 5.75 m/s2
(D) Distance travelled by bullet during its flight can not be calculated from the given data.

8) A boat can travel at a speed of 3 m/s in still water. The speed of the river is 4 m/s, boatman starts
from A. B is a point directly across A on the opposite bank. Boat man wants to cross the river while

covering the shortest possible distance.

(A) The direction in which he must row the boat makes an angle , upstream with the
line AB
(B) The magnitude of resultant velocity of boat is
(C) The boat will reach point B.
(D) The boat will reach to a point which is on the right side of point B.

SECTION-II

1) A particle moves vertically with an upward initial speed v0=10.5 m/s. If its acceleration varies with
time as shown in a-t graph in the figure, find the velocity of the particle at t=4 s

2) A balloon is at a height of 40 m and is ascending with a velocity of 10 ms–1. A bag of 5 kg weight is

dropped from it. When will the body reach the surface of the earth ? Given g = 10 ms–2.

3) It is observed that a projectile is at same height at 3 sec and 5 sec from start at t = 0 sec. Then
the maximum height achieved by particle is 10 x meter. Find x. (g = 10 m/s2)

4) A ball is dropped from rest from a tower of height 5m. As a result of the wind it lands at a
distance 6m from the bottom of the tower as shown. Assuming no air resistance but that the wind
gives the ball a constant horizontal velocity v. Find value of v in m/s.

5) A girl standing on road holds her umbrella at 45º with the vertical to keep the rain away. If she
starts running without umbrella with a speed of , the rain drops hit her head vertically.

The speed of rain drops with respect to the moving girl is . Find n.

6) If vbw = 15 m/s, width of river is 27 m and flow of water is 10 m/s. Find drift of boat when it

reaches on opposite bank of river (in metre).

 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I (i)

Q. 1 2 3 4
A. A B C D

SECTION-I (ii)

Q. 5 6 7 8 9 10 11 12
A. A,B,C,D A,B,D A,B,D A,C A,B C,D A,B,C C,D

SECTION-II

Q. 13 14 15 16 17 18
A. 504 14 32 35 5 3

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22
A. C D A B

SECTION-I (ii)

Q. 23 24 25 26 27 28 29 30
A. B,C,D A,B,D A,C A,B,C,D B,C B,C A,B A,B

SECTION-II

Q. 31 32 33 34 35 36
A. 72 6 8 33 7 4

PART-3 : PHYSICS

SECTION-I (i)

Q. 37 38 39 40
A. A B A B

SECTION-I (ii)

Q. 41 42 43 44 45 46 47 48
A. C,D B,D A,B,D B,C,D A,B,D A,C B,D A,B,D
 SECTION-II

Q. 49 50 51 52 53 54
A. 3 4 8 6 30 6
 SOLUTIONS

PART-1 : MATHEMATICS

1) Fact based .

2)

1, r, r2, r3, .........., (r < 1)

⇒
S∞ = 1 + r + r4 + r6 + ............
2 2

S∞=

3)

Since a, b, c, p, q, r are rational so other root is conjugate of given root.

Its conjugate is

4)
x1 + x3 = 8 ...(1) x2 + x4 = B ...(3)
x1. x3 = A ...(2) x2 . x4 = 40 ...(4)
Let x1, x2, x3, x4 = (a – 3d),(a – d),(a + d), (a + 3d)
(1) ⇒ 2a – 2d = 8 ⇒ a – d = 4 ...(5)
(2) ⇒ (a – 3d) (a + d) A ...(6)
(3) ⇒ 2a + 2d = B ...(7)
(4) ⇒ (a – d) (a + 3d) = 40 ⇒ 4(a + 3d) = 40
a + 3d = 10 ...(8)
Solving (5) & (8)

4d = 6

⇒a=4+d=4+

A = x1 x3 = (a – 3d) (a + d) =
=7
B = x2 + x4 = 2(a + d) =
=B–A=7

5)

a100 + b100 = 100

25 + 99d1 + 75 + 99d2 = 100
99d1 + 99d2 = 0
d1 + d2 = 0
d1 = –d2
(A) Correct
(B) an + bn = a1 + (n – 1)d1 + b1 + (n – 1)d2
= a1 + b1 = 100 (Correct)
(C) Correct (as sum of corresponding terms of two AP's also form an AP)
(D) (a1 + b1) + (a2 + b2) + ..... + (a100 + b100)
= 100 × 100 = 104

6) Tn of A.P. is linear in n.
∴ coeff. of n3 = 0 and coeff. of n2 = 0
⇒ a – 3 = 0 and b – 4 = 0
⇒a=3 and b = 4
∴ Tn = 7n – 4
common diff. = coeff. of n = 7
first term = T1 = 7 – 4 = 3

= 5[6 + 63]
= 5 × 69
= 345

7)
Similarly in all apply A.M. > G.M

8)

2 log10 x – log10 (2x –75) = 2

⇒ = 102 = 100
2
⇒ x - 200x + 7500 = 0
⇒ x = 50, x = 150

9)

Graph of y=|x+2|–|x+1|+|x–1|
for two solutions K∈(1, 2) ∪ (3, ∞)

10)

k2 – 28 = 36 ⇒ k2 = 64 ⇒ k = +8

11) a = 2, b = 3, c = 4 now check options

12)

=1
⇒ Option C and D are correct

13)

= 504
Ans. 504.00

14) Common term are : 23, 51, 79, ..... Tn

Tn ≤ 407
⇒ 23 + (n – 1)28 ≤ 407
⇒ n ≤ 14.71
 n = 14

15)

16) Here, a = 1, d = 3,

∴ required sum = =

∴ ⇒ 16λ = 35

17) Let roots are α,

so, P.O.R. = 1 ⇒ =1 ⇒

18) D must be perfect square

D = (n + 1)2 – 4(n + 2)n = n2 + 2n + 1 – 4n2 – 8n = –3n2 – 6n + 1
= –3(x2 + 2n) + 1
= –3((n + 1|2 – 1) + 1
D = 4 – 3(n + 1)2
n = 0, –1, –2

PART-2 : CHEMISTRY

19) F– and Na+ are isoelectronic but F belongs to 2nd period while Na belongs to 3rd period.

20) All statements are correct

21)

Energy is given by (n + ℓ) value. When (n + ℓ) value is equal, the orbital with greater n-value
has greater energy.

Energy Thus, energy

(i) 3+0=3

(ii) 5+2=7
(iii) < (i) < (iv) < (ii)
(iii) 2 + 1 = 3

(iv) 4 + 3 = 7

22) 4.9 % W/W means 4.9 g of H2SO4 in 100 g of solution.

Now, Density of solution =

Volume of solution = g/ml

Volume of solution (in L) = 0.102 L

Molarity of H2SO4 =

= =
Molarity = 0.49 M

23)

(b)

No. of different spectral lines

(c) Balmer lines :

(d) Paschen lines:

24)

Total nodal surface = n – 1

Total angular nodal surface + radial nodal surface = 2 for both orbital.
There is a finite probability of finding electron in nucleus in case of 3s orbital.
Hence, 3s have more penetrating power than 3pz.
At radial nod ; the radial nodes in 3s and 2pz are not at equal distance.

25) [Link] = Eincid. – work function

1.5 eV = Eincid. – 2.5
Eincid. = 4 eV

λ= = 10Å = 1 nm

26)

Ans is (ABCD)
(A) Ionic Radius ∝ n.
(B) IE of Na < Mg
(C) EA of O > N
(D) EN of F(4.0) > N (3.0)

27)

Rf and Md comes after Uranium (92U) therefore are transuranic elements.

28)

(P) ⇒ [Ne] 3s23p3 ⇒ P (Phosphorous)

(Q) ⇒ [Ne] 3s23p4 ⇒ S (Sulphur)
(R) ⇒ [Ar]4s1 ⇒ K (Potassium)
(S) ⇒ [Ar] 4s2 ⇒ Ca (Calcium)
* P > Q (IE1) R < S
Half ⇓f
filled

29)

2KClO3 —→ 2KCl + 3O2

mol 4 mol 6 mol

= 2mol, = 3 mol = 3 × 32 = 96 gm

30)
(A) ∴ Number of total atoms

= × 24 × 6 × 1023

= 38.4 × 1023 × = 3.84 × 1024

(B) Number of C atoms

= × 6 × 6 × 1023 = 9.6 × 1023

(C) As number of C & O are same
So, C will be wrong.

31) 2M2 ⇒ M =
2 × (6)2 = 72

32)

X → N2O3, CrO3
 Y = Na2O, MgO, CaO
X+ y→3×2=6

33) Only 'F' is more electronegative than 'O' in Pauling scale

∴ is '8'.

34) For atom 'A' = 76 – 32 = 44 neutron

For atom 'B' = 77 – 44 = 33 atomic no.

35)

24Cr = [Ar] 3d54s1

10 1
29Cu = [Ar] 3d 4s
–
24Cr has 6 unpaired e
–
29Cu has 1 unpaired e

So, x + y = 7

36) Molarity =
Number of moles = 0.1
Weight of NaOH = 0.1 × 40 = 4

PART-3 : PHYSICS

37)

v = u – gt (for upward motion)

(v –t) → straight line
for downward motion v as vf = 0

38) For equal range, two angles are 30° and 60°

39)

Fact based .

40)

8s .
41) Use fundamental equations of kinematics

42)

Fact based .

43) tan q =

⇒ ux = 10 m/s
∴ u = 20 m/s

T=

44)

(Hmax)A = (Hmax)B

time of flight T = (Vy)A = (Vy)B

time of flight is same for both

Horizontal range RB > RA, R =

Vy is same for both it means (Vx)B > (Vx)A

projection speed V = (Vy)A = (Vy)B

(Vx)B > (Vx)A, VB > VA

45)

Fact based .

46) In ground frame

In the grame of B

BC is the minimum distance between A and B.

= 100 sin 37 =

x = 500 = AD
CD = 80
AC = 420
Time from A to D

47) –1.5 = 15T (10 + a)T2. Where T = 2 sec ⇒ a = 5.75 m/s2

As we can not find velocity of bullet with respect to ground, we can not calculate distance from
the given data.

48) To minimise drift direction.

(a) Should be along upstream with the line AB

(b)
Boat will never reach point B directly as It will reach somewhere on right [Link] of
point B.

49) The velocity of the particle at t = 4 s can be given as

graph during first 4s)

Referring to a-t graph (shown in the figure), we have
...(ii)

and
We can find the value of x as follows :

Using properties of similar triangles, we have

This yields x =

Substituting in and we have

Then substituting A1, A2, A3 and A4 in Eq. (ii), we have A = -7.5 and
Hence, we have

50) Given s = –40 m, u = 10 ms–1.

The initial velocity of the bag will be same as that of the velocity of balloon.

Using , we have

⇒ (t – 4) (5t + 10) = 0 ⇒ t = 4s, –2s

Neglecting negative time, time taken by body to reach the ground is t = 4s.

51)
t1 + t2 = time of flight

52) x =

53)

54)

Fact based .