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The document consists of a series of physics and chemistry problems, including questions on atmospheric pressure, dimensional analysis, isotopes, and chemical formulas. It covers various topics such as force, energy, velocity, and chemical reactions, providing multiple-choice answers for each question. The document is structured into sections for physics and chemistry, with a total of 20 questions in each section.

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0% found this document useful (0 votes)
4 views34 pages

Solution

The document consists of a series of physics and chemistry problems, including questions on atmospheric pressure, dimensional analysis, isotopes, and chemical formulas. It covers various topics such as force, energy, velocity, and chemical reactions, providing multiple-choice answers for each question. The document is structured into sections for physics and chemistry, with a total of 20 questions in each section.

Uploaded by

Anwesh Kar
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

19-04-2026

9610WJA802528260001 JA

PART 1 : PHYSICS

SECTION-I

1)

The atmospheric pressure in SI units is 1.01 × 105 Pascal. Its value in CGS units is :

(A) 1.01 × 104 dyne/cm2


(B) 1.01 × 105 dyne/cm2
(C) 1.01 × 106 dyne/cm
(D) 1.01 × 106 dyne/cm2

2) Dimensional formula for spring constant (where x = change in length) (F = Force) is

MaLbTc. Then find the value of .

(A)

(B) –1
(C) 1

(D)

3) We have a composite physical quantity defined as , where F is force, v is speed and W is


work. Then the dimensions of Q matches with which of these:

(A) Linear momentum


(B) Energy per unit area
(C) Acceleration
(D) Pressure

4) In function F = αv2sinβt, F denotes force, v velocity and t time. The dimensional formula of αβ2 is
same as dimensional formula of :

(A) acceleration due to gravity


(B) work done
(C) atmospheric pressure
(D) power

5) A system has basic dimensions as density [D], velocity [V] and area [A]. The dimensional
representation of force in this system is :-

(A) AV2D
(B) A2VD
(C) AVD2
0
(D) A VD

6) Position of particle is given as x = A + Bt + Esin(Ct + D) where x is in meter and t is in seconds.


The dimension of A × D is :

(A) [T]
(B) [LT–1]
(C) [L]
(D) [L–1T]

7) Where A, B, C, D, E, F, G, H, I, J & K are physical quantities. Which of


the following statement(s) are correct ?

(A)

(B)

(C)

(D) all of the above

8) A tribe has its own system of units. For mass they use PATHAR as unit, for length they use HATH
and for time they use GHARI. If their unit of force ZOR equals 10 newtons, which of the conversions
may be that of the system :-

(A) PATHAR = 100 kg, HATH = 0.1 m, GHARI = 1s


(B) PATHAR = 10 kg, HATH = 1m, GHARI = 0.1 s
(C) PATHAR = 50 kg, HATH = 0.4 m, GHARI = 1s
(D) ATHAR = 10 kg, HATH = 0.4 m, GHARI = 0.1 s

9)

Speed (v) of particle is given as


v = Ae , –Bt
where t is time, then dimensions of [A] and [B] are respectively:-

(A) LT–1, T–1


(B) L, T–1
(C) T–1, LT–1
(D) LT, T

10)

If K represents kinetic energy, V represents velocity and T represents time, and these are chosen as
the fundamental units then, the dimensional formula of surface tension is (Given : surface tension,

:-

(A) [KV–2T–2]
(B) [KV–1T–2]
(C) [K2V–1T–3]
(D) [KV–2T–1]

11)

Velocity of a particle depend on time t according to equation,

V= + bt + ; The a, b, c and d represents the


following quantities in order :-
(A) Distance, distance, acceleration, time
(B) Acceleration, distance, time, distance
(C) Acceleration, distance, distance, time
(D) Distance, acceleration, distance, time

12) Suppose we employ a system in which the unit of mass equals 100 kg, the unit of length equals
1 km and the unit of time 100 sec and call the unit of energy as eluoj (joule written in reverse order),
then what is the relation between eluoj and joule?

(A) 1 eluoj = 104 joule


(B) 1 joule = 104 eluoj
(C) 1 eluoj = 103 joule
(D) 1 joule = 103 eluoj

13)

Which of the following is incorrect statement?

(A) a dimensionally correct equation may be correct


(B) a dimensionally correct equation may be incorrect
(C) a dimensionally incorrect equation may be correct
(D) a dimensionally incorrect equation is incorrect

14) Surface tension is the property of a liquid surface. If dimensional formula is [S] =
x y z
[M L T ] then the value of x – z + y is :-

(A) 0
(B) 1
(C) 2
(D) 3

15) A particle is in a unidirectional potential field where the potential energy (U) of a particle
depends on the x-coordinate given by Ux = a (1 – cos bx) & a and 'b' are constants. The physical
dimensions of 'b'

0 0
(A) M LT
0 0
(B) M L–1T
(C) MLT–1
(D) ML2T–2

16) Which of the following quantities are dimensionless? (symbols have their usual meaning. Useful

relation I = mr2, F = 6πηrv, τ = Iα, ) , here I = moment of inertia, m = mass, r =


radius, η = coefficient of viscosity, v = velocity, τ = torque, T = time period, α = angular
acceleration, ω = angular velocity.

(A)

(B)

(C)

(D)

17) In a new system of units force (F), momentum (P) and mass (M) are taken as fundamental
physical quantities. Find the dimensional formula of power in new system.
(force = mass × acceleration), (momentum = mass × velocity)

(A) FP2M–1
0
(B) F PM–1
(C) FPM–1
0
(D) F P2M–1

18) If force = then dimensions of are


(A) M1/3L–1
(B) M2L2T–2
(C) M2/3T–1
(D) can't be determined

19) Which of the following forces cannot be a resultant of 15 N force and 11 N force ?

(A) 2 N
(B) 10 N
(C) 14 N
(D) 5 N

20) The initial and final velocities of an object are as shown in figure-(a). Which arrows shown in

figure-(b) can represent change in velocity vector ?

(A) 1
(B) 2
(C) 3
(D) 4

SECTION-II

1)

In the given figure if the angle between and is 5α°. Find the value of α.
2) A force F is acting on end B of a rod of length r. If magnitude of torque about hinge point O is
given by τ = rxFysinθ then fill the value of 2x + y. (torque has same dimension as work.)

3) The potential energy of a particle varies with distance x from a fixed origin as where A
and B are dimensional constants. If the dimensional formula for AB is , then find the value of
x + y+ z.

4) If mass, length and acceleration are taken as base quantities in a system then dimension of length
in dimensional formula of energy is.

5) A particle moves in the xy-plane with constant acceleration g directed along the negative y-axis.
The equation of trajectory of the particle is y = ax – bx2, where a and b are positive constants.

Velocity of the particle at the origin is given by . Find the value of 2n.

PART 2 : CHEMISTRY

SECTION-I

1) Two isotopes of an element are present in sample in 2 : 3 mol ratio of mass number (M + 0.5) and
(M + 1) respectively. The mean atomic mass of element will be :

(A) 5M + 4
(B) 5M + 0.4
(C) M + 0.8
(D) M + 0.5
2) What is the mass of oxygen atoms present in the 100g of CaCO3?

(A) 12 g
(B) 60 g
(C) 48 g
(D) 240 g

3) 16 g of an ideal gas SOx occupies 5.6 L. at STP. The value of x is :-

(A) x = 3
(B) x = 2
(C) x = 4
(D) none

4) A gas is found to have the formula (CO)x. It's Vapour Density is 70. The value of x must be :-

(A) 7
(B) 4
(C) 5
(D) 6

5) The mass of one molecule of CO2 in grams is

(A) 44 g

(B)
grams
(C) 44NA grams
(D) 4.4 grams

6)

Mass of 1 atom of He is

(A) 4g
(B) 4amu
(C) 2g
(D) 2amu

7) When 0.36 g of Mg is heated strongly in a nitrogen (N2) atmosphere, 0.5 g of the compound is
formed. Hence, compound formed is :-

(A) Mg3N2
(B) Mg3N
(C) Mg2N3
(D) MgN
8) Moles of calcium phosphate Ca3(PO4)2 which contains 0.25 gm-atoms of oxygen-

(A) 0.02
(B) 3.125 × 10–2
(C) 1.25 × 10–2
(D) 2.5 × 10–2

9) If 40.6 gm of a hydrocarbon contains 4.21 × 1023 molecules, then the hydrocarbon can be:

(A) C2H2
(B) C3H8
(C) C4H10
(D) C2H6

10) The weight of 2.01 × 1023 molecules of CO is

(A) 9.3g
(B) 7.2g
(C) 1.2g
(D) 3g

11) A diatomic gas occupies 15.68 L at 1atm & 273K. The number of atoms present in the sample
will be -

(A) 8.43 × 1023


(B) 6.022 × 1023
(C) 9.23 × 1021
(D) 4.21 × 1023

12) Number of neutrons in 5.5 gm T2O (T is 1H3) are -

(A) 0.25 NA
(B) 2.5 NA
(C) 3 NA
(D) 4 × NA

13)

Mass of calcium (in gms) present in 150 gm of CaCO3.


[Given : atomic mass of Ca = 40 u, C = 12 u & O = 16 u]

(A) 20
(B) 40
(C) 60
(D) 80
14) 3 × 1020 molecules of SO3 are added to 160 mg of SO3, then number of moles of SO3 finally
present :
(NA = 6 × 1023)

(A) 1.5 × 10–3


(B) 3 × 10–3
(C) 2.5 × 10–3
(D) 1.5 × 10–4

15) Which of the following series of compounds have same mass percentage of carbon ?

(A) CO2, CO
(B) CH4, C2H6,C2H2
(C) C2H2, C6H6,C10H8
(D) HCHO, CH3COOH,C6H12O6

16) Which of the following compounds has same empirical formula as that of glucose :-

(A) CH3CHO
(B) CH3COOH
(C) CH3OH
(D) C2H6

17) Find average vapor density of a gaseous mixture of O3 and O2. Molar ratio of O3 to O2 is 1 : 2

(A)

(B)

(C)

(D)

18) Two oxides of a metal contains 50% and 40% of a metal respectively. The formula of the first
oxide is [Link] the formula of the second oxide is -

(A) MO2
(B) M2O3
(C) M2O
(D) M2O5

19) If two neutrons are added to an element x, then it will be converted into its

(A) isobar
(B) isotope
(C) isotone
(D) None of these

20) Vapour density of a metal chloride is 66. Its oxide contains 53% metal. The atomic weight of
metal is approximately. [At. wt. Cl = 35.5]

(A) 21
(B) 54
(C) 27
(D) 37

SECTION-II

1) 5 mole of N2 combined with 6 mole H2 to form NH3 then moles of NH3 produced will be.

2) The % of carbon by mass in C2H6 is x. The value of is -

3) Calculate the mass of urea (NH2CONH2) containing gm-atom H.

4) A gas is found to have the formula (C3O2)n. Its vapour density is 34. The value of n will be ......

5) Molar mass of a macromolecule is 2800 gm, it contains 8% iron by mass. The number of iron atom
in one formula unit of the macromolecule is :

PART 3 : MATHEMATICS

SECTION-I

1) If A = {ϕ, {ϕ}, {{ϕ}}}, then the number of proper subsets of the power set of A i.e. P(A) is

(A) 7
(B) 8
(C) 255
(D) 125

2) In a group of 40 students, 26 take tea, 18 take coffee and 8 take neither of the two, how many
take both tea and coffee?

(A) 8
(B) 12
(C) 40
(D) 32

3) The set (A ∩ B')' ⋃ (B ∩ C) is equal to

(A) A' ∪ B ∪ C
(B) A' ∪ B
(C) A' ∪ C'
(D) A' ∩ B

4) How many even perfect squares are between 5 to 125?

(A) 3
(B) 5
(C) 4
(D) 6

5) (–5, 10] – (–5, 4) is equal to

(A) [4, 10]


(B) (0, 6)
(C) [5, 10]
(D) (4, 10]

6) A survey shows that 61% of Indian like cheese where as 72% like mangoes. If µ% of the Indian
like both cheese and mangoes then

(A) µ < 61
(B) µ < 33
(C) µ > 61
(D) 33 ≤ µ ≤ 61

7) For two sets A and B if n(A) = 7, n(B) = 13 and n(A ∩ B) = 5, then the incorrect statement is

(A) n(A ∪ B) = 15
(B) n (A – B) = 6
(C) n(A × B) = 91
(D) n{(A ∪ B) × (A ∩ B)} = 75

8) A survey shows that 73% of the persons working in an office like coffee, whereas 65% like tea. If x
denotes the percentage of them, who like both coffee and tea, then x cannot be:

(A) 63
(B) 38
(C) 54
(D) 36
9) Which of the following sets are pairs of disjoint sets?

(A) A = {1, 2, 3, 4} B = {x : x is prime number, x ≤ 11}


(B) A = {x : x ∈ N, x ≤ 8}, B {x : x is prime number, x ≥ 3}
(C) A = {x : x ∈ N, x is even}, B = {x : x is prime, x ≥ 4}
(D) A = {x : x ∈ N, x is odd} B = {x : x is composite number}

10) If A = {x : x is a prime number < 25} and B = {x : x is odd number < 20} then

(A) n(A∪B) = 20
(B) n(A∩B) = 7
(C) n(A∪B) = 18
(D) n(A∪B') = 9

11) The shaded region in the given figure is

(A) A∩(B∪C)
(B) A∪(B∩C)
(C) A∪(B–C)
(D) A–(B∪C)

12) If A and B are two sets, then A ∩ (A∪B)' is equal to

(A) A
(B) B
(C) ϕ
(D) None of these

13) If A = {2, 3, 4, 8, 10}, B = {3, 4, 5, 10, 12}. C = {4, 5, 6, 12, 14} then (A ∩ B) ∪ (A ∩ C) is equal
to

(A) {3, 4, 10}


(B) {2, 8, 10}
(C) {4, 5, 6}
(D) {3, 5, 14}

14) If A, B and C are three sets such that A ∩ B = A ∩ C and A ∪ B = A ∪ C, then :

(A) B = C
(B) A ∩ B = ϕ
(C) A = B
(D) A = C

15) Which of the following Venn diagram represent disjoint sets?

(A)

(B)

(C)

(D) None of these

16) Let A = {1, 2, 3, 4, 5}; B = {2, 3, 6, 7}. Then the number of elements in (A × B) ∩ (B × A) is

(A) 18
(B) 6
(C) 4
(D) 0

17) If A and B are two finite sets such that A ∩ B = ϕ then n(A ∪ B) =

(A) n(A) + n(B)


(B) n(A) + 2n(B) + n(A ∩ B)
(C) 2n(A) + n(B) – n(A ∩ B)
(D) None of these

18) The set (A∩B')' ⋃ (B∩C) is equal to:

(A) A' ∪ B ∪ C
(B) A' ∪ B
(C) A' ∪ C'
(D) A' ∩ B

19) In a group of 60 person 40 speak English and 30 speak Hindi. Each person speaks at least one of
the two languages. If the number of persons who speak only Hindi is α and the number of person
who speaks both the languages is β, then find the value of α and β

(A) α = 20, β = 10
(B) α = 20, β = 20
(C) α = 10, β = 10
(D) α = 10, β = 20

20) Find .
(Where P(A) is power set of A)

(A) 4
(B) 8
(C) 1
(D) 16

SECTION-II

1) If set A has 8 different elements then total number of proper subsets of set A is:

2) Let A = {n ∈ N | n2 ≤ n + 10,000}, B = {3k +1 | k ∈ N} and C = {2k | k∈N}, then the sum of all
the elements of the set A∩(B – C) is equal to_______ .

3) If aN = {ax : x ∈ ℕ}, then the set 3N ∩ 4N = αN, find the value of α:

4) If A and B are two sets such that n(A) = 150, n(B) = 250 and . Then

is

5) Set A has m elements and Set B has n elements. If the total number of subsets of A is 112 more

than the total number of subsets of B, then the value of


ANSWER KEYS

PART 1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D D C C A C D A A A D A C D B C C C A B

SECTION-II

Q. 21 22 23 24 25
A. 3 3 4 1 2

PART 2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C C B C B B A B C A A C C C D B D B B C

SECTION-II

Q. 46 47 48 49 50
A. 4 8 5 1 4

PART 3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C B B C A D B D C B D C A A C C A B A D

SECTION-II

Q. 71 72 73 74 75
A. 255 832 12 1 7
SOLUTIONS

PART 1 : PHYSICS

1) Explain Question: We need to find value of pressure in CGS


Concept: Conversion of units
Solution:
1.01 × 105 kg m–1 s–2 = n gm cm–1 s–2

n = 1.01 × 105 = 1.01 × 105 × 10


= 1.01 × 106
Final Answer: (D)

2) Explain Question: We need to find dimensional formula of spring constant


Concept: Finding of dimensions
Solution:
0
[k] = [ML T–2]
Final Answer: (D)

3) Explain Question: We need to find dimensional of Q


Concept: Dimensional analysis
Solution:

= acceleration
Final Answer: (C)

4) Explain Question: We need to find dimensional formula of αβ2


Concept: Dimensional analysis
Solution:

and

Final Answer: (C)

5) Explain Question: We need to find dimensional formula of force if fundamental quantities


are changed
Concept: Dimensional analysis
Solution:
F = DxVyAz
MLT–2 = MxL–3xLyT–yL2z
x = 1, –3x + y + 2z = 1 and –y = –2, z = 1
∴ [F] = AV2D
Final Answer: (A)

6) Explain Question: We need to find dimensions of A ×D


Concept: Dimensional analysis
Solution:
[x] = [A] = [Bt]
[A] = [x] = L
[D] = 1 ([Angel = 1]
∴ [A × D] = [A] [D] = [L]
Final Answer: (C)

7) Explain Question: We need to find correct statement


Concept: Principle of Homogenity
Solution:
Dimension of quantities in addition and substration will be same.
Final Answer: (D)

8) Explain Question: We need to find correct conservation


Concept: Conversion of units
Solution:

F= =
Final Answer: (A)

9) Explain Question : The problem asks for the dimensions of constants A and B in the given
equation V = Ae–Bt
Concept : Dimensional analysis
Solution : The exponent of an exponential function must be dimensionless . therefore , Bt
must be dimensionless

0 0 0
[Bt] = M L T
0 0 0
[B] [T] = M L T
[B] = T–1

Since e–Bt is dimensionless, the dimensionless of A must be the same as the dimension of V

The dimension of speed V is LT–1

Therefore [A] = :LT–1

The dimension of [A] and [B] are LT–1 and T–1 respectively
Final answer : (A)

10) Explain Question: We need to derive dimensional formula of surface tension


Concept: Derivation of formula using dimensions
Solution:
[Surface tension] = KaVbTc
0
⇒ ML T–2 = (ML2T–2)a(LT–1)bTc
0
ML T–2 = MaL2a+bT–2a – b + c
a = 1, 2a + b = 0, –2a – b + c = –2
b = –2a, –2 + 2 + c = –2
⇒ b = –2 c = –2
Surface tension = KV–2T–2
Final Answer: (A)

11) Explain Question: We need to find physical quantities


Concept: Principle of homogenity
Solution:

[b] = ⇒ acceleration
–1
[c] = [LT T] = L ⇒ Distance
[d] = [T] ⇒ Time

[a] = ⇒ Distance
Final Answer: (D)

12) Question Explanation: Find the relation between 'eluoj' and 'joule' based on the new
system of units.
Concept: This question is based on conversion of units
Solution:
[Energy] = [ML2T–2]
1 eluoj = (100 kg) × (1 × 1000 m)2 × (100 sec)–2
⇒ 1 eluoj = 104 kg m2s–2 = 104 Joule

Final Answer : The correct option is (1)

13) Explain Question: We need to find incorrect statement


Concept: A dimensionally incorrect equation may be correct
Solution:
Conceptual
Final Answer: (C)

14) Explain Question: We need to find dimensions of surface tension


Concept: Dimension of different physical quantities
Solution:
0

= [M1L T–2]
Final Answer: (D)
15) Explain question : We have to find the dimension of 'b' when potential energy of particle
is Ux = a(1 – cos bx)
Concept : This question is based on finding the dimensions of constants by dimension
analysis.
Solution : The dimension of angle is 1 i.e. angle is a dimensionless quantity.
∴ [bx] = 1

⇒ [b] =

=
0 0
∴ [b] = M L–1T

Final Answer The correct option is (2)

16) Explain Question: We need to derive dimensional less expressions


Concept: Dimensional anlysis.
Solution:
Option 'C'
1 –3
ρ=ML
v = L1T–1
r = L1
η = M1L–1T–1 (unit kg/m sec)

⇒ (Dimensions less)
Final Answer: (C)

17) Explain Question: We need to find dimensional formula of power


Concept: Dimensional analysis
Solution:
[P] = [FaPbMc] = [Ma+b+cLa+bT–2a–b] = [M1L2T–3 ]
⇒a+b=2 ....(i)
⇒ a + b + c =1 ....(ii)
⇒ – 2a – b = –3 ....(iii)
⇒ c = –1, a = 1, b = 1
[P] =[FPM–1]
Final Answer: (C)

18) Explain Question: We need to find dimensions of


Concept: Principle of homogenity
Solution:
[β3]= [density]
⇒ [β] = [M1/3L–1] and [α] = [Force × density]
= [MLT–2 × ML–3] = [M2L–2T–2]

Final Answer: (C)


19) Explanation :- Which option cannot be resultant of two given forces.
Concept :- Addition of vectors
Solution :-

Rmax = A + B
Rmin = |A – B|
A + B = 15 + 11 = 26 N
A – B = 15 – 11 = 3 N
Resultant can be [3, 26]
Final Answer : ''2N'' cannot be resultant

20)

Explanation :- Initial and find vel. vectors are given we have to find change in velocity
Concept :- Addition - subtraction.

Solution :-

Final Answer: option (2)

21) Explain Question: We need to find α.


Concept: Angle between vectors.
Solution:

5α = 15
α=3
Final Answer: (3)

22) Explain Question: We need to find dimensions of torque


Concept: Derivation of formula using dimensional analysis.
Solution:
τ = rFsinθ
[ML2T–2] = [L]x[MLT–2]y
ML2T–2 = MyLx + y T–2y
y=1
x=1
Final Answer: (3)

23) Explain Question: We need to find dimensions of AB


Concept: Principle of homogenity
Solution:
From the dimensional homogeneity

As well as

Now

Final Answer: (4)

24) Explain Question: We need to find dimensional formula of energy


Concept: Derivation of formula using dimensional analysis
Solution:
E = [ML2T–2] = [MLLT–2] = [M1L1A1] where A = [LT–2] = acceleration
Final Answer: (1)

25) Explain Question: We need to find velocity at origin


Concept: Dimension analysis
Solution:

= dimenstionless

Now, ⇒

⇒n=1
Final Answer: (2)

PART 2 : CHEMISTRY

26) Explain Question: Calculate the mean atomic mass of element.


Concept: Mean atomic mass
Solution:

=
Mave = M + 0.8
Final Answer: (C)

27) Question Explanation: Determine the mass of oxygen atoms in 100 g of CaCO3.
Concept: Principle of Atom Conservation (POAC).
Solution:
One mole of CaCO3 contains 3 moles of oxygen atoms. Use the molar mass of CaCO3 (100
g/mol) to find the moles of the compound.

no. of moles of CaCO3 = =1


no. of moles of oxygen in 1 mole CaCO3 = 1 3 = 03
mass of 3 mole oxygen atom = 3 16 = 48g
Final answer : (C)

28) Question Explanation: Determine the value of x in SOx from the given gas data.
Concept: Mole Concept and Ideal Gas Law.
Solution:
At STP, 1 mole of any ideal gas occupies 22.4 L.
First, find the number of moles of the gas. Moles = Volume (L) / 22.4 L/mol = 5.6 L / 22.4
L/mol = 0.25 mol.
Now, find the molar mass (M) of the gas.
Molar Mass = Mass / Moles = 16 g / 0.25 mol = 64 g/mol.
The molar mass of SOx is M(S) + x * M(O).
64 = 32 + x * 16
32 = 16x
x=2
The value of x is 2, and the gas is SO2​.
Final Answer : (B)

29)

Question Explanation: Calculate the subscript x for a molecular formula using Vapour
Density.
Concept: Molecular Weight and Vapour Density
Solution:
Vapor Density is defined as half of the molecular weight. The molecular weight of (CO)x is the
sum of atomic weights of Carbon and Oxygen multiplied by x.

V.D =
M.W = 140
M.W =
28x = 140
x=5
Final Answer : (C)

30) Question Explanation : Question is asking about mass of one molecule of CO2.
Concept : This question is based on mole concept.
Solution :
Mass of one molecule of CO2 = 44 amu

(∵ 1 amu = )

∴ Mass of one molecule of CO2 =


Final Answer : (B)

31)

Explain the question : Mass of one Helium atom.


Concept : This question is based on Atomic Mass Unit (amu)
Solution:
Atomic mass is the mass of one atom. For Helium (He), this is 4 amu. (4g is the mass of one
mole of He ).
Final Answer: (B)

32) Question Explanation: Question is asking about molecular formula of compound formed
by reaction between Mg and N2.
Concept: This question is based on stoichiometry.
Solution:

Moles of Mg =

moles of N2

=
then
= Mg3 N2
it is the compound formed
Final Answer: (A)

33)

Explain the question:


Find moles of Ca3(PO4)2 from 0.25 gm -atoms (moles) of O.

Concept:
This question is based on Mole Concept

Solution:
1 mole of Ca3(PO4)2 contains 2 × 4 = 8 moles of oxygen atoms.

Moles of Ca 3(PO4)2 = = 0.03125 mol. = 3.125 ×


10–2.

Final Answer:
The correct option is (2)

34) Explain Question:


Identify the hydrocarbon.

Concept:
Empirical and molecular formula.
Solution:

no. of moles = = 0.699 0.7

⇒ 0.7 =

GMM = = C4H10

Final Answer: Option(3)

35)

Question Explanation:
Question asks to find the mass of 2.01×1023 molecules of CO.
Concept:
Mole Concept, Avogadro's Number, Molar Mass
Solution:

Moles =

Moles =
Molar mass of CO:
M(CO) =12 + 16 =28g/mol
Mass of CO:
Mass = Moles × Molar mass

Mass =

Final Answer: Option (1)

36)

Explain the question: Find atoms in 15.68 L of a diatomic gas at NTP.


Concept: This question is based on Molar Volume at NTP ( 22.4 L/mol)
Solution:
Moles of gas =15.68 L / 22.4 L/mol = 0.7 mol.
Since the gas is diatomic, Moles of atoms = 0.7 × 2 = 1.4 mol.
Number of atoms = 1.4 × (6.022 × 1023) ≈ 8.43 × 1023.
Final Answer: (A)

37) Question Explanation:


Question is asking about Number of neutrons in 5.5 gm T2O.

Concept:
This question is based on mole concept.

Solution:

Mole of T2O =
molecule of T2O = × NA

Number of neutron in molecule of T2O = × NA × 12


= 3 NA

Final Answer: The correct option is (3).

38)

Explain the question: Find the mass of Ca in 150 g of CaCO3.


Concept: This question is based on Mass Percentage
Solution:
Molar Mass CaCO3 = 40 + 12 + 3(16) = 100 g/mol.
Mass fraction of Ca = (Mass Ca)/(Mass CaCO3) = 40/100.
Mass of Ca = (40/100) × 150 g = 60 g.
Final Answer: (C)

39) Explain the question: Find total moles of SO3 from two samples.
Concept: This question is based on Mole Concept (from Mass & Molecules)
Solution:

initial molar =

moles added =
Final Answer: (C)

40)

Question Explanation: Question is asking about compounds have same mass percentage of
carbon
Concept: This question is based on percentage composition.
Solution:
The molecules having same empirical formula will have same percent of constituent atoms.
HCHO CH3COOH C6H12O6
↓ ↓ ↓
Emp. form CH2O CH2O CH2O

%C =
Final Answer: (D)

41)

Explain the question:


Find the compound whose simplest whole-number ratio of atoms matches that of glucose.

Concept:
Empirical Formula is the simplest whole-number ratio of atoms in a compound.
Solution:
First, find the empirical formula of Glucose.

A. Molecular Formula of Glucose: C6H12O6.


B. The ratio of C:H:O atoms is 6:12:6.
C. Dividing all subscripts by the greatest common divisor (6), the Empirical Formula is CH2O.

Next, find the empirical formula for each option:

A. Option 1 (CH3CHO - Acetaldehyde): Total atoms are C 2H4O1. The ratio C:H:O is 2 : 4 : 1.
(Empirical Formula: C2H4O ).
B. Option 2 (CH 3 COOH - Acetic Acid): Total atoms are C 2 H 4 O 2 . The ratio C:H:O is 2 : 4 : 2.
Dividing by 2 , the Empirical Formula is CH2O. (Matches Glucose).
C. Option 3 (CH3OH - Methanol): Total atoms are C1H4O1. The ratio C:H:O is 1 : 4 : 1. (Empirical
Formula: CH4O).
D. Option 4 (C2H6 - Ethane): Total atoms are C2H6. Dividing by 2 , the Empirical Formula is CH3.

Final Answer:
The correct option is (2)

42) Question Explanation: Find average vapor density of a gaseous mixture.


Concept: Vapor Density and Average Molar Mass.
Solution: Calculate the average molar mass of the mixture based on the mole ratio, then
divide by 2 to find the vapor density.
O 3 O2
Mole ratio : 1 2

[VD]mix = =
Final answer: (D)

43) Explain Question: Find the formula of the second compound.


Concept: Empirical formula and molecular formula
Solution:

Final Answer: (B)

44) Question Explanation: Effect of adding neutrons to an element's nucleus.


Concept: Isotopes.
Solution: Adding neutrons to an atom increases its mass number but keeps the atomic
number (protons) the same, resulting in an isotope of that element.
If element X has Z protons, adding 2 neutrons results in an atom with Z protons and a mass of
A+2.
Final Answer: (B)

45) Question Explanation: Using composition data of two compounds to find atomic weight.

Concept: This question is based on Valency and Atomic Mass.

Solution: V.D. = ,
M’ = 2 × 66 = 132
metal chloride MCln ⇒ M + n × 35.5 = 132 ... (1)

Metal oxide M2On ⇒ ...(2)


Solving (1) and (2)
M = 27

Final Answer: Option (3)

46) Question Explanation: Calculating moles of ammonia produced from nitrogen and
hydrogen.
Concept: Limiting Reagent in Ammonia Synthesis.
Solution:
N2 + 3H2 → 2NH3

6 mol H2 → mole NH3


Final answer: (4)

47) Question Explanation: Question is asking about % of carbon by mass in C2H6.


Concept: This question is based on % composition.
Solution:

% of carbon by mass in C2H6 is x = = 80

Value of = =8
Final Answer: (8)

48) Question Explanation : Question asks to find the mass of urea containing 1/3 gram-atom
of hydrogen.
Concept : Mole Concept, Gram-Atom, Molecular Composition
Solution:
Given: H = 1/3 g-atom; Urea NH2CONH2
Hydrogen atoms in urea:
1 molecule of NH2 CONH2 contains 4 hydrogen atoms
∴1 mole of urea contains 4 moles of H atoms
Moles of urea:
4 mol H atoms present in → 1 mol urea
1/3 mol H atoms present in → mol urea
Molar mass of urea:
M(NH2CONH₂)=2(14) + 4(1) + 12 + 16 = 28 + 4 + 12 + 16 = 60 g/mol
Mass of urea:
Mass = Moles x Molar mass

Mass =
Final Answer: (5)

49) Explain the question : Find 'n' for (C3O2)n from V.D. = 34.
Concept : This question is based on vapour density & molar mass.
Solution :
First, calculate the molecular mass (M) from the vapour density (V.D.) using the relationship
molar mass = 2 × vapour density. This gives M = 2 × 34 = 68 g/mol. Next, calculate the mass
of the empirical formula unit (C3O2): Empirical mass = (3 × 12) + (2 × 16) = 36 + 32 = 68
g/mol. The molecular mass is 'n' times this empirical mass, so molar mass = n × (empirical
mass). Therefore, 68 = n × 68, which means n = 1.
Final answer : (1)

50)

Question Explanation: Finding number of iron atoms in a macromolecule.


Concept: Atomic Count in Formula Unit
Solution:
Calculate the total mass of iron in one mole and divide by its atomic mass.

Mass of iron in 1 mole marcromolecule =

Moles of iron in 1 mole marcromolecule =

Atoms of iron in 1 unit of macromolecule = 4


Final answer : (4)

PART 3 : MATHEMATICS

51) Explain Question : Given a set A containing three elements, find the total number of
proper subsets of its power set, P(A).
Concept : Power Sets, Cardinality, and Proper Subsets (2n – 1).
Solution :
No. of elements in P(A) = 23 = 8
So no. of proper subsets of P(A) = 28 – 1 = 255
Final Answer : (C)

52) Explain Question : In a group of 40 students, determine how many take both tea and
coffee given the counts for each individually and those who take neither.
Concept : Set Theory (Inclusion-Exclusion Principle) and De Morgan's Laws.
Solution :
n(U) = 40, n(T) = 26, n(C) = 18
n(T' ∩ C') = 8
⇒ n(T ∪ C)' = 8
⇒ n(U) – n(T ∪ C) = 8
⇒ n(T ∪ C) = 32
⇒ n(T) + n(C)– n(T ∩ C) = 32
n(T ∩ C) = 12
Final Answer : (B)

53) Explain Question : Simplify the set expression to find its equivalent form.
Concept : Set Operations, Complements, and Distributive Laws.
Solution :
(A' ∪ B) ∪ (B ∩ C)
((A' ∪ B) ∪ B) ∩ ((A' ∪ B) ∪ C)
(A' ∪ B) ∩ ((A' ∪ B) ∪ C)
⇒ (A' ∪ B)
Final Answer : (B)

54) Explain Question : Identify how many numbers between 5 and 125 are both even and
perfect squares.
Concept : Number Theory (Perfect Squares and Parity).
Solution :
42, 62, 82, 102 are even perfect square between 5 and 125.
Final Answer : (C)

55) Explain Question : Determine the resulting set when the interval (–5, 4) is subtracted
from the interval (–5, 10].
Concept : Set Theory (Interval Notation and Set Difference).

Solution : ⇒ [4, 10]


Final Answer : (A)

56) Explain Question : Given the percentages of people liking cheese (61%) and mangoes
(72%), find the possible range for the percentage ( ) of people liking both .
Concept : Set Theory (Max/Min of Intersection and Union Constraints) .
Solution :
Let total number of Indians be 100, let X, C, A be the sets of all Indians, Indians liking cheese,
Indian liking mangos respectively.
n(X) = 100 n(C) = 61
n(A) = 72 n(C ∩ A) = µ
n(A ∪ C) = n(A) + n(C) – n(A ∩ C)
n(A ∪ C) = 72 + 61 – µ
n(A ∪ C) =133 – µ
n(A ∪ C) ≤ 100
133 – µ ≤ 100
µ ≥ 33
Also then n(C ∩ A) ≤ n(A) and n(C ∩ A) ≤ n(C)
µ ≤ 61
∴ 33 ≤ µ ≤ 61
Final Answer : (D)

57) Explain Question : Given the cardinalities of sets A, B, and their intersection, identify
which of the provided four statements is mathematically incorrect.
Concept : Set Cardinality Formulas and Cartesian Products .
Solution :

n(A) = 7 ; n(B) = 13 ; n(A ∩ B) = 5 (A) n(A ∪ B) = n(A) + n (B) – n(A


∩ B)
= 7 + 13 – 5 = 15
(B) n(A – B) = n(A) – n(A ∩ B)
=7–5=2
(C) n(A × B) = n(A) n (B)
= 7 × 13 = 91
(D) n((A ∪ B) × (A ∩ B)) = n(A ∪ B) × n(A ∩ B)
= 15 × 5 = 75
Final Answer : (B)

58) Explain Question : Given office workers' preferences for coffee (73%) and tea (65%),
identify which value x (intersection) cannot be.
Concept : Min/Max Intersection in Set Theory .
Solution :
C → person like coffee
T → person like Tea
n(C) = 73
n(T) = 65
n(C ∪ T) ≤ 100
n(C) + n(T) – n(C ∩ T) ≤ 100
73 + 65 – x ≤ 100
x ≥ 38 …(i)
73 – x ≥ 0 ⇒x ≤ 73 …(ii)
65 – x ≥ 0 ⇒ x ≤ 65 …(iii)
(i) ∩ (ii) ∩ (iii) =

Final Answer : (D)


59) Explain Question : Identify which pair of sets from the given options has no common
elements (disjoint).
Concept : Disjoint Sets and Properties of Prime/Even/Odd Numbers .
Solution :
(1) A = {1, 2, 3, 4}, B = {2, 3, 5, 7, 11}
A ∩ B = {2, 3}
(2) A = {1, 2, 3…..8}, B = {3, 5, 7,….}
A ∩ B = {3, 5, 7}
(3) A = {2, 4, 6, 8, 10….}, B = {5, 7, 11, 13,….}
A∩B=ϕ
(4) A = {1, 3, 5, 7, 9, 11,….}, B = {x : x is composite number}
A∩B≠ϕ
Final Answer : (C)

60) Explain Question : Given set A (primes < 25) and set B (odd numbers < 20), verify the
correct cardinality for their union or intersection.
Concept : Set Roster Method and Set Operations (Union/Intersection) .
Solution :
A = {2, 3, 5, 7, 11, 13, 17, 19, 23}
B = {1, 3, 5, 7, 9, 11, 13, 15, 17, 19}
A∪B = {1, 2, 3, 5, 7, 9, 11, 13, 15, 17, 19, 23}
A∩B = {3, 5, 7, 11, 13, 17, 19}
n(A∩B) = 7
Final Answer : (B)

61) Explain Question : Identify the set notation that correctly describes the shaded region in
a three-set Venn diagram.
Concept : Venn Diagrams and Set Difference.
Solution :
By using venn diagram A – (B∪C)
Final Answer : (D)

62) Explain Question : Simplify the expression A ∩ (A ∪ B)'.


Concept : De Morgan's Laws and Intersection with Complement.
Solution :
A ∩ (A ∪ B)' ⇒ A ∩ (A' ∩ B') ⇒ (A ∩ A') ∩ B'
⇒ ϕ ∩ B' = ϕ {A ∩ A' = ϕ}
Final Answer : (C)

63) Explain Question : Find the union of (A ∩ B) and (A ∩ C) using the provided elements for
sets A, B, and C.
Concept : Set Intersection and Union.
Solution :
A ∩ B = {3, 4, 10}, A ∩ C = {4}
(A ∩ B) ∪ (A ∩ C) = {3, 4, 10}
Final Answer : (A)
64) Explain Question : If A ∩ B = A ∩ C and A ∪ B = A ∪ C, prove the relationship between
B and C.
Concept : Set Equality and Distributive Laws .
Solution :
We have, A ∪ B = A ∪ C ⇒ (A ∪ B) ∩ C = (A ∪ C) ∩ C
⇒ (A ∩ C) ∪ (B ∩ C) = C [∵ (A ∪ C) ∩ C = C]
⇒ (A ∩ B) ∪ (B ∩ C) = C ...(i) [∵ A ∩ C = A ∩ B]
Again, A ∪ B = A ∪ C
⇒ (A ∪ B) ∩ B = (A ∪ C) ∩ B ⇒ B = (A ∩ B) ∪ (C ∩ B)
⇒ (A ∩ B) ∪ (C ∩ B) = B ⇒ (A ∩ B) ∪ (B ∩ C)= B ...(ii)
From (i) and (ii), we get B = C
Final Answer : (A)

65) Explain Question : Choose the Venn diagram that represents disjoint sets.
Concept : Visual Representation of Disjoint Sets (No overlap).
Solution :
Disjoint sets mean no common elements.
Final Answer : (C)

66) Explain Question : Calculate the number of elements in the intersection of Cartesian
products (A × B) and (B × A).
Concept : Cartesian Products and the property: (A × B) ∩ (B × A) = (A ∩ B) × (A ∩ B) .
Solution :
Let S = (A × B) ∩ (B × A)
If (α, β) ∈ S then (α, β) ∈ (A × B) and (α, β) ∈ (B × A)
⇒ α ∈ A and β ∈ B as well as α ∈ B and β ∈ A
⇒ α, β ∈ (A ∩ B)
A ∩ B = {2, 3}
S = {(2, 2), (2, 3), (3, 2), (3,3)}
Number of elements in S is 4.
Final Answer : (C)

67) Explain Question : Find the formula for n(A ∪ B) specifically when sets A and B are
disjoint.
Concept : Cardinality of Union for Disjoint Sets.
Solution :
n(A ∪ B) = n(A) + n(B) – n(A ∩ B) (but n (A ∩ B) = 0)
n(A ∪ B) = n(A) + n(B)
Final Answer : (A)

68) Explain Question : Simplify the expression using set algebra to find the most reduced
equivalent form.
Concept : De Morgan's Laws and Absorption/Distributive Laws in Set Theory.
Solution :
(A'∪B)∪(B∩C)
((A' ∪B)∪B)∩((A' ∪B)∪C)
(A' ∪B)∩((A' ∪B)∪C)
⇒ (A' ∪B)
Final Answer : (B)

69) Explain Question : Calculate the equation of a line using the number of "only Hindi"
speakers as the x-intercept and "both language" speakers as the y-intercept.
Concept : Principle of Inclusion-Exclusion for two sets.
Solution :
n(E ∪ H) = 60
n(E) = 40
n(H) = 30
n(E ∪ H) = n(E) + n(H) – n(E ∩ H)
60 = 40 + 30 – n(E ∩ H)
n(E ∩ H) = 10
English and Hindi both = β = 10
only Hindi = α = n(H) – n(E ∩ H) = 30 – 10 = 20
Final Answer : (A)

70) Explain Question : Find the total number of elements (cardinality) in a nested power set
starting from an empty set, applied four times.
Concept : Set Theory and Cardinality of Power Sets .
Solution: The cardinality of the power set of a set A is n(P(A))=2n(A). We start with the null set
ϕ, where n(ϕ)=0, and apply the power set operation four times.
Calculation:
n(ϕ)=0.
0
n(P(ϕ))=2 =1.
n(P(P(ϕ)))=21=2.
n(P(P(P(ϕ))))=22=4.
n(P(P(P(P(ϕ)))))=24=16.
Final Answer: (D)

71) Explain Question : Calculate the number of proper subsets for a set containing 8 distinct
elements.
Concept : Proper Subsets (2n – 1).
Solution :
⇒ 28 – 1 = 256 – 1 = 255
Final Answer : 255

72) Explain Question : Find the sum of all elements that are in set A ( ) and
also in (B – C) (numbers 3k + 1 that are not even).
Concept : Set Intersection, Set Difference, and Arithmetic Progression Sum .
Solution :
B – C {7,13,19,...97, ....}
Now, n2 – n ≤ 100 × 100
⇒ n(n – 1) ≤ 100 × 100
⇒ A = {1,2,...., 100}.
So, {7,13,19,...,97}

Hence, sum =
Final Answer : 832

73) Explain Question : Given aN represents multiples of a, find the value of a such that 3N ∩
4N = aN.
Concept : Least Common Multiple (LCM) in Set Theory.
Solution :
3N = {3,6,9,12,15,…}
4N = {4,8,12,16,20,…}
3N ∩ 4N = {12,24,36,48,..……}
Note : If a number is multiple of 3 as well as 4 it will be a multiple of 12, i.e. LCM (3, 4) = 12.
i.e. LCM (3, 4) = 12.
Final Answer : 12

74) Explain Question : Calculate the value of the expression using given
set cardinalities.
Concept : Cardinality of Set Difference .
Solution :
n(A) = 150 n(B) = 250
n(A – B) = 50
n(B – A) = 150
Then,

Final Answer : 1

75) Explain Question : Given that set A has 112 more subsets than set B, calculate the value

of .
Concept : Subset Formulas ( ).
Solution :
2m – 2n = 112
m =7, n = 4
(27 – 24 = 112)
m × n =7 × 4 = 28

=7
Final Answer : 7

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