MOLE CONCEPT (Physical Chemistry)

EXERCISE-I (x) Glucose (C6H12O6)

DPP-1 (xi) Acetic acid (CH3COOH)
INTRODUCTION OF MOLE (xii) Sucrose (C12H22O11)
1. 1 a.m.u equals to (a.m.u = atomic mass unit.) (xiii) Blue vitriol (CuSO 4.5H2O)
(A) 6.022 × 1023 gm
DPP-2
(B) 6.022 × 1023 kg
PROBLEMS RELATED WITH INTERCONVERSION OF
(C) 1.66 × 10 −24 gm
MOLE, MASS AND NUMBER
(D) 1.66 × 10 −24 kg
1. The number of moles of ammonia in 4.25 g of
2. Define atomic mass
mass of an atom (in gm) ammonia is:
(A) atomic mass = (A) 0.425 (B) 0.25
1 a⋅m⋅u.
(B) Atomic mass = 1
mass of an atom (in gm) (C) 0.236 (D) 0.2125
of mass of single atom of C−12 (in gm)
12
mass of an atom (in gm) 2. The approximate number of molecules of CO2
(C) Atomic mass = 1 present in 44 g of CO2 is:
th of mass of single atom of C −12 in a mu
12
mass of an atom (in gm) (A) 6.0 × 1023 (B) 3 × 1023
(D) Atomic mass =
6.022×1023 (C) 12 × 10 23
(D) 3 × 1010
3. Unit of atomic mass is 3. The number of carbon atoms present in a signature,
(A) a.m.u (B) gm if a signature written by carbon pencil by 1.2 × 10 –3
(C) kg (D) Unit less gm carbon is
4. Mass of atom is 80 amu, its atomic mass will be (A) 12.04 × 1020 (B) 6.02 × 1019
(A) 80 (B)
80 (C) 3.01 × 10 19 (D) 6.02 × 1020
NA
(C) 80 NA (D) 80 × 1.66 × 10–24 4. The weight of 1  1022 molecules of CuSO4. 5H2O is :
(A) 41.59 g (B) 415.9 g
5. If mass of one apple is 50 gm, then mass of 1 mole (C) 4.159 g (D) 2.38 g
apple (Given NA = 6 × 1023 )
(A) 3 × 1025 gm (B) 1.2 × 1022 gm 5. Find the number of moles of the following :
(C) 3 × 10 amu
25
(D) 50 amu (i) 28 g of N2 (ii) 28 g of N
(iii) 64 g of O2 (iv) 64 g of O
6. Molar mass of electron is nearly (N A = 6 × 1023) (v) 54 mg of H2O (vi) 48 mg of CH4
Given: Mass of 1 electron = 9.1 × 10–31 kg (vii) 23 mg of NO2 (viii) 15 mg of CH3COOH
(A) 9.1 × 10–31 kg mol –1
(B) 9.1 × 10–31 gm mol –1 6. Find the following for 180 gm of Urea:
(C) 54.6 × 10–8 gm mol –1 Give: Urea (NH2CONH2)
(D) 54.6 × 10–8 kg mol –1 Atomic weight :( C = 12 , H = 1 , O = 16, N=14 )
(i) Number of moles of Urea
7. Mass of 1 mol (Molar mass) of Al is (Given; Atomic (ii) Number of molecules of Urea
mass of Al = 27) (iii) Number of moles of carbon atom
(A) 27 kg (B) 27 amu (iv) Number of moles of hydrogen atom
27
(C) 27 gm (D) gm (v) Number of moles of oxygen atom
NA
(vi) Number of moles of nitrogen atom
8. Mass of an atom of Sodium (Given atomic mass of (vi) Number of atoms of carbon, hydrogen, nitrogen
Sodium : 23) and oxygen
(A) 23 gm (B) 23 kg (vii) Total number of atoms
(C) 23 amu (D) 23 × 1.66 × 10–23 amu
7. For 49 g of H2SO4, Find the following:
9. Mass of 1 molecule of CO2 is (i) Number of moles of H 2SO 4
(A) 44 gm (B) 44 amu (ii) Number of moles of hydrogen, sulphur and
(C) 44 kg (D) 44 NA gm oxygen atom
10. Find the molar mass of the following molecules: (iii) Number of molecules of H 2SO 4
Given : Atomic mass : O = 16, N = 14, S = 32, C = 12, Cu (iv) Number of atoms of hydrogen, sulphur and
= 63.5 oxygen
(i) O2 (ii) N2 (v) Total number of atoms
(iii) NO2 (iv) H2O 8. Find
(v) NH3 (vi) N2O4 (i) Mass of 200 atoms of 16
8 O in amu
(vii) SO2 (viii) H2SO4
(ii) Mass of 100 atoms of 14
7 N in gm.
(ix) CO2
9. Find:
14
DOWNLOAD
IIT SCHOOL APP NOW
 MOLE CONCEPT (Physical Chemistry)

(i) No. of moles of Cu atom in 1020 atoms of Cu. 2. How many moles are there in 2.24m 3 of any gas at 190
(ii) No. of molecules and atoms in 54 gm H 2O. torr and 273ºC.
(iii) No. of atoms in 88 gm CO2. (A) 1.25 moles (B) 12.5 moles
(C) 1.25 × 10–3 moles (D) 1.25 × 103 mole
10. Calculate the number of electrons, protons and
neutrons in 1 mole of 16O –2 ions. 3. If V ml of the vapours of substance at 1 atm and 273 K
weighs W gm. Then molar mass of substance is:
DPP-3 V
PROBLEMS RELATED WITH INTERCONVERSION OF (A) (W/V) × 22400 (B) × 22.4
W
MOLE, MASS AND NUMBER (C) (W – V) × 22400 (D)
W×1
V×22400
1. Ethanol, C2H5OH, is the substance commonly called 4. 80 gm of SOx gas occupies 15 lit at 2 atm & 300 K . The
alcohol. The density of liquid alcohol is 0.8 g/ml at value of x is -
293 K. If 1.2 mole of ethanol are needed for a
(Given : R = 0.08 L-atm/K-Mole)
particular experiment, what volume of ethanol (A) 3 (B) 2 (C) 1 (D) None
should be measured out?
(A) 55 ml (B) 58 ml (C) 69 ml (D) 79 ml 5. While resting, an average 70 kg human male
consumes 16.628 L of oxygen per hour at 27°C and
2. Which of the following has the Maximum mass ? 100 kPa. How many moles of oxygen are consumed by
(A) 1 g-atom of Carbon
1 the 70 kg man while resting for 1 hour?
(B) mole of CH4 (A) 0.67 (B) 66.7 (C) 666.7 (D) 67.5
2
(C) 10 mL of water
6. At same temperature and pressure, two gases have the
(D) 3.011 × 1023 atoms of oxygen
same number of molecules. They must
3. Which of the following contain largest number of (A) have same mass
carbon atoms? (B) have equal volumes
(A) 15 gm ethane, C2H6 (C) have a volume of 22.7 dm 3 each
(B) 40.2 gm sodium oxalate, Na2C2O4 (D) have an equal number of atoms
(C) 72 gm glucose, C6H12O6
7. Four 1-1 litre flasks are separately filled with the gases
(D) 35 gm pentene, C5H10
H2, He, O2 and O3 at the same temperature and
4. A sample of aluminium has a mass of 54.0 g. What is pressure. The ratio of total number of atoms of these
the mass of the same number of magnesium atoms? gases present in different flask would be :
(At. wt. Al = 27, Mg = 24) (A) 1 : 2 :3 : 4 (B) 2 : 1 :2 : 4
(A) 12 g (B) 24 g (C) 48 g (D) 96 g (C) 2 : 1 :2 : 3 (D) 2 : 1 :2 : 3
5. A gaseous mixture contains CO2 (g) and N2O (g) in a 8. For the ideal gas, find the number of moles:
2 : 5 ratio by mass. The ratio of the number of (i) P = 0.8314 Pa V = 6000 m3 T = 300 K
molecules of CO2 (g) and N2O (g) is (ii) P = 5 atm V = 8.21 L T = 200 K
(A) 5 : 2 (B) 2 : 5 (C) 1 : 2 (D) 5 : 4 (iii) P = 831.4 Pa V = 5000 L T = 250 K
6. What is the mass of one 12C atom in gram? 9. For the ideal gas, find pressure:
(iv) V = 8.21 L T = 500 K n = 10
7. Calculate the weight of 12.046 × 1023 atoms of
(v) V = 100 m 3 T = 300 K n = 3
carbon.
(viii) V = 45.4 m 3T = 2730 K n = 5
8. Calculate mass of O atoms in 6 gm CH 3COOH?
10. For the ideal gas, find the missing parameter in each
9. Calculate mass of water present in 499 gm part among P, V, T and n:
CuSO4.5H2O? (vi) P = 831.4 Pa V = 1000 L n = 0.1
(Atomic mass – Cu = 63.5, S = 32, O = 16, H = 1) (vii) P = 22.4 atm T = 273 K n = 2
10. What mass of Na2SO 4.7H2O contains exactly 6.023 × 11. Find the volume of ideal gas at STP:
1022 atoms of oxygen? (i) 2 moles of PCl 5
(ii) 0.25 moles of NH 3
DPP-4
(iii) 0.5 moles of NO2
PROBLEMS RELATED WITH PV = nRT
(iv) 4 moles of N 2
1. How many moles are there in 0.821 L of any gas at 50
12. Find the moles of ideal gas at STP:
atm and 200 K.
(i) 22.7 L of O2 (ii) 45.4 L of N2
(A) 2 moles (B) 4 moles
(iii) 45.4 mL of NO2 (iv) 11.35 mL of NH3
(C) 1.25 × 10–3 moles (D) 1.25 × 103 mole
(v) 2.27 dm3 of SO 3 (vi) 113.5 m3 of CO 2

15
DOWNLOAD
IIT SCHOOL APP NOW
 MOLE CONCEPT (Physical Chemistry)

DPP-5 5. Mass of sucrose C12H22O11 produced by mixing 84 gm

BALANCING OF CHEMICAL REACTIONS of carbon, 12 gm of hydrogen and 56 lit. O2 at 1 atm &
273 K according to given reaction, is
1. C + O2 ⎯→ CO
C(s) + H2(g) + O2 (g) ⎯→ C12H22O11(s)
2. H2 + O2 ⎯→ H2O (A) 138.5 (B) 155.5
(C) 172.5 (D) 199.5
3. P + O2 ⎯→ P2O5
6. Calculate the volume of O2 needed for combustion of
4. S8 + O2 ⎯→ SO3 1.2 kg of carbon at STP.
Δ
5. C3H8 + O2 ⎯→ CO2 + H2O Reaction: C + O2 → CO2.
6. C2H6 + O2 ⎯→ CO2 + H2O 7. Methyl-t-butyl ether, C5H12O, is added to gasoline to
7. CxHy + O2 ⎯→ CO2 + H2O promote cleaner burning. How many moles of oxygen
gas, O2 are required to burn 1.0 mol of this compound
8. PCl 5 + H2O ⎯→ H3PO4 + HCl completely to form carbon dioxide and water?
9. NaHCO3(s) → Na2CO3(s) + CO2(g) + H2O(l) 8. Aluminum carbide (Al 4C3) liberates methane on
treatment with water:
10. KOH + H2CO3 ⎯→ K2CO3 + H2O
Al 4C4 + 12H2O → 3CH4 + 4Al(OH)3.
11. Ba(OH)2 + H3PO4 ⎯→ Ba3(PO4)2 + H2O Find mass of aluminum carbide required to produce
11.35 L of methane under STP conditions.
12. Pb(OH)4 + Cu2O ⎯→ PbO2 + CuOH
9. Reaction 4A + 2B + 3C → A4B2C3, is started from 2
13. ZnS + AlP ⎯→ Zn3P2 + Al 2S3
moles of A, 1.2 moles of B & 1.44 moles of C. find
14. CaSiO3 + HF ⎯→ SiF4 + CaF2 + H2O number of moles of product formed.

15. Ca(ClO3)2 + Na2SO4 ⎯→ CaSO4 + NaClO3 10. Carbon reacts with chlorine to form CCl 4. 36 gm of
carbon was mixed with 142 g of Cl 2. Calculate mass of
16. FeS2 + O2 → Fe2O3 + SO2 CCl 4 produced and the remaining mass of reactant.
17. P4S3 + O2 ⎯→ P4O10 + SO2 DPP-7
18. BCl 3 + P4 + H2 ⎯→ BP + HCl PROBLEMS RELATED WITH MIXTURE, % YIELD

19. Cl 2 + Ca(OH)2 ⎯→ Ca(ClO3)2 + CaCl 2 + H2O 1. A mixture containing 3 moles each of C4H8 and C6H6
undergoes complete combustion with O2 to form CO2
20. KMnO 4 + HCl ⎯→ KCl + MnCl 2 + H2O + Cl 2 and H2O. Calculate total mass of CO2 produced
DPP-6 (A) 1320 gm (B) 610 gm
PROBLEMS RELATED WITH LIMITING REACTANT (C) 528 gm (D) 792 gm

1. For the reaction 2P + Q → R, 8 mol of P and excess of 2. 12.46g of a mixture of MgO and MgCO3 on strong
Q will produce : heating lost 4.4g in weight what is the % MgO in the
(A) 8 mol of R (B) 5 mol of R initial mixture.
(C) 4 mol of R (D) 13 mol of R (A) 32.58 (B) 64.42
(C) 17.79 (D) 82.21
2. If 1.5 moles of oxygen combine with Al to form Al 2O3,
the weight of Al used in the reaction is: 3. Aluminium reacts with sulphur to form aluminium
(A) 27 g (B) 40.5 g sulphide. If 5.4 gm of Aluminium reacts with 12.8gm
(C) 54g (D) 81 g sulphur gives 12gm of aluminium sulphide, then the
percent yield of the reaction is-
3. The mass of Mg3N2 produced if 48 gm of Mg metal is 2Al + 3S ⎯⎯→ Al 2S3
mixed with 34 gm NH3 gas is (A) 100 % (B) 95 % (C) 80 % (D) 75 %
Mg + NH3 ⎯→ Mg3N2 + H2
200 100 4. Two successive reactions, A → B and B → C, have yields
(A) gm (B) gm
3 3 of 90% and 80%, respectively. What is the overall
400 150
(C) gm (D) gm percentage yield for conversion of A to C?
3 3
(A) 90% (B) 80% (C) 72% (D) 85%
4. The mass of P4O10 produced if 440 gm of P4S3 is mixed
with 384 gm of O2 is 5. Hydrazine N2H4 (used as a fuel in rocket system) can
P4S3 + O2 ⎯→ P4O10 + SO2 be produced according to the following reaction.
(A) 568 gm (B) 426 gm CINH2 + 2NH3 → N2H4 + NH4Cl
(C) 284 gm (D) 396 gm

16
DOWNLOAD
IIT SCHOOL APP NOW
 MOLE CONCEPT (Physical Chemistry)

When 1.0 kg CINH; is reacted with excess of NH 3, 473 g 4. 25.4 g of iodine and 14.2g of chlorine are made to
of N2H4 is produced. What is the percentage yield? react completely to yield a mixture of Cl and Cl 3.
(A) 76.12 (B) 67.21 (C) 26.17 (D) 16.72 Calculate The number of moles of Cl and Cl 3 formed.
6. When 4 gm of a mixture of NaHCO3 and NaCl is heated, (A) 0.1 mole, 0.1 mole (B) 0.1 mole, 0.2 mole
(C) 0.5 mole, 0.5 mole (D) 0.2 mole, 0.2 mole
0.66 gm CO2 gas is evolved. Determine the percentage
composition (by mass) of the original mixture. 5. Sulphur trioxide may be prepared by the following
two reactions :
7. One gram of an alloy of aluminium and magnesium
when heated with excess of dil. HCl forms magnesium S8 + 8O2(g) → 8SO2(g)
chloride, aluminium chloride and hydrogen. The 2SO2(g) + O2(g) → 2SO3(g)
evolved hydrogen collected at 0°C has a volume of 1.12 How many grams of SO3 will be produced from 1 mol
litres at 1 atm pressure. Calculate the composition of of S8?
(% by mass) of the alloy. 6. 2PbS + 3O2 → 2PbO + 2SO2
8. Cyclohexanol is dehydrated to cyclohexene on heating 3SO2 + 2HNO3 + 2H2O → 3H2SO4 + 2NO
with conc. H2SO4. Find %yield of this reaction, if 61.5 According to the above sequence of reactions, how
gm cyclohexene is obtained from 100 g of much H2SO4 will 1075.5 gm of PbS produce?
cyclohexanol? 7. Moles of ABC3 produced in the following set of
con.H2SO 4
C6H12O → C6H10 + H2O reaction when 180 gm of A, 180gm of B and 200 gm of
C are mixed in a container (given molar masses of
9. 200 g impure CaCO3 on heating gives 11.35 L CO2 gas
A,B,C are 20, 30 & 10 respectively.
at STP. Find the percentage of calcium in the lime stone
2A + 3B + 5C ⎯⎯→ A2BC2 + B2C3
sample.
B2C3 + 3C ⎯⎯→ 2BC3
DPP-8 BC3 + A ⎯⎯→ ABC3
PROBLEMS RELATED WITH SEQUENTIAL AND
8. Total weights (in gm) of P4O6 and P4O10 will be
PARALLEL REACTION
produced by the combustion of 31g of P4 in 32g of
1. The following process has been used to obtain iodine oxygen leaving no P4 and O2.
from oil-field brines in California.
DPP-9
NaI + AgNO3 → AgI + NaNO3 ; PROBLEMS RELATED WITH % by Mole, % by Mass and
2AgI + Fe → Fel 2 + 2Ag Mavg
2FeI2 + 3Cl 2 → 2FeCl 3 + 2I2 1. Average mol. wt. of a gaseous mixture which contains
How many grams of AgNO3 are required in the first 80% by mole N2 & rest O2 gas is-
step for every 254 kg 2 produced in the third step? (A) 28 (B) 30.6 (C) 28.8 (D) 29.2
(A) 340 kg (B) 85 kg 2. The percentage by mole of NO2 in a mixture of NO2(g)
(C) 68 kg (D) 380 kg and NO(g) having average molecular mass 34 is :
2. 10 g of a sample of a mixture of CaCl 2 and NaCl is (A) 25% (B) 20% (C) 40% (D) 75%
treated to precipitate all the calcium as CaCO3. This 3. The vapour density of a sample of SO3 gas is 28. Its
CaCO3 is heated to convert all the Ca to CaO and the degree of dissociation into SO2 and O2 is
final mass of CaO is 1.62 g . The percent by mass of (A) 1/7 (B) 1/6 (C) 6/7 (D) 2/5
CaCl 2 in the original mixture is:
(A) 32.1 % (B) 16.2 % (C) 21.8 % (D) 11.0 % 4. An organic compound contains 40% carbon and
6.67% hydrogen by mass. Which of the following
3. Consider the following reaction represents the empirical formula of the compound?
2Na + 2NH3 ⎯→ 2NaNH2 + H2(g) (A) CH2 (B) CH2O (C) C2H4O (D) CH3O
2NaNH2 + C ⎯→ Na2CN2 + 2H2 (g)
Na2CN2 + C ⎯→ 2NaCN 5. A quantity of 1.4 g of a hydrocarbon gives 1.8 g water
51gm dry ammonia gas is passed over excess heated on complete combustion. The empirical formula of
sodium to form sodamide (NaNH 2) which is further hydrocarbon is
reacted with carbon (excess) to finally form NaCN. (A) CH (B) CH2 (C) CH3 (D) CH4
Find the total volume of H 2(g) evolved at 0.5 atm, 6. Calculate the atomic mass (average) of chlorine using
273K the following data:
(A) 201.6 L (B) 100.8 L % Natural Abundance Molar Mass
(C) 403.2 L (D) 50.4 L 35Cl 75.77 34.9689
37Cl 24.23 36.9659

17
DOWNLOAD
IIT SCHOOL APP NOW
 MOLE CONCEPT (Physical Chemistry)

7. Average atomic mass of Magnesium is 24.31 amu. This [Aq. tension at 250 K is 24 mm Hg and R = 0.08 L atm
magnesium is composed of 79 mole % of 24Mg and mol –1 K–1]
remaining 21 mole % of 25Mg and 26Mg. Calculate mole 10
(A) %
5
(B) %
20
(C) % (D)
100
%
% of 26Mg. 3 3 3 3

6. 40 gm of a carbonate of an alkali metal or alkaline

8. An organic compound contains carbon, hydrogen and
earth metal containing some inert impurities was
nitrogen. If weight ratio of C, H, N (in same order) is 9 :
made to react with excess HCl solution. The liberated
1 : 3.5 and molar mass of compound is 216 gm/mole
CO2 occupied 12.315 lit. at 1 atm & 300 K. The correct
and number of atoms present in 1 molecule of
x option is
compound are x then calculate value of . (A) Mass of impurity is 1 gm and metal is Be
4

9. A compound has carbon, hydrogen and oxygen in 3 : 3 (B) Mass of impurity is 3 gm and metal is Li
: 1 atomic ratio. If the number of moles in 1 g of the (C) Mass of impurity is 5 gm and metal is Be
compound is 6.06 × 10–3, then the molecular formula (D) Mass of impurity is 2 gm and metal is Mg
of the compound will be 7. Industrially TNT (C7H5N3O6, explosive material) is
10. A 60 gm sample of organic compound having synthesized by reacting toluene (C7H8) with nitric acid
empirical formula CxHy O on complete combustion in presence of sulphuric acid. Calculate the maximum
gives 88 gm of CO2 & 36 gm of H2O. The value of (x + weight of C7H5N3O6 which can be produced by 140.5
y) is. gm of a mixture of C7H8 and HNO3.
C7H8 + 3HNO3 ⎯→ C7H5N3O6 + 3H2O
DPP-10 (A) 140.5 (B) 113.5
MISCELLANEOUS PROBLEM (C)
140 .5
(D) 140.5 – (3 × 18)
2
1. If the mass of neutron is double and that of proton is
8. One gram of the silver salt of an organic dibasic acid
halved, the molecular mass of H 2O containing only H1
and O16 atoms will yield, on strong heating, 0.5934 g of silver. If the
weight percentage of carbon in it 8 times the weight
(A) increase by about 25%
(B) decrease by about 25% percentage of hydrogen and one-half the weight
(C) increase by about 16.67% percentage of oxygen, determine the molecular
formula of the acid.
(D) decrease by about 16.67%
[Atomic weight of Ag = 108]
2. The mass of CO2 produced from 620 gm mixture of (A) C4H6O 4 (B) C4H6O 6
C2H4O2 & O2, prepared to produce maximum energy is (C) C2H6O 2 (D) C5H10O 5
(Combustion reaction is exothermic)
(A) 413.33 gm (B) 593.04 gm
(C) 440 gm (D) 320 gm
3. X gm A atoms on combining with Y atoms of B form 5
molecules of a compound containing A & B. Find the
molecular weight of compound formed. (Atomic
weight of B = M)
(XNA +MY ) X+M
(A) (B)
5 5
X+MY X+MY NA
(C) (D) ( )
5 5

4. The minimum mass of mixture of A 2 and B4 required

to produce at least 1 kg of each product is:
(Given At. mass of 'A' = 10 ; At. mass of 'B' = 120)
5A2 + 2B4 ⎯⎯→ 2AB2 + 4A2B
(A) 2120 gm (B) 1060 gm
(C) 560 gm (D) 1660 gm
5. In the quantitative determination of nitrogen, N 2 gas
liberated from 0.42 gm of a sample of organic
compound was collected over water. If the volume of
100
N2 gas collected was mL at total pressure 860 mm
11
Hg at 250 K, % by mass of nitrogen in the organic
compound is

18
DOWNLOAD
IIT SCHOOL APP NOW