Chapter 9 Notes
Chapter 9 Notes
Acids Alkalis
Feel / Slippery
➢ NEVER taste acids or alkalis in science laboratory.
➢ Acids and alkalis are aqueous solutions, So, they are mixtures.
1am 10
mass of solute (g)
➢ Concentration (g dm ) = volume of solution (dm3) ; 1 dm3 = 1000 cm3
-3
● – Solute solute
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Integrated Science Chapter 9 Common acids and alkalis
*** Chemical formulae of acids and alkalis to be further discussed in Ch. 9.3
➢ Safety precautions
◼ NOT to fill more than half of the test tube with acids or alkalis.
◼ NOT to pour waste solution into sinks. Pour them into waste bottles.
◼ NOT to mix acids and alkalis without the getting approval of your teacher.
◼ Skin: wash the affected part with cold running water for at least 10 minutes
◼ Eye: wash the affected part with eye wash bottle for at least 10 minutes
Acids Alkalis
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Integrated Science Chapter 9 Common acids and alkalis
➢ Acid-alkali indicators:
◆ Contains natural pigment, which shows different colours in acidic and alkaline
conditions
e.g. Red cabbage extract, butterfly pea flower extract, red onion skill extract, etc.
Procedures
(Refer to textbook P.9-10)
Results
Original Colour of extract after adding …
colour of
extract distilled water lemon juice baking soda solution
acid
Purple Purple Red Blue
Discussion
1. Suggest the purpose of tube A in the experiment.
2. Explain whether the red cabbage extract can be used as an acid-alkali indicator.
Yes, it can. It is because it shows different colours in acidic and alkaline conditions.
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Integrated Science Chapter 9 Common acids and alkalis
b. Litmus
◆ There are two types of litmus indicators, red litmus and blue litmus.
[Link] 1 I
Practical 9.2 Using litmus paper to classify solutions as acidic, alkaline or neutral
a
Procedures
(Refer to textbook P.15)
Results
Litmus Colour of extract after adding solution
paper A B C D
Discussion
1.
A&C Neutral:
W
Classify the solutions A to D as a/an acid, neutral or alkali.
Acid: D Alkali: B
2. Which two solutions show the same result? Can you tell which solution is more
corrosive? Why?
Solutions and shows the same result. It cannot be told which is more
corrosive, since both solution shows the same result with litmus.
➢ Limitations of acid-alkali indicators:
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Integrated Science Chapter 9 Common acids and alkalis
Due to the limitation of acid-alkali indicator, we need to use another method to describe
the relative acidity and alkalinity of a solution. The pH scale serves the purpose.
howacidic nowalkaline
*** The term pH --- the p must be written as small letter, while H is capital letter***
pH
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
D
More acidic Less acidic Less alkaline →
O
More alkaline
moreconcentrated Lymoreconcentrated
Lamorecorrosive
morecorrosive
◼ Universal indicator and pH paper
1. Require acat
smalldrops
amount of solution only
Pros
2. No calibration is needed
1. Cannot be used to measure pH value of dark-coloured solution
Cons 2. Cannot be reused
3. A rough value of pH value indicated with colour chart
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Integrated Science Chapter 9 Common acids and alkalis
Procedures
(Refer to textbook P.19-20)
Results
pH value of
measured
distilled oven baking soda
by lemon juice apple juice
water cleaner solution
pH paper 7 13 11 1 3
Universal
7 13 11 1 3
indicator
Discussion
1. Classify the solution as a/an acid, neutral solution or alkali.
C
Acid: Lemon juice, apple juice
➢ pH meter
◼ is an electronic instrument;
◼ requires calibration before use (with buffer solutions of accurately known pH).
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Integrated Science Chapter 9 Common acids and alkalis
9.3 Neutralization
➢ It is a chemical change.
◆ In nucleus
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Integrated Science Chapter 9 Common acids and alkalis
◼ We can arrange the elements in increasing order of atomic number to have the
following series of first 20 elements.
1 Hydrogen H 11 Sodium Na
2 Helium He 12 Magnesium Mg
3 Lithium Li 13 Aluminium Al
4 Beryllium Be 14 Silicon Si
5 Boron B 15 Phosphorus P
6 Carbon C 16 Sulphur S
7 Nitrogen N 17 Chlorine Cl
8 Oxygen O 18 Argon Ar
9 Fluorine F 19 Potassium K
10 Neon Ne 20 Calcium Ca
2. Usually, they are set from the first or first two letters of the name of the element.
3. In some cases, they are set from the Latin name of the element.
e.g. Sodium --- Na (from Latin name [Natrium])
Potassium ---- K (from Latin name [Kalium])
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Integrated Science Chapter 9 Common acids and alkalis
In this topic, we will focus on the two types of changes found in neutralization.
a. Changes in pH
Practical 9.5 Change in pH value during neutralization [Amended]
Materials and apparatus
Apparatus Chemicals
25 cm3 Burette 1 Dilute sodium hydroxide solution
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10 cm Measuring cylinder 1 Dilute hydrochloric acid
Stand and burette clamp 1 Universal indicator
50 cm3 Conical flask 2 Methyl orange
100 cm3 Beaker 1 (an acid alkali indicator)
White tile 1
Procedures
Part 1 How to fill a burette?
Burette works similar to a measuring cylinder, yet it can control the flow of solution with a
valve called stopcock.
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Integrated Science Chapter 9 Common acids and alkalis
Results
Volume of acid
0 1 2 3 4 5 6 7
added (cm3)
pH 11 11 11 11 11 11 8 2
Volume of acid
8 9 10 11 12 13 14 15
added (cm3)
pH 2 1 1 1 1 1 1 1
Discussion
1. What is the volume of dilute hydrochloric acid needed to completely neutralize the
dilute sodium hydroxide solution?
6cm3
2. Describe the change of pH when dilute hydrochloric acid is added to dilute sodium
hydroxide solution.
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Integrated Science Chapter 9 Common acids and alkalis
➢ Determine the volume of acid or alkali needed for complete neutralization using graphical
method.
We can make a plot of the pH value against the volume of acid or alkali added to find the
volume of acid or alkali needed for complete neutralization.
pH 7 pH 7
0 10 0
Isami 20 30 10 20 30
3
Volume of alkali added (cm ) Volume of acid added (cm3)
totalv 36cm
18cm is needed to neutralize
◼ How to find the volume of acid or alkali needed for complete neutralization?
➔ Find the section of curve which has the most significant change in pH.
➔ Trace the corresponding volume of acid or alkali on the x-axis.
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Integrated Science Chapter 9 Common acids and alkalis
a
12
O 2
0
5 10 15 20 25
3
volume of X added (cm )
X : 2 , Y : 12
28 cm3
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Integrated Science Chapter 9 Common acids and alkalis
Procedures
(Refer to textbook P.33)
Results
1. Is there any residue left on the watch glass? If yes, describe the appearance of the
residue on the watch glass.
Yes. White solids/powders are formed on the watch glass.
Discussion
1. Suggest the substance that evaporated while the solution was being heated.
mm
water
name of salt = (name of metal from the alkali) + (converted name from the acid)
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Integrated Science Chapter 9 Common acids and alkalis
The following example shows how to express the word equation with chemicals given.
As you have learned the chemical symbols of some elements, let’s convert the names of
salts into chemical formulae. The following table shows the chemical formulae of the salts
formed from the above neutralization reactions.
*** The method to find the chemical formulae of salts will be discussed in F.3 chemistry
*** The chemical formula of water is H2O.
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Integrated Science Chapter 9 Common acids and alkalis
Reactant Product
H: 1+2=3 O: 2 H: 2 O: 1
Cl : 1 Ca : 1 Cl : 2 Ca : 1
Step 3 Spot out any elements that are not in equal number. Multiply one or some of
the chemicals to balance the number. Add the number to be multiply in front
of the chemical formulae.
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Integrated Science Chapter 9 Common acids and alkalis
b. Changes in mass
9.7 Is mass conserved in neutralization? [Demonstration]
Materials and apparatus
(Refer to textbook P.39)
Procedures
(Refer to textbook P.39-40)
Results
Initial mass of the test tubes and the Final mass of the test tubes and the
solutions (m1) (g) solutions (m2) (g)
Discussion
1. Referring to the colour of the resulting solution in Part I, explain whether neutralization
occurs between dilute sulphuric acid and dilute barium hydroxide solution.
Yes. It is because the colour of the solution is changed from blue to red gradually.
2. What did you observe in tube B after pouring the dilute sulphuric acid into the dilute
barium hydroxide solution?
White precipitate was formed.
3. What is the relationship between m1 and m2? Suggest whether there is a change in mass
in neutralization.
m1 is equal to m2. There is no change in mass in neutralization.
Conclusion
Mass is conserved in neutralization.
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Integrated Science Chapter 9 Common acids and alkalis
Procedures
(Refer to textbook P.45-46)
Results
Part 1 Test for hydrogen
The burning splint gives a “pop” sound .
a “pop” sound is
Zinc Zn Yes Yes
heard
a “pop” sound is
Magnesium Mg Yes Yes
heard
a “pop” sound is
Iron Fe Yes Yes
heard
No observable
Copper Cu No No
change
Discussion
1. Which of the metals reacts with dilute hydrochloric acid?
2. When the metal(s) you stated in Q.1 react(s) with dilute hydrochloric acid,
(a) what kind of gas is produced? Hydrogen
(b) how does the size of the metal samples change? Decreases gradually
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Integrated Science Chapter 9 Common acids and alkalis
In Practical 9.8, dilute hydrochloric acid reacted with zinc, magnesium and iron. Hydrogen
was produced in the reactions. The metal samples decreased in size. In other words, the acid
corroded the metals.
Name of salt formed from the reaction between dilute acid and metals
Metal
Zinc Magnesium Iron
Acid
Hydrochloric
Zinc chloride Magnesium chloride Iron chloride
acid
Sulphuric
Zinc sulphate Magnesium sulphate Iron sulphate
acid
As taught in Ch.9.3, you may use the chemical equation to represent a chemical reaction.
The following table shows the chemical formulae of the salts formed from the reaction
between dilute acid and metals.
Chemical Formulae of salt formed from the reaction between dilute acid and metals
Metal
Zn Mg Fe
Acid
HCl ZnCl2 MgCl2 FeCl2
2 HCl + Zn → ZnCl2 + H2
(b) Adding a magnesium ribbon into dilute sulphuric acid
H2SO4 + Mg → MgSO4 + H2
(c) Adding an iron nail into dilute nitric acid
2 HNO3 + Fe → Fe(NO3)2 + H2
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Integrated Science Chapter 9 Common acids and alkalis
Procedures deliverytube
be
must immersed Exit
(Refer to textbook P.45-46) inlimewater
Results
Changes from
Marble Yes Decrease gradually
colourless to milky
Changes from
Limestone Yes Decrease gradually
colourless to milky
Discussion
1. Which of the solid(s) reacts with dilute hydrochloric acid?
Marble, limestone
2. When the solid(s) you stated in Q.1 react(s) with dilute hydrochloric acid,
(a) what kind of gas is produced? Carbon dioxide
(b) how does the size of the solid samples change? Decrease gradually
Building materials like marble and limestone contain calcium carbonate (CaCO3).
When they come into contact with dilute acids, the calcium carbonate reacts with the
acids to produce water and carbon dioxide. The building materials become corroded
as a result.
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Integrated Science Chapter 9 Common acids and alkalis
➢ General word equation of reaction between dilute acid and calcium carbonate:
As taught in Ch.9.3, you may use the chemical equation to represent a chemical reaction.
The following table shows the names and chemical formulae of the salts formed from the
reaction between dilute acids and calcium carbonate.
Name and chemical formulae of salt formed from the reaction between dilute acid
and calcium carbonate
Acid Name of salt formed Chemical formulae
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Integrated Science Chapter 9 Common acids and alkalis
Glossary
Vocabulary Meaning
Acid (n.) Substance that are soluble in water to give a solution that has a sour
taste
Alkali (n.) Substance that are soluble in water to give a solution that gives a
slippery feel and some of them have a bitter taste
Acidic (adj.) To describe a solution has a pH < 7 at 25°C
Alkaline (adj.) To describe a solution has a pH > 7 at 25°C
Neutral (adj.) To describe a solution has a pH = 7 at 25°C
Acid-alkali indicator (n.) To show a distinct colour when added to an acidic solution and an
alkaline solution correspondingly
Litmus (indicator) (n.) Available as red and blue litmus solution and paper
Acidity (n.) How acidic of a solution
Alkalinity (n.) How alkaline of a solution
pH scale (n.) A range of pH value, generally from 0 to 14
pH value (n.) A numeral value that has no unit, which is used to show the relative
acidity of a solution
Universal indicator (n.) To show the relative acidity and alkalinity of a non-coloured solutions
with reference to a colour chart
pH paper (n.) Paper form of universal indicator
pH meter (n.) An electronic device used to measure the accurate pH value of solutions
of any colour. Requires calibration before use.
Neutralization (n.) Reaction between acid and alkali which gives salt and water as only
product
Physical change (n.) A process that has no new substance formed
Chemical change (n.) A process that has new substance formed
Atom (n.) The simplest unit of matter, consist of proton, neutron and electron
Element (n.) The pure substance that made up of same kinds of atoms
Atomic number (n.) The number of protons in an atom
Chemical symbol (n.) The abbreviated form of the name of an element
Chemical formula (n.) Represent the chemical composition of a pure substance with chemical
symbols
Chemical equation (n.) Represent the chemical change with corresponding chemical formulae
include. Balancing of equation is required.
Corrosion (n.) A process which a solid is chemically dissolved.
Corroded (v.)(adj.) To describe the solid which is chemically dissolved.
Acid rain (n.) Environmental degradation caused when acidic pollutant in air
dissolves in rainwater.
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Summary table for names of salts
Chemical Sodium Potassium Calcium Calcium
Zinc Magnesium Iron
Acid hydroxide hydroxide hydroxide carbonate
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Integrated Science Chapter 9 Common acids and alkalis
Extra notes:
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