Chapter 7

Solution

4. A glucose solution weighing 200 g contains 36 g

SECTION - A
water. The molal concentration of solution is
Objective Type Questions
164 1000 200 1000
1. The boiling temperature and composition curve of (1)  (2) 
180 36 180 200
“water ethanol” solution is given below.
36 1000 164 1000
(3)  (4) 
180 55.5 180 200
Temperature

A 5. 1 kg of 0.3 mole glucose solution in water is

Boiling

B cooled to – 3.2°C. What weight of ice would be

separated out if a solution containing 50 g ethylene
C
glycol in 0.2 kg water freezes at – 9.3°C?

0 1 (1) 960 g (2) 784 g

Mole fraction of B
At point ‘C’, the mixture has ethanol 95.8% by (3) 50 g (4) 37.2 g
weight in vapour phase. If this solution is boiled at 6. Correct order of depression in freezing point of
78.13°C, then percentage by weight of water in following aqueous solutions
liquid phase is (boiling temperature = 78.13°C)
A. 0.1 M NaCl B. 0.1 N BaCl2
(1) 95.8% (2) 4.2%
C. 0.3 M Glucose D. 0.1 M K4[Fe(CN)6]
(3) 80.8% (4) 43.5%
(1) D < B = C < A
2. If the total vapour pressure of the liquid mixture A
and B is given by the equation P = 160 XA + 80, (2) B < A < C < D
then the ratio of the vapour pressure of the pure (3) D < C < A < B
liquids A and B is given by
(4) A < B = C < D
(1) 1 : 2 (2) 2 : 3
7. Which of the following passes through
(3) 2 : 5 (4) 3 : 1
semipermeable membrane?
3. A solution containing 0.1 mole of urea in 1 L of
(1) Solute (2) Solvent
glacial acetic acid, when cooled the first crystal
which appears at the freezing point contain the (3) Both (1) & (2) (4) Only colloids
molecules of 8. Which one of the following is not an ideal solution?
(1) Urea
(1) C2H5Br and C2H5I mixture
(2) Acetic acid
(2) C6H5Cl and C6H5Br mixture
(3) Both urea and acetic acid
(3) C6H6 and C6H5CH3 mixture
(4) Either of these depending upon experimental
(4) C2H5Cl and C2H5OH mixture
conditions
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74 Solution Last Leap for NEET (Part-II)

9. The plant cells contract, when placed in 17. Solutions A, B, C and D are respectively 0.1 M
urea, 0.05 M KBr, 0.05 M MgCl2 and 0.1 M AlCl3.
(1) Hypotonic solution (2) Hypertonic solution
Which one of the following pair is isotonic?
(3) Isotonic solution (4) Both (1) & (2)
(1) A and B (2) B and C
10. 0.1 molal aqueous solution of sodium bromide (3) A and D (4) A and C
freezes at –0.335°C at atmospheric pressure. Kf
18. 0.2 moles of KCl and 0.1 mole of MgCl 2 were
for water is 1.86 K kg mol–1. The percentage of
dissolved in water to have 500 ml of solution, the
dissociation of the salt in solution is
molarity of Cl– ions is
(1) 40 (2) 60 (1) 0.8 M (2) 0.4 M
(3) 80 (4) 90 (3) 0.04 M (4) 0.08 M
11. 0.2 molal solution of a weak electrolyte AB is 20% 19. A 0.004 M solution of K4[Fe(CN)6] is isotonic with
dissociated. Freezing point of the solution would 0.01 M solution of urea at same temperature. The
be [Kf = 1.86°C/m]
molarity of K  in the solution will be
(1) – 0.90°C (2) – 0.45°C (1) 0.375 M (2) 3 M
(3) – 0.25°C (4) – 0.71°C (3) 0.006 M (4) 0.015 M
12. At a particular temperature, the vapour pressure 20. The boiling point of water in pressure cooker is
of two liquids, A and B are 140 and 160 mm Hg (1) 100°C (2) > 100°C
respectively. If 2 moles of A and 6 moles of B are
(3) < 100°C (4) 25°C
mixed to form an ideal solution, its vapour pressure
(mm Hg) at the same temperature will be 21. Which statement is correct?
transferred to
(1) 155 (2) 110 vessel of 200 ml
Case I
at same temperature
(3) 115 (4) 130
transferred to another
13. Vapour pressure of 1 molal aqueous solution of vessel of 100 ml capacity
Case II
100 ml ether at double temperature
solute at 100°C is
(1) In case-I vapour pressure decreases while
(1) 1.00 atm (2) 0.9823 atm increases in case-II
(3) 0.0177 atm (4) 0.80 atm (2) Vapour pressure increases in both the cases
14. 7.483 × 105 Nm–2
osmotic pressure is found for (3) Vapour pressure decreases in both the cases
0.1 M Kx[Fe(CN)6] which dissociate 50% at 300 K, (4) Vapour pressure remains same in case-I while
the value of x is increases in case-II
(1) 1 (2) 2 22. Calculate the molality of a solution of urea in
(3) 3 (4) 4 acetic acid if the mole fraction of urea in solution
is 0.5 (Molecular weight of urea = 60)
15. On mixing 10 ml of CH 3COCH 3 and 40 ml of
50 25
CHCl3, the total volume of the solution is (1) (2)
3 3
(1) < 50 ml (2) > 50 ml
100 40
(3) = 50 ml (4) Cannot be predicted (3) (4)
3 3
16. When mercuric iodide is added to the aqueous
23. The value of Henry’s law constant
solution of KI, the
(1) Increases with increase in temperature
(1) Freezing point is raised
(2) Decreases with increase in temperature
(2) Freezing point is lowered
(3) Increases with decrease in temperature
(3) Freezing point does not change (4) Independent of temperature and depend only
(4) Boiling point does not change on pressure

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Last Leap for NEET (Part-II) Solution 75
24. If P° and P are the vapour pressures of pure (1) Flow of solvent molecules occurs from C1 to C2
solvent and solution of nonvolatile solute only
respectively and n1, n2 are moles of solvent and (2) Flow of solvent molecules occurs from C2 to C1
solute, then which of the following relation holds only
good for a solution of all concentrations?
(3) Flow of solvent occurs from C1 to C2 and C2 to
P  P n2 P  P n2 C1 also
(1)  (2) 
P n1  n2 P n1 (4) Flow of solute occurs from C1 to C2

P  P n2 P  P n2 29. The osmotic pressure of a solution obtained by

(3)  (4)  mixing 100 ml each of 1.8% (w/v) glucose (M =
P n1 P n1  n2
180) solution and 0.4% (w/v) NaOH (M = 40)
25. The relation Tb = Kbm (where Tb is elevation in solution at 300 K will be (Assume complete
boiling point and 'm' is molality of solution) holds ionization of NaOH)
good for (1) 2.46 atm (2) 3.69 atm
(1) Solutions of any solute (3) 5.42 atm (4) 7.38 atm
(2) Dilute solutions of nonvolatile solute only 30. Which of the following solution will have minimum
(3) Solutions of all concentrations but of nonvolatile vapour pressure?
solute (1) 1 N NaCl (2) 1 N MgCl2
(4) Dilute solution of volatile solute only (3) 1 N AlCl3 (4) 1 M sucrose
26. Which of the following is correct statement? 31. A solution of 5.85%(w/v) NaCl has boiling point
(1) Azeotropes are formed in non ideal solution at equal to 5.8%(w/v) Mg(OH)2 solution. If NaCl is a
all concentrations strong electrolyte then what will be the degree of
dissociation of Mg(OH) 2? (Assume molarity =
(2) A solution boils at constant temperature only molality)
when it forms an azeotrope
(1) 1 (2) 0.5
(3) Maximum boiling azeotropes show a maxima
(3) 0.75 (4) 0.33
in pressure composition curve
32. Which of the following is a chemical
(4) Minimum boiling azeotropes show a maxima in
semipermeable membrane?
temperature composition curve
(1) Pig’s bladder (2) Parchment paper
27. The correct relation for Kb is
(3) Cellophane (4) Copper ferrocyanide
RT02
(1) K b  33. At 17ºC the osmotic pressure of sugar solution is
M  1000  l v
580 torr. The solution is diluted and the temperature
RT02 is raised to 57ºC. The osmotic pressure is found
(2) K b  to be 165 torr. The extent of dilution is
M  1000  Hv
(1) 2 times (2) 4 times
MRT02
(3) K b  (3) 6 times (4) 8 times
1000  l v
34. Liquid A and B form solution deviating from Raoult’s
MRT02
(4) K b 
law and the former has stronger intermolecular
1000  Hv forces, if XA and YA are the mole fractions of ‘A’ in
(M = mol. mass of solvent, T0 = boiling point of solution and in vapour in equilibrium respectively,
solvent, l v, H v = latent heat and enthalpy of then
vaporisation respectively) YA YA
(1) X  1 (2) X  1
28. When two solutions of concentrations C1 and C2 A A

(C 1 > C 2 ) are separated by semipermeable YA

(3) X  1 (4) YA + XA = 1
membrane then A

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76 Solution Last Leap for NEET (Part-II)

35. The mole fraction of a solute in aqueous solution (1) Increases 10 times
is 0.5. The molality of solution is
1
(1) 9.80 (2) 25.65 (2) Decreases th times
10
(3) 55.55 (4) 15.75 (3) Increases 100 times
36. Which of the following set of aqueous solutions are (4) Remains as such
having same freezing point?
42. Molarity of liquid nitric acid, if density of its
(1) 1 M NaCl and 2 M glucose aqueous solution is 0.95 g/cc
(2) 0.05 M urea and 0.025 M HCl (1) 15 (2) 9.5
(3) 100 ml 0.1 M Na2SO4 and 100 ml of 0.1 M (3) 0.15 (4) 0.95
Ca(OH)2
43. Calculated molecular mass is greater than
(4) All of these observed molecular mass for which of the given set
37. The difference between elevated boiling point and of examples?
depressed freezing point of an aqueous solution is (1) 1 Maq MgCl2, 1 Maq Urea, 1 Maq sucrose
102ºC. The molality of the solution if it contains
non-volatile and non-electrolyte solute will be (2) 0.1 Maq Al2(SO4)3, 0.1 Maq NaCl, 0.1 M acetic
acid in benzene
2 102
(1) K  K (2) K  K (3) 0.1 Maq HCl, 0.1 Maq H2SO4, 0.1 Maq Ca(OH)2
f b b f
(4) Both (2) & (3)
K f  Kb 3
(3) (4) K  K 44. When HNO 3 is mixed in H 2 O, which of the
3 b f
following set of information will be correct?
38. Which of the following solutions will be having the
maximum freezing point? (1) Ptotal  PHNO3  PH2 O , Vmix  –ve

M (2) HNO 3 – H 2 O interaction > HNO 3 – HNO 3

(1) Al (SO4)3 interaction, Smix > 0
10 2
(2) 18% (wt/volume) glucose solution (3) Smix < 0, Vmix < 0
N (4) Hmix < 0, it forms minimum boiling azeotrope
(3) Na2SO4
5 45. Following solutions are given below
(4) 3.42% (wt/volume) sucrose solution I. Centimolar magnesium bromide solution
39. Total vapour pressure of a mixture of 2 mole A
II. Centinormal potassium chloride solution
(P°A = 200 torr) and 4 mole B (P°B = 400 torr) is
250 mm. Therefore solution shows III. Normal solution of urea

(1) Positive deviation from Raoult’s law IV. Molar solution of aqueous benzoic acid

(2) Negative deviation from Raoult’s law Correct order of freezing point is given below as

(3) No deviation (1) III > IV > I > II

(4) Molecular masses of A and B are also required (2) II > I > IV > III
40. In the preparation of solution of two liquids by (3) IV > III > I > II
mixing them, Vmixing is found to be negative, then (4) II > I > III > IV
the values of Hmixing and Smixing will be
46. Ebullioscopic constant calculation depends upon
(1) H > 0 & S > 0 (2) H < 0 & S > 0
(1) Freezing point of solvent
(3) H < 0 & S < 0 (4) H > 0 & S < 0
(2) Molecular mass of solute
41. A liquid (v.p. = 100 mm Hg) is transferred from a
vessel of 100 ml capacity to 1000 ml capacity, (3) Enthalpy of vapourisation of solvent
hence its vapour pressure (4) All of these

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Last Leap for NEET (Part-II) Solution 77
47. A 1% solution of a non electrolyte having molecular 54. Which of the following is correct?
mass approximately 69 is isotonic with 5% (w/v)
P0T0
solution of (1) Pt .T 
1  T0
(1) Urea (2) Glucose
 273  t 
(3) Potassium chloride (4) Sucrose (2) P0  Pt  
 273 
48. Vapour pressure of pure water, if lowering of vapour
P0  t
pressure becomes 0.125 torr when 50 g of cane- (3) Pt  P0 
273
sugar is added to 0.5 litre of water is
(4) All of these
approximately
55. Which of the following is correct?
(1) 0.03 atm (2) 23.8 atm
(1) Solubility of CO 2 in water is explained by
(3) 30 atm (4) 2.3 atm
Henry’s law
49. When placed in hypotonic solution, plant cell will
(2) Henry’s law can be applied even at very low
(1) Remain as such temperature
(2) Shrink (3) Henry’s law cannot be applied in solubility of
(3) Swell O2 in blood
(4) Both shrink and swell (4) Both (1) & (3)
50. What will be the concentration of chloride ion when 56. 18 g glucose and 34.2 g sucrose are added in one
100 ml of 0.1 M AgCl is mixed with 200 ml of 0.05 litre water, the osmotic pressure of solution at 27°C
M BaCl2 solution? is (assume no volume change)
(1) 0.1 M (2) 0.05 M (1) 4.9 atm (2) 2.4 atm
(3) 0.2 M (4) 0.01 M (3) 9.6 atm (4) 3.55 atm
51. In which of the following boiling point will not be 57. An aqueous solution of AB has boiling point of
increased? 101.8°C when it is 100% ionised. The freezing
(1) Addition of KI in 1 M glucose solution point of the same solution is –1.80°C. Hence AB
(Kb/Kf = 0.3)
(2) Addition of KI in 1 M urea solution
(1) Is 100% ionised at freezing point of solution
(3) Addition of KI in 1 M HgI2 solution
(2) Is 50% ionised at freezing point of solution
(4) Addition of KI in 1 M NaCl solution
(3) Neither dissociated nor associated at freezing
52. 10 g of a non-volatile solute when dissolved in
point of solution
100 g benzene raises its boiling point by 1°.
Molecular mass of the solute is (Kb for benzene = (4) Forms a associated molecule at freezing point
2.53 Kg mol–1) of solution
(1) 25 58. Which has maximum molal depression constant?
(2) 253 (1) 0.1 M aq. KCl
(3) 44 (2) 0.1 M aq. sodium sulphate
(4) 180 (3) 0.2 M aq. barium phosphate
53. If an aqueous solution of sugar is allowed to (4) Same for all
freeze, then crystals of which will be separated out
59. What will be the resultant osmotic pressure if 300
first?
ml of solution with osmotic pressure 2 atm is
(1) Sugar mixed with 200 ml of same solution with osmotic
(2) Water pressure 3 atm, at 27°C?

(3) Sugar + glucose (1) 2 atm (2) 3 atm

(4) Glucose + Fructose (3) 2.5 atm (4) 2.4 atm

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78 Solution Last Leap for NEET (Part-II)

60. A solution of W g urea in 500 g of water is cooled 67. Solution A is 1 M of toluene in benzene but B
to –0.5°C. 128 g of ice separates out. What is the is 1 m of toluene in benzene having density
value of W? (Kf for water = 1.86 K kg/mol) 0.85 g/cc, then correct statement
(1) 4 g (2) 6 g (1) b.p. of A < b.p. of B
(3) 5 g (4) 8 g (2) b.p. of A > b.p. of B
61. Solubility of a gas X in water increases by lowering (3) b.p. of A = b.p. of B
the temperature. This means that
(4) f.p. of A = f.p. of B
(1) Dissolution process is endothermic
68. If t moles of a solute which dimerises is dissolved
(2) Dissolution process is independent of in one L-water, then degree of association  is
temperature given by
(3) Sdissolution > 0
Kb 2(K b t – Tb )
(1)   (2)  
(4) Hdissolution < 0 Tb Kb t
62. The molecular weight of benzoic acid in benzene 2Tb Tb
as determined by depression in freezing point (3)   2  (4)  
Kb t 2K b t
method corresponds to
69. Solvent which is better to be used during
(1) Ionization of benzoic acid ebullioscopic measurement has
(2) Dimerization of benzoic acid (1) High Kb (2) Low Kb
(3) Trimerization of benzoic acid (3) Kf = Kb (4) Unpredictable
(4) Solvation of benzoic acid 70. 0.9 gm of a hydrocarbon with molecular formula
63. Van’t Hoff factor of 80% ionised Hg2Cl 2 in its H2(CH2)n when dissolved in 180 gm of solvent
aqueous solution will be freezes at 8.48°C. If freezing point of pure solvent
is 9°C, then the formula of hydrocarbon is
(1) 1.6 (2) 2.6
(Kf = 12 K kg mol–1)
(3) 3.6 (4) 4.6
(1) C8H6 (2) C8H18
64. Assuming the salts to be unionised in solution.
Which of the following has the highest osmotic (3) C8H16 (4) C7H8
pressure? 71. 0.5% (w/v) aqueous solution of KCl was found to
(1) 1% (w/v) CsCl (2) 1% (w/v) RbCl freeze at – 0.24°C. The degree of dissociation of
the solute at this concentration will be (Kf for H2O
(3) 1% (w/v) KCl (4) 1% (w/v) NaCl = 1.86 K kg mol–1).
65. Which of the following is an intensive property?
(1) 74.5% (2) 19.2%
(1) Boiling point of the solution
(3) 92% (4) 48%
(2) Freezing point of the solution
72. Select the correct statement
(3) Osmotic pressure
(1) Freezing point, boiling point and vapour
(4) All of these pressure are all colligative properties
66. A solution containing 30 g of a non-volatile solute (2) The freezing point, boiling point and vapour
exactly in 90 g water has a vapour pressure of pressure all decrease when a solute is
2.8 kPa at a given temperature. When 18 g of dissolved in a solvent
water is added to the solution, the new vapour
(3) Plots of freezing point versus molal
pressure becomes 2.9 kPa at the same
concentration for ethyl alcohol, propyl alcohol
temperature, the molar mass of the solute is
and butyl alcohol dissolved in water will all be
(1) 34 g mol–1 (2) 23 g mol –1 linear with different slopes
(3) 46 g mol–1 (4) 17 g mol –1 (4) All are incorrect

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Last Leap for NEET (Part-II) Solution 79
73. The vapour pressure of two liquids A and B are 100 78. Equal moles of benzene and toluene are mixed.
and 80 torr respectively. The total pressure of the The vapour pressures of benzene and toluene in
solution obtained by mixing 2 moles of A and 3 pure state are 700 and 600 mm Hg respectively.
moles of B would be The mole fraction of benzene in vapour state is
(1) 20 torr (2) 36 torr (1) 0.50 (2) 0.7
(3) 88 torr (4) 180 torr (3) 0.53 (4) 0.6
74. Which of the following is the correct order of boiling 79. At freezing point of a solution which of the
points of the following solutions? (Assume following are in the equilibrium?
complete dissociation of salts)
(1) Liquid solvent, solid solvent
a. 0.15 M NaCl
(2) Liquid solvent, solid solute
b. 0.4 M glucose solution
c. 0.15 M CaCl2 solution (3) Liquid solute, solid solvent

d. 0.15 M urea solution (4) Liquid solute, solid solute

(1) d < a < c < b (2) d < b < a < c 80. Vapour pressure of a solution is 4.5 atm. This
solution has been separated from the solvent by
(3) d < a < b < c (4) d < c < b < a
semipermeable membrane. If 5.2 atm external
75. When you dissolve sugar in a glass containing ice pressure is applied over the solution, then
and water in equilibrium, and assuming that no
heat enters or leaves the system (1) Osmosis will be stopped

(1) Some of the ice should melt and the (2) Osmosis will be held in opposite direction
temperature of water/ice mixture should (3) Solute molecules will start migrating
increase
(4) No effect on osmosis
(2) Some of the ice should melt and the
temperature of the water/ice mixture should 81. van’t Hoff’s factor for a dilute solution of potassium
decrease argentocyanide is (assuming,  = 1)

(3) Some of the water should freeze and the (1) 2 (2) 0.25
temperature of the water/ice mixture should (3) 0.5 (4) 3
increase
82. A 1.2 M solution of NaCl is isotonic with 2.4 M
(4) Some of the water should freeze and the solution of glucose. Calculate the van’t Hoff’s factor
temperature of the water-ice mixture should of NaCl solution (Assuming NaCl completely
decrease dissociates)
76. At 323 K, the vapour pressure in millimeters of Hg
(1) 2.36 (2) 1.50
of a methanol-ethanol solution is represented by
the equation p = 120 xA + 140, where xA is the (3) 2 (4) 1.00
mole fraction of methanol. Then the value of 83. 5.85 g NaCl is dissolved in 200 ml of water at
p
lim A is 27°C. The osmotic pressure of solution will be
x A 1 x (Assume that NaCl is completely ionised)
A
(1) 250 mm Hg (2) 140 mm Hg
(1) 6 atm (2) 12.315 atm
(3) 260 mm Hg (4) 20 mm Hg
(3) 24.63 atm (4) 30 atm
77. x mole of KCl and y mole of BaCl 2 are both
dissolved in 1 kg of water. Given that x + y = 0.1 84. A 0.1 molal solution of nitrous acid freezes at
and K f for water is 1.86 K/molal. What is the – 0.198ºC. The Kf of water is 1.86 K kg mole–1.
observed range of Tf if the ratio of x and y is The percentage ionization of nitrous acid at this
varied? concentration is

(1) 0.37° to 0.55° (2) 0.185° to 0.93° (1) 15% (2) 17.5%
(3) 0.56° to 0.93° (4) 0.37° to 0.93° (3) 9.6% (4) 6.5%

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80 Solution Last Leap for NEET (Part-II)

85. The mole fraction of benzene in solution containing

30% mass in CCl4 is 0.0001 M 0.00001 M 0.001 M
(1) 0.20 (2) 0.45 90. KCl KCl KCl
(3) 0.83 (4) 0.65
A B C
86. 0.6 ml of acetic acid having density 1.06 g/ml, is
dissolved in one litre of water. The depression in Which of the following is correct about van’t Hoff
freezing point observed is 0.02°C. van’t Hoff factor factor of A, B & C? (Assume complete ionization
of acetic acid is (assuming molarity = molality and of KCl)
Kf = 1.86 K kg mol–1) (1) iA > iB > iC (2) iA < iB < iC
(1) 1.88 (approx) (2) 1.99 (approx) (3) iA > iB < iC (4) iA = iB = iC
(3) 1.06 (approx) (4) 2.6 (approx)
91. Which of the following substance will sublime?
87. Henry’s law constant (KH) values for P, Q, R and
S are 40.39, 1.67, 1.83 × 10 –5 and 0.413 (1) H2O (ice) (2) Graphite
respectively. Which one has maximum solubility? (3) Diamond (4) CO2 (dry ice)
(1) P (2) Q
92. Choose the correct statement(s)
(3) R (4) S
88. Choose the incorrect statement (1) Ethanoic acid dimerises in benzene
(1) When methyl alcohol is added to water, boiling (2) Ethanoic acid dissociates in water
point of solution increases (3) van’t Hoff factor of CH3COOH is less than 1 in
(2) Lowering of vapour pressure of a solution benzene while that in water is more than 1
causes depression in freezing point
(4) All are correct
(3) Molarity of a solution in liquid state changes
with temperature 93. Consider the following graph
(4) When a non-volatile solute is added to a
volatile solvent, elevation in boiling point is 1 atm
Vapour pressure

observed
Solution
89. Which of the following graph is correct for an ideal
Liquid
binary liquid solution containing nonvolatile solute? solvent
Frozen
solvent
(1) Total V.P.
T1 T2 T3 T4
Temperature
XA = 1 XA = 0 Choose the correct option(s) :
XB = 0 XB = 1
(1) Depression in freezing point = T2 – T1
(2) Elevation in boiling point = T3 – T4
(2) Total V.P.
(3) Boyle temperature = T3 – T2
(4) All are correct
XA = 1 XA = 0 94. 200 mL of an aqueous solution of a protein
XB = 0 XB = 1 contains 0.63 g of the protein. The osmotic
pressure of such a solution at 27°C is found to be
2.57 × 10–3 bar. What will be the approx molar
(3) Total V.P.
mass of the protein?
[R = 0.083 L bar mol–1 K–1]
XA = 1 XA = 0
(1) 61022 g mol–1 (2) 30520 g mol–1
XB = 0 XB = 1
(4) All are correct (3) 15255.5 g mol–1 (4) 122044 g mol–1

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Last Leap for NEET (Part-II) Solution 81
95. 31 g of ethylene glycol (C2H6O2) is mixed with 102. Which of the following solution has maximum
500 g of water. What will be the freezing point of boiling point?
water? [Kf for water = 1.86 K kg mol–1] (1) 0.1 M KNO3 (2) 0.01 M CH3COOH
(1) 269.14 K (2) 271.29 K (3) 0.5 M urea (4) 0.2 M K4[Fe(CN)6]
(3) 275.01 K (4) 273.95 K 103. If 25.6 g of sulphur is dissolved in 100 g benzene,
96. Which is true about azeotropic mixture? solution shows depression of freezing point of
5.12°C. If (Kf)Benzene is 5.12°C kg/mol, then the
(1) It is a constant boiling mixture
best possible structure of sulphur molecule may be
(2) Vapour phase composition and liquid phase given as (Atomic weight of S = 32 g)
composition are same (1) Monoatomic molecule, S
(3) Cannot be separated by simple distillation (2) Diatomic molecule, S2
(4) All are true (3) Crown shape, S8
97. If two solutions have same osmotic pressure then (4) Polymeric shape, Sn
the solution are said to be
104. 0.5 molal aqueous solution of KCl, MgCl2 and
(1) Hypertonic (2) Isotonic FeCl 3 have freezing points T 1 , T 2 and T 3
(3) Hypotonic (4) Isobaric respectively. Which of the following is correct?

98. The magnitude of heat of solution on addition of (1) T1 > T2 > T3

solvent to solution (2) T3 > T2 > T1
(1) Decreases (3) T2 > T1 > T3
(2) Increases (4) T1 > T3 > T2
(3) Remains constant
SECTION - B
(4) Increases or decreases
Assertion - Reason Type Questions
99. If mole fraction of the solvent in a solution
decreases, then In the following questions, a statement of assertion
(A) is followed by a statement of reason (R)
(1) Vapour pressure of solution increases
(1) If both Assertion & Reason are true and the
(2) Boiling point decreases reason is the correct explanation of the
(3) Osmotic pressure increases assertion, then mark (1).
(4) All are correct statements (2) If both Assertion & Reason are true but the
reason is not the correct explanation of the
100. Which one is isotonic with 3 M NaCl aq. solution?
assertion, then mark (2).
(1) 3 M Urea (2) 2 M BaCl2
(3) If Assertion is true statement but Reason is
(3) 1 M AlCl3 (4) 2 M KCl false, then mark (3).
101. Consider the following 0.01 M aqueous solutions (4) If both Assertion and Reason are false
of statements, then mark (4).
I. KCl 1. A : Ethanol water mixture forms minimum boiling
azeotropes.
II. CaCl2
R : 95.4% ethanol in water (by volume), the liquid
III. Glucose
and vapour have the same composition, and no
The relative lowering of vapour pressure will be in further separation occurs.
the order
2. A : C2H5I and C2H5Br form ideal solution.
(1) III > II > I (2) I > II > III
R : The interaction between the components are
(3) III > I > II (4) II > I > III similar to those in the pure components.
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82 Solution Last Leap for NEET (Part-II)

3. A : Azeotropes have different composition in liquid 5. A : When 100 ml of A mixed with 25 ml of B then
and vapour state depending upon the volatility total volume cannot exceed 125 ml.
of components. R : Intermolecular forces between A and B is
always stronger than pure A or pure B.
R : Composition in both, liquid and vapour phase
depends upon volatility of the substance. 6. A : Raoult’s law for the solution of non-volatile
solute can be given as
4. A : A liquid mixture which distil with change in
Pº  Ps nsolute
composition is called zeotropic mixture. 
Ps nsolvent  nsolute
R : Non-ideal solution forms zeotropic mixture at R : Raoult’s law is not applicable for the solution
composition other than a zeotropic point. of FeCl3 in water.

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