12-04-2026

9610ZJA802322250034 JA

PART 1 : PHYSICS

SECTION-III

1) If the switches S1, S2 and S3 in the figure are arranged such that current through the battery is

minimum, find the voltage across points A and B.

2) A uniform disc of radius r and mass m is charged uniformly with the charge q. This disc is placed
flat on a rough horizontal surface having coefficient of friction µ. A uniform magnetic field is present
in a circular region (a > r) but varying as kt3 as shown in figure. Find the time in second after which
the disc begins to rotate.

(Given r = 1 m, m = 18 kg, q = 1C, µ = 0.1m, K = 4, g = 10 m/s2)

3) Two identical hoop of same mass is rigidly attached at their circumference as shown. Now the
system is hinged from point ‘P’ such that it can oscillate. Let 'T1' is the period of oscillation, if system
is slightly displaced from its equilibrium position and oscillation occurs in xy plane. Now system is
turned through 90° such that plane of hoop is yz plane. Let 'T2' is the period of oscillation, if system
is again slightly displaced from its equilibrium position and oscillation occurs again in xy plane. If

the ratio of period of oscillation Then find the value of λ.

4) A solid conducting sphere of radius ‘a’ having charge q is surrounded by a concentric conducting
spherical shell of inner radius 2a and outer radius 3a as shown in figure. The net charge on spherical

shell is –2q. If the amount of heat produced when switch is closed is . Fill the value of

x.

5) A uniform stick of mass 18 kg and length 3 m spins around on a frictionless horizontal plane, with
its Centre of Mass stationary. A mass M is placed on the plane, and the stick collides elastically with
it, as shown (with the contact point being the end of the stick). What should M (in kg) be so that

after the collision, the stick has translational motion, but no rotational motion ?

6) In an interference experiment as shown in the figure, the source plane and screen are separated

by a distance 1m. At a certain position of source, fringe width is and by moving the source

away from mirror along the line AB by 0.6 mm, the fringe width changed to , then wavelength
of light used is (N × 1000) Å, where N is:

7) If the dimensions of B2 l2 C is [Ma Lb Tc], then the value of a + b + c is .........

[Here B, l and C represent the magnitude of magnetic field, length and capacitance respectively]

8) A particle of mass 'm' moves along the quarter section of the circular path whose centre is at the
origin. The radius of the circular path is 'a'. A force newton acts on the particle, where x,
y denote the coordinates of position of the particle. The magnitude of work done by this force in

taking the particle from point A (a, 0) to point B (0, a) along the circular path is . Then find the

value of (x + y).

SECTION-I (i)

1) Two balls are thrown from an inclined plane at angle of projection α with the plane, one up the
inclined and other down the inclined as shown in figure. Then :

h1 = h2 =
(A)

(B)
T1 = T2 =
(C) R2 – R1 = g sin θ. T2 (where T represents time of flight)
(D) None of these

2) A bullet is fired horizontally down an open cylinder of cross-sectional area 10–2m2. When the gun is
fired, bullet is at rest and the volume between the end of cylinder and bullet is 5 × 10–4 m3, and
pressure of gas in this volume is 8P0 where P0 is atmospheric pressure. Gaseous mixture in the
cylinder has γ = 1.5. The bullet moves down quickly, so that no heat is transferred to the gas.
Friction between bullet and the barrel is negligible and no gas leaks around bullet. (P0 = 105 N/m2)

(A) The maximum kinetic energy with which bullet can leave is 150 J
(B) The maximum kinetic energy with which bullet can leave is 250 J
(C) If bullet leaves with maximum kinetic energy, then minimum length of barrel required is 20 cm.
(D) If bullet leaves with maximum kinetic energy, then minimum length of barrel required is 10 cm.

3) A cubical vessel closed at top filled with a liquid of density ρ is moving with acceleration g/2 along
negative x-axis as shown in figure. The level of liquid in the vessel is as shown in figure. The side
view of the level of liquid in vessel is as shown in the figure. The free part of vessel is evacuated :

(A)
Pressure at point (x, z) inside vessel will be 0 for

(B)
Pressure at point (x, z) inside vessel will be (L – ℓ + x – z)ρg for z >

(C)
Pressure at point (x, z) inside vessel will be 0 for

(D)
Pressure at point (x, z) inside vessel will be ρg for

4) A positively charged particle P crosses a region of uniform electric field of intensity E. Velocity u
of the particle at the entry on the left side of the region is perpendicular to the electric field as
shown in the first figure. Speed of the particle at exist on the right side is v1. Now the experiment is
repeated with a uniform magnetic field of induction B superimposed on the electric field as shown in
the second figure, keeping entry velocity of the particle unchanged. In this experiment, speed of the
particle at exist on the right side is v2. What can you conclude regarding the speeds v1 and v2 ?

(A)
If , then v2 < v1

(B)
If , then v2 < v1

(C)
If , then v2 = v1

(D)
If , then v2 < v1

5) The system shown in figure has a natural frequency of 5 Hz for the following data: m = 10 kg, I0 =
5 kg-m2, r1 = 10 cm, r2 = 25 cm. The damper exerts a resistive force given by , where is the
velocity of string connected to the damper. The pulley is free to rotate about point O. When the
system is disturbed by giving
it an initial displacement, the amplitude of free vibration is reduced by 80 percent in 10 seconds.
Assume that the string does not slack during the motion. Neglect gravity (Take : π2 = 10, ℓn5 = 1.6)

(A) The spring constant k is 9 × 104 N/m (approximately).

(B) The spring constant k is 4.5 × 104 N/m (approximately).
(C) The damping constant c is 180 N-s/m (approximately)
(D) The damping constant c is 90 N-s/m (approximately).

6) Two rods of different materials are placed between massive walls as shown in figure. The cross
section of the rods is A their moduli of elastically are E1 and E2 respectively. If rods are heated by T
degrees, then (coefficients of linear expansion of material of rods are α1 and α2 respectively)

(A) the strain produced in both rods is equal.

(B) the stress produced in both the rods is equal.

(C)
the force exerted by one rod on the other is .

(D)
the force exerted by one rod on the other is .

SECTION-I (ii)

1) Choose the correct statement(s) (Take Wiens constant to be equal to 2.9 × 10–3 mK)

An object at room temperature (T = 17°C) emits the maximum thermal radiation

(A)
at wavelength λmax = 10 µm
The temperature to which the object must be heated to give the peak thermal radiation in red
(B) region of spectrum
(λ≈ 725 nm) is 4000°C
The object emits approximately same thermal radiation at the higher temperature at it was
(C)
emitting at room temperature
Ratio of thermal radiation emitted by object at higher temperature to that emitted at room
(D)
temperature is of the order 103.

2) The variation of density (ρ) with temperature (T) of an ideal gas of molecular mass (M) at constant
pressure is plotted as shown in figure. The pressure of the gas at state P will be :-

(A)

(B)
(C)

(D)

3) A train stopping at two stations 5 km apart takes 5 min on the journey from one of the station to
the other. Assuming that it first accelerates with a uniform acceleration α and then have an uniform
retardation β. If units of mass, length, and time are kg, km and min respectively then :-

(A)

(B)

(C)

(D)

4) Six wire each of cross-sectional area A and length l are combined as shown in the figure. The
thermal conductivities of copper and iron are K1 and K2 respectively. The equivalent thermal

resistance between points A and C is :-

(A)

(B)

(C)

(D)

PART 2 : CHEMISTRY

SECTION-III

1)
How many optically active compounds having molecular formula C8H8Br8 will be obtained in above
reaction ?

2) Some aqueous solutions are given below. If ‘x’ be the number of solution(s) whose pH does not
change appreciably by adding small amount of H2SO4. Then find value of x.
(a) 0.1 M NH4CN
(b) 0.1 M NH4OH + 0.1 M NH4Cl
(c) 100 mL, 0.1 M HCl + 100 mL, 0.5 M Ca(OH)2
(d) 100 mL, 0.1 M HCl + 100 mL, 0.2 M NaCN
(e) 100 mL, 0.1 M Ca(OH)2 + 100 mL, 0.4 M H2S
(f) 100 mL, 0.1 M NaOH + 100 mL, 0.2 M HCl
(g) 100 mL, 0.1 M NaOH + 100 mL, 0.2 M K2SO4
(h) 100 mL, 0.5 M CH3COOH + 100 mL, 0.1 M Ba(OH)2
(i) 100 mL, 0.5 M Ca(OH)2 + 100 mL, 0.1 M HCl

3) Consider the following ions:

If the number of ions having S – S or S = S linkage be ‘x’ and the number of ions having

S – O – S linkage be ‘y’, the number of ions having peroxy linkage be ‘z’. Find the value of .

4) If V milliliters of 2.0 M NaOH solution must be added to 100 mL of 0.1 M H3PO4 solution in order

to obtain a buffer solution with pH about 7.2, then calculate .

(The pKa values of H3PO4 are = 2.1 ; = 7.2 and = 12.0 )
Assume the temperature of reaction mixture to be 298 K.

5) Consider the following reaction scheme

How many deutrium are present in the compound D ?

6) The pH of an aqueous solution containing 1M benzoic acid (pKa = 4.20) and 1M sodium benzoate
is 4.5. The volume of benzoic acid solution in 300 mL of this buffer solution is x × 102 mL. What is
the value of x ?

7) How many of below given aromatic compounds are more reactive than Benzene towards
electrophilic aromatic substitution reaction ?
8) Number of molecule which has higher bond dissociation energy than F2
a. Cl2 b. Ι2 c. Br2 d. F2

SECTION-I (i)

1) For the following geometry, which of the inequality is/are correct?

(A)
(B)
(C)
(D)

2) Two moles of a monoatomic ideal gas is taken through a reversible cyclic process starting from
“A” as shown in figure.
The volume ratio . If temperature TA at ‘A’ is 27oC, then choose the correct
option(s)

(A) Temperature of the gas at point ‘B’ is 600 K.

(B) Work done in cyclic process (ABCDA) is -1200 cal.
(C) Work done in the process (C → B) is – 1663.68 cal.
(D) Work done in the process (A → D) is – 1663.68 cal.

3) Choose the only incorrect statement(s) among the following

(A) All boron halides are ionic halides.

(B) Anhydrous aluminium chloride is an ionic compound
(C) Coordination number of Al in AlCl3(s) is 4.
(D) BI3 is the least acidic among all boron halides.

4) For which of the following complexes, IUPAC names is/are correctly matched?

Na [Pt(NH3)BrCl(NO2)] -
(A)
Sodium amminebromidochloridonitrito-N-platinate (II)
(B) [CuCl2 {O = C(NH2)2}2] - Dichloridobis(dicarboxidotetraamine) copper (II)
2 – 2
(C) [PtCl3 (η – C2H4)] - Trichlorido(η - ethene)platinate(II)ion.
4–
(D) [FeCl(CN)4(O2)] - Chloridotetracyanosuperoxoferrate (II) ion

5) Correctly matched product in the given reactions is/are :

(A)

(B)
(C)

(D)

6) Acyl halides can be reduced to aldehydes by treatment with ‘X’. ‘X’ can be

(A) Lithium tri-t-butoxyaluminium Hydride in diglyme at –78°C

(B) 1 Eq. Nickel as the catalyst during hydrogenolysis.
(C) Hydrogenolysis with Pd-BaSO4
(D) BH3–THF/AcOH

SECTION-I (ii)

1) Which of the following statement is incorrect?

+ –
(A) Ammonia reacts with diborane gives B2H6.2NH3 and it is formulated as [BH2 (NH3)2] [BH4]

(B)
The hybridization of contain two d-orbitals.
–
(C) H2CO3/HCO3 buffer system helps to maintain pH of blood below 7.
(D) SiO2 reacts with HF to form a compound containing 4 mole F atoms per mole of compound.

2) An excited H atom emits a photon of wavelength λ in returning to the ground state. If R is the
Rydberg constant, then the quantum number n of the excited state is

(A)
(B)

(C)

(D)

3) A water heater, operating on a hydrocarbon fuel heats water flowing at the rate of 5 kg per
minute, from 27oC to 77oC. If the heat of combustion of hydrocarbon is 20,000 J/g, how much fuel in
g is consumed per minute? (Specific heat of water is 4200 J/Kg – K)

(A) 52
(B) 52.7
(C) 53
(D) 52.5

4)
The product D is :

(A)

(B)

(C)

(D)

PART 3 : MATHEMATICS

SECTION-III

1) If , then value of is

2)

The number of solutions of the equation for x ∈ [–4, 4], is (where [.] denotes
greatest integer function)

3) If a function y = ƒ(x) satisfying is such that ƒ(0) = 1, then the value of

 , where [.] denotes greatest integer function, is

4) Let a vector , where O is origin and P is (2, 0, 2). Vector is rotated about origin by an

angle of in a plane which is perpendicular to XOZ plane to get vector where . Again
is rotated about origin by right angle in XOZ plane to get vector . If V is volume of tetrahedron

whose coterminous edges are , and then value of is equal to

5)

Let a plane P contain two lines

, λ ∈ R and

,μ∈R
If Q(α, β, γ) is the foot of the perpendicular drawn from the point M(1, 0, 1) to P, then 3(α + β + γ)
equals _______.

6) Let , where , and . Let and I be the

identify matrix of order 2. Then the total number of ordered pairs (r, s) for which P2 = –I is

7) Find the number of integral values of α for which the equation x26 + (k2 + 2kα – α – 3) x6 + x4 + 3
= 0 has no real solution for all real values of k.

8) If a differentiable function f(x) satisfies then value of

is

SECTION-I (i)

1) Let the equation x3 + px2 + qx - q = 0, where p, q has 3 real roots in H.P., then

(A)

(B) 9p+2q+27=0
(C) Maximum value of is

(D)

2) Let a, b, c be integers and a2 + b2 + c2 = 2 . Let consider the system

of equations .
Then which of the following statement(s) is/are correct -

(A) The probability that the system of equations has unique solution is 1/2
(B) The probability that the system of equations has infinitely many solutions is 1/2
(C) If a = 0 , then the number of ordered pairs (b, c) for which the system has no solution is 2
(D) The number of integers in the range of ab + bc + ca is 2

3)

Which of the following statements are true ?

(A) If xexy = y + sin2x, then at x = 0, (dy/dx) = 1.

If ƒ(x) ≡ a0x2m+1 + a1 x2m + a3 x2m–1 +.....+ a2m+1 = 0 (a0 ≠ 0) is a polynomial equation with
(B)
rational coefficients then the equation ƒ'(x) = 0 must have a real root. (m ∈ N ).
If (x – r) is a factor of the polynomial ƒ(x) = anxn + an–1xn–1+ an–2xn–2 +.......+ a0 repeated m
(C)
times where 1 ≤ m ≤ n then r is a root of the equation ƒ'(x) = 0 repeated (m–1) times.

(D)
If y = sin–1 (cos sin–1 x) + cos–1 (sin cos–1 x) then is dependent on x.

4) Let , then (where [.] denotes greatest integer function)

(A) number of points where ƒ(x) is non-differentiable is 6

sum of global maximum value and global minimum value of ƒ(x) is
(B)

(C) number of points of extrema of ƒ(x) is 3 points

(D) number of solutions of ƒ(x) = 4 is 3
5) Consider two straight lines, each of which is tangent to both the circle and the
2
parabola y = 4x. Let these lines intersect at the point Q. Consider the ellipse whose center is at the
origin O(0, 0) and whose semi-major axis is OQ. If the length of the minor axis of this ellipse is ,
then the which of the following statement(s) is (are) TRUE ?

(A)
For the ellipse, the eccentricity is and the length of the latus rectum is 1

(B) For the ellipse, the eccentricity is and the length of the latus rectum is

(C) The area of the region bounded by the ellipse between the lines and x = 1 is

(D)
The area of the region bounded by the ellipse between the lines and x = 1 is

6) In a ΔABC, if a,b,c are in AP , then which of the following is/are in A.P (where symbols have their
usual notations) -

(A)

(B) 2r1 + r2 + r3, 2r2 + r1 + r3, 2r3 + r1 + r2

(C)

(D) (sinB + sinC)2 – sin2A, (sinA + sinC)2 – sin2B, (sinA + sinB)2 – sin2C

SECTION-I (ii)

1) Line segments AK1, AK2, ..., AKn are drawn from A(1, 1) where K1, K2, K3, ..., Kn are points in

1st quadrant on = 1(a > b) such that chord AKr makes an angle of with the

positive x-axis. The value of is

(A)

(B)

(C) ab

(D)

2) On the side AC of an acute angled triangle ABC, a point D is taken such that AD =1, DC = 2 and
BD is an altitude of ΔABC. A circle of radius 2 which passes through points A and D and touch a
circle at the point D circumscribed about the ΔBDC. The area of ΔABC is (p → prime number

and q is natural number.) The value of is :

(A) 3
(B) 6
(C) 9
(D) 15

3) If asinθ + bcosθ = acosecθ – bsecθ = 1, the value of a2 + b2 + b4/3 – b2/3 = k and

, then the value of β + k is equal to

(A)

(B)

(C) 0
(D) 1 + e

4) The number of 6 digit numbers that can be formed using the digits 0, 1, 2, 5, 7 and 9 which are
divisible by 11 and no digit is repeated, is :

(A) 36
(B) 60
(C) 48
(D) 72
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-III

Q. 1 2 3 4 5 6 7 8
A. 1 2 3 6 9 6 1 3

SECTION-I (i)

Q. 9 10 11 12 13 14
A. A,B,C B,C A,D A,B,D A,C B,C

SECTION-I (ii)

Q. 15 16 17 18
A. A A C D

PART 2 : CHEMISTRY

SECTION-III

Q. 19 20 21 22 23 24 25 26
A. 0 5 5 5 4 1 4 2

SECTION-I (i)

Q. 27 28 29 30 31 32
A. A,B A,B,D A,B,C,D A,B,C A,B,C,D A,B,C

SECTION-I (ii)

Q. 33 34 35 36
A. C C D B

PART 3 : MATHEMATICS

SECTION-III

Q. 37 38 39 40 41 42 43 44
A. 7 8 6 4 5 1 2 1

SECTION-I (i)

Q. 45 46 47 48 49 50
A. A,B,C,D A,C,D A,C A,B,C A,C A,C,D
 SECTION-I (ii)

Q. 51 52 53 54
A. C B A B
 SOLUTIONS

PART 1 : PHYSICS

1) Question Explanation:
We have to calculate the voltage across points A and B for the figure are arranged such that
current through the battery is minimum.

Concept:
KVL and KCL.

Solution:

Current in branch AB = 1A
vAB = 1 × 1 = 1V

Final Answer: 1

2) Question Explanation: Disc starts rotating when magnetic torque due to induced current
overcomes frictional torque.
Concept : Induced electric field and torque balance.
Solution:

..........(i)
torque due to friction force
dτ = μdmgx

......(ii)

Final Answer: (2)

3) Question Explanation: Change in orientation changes moment of inertia, affecting time

period ratio.
Concept : Physical pendulum relation T ∝ √I.
Solution:

Final Answer: (3)

4) Question Explanation: Electrostatic energy difference after switching converts into heat.
Concept: Energy conservation in electrostatics.
Energy in between r = a to r = 2a gets converted to heat.

x=6

5) Question Explanation: Find mass such that after collision rod has no rotational motion.
Concept: Conservation of linear and angular momentum.
Solution:

(i) Li = Lf ; = MV ×

⇒ V=

(ii) Pi = Pf ; 0 = MV – mV1

⇒ V= ⇒
(iii) e = 1 =

⇒ V + V1 =

⇒ =2 ⇒ M= = 9 kg
Final Answer: (9)

6)

Question Explanation: Change in fringe width due to source shift is used to find wavelength.
Concept : Interference (fringe width ∝ wavelength).
Solution:
Let AS = h

...(i)

...(ii)
h = 1.2 mm
λ = 0.6 × 10–6 m = 6000 Å
Final Answer: (6)

7) Question Explanation: Find dimensions of given expression and compare with mass.
Concept : Dimensional analysis.
Solution:
B2 l2 C is has dimension same as mass.
Final Answer: (1)

8) Question Explanation: Work done along circular path with tangential opposing force.
Concept : Work = Force × arc length.
Solution:
Work done by force F

... (1)
2 2 2
∵x +y =a ∴ xdx + y dy = 0

Alternate method
It can be observed that the force is tangent to the curve at each point and the magnitude is
constant. The direction force is opposite to the direction of movement of the particle

∴ work done = (force) × (distance) = –

Final Answer: (3)
9) Question Explanation: Compare height, time and range relations for projectile on inclined
plane.
Concept: Projectile motion on inclined plane.
Solution:
vx = v0 cos α – g sinθ t
vy = v0 sin α – g cosθ t
Consider that motion along our y-axis does not deperd whether particle is projected from
which end. However motion along x-component does deperd on it.

∴ h1 = h2 To calculate, vy = 0

For time of flight, sy = 0,

∴ A and B are correct
Now for range,

R2 – R1 = g sin θ t2

Final Answer: (A,B,C).

10) Question Explanation: Find maximum kinetic energy and barrel length using adiabatic
expansion.
Concept: Thermodynamics (adiabatic process).
Solution:
Final Answer: (B, C)

11) Question Explanation: Determine pressure distribution in accelerating frame.

Concept: Hydrostatics in non-inertial frame.
Solution:
Since the vessel is moving with acceleration g/2 towards negative x-axis, so

Pressure at free space = 0 and it will be non zero inside liquid.

Final Answer: (A, D)

12) Question Explanation: Compare speeds when both electric and magnetic fields act on
particle.
Concept: Lorentz force and work-energy principle.
Solution:

If
Electric force dominates → upward motion
But magnetic apposes → less displacement than case 1
⇒

2. If
Electric = Magnetic → no vertical motion
⇒ No work done F2 = u
But in case1, speed increased ⇒ v1 > u

3. If
Magnetic dominates → motion downward (opposite E)
⇒ Work done by E is negative → speed decreases

Final Answer: (A, B, D)

13) Question Explanation: Determine spring constant and damping using amplitude decay.
Concept: SHM with damping.
Solution:

Final Answer: (A, C)

14)

Question Explanation: Thermal expansion in constrained rods produces equal stress and
force relations.
Concept: Thermal stress and strain.
Solution:

.....(1)
...(2)
Final Answer: (B, C)

15) Question Explanation: Find wavelength-temperature relation using Wien’s law.

Concept: Wien’s displacement law.
Solution:

(1) λmT = 2.9 × 10–3 ⇒ λm = = 10μm

(2) λmT = 2.9 × 10–3 ⇒ λm = = 678 nm

Final Answer: (A)

16) Question Explanation: Use density vs temperature graph to determine pressure.

Concept: Ideal gas law.
Solution:
At point P slope is tan 150o

∴ (1)

Since ⇒ (2)

Hence pressure
Final Answer: (A)

17) Question Explanation: Find relation between acceleration and retardation in train
motion.
Concept: Kinematics equations.
Solution:
Let maximum velocity during journey be v0 then

0 0 0
t1 + t2 = 5; v = αt1 = βt2 and 5 = v ⇒v =2

Also t1 + t2 = +
 ⇒5= ⇒
Final Answer: (C)

18) Question Explanation: Simplify thermal resistance network to find equivalent resistance.
Concept: Heat conduction and network analogy.
Solution:
Let R1 and R2 be the thermal resistance of copper and iron wires. Then

R1 = and R2 =
According to the principle of Wheat stone's bridge, the point B and D must be at same
temperature when the bridge is balanced. Therefore, thermal resistance of arm BD becomes
ineffective.
Now the equivalent circuit at balance is

The effective resistance between A and C is

R=

Final Answer: (D)

PART 2 : CHEMISTRY

19) Explain Question: Calculate how many optically active compounds having molecular
formula C8H8Br8
Concept: Halogenation of alkene
Solution:
4 optically inactive compound will be obtained.
Final Answer: (0)

20) Explain Question: Find number of buffer solution.

Concept: Buffer solution.
Solution:
x=5
Only a, b, d, e and h will form buffer.
Final Answer: (5)

21) Explain Question: Calculate number of ions having S – S or S = S linkage be ‘x’ and the
number of ions having S – O – S linkage be ‘y’, the number of ions having peroxy linkage be ‘z’.
Concept: Oxyacids of sulphur
Solution:

x = 5, y = z = 1

= Final Answer: (5)

22) Explain Question: Calculate volume of NaOH added.

Concept: Buffer solution.
Solution:
Let, x ml of 2.0 M NaOH solution be added, then
H3PO4 + NaOH → NaH2PO4 + H2O
Millimoles 10 2x 0 0
0 (2x – 10)
NaH2PO4 + NaOH → Na2HPO4 + H2O 10 (2x – 10) 0
10–(2x – 10) 0 2x – 10
= 20 – 2x

So, 7.2 = 7.2 + log , on solving x = 7.5

Final Answer: (5)

23) Explain Question: Identify the compound D

Concept: Kucherov Reaction.
Solution:

4-Deuterium exchange occur

Final Answer: (4)

24)

Explain question :
Question is asking about value of x for volume benzoic acid in given buffer solution
Concept :
This question is based on buffer solution.

Solution :-

pH = 4.5

pH = pka +

4.5 = 4.2 +

…(1)

…(2)

Va = 100 ml

Final answer : 1

25) Explain Question: Find rings which are more reactive than Benzene towards electrophilic
aromatic substitution reaction
Concept: ESR of aromatic compound.
Solution:
The following aromatic compounds are more reactive than benzene towards electroplic
aromatic substitution reaction.

Final Answer: (4)

26) Explain Question: Identify number of molecule which has higher bond dissociation
energy than F2
Concept: Bond energy of halogens.
Solution:
Bond energy of F2 is less than Cl2 and Br2 due to lone pair – lone pair repulsions.
Bond energy order Cl2 > Br2 > F2 > I2
Final Answer: (2)

27) Explain Question: Identify which of the inequality is/are correct

Concept: Bond parameters, Bond angle
Solution:
In first molecule, lone pair of electrons lie in equatorial position, hence decreases θ2 more
rapidly
the θ2'. In second molecule, π-electron cloud lie closer to axial bonds and pushes them more,
so .
Final Answer: (AB)

28) Explain Question: Calculate thermodynamic variable in cyclic process

Concept: Cyclic process.
Solution:
Since AB is an isobaric process, so

WABCDA = WAB + WBC + WCD + WDA

WAB = –nRΔT = –1200 cal

WBC = –2.303nRTB log = 2.303nRTB log (as VC = VD)

WBC = 2.303 × 2 × 2 × 600 × log

= 2.303 × 2 × 2 × 600 × log 2/4
= –1663.68 cal.
WC→D = 0

WD→A = 2.303 nRTA × log

= 2.303 × 2 × 2 × 300 × log4
= 1663.68 cal.
WA→B→C→D→A = –1200 – 1663.68 + 0 + 1663.68
= –1200 cal
Final Answer: (ABD)

29) Explain Question: Identify incorrect statement(s) among the following

Concept: Physical and chemical properties of group 13 elements.
Solution:
Coordination number of Al in AlCl3(s) is 6.
Anhydrous AlCl3 is covalent but becomes ionic when dissolved in water.
BI3 is the strongest Lewis acid among all boron halides.
All BX3 are covalent in nature.
Final Answer: (ABCD)

30) Explain Question: Identify which of the following complexes, IUPAC names is/are
correctly matched
Concept: IUPAC nomenclature of co-ordination compounds.
Solution:
[CuCl2{O = C (NH2)2}2] - Dichloridodicarbamidocopper(II)
Final Answer: (ABC)

31) Explain Question: Identify correct reaction with product

Concept: Reactions of alkyne.
Solution:
Final Answer: (ABCD)

32) Explain Question: Identify the correct 'X' reagent.

Concept: Preparation of aldehyde.
Solution:

Final Answer: (ABC)

33) Explain Question: Identify which of the following statement is incorrect

Concept: Physical and chemical properties of group 14 elements.
Solution:
SiO2 + 4HF → SiF4 + 2H2O
help to maintain pH of Blood
Final Answer: (C)

34) Explain Question: Calculate the quantum number n of the excited state is
Concept: Hydrogen spectrum.
Solution:
 Final Answer: (C)

35) Explain Question: Calculate how much fuel in g is consumed per minute
Concept: Bomb calorie meter
Solution:
ms ΔT = 20000 × Mass of HC

Mass of HC =
= 52.5 g
Final Answer: (D)

36) Explain Question: Identify product A, B, C and D

Concept: Oxidation followed by grignard and reduction.
Solution:

Final Answer: (B)

PART 3 : MATHEMATICS

37)

Explain Question: Calculate the absolute value of a specific trigonometric expression

involving the sum of products of tangents of angles α, 2α, and 4α, given that .
Concept: Trigonometric Identities (Product-to-Sum and cos(A+B+C)), Compound Angles, and

properties of angles in the form .

Solution:

=
{using cos(A + B + C) formula}

Final Answer: (7)

38)

Explain Question: Determine the total number of solutions for the equation

within the specific interval x ∈ [-4, 4].

Concept: Greatest Integer Function [x], Fractional Part Function {x}, Periodic Functions, and
Graphical Analysis of functions.
Solution:

Final Answer: (8)

39)

Explain Question: Given a differential equation involving an integral constant and an initial
condition f(0)=1, find the greatest integer value of a specific expression related to the integral
of f(x) from 0 to 2 .
Concept: Linear Differential Equations, Definite Integrals, and the Greatest Integer Function
[.] .
Solution:
Let

⇒ ......(1)
put x = 0, y = 1
⇒ c = log(k + 1)
∴ (1) ⇒ log(k + y) = x + log(k + 1)
⇒

⇒ (4 – e2)k = e2 – 1
2
∴ [(4 – e )k] = 6
Final Answer: (6)

40) Explain Question: Calculating value from volume of a tetrahedron formed by rotated
vectors. Concept: Vector Rotation & scalar triple product. Solution: Equation of plane
perpendicular to XOZ plane is P : x – z = 0 is coplanar with and j

∴ 4x2 + y2 + 4x2 = 8 ...(1) Now,

Now, ⇒

volume of tetrahedron Final Answer : (4)

41) Explain Question: Find the foot of the perpendicular Q(α, β, γ) from point M(1,0,1) to a
plane containing two given lines, then calculate the value of 3(α + β + γ).
Concept: Equations of Planes containing lines, Cross Product for Normal Vectors, and the
Foot of Perpendicular formula.
Solution:

Dr's normal to plane

Equation of plane –1(x – 1) + 1(y – 0) + 1(z – 0) = 0
x–y–z–1=0 ......(1)

Now

Final Answer: (5)

42)

Explain Question: Identify the number of ordered pairs (r, s) for r, s ∈ {1, 2, 3} such that the
square of a specific 2 × 2 matrix P, involving complex cube roots of unity, equals -I .
Concept: Complex Numbers (Cube Roots of Unity), Matrix Multiplication, and Identity
Matrices .
Solution:

z=w p2 =
z2r + z4S = –1 (–z)r (z)2S + z2Szr = 0
w2r + wS = –1 r ∈ odd
r=1 S=1
Final Answer: (1)

43) x26 + x4 + 3 = – (k2 + 2kα – α – 3) x6

x20 + = – (k2 + 2kα – α – 3)

∴ For no solution
– (k2 + 2kα – α – 3) < 5 ∀ k ∈ R
k2 + 2kα – α – 3 > –5
k2 + 2kα – α + 2 > 0 ∀ k ∈ R
↓
D<0
2
4α – 4 (–α + 2) < 0
α2 + α – 2 < 0 ⇒ (α + 2) (α – 1) < 0
⇒ α ∈ (–2, 1)
∴ Number of integral values of α is 2.

44) Explain Question: For a differentiable function defined by an integral equation, calculate

the value of .
Concept: Leibniz Rule for differentiating under the integral sign, Linear Differential
Equations, and Second-order Derivatives.
Solution:

ƒ'(x) = ƒ(x) cosx – cosx

ln |ƒ(x) – 1| = sin x + c
ƒ(x) = 1 – esinx+c
since ƒ(0) = 0 ƒ(0) = 1 – ec = 0 c=0
ƒ(x) = 1 – esinx
ƒ'(x) = –esinx cosx

Final Answer: (1)

45)

Explain Question: Analyze the properties of the roots of a cubic equation given they are in
Harmonic Progression (H.P.), evaluating inequalities and specific algebraic relationships
between coefficients .
Concept: Theory of Equations, Harmonic Progression (H.P.), AM-GM Inequality, and relations
between roots and coefficients.
Solution:
Given α, β, γ are roots of x3 + px2 + qx - q = 0
∴ α + β + γ = –p
αβ + βγ + γα = q
αβγ=q
as α , β, γ in H.P.

put in the given equation

⇒ 27 + 9p + 3q - q = 0
⇒ 9p + 2q + 27=0
we know

Again

Final Answer: (A, B, C, D)

46)

Explain Question: Given a2 + b2 + c2 = 2 for integers a, b, c determine the probability of

unique/infinite solutions for a specific system and the range of ab+bc+ca .
Concept: Systems of Linear Equations (Cramer's Rule), Integer Solutions, and Probability.
Solution:
a, b, c are integers and a2 + b2 + c2 = 2 ⇒ one of them is 0 and the other can be ±1.
∴ No. of cases = 12

For unique solution |A|≠0 ⇒

∴ a = 0, b = 1, c = –1 and there are 6 cases

∴ Probability =
But in all the remaining 6 cases it cannot have infinitely many solutions
For example for a = 0, b =–1, c = 1, 1 Δ1 ≠ 0
∴ It has no solution
∴ B is not correct
a = 0 ⇒ b2 + c 2 = 2 (1, –1) (–1, 1) it has no solution
2 2 2
a + b + c – ab – bc – ca ≥ 0
⇒ ab + bc + ca ≤ 2
(a + b + c) ≥ 0 ⇒ ab + bc + ca ≥–1
But a = b = c not possible
∴ 2 is not there
ab + bc + ca ≠ 0
∴ –1,1 are possible values
Final Answer: (A, C, D)

47)
Explain Question: Evaluate the truth of four statements regarding implicit differentiation,
the existence of real roots for polynomial derivatives, and the properties of inverse
trigonometric functions.
Concept: Implicit Differentiation, Rolle's Theorem (Polynomial roots), Repeated Roots of
Polynomials, and Inverse Trigonometric Identities.
Solution:
Which of the following statements are true?
(A) xexy = y + sin2x
differentiate w.r.t. x we get
exy + xexy (y + xy') = y' + 2sinxcosx
at x = 0, y = 0
0 0
∴ e + 0.e (0 + 0.y') = y'

(B) f'= a0(2m+1) x2m + 2m a1 x2m–1 + ..........a2m = 0

We let example :- f'(x) = x2 + x + 1 ⇒ D < 0
∴ No real root
(C) f (x) = anxn +an–1 xn–1 + an–2 xn–2 + ..............a0
f (x) = an (x – r)m (xn–m + ...........)
m–1
f' (x) = an (x – r) (............)
∴ r is a (m–1) times repeated root of f' (x).
(D) y = sin–1 (cos sin–1x) + cos–1 (sin cos–1x)
= sin–1 + cos–1

Final Answer: (A, C)

48) For : The function is f(x) = x[x]. We break this into integer steps:

For (No brackets to evaluate here).

For (No brackets here either).
For : The function is f(x) = (x - 2)[x]. We break this down as well:

Now we have our simplified, fully expanded piecewise function without any greatest integer
brackets:
49)

Explain Question: For an ellipse defined by tangents common to a circle and a parabola,
verify its eccentricity, latus rectum length, and the area bounded by specific vertical lines .
Concept: Common Tangents to Conics, Ellipse Properties (eccentricity, L.R.), and Area under
Curves using Definite Integration.
Solution:

⇒ (m2 + 2) (m2 – 1) = 0
⇒m=±1
⇒y=x+1&y=–x–1
⇒ Q ≡ (–1, 0)

L.R. =

Ellipse is

Area of region =

=
Final Answer: (A, C)

50)

Explain Question: In a triangle where sides a, b, c are in A.P., identify which other
trigonometric or geometric properties (cotangents, ex-radii, sines) also form an Arithmetic
Progression .
Concept: Properties of Triangles (Sine Rule, Half-angle formulas), Ex-radii (r1, r2, r3), and
Arithmetic Progressions (A.P.).
Solution:

(A) subtract in each term

→ A.P.
(B) Subtract r1 + r2 + r3 in each term
r1, r2, r3 AP (Not true)

(C)
⇒ a,b,c in A.P
(D) (sinA + sinB + sinC)
(sinB + sinC – sinA),
(sinA + sinC + sinB) (sinA + sinC – sinB),
(sinA + sinB + sinC) (sinA + sinB – sinC)
subtract sinA + sinB + sinC in each term
sinA, sinB, sinC are in A.P.
Final Answer: (A, C, D)

51) Explain Question:

Evaluate the limit of the Riemann sum representing the average of squared lengths of chords
drawn from the center of a shifted ellipse to its boundary.
Concept: Definite integral as Limit of a Sum.
Solution:

Ellipse: Center A = (1, 1)

Let Rr = AKr. The coordinates of Kr are (1 + Rrcosθr, 1 + Rrsinθr) ---- not parametric point

Put in ellipse ⇒
Convert Limit of Sum to Definite Integral

= ab (after dividing by cos2θ then integrating)

Final answer: Option (3)

52)

Explain Question: In an acute triangle ABC with altitude BD, find the area of the triangle
given a circle of radius 2 passes through specific points and touches another circumcircle .
Concept: Geometry of Triangles, Circle Properties (tangency and chords), and Trigonometric
ratios in right triangles.
Solution:

BD =

=
Area of ΔABC =
P = 3, q = 15
Final Answer: (B)

53)

Explain Question: Solve a system of trigonometric equations to find a constant k and then
determine the value of β + k using a provided integral relationship .
Concept: Trigonometric Elimination, Integration by Parts, and Definite Integrals involving
.
Solution:
asinθ + bcosθ = 1 ...(1)
acosθ – bsinθ = sinθcosθ ...(2)
squaring and adding
a2 + b2 = 1 + sin2θcos2θ
a2 + b2 = 1 + cos2θ – cos4θ ...(3)
(1) × cosθ – (2) × sinθ
asinθcosθ + bcos2θ – acosθsinθ + bsin2θ
= cosθ – sin2θcosθ
b = cos3θ ⇒ cosθ = b1/3
Put in (3)
a2 + b2 = 1 + b2/3 – b4/3
k=1

Final Answer: (A)

54)

Explain Question: Determine the total count of 6-digit numbers without repetition using a
specific set of digits that are divisible by 11.
Concept: Combinatorics (Permutations) and the Divisibility Rule for 11 (alternating sum of
digits).
Solution:
Sum of given digits 0, 1, 2, 5, 7, 9 is 24.
Let the six digit number be abcdef and to be divisible by 11
so |(a + c + e) – (b + d + f)| is multiple of 11.
Hence only possibility is a + c + e = 12 = b + d + f
Case-I {a, c, e} = {9, 2, 1} & {b, d, f} = {7, 5, 0}
So, Number of numbers = 3! × 3! = 36
Case-II {a,c,e} = {7,5,0} and {b,d,f} = {9,2,1}
So, Number of numbers 2 ×2! × 3! = 24
 Total = 60
Final Answer: (B)