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0% found this document useful (0 votes)
4 views28 pages

Solution

The document contains a series of physics, chemistry, and mathematics questions and problems, each with multiple-choice answers. It covers topics such as dimensional analysis, quantum numbers, electronic configurations, and polynomial equations. The questions are structured in sections, with each section focusing on a specific subject area.

Uploaded by

sarikadhote774
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

03-05-2026

1803CJA101001260001 JM

PART-1 : PHYSICS

SECTION-I

1) Which of the following functions of A and B may be performed if A and B possess different
dimensions

(A)

(B) A + B
(C) A – B
(D) none

2) Velocity v (in cm/sec) of a particle is given in terms of time t (in sec) by the equation :-

v = at +
The dimensions of a, b and c are :

a b c

(A) [L2] [T] [LT2]

(B) [LT2] [LT] [L]

(C) [LT–2] [L] [T]

(D) [L] [LT] [T2]


(A) A
(B) B
(C) C
(D) D

3) If x = at + bt2 , where x is in metres and t is in hours, the unit of b will be :-

(A) metre
(B) metre/hour
(C) metre/(hour)2
(D) metre2/hour

4) If area (A), velocity (v) and density (ρ) are taken as fundamental units, what is the dimensional
formula for force ?

(A) [Av2ρ]
(B) [A2vρ]
(C) [Avρ2]
(D) [Avρ]

5) In the gas equation (V – b) = RT, the dimensions of constant a is :

(A) [L3]
(B) [ML3T–2]
(C) [ML5T–2]
(D) [ML2T–2]

6) The unit of force and length are doubled, the unit of energy will be :-

(A)
times

(B)
times
(C) 2 times
(D) 4 times

7) The density of a material in S.I units is 128 kg/m3. In certain units in which the unit of length is 25
cm and unit of mass is 50 g, the numerical value of density of material is

(A) 40
(B) 16
(C) 640
(D) 410

8) If force (F), length (L) and time (T) are taken as the fundamental quantities. Then what will be the
dimension of density :

(A)

(B)

(C)

(D)

9) Which of the following is a quantity that has no dimensions ?

(A) Refractive index


(B) Gravitational constant
(C) Velocity
(D) Planck's constant

10) The dimensions of universal gravitational constant are:


(A)
(B)
(C)
(D)

11) A physical quantity is measured and the result in expressed as nu where 'u' is the unit used and
'n' is the numerical value. If the result is expressed in various units then :

(A) n ∝ u
(B) n ∝ u2
(C)

(D)

12) Which of the following can not be a set of fundamental quantities?

(A) Mass, length, density


(B) Length, time, density
(C) Mass, time, density
(D) Time, volume, density

13)

Find the value of sin(74°) :-

(A)

(B)

(C)

(D) can't be determined

14) In figure equal :-

(A)
(B)
(C)

(D)

15) A vector is given by . Find the unit vector along


(A)

(B)

(C)

(D) None of these

16) If & are unit vectors such that + and are perpendicular to each other, then
angle between & is :-

(A)

(B)

(C)

(D)

17) The resultant of two forces, one double the other in magnitude, is perpendicular to the smaller of
the two forces. The angle between the two forces is :-

(A) 120°
(B) 60°
(C) 90°
(D) 150°

18) In the following figure what are the angle between vectors & , & and &

respectively:

(A) 60°, 60°, 60°


(B) 60°, 120°, 120°
(C) 120°, 60°, 60°
(D) 120°, 120°, 60°

19) The vectors and are such that then the angle between the two vectors
and will be :-

(A) 0°
(B) 60°
(C) 90°
(D) 180°

20) If a vector is perpendicular to the vector , then the value of α is :-

(A) 1/2
(B) –1/2
(C) 1
(D) –1

SECTION-II

1) If the resultant of two forces of magnitudes P and Q acting at a point at an angle of 60° is

√7 Q, then P/Q is

2) The density of a material in CGS system of units is 4 g/cc. In a system of units in which unit of
length is 2 cm and unit of mass is 16 g, find the numerical value of density of material.

3) Average power is given by

If the dimensional formulae of power is MxLyTz. Find the value of x + y + z.

4)

Two forces, each equal to F, act as shown in fig. Their resultant is nF, then n = ?

5) In the figure shown, a body is acted upon by three forces such that it is in equilibrium. Find the

force F (in N).


PART-2 : CHEMISTRY

SECTION-I

1) In the given electronic arrangement which of the following rule is violated

(A) Aufbau's principle


(B) Hund's rule
(C) Pauli's exclusion
(D) none of these

2) Which of the following sets of quantum numbers are not possible :-

(A) n = 3, l = 2, m = 0, s = – 1/2
(B) n = 3, l = 2, m = –2, s = – 1/2
(C) n = 3, l = 3, m = –3, s = + 1/2
(D) n = 3, l = 1, m = 0, s = + 1/2

3) When the value of (n + ℓ) is not more than 3 then which of the following subshells is not possible
to exist?

(A) 2s
(B) 3s
(C) 3p
(D) 2p

4)

If the principle quantum number is 3, the azimuthal quantum number can have values of

(A) 1, 2, 3
(B) –3, –2, –1, 0, 1, 2, 3
(C) 0, 1, 2

(D)

5) Which electronic configuration does not follow the Aufbau rule ?

(A) 1s2, 2s2, 2p6


(B) 1s2, 2s2, 2p4, 3s2
(C) 1s2
(D) 1s2, 2s2, 2p6, 3s3
6) The element having no neutron in the nucleus of its atom is :

(A) H
(B) He
(C) N
(D) B

7)

Which orbital is non directional :

(A) s
(B) p
(C) d
(D) All

8) Which of the following electron shown highest energy :-

(A)

(B)

(C)

(D)

9) The calculated value of magnetic moment of 26Fe3+ is

(A) 3.89 B.M


(B) 1.73 B.M
(C) 4.90 B.M
(D) 5.92 B.M

10) Consider d5 arrangement

the no. of exchange pairs are:

(A) 5
(B) 10
(C) 0
(D) 15

11) The number of orbitals associated with quantum numbers n = 5 is :

(A) 11
(B) 25
(C) 15
(D) 50

12) Which of the following is the correct order of energy level for Hydrogen atom?

(A) 1s < 2s < 2p < 3s < 3p < 3d < 4s


(B) 1s < 2s < 2p < 3s < 3p < 4s < 3d
(C) 1s < 2s = 2p < 3s = 3p = 3d
(D) 1s < 2s < 2p < 3s = 3p = 3d

13) 2py , 3py and 4py have same


(P) (n + ℓ)
(Q) shape
(R) size
(S) nodal plane
(T) Energy

(A) P, Q, S
(B) Q, S, T
(C) Q, S
(D) P, Q, S, T

14) Which one of the following sets of ions represents a collection of isoelectronic species?
(Given: Atomic Number: F : 9, Cl : 17, Na= 11, Mg = 12, Al = 13, K = 19, Ca = 20, Sc = 21)

(A) Li+, Na+, Mg2+, Ca2+


(B) Ba2+, Sr2+, K+, Ca2+
(C) N3–, O2–, F–, S2–
(D) K+, Cl–, Ca2+, Sc3+

15) Select the correct statement -

(A) In orbital 2 nodal planes are in xz and yz plane


(B) and have one common nodal plane
(C) one 4d orbital contains maximum 2 electrons of opposite spin
(D) one 3d orbital contains a total of 10 electrons

16) Which of the following element does not contain atleast five electrons in p-subshell.

(A) Na
(B) F
(C) N
(D) Mg

17) The number of electrons that are present in Argon (Z = 18) atom for which m = 0, are :-
(A) 6
(B) 8
(C) 10
(D) 18

18) Among the given elements, select those, which are at the peak of Lothar Meyer's curves ?

(A) Alkaline earth metals


(B) Alkali metals
(C) Halogens
(D) metalloids

19) An isodiapher of 6C13 is :

11
(A) 5B
15
(B) 7N
19
(C) 9F
(D) All of these

20) Mendeleev’s periodic law is based on

(A) Atomic number


(B) Atomic weight
(C) Number of neutrons
(D) None of these

SECTION-II

1) If unpaired electron in Mn+2 and Fe+2 is x and y, find value of x + y :-

2) How many of the following species are isoelectronic ?


He, Be, , Na+, O2–, N3–, P3–, Al3+, Mg2+

3) How many of the following set of quantum numbers is possible for electron?

(i) n = 1, = 0, m = 0, ms = +

(ii) n = 9, = 7, m = –6, ms = –

(iii) n = 2, = 1, m = 0, ms = +

(iv) n = 3, = 2, m = –3, ms = +

4) H-atom have infinite shells, write total number of shells which does not contain d-subshell.
5) Find total number of orbitals in which electron density is observed along any of the axis (x, y, or z)
:

PART-3 : MATHEMATICS

SECTION-I

1) If x – y = a and x2 + y2 = b, then the value of x3 – y3 is

(A)

(B)

(C)

(D) a2 + b

2) If positive integer x satisfies the equation , then value of x is

(A) 105
(B) 125
(C) 225
(D) 243

3) is (wherever defined)

(A) 0
(B) 1
(C) 2
(D) 3

4) If 2x5 – 3x4 + 4x2 – 3x + 9 is divided by (x – 1) then the remainder is :–

(A) 9
(B) –9
(C) –8
(D) –3

5)

If p > q > 0 are two real numbers, then the value of

is -
(A) independent of q
(B) independent of p
(C) independent of both p and q
(D) dependent on both p and q.

6) The number of real solutions of is -

(A) 0
(B) 1
(C) 2
(D) Infinite

7) Product of all values of x satisying the equation

(A)

(B) 3

(C)

(D)

8) The value of is

(A) 5
(B) 2
(C) 7
(D) 3

9) If (x + y)(y + z)(z + x) = 11 and x + y + z = 11, then value of x3 + y3 + z3 is -

(A) 1320
(B) 1364
(C) 1164
(D) 1298

10) Value of is

(A) 1

(B)
(C)

(D) 3

11) The value of :

(A) 7
(B) 5
(C) 2
(D) none of these

12) The solution set for :

(A) (2, 4)
(B) (–1, 2)
(C) (–∞, –1]
(D) (4, ∞)

13) If x2–1 is a factor of x4 + ax3 + 3x – b then

(A) a = 3, b = –1
(B) a = –3, b= 1
(C) a = 3, b = 1
(D) None of these

14) If , then which of the following can be true -

(A) a = 1, b = 4/3, c = 7/3


(B) a = 1, b = 2/3, c = 7/9
(C) a = 2/3, b = 1, c = 7/3
(D) a = 7/9, b = 4/3, c = 1

15) Sum of all real values of x satisfying equation is :-

(A) 0
(B) 1
(C) 1
(D) None of these

16) Suppose that a, b are two real numbers such that a2 + b2 + 8a – 14b + 65 = 0, find a + b :
(A) 3
(B) 11
(C) 4
(D) –11

17) If a = &b= then a + b equals to

(A) 5
(B) 6
(C) −6
(D) 0

18) The polynomial P(x) has remainder 3 when divided by (x – 1) and remainder 5 when divided by (x
– 3). If the remainder when P(x) is divided by x2 – 4x + 3 is ax + b, then a + b is equal to :-

(A) 3
(B) 2
(C) –2
(D) 4

19) If then can be equal to

(A)
(B)
(C)
(D)

20) The number of positive integral solutions of , ≤ 0 is :

(A) 1
(B) 2
(C) 3
(D) 4

SECTION-II

1) If the number M39048458N is divisible by both 8 and 11, where M & N are single digit non-
negative integers, then (M + N) =

2) If P(x) is a cubic polynomial such that P(1) = 1; P(2) = 2; P(3) = 3 with leading coefficient 3 then
find the value of P(4).
3) The value of is :

4) The value of

,
where x = 2 and ℓ = 2, m = 2, n = 3 is

5)

Number of ordered pair (x, y), satisfying the equation is


ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A C C A C D A A A B D A A D A B A C C A

SECTION-II

Q. 21 22 23 24 25
A. 2 2 0 1 8

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B C C C B A A B D B B C C D C C C B D B

SECTION-II

Q. 46 47 48 49 50
A. 9 5 3 2 4

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B D D A A A D A D D C A B A A A B A C C

SECTION-II

Q. 71 72 73 74 75
A. 10 22 60 1 4
SOLUTIONS

PART-1 : PHYSICS

1)

Ans. (A)
A is the correct answer

2)

[a] = = LT–2 [C] = [T]


–1
[b] = [V][T] = [LT ,T] = [L]

3) x = at + bt2
Units of quantities x and bt2 must be same

∴ Units of b =

4) F = Aαvβργ
or [MLT–2] = [L2]α [LT–1]β [ML–3]γ
= [MgL2α+β–3γT–β]
This gives : γ = 1, β = 2
and 2α + β – 3γ = 1
or α = 1; F = Av2ρ

5)

[P] =

6) Energy µ (Force) (Length)

7)

Density

8)
Using dimensional analys

9)

Retractive index is ratio of same quantity


dimensionless quantity

10)

11) Q= n1u1 = n2u2 ⇒ n

12) Question Explanation: Identify which set of quantities cannot be fundamental.


Concept Involved: Fundamental quantities in a set must be independent.
Solution:

Density = Mass / Volume = Mass /(Length)3.


Since Density is directly expressed using Mass and Length, these three are not independent.

Other options (2,3,4) contain quantities that cannot be derived from each other.

Final Answer: Option (1)

13) Question Explanation:


We are asked to determine the value of sin(74⁰) from the given options.
Concept: Value of trigonometric functions
Solution:
By the identity, sin(2θ) = 2sinθcosθ

sin(74º) = sin(2 × 37º) = 2 sin37º cos37º = 2 × =


Final Answer: Option (1)

15)

16)

5(1)2 + 6abcosθ – 8(1)2 = 0


5 + 6cosθ – 8 = 0

cosθ =

θ = 60°

17)

⇒ θ = 120°

18)

(i) =

(ii) =

(iii) =

19)

and
Now, A2 + B2 + 2AB cosθ = A2 + B2 – 2AB cosθ

4AB cosθ = 0, i.e. ,

20) Question Explanation:


Finding a value using perpendicular vector condition.
Concept:
Dot Product of Perpendicular Vectors.
Solution:
Two vectors are perpendicular if their dot product is zero. We multiply the corresponding i,
j, and k components and sum them to zero.

Final Answer:
Option (1)

21)

7Q2 = P2 + Q2 + PQ
P2 – 6Q2 + PQ = 0
P2 + QP – 6Q2 = 0

22) ∵ [density] = [ML–3]

∴ n2 = n1

23)

24)

Note that the angle between two forces is 120° and not 60°.
R2 = F2 + F2 + 2F2 cos120°

or or R = F

25)
PART-2 : CHEMISTRY

26)

only Hund's rule of maximum multiplicity is violated.

27)

n = 3, l = 0, 1, 2
l = 0, n = 0
l = 1, m = +1, 0, –1

l = 2, n = – 2, –1, 0, +1, +2

28) n + l ≤ 3
n+1=1 n+l=2 n+l=3
1 + 0 ⇒ 1s 2 + 0 ⇒ 2s 2 + 1 = 2p
3 + 0 = 3s

29)

Azimuthal quantum number 0 to (n – 1)


n=3
l = 0, 1, 2

30)

1s2, 2s2, 2p6 is correct configuration.

31) 1H1 e = 1, p = 1, n = 1 – 1 = 0

32)

Refer to notes

33) e– (n + ℓ)
3,2,1,+½ 5
4,2,–1,+½ 6
4,1,0,–½ 5
5,0,0,+½ 5

34) Magnetic moment = where n is the number of unpaired electrons.


For Fe3+ ion n=5 so, = B.M

35)

Ans. (B)

4+3+2+1 = 10 exchanges

36)

Explaining the Question :- Question is asking to Calculate number of orbitals having n = 5


,

Concept:- This question is based on Quantum number

Solution :-

no. of orbitals in a given shell (n) =

So, in shell no. of orbitals =


= 25
Final Answer :- 2

37)

For single electron species energy of subshell depends on only principle quantum number (n)

38) The correct answer is option (C)

39)

K+ Cl– Ca2+ Sc3+


No. of electrons 18 18 18 18

Concept :- Iso electronic species have same no. of electrons.

40)

An orbital can accomodate maximum two electrons with opposite spin.

41)

First we need to write the electronic configuration of each element.


(a) Na → 1s2 2s2 2p5 3s1
Here, p-subshell contain 6e− (i.e. more than 5e−). So, this option is incorrect
(b) F → 1s2 2s2 2p6
Here, p-subshell contain 5e−. Hence, this option is incorrect.
(c) N → 1s2 2s2 2p3
Here, p- subshell contain only 3e− so, this option is correct.
(d) Mg → 1s2 2s2 2p6 3s2
Here, p-subshell contain more than 5e−. Hence, this option is incorrect.

42) Question Explanation : Find The number of electrons that are present in Argon (Z = 18)
atom for which mℓ = 0

Concept: This question is based on electronic configuration.

Solution:

For Ar (z = 18)

So, total e– with mp = 0 are 10.

Final Answer: Option (3)

43) Question Explanation: Identifying elements that occupy the peaks of Lothar Meyer's
curves.

Concept: Lothar Meyer's Atomic Volume Curves.

Solution: Lothar Meyer plotted atomic volume against atomic weight. He observed that alkali
metals (Li, Na, K, Rb, Cs) occupy the peaks of these curves because they have the largest
atomic volumes in their respective periods.

Calculation:

A. Peaks: Alkali Metals (Group 1).

Final Answer: Option (2)

44)

Question Explanation : Identify the Isodiaphers of carbon- from the given options.
Concept: Isodiaphers are atoms of different elements having the same neutron-proton
difference ( or ).
Solution:

A. For given atom .


B. Checking Option : . It matches.
C. Checking Option . It matches.
D. Checking Option : . It matches.
Since all three provided species have the same value as , they are all classified as
its Isodiaphers.
Final Answer: Option (4)

45) Question Explanation : Find base of Mendeleev's periodic law


Concept : Mendeleev's periodic law
Solution : Mendeleev's periodic law is based on atomic weight
(also known as atomic mass)
Final Answer : Option (2) Atomic weight

46) Mn+2 → 1s2 2s2 2p6 3s2 3p6 3d5


Fe+2 → 1s2 2s2 2p6 3s2 3p6 3d6
In Mn+2 → 3d5 → 5 unpaired e– = x

ln Fe+2 → 3d6 →
→ 4 unpaired e– = y
x+y=5+4=9

47) O2–, N3–, Al3+, Mg2+, Na+ → 10e–


[isoelectronic same electrons]

48) First three set is correct

49) For d-subshell ℓ = 2, so shell with n = 1, 2, do not contain f-subshell

50)
have electron density along axis.

PART-3 : MATHEMATICS

51) x – y = a
∴ x2 + y2 – 2xy = a2
b – a2 = 2xy

...(1)
Now x – y = (x – y)3 + 3xy(x – y)
3 3
52)

Explanation Question:
We have to find the value of positive integer x satisfies the given equation.
Concept:
This question is based on surds
Solution:
Given:



Squaring on both sides, we get
81(3) = x
⇒ x = 243
Final Answer: The correct option is (4)

53) Question Explanation:


In this question we have to find value of given expression.

Concept:
This question is based on factorization.

Solution:

Given
Let p + q – 2r = x ... (i)
q + r – 2p = y ... (ii)
r + p – 2q = z ... (iii)
Adding
⇒ 2(p + q + r) – 2(p + q + r) = x + y + z
⇒ 0=x+y+z
If x + y + z = 0 then x3 + y3 + z3 = 3xyz
So, (p + q – 2r)3 + (q + r – 2p)3 + (r + p – 2q)3
= 3(p + q – 2r)(q + r – 2p)(r + p – 2q)

So, required

Final answer: The correct option is (4).

54) Question Explanation:


In this question we have to find remainder when given polynomial is divided by (x – 1).

Concept:
This question is based on polynomials.

Solution:
Let P(x) = 2x5 – 3x4 + 4x2 – 3x + 9
When divided by (x – 1)
Then remainder is P(1) = 2 – 3 + 4 – 3 + 9 = 9

Final answer: The correct option is (1).

55) Question Explanation: In this question we have to simplify given expression.

Concept: This question is based on surds.

Solution:

Let

x2 = (p – q)x + pq
x2 – (p – q)x – pq = 0
(x – p)x + q(x – p) = 0
(x – p)(x + q) = 0 x = p x = –q (rejected)

Final answer: The correct option is (1).

56) x = 2 but x2 – 4 ≠ 0 ⇒ x ≠ ±2
hence no solution

57) Question Explanation: In this question we have a equation and we have to find product
of all values of x satisfying it.

Concept: This question is based on equations.

Solution: Given

So, required product of roots =


Final answer: The correct option is (4).

58) Question Explanation:


We have to find the value of the given infinite series.

Concept:
This question is based on Convergent series.

Solution:

Let y =
, y>0
2
y – 3y – 10 = 0
(y – 5)(y + 2) = 0 y = 5, –2(Reject)

Final Answer:
The correct option is (1).

59) Use : (x + y + z)3


= x3 + y3 + z3 + 3(x + y)(y + z)(z + x)
(11)3 = x3 + y3 + z3 + 3(11)
∴ x3 + y3 + z3 = 1298

60)

61) Solution:

After Rationalization

=
=2

Final Answer: option (3)

63) P(1) = 0 ⇒ 1 + a + 3 – b = 0
a – b = –4
P(–1) = 0 ⇒ 1 – a – 3 – b = 0
⇒ a + b = –2
So, a = –3, b = 1

64)

a = 1, b = 4/3, c = 7/3

66) a2 + 8a + 16 + b2 – 14b + 49 = 0
(a + 4)2 + (b – 7)2 = 0
which is possible only when
a = –4 and b = 7

67) a =
a=

b= =
⇒a+b=6

68) Let P(x) = (x – 1) (x – 3) Q(x) + Ax + B


P(1) = A + B = 3 ...(1)
P(3) = 3A + B = 5 ...(2)
From (1) and (2) A = 1, B = 2
∴Remainder is x + 2.

69)

70)

The number of positive integral solutions of , ≤ 0 is 3.

71) Question Explanation: We have to find value of 'M' and 'N' for which given number is
divisible by both 8 and 11.
Concept: This question is based on divisibility of numbers
Solution:
M390484584
Hence 58N divisible by 8, possible only when N = 4
For divisible by 8 last three digits should be divisible by 8.
58N should be divisible by 8
only 584 is divisible by 8
hence N = 4
for divisible by 11
|Sum of the digits at even places – Sum of the digits at odd places| = 0
Hence |(16 + N) – (M + 25)| = 0 or multiple of 11
for N = 4, M + 5 = 0 or multiple of 11
M + 5 = 0 or M + 5 = 11
M = –5 or M = 6
But

So, M = 6

72) Question Explanation: Find value of P(4).

Concept: Factor theorem.

Solution: Given P(1) = 1, P(2) = 2, P(3) = 3


⇒ P(1) – 1 = 0, P(2) – 2 = 0, P(3) – 3 = 0
Solution of P(x) – x = 0 are x = 1, 2, 3
By factor theorem
P(x) – x = 3(x – 1) (x – 2) (x – 3)
⇒ P(x) = 3(x – 1) (x – 2) (x – 3) + x
⇒ P(4) = 3(1) (2) (3) + 4
⇒ P(4) = 22

Final Answer: 22

73)

The value of is 60.

74)

75)

Sol. 4

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