Bansal Classes jalgaon

Jalgaon
Jalgaon, Maharashtra 425001

12TH JEE (RT-02)

Answer Key
Physics

1) 1 2) 3 3) 2 4) 1 5) 2 6) 4 7) 1 8) 1 9) 1 10) 4

11) 2 12) 4 13) 2 14) 1 15) 4 16) 3 17) 1 18) 2 19) 3 20) 1

21) 1 22) 65 23) 320 24) 1 25) 25

Chemistry

26) 1 27) 2 28) 2 29) 4 30) 3 31) 1 32) 2 33) 4 34) 1 35) 1

36) 2 37) 1 38) 2 39) 3 40) 4 41) 3 42) 4 43) 4 44) 3 45) 3

46) 5 47) 7 48) 2 49) 3 50) 458

Mathematics

51) 1 52) 2 53) 3 54) 2 55) 1 56) 1 57) 3 58) 1 59) 4 60) 2

61) 2 62) 1 63) 1 64) 2 65) 3 66) 3 67) 4 68) 2 69) 2 70) 4

71) 1 72) 6 73) 38 74) 2039 75) 16

1
 Hint And Solutions

1. (1)

The magnitude of force on charge, q 3 = 5μC placed at mid-

point O is given as
1 q1 q3 1 q1 q2
F = +
4πε0 (AO)2 4πε0 (OB)2
−6 −6 5. 2λ

= 9 × 10
9
×
10 × 10 × 5 × 10 (2) E = × 2
2πε0 R
2
−2
(5 × 10 )

−6 −6
5 × 10 × 10 × 10
9
+9 × 10 ×
2
−2
(5 × 10 )

−2 −2
45 × 10 45 × 10 2λ
= + E =
−4 −4
25 × 10 25 × 10 πε0 R

9 9 18
6. (4) For equilibrium of the charge q
2 2 2
= × (10) + × (10) = × (10)
5 5 5
2 q (e) q (4e)
= 3.6 × 10 N = 360N =
2 2
4πε0 d 4πε0 (x − d)
2. (3) From Coulomb's law, the force of attraction
where d is the distance of q from the charge e.
between two charged particles (q), kept at distance r apart is x
2 ⇒ d =
1 q
3
F =
2
4πε0 r
7. (1) The potentials at the centre of the rings are
Q 1 1
V1 = [ − ]
4πε0 R √R2 + d 2

−Q 1 1
and V 2 = [ − ]
4πε0 R √R 2
+ d
2

ΔV = V1 − V2

8. (1) Option (1) is correct

When two identical spheres are brought in contact,
9. (1) If potential at centre is zero, then
then charge on them is equalised,
hence total charge on C is equally shared when brought in
contact with sphere B having a charge q.
q
Therefore, charge on B and C is .
2
From Coulomb's law, the force on C is
q × q/2 (q/2)(q/2)
FC = −
2 2
4πε0 (r/2) 4πε0 (r/2)
V1 + V2 + V3 + V4 = 0
qq
= (2 − 1) = F kQ kq k2Q k2q
2
4πε0 r − − + + = 0
r r r r

3. 1 q −Q − q + 2q + 2Q = 0
(2) E =
2
4πε0 Q = −q
|r|
→
r = (9 − 3) î + (12 − 4) ĵ = 6 î + 8 ĵ 10. (4)
2 2
⇒ r = √6 + 8 = 10m
9 −6
9 × 10 × 100 × 10
−1
E = = 9000 V m
2
10 Q
2L 2L
( ) dx
4. (1) According to symmetry V = ∫
1 dq
= ∫
1 L

=
Q
ln(2)
EAKB = EALC + ECM D = E 4πε0 x 4πε0 x 4πε0 L
L L
⇒ EACD = √2E

11. (2) The pressure difference across the air bubble is

2T
ΔP =
r

ΔP = Pin − Pout , Pout = P + hdg

⇒ The pressure inside the soap bubble is

2T
Pin = P + hdg +
r
12. (4) In the given situation A and B lie on the same ⎛ 1 ×
1
⎞
horizontal level. Now, applying Bernoulli's equation ⎜ 2 ⎟ ℓ 1 ℓ
R2 = ⎜ ⎟ =
1 ⎜ 1 ⎟ KA 3 KA
2 2
PA − PB = ρ (v − v ) (hA = hB ) (1)
B A ⎝ 1 + ⎠
2 2
Also, from equation of continuity, we have (ΔT )

S A vA = S B vB We have Q = t
R
where S and S are corresponding cross - sectional area.
A B
As Q is constant
Given, t ∝ R
2
SA = 1.5 cm t2 R2 2

SB = 25 mm
2
= 25 × 10
−2
cm
2
, t1
=
R1
⇒ t2 =
9
× 9 = 2 min.

vB = 60 cm/s

∴ (1.5) (vA ) = 25 × 10
−2
× 60
21. (1) Buoyant force = weight of the body in air - weight of
25
the body in liquid
−2
⇒ vA = × 10 × 60 cm/s
1.5 22. (65) Density of water = 10 kg/m 3 3

= 10 cm/s
Let the final temperature of the mixture be T
Now, from eq. (1) Assuming no heat transfer to or from container.
1
PA − PB = × 10
3
(60
2
− 10 ) × 10
2 −4
Heat lost by water at 80 C ∘

2 3
= 0.1 × 10 × swater × (80 − T )
= 175 P a
Heat gained by water at 60 ∘
C

13. (2) = 0.3 × 10

3
× swater × (T − 60)

Excess pressure =
2T
Heat lost = Heat gain
r 3
= 0.1 × 10 × swater × (80 − T )
−3
2 × 70 × 10 3
= = 0.3 × 10 × swater × (T − 60)
−3
1 × 10 ∘
⇒ 1 × (80 − T ) = 3 × (T − 60) ⇒ T = 65 C
−2
= 140 N m

23. (320) From Stefan's law the rate at which an object

14. (1)
2 2 2 2 2
radiates, energy (E) per unit surface area is
W = 8πS (R − R ) = 8πS [(2R) − R ] = 24πR S
P = σT ;
2 1 4

15. Fb + Fb Given, P = 20 cal m s

1
−2 −1

(4)
1 2

m =
g ∴ T1 = 227 + 273 = 500K
4
2 2 ∴ 20 = σ(500) (1)
m = 10 × 6 × 0.6 + 10 × 4 × 1 = 760g

Also T 2
∘
= 727 C = 727 + 273 = 1000 K
16. (3) The capillary rise h is given by, 4
∴ P2 = σ(1000)
2S cos θ
4
h = (500)
20
ρgr
∴ =
hr = constant for a given glass and liquid. P2 (1000)
4

The correct graph is hyperbolic in shape. (1000)

4
× 20
−2 −1
P2 = = 320 cal m s
17. (1) Path bc is an isochoric process. (500)
4

∴ Work done by gas along path bc is zero.

24. (1) Both gases will have same number of rotational degree
18. (2) In isothermal process, curves between p and V is such of freedom (equal to 2). Since both are diatomic and are at
that T is farther from the origin than T . Therefore,
2 1
the same temperature. Average rotational kinetic energy per
T > T .
2 1 1
molecule for both the gases = 2 ( KT ) . Required ratio =
19. (3) 2

From the right angle triangle P RO 1.

2

(OR)
2
= (P R)
2
− (P O)
2
= l
2
− (
l
)
25. (25) From Ist law of thermodynamics,
2 Q = W + ΔU (1)

After expansion where Q is heat supplied to the gas,

W = work done by the gas
2
2 1
2
( OR ) = [l (1 + α2 t)] − [ l (1 + α1 t)]
2 ΔU = change in internal energy

2 2 Q

l
2
−
l
= l
2
(1 + α t
2 2
+ 2α2 t) −
l
(1 + α t
2 2
+ 2α1 t)
Also, W =
2 1 5
4 4
Neglecting α 2
t
2
and α 2
t
2 So, from equation (1),
2 1
2
Q 4Q
l 2α1
2 ΔU = Q − = (2)
0 = l (2α2 t) − (2α1 t) ⇒ 2α2 = ⇒ α1 = 4α2
5 5
4 4
nRΔT

20. (1) In configuration I Now, ΔU = , where n is the number of mole.

γ − 1
total thermal resistance R = universal gas constant, ΔT = change in temperature
ℓ ℓ ℓ
R1 = + =
3
For a diatomic gas, γ = 7/5
KA 2KA 2 KA nRΔT
In configuration II ΔU = (3)
5/2

From equation (2) and (3),

3
 4Q nRΔT 0.5
= pCO = × 12 = 8 atm
5 2/5 0.75
pCO 8 8
Also, Q = nCΔT Kp = = = = 4 .
1/2 1/2
(4) 2
4nCΔT nRΔT
= (p )
CO2
5 2/5

5 5 25 36. (2) NH NO solution is acidic as it is salt of weak base

4 3
or C = ( )( )R = R
4 2 8
and strong acid. NaNO solution is neural as it is salt of 3

∴ x = 25
strong acid and strong base Na CO solution is alkaline as 2 3

it is salt of strong base and weak acid.

26. (1) For equilibrium process
37. (1) Increase in pressure favours less moles side.
27. (2) Aqueous solutions of strong base + weak acid salts are i. e. , Δn = −ve.
alkaline in nature. (1) N2 + 3H2 ⇌ 2NH3 ; Δn = − 2
NH Cl : WB + SA
4 (2) I2 + H2 ⇌ 2HI ; Δn = 0
K2 CO3 : SB + WA
(3) N2 + O2 ⇌ 2NO ;Δn = 0
Na2 B4 O7 ⋅ 10H2 O : SB + WA
(4) N2 O4 ⇌ 2NO2 ; Δn = + 1.
NaCl : SA + SB
Hence, option (1) is correct.
28. 1
(2) pH = 7 + [pKa − pKb ] 38. (2) 6HCHO ⇌ C H O 6 12 6
2
1
A very high value of K for the given equilibrium shows that
= 7 + (3.2 − 3.4) = 6.9 dissociation of glucose to form HCHO is very-very small.
2
Hence, at equilibrium,
29. (4) Given, [OH −
] = 5 × 10
−2
[C6 H12 O6 ] = 1M
−2
∴ pOH = − log 5 × 10 [C6 H12 O6 ]
K =
= − log 5 + 2 log 10 = 1.30 6
[HCHO]
∵ pH + pOH = 14
22
1
∵ pH = 14 − pOH i. e.6 × 10 =
6
[HCHO]
= 14 − 1.30 = 12.70
1/6
1
30. (3) BaCO → Ba 3
2+
+ CO
2−

3
or [HCHO] = (
22
)
6 × 10
If solubility = x −4
= 1.6 × 10 M
2
Ksp = x ⇒ x = √Ksp

39. (3) It is a basic buffer

31. (1) pH is lower, acidic strength is more. [ salt ] 0.01
∴ pOH = pK + log = 5 + log = 4
32. (2) Self Explanatory b
[ base ] 0.1

33. (4) Acid1 + Base2 ⇌ Acid2 + Base1

∴ pH = 14 − pOH = 14 − 4 = 10 .
40.
2− + 2−
HPO3 + H2 O ⇌ H3 O + PO3 1

− + 2−
(4) Milli equivalent of HCl = × 75 = 15
H2 PO4 + H2 O ⇌ H3 O + HPO4 5
1
H3 PO4 + H2 O ⇌ H3 O
+
+ H2 PO
−

4
Milli equivalent of NaOH = 25 × = 5
5
Therefore, pair paid given in option (4) is not a conjugate
Total number of eq. = 15 − 5 = 10
acid pair as one species is not formed from the other by
Total volume = 100 mL
donation of proton. 10 1
Normality = = , [H
+
] = 10
−1
M .
34. (1) AgCN ⇌ Ag
+
+ CN
−
100 10
+ − −17
KSP = [Ag ] [CN ] = 6 × 10 41. (3) Addition of inert gas at constant volume has no effect
Let[Ag
+
] = S1 , then [CN
−
] = S1
on equilibrium.
42. (4) Salt if SB and WA increases pH.
2 −17 −9
S = 6 × 10 , S1 = 7.8 × 10
1
2+
Ni(OH)2 ⇌ Ni + 2OH
2
43. (4) Δng = 0, then Kp = Kc
2+ − −15
KSP = [Ni ] [OH ] = 2 × 10 If Δng = + ve, then Kp > Kc

2 + - If Δng = - ve, then Kp < Kc

Let [Ni ] = S2 ,then [OH ] = 2S2

2 −15 −4 Δng = np - nr in gaseous state

(S2 ) (2S2 ) = 2 × 10 , S2 = 0.58 × 10
For (4) Δn = 1
Ni(OH)2 is more soluble than AgCN.
35. (1) 44. (3) K = [B] [C]
c
2

1 1 even [C] is doubled, K will remain same, as K depends c c

C+ CO2 → CO2
2 2
only on temp.
Initial 0.5 − 2 ′ 2
⇒ Kc = [B] [C] = [B ] [2C]
0.5 − 0.25 0.5 (As 50 % 2
At equilibrium [B] 2
′
= 0.25 only converted) ⇒ [C] = [B ] [C]
2
Total moles = 0.75
0.25
pCO = × 12 = 4 atm
2
0.75
 2
[B] [salt]
′ 2
⇒ = [B ] pH = pKa + log
2 [acid]
[B] 2
′
⇒ [B ] = = 4.76 + log
√2 3

= 4.76 + (0.3 − 0.48) = 4.58

45. (3) = 4.58 × 10
−2
= 458( Nearest integer )
A(g) + 3B (g) ⇌ 4C (g)

t = 0 a a 0
51. (1) f (y) = 2y
2
+ by + c

teq a − x a − 3x 4x

given a − x = 4x

a = 5x
4 4
[C] [4x] 256
Kc = = = = 8
3 3
32
[A] [B] [4x] [2x]

46. (5) MX(s) ⇌ M(aq) + X

−

(aq)
S S

Ksp = [M
+
] [X
−
] Now, f (1) = 2(1) 2
+ b(1) + c ]
2 = 2 + b + c = 2 − 5 + 3 = 0
∴ Ksp = S

∴ S
2
= 2.50 × 10
−9
52. (2) Given, f (x) = |x − 2| + |x − 3|
S =
√
2.50 × 10
−9
=
√
25.0 × 10
−10
for f (x) = |x − a| + |x − b| the minimum value of f (x),
= 5.00 × 10
−5
mol L
−1
we get either at x = a or at x = b
∴ Value of x = 5 So for f (x) = |x − 2| + |x − 3|
f (2) = 0 + 1 = 1, f (3) = 1 + 0 = 1.
47. (7) For a salt of weak acid and weak base,
So, f (x) = 1 min
1
pH = 7 + (pKa − pKb ) and maximum value will be ∞ at x = ∞.
2
∵ fmax = ∞ + ∞ = ∞
1
= 7 + (5.23 − 4.75) = 7.24 ≈ 7 So, range = [1, ∞)
2

48. (2) 53. 1

M[OH]
x
⇌ M
x +
+ xOH
−
(3) is defined
(S)
(S) (xS) log(1 − x)

x −12 x x+1 −12 ⇒ 1 − x > 0, x ≠ 0 ⇒ 1 > x, x ≠ 0 ⇒ x < 1, x ≠ 0 ∴

Ksp = S × (x S) = 4 × 10 ∴ x × S = 4 × 10

x −4(x+1) −12 Domain = (−∞, 0) ∪ (0, 1)

∴ x × 10 = 4 × 10

x
x
× 10
−4x
× 10
−4
= 4 × 10
−12
x
x
× 10
−4x
= 4 × 10
−8
54. (2) For f (x) to be defined, we must have
On comparing both sides, x
2
− 3x + 2 = (x − 1)(x − 2) > 0 ⇒ x < 1 or > 2
x = 4 and 10
−4x −8
Domain of f .
x
= 10 = (−∞, 1) ∪ (2, ∞)

∴ x = 2
55. (1) f (x) =
1
is defined
49. (3) 2
x +1

If x 2
+ 1 ≠ 0 ∀x ∈ R

56. (1) R = {(1, 2), (2, 3), (3, 4), (4, 5), (5, 6)}
Domain = {1, 2, 3, 4, 5}
57. √|x| − x
(3) Given, f (x) =
√x − [x]

Case I |x| − x ⩾ 0

∴ x ∈ R (1)

Case II x − [x] > 0

∴ {x} > 0 (2)

From Eqs. (1) and (2), we get

Domain = R − Z
58. (1) (x − 2)(x − 5) > 0

∴ x ∈ (−∞, 2) ∪ (5, ∞)

59. (4) The function is defined for values of x satisfying

50. (458) Millimoles of NaOH = 20 × 0.1= 2 2/3 1/3
x + x − 2 ≤ 0
Millimoles of CH COOH = 50 × 0.1 3
1/3 1/3
⇒ (x + 2) (x − 1) ≤ 0
CH3 COOH + NaOH →CH3 COONa + H2 O

CH3 COOH millimoles left = 5 − 2 = 3

CH3 COONa millimoles formed = 2

5
 ⇒ −2 ≤ x
1/3
≤ 1 68. (2) Domain of sin −1
x is −1 ≤ x ≤ 1 i.e., [−1, 1]

⇒ −8 ≤ x ≤ −1
69. 7π π
(2) cos
−1
(tan ) = cos
−1
[tan(2π − )]
60. (2) A = {1, 2, 3} 4 4

R = {(1, 2)} −1
π
= cos (− tan )
Then R is transitive by definition. 4
−1
= cos (−1) = π
61. (2) Let A = {2, 4, 6, 8}
R = {(2, 4), (4, 2), (4, 6), (6, 4)} 70. 1 π

If (2, 4) ∈ R then (4, 2) ∈ R (4) Given tan(2tan −1

− )
5 4
∴ R is symmetric. 2
⎛ ( ) ⎞
1 5 5
62. 5x − x
2 2tan
−1
= tan
−1
⎜
⎜
⎟ = tan
⎟
−1
( )

(1) Given that f (x) = √log 10

( )
5
⎝ 1 −
1

25
⎠
12

4
5 π

For domain of f (x), −1

5 π 12
− tan
4

2
∴ tan(tan − ) =
5x − x 12 4 5 π

log10 ( ) ≥ 0 1 + ⋅ tan
12 4
4
7
5
2 − 1 −( )
5x − x 12 12 −7
⇒ ≥ 1 = = =
4 5 17 17
2
1 + ( )
⇒ x − 5x + 4 ≤ 0 12 12

⇒ (x − 1)(x − 4) ≤ 0
71. (1) Let tan −1
2 = θ ⇒ tan θ = 2
⇒ x ∈ [1, 4]
x = sin 2θ

63. 1 2 tan θ
(1) Given f (x) = x + , where x ≥ 1 and y ≥ 2 =
2
x 1 + tan θ
1 4 4
i.e., y = x + = = (1)
x 1 + 4 5
2
⇒ x − xy + 1 = 0 4

y ± √y 2 − 4
Let tan −1
( ) = ϕ
3
i.e., x = 4 π
2
⇒ tan ϕ = ,0 < ϕ <
y ± √y 2 − 4 3 2
−1
∴ f (y) = ϕ
2 y = sin( ) (2)
2
x + √x − 4 2
When x ≥ 2, f −1
(x) = ≥ 1 4 3
2 tan ϕ = ⇒ cos ϕ =
3 5
x + √x2 − 4
−1
∴ f (x) = ϕ 3
2
2 ⇒ 1 − 2sin ( ) =
2 5

64. (2) Given f (x) = (a − x n

)
1/n

2
ϕ 1
1/n
⇒ sin =
n
n 1/n 2 5
∴ f of (x) = f (f (x)) = [a − {(a − x ) } ]
ϕ 1
1/n
⇒ sin( ) =
n
= [a − (a − x )] = x 2 √5

1
65. (3) Given, f (x) = x 2
− 1 and g (x) = (x + 1)
2
(2) ⇒ y =

2 √5
∴ gof (x) = g[f (x)} = g (x − 1)
4 1
2
2 ⇒ x + y = + = 1
2 4
= (x − 1 + 1) = x 5 5

66. √5 72. (6) cos

−1
x, cos
−1
y, cos
−1
z ∈ [0, π] .
(3) sin[2cos
−1
]
cos
−1
x + cos
−1
y + cos
−1
z = 3π
3

2
⇒ x = y = z = −1
⎡
−1
⎛ √5 ⎞⎤ ⇒ Required eypression
= sin cos 2( ) − 1
100 100 100
⎣ ⎝ 3 ⎠⎦ = (−1) + (−1) + (1)

−1 −1 2
9
[∵ 2cos x = cos (2x − 1)] −
101 101 101

5 1 (−1) + (−1) + (−1)

−1 −1
= sin[cos (2. − 1)] = sin[cos ( )] 9
9 9 = 1 + 1 + 1 −
−1 − 1 − 1
1
−1 −1 −1
= sin[sin √1 − ] [∵ cos x = sin √1 − x2 ] = 3 + 3 = 6
81

80 80 √80 4√5 73. (38) Let g (15) = k, then f (k) = 15 , which implies
−1
= sin[sin (√ )] = √ = = .
f (k) = 2k − 7 = 15 ⇒ k = 11 ⇒ g (15) = 11
81 81 9 9
Since f (x) = g (x), thus g
−1 −1
(x) = f (x) ,
67. 1 2
which implies
(4) Now, tan −1
( ) + tan
−1
( )
4 9
g
−1
(17) = f (17) = 2 × 17 − 7 = 27 .
1 2

−1
⎛ 4
+
9
⎞
−1
1 Therefore, g (15) + g −1
(17) = 11 + 27 = 38 .
= tan = tan ( )
1 2 2
⎝ 1 − × ⎠
4 9
74. (2039) Given, f (x) = ax − 3, g(x) = x b
+ c and ∴ h(x) = f og(x) = 2x
3
+ 7

Let f og(x) = h(x) Now, f og(x) = a (x + c) − 3

b

−1
x − 7
1/3
get a = 2, b = 3 and c = 5
(f og) (x) = ( )
2 So, f og(ac) = f og(10) = 2(10) 3
+ 7 = 2007

1/3 b 3
g[f (x)] = (ax − 3) + c = (2x − 3) + 5
x − 7
−1
h (x) = ( ) 3
gof (b) = (2(3) − 3) + 5 = 27 + 5 = 32
2
1/3 Sum = 2007 + 32 = 2039
x − 7
Let y = ( )
2 75. (16) Substitute a = 3, b = 1 into the given equation, we
3
x − 7
3 get 3 ⊕ 1 = (3 + 1) = 16.
2

⇒ y = ⇒ x = 2y + 7
2