31-08-2025

9610ZJM802353250003 JM

PART 1 : PHYSICS

SECTION-I

1) A body of mass 1 kg tied to one end of string is revolved in a horizontal circle of radius 0.1 m with
a speed of 3 revolution/sec, assuming the effect of gravity is negligible, then linear velocity,
acceleration and tension in the string will be

(A) 1.88 m/s, 35.5 m/s2, 35.5 N

(B) 2.88 m/s, 45.5 m/s2, 45.5 N
(C) 3.88 m/s, 55.5 m/s2, 55.5 N
(D) None of these

2) A particle of mass m moves with constant speed along a circular path of radius r under the action
of a force F. Its speed is :

(A)

(B)

(C)

(D)

3) Two cars of masses m1 and m2 are moving along the circular path of radius r1 and r2. They take
one round in the same time. The ratio of angular velocities of the two cars will be :-

(A) m1 : m2
(B) r1 : r2
(C) 1 : 1
(D) m1r1 : m2r2

4) A particle starts from point 'A' reaches to B in a uniform circular motion. Find angular
displacement of the particle as seen from centre :-
(A)

(B)

(C)

(D)

5) Two particle having mass M and m are moving in a circular path having radius R and r. If their
time periods are same, then the ratio of their angular velocities will be :-

(A)

(B)

(C) 1

(D)

6) Two particles are moving in circular paths of radii r1 and r2 with same angular speeds. Then the
ratio of their centripetal acceleration is :-

(A) 1 : 1
(B) r1 : r2
(C) r2 : r1
(D) None of these

7) A car is moving at a speed of 40 m/s on a circular track of radius 400 m. This speed is increasing
at the rate of 3 m/s2. The acceleration of car is :-

(A) 4 m/s2
(B) 7 m/s2
(C) 5 m/s2
(D) 3 m/s2

8) The angle between velocity vector and acceleration vector in uniform circular motion is :-

(A) 0°
(B) 180°
(C) 90°
(D) 45°

9) A grinding wheel attained a angular velocity of 20 rad/sec in 5 sec starting from rest. Find the
number of revolutions made by the wheel :-

(A)
revolution
(B)
revolution

(C)
revolution
(D) None

10) A wheel having a diameter of 3 m starts from rest and accelerates uniformly to an angular
velocity of 210 r.p.m. in 5 seconds. Angular acceleration of the wheel is :-

(A)

(B)

(C)

(D)

11) A transformer has a efficiency of 80%. It is connected to a power input of 5 kW at 200V. If the
secondary voltage is 250V, the primary and secondary currents are respectively :-

(A) 25A, 20A

(B) 20A, 16A
(C) 25A, 16A
(D) 40A, 25A

12) A uniform dielectric hollow cylinder of mass M, radius R, length carrying uniform charge of
surface charge density can rotate without friction about a fixed horizontal axle that coincides with
the axis of the cylinder. Several turns of a light thin insulating cord are wrapped on the cylinder and
a block of mass m is suspended from the free end of the cord. Initially the block is held at rest as
shown in the figure. Find acceleration of the block is held at rest as shown in the figure. Find
acceleration of the block after it is released. Neglect charge transferred to the cord and fringing of
magnetic field at the ends of the cylinder. Acceleration due to gravity is g and permeability of the

medium inside the cylinder is .

(A)

(B)

(C)

(D)

13) Find the self inductance per unit length of a co–axial cable the inner conductor is a solid
cylindrical rod having uniform current density per unit cross–section, outer conductor is a thin

cylindrical shell .

(A)

(B)

(C)

(D)

14) A conducting loop with shape (a) is placed in uniform magnetic field B. Its one curved portion is
turned so that the shape becomes (b). Find the correct statements(s). Given be the resistance.

(A) Change in flux is given by

(B) Change in flux is zero
Total charge crossing any point of loop is
(C)

Total charge crossing any point of loop is

(D)
15) A semicircular wire of radius R is rotated with constant angular velocity about an axis passing
through one end and perpendicular to the plane of the wire. There is a uniform magnetic field of

strength B. The induced e.m.f between the ends is :

(A)
(B)
(C)
(D) None of these

16) A magnetic field of T acts at right angles to a coil of area 100 cm2 with 50 turns, The
average emf induced in the coil is 0.1V, when it is removed from the field in time t. The value of t is

(A) 0.1 sec

(B) 0.01 sec
(C) 1 sec
(D) 20 sec

17) In a coil of self inductance 0.5 henry, the current varies at a constant rate from zero to 10
amperes in 2 seconds. The e.m.f. generated in the coil is

(A) 10 volts
(B) 5 volts
(C) 2.5 volts
(D) 1.25 volts

18) A small square loop of side is placed inside a large square loop of wire L The loops are
coplanar and their centres coincide. The mutual inductance of the system is proportional to

(A)

(B)

(C)

(D)

19) In the circuit shown, X is joined to Y for a long time, and then X is joined to Z. The total heat

produced in R2 is
(A)

(B)

(C)

(D)

20) A particle of mass m and charge q starts moving from the origin under the action of an electric
field

and magnetic field with a velocity Then speed of the particle becomes
2v0 after a time t. Then t equals

(A)

(B)

(C)

(D)

SECTION-II

1) An inductor (XL = 2Ω) a capacitor (XC = 8Ω) and a resistance (8Ω) is connected in series with an ac

source. The voltage output of A.C source is given by V = cos 2π 50t. Find the R.M.S. potential

difference between A and B.

2) In a region of space, a time dependent magnetic field B= 0.4t Tesla points vertically upwards.
Consider a horizontal, circular loop of radius 2 cm in this region. The magnitude of the electric field
(in mV/m) induced in the loop is ___________.

3) The potential difference V and the current I flowing through an instrument in an ac circuit of
frequency f are given by volts and amperes The average
power dissipated in the instrument is
4) If the equation for the angular displacement of a particle moving on a circular path is given by (θ)
= 3t2 + 0.5, where θ is in radians and t in seconds, then the angular velocity (in rad / sec) of the
particle after 1s from its start is:-

5)

The square of the angular velocity ω of a certain wheel increases linearly with the angular
displacement during 100 rev of the wheel's motion as shown. The time t required for the increase is

, then x is ?

PART 2 : CHEMISTRY

SECTION-I

1) Most stable carbanion is :-

(A) HC ≡ C
(B) C6H5

(C) (CH3)3C – CH2

(D) (CH3)2C = CH

2) Which Carbanion is more stable.

(A)

(B)

(C)

(D)

3) Select the pair of chain isomer ?

(A)
and

(B)
and

(C)
and

(D)
and

4) Which of the following statements is wrong?

(A) Alkanes with four carbon atoms show chain isomerism.

(B) Alkynes with molecular formula C4H6 show chain isomerism.
(C) Alkanols are functional isomers of alkoxyalkanes.
(D) Alkenol are functional isomers of alkanals.

5) Identify compound which can show geometrical isomerism :

(A)

(B)

(C)

(D)

6) Identify meso compound.

(A)

(B)
(C)

(D)

7) Which of the following molecule is chiral.

(A)

(B)

(C)

(D)

8) Number of POS present in CH4 ?

(A) 2
(B) 3
(C) 4
(D) 6

9) How many alcohols (neglecting stereoisomers) are possible with the molecular formula C5H12O

(A) 5
(B) 6
(C) 7
(D) 8

10)

Which of the following conformer is most stable

(A)

(B)

(C)

(D)

11) Which of the following compounds has no geometrical isomer :-

(A) 1-Phenylpropene
(B) 1, 2-Diphenylethene
(C) 1, 2-Diphenylpropene
(D) 1, 1-Diphenylpropene

12) Which is a pair of geometrical isomers :-

(A) I and II
(B) I and III
(C) II and IV
(D) III and IV

13) How many meso isomers are possible for 2, 3, 4-pentanetriol -

(A) 1
(B) 2
(C) 3
(D) None of these

14) Acidified K2Cr2O7 on reaction with hydrogen peroxide give deep blue solution due to formation of
:-

(A) Cr2(SO4)3
(B) CrO(O2)2
(C)
(D)

15) Among following which are amphoteric oxide?

Mn2O7, CrO3, Cr2O3, CrO, V2O5, V2O4

(A) V2O5, Cr2O3

(B) Mn2O7, CrO3
(C) CrO, V2O5
(D) V2O5, V2O4

16) The point of dissimilarity between lanthanides and actinides is

(A) three outermost shells are partially filled

(B) they show oxidation state of +3 (common)
(C) they are called inner transition elements
(D) they are radioactive in nature

17) The electronic configuration for Neodymium is :

[Atomic Number for Neodymium 60]

(A) [Xe] 4f4 6s2

(B) [Xe] 5f47s2
(C) [Xe] 4f6 6s2
(D) [Xe] 4f15d16s2

18) A complex of certain metal has the magnetic moment of 4.91 BM whereas another complex of
the same metal with same oxidation state has zero magnetic moment. The metal ion could be

(A) Co2+
(B) Mn2+
(C) Fe2+
(D) Fe3+

19) [Fe(H2O)6]+2 has Crystal Filled Splitting Energy value 10,400 cm–1 and pairing energy value
17,600 cm–1 then it is :

(A) Low spin complex

(B) Paramagnetic in nature
(C) Diamagnetic in nature
(D) None of these

20) Which of the following complex is inner orbital as well as low spin -
 2+
(A) [Ni(NH3)6]
(B) [Cr(gly)3]
3+
(C) [Ti(H2O)6]
(D) None

SECTION-II

1) How many total resonating structures can be drawn for the following anion? (include those

without separation of charge)

2) How many of the following compound will show geometrical isomerism ?

3) Total number of sterioisomers possible for the molecule is/are :

4) When mixture of NaCl and K2Cr2O7 is gently warmed with conc.H2SO4 then compound X is formed.
What is the oxidation state of central atom of X.

5) Among the following complexes, how many have 'spin only' magnetic moment of 2.83 B.M.?
[Ni(CO)4], [Ni(CN)4]2–, [NiCl2(PPh3)2], [NiCl4]2–, [NiF6]2–, [NiF6]4–

PART 3 : MATHEMATICS

SECTION-I

1) Number of principal solution(s) of the equation , is

(A) 1
(B) 2
(C) 3
(D) 4

2) Number of solutions of the equation

in

(A) one
(B) two
(C) three
(D) four

3) Number of pairs (x, y) of real numbers that satisfy the equation

(A) 0
(B) 1
(C) 2
(D) Infinite

4) The number of solutions of sin7x + cos7x = 1, x ∈ [0, 4π] is equal to

(A) 11
(B) 7
(C) 5
(D) 9

5) If the maximum value of is λ then the value of is

(A) 0
(B) 6
(C) 8
(D) 1

6) The number of values of 'x' satisfying the equation x3 + 27cot3x + 9x2cotx + 27x cot2x – π3 = 0, in
the interval [–π, π] is

(A) 1
(B) 0
(C) 2
(D) More than 2
7) Let x1 and x2 are two distinct roots of the equation acosx + bsinx = c, then , is

(A)

(B)

(C)

(D)

8) If complete set of value of x is

(where n is an integer)

(A)

(B)

(C)

(D)

9) If y = cos cosx – cos2 , then its graph is -

(A) a straight line through the origin

(B)
a straight line passing through and parallel to x-axis.

(C)
a straight line passing through
(D) not a straight line.

10) Let the tangent at (1, 1) on the curve y2 = x(2 – x)2 meet the curve again at point P(α, β) in the
first quadrant, then α + 4β = ?

(A) 15

(B)

(C)

(D) 4

11) The least perimeter of an isosceles triangle in which a circle of radius r can be inscribed is

(A)
(B)
(C)
(D)

12) If (λ is a real number) has exactly one local maxima and exactly
one local minima then λ cannot be

(A) 1
(B) 2
(C) 3
(D) 4

13) If the surface area of sphere of radius r is increasing uniformly at the rate of 16m2/min, then the
rate of change of its volume is-

(A) proportional to
(B) proportional to r3
(C) proportional to r
(D) proportional to r2

14) Tangent is drawn to ellipse at . Then the

value of θ such that sum of intercepts on axes made by this tangent is least, is

(A)

(B)

(C)

(D)

15) Equation of tangent to the curve y = x10 sin2x + x3tanx + , where it crosses
the y-axis is

(A) 2x + y = 5
(B) x – 2y = 5
(C) x = 5
(D) y = 5

16) The number of real roots of the equation e6x – e4x – 2e3x – 12e2x + ex + 1 = 0 is :

(A) 2
(B) 4
(C) 6
(D) 1
17) If where x1 ≥ –2, x2 ∈ R, then the minimum value of d is
equal to

(A)

(B)

(C) 2
(D)

18) A curve is represented parametrically by the equations x = t + eat and y = – t + eat when t ∈ R
and a > 0. If the curve touches the axis of x at the point A, then the coordinates of the point A are

(A) (1, 0)
(B) (1/e, 0)
(C) (e, 0)
(D) (2e, 0)

19) Let ƒ be any function continuous on [a, b] and twice differentiable on (a, b). If for all x ∈ (a, b),

ƒ'(x) > 0 and ƒ''(x) < 0, then for any c ∈ (a, b), is greater than:

(A)

(B)

(C)

(D) 1

20) Let g : be a non constant twice differentiable such that . If a real valued

function f is defined as , then

(A) f′′(x) = 0 for atleast two x in (0, 2)

(B) f′′(x) = 0 for exactly one x in (0, 1)
(C) f′′(x) = 0 for no x in (0, 1)

(D)

SECTION-II

1) The curve y = ƒ(x) = ax3 + bx2 + cx is inclined at 45° to positive direction of x-axis at (0, 0), but it

touches x-axis at (1, 0) then value of is

2) If ƒ(x) is differentiable function such that ƒ'(α) = 0 = ƒ'(β), ƒ"(α) ƒ"(β) < 0, ƒ(α) = –1, ƒ(β) = 3 (where
α < β). If ƒ"(α) – ƒ"(β) < 0, then minimum number of roots of ƒ'(x) = 0 in [α – 1, β + 1] will be-

3) If f(x) is a twice differentiable function such that f(a) = 0, f(b) = 2, f(c) = -1, f(d) = 2, f(e) = 0
where a < b < c < d < e then the minimum number of zeros of g(x) = (f'(x))2 + f" (x) f(x) in the
interval [a, e] is_______.

4) The number of real solutions of equation 2017x – 2016x = x is_________

5) If , then value of is
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A A C C C B C C C A C A A D B A C B A D

SECTION-II

Q. 21 22 23 24 25
A. 3 4 0 6 7

PART 2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A C D B C A D D D C D C B B A D A C B D

SECTION-II

Q. 46 47 48 49 50
A. 4 3 3 6 3

PART 3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B B D C B C B A B C C B C B D A A D C A

SECTION-II

Q. 71 72 73 74 75
A. 3 4 6 2 7
 SOLUTIONS

PART 1 : PHYSICS

1) Linear velocity
v = wr = 2pnr = 2 × 3.14 × 3 × 0.1 = 1.88 m/s
Acceleration, a = ω2r = (6π)2 × 0.1 = 35.5 m/s2
Tension in string, T = mω2r = 1 × (6π)2 × 0.1 = 35.5 N

2)

3) ω =
T is same for both

∴ ω is also same Hence =

4) Angle mode at centre

= 2 (Angle mode at circumference)

5)

6) ac = w2r

7)

8)

9)

ω = ω0 +αt
20 = 0 + α(5)
ω2 =
(20)2 = 0 + 2(4) Δθ

= 50 rad
10) ω = ω0 + αt

α = 1.4 π rad/s2

11) η = 80%

For transformer η =

output power = 4000 watt

Also, output power = V0 × I0
4000 = 250 × I0
output current I0 = 16 A
(Current across secondary coil)
Input power = Vi × Ii
5000 = 200 × Ii
Input current Ii = 25 A
Current accross primary coils

12)

If magnetic field inside cylinder in Case 2 at the give instant is B, then

In case 2, acceleration of the block after it is released is

13)

Write down total energy

14)
15)
effective length of the wire frame is '2R'

16)

17)

18)

19) Steady-state current in . Energy stored in = heat

produced in R2 during discharge.

20)
21)

22) E × 2πr = = πr2 × 0.4

E=

23)
Here,

24)
2
θ = 3t + 0.5

So angular velocity
ω = 6.t
at t = 1 sec.
ω=6×1
ω = 6 rad./s.

25)

ω2 = ω02 + 2αθ
1600 = 900 + 2α(100 × 2π)
PART 2 : CHEMISTRY

26) Negative charge on more electronegative element is more stable.

27) This Carbanion is Aromatic and Aromatic are more stable.

28) Difference in length of parent carbon chain or side chain.

29) C4H6 → This alkyne will not shows chain isomerism.

30)
 31)

32) D → no POS and no COS so chiral

33)

Plane passing through

(1, 2), (1, 3) , (1, 4)
(2, 3), (2, 4) , (3, 4)

34) Alcohol means –OH

so remaining C are 5C–OH.
Total no. of radicals of 5C are = 8
So, possible alcohol = 8

35)

Due to H-bonding

more stable

36)
Same group present of sp2–c atom
 37)

38) Meso isomers in 2,3,4 – pentanetriol are

= = =2

39)

K2Cr2O7 + H2SO4 + H2O2 → CrO(O2)2 + H2O

or
CrO5
deep-blue

40)

V2O5 and Cr2O3 are amphoteric oxides.

V2O4 and CrO are Basic oxides.
Mn2O7 and CrO3 are Acidic oxides.

41)

All actinides are radioactive in nature while Pm is the only lanthanide which is radioactive
Synthetic substance.
Nucleus of actinides are larger as compare to lanthanide. In order to become more stable, the
nucleus of an actinide element undergoes radioactive decay.

42) Electronic configuration of Nd(Z = 60) is;

[Xe] 4f4 6s2

43)

µ = 4.91 B.M
n=4
[Fe(CN)6]–4 & [Fe(H2O)6]+2
n=0 n=4

µ=0 µ=4.91

44)

Δ0 = 10400 cm–1
P = 17600 cm–1

Δ0 < P WFL
45) For d8, d3, and d1 electronic configuration in octahedral field, low spin and high spin terms
are not defined.

46)

47)

b, d, e

48) 3 geometrical isomers possible.

49) In this reaction CrO2Cl2 is formed in which Cr is +6.

50) [Ni(CO)4],

[Ni(CN)4]2–,

[NiCl2(PPh3)2],

[NiCl4]2–,

[NiF6]2–,
PART 3 : MATHEMATICS

51)

= cos2x = (1 – sin2x)
Let sinx = t

= 1 – t2
t2 – 2t + 1 = t(1 – t)(1 + t)
⇒ (1 – t) [(1 – t) – t(1 + t)] = 0
⇒ (1 – t) [1 – 2t – t2] = 0
t = 1, t2 + 2t – 1 = 0

sin x = 1,

sin x = 1, ⇒
also and cos x < 0

⇒ solution in
So, 2 principal solutions.

52) Use we get

⇒ solution does exists if sinx + cos x =

⇒ Solutions in the interval are

⇒ 2 solutions.

53) Let and Since and we have

where equality holds only when Therefore

with equality only when So we have hence sin y = 1; this also implies

therefore Thus the solutions are

54) sin7x ≤ sin2x ≤ 1 …(1) and cos7x ≤ cos2x ≤ 1 …(2)

also sin2x + cos2x = 1
⇒ equality must hold for (1) & (2)
⇒ sin7x = sin2x & cos7x = cos2x
⇒ sinx = 0 & cosx = 1
or
cosx = 0 & sinx = 1

⇒ x = 0, 2π, 4π, ,
⇒ 5 solutions

55)

y = 7 cos2 x + 6 sinx cos x – sin2 x = 3sin 2x + 4 cos 2x + 3

The maximum value of y is 8
Also

56) x3 + 27cot3x + 9x2cotx + 27x cot2x = π3

(x + 3cotx)3 = π3

(Now graph)
57)

⇒ ,

58) sin2x(4(1 – sin2x) – 1)(1 – 4(1 – cos2x)) ≥ 0

2sinxcosx(3 – 4sin2x)(4cos2x – 3) ≥ 0
2(sin3x)(cos3x) ≥ 0
sin6x ≥ 0

59)

60) 2yy' = (2 – x)2 – 2x (2 – x)

∴ Equation of tangent is :

y–1= (x – 1) ⇒ 2y – 2 = –x + 1
⇒ 2y = 3 – x
This tangent again intersect at P

⇒ 4x3 – 17x2 + 22x – 9 = 0

Its roots are 1, 1, α

∴1+1+α= ⇒α= –2=

Put in curve,
β2 = α(2 – α)2

61)
⇒

Find

62)

f ' (x) = 6x2 – 6 (2 + λ) x + 12 λ

∵ For exactly one local max and min
f '(x)= 0 will have two real and unequal roots.
⇒D>0 ⇒

63)

Now,

64) Equation of tangent at is

Its intercept on coordinates axes are and cosec θ. If S denotes their sum, then

For minimum value of S,

Since , so ⇒
Also

⇒ . Thus S is least when .

65) Since the given curve is even differentiable function with ƒ(0) = 5
⇒ equation of tangent is y = 5.

66)

e6x – e4x – 2e3x – 12e2x + ex + 1 = 0

67)
let ....(1)
C2 : y = –x – 4 ....(2)
∴ Diff. w.r.t x in (1,)
⇒ t = –1

68) x = t + eat
y = –t+eat
At A,

y = 0 and
y=0
⇒ –t + eat = 0
⇒ t = eat ...(i)

⇒ eat = ...(ii)

∴t= = eat

∴ t = e, a =
A is (2e, 0)

69) LMVT for x ∈ [a, c] ⇒

LMVT for x ∈ [c, b] ⇒

∵ f"(x) < 0 ⇒ f'(x) is decreasing & α < β

⇒ f '(α) > f'(β) ⇒

⇒ (∵ f(x) is ↑)

70)

Also

is zero at least twice in

71)
y = ax3 + bx2 + cx

since curve touches x-axis at (1, 0)

a + b + c = 0 ⇒ a + b = –1
and 3a + 2b + c = 0 3a + 2b = –1
a = 1, b = –2
ƒ(x) = x3 – 2x2 + x
ƒ'(x) = 3x2 – 4x + 1
ƒ"(x) = 6x – 4
ƒ"(1) = 2, ƒ"'(2) = 6, ƒ(2) = 8 – 8 + 2 = 2

72)

ƒ"(α) = –ve and ƒ"(β) = +ve

so x = α is a point of maxima
& x = β is point of minima

⇒ minimum 4 roots of ƒ'(x) = 0 in

[α – 1, β + 1]

73)
has at least 3 real roots none of which matches with roots of f(x) = 0 (by Rolle's
Theorem)
Now g(x) =

Consider
Let has at least (4 + 3) real & distinct roots
has at least roots in [a, e].

74)

Let f(t) = tx ; x is some real number.

Applying LMVT for f(t) in [2016, 2017]
⇒ x = x(x-1) (as 2017x – 2016x = x)
⇒ x[λ(x–1) – 1] = 0
⇒ x = 0,1

75)

= {using cos(A + B + C) formula}