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The document consists of a series of physics, chemistry, and mathematics problems, including questions on quantum numbers, electric fields, thermodynamics, and chemical reactions. Each section presents multiple-choice questions that require calculations or conceptual understanding of various scientific principles. The problems are structured to test knowledge in specific areas of the subjects, with a focus on problem-solving skills.

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0% found this document useful (0 votes)
7 views33 pages

Solution

The document consists of a series of physics, chemistry, and mathematics problems, including questions on quantum numbers, electric fields, thermodynamics, and chemical reactions. Each section presents multiple-choice questions that require calculations or conceptual understanding of various scientific principles. The problems are structured to test knowledge in specific areas of the subjects, with a focus on problem-solving skills.

Uploaded by

agrawalkalash848
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

07-05-2026

1803CJA101029250210 JA

PART-1 : PHYSICS

SECTION-I (i)

1) Atoms of a hydrogen like gas are in a particular excited energy level. When these atoms de-excite,
they emit photons of different energies. Maximum and minimum energies of emitted photons are
Emax = 52.224 eV and Emin = 1.224 eV respectively. Calculate principal quantum number of initially
excited energy level. (Ionisation energy of hydrogen atom is 13.6 eV)

(A) 6
(B) 4
(C) 5
(D) 3

2) An infinitely long metal cylinder of radius R and surface charge density σ is placed symmetrically
with an imaginary surface of the shape of a prism. The length of prism is L and its 3 sides are all
equal to 3R. The flux through the prism is :

(A)

(B)

(C)

(D)

3) A rough ball is thrown such that it rotates clockwise and moves right in viscous air. The force due
to pressure difference of air acts :

(A) Upwards
(B) Downwards
(C) Nowhere
(D) Can’t say

4) Mercury is filled in a glass beaker which is heated by a flame from below. The level of mercury
with time

(A) rises
(B) falls
(C) rises & then falls
(D) falls & then rises
5) A bar magnet of mass m is given an initial velocity V0 towards the centre of a metallic coil of same

mass initially at rest in gravity free space. The total loss of energy is :

(A)

(B)

(C)

(D) cannot be determined

6) A string is wound on a spool which is kept on a rough horizontal floor having sufficient friction to

prevent slipping. If string is pulled then (1) String winds


(2) String unwinds
(3) Spool moves left
(4) Spool moves right
(5) Point P moves left
(6) point P moves right
Which of the above options are correct ?

(A) 2,3,5
(B) 1,4,6
(C) 2, 4, 6
(D) 2, 3, 4

SECTION-I (ii)

1) Two girls of equal mass m jump off from the border line of a stationary carriage of mass M with
same horizontal velocity u relative to the carriage in same direction. Neglect the effect of friction.
Mark incorrect options.

(A) They will impart greater velocity to the carriage by jumping off simultaneously
(B) They will impart greater velocity to the carriage by jumping one after the other
(C) They will impart same velocity to the carriage in whatever manner they jump off
(D) Insufficient data to reply

2) A body is suspended from a spring balance kept in a satellite. The reading of the balance is W1
when the satellite goes in an orbit of radius R and is W2 when it goes in an orbit of radius 2R. Mark
incorrect options.

(A) W1 = W2
(B) W1 < W2
(C) W1 > W2
(D) W1 ≠ W2

3) Electric field intensity at a point (x, y) is given by where all


parameters are in S.I. units. Then choose the correct statement(s) out of the following :

(A) It represents a conservative electric field.


(B) It represents a non-conservative electric field.
(C) Electric potential at point (1m, 1m) is –4V if electric potential at origin is zero.
(D) Electric potential at point (1m, 1m) cannot be defined.

4) For the circuit shown in figure, which of the following statements are correct ?

(A) Time constant of the circuit is 0.5 sec.


(B) In steady state current through battery is 1.0A.
(C) In steady state current through inductor is 1.0A.
(D) In steady state potential difference across 2Ω resistor is 4V.

5) A solid cylinder of radius R is projected with velocity v0 on a rough horizontal surface of

coefficient of friction ‘μ’ at t = 0 and at the same instant it has an angular velocity of as shown

in figure. Then

(A)
The cylinder stops at and then turns back.

(B)
At the cylinder starts pure rolling.

(C)
At angular velocity of the cylinder is .
(D) 0
At speed of the cylinder is v .

6) In a cylindrical region of radius R, there exists a time varying magnetic field B such that

. A charged particle having charge q is placed at the point P at a distance d (> R) from
its centre O. Now, the particle is moved in the direction perpendicular to OP (see figure) by an
external agent upto infinity so that there is no gain in kinetic energy of the charged particle. Choose

the correct statement/s.

(A)
Work done by external agent is if d = 2R

(B)
Work done by external agent is if d = 4R

(C)
Work done by external agent is if d = 4R

(D)
Work done by external agent is if d = 6R

SECTION-II

1) A force , (where K is a +ve constant) acts on a particle moving in xy plane starting


from origin, the particle is taken along the positive x-axis to the point (a, 0) and then parallel to y
axis to the point (a, a). If the total work done by force F on the particle is nka2, find n + 3.

2) A mercury thermometer reads 80ºC when the mercury is at 5.2cm mark and 60ºC when the
mercury is at 3.9 cm mark. If the temperature when the mercury level is at 2.6 cm mark is T (in
degree Celsius), find T – 35

3) A standing wave with a frequency of 1000 hz in a column of mixture of unknown gases at 27°C

produces node that are 0.1 m apart. Find the value of r = for the mixture. Use R = 8.3 J/mol–K
and molar mass of mixture 124.5 gm/mol. CP & CV are the molar heat capacities at constant pressure
and constant volume respectively.

4) When a source of sound of frequency 600 Hz moves with velocity 30 m/s towards a stationary
observer, the apparent wavelength is λ. If the same source is kept stationary and the observer is
moved with same velocity 30 m/s towards the source, then apparent wavelength is λ', then find λ' – λ
(in cm) for speed of sound in air to be 340 m/s.

5) Two rigid rods of same material and of length L and are placed in equilibrium on a smooth
horizontal plane at temperature T as shown in figure. Springs are in their natural length. If the

temperature is increased by ΔT amount energy stored in springs is , where k is the


spring constant of spring (A) and α is the coefficient of linear expansion of material. (Note: Neglect
the change in spring constant due to increase in temperature).

6) A particle is moving in a plane according to the law x = at2, y = bt3 where a = 2m/s2, b = 1 m/s3.

Radius of curvature of particle at t = 1 s is found to be . Find η.

PART-2 : CHEMISTRY

SECTION-I (i)

1) Which of the statement is incorrect?

(A) Hyponitrous acid is a weak acid and it is isomeric with nitramide.


(B) Sodium dihydrogen pyrophosphate does not exist.

(C) [Co(en)2SO4] is a low spin optically active compound.
(D) Acidic character (w.r.t. oxide acceptor) : XeF6 > XeO2F4 > XeO3

2)

Born Haber cycle helps to determine lattice enthalpy of ionic compound as well as electron gain
enthalpy of different elements. Based on the diagram drawn, answer the questions given below.
What is the magnitude of lattice enthalpy of MgCl2 ?
(A) 20kJ
(B) 40kJ
(C) 15kJ
(D) 60kJ

3)

Which of the following statement(s) is(are) correct?

(1) When a chalk stick is dipped in ink, both absorption and adsorption takes place and surface of
chalk retains the color of ink while the inside in white. (2) Water vapours are absorbed by silica gel
(3) Water vapours are adsorbed by anhydrous CaCl2
(4) The precipitate of Mg(OH)2 attains pink colour when precipitated in presence of magneson
reagent
(A) 4 only
(B) 1 Only
(C) 2, 3 only
(D) 1, 2, 3 only

4) Density of a Vander Waal's gas at 500 K and 1 atm is found to be 0.8 kg/m3. It is also found that
the gas diffuses times slower than pure O2 gas under identical conditions. The value of 'z' for the
real gas is (R = 0.08 atm-ℓ/mol-K) :

(A) 2/3
(B) 3/2
(C) 1.8
(D) 0.8

5) Which of the following oxyanion has 3 identical resonating structures?

(A)

(B)


(C) ClO4
(D)

6) (+)2–butanol has [θ]λ25 = 13.9°. A sample of 2-butanol containing both the enantiomers was found
to have specific rotation value of –3.5° under similar condition. The percentage of the (+) and (–)
enantiomer present in the sample are, respectively :

(A) 37.4% and 62.6%


(B) 62.6% and 37.4%
(C) 42.2% and 57.8%
(D) 35.5% and 64.5%

SECTION-I (ii)

1) Which of the following do NOT represent the correct sequence of indicated properties ?

3– 4–
(A) [FeF6] > [NiF6] : Magnetic moment
3– 3+
(B) [Fe(CN)6] < [Fe(NH3)6] : stability constant
(C) NiO > CaO > BeO : Basic character
(D) F2 < Cl2 < Br2 < I2 : Colour intensity

2) Which of the following is/are true statements?

(A) In Puddling process wrought iron is produced.


(B) In blast furnace phosphate and silicate are reduced into P and Si which pass into molten iron.
(C) B, Ga, In, Ge and Si are refined by zone refining.
(D) In Mond's process high spin complex is formed.

3) If an optically active compound 'A' decompose through given parallel 1st order kinetics.

Initial mole of A is 2 ( k1 = 0.0693 sec–1 , k2 = 0.1386 sec–1). If only A, B & D are optically active
compounds and their angle of rotation per mole are 60º, 30º, –90º respectively, then which of the
following is/are correct -

(A) Angle of rotation after time 3.33 sec is 20º


(B) Mixture is levorotatary after 75% decomposition of A
(C) Overall t1/2 of A is 10/3 sec.
(D) Percentage of C formed in the product is 11.11%

4)

100 ml, 0.3 M solution of HCl is mixed with 50 of water to form solution (A). 50 ml of solution (A) is
mixed with 50 ml, 0.05M NaOH to form solution (B). Another 50 ml of solution (A) is mixed with 100
ml, 0.05M NH4OH to form solution (C). Last 50 ml of solution (A) is mixed with 100 ml, 0.1 M of
AgNO3 to form solution (D),
[Given Ksp(AgCl) = 10–10 , Kb (NH4OH) = 2 × 10–5 , log 2 = 0.3, log 3 = 0.48)]

(A) pH of solution (A) is 0.7


(B) pH of solution (B) is 1.12
(C) pH of solution (C) is 4.7
(D) mole of Ag+ ion in solution D is 1.5 × 10–6 mole

5) Which of the following reactions give para bromophenol as a major product?

(A)

(B)

(C)

(D)

6) In which of the following reaction(s) the product is/are correctly matched?

(A)
CH3–CH=O CH3–COOH

(B)

(C)
(D)

SECTION-II

1)

Among the following cations(s) :


Hg2+, Mg2+, Cu2+, Ag+, Pb2+
(i) Number of cation(s) gives(s) ppt with H2S / H+ is = (X)
(ii) Number of cation(s) gives(s) ppt with KI is = (Y)
(iii) Number of cation(s) gives(s) ppt with dil. HCl is = (Z)
Find the value of (X + Y + Z)

2)

Consider the following reactions


(i) PbS + H2O2 →
(ii) Ag2O + H2O2 →
(iii) K4[Fe(CN)6] + H2O2 + H2SO4 →
(iv) K3[Fe(CN)6] + H2O2 + KOH →

(v) K2Cr2O7 + H2O2 + H2SO4


(vi) CrCl3 + H2O2 + KOH →

(vii) Cl2 + H2O2

(viii) KIO4 + H2O2


(ix) NaMnO4 + H2O2 + H2SO4 →
In how many reactions oxidising nature of H2O2 is observed.

3)

A definite amount of an ideal gas is taken from state-I to state-II isothermally at 300K. If the process
is carried out reversibly then work done is – 1750 kJ and if process is carried out irreversibly then
work done is –1000 kJ. If ΔStotal is x kJ/K for irreversible isothermal process then give 'x' .

4)

Liquids A and B form ideal solution over the entire range of composition. At temperature T,
equimolar binary solution of liquids A and B has vapour pressure 45 Torr. At the same temperature,
a new solution of A and B having mole fractions xA and xB respectively, has vapour pressure of 22.5

Torr. If the value of in the new solution is Y. Then the value ‘Y’ is :
(Given that the vapour pressure of pure liquid A is 20 Torr at temperature T)

5) Consider the figure

[Link]. Amino acids pKa values

α-COOH Side chain

1 Arginine 2.17 9.04 12.48

2 Alanine 2.34 9.69 ........

3 Aspartic acid 2.09 9.82 3.86

4 Lysine 2.18 8.95 10.79

5 Glutamic acid 2.19 9.67 4.25

6 Valine 2.32 9.62 ........

Calculate :
Number of amino acids move towards cathode = X
Number of non essential amino acids move towards anode = Y

Find =?

6) How many reagents can be used to distinguish these compounds :

(i) NaHCO3 (ii) Na metal (iii) Neutral FeCl3


(iv) AgNO3 + NH4OH (v) CS2, HgCl2 (vi) NaOI
(vii) 2,4–DNP

PART-3 : MATHEMATICS
SECTION-I (i)

1) If where z > 0, then |(1 + z)f '(z) cot(f(z))| is equal to

(A) 0
(B) 1
(C) 2
(D) 3

2) Given vectors ; and . The volume of

parallelopiped with three conterminous edges as

equals

(A)

(B)

(C)

(D)

3) A parabola whose focus S(3, 4) is touching the co-ordinate axes. The equation of circle whose
diameter is the portion of tangent at vertex of the parabola between the co-ordinate axes is

(A) x2 + y2 – 6x – 8y = 0
(B) x2 + y2 + 3x + 4y = 0
(C) x2 + y2 + 6x + 8y = 0
(D) x2 + y2 – 3x – 4y = 0

4) Number of complex number(s) 'z' satisfying |z|n = |z|n–2 z2 + |z|n–2 z + 1 (n ∈ Q) and Re(z) ≠
is(are)

(A) 0
(B) 1
(C) 2
(D) 4

5) A polynomial function P(x) of degree 5 with leading coefficient one, increases in interval (–∞, 1)
and (3, ∞) and decreases in interval (1, 3). Given that P'(2) = 0 then value of P'(4) is
(A) 240
(B) 180
(C) 120
(D) 60

6) Let , then has the value equal to

(A)

(B)

(C) π
(D) –π

SECTION-I (ii)

1) If z is non-real complex number satisfying |z| = 2, then which of the following is(are) correct ?

(A)
(where z ≠ ±2)

(B)

(C) |z2 – 1| ≥ 3
(D) |z2 – 1| ≤ 5

2) Let , where a, b, n are even natural numbers and Cr


represent the coefficient of x in the expansion of (1 + x)100 then
r

(A) a + b + n = 504
(B) a + b = 402
(C) a – n = 102
(D) a + 2b + 3n = 900

3) Let ƒ(x) = 2tan–1x and g(x) be a differentiable function satisfying ∀ x, y


2
∈ R and g'(0) = 1 and g(0) = 2. The number of integers 'x' satisfying ƒ (g(x)) – 5ƒ(g(x)) + 4 > 0 where
x ∈ (–10, 20) is greater than or equal to

(A) 5
(B) 6
(C) 7
(D) 8

4) Let six children B1, B2, B3, B4, B5, B6 each have a fair 6 sided die which they roll simultaneously.
Let E denotes the event that atleast three of them roll a prime number and F denotes the event that

B1, B2, B3 throw a prime number. If the conditional probability of F given E is equal to where a and
b are coprime then

(A) 2a + b = 29
(B) |a – b| = 10
(C) ab ≤ 84
(D) b – 4a = 0

5) If pair of variable straight lines x2 + 4y2 + αxy = 0 (α is real parameter) cuts the ellipse x2 + 4y2 =
4 at two points A and B, then which of the following cannot be the locus of point of intersection of
tangents at A and B of ellipse

(A) x2 + 4y2 = 0
(B) 4x2 – y2 = 0
(C) x2 – xy + 4y2
(D) x2 – xy – 4y2 = 0

6) A non-zero vector is equally inclined to three vectors , , . Let


be three vectors in plane of ; and respectively then

(A)
(B)
(C)

(D)

SECTION-II

1) Let ƒ(x) = x3 – ax2 + bx + 6 where a, b ∈ {1, 2, 3, 4, 5, 6}. The probability that f(x) is strictly
increasing is

2) Let a1, a2, a3, ..., an be an increasing arithmetic progression of positive integers. If a3 = 13, then

the maximum value of is

3) Let 'C' be the curve passing through the point (1, 1) has the property that the perpendicular
distance of the normal from origin at any point P of the curve is equal to distance of P from x-axis. If
area bounded by curve 'C' and x-axis in first quadrant is kπ square units then k is equal to
4) A circle is inscribed in a triangle with side lengths 3, 4, 5. A second circle interior to the triangle,
is tangent to the first circle and to both sides of the larger acute angle of triangle. The radius of the
second circle is

5) Let f be a function defined by , where r = 3k, k ∈ I then value of

is equal to

6) Let A = [aij] be a 3 × 3 matrix such that

, then the value of det(adjA) is


ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. C C B D D B

SECTION-I (ii)

Q. 7 8 9 10 11 12
A. A,C,D B,C,D A,C A,B,C A,B,C A,C,D

SECTION-II

Q. 13 14 15 16 17 18
A. 2.00 5.00 2.00 5.00 4.00 5.00

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. B A B B A A

SECTION-I (ii)

Q. 25 26 27 28 29 30
A. B,C A,B,C A,B,C,D A,B,D A,B,C A,B

SECTION-II

Q. 31 32 33 34 35 36
A. 10.00 3.00 2.50 19.00 2.00 2.00

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. D C D B D D

SECTION-I (ii)

Q. 43 44 45 46 47 48
A. A,C,D B,C A,B,C,D A,C A,B,C,D B,C
SECTION-II

Q. 49 50 51 52 53 54
A. 0.44 365.00 0.50 0.38 16.66 or 16.67 0.00
SOLUTIONS

PART-1 : PHYSICS

1) Let principal quantum number of initially excited energy level be n. Photon of maximum
energy is emitted during transitions n → 1.
hence, Emax = (En – E1) …(1)
Since, difference between energy of two consecutive levels decreases when n increases,
therefore, photon of minimum energy is emitted during transition n → (n – 1)
hence, Emin = En – E(n – 1) …(2)

But energy of nth level is given by,

∴ from equation (1), …(3)

and from equation (3), …(4)


solving equation (3) and (4), and E1 = –54.4 eV and n = 5
Hence, the gas is singly ionized Helium.
∴ (C)

2) Question Explanation:
In this question , we have to find the total electric flux through an imaginary triangular prism
that contains an infinitely long charged metal cylinder.
Concept:
Gauss’s Law:
Solution:

Calculating the Arc Length inside the prism:


The cross-section shows the cylinder surface is inside the prism for three segments.
Each segment corresponds to a 60° (or radians) angle at the center.
Total angle (or radians).
Calculating the Area enclosed:
The area of a cylinder's surface is .

Calculating the Charge Enclosed :

Calculating the Flux :


Using Gauss's Law:
Final answer:
Option (3)

3) As air rotates with the ball and also air comes from front relative velocity is less above and
more below hence pressure is high above and low below causing the net force to be
downwards.

4) First glass receives heat thus it expands and then mercury expands more than glass.

5) Energy loss =

6) Taking torque about pt of contact


⇒ torque on spool is clockwise, hence spool turns clockwise,
and goes right winding the string

7) When girls jump one by one total velocity of the system will be more. (because from
conservation of momentum, velocity of car in this case will be

instead of
when they jump simultaneously.
∴ (B, C, D)

8)

(B) W1 < W2
(C) W1 > W2
(D) W1 ≠ W2

9)

(A) It represents a conservative electric field.


(C) Electric potential at point (1m, 1m) is –4V if electric potential at origin is zero.
10) Req. =

Time constant
in steady state, current through cell

voltage across 2Ω resistor = 2V


∴ (A, B, C)

11) The friction acts backwards initially as point of contact has velocity in forward direction
and when the cylinder stops, the friction pulls it back.
∴ (A, B, C)

12)

∴ (A), (C) and (D)

13) Work done

then and

∴ W = W1 + W2 = – ka2
Hence n is –1, therefore n + 3 is 2.
Answer is 2.

14)
or
1.3 (80 – T3) = 2.6 (20) or T3 = 40°C
Answer is 5

15) T = (273 + 27) k = 300 k


ν = 1000 hz
λ = 0.2 m
M = 124.5 gm/mol
Wave velocity V = νλ = 200 m/s

γ=2

16) In first case

In second case

So,
So, λ' – λ = 5 cm.

17) Total increase in length of rods

Let the compression in spring A is xA, B is xB and C is xC

and

Energy stored

⇒β=4

18)
At t = 1 s

If radius of curvature is R then

v = 5 m/s

= 12 k

PART-2 : CHEMISTRY

19)

Sodium dihydrogen pyrophosphate does not exist.

20)

20kJ

21) When a chalk is dipped in ink, the surface retains the colour of ink due to adsorption of
coloured molecules while solvent of ink goes deeper into stick due to absorption.
→ Precipitate of Mg(OH)2 attains blue colour when precipitated in the presence of magneson
reagent.

22)

d = 0.8 g/L

rgas =

or, = ; M = Mgas

or, ⇒ M = 48g
d= ⇒ Vm =

Z= =

23)

Sol.

24)

O.P. ⇒ – × 100 ⇒ (–) 25.18%

Total d ⇒ 37.4
Total ⇒ 37.4 + 25.18 = 62.6

25) (A) Fe3+ → 5 unpaired electron Ni2+ → 2 unpaired electron


(B) [Fe(CN)6]3– is more stable
(C) Across a period basic character ↓ and down the group, basic character .
(D) I2 is more polarisable.

26)

(A) In Puddling process wrought iron is produced.


(B) In blast furnace phosphate and silicate are reduced into P and Si which pass into molten
iron.
(C) B, Ga, In, Ge and Si are refined by zone refining.

27)
k = k1 + k2 = 0.0693 + 0.1386 = 0.2079
θ0 = 2 × 60 = 120º

∴ At t = ∞ , [A] = 0

CA =

2= (∴ CB = CD)

or, ,

θ∞ =
= 40 – 120 = – 80º

or,
θt = 20
After 75% completion :
CA = 2(1 – 0.75) = 0.5

∵ CA = 2 –

or, 0.5 = 2 – – CB = 0

or, ⇒ CB = 1 ; ∴ C D = 1
θt = 0.5 × 60 + 60 + 1 × 30 + 1X (–90)
= – 30 ⇒ leavorotatory

(t1/2)overall = = 3.33 sec.

% of C formed in the products =

28) A → 0.3 M, 100 ml HCl + 50 ml water


[H+] =
pH = 1 – log2 = 1 – 0.3 = 0.7
B → 50 ml, 0.2 M HCl + 50ml 0.05 M NaOH
HCl = 10 mmole, NaOH = 2.5 mmole

H+ =
pH = 2 – log 7.5 = 2 – 0.88 = 1.12
C → 50 ml, 0.2 M HCl + 100ml 0.05 M NH4OH
HCl + NH4OH → NH4Cl + H2O
10 mmole 5 mmole
5 mmole 0 5 mmole

[H+] =

pH =
= 1.48
D → 50 ml, 0.2 M HCl + 100ml 0.1 M AgNO3
HCl + AgNO3 → AgCl + HNO3
10 mmole 10 mmole
0 0 10 mmole 10 mmole

10–10 = [Ag+]2 [∵ [Ag+] = [Cl–] ]


or, [Ag+] = 10–5 M
∴ moles of Ag+ = 150 × 10–5 × 10–3 mole
= 1.5 × 10–6 mole

29)

(A)

(B)

(C)

30)
(A) CH3–CH=O CH3–COOH

(B)

31)

Sol. 10.00

32)

33)

W = –1750 kJ
Wirr = –1000 kJ

ΔStotal =

= = =

= 2.5 kJK–1

34)

Equimolar, PT = 45 torr

xA & xB ,

,
Initially , xA = xB = 0.5 ,
PT =
or, 45 =
or,
or, = 90 – 20 = 70 torr.

or, 22.5 = (20 –70) xA + 70


or, 22.5 = – 50 xA + 70
or, 50 xA = 47.5

or, xA =
∴ xB = 0.05

∴Y=

35) X = 4, Y = 2
X ⇒ Valine (PI = 5.97), Arginine (PI = 10.76), Lysine (PI = 9.87), Alanine (PI = 6.02)
Y ⇒ Glutamic acid (PI = 3.22), Aspartic acid (PI = 2.98)

PI =
Amino acid having PI > pH moves towards cathode
Amino acid having PI < pH moves towards anode

36)

Reagent Compound-I Compound-II

I NaHCO3 ×

II Na Metal

III Neutral FeCl3 ×

IV AgNO3 + NH4OH × ×

V CS2, HgCl2

VI NaOI × ×

VII 2,4–DNP × ×

PART-3 : MATHEMATICS

37) differentiate both sides w.r.t. 'z'


2
sinf(z)(1 – z) = (2z + 1)sin(f(z)) + (z + z)cos(f(z))f '(z)
–3zsinf(z) = (z2 + z)cos(f(z))f '(z)
–3 = (z + 1)cot(f(z)).f '(z)

38)
39) Required circle is the circle described on O(0,0) & S(3,4) as diameter
(x – 0)(x – 3) + (y – 0)(y – 4) = 0
x2 + y2 – 3x – 4y = 0

40) |z|n = |z|n–2(z2 + z) + 1 ...(1)


from (1) z2 + z is real

Since Re(z) ≠
⇒ ⇒ z is purely real
from (1) zn–1 + 1 = 0
⇒ z = –1 is only solution

41) Degree of P(x) is 5 with leading coeff. one.


∴ degree of P'(x) is 4 with leading coeff. five.
Hence,
P'(x) = 5(x – 1)(x – 2)2(x – 3)
P'(4) = 5 × 3 × 4 × 1 = 60

42) R3 → R3 – (cosx) R1
f(x) = (cos2x – secx – cot2x) (cosx – cos3x)

f(x) = cos3x(sin2x – 1) – sin2x


f(x) = –cos5x – sin2x
43) (A) For P(z) we get

For Q(z) we get

(B)
ΔAOB is equilateral Δ

∠AOB = and ∠AOB =

(C) |z2 – 1|2 = (z2 – 1)( – 1)


= z2 – z2 – +1
4 2 2
|z| – 2(x – y ) + 1
= 17 – 2(x2 – y2) = 25 – 4x2
(∵ |z| = 2 ⇒ x2 + y2 = 4 where x ∈ [–2, 2])
9 ≤ |z2 – 1|2 ≤ 25
Hence 3 ≤ |z2 – 1| ≤ 5

44)
101 200C100 + 101 200C100 + 2100.2100
202 200C100 + 2200 = a 2nCn + 2b
a = 202; n = 100; b = 200

45) g(x) = x + 2
f(g(x)) = 2tan–1(x+2) f2(g(x)) – 5f(g(x)) + 4 > 0
f(g(x)) < 1 or f(g(x)) > 4
tan–1(x + 2) < or tan–1(x + 2) > 2

as


Hence integers in range are {–9, –8, ..., –2}

46) Question Explanation: Conditional probability of three specific children rolling a prime
number, given at least three children roll a prime number.

Concept: Conditional probability and binomial distribution.

Solution:

P(Prime number) =

∴ ; ;n=6
P(E) = P(r ≥ 3)

∴ a = 4 & b = 21

47) Let the point of intersection of tangents at A and B be P(h, k)


then equation of AB is

....(1)
Homogenising ellipse with (1) we get
...(2)
Combined equation of OA and OB is
x2 + 4y2 + αxy = 0 ...(3)
Compare (2) and (3)

⇒ (h2 – 4) = 4(k2 – 1)
⇒ h2 – 4k2 = 0 ⇒ x2 – 4y2 = 0

48)
So are coplanar vectors
As is equally inclined to .
⇒ is perpendicular to .

49) Explain Question:


Finding probability that given function is strictly increasing.

Concept:
Monotonicity of function, probability

Solution: f'(x) = 3x2 – 2ax + b ≥ 0 ∀ x ∈ R ⇒ (2a)2 – 4(3)(b) ≤ 0


a2 – 3b ≤ 0 This is possible for 16 ordered pairs (a, b)
(1,1), (1,2), (1,3), (1,4), (1,5), (1,6), (2,2), (2,3),

(2,4), (2,5), (2,6), (3,3), (3,4), (3,5), (3,6) & (4, 6) Hence probability
Final Answer: 0.44

50)
a1 = 13 – 2d; a2 = 13 – d; a3 = 13; a4 = 13 + d; a5 = 13 + 2d
an = (13 – 2d) + (n – 1)d = (13 – 3d) + nd

= a13–2d + a13–d + a13 + a13+d + a13+2d


S = 5(13+10d)
Now d ≤ 6 as terms are positive
∴ Smax occurs at d = 6 and is equal to 365.
51)

Equation of normal is
X + mY – (x + my) = 0 ...(1)
perpendicular distance from (0, 0) to equation (1) is

2
Put y = t ⇒

I.F. = e–ℓnx =

= –x + c ⇒ = –x + c
(1,1) lies on it so c = 2

C : x2 + y2 – 2x = 0

Area =

∴k= = 0.50
52)

Radius of first circle

...(1)

Also sinC = ⇒


r = 0.38

53)

for r = 0

for r = 3

for r = 6

f(x) is periodic with period = 3


= 16.66 or 16.67

54)

aij = –aji ∀ i & j


So A is a skew-symmetric matrix of order-3
so det A = 0
∴ det(adjA) (det(A))2 = 0

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