07-05-2026

1803CJA101029250209 JA

PART-1 : PHYSICS

SECTION-I (i)

1) Block is in equilibrium in the situation shown then (Here NL1 and NL2 are the natural length of

springs respectively)

(A) Value of x0 is 3cm.

(B) Time period of SHM is 0.314 sec.
(C) If kinetic energy of block is minimum when spring-1 is in its natural length then v0 = 0.6 m/s.
(D) If kinetic energy of block is minimum when spring-2 is in its natural length then v0 = 0.2 m/s.

2) Each of the following figures shows electric field vectors at two points A and B in an electric field.
In which figure of figures can the illustrated field be created by a single point charge?

(A)

(B)

(C)

(D)

3) Three infinitely-long conductors carrying currents I1, I2 and I3 lie perpendicular to the plane of the

0 0
paper as shown below. If the value of integral for the loops C1, C2 and C3 are 2µ , 4µ and
 0

µ in SI units respectively, then

(A) I1 = 5A out of the paper

(B) I2 = 3A into the paper
(C) I3 = 0
(D) I3 = 1A into the paper

4) In the circuit shown, two parallel plate capacitors of capacitance C and 2C consisting of thin
plates of identical dimension. They are connected with an ideal battery of terminal voltage V as
shown in figure I. Now the capacitor smaller in volume is completely inserted into the other
capacitor larger in volume and kept in symmetric position and then connection polarities of the
plates are reversed as shown in figure-II. Identity correct statements.

(A) Capacitance of the new system is 10C.

(B) Capacitance of the new system is 7C.
(C) Charge flown through the battery is 10CV.
(D) Charge flown through the battery is 7CV.

5) Choose the correct statements (s) :

(A) A neutrino is emitted in positron decay and an antineutrino is emitted in electron decay.
Electron capture, occurs when a parent nucleus capture one of its own orbital electrons and
(B)
emits a neutrino.
(C) In carbon dating we use 14C instead of 11C because 14C half-life is smaller then 11C.
Nucleus having higher binding energy must be more stable irrespective of mass number of
(D)
nucleus.

6) A cylinder which was initially completely filled with liquid having two holes as shown in figure is
on rough horizontal surface then choose correct statement(s) (Until level of liquid fall upto Ist hole)
(A) If A1 = 2A2 then initially friction does not act on cylinder.
(B) If A1 = A2 friction on cylinder remain unchanged all the time.
(C) If A1 = 2A2 then after some time friction on cylinder acts towards negative x-direction.
(D) If A1 = A2, magnitude of friction first decrease then increases.

7) If the tension in a stretched string fixed at both ends is changed by 21%, the fundamental
frequency is found to increase by 15 Hz then the

(A) Original fundamental frequency is 150 Hz.

(B) Velocity of propagation of the transverse wave along the string changes by 5%.
(C) Velocity of propagation of the transverse wave along the string changes by 10%.
(D) Fundamental wavelength on the string does not change.

8) What can be the possible values of angle of prism (A) so that whatever be the angle of incidence,
all the rays will emerge from other side i.e. there is no total internal refraction on second surface ?

Refractive index of prism is . (Consider cases in which formula of prism are applicable)

(A) 15°
(B) 45°
(C) 30°
(D) 60°

SECTION-I (ii)

1) Answer the following by appropriately matching the lists based on the information given
in the paragraph.

For a thermodynamic cycle ABCD on a non–linear polyatomic gas, we draw versus

diagram. Match the process.

 List-I List-II

Polytrophic PVm = constant. (m ≠ γ or 1 or

(I) AB (P)
0)

(II) BC (Q) Adiabatic

(III) CD (R) Isochoric

(IV) DA (S) Isobaric

(T) Isothermal

(U) P = a + bV
(A) I → P;II → U;III → R;IV → S
(B) I → P;II → P;III → T;IV → R
(C) I → P;II → Q;III → S;IV → R
(D) I → Q;II → P;III → S;IV → R

2) Answer the following by appropriately matching the lists based on the information given
in the paragraph.

For a thermodynamic cycle ABCD on a non–linear polyatomic gas, we draw versus

diagram. Match the process.

List-I List-II

(I) WA–B (P) Positive

(II) QB–C (Q) Negative

(III) ΔUCD (R) Zero

(IV) QD–A (S) Can't be said

Initially positive and negative after

(T)
that

Initially negative and positive after

(U)
that
(A) I → T;II → P;III → P;IV → P
(B) I → Q;II → R;III → P;IV → P
(C) I → Q;II → R;III → Q;IV → R
(D) I → S;II → Q;III → Q;IV → P
3) Answer the following by appropriately matching the lists based on the information given
in the paragraph.
For the system of charges and electric field at the given axis.

List-I List-II

(I) (P)

Uniformly positively charged ring in yz plane with axis

along x axis

(II) (Q)

Two identical positively charged article placed on y

axis symmetrical to x axis

(III) (R)

Uniformly positively charged on conducting disc in yz

plane with axis along x axis.

(IV) (S)
Uniformly positively charged (charge distribute
throughout its volume) non conducting sphere with
diameter axis along x-axis.

(T)

(U)

(A) I → U;II → U;III → P;IV → R

(B) I → T;II → T;III → P;IV → R
(C) I → T;II → T;III → S;IV → R
(D) I → Q;II → R;III → S;IV → T

4) Answer the following by appropriately matching the lists based on the information given
in the paragraph.
For system of charges and electric potential at given axis (Take : potential is zero at infinite)

List-I List-II

(I) (P)

Uniformly positively charged ring in yz plane with

axis along x axis

(II) (Q)
Two identical positively charged
article placed on y axis
symmetrical to x axis

(III) (R)
Uniformly positively charged conducting sphere
with diameter axis along x-axis.

(IV) (S)
Uniformly positively charged (charge distribute
throughout its volume) non conducting sphere with
diameter axis along x-axis.

(T)

(U)

(A) I → S;II → S;III → R;IV → T

(B) I → Q;II → S;III → P;IV → T
(C) I → S;II → R;III → R;IV → U
(D) I → P;II → P;III → R;IV → U
 SECTION-II

1) As shown in figure a disc is released from rest where coefficient of friction between disc &

inclined plane for path AB is & for BC is . If AB = BC then find the ratio of time interval .

2) If potential difference between C & B is 20V then find potential difference between A & B (in

volt).

3) A thin hollow cylinder (opened at both ends) of radius and length both equal to L. This object
carries a uniform surface-charge density σ. The electrostatic potential at the point P on the axis of

the cylinder (as shown in the figure) comes out to be . Find the value of k. [You

may use .]

4) In a Young's interference experiment, the two slits are separated by 0.150 mm and the incident
light includes two wavelengths: λ1 = 540 nm (green) and λ2 = 450 nm (blue). The overlapping
interference pattern are observed on a screen 1.40 m from the slits. Calculate the minimum distance
(in cm) from the center of screen to a point where a bright fringe of the green light coincides with a
bright fringe of the blue light.

5) Longest wavelength of lyman series for H atom is λ1 nm & shortest wavelength of Balmer series is
λ2 nm then the value of (λ2 – λ1) is : [Take R = 1.1 × 107 /m.]
6) Calculate the wavelength (in Å) of the x-ray emitting from a molybdenum target (z = 42), when an
electron moves from L shell to K shell. (Take R = 1.1 × 107 /m)

PART-2 : CHEMISTRY

SECTION-I (i)

1)

Which of the following reaction(s) can make alkyl benzene ?

(A)
+ Me3CCOCl

(B)
+ MeCOCl

(C)
+ MeCOCl

(D)
+ CH3CH = CH2

2)

Consider following reaction sequence :

A (Major product) P1 + P2
P1 undergoes aldol condensation while P2 can not. Which of the following statement(s) is/are
INCORRECT ?

(A) NaHSO3 can be used to distinguish P1 and P2.

(B) P2 reduces tollens reagent but can not reduce Fehling’s solution.
(C) P1 and P2 can undergo iodoform test.
(D) Compound P2 can give positive 2,4-DNP test but can not undergo Cannizzaro reaction.

3)

Select incorrect statement :

(A) Soaps are sodium or potassium salt of higher carboxylic acid like stearic acid
(B) Penicilline is a sweetening agent
(C) Monomer of Neoprene is isoprene
With one equivalent Na / liq. NH3 propyne give propene and reaction is known as Birch
(D)
reduction

4)

Incorrect statements is/are from the following -

(A) Adsorption is exothermic in nature

(B) CaCl2 causes coagulation of gold sol more easily than AlCl3
Surface tension of associated colloids increases with increase in concentration of their aqueous
(C)
sols.
With increase in concentration, conductance hydrosols of associated colloids increases more
(D)
rapidly after CMC than before it.

5) For first order reaction with single reactant :

(A) time taken for completion of 75% of reaction is twice that of half-life
(B) Rate constant of reaction increases linearly with temperature.
(C) The reaction may be either elementary or complex.
(D) Time taken for reaction to be 80% complete will not depend on initial concentration of reactant.

6) Which of the following coloured spin paired complex(es) shows isomerism?

(A) [Fe(en)3] Cl3

(B) [Sc(H2O)6] Cl3
(C) Cu2[Fe(CN)6]
(D) Na3[Cr(ox)3]

7) In which of the following reactions, xenon fluorides do not give redox reaction?

(A) XeF6 + SiO2 →

(B) XeF4 + H2O →
(C) XeF6 + H2O →
(D) XeF2 + H2O →

8) Calcination and roasting are carried out to :

(A) convert ores into their respective metal oxide

(B) remove water of crystallisation
(C) melt the ore
(D) remove impurities into their respective volatile oxides

SECTION-I (ii)
1)

List-II
List-I Conversion
Reagents

⊕
(I) (P) NaNO2 / HCl / Δ / H3O

(II) (Q) N3H / H2SO4 / Δ

(III) (R) KOH / Br2 / Δ

(IV) (S) NaOH / Δ

(T) HgCl2 / CS2 / Δ

(U) Hg(OAc)2 / NaBH4 / H2O

Which of the following having correct combination considering List-I and List-II
(A) II → T
(B) II → P
(C) III → Q
(D) IV → T

2)

List-I List-II
Conversion Reagents

⊕
(I) (P) NaNO2 / HCl / Δ / H3O

(II) (Q) N3H / H2SO4 / Δ

(III) (R) KOH / Br2 / Δ

 (IV) (S) NaOH / Δ

(T) HgCl2 / CS2 / Δ

(U) Hg(OAc)2 / NaBH4 / H2O

Which of the following having correct combination considering List-I and List-II
(A) II → T
(B) III → U
(C) IV → S
(D) I → R

3)

List-I (Type of process) List-II (Parameter change)

(I) Isothermal free expansion of ideal gas (P) ΔSsystem > 0

(II) 2SO2(g) + O2(g) → 2SO3 (g) + Heat (Q) ΔSsurr. = 0

(III) Condensation of water vapour at 1 atm (R) ΔSsystem < 0

(IV) Adiabatic reversible compression of ideal gas (S) ΔSsurr. > 0

(T) W > 0

(U) ΔH = 0 or ΔH < 0

Which of the following having correct combination considering List-I and List-II
(A) I → P;II → Q;III → U
(B) II → P;III → Q
(C) III → P;IV → T
(D) IV → Q;V → R

4)

List-I (Type of process) List-II (Parameter change)

(I) Isothermal free expansion of ideal gas (P) ΔSsystem > 0

(II) 2SO2(g) + O2(g) → 2SO3 (g) + Heat (Q) ΔSsurr. = 0

(III) Condensation of water vapour at 1 atm (R) ΔSsystem < 0

(IV) Adiabatic reversible compression of ideal gas (S) ΔSsurr. > 0

(T) W > 0

(U) ΔH = 0 or ΔH < 0

Which of the following having incorrect combination considering List-I and List-II
(A) I → P;II → Q;III → U
(B) II → R;III → S;IV → T
(C) III → R;IV → S;V → T
(D) IV → Q;V → U

SECTION-II

1)
pKa1 = 2 ; pKa2 = 4 ; pKa3 = 10
Find isoelectric point of the above amino acid.

2) For the galvanic cell,

Zn(s) + Cu2+ (0.02 M) → Zn2+ (0.04 M) + Cu(s),
Ecell =_______ × 10–2 V. (Nearest integer)

[Use : = –0.34 V, = +0.76 V, = 0.059 V]

3) A solution of 12.4 gm ethylene glycol in 100g H2O is cooled to –5.58°C. What is the weight (in
grams) of the ice separated from solution (Kf (H2O) = 1.86 K. kg mole–1) ?

4) A compound (X) on heating with an excess of NaOH solution gives gas (Y) which gives white
fumes on exposure of HCl. Heating is continued to expel the gas completely. The resultant alkaline
solution again liberates the same gas (Y) when heated with Zn powder. However, the compound (X)
when heated alone does not give diatomic gas. If the number of atoms in one molecule of compound
(X) is ‘a’ and the number of atoms in one molecule of gas (Y) is ‘b’ then find the value of a/b ?

5) Find the number of process in which hybridisation of underlined atom does not changed ?
(i) B2H6 + THF →
(ii)
(iii) K2[Ni(CN)4] + K
(iv) SiO2 + HF →
(v) PCl5 + CH3COOH →
(vi) KMnO4 + NaNO2 + H+
(vii) H3BO3 + NaOH →

6) Consider following complexes for stereo isomerism only :

[Co(NO2)3(NH3)3] , [Pt(en)Cl2] , [Co(en)2(NO2)Cl] ,
Na[PtBrCl(NO2)(NH3)] , Sodium nitro prusside,
[Ir(SCN)(SO4)(NH3)4] , Na3[Cr(ox)3]
Let number of complexes showing
(i) Only geometrical isomerism =a
(ii) Only optical isomerism = b
(iii) Neither geometrical nor optical isomerism = c
(iv) Showing both geometrical and optical isomerism =d
Then find the value of (a + b + d)/c

PART-3 : MATHEMATICS

SECTION-I (i)

1) In a triangle ABC points D, E lie on sides AC and AB respectively. M and N are mid points of side
BD and CE respectively. If Δ1 is area of triangle AMN, Δ2 be the area of triangle ADE, Δ be area of
triangle ABC, Δ3 be area of quadrilateral BCDE, Δ4 be area of quadrilateral MNDE. Which of the
following is/are always true ?

(A) 4Δ1 = Δ3
(B) 4Δ1 + Δ2 = Δ
(C) Δ1 = Δ4
(D) 4Δ4 = Δ2 + Δ

2) Tangents are drawn from to f : [0, ∞) → R ; y = sinx and (ai, sinai) are the points of
contact of these tangents for i = 1, 2, 3, ... and ai+1 > ai. Choose the correct options(s)

(A)

(B) an+1 – an < π

(C) an+2 – an > 2π
(D) sina2n – sina2n–1 < 0

3) P is a point on ellipse in first quadrant. F1(α, 0) and F2(β, 0) are two foci of the ellipse
(α < β). Line PF1 intersect circle x + y2 – 6y + 8 = 0 in Q. Choose the correct option(s)
2

(A) The maximum value of PQ + PF2, as P moves on the ellipse in first quadrant, is 8.
(B) The minimum value of PQ + PF2, as P moves on the ellipse in first quadrant, is 6.
(C) If the line PF1 is at maximum distance from (0, 3) then the value of PQ + PF2 is 12 –
(D) The maximum value of PQ + PF2, as P moves on the ellipse in first quadrant, is 12.

4) Let n ≥ 0 be an integer and , then

(A) I0, I1, I2, ..., is an A.P.

(B) I0, I1, I2, ..., is a G.P.
(C) In = nπ; n ≥ 1
(D) absolute value of the integrand is bounded

5) ABCD is a tetrahedron with ΔBCD being equilateral, having each side equal to 12 units. H is foot
of perpendicular from A to ΔBCD and it lies inside the triangle if area of ΔCDH is three times the
area of ΔBCH and area of ΔDBH is two times the area of ΔBCH, AH = 3 and M is midpoint of side
BD. Choose the correct option(s)

(A) Perpendicular distance of Point H from side BC is

Perpendicular distance of Point H from side BD is
(B)

(C) Perpendicular distance of Point A from line CM is

(D) Perpendicular distance of Point A from line CM is

6) Tangent are drawn from (–2, 0) to y2 = 8x, radius of circle(s) that would touch these tangents and
the corresponding chord of contact, can be equal to

(A)

(B)

(C)
(D) None of these

7) The equation of the plane which contains line and its projection in the plane
x + 2y + z = 6, is/are

(A) x + 2y + z – 6 = 0
(B) 9x – 2y – 5z + 4 = 0
(C) x – 2y – z + 6 = 0
(D) 9x + 2y – 5z + 4 = 0

8) If A and B are any two different square matrices of order n with A – B is non-singular A3 = B3 and
A(A(B)) = B(B(A)), then

(A) A2 + B2 = 0
(B) A2 + B2 = I
(C) A2 + B3 = I
(D) A3 + B3 = 0

SECTION-I (ii)

1) Match the List-I with List-II.

List-I List-II
 f : Df → R;
(I) (P) An even function
Where Df is domain of f(x), then f(x) is

f : R → (1, 3]; f(x) = [x + 1] + [x – 1] – 2x + 3,

(II) where [.] denotes greatest integer function, then (Q) An odd function
f(x) is

(III) (R) Injective function

f : R → (–1, 1); ; then f(x) is

Surjective
(IV) f : R → [0, ∞); ; then f(x) (S)
function
is

(T) Periodic function

(U) Bijective function

Which of the following is correct combination ?

(A) I → P;II → T
(B) II → Q;III → T
(C) III → Q;IV → R;V → S;VI → U
(D) III → Q;IV → R

2) Match the List-I with List-II.

List-I List-II

f : Df → R;
(I) (P) An even function
Where Df is domain of f(x), then f(x) is

f : R → (1, 3]; f(x) = [x + 1] + [x – 1] – 2x + 3,

(II) where [.] denotes greatest integer function, then (Q) An odd function
f(x) is

(III) (R) Injective function

f : R → (–1, 1); ; then f(x) is

Surjective
(IV) f : R → [0, ∞); ; then f(x) (S)
function
is

(T) Periodic function

(U) Bijective function

Which of the following is correct combination ?

(A) IV → P;V → S
(B) IV → P;V → R;VI → S
(C) II → R;III → S;IV → T;V → U
(D) II → Q;III → R;IV → S;V → U
3) Consider the system of equations.
a2x + (a2 – (b – c)2)y + bcz = 0
b2x + (b2 – (c – a)2)y + caz = 0
c2x + (c2 – (a – b)2)y + abz = 0

List-I List-II

If a + b + c = 0 and no two of a, b, c
(I) (P) System of equation have unique solution
are equal then

System of equation have infinite number of

(II) If a = b = c = 0 then (Q)
solutions

∀ x, y, z ∈ R, the system of equations will

(III) If a = b = c, a + b + c ≠ 0 then (R)
be true

If a + b + c ≠ 0 and no two out of a, b, Solution of system of equations are in the

(IV) (S)
c are equal, then form (λ1, λ2, –λ1 – λ2), where λ1, λ2 ∈ R

System of equation have atleast two

(T)
solutions

(U) System of equation have no solution

Which of the following is correct combination ?

(A) I → Q;II → R
(B) I → Q;II → R;III → T
(C) II → Q;III → R
(D) II → Q;III → R;IV → T

4) Consider the system of equations.

a2x + (a2 – (b – c)2)y + bcz = 0
b2x + (b2 – (c – a)2)y + caz = 0
2 2 2
c x + (c – (a – b) )y + abz = 0

List-I List-II

If a + b + c = 0 and no two of a, b, c
(I) (P) System of equation have unique solution
are equal then

System of equation have infinite number of

(II) If a = b = c = 0 then (Q)
solutions

∀ x, y, z ∈ R, the system of equations will

(III) If a = b = c, a + b + c ≠ 0 then (R)
be true

If a + b + c ≠ 0 and no two out of a, b, Solution of system of equations are in the

(IV) (S)
c are equal, then form (λ1, λ2, –λ1 – λ2), where λ1, λ2 ∈ R

System of equation have atleast two

(T)
solutions

(U) System of equation have no solution

Which of the following is correct combination ?

(A) III → Q
(B) III → Q;IV → S;V → T
(C) IV → Q;V → T
(D) IV → U

SECTION-II

1) Consider f : (0, ∞) → R, f(x) = xx be a differentiable function. Let f(x) = k has two distinct real roots
α and β such that max|α – β| < λ then the least integral value of λ is

2) If , where k1 and k2 are integers; then (k1 – k2)

equals

3) A question paper consists of 5 multiple choice questions with 4 options each. Out of these 3
questions have only one option correct and 1 mark will be awarded for correct answer while
remaining 2 questions have one or more than one option(s) correct and two marks will be awarded
for correct answer. The probability that student scored 4 marks in the paper; if he guesses all the

answers (no negative marks will awarded for wrong answers), is , then find k

4) If m is the minimum value of f(x), where , x > 0, then the value

of |m| is

5) Let and , then the value of p + q is

6) The quadratic equation x2 – (a + 5)x + 2a = 0, a ∈ I, has rational roots α and β. Then the

maximum value of
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6 7 8
A. A,B,C,D A,C A,B,D A,D A,B A,B A,C,D A,B,C

SECTION-I (ii)

Q. 9 10 11 12
A. C B B D

SECTION-II

Q. 13 14 15 16 17 18
A. 0.41 111.00 to 111.90 2.00 2.50 to 2.59 242.00 to 242.90 0.71 to 0.73

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24 25 26
A. A,B,D A,C,D B,C,D B,C,D A,C,D A,C A,C A,B

SECTION-I (ii)

Q. 27 28 29 30
A. C D A D

SECTION-II

Q. 31 32 33 34 35 36
A. 3.00 109.00 33.33 2.25 4.00 2.50

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42 43 44
A. A,B,C A,C,D A,B,C A,C,D A,B,C A,B B A

SECTION-I (ii)

Q. 45 46 47 48
A. C A D B
 SECTION-II

Q. 49 50 51 52 53 54
A. 1.00 2.00 1.94 11.50 1.00 0.65
 SOLUTIONS

PART-1 : PHYSICS

1)

keq = k1 + k2 = 400 N/m

& &
& Vmax = Aω

if
⇒ vmax = 0.2 m/s

if
⇒ vmax = 0.3 m/s

2)
(a) Larger the distance shorter the field vector.

(b) A negative charge at point of intersection.

3) µ0 (I1 + I2) = 2µ0

µ0 (I1 + I3) = 4µ0
µ0 (I1 + I2 + I3) = µ0
⇒ I1 = 5A & I3 = –1A
I2 = –3A

4)

(A) Capacitance of the new system is 10C.

(D) Charge flown through the battery is 7CV.
5)

(A) A neutrino is emitted in positron decay and an antineutrino is emitted in electron decay.
(B) Electron capture, occurs when a parent nucleus capture one of its own orbital electrons
and emits a neutrino.

6)

(A) If A1 = 2A2 then initially friction does not act on cylinder.

(B) If A1 = A2 friction on cylinder remain unchanged all the time.

7) (A)

= 1.1
f2 = 10% more than f1
Δf = (0.1) f1 = 15 Hz
f1 = 150 Hz

(C)

= 1.1
v2 = 10% more than v1
(D) λ = 2L remains unchanged.

8)
µ sinθC = 1
θC = 53°
A = r1 + r2 < 2θC
A < 106°

9)

10)
11)

12)

13)
For pure rolling
mgsinθ – f = ma .... (1)

.... (2)
Rα = a .... (3)
From (1), (2) & (3)

&

[For pure rolling]

⇒ disc will pure roll all the time

Now & tBC = tAC – tAB

14)

Now
3R2 + RZ + 3RZ = 3RZ + Z2
Z2 + RZ + 3RZ = 3RZ + Z2
Z2 – RZ – 3R2 = 0
Now

ΔV = 111.11

15)
 16) A bright line for the green light requires
dsinθ = dtanθ = m1λ1

Similarly, a blue interference maximum requires

for integers m1 and m2. Thus,

m1(540 nm) = m2(450 nm)

and smallest integers satisfying the equation are m1 = 5 and m2 = 6.

Then for both,

= 2700 nm
which gives

y = (2.700 nm) = 2.52 cm

17)
λ1 = 121.76 ⇒ λ2 – λ1 = 243.53

λ2 = 365.29

18)

⇒ λ = 0.72 Å

PART-2 : CHEMISTRY

20)

(A, C, D)
 P1 (CH3COCH3) + P2(PhCHO)
Both compounds P1 and P2 reacts with NaHSO3.
P2 reduces tollens reagent but can not reduce Fehling's solution.
Only P1 can undergo iodoform test.
Compound P2 can undergo positive 2,4-DNP test as well as Cannizzaro reaction.

23)

K increases exponentially with increase in temperature.

32)

Galvanic cell:

Nernst equation = Ecell =

= 1.0911 = 109.11 × 10–2

= 109

33)

Ice separated =

PART-3 : MATHEMATICS
37) ;

38)

Taking intersection of y = tanx

and

39) PQ + PF2 = 2a – QF1

(PQ + PF2)max = 12 – (QF1)min = 12 – (4) = 8
(PQ + PF2)min = 12 – (QF1)max = 12 – 6 = 6
For option C, PF1 is tangent to circle
So so PQ + PF2 = 12 –

40)
 ; ∀n≥1

Now I = 0 ;
Hence In = nπ ;
∵ I0, I1, I2, ... are in A.P.
Hence A, C, D is correct.

41)

Let ⊥ distance from H to BC, BD and CD be

p, 2p, 3p

× 12(p + 2p + 3p) = 122sin60°

∴ h0 = 2. So ⊥ distance of A from CM =

42) Point P clearly lies on the directrix of y2 = 8x. Thus, slopes of PA and PB are 1 and –1
respectively.
Equation of PA : y = x + 2,
Equation of PB : y = –x – 2,
Equation of AB : x – 2
Let the centre of the circle be (h, 0) and radius be
r.

⇒
⇒ h2 + 4 + 4h = 2(h2 + 4 – 4h)
⇒ h2 – 12h + 4 = 0

⇒ radius = |h – 2| = , .

43)

Equation of any plane through the line is a(x – 1) + b(y + 1) + c(z – 3) = 0

where 2a – b + 4c = 0 ...(i)
The plane x + 2y + z = 6 perpendicular to a(x – 1) + b(y + 1) + c(z – 3) = 0
∴ a + 2b + c = 0 ...(ii)
Solving (i) & (ii) we get
equation of the plane is 9x – 2y – 5z + 4 = 0
Hence the equation of projection is 9x – 2y – 5z + 4 = 0

44) A3 = B3 ...(i)
2 2
AB=BA ...(ii)
Subtracting (ii) by (i)
(A2 + B2)(A – B) = 0
∵ |A – B| ≠ 0, A2 + B2 = 0

45) Hint : (I) Find domain (II) f(x) = 3 – 2{x}

(III) f(–x) = –f(x) and

(IV) f(–x) = f(x) and ∀x≥0
Solution :

(I) f(x) = tanx – sinx ∀

If f(x) exists the f(–x) does not exist. So f(x) is neither even nor odd.
Also f(x) ≥ 0 ∀ x ∈ Df (not surjective)
and f(2π + x) = f(x) (periodic and many one)
(II) f(x) = 2[x] – 2x + 3 = 3 – 2{x}
Range of f(x) is (1, 3] (not surjective)
f(x) is periodic and not injective.
(III) f(–x) = –f(x) (odd function)

Range of f(x) is (–1, 1) (surjective)

and f'(x) > 0, f(x) is strictly increasing (one-one)

(IV)

⇒
(even function and many one)
Also ∀x≥0

⇒ ∀x≥0
Range of f(x) is [0, ∞) (surjective)

46) Hint : (I) Find domain

(II) f(x) = 3 – 2{x}

(III) f(–x) = –f(x) and

(IV) f(–x) = f(x) and ∀x≥0
Solution :

(I) f(x) = tanx – sinx ∀

If f(x) exists the f(–x) does not exist. So f(x) is neither even nor odd.
Also f(x) ≥ 0 ∀ x ∈ Df (not surjective)
and f(2π + x) = f(x) (periodic and many one)
(II) f(x) = 2[x] – 2x + 3 = 3 – 2{x}
Range of f(x) is (1, 3] (not surjective)
f(x) is periodic and not injective.
(III) f(–x) = –f(x) (odd function)

Range of f(x) is (–1, 1) (surjective)

and f'(x) > 0, f(x) is strictly increasing (one-one)

(IV)

⇒
(even function and many one)
Also ∀x≥0

⇒ ∀x≥0
Range of f(x) is [0, ∞) (surjective)

47) C2 → C2 – C1

C2 → C2 + 2C3

C1 → C1 + C2
 R1 → R1 – R2, R2 → R2 – R3
2 2 2
= –(a + b + c )(b – a)(c – b)(a – c)(a + b + c)
= (a – b)(b – c)(c – a)(a + b + c)(a2 + b2 + c2)
(I) If a + b + c = 0 ⇒ Δ = 0
Given system is homogeneous system, therefore infinite number of solutions will exist
(II) If a = b = c = 0, then all three equation will be 0.x + 0.y + 0.z = 0
therefore any (x, y, z) will satisfy the given set of equations where x, y, z ∈ R.
(III) a = b = c, a + b + c ≠ 0
then all three equations will come in form x + y + z = 0
solution of equation are (λ1, λ2, –λ1 – λ2)
(IV) Δ ≠ 0
⇒ only (0, 0, 0) is the solution.
⇒ unique solution.

48) C2 → C2 – C1

C2 → C2 + 2C3

C1 → C1 + C2

R1 → R1 – R2, R2 → R2 – R3
= –(a2 + b2 + c2)(b – a)(c – b)(a – c)(a + b + c)
= (a – b)(b – c)(c – a)(a + b + c)(a2 + b2 + c2)
(I) If a + b + c = 0 ⇒ Δ = 0
Given system is homogeneous system, therefore infinite number of solutions will exist
(II) If a = b = c = 0, then all three equation will be 0.x + 0.y + 0.z = 0
therefore any (x, y, z) will satisfy the given set of equations where x, y, z ∈ R.
(III) a = b = c, a + b + c ≠ 0
 then all three equations will come in form x + y + z = 0
solution of equation are (λ1, λ2, –λ1 – λ2)
(IV) Δ ≠ 0
⇒ only (0, 0, 0) is the solution.
⇒ unique solution.

49) Hint : α, β ∈ (0, 1)

Solution :
Let y = xx

So f(x) is decreasing in and increasing in

Also
So we can draw the graph y = f(x)

If f(x) = k has two distinct solutions α, β, then

Also α, β ∈ (0, 1)
Then |α – β| < 1

50) Let

51) Hint: Use binomial distribution

Solution: Probability that a question with only
one option correct is correct = .
Probability that a question with one or more

option correct is correct =

If a student is getting 4 marks then there will be two cases only.
(i) 2 single option correct and one more than one option correct
(ii) No single option correct and two more than one option correct

required probability =

So,

52)

(where ) which has minimum at u = 3

53)

q=1–p

54)
for α, β to be rational
Hence (a + 5)2 – 8a = perfect square of some integer
a2 + 2a + 25 = N2
24 = N2 – (a + 1)2
C-I : N2 = 49

a + 1 = ±5
C-II : N2 = 25

a + 1 = ±1
Hence for a = 4, (α, β) ≡ (1, 8)
a = –6, (α, β) ≡ (–4, 3)
a = 0 ; (α, β) ≡ (0, 5)
a = –2 ; (α, β) ≡ (–1, 4)
(α2 + β2)max = 65