10-05-2026

1001CJA101021250075 JA

PART-1 : MATHEMATICS

SECTION-I (i)

1)

Let a,b,c ∈ R such that a2 + b2 + c2 = 2bc, a2 + b2 + c2 ≠ 0. Then which of the following point lies on
the line ax + by + c = 0, is

(A) (–1,2)
(B) (1,2)
(C) (–1,–2)
(D) (2,–1)

2) If the domain of the function is non-empty, then the number of

integral values of 'a' in the interval (–7, 7) is :

(A) 6
(B) 10
(C) 12
(D) 13

3) is equal to

(A)

(B) 2

(C)

(D)

4) Four digit numbers are formed using the digits 1,2,3,4 (repetition is allowed). The number of such
four digit numbers which are divisible by 11 is

(A) 22
(B) 36
(C) 44
(D) 52
 SECTION-I (ii)

1) Two tangents are drawn from the point (2, 1) to a circle, one of which has equation x + y = 3. The
corresponding chord of contact has equation x – 2y + 6 = 0, then :

(A)
the centre of the circle is

(B)
the radius of the circle is
(C) a tangent from point (0, 0) to the circle has length
(D) the point (2, 0) lies inside the circle.

2) Let m be the coefficient of xn in (1 + x) + (1 + x2)2 + (1 + x3)3 + ... +(1 + x30)30, then which of the
following statement(s) is/are true ?

(A) If n = 24, then m = 161.

(B) If n = 9, then m = 9.
(C) If n = m, then n has 11 values.
(D) If n = m, then n has no values.

3) If the imaginary part of is zero (θ is a fixed constant), then z can lie on

(A) a circle with unit radius

(B) a circle with radius 3 units.
(C) a straight line through point (3,0)
(D) a parabola with vertex (3,0)

SECTION-I (iii)

1) Match the following List-I with List-II :

List-I List-II

The distance between the point A(–1, –5, –10) and point of
(P) (1)
intersection of with the plane x + 5y + z +
1 = 0 is

The distance of the point P(–2, 3, –4) from the line

(Q) (2) 2
measured parallel to the plane 4x +
12y – 3z + 1 = 0 is
 In let P and Q be points on AB and BC respectively, such

(R) that and . Let R be the point of intersection of (3)

AQ and CP, then area of is (given area of is 1
square unit)

(S) If has local maximum at x = k, (4) 13

then is

(5)

The correct option is:

(A) P → 4;Q → 5;R → 1;S → 3
(B) P → 4;Q → 3;R → 5;S → 1
(C) P → 4;Q → 1;R → 3;S → 5
(D) P → 4;Q → 5;R → 3;S → 1

2) Match each entry in List-I to the correct entries in List-II :

List-I List-II

(P) Let where for all , (1) 0

then the sum of all the possible values of det(A) is

(Q) (2) 1
Let , then the sum of the elements lying along
principal diagonal of A2024 is

Let f(x) be a polynomial whose coefficients are integer and satisifes

(R) f(1) = 1 and f(3) = 5, then the smallest positive value of f(0) that is (3) 2
possible is

The coefficient of x18 in the expansion of

(S) (1 + x)20 + x(1 + x)19 + x2(1 + x)18 + .... + x18(1 + x)2 is (4) 4
λ then sum of digits in λ, is

(5) 7
The correct option is :
(A) P → 1;Q → 2;R → 3;S → 5
(B) P → 1;Q → 3;R → 3;S → 5
(C) P → 3;Q → 2;R → 5;S → 3
(D) P → 4;Q → 2;R → 5;S → 3

3) Match the following List-I with List-II :

List-I List-II
 (P) (1)
Let and , then g''(1) is

(Q) (2)
Let , then is

Let g: R → R be differentiable function such that

(R) (3) 4
. If g(0) = 1, ,
then area bounded by y = g(x) and co-ordinate axes is

(S) Area bounded by curves and y = x + 1 is (in (4) 3

sq. unit)

(5)

The correct option is:

(A) P → 4;Q → 2;R → 1;S → 5
(B) P → 4;Q → 5;R → 1;S → 2
(C) P → 4;Q → 5;R → 2;S → 1
(D) P → 4;Q → 5;R → 2;S → 3

4) Match the following List-I with List-II :

List-I List-II

(P) Let , then the number of points in at (1) 18

which is

Let ,
(Q) (2) 20
if where and , then 2g(2) is

(R) Let , (3) 23

then f(9) will be equal to

(S) (4) 27
Let then
is (where [.] represents greatest integer function)

(5) 32
The correct option is:
(A) P → 2;Q → 4;R → 1;S → 3
(B) P → 3;Q → 4;R → 2;S → 1
(C) P → 1;Q → 3;R → 4;S → 5
(D) P → 2;Q → 4;R → 5;S → 3
 SECTION-II

1) If area of triangle whose vertices are (α2, α), (β2, β) and (γ2, γ) is 3, then the absolute value of

is ____.

2) If has two distinct solutions α and β in

then is equal to ____.

3) Value of is equal to

4) An insurance agent insured 50 scooters, 40 cars and 60 trucks in a month. Statistics show that
respective probabilities of accidents of these vehicles are 0.02, 0.06 and 0.15. One of his insured

vehicles applied for a claim. Probability that the vehicle was a scooter is where a and b are
coprime numbers then value of a + b is

5) If f : R → R, has range [–4,3) then m2 + n2 is

6) Parabola, P1 has focus at S(2, 2) and y-axis is it's directrix. Parabola, P2 is confocal with P1 and it's
directrix is x-axis. Let Q(x1, y1) and R(x2, y2) be real points of intersection of parabolas P1 and P2. If

the ratio find (a + b) (Given x2 > x1 and )

PART-2 : PHYSICS

SECTION-I (i)

1) A block lying on a long horizontal conveyor belt moving at a constant velocity receives a velocity 5
m/s at t = 0 sec. relative to the ground in the direction opposite to the direction of motion of the
conveyor. After t = 4 sec, the velocity of the block becomes equal to the velocity of the belt. The
coefficient of friction between the block and the belt is 0.2. Then the velocity of the conveyor belt is :
(g = 10 m/s2)

(A) 13 m/s
(B) –13 m/s
(C) 3 m/s
(D) 6 m/s

2) If pole of mirror is taken to be origin, is location of image and is velocity of image then,

(A)

(B)

(C)

(D)

3) The ratio of power consumed by both 3Ω resistors together when k is closed to power consumed

by both 6Ω resistors together when k is opened, is :

(A)

(B)

(C) 1

(D)

4)
Bottom arm of a U-tube of uniform section has length ℓ and the vertical arms have length 3ℓ each.
The tube is held with its parallel arms vertical and filled with a liquid of density ρ to occupy a total
length of 4ℓ of the tube and then it is made to accelerate horizontally in the plane of the tube with
an acceleration g that is modulus of acceleration of free fall. What will gauge pressure at the
midpoint of the bottom arm be immediately after acceleration of the tube is made abruptly zero?

(A) ρgℓ
(B) 2 ρgℓ
(C) 1.5 ρgℓ
(D) 1.375 ρgℓ

SECTION-I (ii)

1) A particle of specific charge 'α' is moving with velocity V0 at t = 0, on a rough horizontal floor and
the coefficient of friction is μ. A uniform magnetic field B, directed vertically downwards is also
switched on at t = 0. Find out the INCORRECT statements out of the following.

(A) The path of the particle is ellipse.

(B)
The magnitude of displacement of the particle before it stops is

(C)
Total distance covered by particle is
(D) None of these
2) A disc of mass 'm' and radius 'R' has a particle of mass 'm' attached to its surface at distance R/2
from centre. The disc is placed on rough surface with point P on its periphery as point of contact. If

there is no slipping and if the system is at rest at the instant shown,

(A)
acceleration of centre of mass of system is

(B)
acceleration of centre of disc is

(C)
friction acting on disc is

(D)
reaction force from ground makes an angle of with vertical.

3) If I is intensity and f is the frequency of radiation incident on a photo sensitive metal in the photo-
electric experiment set up :

(A) If f is increased keeping I constant, saturation current remains same.

If f is decreased (but higher than thershold frequency) keeping I constant, saturation current
(B)
increases.
If distance between cathode and anode is increased keeping f and I constant, kinetic energy of
(C)
electrons just after ejection increases.
If the metal is replaced with another metal of lower work-function, keeping f and I constant
(D)
saturation current remains same.

SECTION-I (iii)

1) The 5 kg block in the figure

is pulled with a constant velocity of Initially springs are in natural length and 3kg block is at rest.

(Take : π2 = 10 and K = 10 N/m)

List-I List-II

(P) Time after which velocity of 3 kg block becomes (in sec) (1) 40

(Q) Time after which 3 kg block comes to rest again (in sec) (2) 2/3

Displacement of 5 kg block when relative velocity between the

(R) (3) 60
blocks is zero (in m)
 External force required on 5 kg block when 3 kg block comes to
(S) (4) 2
rest again (in N)

(5) 10
(A) P → 2;Q → 4;R → 4;S → 1
(B) P → 5;Q → 4;R → 2;S → 3
(C) P → 2;Q → 4;R → 5;S → 3
(D) P → 5;Q → 2;R → 4;S → 1

2) The slit plane contains 3 identical slits. P, Q, R are points on screen directly infront of the slits A,
B, C. Intensity at any point on screen due to each slit is I0. (λ is wavelength of light used) Initial

phase at A, B and C is same.

List-I List-II

(P) (1) I0
Intensity at P, if .

(Q) (2) 2I0

Intensity at Q, if .

(R) (3) 5I0

Intensity at Q, if slit B is closed and .

(S) (4) 0
Intensity at mid-point of P and R, if .

(5) 9I0
(A) P → 1;Q → 3;R → 4;S → 5
(B) P → 3;Q → 1;R → 2;S → 5
(C) P → 1;Q → 4;R → 2;S → 3
(D) P → 3;Q → 2;R → 4;S → 5

3) For a uniform solid spherical charge of radius R and total charge Q. and potential
is zero at infinity]

List-I List-II
 (P) (1)
Potential at from centre

(Q) Potential at r = 3R from centre (2)

(R) (3) 0
Potential difference between points at and r = 2R

(S) Potential at centre (4)

(5)

(A) P → 4;Q → 5;R → 1;S → 3

(B) P → 2;Q → 2;R → 4;S → 3
(C) P → 3;Q → 2;R → 4;S → 5
(D) P → 4;Q → 2;R → 1;S → 5

4) In List-I, certain situations are depicted where steam at 100°C is used to melt ice at 0°C by means
of a conducting body which is insulated to prevent heat losses to surrounding. Match the numerical
value of question asked in each entry to the corresponding entry in List-II. Symbols have usual
meaning.

List-I List-II

(P) (1) 10

Find temperature of interface of two rods in °C.

(Q) (2) 20

Find total rate of heat transfer through the two rods in SI

units.

(R) (3) 30

hollow sphere of . Find thermal resistance in

SI units.
 (S) (4) 40

Hollow cylinder of . Find temperature gradients

in SI units.

(5) 50

(A) P → 2;Q → 3;R → 4;S → 1

(B) P → 3;Q → 4;R → 1;S → 5
(C) P → 2;Q → 3;R → 5;S → 4
(D) P → 3;Q → 4;R → 2;S → 1

SECTION-II

1) A vertical cylindrical container of radius 1 m, filled with liquid is rotated about its axis with
angular velocity rad/sec. A light ray travelling vertically downwards is incident on the liquid

surface at distance from the axis. The angle of refraction in the liquid is n × 10°. (refractive
index of liquid = ) Where n is ____. (g = 10 m/s2)

2) An ideal gas is heated such that TV3 = Constant. Ratio of internal energy change to magnitude of
work done if adiabatic exponent of gas is 3/2.

3) Switch 'S' is initially closed. When steady state is reached, S is opened. Heat lost in resistor after

'S' is opened is n × 50 µJ. n = ?

4) For a planet of mass density ρ = ρ0r (ρ0 = constant, r = distance from centre) and radius R, ratio
of acceleration due to gravity at surface to acceleration due to gravity at r = R/3 is ____.

5) When voltage of an X-ray tube is changed from 10 KV to 20 KV, the difference between Kα wave
length and cut-off wavelength becomes 3 times. Find atomic number of target element.

6) The moment of inertia of the plate in fig(a) about the axis shown is I. The moment of inertia of the
hexagonal plate of same material shown in figure(b) about the axis given in figure(b) is 10α I, find
value of α.

PART-3 : CHEMISTRY

SECTION-I (i)

1) A 1.2 L closed rigid vessel contains 1 mole of an ideal A intially gas. Gas A undergoes the
reaction: 2A(g) ⇌ A2(g) ; KP = 10–2bar–1 at 300 K. Calculate degree of dimerisation of A. (Given: R = 0.08
L-bar mol–1K–1)

(A) 0.468
(B) 0.117
(C) 0.766
(D) 0.234

2)
Identify CORRECT statements:

(A) All bond lengths in A are identical.

(B) B is sp3 hybridized at central atom
(C) C is a dibasic acid

(D)

3) The best leaving group among the following is :

(A) –OTf(Triflate)
(B) –OTs(Tosylate)
(C) –OBs(Brosylate)
(D) –ONs(Nosylate)
4)
Observe the given reaction of metal nitrates in test tube and select option which are present in test
tube -

(A) Pb(NO3)2, AgNO3

(B) Bi(NO3)3, Cd(NO3)2
(C) Al(NO3)3, Hg(NO3)2
(D) Pb(NO3)2, Bi(NO3)3

SECTION-I (ii)

1) How many of the following are correctly matched with its major product?

(A)

(B)

(C)

(D)

2) A reaction proceeds as with B in large excess. In an experiment, B

is replaced with B' (isotopologue) and it is found that rate changes, but equilibrium
constant for forming I remains effectively unchanged.
Which of the following statements are CORRECT ?

(A) RDS is I → P
(B) RDS is A + B → I
(C) Primary kinetic isotopic effect may appear in the step I → P but not in K.
(D) Rate = K K2[A][B] if K2 >> K–1.

3) 100 mL of 0.1 M aqueous solution of sodium phosphate is titrated using 0.1 M HCl. Now, choose
the CORRECT statement(s) of the following :
(For H3PO4 : and at 25°C)

(A) pH of the solution is 13 at 25°C, when the titre value is 50 mL.

(B) pH of the solution is 10.5 at 25°C, when the titre value is 100 mL.
(C) pH of the solution is 8 at 25°C, when the titre value is 150 mL.
(D) pH of the solution is 3 at 25°C, when the titre value is 200 mL.

SECTION-I (iii)

1) Match pKa value with suitable acid (pKa value of is 4.17)

List-I List-II
(Acid) (pKa)

(P) (1) 2.21

(Q) (2) 4.25

(R) (3) 3.82

(S) (4) 3.40

(5) 4.12
(A) P → 4;Q → 5;R → 1;S → 3
(B) P → 5;Q → 3;R → 1;S → 4
(C) P → 5;Q → 3;R → 4;S → 1
(D) P → 4;Q → 5;R → 3;S → 1

2)
 List-I List-II
(Complex) (Charcteristics)

Synergic bonding involving d→π* back

(P) [Ni(dmg)2] (1)
bonding

Intramolecular H-bonding stabilizes the

(Q) K[PtCl3(C2H4)] (2)
geometry
2+
(R) [Fe(H2O)5(NO)] (3) Optically active

– Charge transfer results in intense colour

(S) MnO4 (4) 0
despite d state

(5) Paramagnetic
Choose the CORRECT combinations.
(A) P → 2;Q → 1;R → 5;S → 4
(B) P → 3;Q → 2;R → 1;S → 5
(C) P → 4;Q → 3;R → 2;S → 1
(D) P → 5;Q → 4;R → 3;S → 2

3)

List-I List-II
(Test) (Identification/Result)

Chromyl chloride White precipitate turning grey with

(P) (1)
test excess SnCl2

Orange vapours that turn NaOH

(Q) Sodium nitroprusside (2)
solution yellow

Greenish yellow gas with bleaching

(R) Nessler's reagent (3)
action
+
(S) HgCl2 solution (4) Brown precipitate confirming NH4

(5) Purple colouration with sulphide ion

The CORRECT option is

(A) P → 3;Q → 2;R → 5;S → 4
(B) P → 2;Q → 5;R → 4;S → 1
(C) P → 1;Q → 3;R → 2;S → 5
(D) P → 4;Q → 1;R → 3;S → 2

4)

List-I List-II
(Reaction) (Observation)

(P) Phenol + CHCl3, NaOH(aq), 70°C (1) Formation of salt that is soluble in HCl

Aniline + NaNO2|HCl, 0 – 5°C, then β-

(Q) (2) E2, alkene formed on larger ring
Naphthol
 Reaction involves neutral divalent carbon
(R) Ethanamine + PhSO2Cl, then KOH (3)
intermediate (CCl2)

(S) 1-Bromo bicycloheptane, alc. KOH, Δ (4) Brilliant orange – red dye is formed

(5) No reaction
The CORRECT combination is
(A) P → 4;Q → 1;R → 5;S → 2
(B) P → 5;Q → 2;R → 3;S → 4
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 3;Q → 4;R → 1;S → 5

SECTION-II

1) A racemic secondary alcohol undergoes enzymatic acylation. After some time, 40% of the initial
racemate is converted to ester. This ester has enantiomeric excess 80%. Find enantimeric excess(%)
of the unreacted alcohol. (Nearest Integer)

2) Consider limiting molar conductivities ( ) of H+, Li+, Na+, Cs+ ions in aqueous solution and the
statements given below:
(i) of Li+ < of Cs+
(ii) Hydration radius of Li+ is smaller than that of Cs+.
(iii) H+ has highest due to smallest hydration radius.
(iv) H+ has highest ionic mobility.
(v) As temperature increases, increases.
Number of correct statements is ____.

3)
Sum of position of substituents in major product Y. (According to IUPAC)

4) In Nickel refining, Impure Ni is heated in stream of CO to form volatile compound A. In titanimum

refining, Impure Ti is heated with I2 in an evacuated vessel to form volatile compound B.
x = Number of d-orbitals of central atom participating in hybridisation in A.
y = Oxidation state of Ti in B.
z = Sum of the unpaired electron(s) in A & B

Find (x + y + z).

5) Find coagulation value of MgCl2 for gold sol if 100 mL of this gold sol requires minimum 2 mL of
0.5M MgCl2.
6)
(X) is a bicyclic organic product. Calculate the DOU (degree of unsaturation) of (X)
 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I (i)

Q. 1 2 3 4
A. D B B C

SECTION-I (ii)

Q. 5 6 7
A. A,B,C A,C A,C

SECTION-I (iii)

Q. 8 9 10 11
A. D B C A

SECTION-II

Q. 12 13 14 15 16 17
A. 72 4 7 67 16 5

PART-2 : PHYSICS

SECTION-I (i)

Q. 18 19 20 21
A. C B B D

SECTION-I (ii)

Q. 22 23 24
A. A,B B,C B,D

SECTION-I (iii)

Q. 25 26 27 28
A. A B D A

SECTION-II

Q. 29 30 31 32 33 34
A. 3 6 0 9 29 3

PART-3 : CHEMISTRY
 SECTION-I (i)

Q. 35 36 37 38
A. D B A D

SECTION-I (ii)

Q. 39 40 41
A. A,C,D A,C A,B,C

SECTION-I (iii)

Q. 42 43 44 45
A. C A B D

SECTION-II

Q. 46 47 48 49 50 51
A. 53 3 7 4 10 6
 SOLUTIONS

PART-1 : MATHEMATICS

1) a2 + (b – c)2 = 0
⇒ a = 0 and b = c ≠ 0 ∵ a2 + b2 + c2 ≠ 0
∴ Required line becomes by + c = 0
∴ y = –1
∴ (2,–1) lies on line

2) x > 0
1 – a + 6x – ax2 > 0 for atleast one x > 0
ax2 – 6x + a – 1 > 0 for atleast one x > 0
a < 0 or atleast one root is positive.
Case(i) : a > 0 and 2 distinct positive roots
D>0
36 – 4a(a – 1) > 0
a2 – a – 9 < 0

a(a – 1) > 0

Case(i) : a > 0 and one positive root

a–1<0
a ∈ (0, 1)
a can also be 0, 1

a = –6, –5, –4, –3, –2, –1, 0, 1, 2, 3

3) Given limit =

4) N = xyzw
x + z = y +w = k
k = 2 : 12
k = 3 : 22
k = 4 : 32
k = 5 : 42
k = 6 : 32
k = 7 : 22
k = 8 : 12
⇒ Total = 44

5)
Point A = (0, 3)
Line passing through (2, 1) and perpendicular to the chord is 2x + y – 5 = 0

B is the image of A on this line

Equation of circle touching x + y – 3 = 0

at (0, 3) is (x – 0)2 + (y – 3)2 + λ(x + y – 3) = 0

This circle passes through

Centre

Radius
Length of tangent
(2, 0) lies outside the circle.

6) (1 + xk)k
Tr+1 = [Link]
kr = 24
(k, r) = (24, 1) (12, 2) (8, 3) (6, 4)
24
C1 + 12C2 + 8C3 + 6C4
= 24 + 66 + 56 + 15 = 161
If kr = 9
(k, r) = (9, 1) (3, 3)
9
C1 + 3C3 = 10
If n = m, kr = n and kCr = n
k = n, r = 1 is the only possibility
n is a prime number
n = 2, 3, 5, 7, 11, 13, 17, 19, 23, 29

7)

Imz part = 0

circle straight line

8) (P) The point of intersection is (2, –1, 2)

(Q) Line drawn from P intersects the line measured parallel to the

plane 4x + 12y – 3z + 1 = 0 at .

(R) (use vector)

(S) or at local maxima exists

9) (P) For each matrix having |A| = k, there exists a matrix with |A| = –k.

(Q)
(R)

(S) Coefficient of x18 in (1 + x)20

⇒ (1 + x)21 – (1 + x)2 + x19
coefficient of x18 is 21C18

10) (P) Expand the square.

(Q)
(R) g(x) = ax + b

(S)

y=x+1

11) (P)

as

Now, number of solution of in is 20.

(Q) Let a and b roots of f(x) = 0

Now, , but and

Adding above two equation

Also,

(R)

(S)
12)

13)

14)

15) By Baye's Theorem

16)
now mx + n – 3 < 0 Think !
m=0 ∀x ∈ R
n–3<0
 ymin at x = 0 think !
y = 3 + n – 3 = –4
n = –4

17)

Substrating them (x – y) (x + y) = 0
Equation of line QR .
Now, x1 and x2 are roots of equation,

⇒x= ,

PART-2 : PHYSICS

18)

Correct Answer is (C)

19)
v = +10
20) When k is open

P3Ω × 2 = 6W
When k is closed

21)

Correct Answer is (D)

22)

.... (i)

and

.... (ii)
Radius of curvature is which is reducing with time. So, the path is spiral.

Form work energy theorem,

S is distance travelled before the particle stops.

For the velocity to become parallel to itself, θ = 2nπ

23)
2mg – N = 2may

24) Number of photons incident per second

25)
Consider a displacement 'x' in 3 kg block in time 't'.
Fnet = –kx – 2k (x – vt)

w.r.t frame moving with velocity

Initial situation

For a displacement 'x' of 3kg block in time 't', w.r.t the frame.

3 kg block executes SHM with time period.

(A) In the frame considered

at t = 0

at
(B) Attains same velocity after t = T, 2T
(C)
(D) Expansion in spring 2k when 3 kg block comes to rest = 2m, 4m
Froce = 40N, 80N

26) At P, path difference between A and B

path difference between A and C

Resultant amplitude
Resultant intensity = 5I0

At Q, path difference between A and B

path difference between B and C

At Q, path difference between A and C

Path difference between A and B at mid-point

Path difference between A and C at mid-point = 0

27)

28)

(P) (100 – T) = (T – 0)
100 – T = 4 T
T = 20

(Q) +
3000 × 100 × 10–4 = 30 W

R) RTh = = 40 SI units.

(S) = = 10°C/m
 29)

Surface of liquid in the shape of

Snell's law

30) TV3 = Constant

PV4 = Constant

31) No charge passes through circuit after opening switch.

32)

33)

34) Correct answer is 3.

PART-3 : CHEMISTRY

35) 2A ⇌ A2

1–α
KC =
∴ α = 0.234

36) A → PCl5
B → POCl3
C → H3PO4
D → HCl

37) More EWG

Better stability and better leaving ability.

38) The correct answer is Pb(NO3)2, Bi(NO3)3

39) The correct answer is option (A), (C), (D)

40) K2 is RDS and hence rate changes but Keq doesn't change.
Rate = K K2[A][B] if K–1 >> K2. (pre-equilibrium holds)

41) (i)
[Link]. 10 5 0
after neutralization 5 0 5
So, pH = (Buffer)

(ii)
[Link]. 10 10 0
after neutralization 0 0 10

So, pH = (Amphiprotic anion)

(iii)
[Link]. 10 15 0
after neutralization 0 5 10
So, pH = (Buffer)

(iv)
[Link]. 10 20 0
after neutralization 0 10 10

[Link]. 10 10 0
after neutralization 0 0 10
42) Acidic strength of S > R > Q > P > Benzoic acid

43) I → Chelation
II → C2H4 → Synergic bonding
III → 3 unpaired electrons with Fe in +1 state
IV → LMCT from O → Mn

44)

45) I → Riemer – Tiemann

II → β – Naphthol dye test
III → Hinsberg reagent
IV → No reaction as blidge head cannot form sp2 planar centre

46)
Unreacted alcohol:
R → 50 – 36 = 14
S → 50 – 4 = 46

47)
H+ has higest ionic mobility due to proton-jumping.
As T ↑, hydrogen bonding network weakens.
(i), (iv), (v) are correct statements.

48)
IUPAC name of Y ⇒ 1, 2-Dichloro-4-Nitrobenzene
Sum of position = 1 + 2 + 4 = 7
Ans. 7

49) x = 0 [Ni(CO)4] → sp3 hybridized

y = 4 TiI4
z=0

50) Coagulation value in mmol/L.

2 × 0.5 = 1 mmol required for 100 ml of gold sol.
10 mmol per L of gold sol.

51)
(X) is formed by intramolecular aldol condensation.