THE TEACHER’S ACADEMY
TEST (SOLUTION)
Time:1 Hrs Max Marks: 23
*Question 1 to 5 carry one marks (select correct option)
1. Which of the following correctly represents Henry's law?
(a) m= KHP (b) xA=KHPA
(c) PA = KHxA (d) All of these
2. 5 mL of acetone is mixed with 100 mL of H₂[Link] vapour pressure of water above the solution is
(a) equal to the vapour pressure of pure water
(b) equal to the vapour pressure of the solution
(c) less than the vapour pressure of pure water
(d) more than the vapour pressure of pure water
3. The boiling point of an azeotropic mixture of water and ethanol is less than that of water and
ethanol. The mixture shows
(a) negative deviations from Raoult's law
(b) positive deviations from Raoult's law
(c) no deviation from Raoult's law
(d) deviations which cannot be predicted from the given information.
4. Which of the following liquid pairs shows a positive deviation from Raoult's law?
(a) Water-hydrochloric acid (b) Water-nitric acid
(c) Acetone-chloroform (d) Benzene-methanol
5. 12g of urea isdissolved in 1 litre of water and 68.4 of sucrose is dissolved in 1 litre of water. The
lowering of vapour pressure of first case is
(a) equal to second (b) greater than second
(c) less than second (d) double that of second
6. The outer shell of an egg was dissolved in hydrochloric acid and then placed in concentrated NaCl
solution. Which one of the following will happen?
(a) The egg will swell (b) The egg will shrink
(c) Nothing will happen to the egg
(d) The inside of the egg will become saltish.
7. The value of osmotic pressure does not depend upon
(a) Concentration of the solution
(b) Temperature of the solution
(c) Number of the particles of the solute present
(d) Structure of the solute particles.
8. Which of the following colligative properties can provide molar mass of proteins (or polymers or
colloids) with greater precision?
(a) Relative lowering of vapour pressure (b) Elevation of boiling point
(c) Depression in frezzing point (d) Osmotic Pressure
9. The best and accurate method for determining osmotic pressure is
(a) Negative pressure method
(b) Berkeley and Hartley method
(c) Morse and Frazer method
(d) Pfeffer's method.
10. Which inorganic precipitate acts as a semipermeable membrane?
(a) Calcium phosphate (b) Nickel phosphate
(c) Calcium sulphate (d) Copper ferrocyanide.
11. Molal elevation constant and molal depression constant for water respectively (in °C/m) are
(a) 0.52, 1.86 (b) 1.86, 0.52
(c) 1.52, 0.86 (d) 0.86, 1.52.
12. Which of the following solutions will have the highest boiling point at 1 atm pressure?
(a) 0.1 M FeCl3 (b) 0.1 M BaCl₂
(c) 0.1 M NACI (d) 0.1 M urea (NH₂CONH₂).
13. Solutions A, B, C and D are respectively 0.1 M glucose, 0.05 M NaCl, 0.05 M BaCl₂ and 0-1 M AICI 3.
Which one of the following pairs is isotonic?
(a) A and B (b) B and C
(c) A and D (d) A and C.
14. The van't Hoff's factor (i) for a 0-2 molal aqueous solution of urea is
(a) 0.2 (b) 0.1
(c) 1.2 (d) 1.0.
15. Which of the following would exert maximum osmotic pressure?
(a) Decinormal aluminium sulphate
(b) Decinormal barium chloride
(c) Decinormal sodium chloride
(d) A solution obtained by mixing equal volumes of (b) and (c) and filtering.
16. Acetic acid dissolved in benzene shows molecular mass of
(a) 30 (b) 60
(c) 120 (d) 180
17. The normality of 10% (weight/volume) acetic acid is
(a) 1 N (b) 10 N
(c) 1.7 N (d) 0.83 N.
18. The normality of 10% H₂SO4 solution (d=1.1gcm³) is
(a) 2.04 (b) 1.02
(c) 1.85 (d) 2.25.
19. Normality of a 2 M sulphuric acid is
(a) 2 N (b) 4 N
(c) N/2 (d) N/4.
20. A/500 g toothpaste sample has 0.2 g fluoride concentration. What is the concentration of fluorine
in terms of ppm level?
(a) 250 (b) 200
(c) 400 (d) 1000
22. The millimoles of N₂ gas that will dissolve in 1 L of water at 298 K. when it is bubbled through
water and has a partial pressure of 0.96 bar will be (Given that at 298 K K H = 76.8 k bar)
(a) 0.59 (b) 0.69
(c) 0.79 (d) 0.89
23. The amount of oxalic acid (mol. wt. 63) required to prepare 500 mL of its 0-10 N solution is
(a) 0.315 g (b) 3.150 g
(c) 6.300 g (d) 63.00 g