Module 5
Module 5
MODULE 5
Bio Mass Energy- Biomass conversion technologies –Bio Gasification, Bio
ethanol, BioDiesel, Biogas production from waste biomass, factors affecting biogas
generation Bio Gas-KVIC and Janata model, Hydrogen Energy – various routes for
production of Hydrogen energy
Economic Analysis – Initial and annual cost, basic definitions, present worth
calculations, repayment of loan in equal annual instalments, annual savings,
cumulative saving and lifecycle cost, economic analysis of add on solar system,
payback period(derivation)
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Introduction
• Biomass is an organic renewable energy.
• It is mostly produced from agriculture and forest products and residues, energy
crops, and algae.
• Organic component of municipal and industrial wastes and the fuel produced from
food processing waste such as used cooking oil are also considered biomass.
• Before coal, oil and natural gas replaced it as primary fuels, wood was the primary
fuel for space heating in winter.
• Crops and forest products are usually converted to liquid and gaseous fuels through
some engineering processes.
• Growing of crops and trees as well as the conversion to liquid and gaseous fuels
involves the consumption of energy in the form of electricity and fossil fuels such as
coal, oil, and natural gas.
• The consumption of fossil fuels is accompanied by the pollutant and greenhouse
emissions.
• Renewability and emission characteristics of biomass are not as good as other
renewables such as solar, geothermal, or wind.
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Biomass Resources
Biomass can be obtained from variety of resources called feedstock. Biomass resources can be listed as
follows (DOE/EERE, 2018):
• Dedicated Energy Crops These herbaceous energy crops are perennials that are harvested after reaching
maturity. These include such grasses as switchgrass, miscanthus, bamboo, sweet sorghum, tall fescue,
kochia, wheatgrass, and others.
• Agricultural Crops These include cornstarch and corn oil, soybean oil and meal, wheat starch, and
vegetable oils. They generally yield sugars, oils, and extractives.
• Agriculture Crop Residues Biomass materials consisting primarily of stalks and leaves not used for
commercial use such as corn stover (stalks, leaves, husks, and cobs), wheat straw, and rice straw are
included in this resource. Approximately, 80 million acres of corn is planted annually.
• Forestry Residues These are biomass not harvested or used in commercial forest processes including
materials from dead and dying trees.
• Aquatic Crops Aquatic biomass resources include algae, giant kelp, other seaweed, and marine microflora.
• Biomass Processing Residues By-products and waste streams produced by biomass processing are
called residues, and they represent an additional biomass resource.
• Municipal Waste Plant-based organic material generated from industrial, residential, and commercial
waste represents an important biomass source. Some examples include waste paper, wood waste, yard
waste, and cooking oil.
• Animal Waste Animal wastes consist of organic materials and are generated from farms and animal-
processing operations. Animal waste is used as a heating fuel in some parts of the world.
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Biomass based fuels
Biomass
• Ethanol
• Wood • Methane
• Methanol
• Agricultural residue • Syngas
• Organic oil
• Solid biomass are highly dispersed and bulky and contain large quantity of water (50-90%)
• Low calorific value
• Not economical to transport
• Conversion to useable energy should be done at the source
• Conversion to liquid and gaseous form improves transportability and energy density 4
Biomass based fuels
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Conversion of biomass to fuel
Biomass can be converted into liquid or gaseous fuels through biochemical- and thermochemical-
based conversion processes.
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Conversion of biomass to fuel
• Thermochemical conversion processes, heat energy and chemical catalysts are used to
break down biomass into intermediate compounds or products.
• In gasification, biomass is heated in an oxygen-starved environment to produce a gas
composed primarily of hydrogen (H2) and carbon monoxide (CO).
• In pyrolysis, biomass is exposed to high temperatures without the presence of air, causing it to
decompose. Solvents, acids, and bases can be used to fractionate biomass into an array of
products including sugars, cellulosic fibres, and lignin
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Biochemical conversion process
• The biomass material in the form of water slurry is digested by the bacteria anaerobically for
several days in an airtight container.
• The reactions are slightly exothermic and small amount of heat (equivalent to 1.5 MJ per kg dry
digestible material) is also generated that helps in maintaining favorable temperature.
• The process may be expedited at somewhat higher temperature.
• The most useful biomass materials appear to be animal manure, algae, kelp, hyacinth, plant
residues and other organic waste materials with high moisture content.
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Biomass Gasification
• The word gasification (or thermal gasification) implies converting solid fuel into a gaseous fuel
by thermo-chemical method without leaving any solid carbonaceous residue.
• Gasifier is the equipment that converts biomass into producer gas.
• Most common raw materials are: wood chips and other wastes from wood industry, coconut
shells, straw etc.
• Biomass that has high ash content such as rice husk etc. can also be handled though with some
difficulty.
• Gasification involves partial combustion (oxidation in restricted quantity of air/oxidant) and
reduction operations of biomass.
• In a typical combustion process generally oxygen is surplus, while in gasification process fuel is
surplus.
• The combustion products, mainly carbon dioxide, water vapour, nitrogen, carbon monoxide and
hydrogen pass through the glowing layer of charcoal for the reduction process to occur.
• During this stage both carbon dioxide and water vapour, oxidize the char to form CO, H2 and CH4.
• Following are the typical reactions, which occur during gasifcation:
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Biomass Gasification
• The moisture available in the biomass is converted to steam and generally no extra moisture is
required.
• Thus the product of combustion of pyrolysis gases results in CO2 and H2O (steam), which further
react with char:
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Ethanol
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Hydrolysis – biomass to ethanol
• Hydrolysis is a critical step in converting biomass into ethanol, particularly when dealing with
lignocellulosic (plant-based) materials like wood, agricultural residues, or grasses. The
hydrolysis process breaks down complex carbohydrates in biomass into simpler sugars that can
then be fermented into ethanol.
• Here’s an outline of the process:
• Pretreatment: Biomass typically has a complex structure with cellulose, hemicellulose, and
lignin tightly bound together. Pretreatment (using heat, chemicals, or steam) is essential to
open up this structure, making cellulose and hemicellulose accessible to enzymes.
• Enzymatic Hydrolysis: Enzymes, particularly cellulases and hemicellulases, are added to
the pretreated biomass. They break down cellulose and hemicellulose into simple sugars,
mainly glucose and xylose.
• Fermentation: The resulting simple sugars are then fermented by microorganisms (like
yeast or bacteria) to produce ethanol.
• Distillation and Purification: Ethanol is separated from the fermentation solution,
purified, and concentrated to reach the desired ethanol purity for fuel or other applications.
• Hydrolysis is a key step because the efficiency of sugar release directly impacts the yield of
ethanol, and effective hydrolysis is necessary to make the process economically viable for large-
scale production.
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Biomass to Ethanol Production
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Biomass to Ethanol Production
The hexose (glucose and/or fructose) required for ethanol fermentation is derived from: (a) sucrose
(b) starch or (c) cellulose.
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Biomass to Ethanol Production
(c) Preparation from cellulose
Cellulose is not hydrolyzed so easily as starch, but on heating with dilute sulphuric acid under
pressure yield glucose (i.e. at 393K and pressure (2–3 atm).
• Sucrose materials are readily available in fermentable form, require least expensive preparation,
but are generally most expensive to obtain.
• Starch bearing materials are often cheaper, but require processing to solubilize and convert starch
to sugars.
• Cellulosic materials are the most readily available raw materials, as cellulose is the most
abundantly available organic compound in the world, but they require the most extensive and
costly preparation
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Biodiesel
• Biodiesel is ethyl or methyl ester that is produced through a process that combines organically
derived oils with ethanol or methanol in the presence of a catalyst.
• Common sources of biodiesel include new and used vegetable oils, animal fats, and recycled
restaurant greases.
• The Higher Heating Value (HHV) of biodiesel is about 40,700 kJ/kg (17,500 Btu/lbm), which is
about 12 percent less than that of petroleum diesel (HHV = 46,100 kJ/kg).
• Biodiesel can be used in compression ignition engines as a single fuel or can be added to
conventional diesel fuel.
• The most common biodiesel mixture used in the United States is B20, which is 20 percent
biodiesel and 80 percent conventional diesel.
• Biodiesel is also used as a single fuel in compression ignition engines, called B100.
• Whereas B20 can be used in a diesel engine without any modification, B100 usually requires the
use of special material for parts such as hoses and gaskets.
• Due to Lower Heating Values, B100 provides less power from the engine.
• Some maintenance issues can also arise and some manufacturers may not cover biodiesel use in
their warranties.
• B100 could increase nitrogen oxides emissions while significantly reducing hydrocarbon, sulfur,
and carbon monoxide emissions. 18
Biodiesel Production
• Biodiesel production involves converting oils or fats (usually from plants or animals) into a
usable fuel that can replace or blend with traditional diesel.
• The process primarily relies on transesterification, where triglycerides (fats or oils) are
chemically reacted with an alcohol (usually methanol or ethanol) in the presence of a catalyst
(often sodium or potassium hydroxide) to produce biodiesel and glycerol as a byproduct.
• Here's a brief outline of the process:
• Feedstock Preparation: Vegetable oils (e.g., soybean, canola) or animal fats are collected
and pretreated to remove impurities and free fatty acids that could affect the reaction.
• Transesterification: The oil or fat reacts with alcohol in the presence of a catalyst. This
breaks down triglycerides into fatty acid methyl esters (FAME) or biodiesel and glycerol.
• Separation: After the reaction, the biodiesel and glycerol separate due to their different
densities. Glycerol settles at the bottom and can be removed for other uses.
• Purification: The biodiesel is washed and purified to remove any residual catalyst, alcohol,
or impurities.
• Quality Testing: The final biodiesel is tested to ensure it meets fuel quality standards before
being blended with or used as a replacement for traditional diesel.
• Biodiesel is renewable, biodegradable, and burns cleaner than conventional diesel, which helps
reduce greenhouse gas emissions.
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Biogas production from waste biomass
• Biogas is produced from wet biomass with about 90–95 per cent water content by the action of
anaerobic bacteria (bacteria that live and grow in absence of oxygen).
• Part of carbon is oxidized and another part reduced to produce CO2 and CH4.
• These bacteria live and grow without oxygen.
• They derive the needed oxygen by decomposing the biomass.
• The process is favored by wet, warm and dark conditions.
• The airtight equipment used for conversion is known as biogas plant or digester, which is
constructed and controlled to favor methane production.
• The conversion process is known as anaerobic fermentation (or biodigestion).
• Nutrients such as soluble nitrogen compounds remain available in solution and provide excellent
fertilizer and humus.
• The energy available from the combustion of biogas is 60–90% of the input dry matter heat of
combustion. Thus the energy conversion efficiency of the process is 60–90 per cent.
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Stages in Biogas production
Stage I: First of all the original organic matter containing complex compounds e.g.
carbohydrate, protein, fats etc. is broken through the influence of water (known as
hydrolysis) to simple water soluble compounds. The polymers (large molecules)
are reduced to monomers (basic molecules). The process takes about a day at 25
°C in an active digester.
Stage II: The micro-organisms of anaerobic and facultative (that can live and grow
with or without oxygen) groups, together known as acid formers produce mainly
acetic and propionic acids. This stage also takes about one day at 25 °C. Much of
CO2 is released in this stage.
Stage III: Anaerobic bacteria, also known as methane formers slowly digest the
products available from second stage to produce methane, carbon dioxide, small
amount of hydrogen and trace amount of other gases. The process takes about
two weeks’ time to complete at 25 °C. This third stage, i.e. methane formation
stage is carried out strictly by the action of anaerobic bacteria.
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Floating Drum (Constant Pressure) Type Biogas Plants
• Numerous models of floating drum type biogas plants
are developed in various countries. Most
representative of this type is the KVIC model (Khadi
Village Industries Commission), developed in India,
shown in Fig.
• It has an inverted mild steel drum to work as
gasholder. This is the most expensive component of
the plant.
• The drum floats either direct on fermentation slurry
or in a water jacket of its own.
• Most Indian plants now have a pair of central guide
pipes.
• The gasholder is free to rise or fall depending on the
production and use of gas.
• It is also free to rotate on its axis which will also be
useful as a device to break the scum in the digester.
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Floating Drum (Constant Pressure) Type Biogas Plants
• A flexible hosepipe is attached at the top of the gasholder for gas dispersion.
• The gas passes through a moisture trap before supplying to the utility/house.
• The digester is a deep circular pit or a well, built of bricks, mortar and plaster,
with a partition wall.
• The bifurcation of digestion chamber through partitioning wall provides
optimum conditions for growth of acid formers and methane formers as the
requirement of pH values for these bacteria are different.
• Therefore, this plant operates very well with good biogas yield.
• The underground structure helps minimize the heat loss from the plant and the
cylindrical shape has better structural strength.
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Fixed Dome (Constant Volume) Type Biogas Plants
Janata Model
• Many variations of this basic design are developed to reduce the cost by making use of
different materials to suit local conditions.
• The slurry enters from inlet and the digested slurry is collected in a displacement
tank.
• Stirring is required if raw material is crop residue.
• There is no bifurcation in the digester chamber and therefore the gas production is
somewhat less as compared to floating point design.
• The gas produced is stored in the dome and displaces the liquids in inlet and outlet,
often leading to gas pressure as high as 100 cm of water.
• The gas occupies about 10 per cent of the volume of the digester.
• As complete plant is constructed underground, the temperature tends to remain
constant and is often considerably higher than ambient temperature in winter.
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Comparison of Floating Drum and Fixed Dome Type Plants
S No. Feature Floating drum Fixed dome
1. Cost More (due to steel drum) Less
11. Masonry workmanship Average skill Specialized, skilled masonry work required
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Hydrogen Energy Production
2. Electrolysis of Water
• Electrolysis is the simplest method of hydrogen production.
• Not as efficient or cost effective as thermo-chemical method using fossil fuels or
biomass.
• But it would allow for more distributed hydrogen generation and open the
possibilities for use of electricity generated from renewable and nuclear resources
for hydrogen production
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Hydrogen Energy Production
3. Thermolysis of Water
• Thermolysis is splitting water directly from heat energy
• More efficient than conversion of heat, first to electricity (using heat engine –
generator) and then producing hydrogen through electrolysis.
• Direct thermal decomposition of water is possible but it requires a temperature of at
least 2500 °C
• Sequential chemical reactions at substantially lower temperature can be devised to
split water into H2 and O2
• In the reaction series, water is taken up at one stage and H2 and O2 are produced in
different stages.
• The energy is supplied as heat at one or more stages and partly released at some stage
in the cycle.
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Hydrogen Energy Production
• Several thermo-chemical cycles have been proposed and are under investigation.
One such cycle is given below:
4. Biophotolysis
• In this method the ability of the plants (especially algae) to split water during
photosynthesis process is utilized.
• An artificial system is devised, which could produce hydrogen and oxygen from water
in sunlight using isolated photosynthetic membrane and other catalysts.
• Since this process is essentially a decomposition of water using photons in the presence
of biological catalysts, the reaction is called photolysis of water.
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Hydrogen Energy Production
• There are three distinct functional components coupled together in the system as
shown in Fig. 12.11:
• (i) photosynthetic membrane, which absorbs light, split water to generate oxygen,
electrons and protons,
• (ii) an electron mediator, which is reducible by photo-synthetically generated electrons
and
• (iii) a proton activator that will accept electrons from the reduced mediator and
catalyze the reaction: 2 H + 2 e → H2.
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Economic analysis
Importance of Economic analysis in Renewable energy
Economic analysis not only enhances the financial understanding of renewable projects but also aids in planning
sustainable, cost-effective energy solutions aligned with environmental and societal goals.
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Basic Terms and Definitions
• Cash Flow Diagram
• Any organization usually has frequent receipts and
disbursements taking place over a particular interval of
time. These transactions can be shown on a cash flow
diagram.
• A cash flow diagram is simply a graphical representation of
cash flows drawn on time scale, as shown in Fig.
• The horizontal line represents the progression of time from
left to right.
• The time scale is divided into equal intervals, known as
interest periods.
• The numbers 1, 2, 3, · · ·, n, on time scale represent the end
of corresponding periods.
• Time “0” represent the starting date or present time.
• A vertical arrow pointing upwards indicates positive cash flow (cash receipt, income) and the arrow
pointing downwards indicate negative cash flow (disbursement, cost).
• At any point in time the net cash flow would be represented as: Net cash flow = receipts –
disbursements
• All cash flows occur at the end of interest period.
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• This practice in engineering economics is known as end of period convention
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Basic Terms and Definitions
Principal Amount, P
• This is the amount of money that is being considered initially.
• It might be an amount to be invested or loaned or it may refer to initial value or cost of a plant or
machinery
Interest, I
• Interest is the payment (other than the sum borrowed) made for the money borrowed from the
bank or financer.
• Interest is the consideration which the money lender receives for the use of money lent.
Alternatively, interest may be regarded as the return obtained by the productive investment of
capital.
Interest Rate
• Interest rate is essentially a measure of productivity of money as a resource.
• Alternatively, interest rate is a measure of investor’s preference for the time value of money.
• Interest rates are also quoted for a period other than one year. However, unless otherwise stated,
it is customarily understood to be specified on annual (per annum) basis
Cost of Capital
• It is usually defined as the minimum rate of return that an investor (or company) expects to earn
on its investment
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Basic Terms and Definitions
Number of Time Periods, n
• The number of time intervals over which the amount of money is being invested or borrowed.
Although “n” is usually the number of years, it may represent other time periods such as number
of quarters or months.
• Cumulative Saving: Cumulative saving refers to the total amount of savings accumulated over a
specific period. It sums up all the savings generated year over year until a particular point. For
example, in energy or cost-saving projects, cumulative saving represents the overall reduction in
costs or energy consumption from the start of the project until a given end date.
• Life Cycle Saving: Life cycle saving is the total savings realized over the entire lifespan of a
project, product, or investment. It accounts for all savings achieved from the beginning to the end
of its useful life. For instance, in renewable energy projects, life cycle savings would include all
cost or energy savings from the installation until the system is no longer functional or is replaced.
• Annual Saving: Annual saving is the amount of savings achieved in a single year. It measures the
reduction in costs or energy consumption within a given 12-month period, often used to assess
the yearly performance of a savings initiative or investment. Annual savings can be used as a
benchmark to estimate cumulative and life cycle savings over multiple years.
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Kinds of Interest
Simple Interest
Simple interest is directly proportional to the capital involved, the number of
interest periods and the interest rate.
Compound Interest
When the simple interest is added to the principal amount so that the amount
becomes the principal amount for the next term (period), the interest so
obtained is called compound interest.
An amount, P invested at an annual interest rate of i compounded annually, after
n years becomes: F = P (1 + i) n
P is known as present value of the investment; i is the annual interest rate, n is number of interest
periods, and F is the future value of the investment
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Kinds of Interest
When the period of interest is less than one year, compound interest rates may be quoted in two
ways:
(a)Nominal Interest Rate
Nominal interest rate is the annual interest rate obtained simply by converting the interest rate
specified for one period (where the period is less than one year) to a year disregarding the effect of
compounding after each period. For example, an interest rate of 2% compounded each month for a
year is typically quoted as 24% (2 × 12) nominal interest rate or annual interest rate.
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Kinds of Interest
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Effect of Inflation on Cash Flows
• In general, there is inflationary trend in the cost of goods and services. At times,
reverse trend is also noticed.
• Monitory inflation occurs when the purchasing power of a currency (say rupee)
declines or, in other words, there is general increase in the level of prices in an
economy.
• On the contrary, deflation reflects an upward change in the purchase power of the
currency.
• Inflation may cause the borrowing cost to rise because the lender would demand a
higher rate of interest to counter the effect of inflation.
• Therefore, it is important to take anticipated inflation into account when estimating
the expected cash flows of an investment.
• The average rate of inflation is usually expressed as an annual percentage rate that
represents the annual increase in the sample prices of some stipulated “market
basket” of commodities (usually both goods and services) over one year period.
• The inflation rate has a compounding effect because its value for each year is based on
the previous year’s price.
• If Co is the present (initial) cost of a commodity and j1, j2, . . . jn is the rate of inflation
in year 1, 2, ..., n, then its cost at the end of corresponding years will be: 46
Effect of Inflation on Cash Flows
If Co is the present (initial) cost of a commodity and j1, j2, . . . jn is the rate of inflation in year 1, 2,
..., n, then its cost at the end of corresponding years will be:
If j is the average rate of inflation during year 0 to year n, the cost Co changes to Cn as:
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Payback Period
Payback Period
Payback period is defined as the number of years required to recover the original cash investment.
In other words, it is the period of time at the end of which a machine, facility, or other investment
has produced sufficient net revenue to recover its investment costs.
Business firms are concerned with the number of years required to recover the initial outlay of an
investment. The payback period is found in two ways: conventionally and by discounting the cash
flow.
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Payback Period
Q. A proposed solar PV street light will cost Rs 10,000 and last for 20 years. The savings of
electricity bill is estimated as Rs 900 per year. What is the simple payback period of the proposal?
Soln. Initial investment, Co = 10,000
Net annual savings = B = 900 per year
Now, Simple payback period, nsp =10,000/ 900
=11.11 years
This period is much less than the expected useful life of the street light. Hence, the proposal may be accepted.
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Payback Period
Q. The cash flows of three project proposals during their lifetime of 5 years are given in Table.
Calculate the simple payback period for each of them.
Soln. The cumulative cash flows for the above problem are given Table
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Payback Period
• Simple payback periods as seen from Table,
• For project A = 4 years
• For project B = 3 years
• For project C the cumulative cash flow becomes zero somewhere during year 4.
• If it is assumed that the cash flow of Rs. 1100 is uniformly distributed over the 4th year
• The exact value of simple payback period can be determined as:
• Simple payback period for project C = 3 + 300/1100
≈ 3.27 years
Discounted Payback Period, ndp
• Simple payback period fails to consider the time value of money.
• The discounted payback period accounts for the changing value of money over time.
• Therefore, the discounted payback period, ndp is the smallest n that satisfies: