03-05-2026

1001CJA101021250074 JA

PART-1 : MATHEMATICS

SECTION-I

1) If (500)! = k.(2a3b5c), (where a,b,c ∈ N, k does not contain any factor of 2,3 or 5) then-

(A) a > c
(B) c = 124
(C) number of zeros at the end of (500!) is equal to 124
(D) (500!) is an even number

2) If , then

(A)

(B)

(C)

(D)

3) Let 'H' be a hyperbola passing through and 'E' be an ellipse passing through
Q(3, 4). Both 'H' and 'E' have same pair of vertices (–4, 8) and (4, 2). Let e1 and e2 be eccentricities of
'H' and 'E' respectively, then which of the following is/are true?

(A)

(B)

(C)

(D)

4) If 1,ω,ω2,.....ωn–1 are the nth roots of unity, then the value of (4 – ω)(4 – ω2)... (4 – ωn–1) is equal to

(A)
is
(B) can't be prime number
(C) is
(D)

5) Let A and B be two square matrices of order 3 then which of the following statements is/are
correct -

(A) ABAT is symmetric matrix

(B) AB – BA is skew symmetric matrix
(C) If B = |A|A–1, |A| ≠ 0, then adj(AT) – B is skew symmetric matrix
(D) If B + AT = 0 and A is skew symmetric matrix then B15 is also skew symmetric matrix

6) Let f : R → R be a thrice differentiable function such that f(1) = 2, f(4) = –1.

Let g(x) = x2 f(x) ∀ x ∈ R. (where R is set of real numbers)

If
Then which of the following is/are True ?

(A) 16 g'(4) – g'(1) = –132

(B)

(C)

(D) 16 g'(4) – g'(1) = –168

7) Which of the following is/are correct

30 90 30 89 30 88 30 60 60
(A) C0 . C60 – C1 . C60 + C2 C60 + ... + C30 C60 = C30
30 90 30 89 30 88 30 60
(B) C0 . C30 – C1 . C30 + C2 C30 + ... + C30 C30 = 0
30 90 30 88 30 86 30 30 30
(C) C0 . C30 – C1 . C30 + C2 C30 + ... + C30 C30 = (2)
30 90 30 87 30 84 30 30
(D) C0 . C30 – C1 . C30 + C2 C30 + ... + C20 C30 = 1

8) If λ1 is the area of the region on the plane bounded by max (|x|, |y|) < 1 and xy < and λ2 is the y-
intercept of the plane which is passing through the intersection of the planes x + 2y + 3z + 5 = 0

and 2x – 3y + 7z + 1 = 0 and is parallel to the line where t ∈ R, then value

of [λ1] + [λ2] is less than or equal to (where [.] denotes greatest integer function)

(A) 3
(B) 4
(C) 5
(D) 6

SECTION-II (i)
Common Content for Question No. 1 to 2

Consider the trigonometric equation +

1) Number of solutions of the equation in is

2) If f : A → B be a function where A is set of all solutions of above equation in [0, 3π] and B is set of
all solutions of above equation in [0, 5π], then number of such function is mn, then minimum value of
(m + n) is (m, n are positive integers)

Common Content for Question No. 3 to 4

If f : R → R, f(x) = 4x – cosπx; g : R → R, g(x) = x3 + 4x – cos πx. Then

3) at x = –3 is then |k| is

4) at x = –4 is then is equal to

Common Content for Question No. 5 to 6

Let P1 : x + y + 2z – 3 = 0 and P2 : x – 2y + z = 4 be two planes. Let A(1,3,4) and B(3,2,7) be two
points in ℝ3.

5) The equation of plane P3 through line of intersection of P1 and P2 and length of projection upon
which of the line segment AB is greatest is equal to ax + by + cz + 1 = 0, then (a + b + c) is equal to
(where a,b,c ∈ I)

6) The equation of plane P4 through the line of intersection of P1 and P2 and the length of projection
upon which of the line segment AB is least is ax – by + cz – d = 0, then (a – b – c + d) is equal to
(where a,b,c,d ∈ N and a,b,c,d are pairwise coprime)

SECTION-II (ii)

1) Let f(x) = (where {.} denotes fraction part function) is continuous at x = 2,

then p + q is
2) Let there are 6 hats of different colours and 6 shirts of same colours as that of hats. If the number
of ways in which these can be put on by 5 men such that no man wear the shirt and the hat of the
same colour is K × 6!. Then the value of K is

3) If an = ; (n ≥ 1), then value of is

4) If the solution of the differential equation is eλx

(where C is constant of integration) then the value of (λ + μ) is equal to

PART-2 : PHYSICS

SECTION-I

1) An imaginary particle has a charge equal to the charge of electron but mass of imaginary
particle is 50 times the mass of electron. Now, consider that imaginary particle moves in circular
orbit around a nucleus. The charge of nucleus is +4e, and nucleus is assumed to be at rest. Assume
mass of nucleus is very large as compared to the mass of imaginary particle moving around it.
Choose the correct option(s).

(A) The radius of nth orbit is , where m is mass of electron, h is Planck constant, e is
charge of electron.
If all atoms are at 16th excited state then during de-excitation till 10th excited state the total
(B)
maximum number of possible wavelengths emitted is 21.
The wavelength of photon emitted when transition takes place from third excited state to
(C)
ground state is 1.21 Å.
Since mass of imaginary particle is different from the mass of electron so the velocity
(D)
of imaginary particle and the electron in nth orbit will be different.

2) A current is flowing through a cylindrical wire of radius R. Comment on the energy stored in the

coaxial cylindrical volume of radius 2R and length ℓ.

(A)
Energy stored inside the cylinder (0 ≤ r ≤ R) is .

(B)
Energy stored inside the cylinder (0 ≤ r ≤ R) is .

(C)
Energy stored outside the cylinder (R ≤ r ≤ 2R) is .

(D)
Energy stored outside the cylinder (R ≤ r ≤ 2R) is .

3) A whistle S of sound frequency f is oscillating with angular frequency ω along the x-axis. Its
instantaneous position and the velocity are given by x(t) = a sin (ωt) and v(t) = v0 cos(ωt),
respectively. An observer P is located on the y-axis at a distance L from the origin (see figure). Let
vPS(t) be the component of v(t) along the line joining the source and the observer. Choose the correct

option(s). (Here a and v are constant)

(A)

(B) The observed frequency will be f when the source is at x = 0 and x = ± a

(C)
The observed frequency will be f when the source is at position x = ±

(D)

4) A particle (p1) of mass m moving with speed v collides with a stationary identical particle (p2). The
particles bounce off each other elastically with p1 getting deflected by an angle θ = 30° from its
original direction. Then, which of the following statement(s) is/are true after the collision?

(A)
Speed of p1 is .
(B) Kinetic energy of p2 is 25% of the total energy.
(C) Angle between the directions of motion of the two particles is 90°.
(D) The kinetic energy of the centre of mass of p1 and p2 decreases.

5) A uniformly charged right angled triangular lamina PQR is shown in figure. The acute angle at
vertex P is θ. If potential at vertices P and R are VP and VR then choose the correct statement(s).
(A) Potential at vertex Q is VRcosθ + VPsinθ
(B) Potential at vertex Q is VRsinθ + VPcosθ
Keep θ and charge density same and lamina is right angled, if the dimensions of triangles are
(C)
decreased then potential at vertices decreases.
Keep θ and charge density same and lamina is right angled, if the dimensions of triangles are
(D)
increased then potential at vertices decreases.

6) An elastic conducting wire of length L and force constant K is secured between two Peg P1 and
P2 on a horizontal frictionless table in the presences of strong uniform magnetic field induction B
pointing vertically upward as shown in figure. A constant current I is switched on in wire that flow

from Peg P1 to P2. Choose correct statement(s).

(A) If shape of wire is stable then must be circular.

(B)
If shape of wire is semicircular then value of K is .

(C)
If shape of wire is stationary circular then K is greater than .

(D)
If shape of wire is stationary circular then K is less than .

7) A capacitor with air as dielectric has capacity C as shown in figure is completely filled with
dielectric slab of mass M and is connected to a block of mass M. The system is released form rest at
time t = 0 when the capacitor was completely filled with dielectric. Then :- (Dielectric constant of

slab = K)

(A)
Charge on the plate of the capacitor when it is half filled with air is .
 The kinetic energy of the block when the capacitor is half filled with dielectric is
(B)
.
(C) The potential difference between the plates when the capacitor is half filled with air is V.

(D)
The energy stored in the capacitor when it is half filled with dielectric is .

8) Two identical ring I and II of equal mass 'm' and radius 'R' are moving in opposite direction with
linear speed ωR and 2ωR respectively. Rings are rotating with equal angular speed in opposite
direction. The line joining the centres makes an angle of 30° with the velocity. Then, at the given

instant (AB = 6R) :-

(A) The angular momentum of ring I about point P is 2mR2ω.

(B) The angular momentum of ring I about point Q is 7mR2ω.
(C) The angular momentum of ring II about point Q is 2mR2ω.
(D) The angular momentum of ring II about point P is 15mR2ω.

SECTION-II (i)

Common Content for Question No. 1 to 2

A multirange dc ammeter circuit as shown in figure consist of a single meter having resistance Rm =
50Ω, in parallel with series of resistance Ra, Rb and Rc which can be selected in different
combinations by rotary switch S that can be represented by an arrow. The arrow may be turned
about its midpoint and accordingly the arrow head can touch the points 1, 2 or 3. The positions of
switch S determines the range of dc ammeter as given in table.

Arrow head in S Operating range of Ammeter

Position 3 0 - 2 mA
Position 2 0 - 10 mA
Position 1 0 - 50 mA

Given full scale deflection current is Im = 1mA.

1) Find value of (in Ω).

2) Find effective ammeter resistance (in Ω) when range is 0 – 10 mA.

Common Content for Question No. 3 to 4

A nonlinear circuit element can be made out of a parallel plate capacitor and small balls, each of
mass m, that can move between the plates. The balls collide inelastically with the plates, dissipate all
kinetic energy as thermal energy and immediately release all the charge they are carrying to the
plate. Almost instantaneously, the balls then pick up a small charge of magnitude q from the plate,
the balls are then repelled directly towards the other plate under electrostatic forces only. Another
collision happens, kinetic energy is dissipated, the balls give up the charge, collect a new charge and
the cycle repeats. There are n0 balls per unit surface area of the plates. The capacitor has a
capacitance C, the separation 'd' between the plates is much larger than the radius r of the balls. A
battery is connected to the plates in order to maintain a constant potential difference V. Neglect
edge effects and assume magnetic and gravitational forces to be negligible. (ε0 is permittivity of free
space)

3) The current between the plates in terms of any or all of the given parameters ε0, m, n0, c, q

and V is . The value of k is :-

4) The effective resistance of the device in terms of any or all of the given parameters ε0, m, n0, c,

q and V is . The value of k is :-

Common Content for Question No. 5 to 6

If a point P moves in plane along a given curve y = f(x), the angular velocity of point P about a fixed
point O in the plane is the rate of change of the angle that OP line makes with a fixed direction [OX-

line] in the plane. Let OP = r at t = t sec, PM = rdθ =

PQ sinϕ, But if dθ is very small then, (arc length)
⇒ rdθ = ds sin ϕ

5) If two particles A and B are having speed m/s and 20 m/s at a particular instant as shown in
the figure, then the angular velocity (in rad/sec) of A with respect to B at the same instant is :-

6) The point P moves on parabolic path y2 = 4(x + 1), where x and y are in meter with constant
speed 2 m/s. Its angular velocity (in rad/sec) about focus at an instant when it makes angle 60° at
focus with x-axis is :- [all angles are measured in anticlockwise direction with positive x-axis]

SECTION-II (ii)

1) A laser beam propagates through a spherically symmetric media. The refractive index varies with

0 0 0
the distance to symmetry centre C by the law where n = 1, r = 30 cm, r ≤ r < ∞. The
beam's trajectory lies in the plane that includes C. At distance r1 = 100 cm the beam makes an angle
ϕ = 30° with , as shown in figure. If the minimal distance does the beam reach relative to the
symmetry centre C is , find the value of k.

2) A "spring dumb-bell" comprises of two balls each of mass m = 1 kg that connected with a light
spring of natural length 10 cm and stiffness k = 0.5 N/m. Two such dumb-bells are sliding towards
one another, the velocity of either is v0 = 1 m/s as shown in the figure. At time t = 0, the distance
between them is L = 2π meters. All the collisions are perfectly elastic and instantaneous. After the

0
time t , spring potential energy will be maximum first time. If sec, then find the value of k.

3) A conducting rod of length 1 m aligned along the unit vector , is moving with a velocity
m/s. The motion take place in a uniform magnetic field tesla. Find the
magnitude of induced emf across the rod in volt.

4) In an α-decay of stationary nucleus the kinetic energy of α particle is 48 MeV and Q value of the
reaction is 50 MeV. The mass number of the parent nucleus is 20n then find n : (Assume that
daughter nucleus is in ground state)

PART-3 : CHEMISTRY

SECTION-I

1) On heating, ammonium perchlorate decomposes to give

(A) Cl2(g)
(B) N2(g)
(C) O2(g)
(D) NH3(g)

2) For 1 mole of oxygen gas (assuming ideal behaviour), P-V curve is given

Then for the given change, select the correct statement(s)

(A) For process AB, change in internal energy (ΔU) > 0

(B) For process BC, change in temperature (ΔT) > 0
(C) For process CD, heat is rejected from the system.
(D) For process DA, heat is abserbed by the system.

3) Identify reaction correctly match with their product?

(A)

(B)
(C)
Product P is

(D)

4) Reaction of Hg2Cl2 with ammonia solution gives

(A) Greyish black Precipitate formed

(B) Hg(NH2)Cl
(C) Hg
(D)

5) Which of the following is/are correctly matched?

(A)
α-napthol
Number of oxygen atoms in major product is 2

(B)

Number of oxygen atom in major cyclic product is 1

(C)
Degree of unsaturation in major product is 2.
(D)

Number of moles of CH3COCl consumed by 1 mole of major product is 4.

6) Following conversion can be carried out by using sequence.

(A) (i) LiAlH4, PBr3, DMSO/NaHCO3/Δ

(B) (i) Ca(OH)2 (ii) (HCOO)2Ca/dry distillation
(C) (i) R'–OH/H+ (ii) DIBAL-H
(D) (i) SOCl2 (ii) H2/Ni, Δ

7) For the following sequence, choose the correct option(s).

(A) (Q) will give positive Br2, H2O Test

(B) (R) on reaction with NaNO2, HCl produces (Q)
(C) Major product (P) & (S) both give positive carbyl amine test

(D)
Product T is

8) Which of the following statement(s) is/are correct?

The change in Gibb's free energy with pressure at constant temperature is equal to volume of
(A)
the system.
(B) The crystals of CO and NO have some residual entropy.
For a mixture of two ideal gases, the entropy of mixing have a maximum value of about 5.76 J
(C)
K–1 mole–1
(D) In a reversible process, ΔSsystem is always zero in an isolated system

SECTION-II (i)
Common Content for Question No. 1 to 2
In qualitative analysis, confirmation of ferric ion by adding KSCN results in blood-red coloration. It is
largely due to compound 'P', but in addition of excess KSCN, complexes such as 'R' (C. No. = 4) and
'S' (C. No. = 6) formed respectively.

1) Spin only magnetic moment (in BM) of compound 'P' is

2) Number of linkage isomers in compound 'R' and compound 'S' are 'X' and 'Y' respectively.

Calculate .

Common Content for Question No. 3 to 4

3) How many statements are incorrect?

(a) Compound C on treating with conc. NaOH show disproportionation reaction.
(b) Compound C is primary amine
(c) Compound E is Ph-COO–Na+
(d) Compound D is Ph – CH2 – N = CH2

(e) Compound B

(f) Compound A

4) Calculate degree of unsaturation (D.U.) in product D

Common Content for Question No. 5 to 6

At 298 K, the limiting molar conductivity of a weak monobasic acid is 4 × 102 S cm2 mol–1. At 298 K,
for an aqueous solution of the acid the degree of dissociation of α and the molar conductivity is y ×
102 Scm2 mol–1. At 298 K, upon 20 times dilution with water, the molar conductivity of the solution
becomes 3y × 102 S cm2 mol–1.
5) The value of α is ______.

6) The value of y is ______.

SECTION-II (ii)

1) I. Number of cations that form soluble complex with excess NH3 solution from the following = p.
Fe+2, Zn+2, Co+2, Fe+3, Mn+2, Al+3, Hg+2, Cu+2
II. Number of compounds that do not respond to Chromyl Chloride Test in the following = q
NaCl, AgCl, HgCl2, KCl, SnCl4, NH4Cl, CaCl2, Hg2Cl2
Then calculate p × q.

2) Toluene on Etard oxidation gives an organic compound (X), which on heating with Ac2O/AcONa
followed by hydrolysis gives an aromatic compound (Y). Calculate the sum of degree of unsaturation
of (X) & (Y).

3) In the given substances below, x be the number of emulsions and y be the number of gels
respectively, then find the value of (x + y).
Butter, milk, jam, fog, mist, smoke, blood, cheese, jellies.

4) A vessel fitted with a weightless, frictionless piston of surface area 0.025 m2, contains excess of
conc. HCl. 1 kg of iron fillings were added at 300 K and X is the percentage purity of iron sample.
The solution contains iron in (+2) oxidation state. If the piston is moved by 14.94 m then find X.
[Take atmospheric pressure = 105 Pa, R = 8.3 Joule mole–1 K–1, consider temperature constant during
the process]
 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I

Q. 1 2 3 4 5 6 7 8
A. A,B,C,D A,C A,C A,C C,D C,D A,C B,C,D

SECTION-II (i)

Q. 9 10 11 12 13 14
A. 8.00 16.00 4.00 7.00 4.00 5.00

SECTION-II (ii)

Q. 15 16 17 18
A. 0 309 7 2

PART-2 : PHYSICS

SECTION-I

Q. 19 20 21 22 23 24 25 26
A. A,B,C A,C A,B A,B,C A,C A,B,C A,B,C A,C,D

SECTION-II (i)

Q. 27 28 29 30 31 32
A. 0.40 9.00 1.00 1.41 to 1.42 1.00 0.25

SECTION-II (ii)

Q. 33 34 35 36
A. 2 3 4 5

PART-3 : CHEMISTRY

SECTION-I

Q. 37 38 39 40 41 42 43 44
A. A,B,C A,C,D A,C,D A,B,C A,B,D A,B,C A,C,D A,B,C,D

SECTION-II (i)

Q. 45 46 47 48 49 50
A. 5.80 to 6.00 1.40 4.00 4.00 0.21 or 0.22 0.86
 SECTION-II (ii)

Q. 51 52 53 54
A. 12 11 5 84
 SOLUTIONS

PART-1 : MATHEMATICS

1) (500!) = k.(2a3b5c)

(where [.] denotes greatest integer function)

= 100 + 20 + 4 ∴ c = 124
any set of 2 and 5 produces a zero at the end
∴ number of zeroes at the end = number of sets of 2 and 5. Clearly a > c
∴ Number of zeros = 124

2)

3) Let F1(4e1 5 – 3e1), F2(–4e1, 5 + 3e1) be foci of hyperbola.

,

Now PF2 – PF1 = Length of transverse axis = 10

Now semi conjugate axis =

∴ Latus rectum of H =
Let F1(4e2, 5 – 3e2), F2(–4e2, 5 + 3e2) be foci of ellipse.
Now, QF1 + QF2 = 10

Now semi-minor axis of

Latus rectum of 'E' =

4)

Put z = 4
for n = 2 ⇒ 5 can be prime.

5)
∴ adjA = B and adj(AT) = BT
Now X = adj(AT) – B
XT = (BT)T – adj(AT)
XT = B – adj(AT) ∴ XT = –X
AT = –A and B + AT = 0 ∴ B = A
Now X = B15
XT = (BT)15 = (–A)15 = –(A15) = –B15
XT = –X

6) (1) 64 f(4) – f(1) –

(2)
∴ 256 f '(4) – f '(1) = –36
(3) g'(x) = 2x f(x) + x2 f '(x)
∴ g'(4) = –8 + 16f '(4) and
g'(1) = 4 + f '(1)
∴ 16 g'(4) – g'(1) = –128 + 256 f '(4) – 4 – f '(1)
= –132 – 36 = – 168

7) Compare coefficient of x60 and x30

Both side in expansion of to get A and B for (C) compare coefficient of

x30 in
8)

= 3 + loge2 = λ1
(x + 2y + 3z + 5) + λ(2x – 3y + 7z + 1) = 0
x(1 + 2λ) + y(2 – 3λ) + z(3 + 7λ) + (3 + λ) = 0

is parallel to
8(1 + 2λ) – 7(2 – 3λ) – 4(3 + 7λ) = 0
⇒λ=2
5x – 4y + 17z + 7 = 0

y-intercept =
[λ1] + [λ2] = 4

9) Put

we get

Using

a=b=c

Number of solution is is 8.

10) n(A) = 6; n(B) = 10

∴ Number of functions = 106

11) (g–1of–1(x)) = (g–1(f–1(x)))′ . (f–1(x))′ here f(–1) = –3

 (g–1of–1(x))x = –3 = (g–1(–1))′ . (f–1(–3))′ ....(I)
Again f–1(f(x)) = x

(f–1(f(x)))′ . f ′ (x) = 1 ⇒ (f–1(f(x))′ =

at x = –1, (f–1(–3))′ = ....(II)

f–1(–1) =
f(0) = –1
g–1(g(x)) = x but g(0) = –1
(g–1(g(x)))′ . g′(x) = 1 g–1(–1) = 0

(g–1(g(x)))′ = ⇒ (g–1g(–1))′ =

at x = 0, (g–1(g(0)))′ = ⇒ (g–1(–4))′ =

(g–1(–1))′ = ....(III)
Using equation (II), (III) in (I)

We get

12) We get

Here g(–1) = –4 g–1(–4) = –1

13) Equation of family of planes containing the line of intersection of P1 and P2 is given by P1 +
λP2 = 0
⇒ (1 + λ)x + (1 – 2λ)y + (2 + λ)z – 3 – 4λ = 0
Projection of length of line segment AB is greatest, then AB must be parallel to plane (1)
∴ drs of AB = 2, – 1,3.
2(1 + λ) – 1 (1 – 2λ) + 3(2 + λ) = 0
∴ P3 : 3y + z + 1 = 0

14) Projection of length of line segment is least is if AB is perpendicular to plane (1).

∴ Equation of plane P4 is 2x – y + 3z = 7.

15)
 For RHL =

RHL =

For LHL =
(∵ {–x} = {–(2 – h)} = {–2 + h})
⇒p=q=0
So p + q = 0

16) Dn = de arrangement of n persons

K = 6P5 (D6 + D5) = 6!(265 + 44) = 309 × 6!

17)

18)

integrating w.r.t. x,
⇒ xy + y2 – x = ln(sin–1x) ⇒ ex sin–1x =

PART-2 : PHYSICS

0
19) (Where m = 50 m) ....(i)
 ...(ii)

E4 = –680 eV
E1 = –10880 eV
ΔE = E4 – E1 = 10,200 eV

20) (R ≤ r ≤ 2R)
Energy density,

(0 ≤ r ≤ R)

21)
VPS(t) = V(t) cos θ

at x = 0 and at x = ±a,
VPS(t) = 0
⇒ Observed frequency = original frequency = f
22)
By CE :

KE of CM = KETotal, ground – KECM frame

23)
vP = f(θ) × σ × L
vR = g(θ) × σ × L

= vR cos θ + vP sin θ
24)

= uniform
⇒ shape is circle
If semicircle, R = L/2

T = BiR = K(Rθ – L)

and θ ≤ 2π

25)
V remain same as capacitor is connected with battery charge on C = C'V

Charge on C =
Energy stored in C when slab is half filled

Total work done = KE – 0

Wby battery + (Qt – Qi) × V

Mg – T = Ma
T = Ma

26) Angular momentum of rigid body about any point is given as

For Ring I,
LP = (mR + mR )ω = 2mR2ω
2 2

LQ = 2mωR × 4R + mR2ω = 9mR2ω

For Ring II
LP = 4mωR × 4R – mR2ω = 15mR2ω
LQ = (mR2 + mR2)ω = 2mR2ω

27)

At 1 :

At 2 :

At 3 :

⇒ Rb = 4Ra

⇒ Rc = 20 Ra
Also, Ra = 2, Rb = 8, Rc = 40

28)

At position 2,

29) Acceleration of ball,

So, time of motion,

So,
30)

31) rad/sec

32)
y2 = 4x + 4

2yy' = 4 ⇒

θ = 30°

33)

µ(r)·r·sinϕ = constant

34)

Just before 1st collision :

t = π sec
 Just after 1st collision :
t = π sec

The maximum compression would occur simultaneously in both spring after further time

35)

36)

my = 96
∴ mass of parent nuclei = mα + my = 100

PART-3 : CHEMISTRY

37) NH4ClO4(s)→Cl2(g) + N2(g) + O2(g) + H2O(g)

38)

Process AB → V increases T↑ ΔU > 0

Process BC v decreases T↓ ΔT < 0
Process CD P↓ T↓ ΔQ < 0
Process DA P↑ ΔQ > 0

39) H2/Pd-BaSO4 used for single step reduction; halogen is o/p directing in EAS reaction.
40)

41) The correct answer is option (A,B,D)

42)
DIBALH used as single step Reduction.

43)

→ → Ph – CH = C = O

44)

= 5.763 J mol–1K–1

45)

undergoes sp3d2 hybridisation

no. of unpaired e– = 5
µ = 5.92 BM

46) No. of linkage isomers in R = 5

No. of linkage isomers in S = 7

47) Incorrect : b, c, d, f
Solution : Self Cannizaro is disproportionation reaction
48)

49)

= 4 × 102 Scm2 mol–1

= y × 102 Scm2 mol–1; = 3y × 102 Scm2 mol–1

or, a = ...(1)

a2 =

or,
or, 80 – 60y = 36 – 9y

or, y= = 0.862
∴

50)

= 4 × 102 Scm2 mol–1

= y × 102 Scm2 mol–1; = 3y × 102 Scm2 mol–1

or, a = ...(1)

a2 =

or,
or, 80 – 60y = 36 – 9y

or, y= = 0.862 ∴

51)
Fe+2, Fe+3, Mn+2, Hg+2, Al+3 are insoluble.
AgCl, Hg2Cl2, HgCl2, SnCl4 do not respond due to high covalent character.

52) x = Benzaldehyde
y = Cinnamic acid

53) Emulsion → Butter, milk

Gels → Cheese, jams, jellies

54) pΔv = nRT

14.94 × 105 × 25 × 10–3 = X × 8.3 × 300
X = 15
Mass of pure iron = 56 × 15 = 840 g
% purity = 84