26-04-2026

9610WJA802542260007 JA

PART 1 : PHYSICS

SECTION-II

1) If rain drops are falling with speed 12 m/s at angle of 30° with vertically for the observer at rest.
Then if observer starts moving with constant acceleration 4 m/s2 along horizontal. After time T
observer observes rain drop again at an angle of 30° with vertical. Then find T.

2) Position x of a particle moving along the x-axis is given by equation x = 2t3 – 21t2 + 36 t – 72,
where x is in meters and t is in seconds. Find time interval (in seconds) between the instants it
changes its direction of motion.

3) Two identical planets are orbiting around a star in elliptical paths having their semi-major axes in
the ratio of 1 : 9. If life of man on 1st planet is 80 years then what will be his life on 2nd planet in
terms of that planet's year?

4)

Calculate ratio of (i1 + i2) and i3 in following diagram.

5) Resistance are connected in a meter bridge circuit as shown in the figure. The balancing length ℓ1
is 40cm. Now an unknown resistance x is connected in series with P and new balancing length is
found to be 80cm measured from the same end. Then the value of x will be _____ Ω

6) Two concentric uniformly charged spheres of radius 10 cm & 20 cm are arranged as shown in the
figure. Potential difference between the spheres is x × 1011 V. The value of x is :-
7) A point charge Q and an electric dipole of dipole moment P are placed as given in figure. The

force on dipole due to point charge is . The value of N is :-

8) A particle of mass m is moving in circular motion of radius r with constant speed v in influence of
two fixed particles of mass M. Plane of circular motion is perpendicular to line joining fixed particles

as shown. Speed of particle is given as find value of n (a = r )

SECTION-I (i)

1) Three planets of same density and with radii and such that have
gravitation fields on the surfaces of magnitudes and escape speeds respectively.

(A)

(B)

(C)

(D)

2) S is solid neutral conducting sphere. A point charge q of 1 × 10–6 C is placed at point A. Point C is

the centre of sphere and AB is a tangent. BC = 3m and AB = 4m:

(A) The electric potential of the conductor is 1.8 kV.
(B) The electric potential of the conductor is 2.25 kV.
(C) The electric potential at B due to induced charges on the sphere is –0.45 kV.
(D) The electric potential at B due to induced charges on the sphere is 0.45 kV

3) Consider two-point charges Q and fixed on x-axis at a finite distance from each other. Select

correct alternative(s) for points lying on x-axis.

(A) At finite distance from charge system there is only one point at which net Electric field is zero
(B) At finite distances from charge system there is only one point at which potential is zero
(C) At finite distances from charge system there are two points at which potential is zero
(D) The electric field at points lying between the charges is towards +x direction.

4) In a potentiometer primary cell has internal resistance of as shown in figure. The

potentiometer wire is combination of two wires connected in series as shown in figure. The common
cross sectional radius of both wires used for potentiometer is 'a'.

(A)
Range of potentiometer is

(B)
Range of potentiometer is

(C)
If null point is at mid point of longer wire then ε' =

(D)
If null point is at mid point of longer wire then ε' =

5) A galvanometer has a resistance of 96 Ω and full scale deflection of 100 µA. It can be used as
ammeter provided a resistance is added to it. Pick up the correct range and resistance
combination(s)

(A) 1.3 mA range with 25 kΩ resistance in parallel

(B) 1.3 mA range with 8Ω resistance in parallel
(C) 2.5 mA range with 2.5 Ω resistance in parallel
(D) 2.5 mA range with 4Ω resistance in parallel
6) A 470 g lead ball is launched at 60° angle above the horizontal with an initial speed of 100 m/s
directly towards a target on a vertical cliff wall which is 150 m away as shown in the figure.

(A) Time taken by ball to hit the cliff is 1.5 second.

(B) Time taken by ball to hit the cliff is 0.75 second.
(C) The distance by which lead ball misses the target when it hits the wall is 2.81 m.
(D) The distance by which lead ball misses the target when it hits the wall is 11.25 m.

SECTION-I (ii)

1) List-I shows position versus time graph for an object and List-II shows its possible motion.

List–I List–II

(P) (1) A ball rolls along floor towards origin.

(Q) (2) A ball rolls towards a wall at the origin, then ball rebounds.

A ball rolling away from the origin; hits a wall and bounces
(R) (3)
straight back.

(S) (4) An object rolling towards the origin and suddenly stops.

(5) A book at rest on table.

(A) P → 1;Q → 3;R → 2;S → 4
(B) P → 2;Q → 3;R → 4;S → 1
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 4;Q → 2;R → 3;S → 1

2)

Match the entries on left side with entries on right side when left most plate is grounded. Then

List-I List-II
(P) The charge appearing on outer surface of right most plate is (1) 0
(Q) The charge appearing on outer surface of left most plate is (2) Q
(R) The charge appearing on left surface of middle plate is (3) –Q
(S) The charge appearing on right surface of middle plate is (4) 2Q
(5) –2Q
(A) P → 1;Q → 2;R → 3;S → 5
(B) P → 1;Q → 1;R → 5;S → 5
(C) P → 1;Q → 1;R → 5;S → 4
(D) P → 2;Q → 2;R → 3;S → 4

3) A planet is rotating about it's axis. The radius of planet is R and its mass is m. It has a
geostationary satellite in equatorial plane at a height h from surface.

List-I List-II

If the planet suddenly contracts without

(P) (1) The energy of satellite decreases.
change in it's mass

(Q) If the planet suddenly stop rotating. (2) The energy of satellite increases.

If the geostationary satellite is pushed in direction

(R) (3) The energy of satellite remains same.
of motion to suddenly double the velocity.

If the geostationary satellite suddenly detaches half

(S) (4) The satellite covers larger area on the planet.
of it's mass without any relative velocity.

(5) The satellite does not remain geostationary.

(A) P → 3;Q → 4;R → 5;S → 3

(B) P → 3;Q → 4;R → 5;S → 2
(C) P → 3;Q → 5;R → 3;S → 4
(D) P → 3;Q → 4;R → 5;S → 3
4) Figure shows two cylindrical uniform specimen of electrical resistances with their character :

Resistivity : ρ1 = ρ ρ2 = 2ρ
Length : ℓ1 = ℓ ℓ2 = 2ℓ
Area of cross-section : A1 = A A2 = A/2
No. of electron per unit volume: n1 = n n2 = 2n
R1 and R2 are connected in circuit as shown in figure. Voltmeter and ammeter connected in the
circuit are ideal. Comparison of electric field, drift speed and power dissipated per unit
volume through R1 & R2 is to be done only if current flows in them.

Column–I Column–II
(A) S1 is open S2 is closed (P) Reading of voltmeter is maximum
(B) S1 is closed S2 is open (Q) Reading of ammeter is maximum
(C) S1 and S2 both are closed (R) Magnitude of electric field in R2 is greater than that in R1
(D) S1 and S2 both are open (S) Drift speed of electron is greater in R2 than in R1
(T) Power dissipated per unit volume is greater in R2 than in R1
(A) A → P;B → R;C → T;D → R
(B) A → R;B → T;C → P;D → R
(C) A → Q;B → R;C → P;D → S
(D) A → S;B → T;C → P;D → R

PART 2 : CHEMISTRY

SECTION-II

1) For the reaction:

3A → 2B, the rate law is: Rate = k[A]n. The following graph is obtained experimentally:
The rate of reaction when [A] = 0.1 M is P × 10–4 M min–1
Determine P.

2) The rate constant of a zero order reaction is 2.0 × 10-2 mol L-1 s-1. If the concentration of the
reactant after 25 s is 0.5 M, what is the initial concentration?

3) The reaction that occurs in a breath analyser, a device used to determine the alcohol level in a
person's blood stream is
2K2Cr2O7 + 8H2SO4 + 3C2H6O → 2Cr2(SO4)3 + 3C2H4O2 + 2K2SO4 + 11H2O
If the rate of appearance of Cr2(SO4)3 is 2.67 mol min–1 at a particular time, the rate of disappearance
of C2H6O at the same time is ________ mol min–1.
(Nearest integer)

4) If a 1st order reaction is completed to the extent of 60% and x% in time intervals, t1 and t2 (min)

calculate x given that and fill the answer as .

[Take [log 2.5 = 0.3979]
[100.0961 = 1.25]

5) Calculate mass of CaBr2 (in gram) required in 960 gm of solution to have a depression in freezing
point of solution equal to 2K. (Kf of H2O = 2K-kg/mole)

6) Find Ecell for

Ag(s) | AgBr(s) | KBr(aq., 10–1M) || KCl(aq., 10–6 M) | AgCl(s) | Ag(s)
Given, Ksp (AgCl) = 10–10 M2.
Ksp (AgBr) = 10–15 M2.

7) Find the number of correct statements ?

(I) Pd(II) and Pt(II) form mostly the 4-coordination, square planar, diamagnetic co-ordination
entities.
(II) The free ions Pd+2, Pt+2 and Ni+2 are paramagnetic in ground states.
(III) Octahedral [Co(H2O)6]+2 is pink, that of tetrahedral [CoCl4]2– is blue

0
(IV) Δ = Δt
(V) If a multidentate ligand happens to be cyclic and there are no unfavourable steric effects a
further increase in stability occurs. This is termed the macrocyclic effect.

8) The oxidation state of Mo in its oxo-complex species [Mo2O4(C2H4)2(H2O)]2– is :

SECTION-I (i)

1) Fusion of MnO2 with KOH in presence of O2 produces a salt W. Alkaline solution of W upon
electrolytic oxidation yields another salt X. The manganese containing ions present in W and X,
respectively, are Y and Z. Correct statement(s) is (are)
(A) Y is diamagnetic in nature while Z is paramagnetic
(B) Both Y and Z are coloured and have tetrahedral shape
(C) In both Y and Z, hybridization is d3s
(D) In aqueous acidic solution, Y undergoes disproportionation reaction to give Z and MnO2.

2) Which of the following is/are correct ?

(A) For A(g) + e– → A¯ (g) ΔH may be negative

(B) For A¯(g) + e– → A2– (g) ΔH may be negative
(C) For A¯(g) + e– → A2– (g) ΔH must be positive
(D) For Ne(g) + e– → Ne¯ (g) ΔH is negative

3) In halogens, which of the following properties increase from iodine to fluorine

(A) Ionisation energy

(B) Electronegativity
(C) Bond length
(D) Electron affinity

4) An α-particle having kinetic energy 4.0 MeV is projected towards tin nucleus (Z = 50). Select the
correct information(s) regarding the α-particle.

(A) Its distance of closest approach towards the nucleus is 3.6 × 10−14 m.
(B) Its potential energy at a distance of 9.0 × 10−14 m from the nucleus is 1.6 MeV.
(C) Its kinetic energy at a distance of 4.5 × 10−14 m from the nucleus is 0.8 MeV.
(D) At a moment, the distance between α-particle and the nucleus becomes 2.0 × 10−16 m.

5) The ground state energy of hydrogen atom is –13.6 eV. Consider an electronic state Ψ of He+
whose energy, azimuthal quantum number and magnetic quantum number are –3.4 eV, 2 and 0
respectively. Which of the following statement(s) is(are) true for the state Ψ?

(A) It has 2 angular nodes

(B) It has 3 radial nodes
(C) It is a 4d state
The nuclear charge experienced by the electron in this state is less than 2e, where e is the
(D)
magnitude of the electronic charge.

6) The correct statement(s) regarding the binary transition metal carbonyl compounds is (are)
(Atomic numbers : Fe = 26, Ni = 28)

(A) Total number of valence shell electrons at metal centre in Fe(CO)5 or Ni(CO)4 is 16
(B) These are predominantly low spin in nature
(C) Metal - carbon bond strength is less when the oxidation state of the metal is lowered
(D) The carbonyl C–O bond weakens when the oxidation state of the metal is increased

SECTION-I (ii)
1) In a conductometric titration, small volume of titrant of higher concentration is added stepwise to
a larger volume of titrate of much lower concentration, and the conductance is measured after each
addition.
The limiting ionic conductivity values (in mS m2 mol–1) for different ions in aqueous solutions are
given below :

Ions Ag+ K+ Na+ H+ Cl– OH– CH3COO–

Λ0 6.2 7.4 5.0 35.0 7.2 7.6 16.0 19.9 4.1

For different combinations of titrates and titrants given in List-I, the graphs of 'conductance' versus
'volume of titrant' are given in List-II.
Match each entry in List-I with the appropriate entry in List-II and choose the correct option.
List-I List-I

Titrate : KCl
(P) (1)
Titrant : AgNO3

Titrate : AgNO3
(Q) (2)
Titrant : KCl

Titrate : NaOH
(R) (3)
Titrant : HCl

Titrate : NaOH
(S) (4)
Titrant : CH3COOH

(5)

(A) P → 4;Q → 3;R → 2;S → 5

(B) P → 2;Q → 4;R → 3;S → 1
(C) P → 3;Q → 4;R → 2;S → 5
(D) P → 4;Q → 3;R → 2;S → 1
2)

List-I
List-II
(Order - nA → P)

(P) Zero (1) Reaction complete in finite time

(Q) One (2)

v/s time graph is straight line

(R) Two (3) Half life increases when [A]0 decreases

(S) Half (4) Rate of reaction decrease during reaction

(5) May be elementary reaction

(A) P → 1;Q → 5;R → 4;S → 2
(B) P → 2;Q → 3;R → 4;S → 5
(C) P → 4;Q → 5;R → 1;S → 2
(D) P → 2;Q → 3;R → 3;S → 4

3) Match the Column -

Column-I Column-II

(A) Acetone + CHCl3 (P) ΔSmix. > 0

(B) Ethanol + Water (Q) ΔVmix. > 0

(C) C2H5Br + C2H5I (R) ΔHmix. < 0

(D) Acetone + Benzene (S) Maximum boiling azeotropes

(T) Minimum boiling azeotropes

(A) A → PRS;B → PQT;C → PRS;D → P
(B) A → PRS;B → PQT;C → P;D → PQT
(C) A → PQT;B → P;C → PRS;D → PQT
(D) A → PQR;B → PRS;C → QT;D → PQ

4)

List-II
List-I (Reactions) (Observations)

CrO5 (on standing in acidic

(P) (1) Redox reaction
medium)

(Q) (2) Evolution of O2 is associated

Green colour
(R) (3) solution/compound is
formed as product
 Orange/Yellow colour
(S) (4) solution/compound is
formed as product

(5) Decomposition reaction

The correct option is :-
(A) P → 3,4,5;Q → 1,4;R → 2,4;S → 1,2,3,4
(B) P → 1,2;Q → 2,4;R → 1,2,3;S → 1,2,4
(C) P → 1,2,3;Q → 1,3;R → 1,3;S → 1,2,3
(D) P → 3,4;Q → 1,2,3;R → 2,3,5;S → 2,3,4

PART 3 : MATHEMATICS

SECTION-II

1) Let ƒ(x) be a polynomial function satisfying and

, where p,q ∈ N, then the least value of p + q is

2) Let and , then is

(where [.] and {.} denotes greatest integer and fractional part function respectively)

3) Find the number of points where f(x) = [sin x + cos x] (where [.] denotes greatest integral
function) is not continuous in x ∈ (0, 2π).

4) Let f(x) =
If f(x) is continuous at x = 0, then the value of (a2 . b2) is

5) If a, b, c are the roots of the equation x3 – 2x2 + 1 = 0, then the value of

is equal to

6) The equation x2 + bx + c = 0 has two distinct roots. If 2 is subtracted from each root the results

are reciprocal of original roots, so find value of

7) Let and If k is product of

different values of then the value of is

8)

If ƒ(x) is onto function & ƒ : [0,2] → [–1,1]. Let domain & range of (ƒ (2x))2 is [α1,α2] & [β1,β2]
respectively, then α1+ α2+β1+β2 is equal to

SECTION-I (i)

1) is

(A) 1; n > 1
(B) e; n > 0
(C)
(D) 0; n > 1

2) If = y2 + 4y + 5, then y can be equal to-

(A) 1
(B)
(C)
(D)

3) Let [x] be the greatest integer less than or equal to x. Then, at which of the following points(s) the
function is discontinuous

(A) x = -1
(B) x = 0
(C) x = 2
(D) x = 1

4) If where & , then the

possible value(s) of α is/are

(A)

(B)

(C)
(D)

5) Given a real valued function f such that

where [x] is the integral part and {x} is the fractional part of x, then :

(A)

(B)

(C)

(D)

6) For a quadratic plynomial f(x)=4x2 − 8kx + k, the statements which hold good are ?

(A) There is only one integral k for which f(x) is non-negative ∀ x ∈ R

(B) for k < 0 the number zero lies between the zeros of the polynomial.

(C)
f(x) = 0 has two distinct solutions in (0,1) for
(D) Minimum value of f(x) is k(1 + 12k) ∀ k ∈ R

SECTION-I (ii)

1)

Column-I Column-II

(P) (1) –1
equals

(Q) (2) 0
The value of equals

(R) (ln sin3x – ln(x4 + ex3)) equals (3) 1

(S) (4)
If can be expressed as rational in the lowest
form, then the value of (p + q), is
 (5) 4
(A) P → 3;Q → 2;R → 1;S → 4
(B) P → 3;Q → 3;R → 1;S → 5
(C) P → 2;Q → 3;R → 1;S → 5
(D) P → 2;Q → 3;R → 5;S → 1

2)

Column 1 Column 2

(P) If x = cosec2 (cot–1 3) – sec2 (tan–1 2), then (1) x = 2

(Q) If tan–1 x + tan–1 (1/y) = tan–1 3 and y2 + y – 56 = 0 (2) x = 5

(R) If cos–1 x = tan–1 y and y2 = 3 (3) X = 1/2

(S) If sin–1 (tan π/4) – sin–1 – π/6 = 0 and x2 = y (4) x = –1/2

(5) x = 0
(A) P → 2;Q → 1,3;R → 3,4;S → 5
(B) P → 1,2;Q → 3,4;R → 5;S → 2
(C) P → 2;Q → 1,2;R → 3,4;S → 1
(D) P → 1,2,3;Q → 4;R → 3;S → 2

3) Match the function mentioned in column-I with the respective classification given in column-II.
(where [.] and {.} denote greatest integer function and fractional part function respectively)

Column-I Column-II

(P) (1) one-one

(Q) ƒ(x) = ℓn(x2 + 2x) (2) many-one

(R) ƒ : [–2,2] → [–1,1] ƒ(x) = sinx (3) onto

(S) ƒ : → ƒ(x) = x3 – 3x2 + 3x – 7 (4) periodic

(5) aperiodic
(A) P → 1,3;Q → 2,3,5;R → 2,3,5;S → 1,3,5
(B) P → 1,2;Q → 3,5;R → 2,3,5;S → 1,4
(C) P → 1,2,3;Q → 2,3;R → 4,5;S → 1,2
(D) P → 2,3;Q → 2,3,4;R → 3;S → 1

4)

Column-I Column-II

(P) If (1) 2
then maximum value of y is
 The value of λ where
(Q) log(log4) + log(log25) = logλ + log(log2) (2) 3
+ log(log5) is

The number of natural numbers

satisfying the inequality
(R) (3) 4

is

The value of 'a' satisfying the equation

(S) loge2.loga625 = log1016.loge10 is (4) 5
(where e is Napier's constant)

(5) 6
(A) P → 2;Q → 4;R → 5;S → 1
(B) P → 2;Q → 3;R → 5;S → 4
(C) P → 3;Q → 4;R → 5;S → 1
(D) P → 1;Q → 3;R → 5;S → 2
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-II

Q. 1 2 3 4 5 6 7 8
A. 3.00 5.00 2.96 1.16 20.00 4.50 3.00 4.00

SECTION-I (i)

Q. 9 10 11 12 13 14
A. B,C,D A,C A,C,D A,C B,D A,D

SECTION-I (ii)

Q. 15 16 17 18
A. A C B B

PART 2 : CHEMISTRY

SECTION-II

Q. 19 20 21 22 23 24 25 26
A. 0.11 1.0 4.00 2.00 60.00 0.59 to 0.60 4.00 3.00

SECTION-I (i)

Q. 27 28 29 30 31 32
A. B,C,D A,C A,B A,B,C A,C B,C

SECTION-I (ii)

Q. 33 34 35 36
A. C A B C

PART 3 : MATHEMATICS

SECTION-II

Q. 37 38 39 40 41 42 43 44
A. 5.00 3.00 5.00 1.00 4.00 1.00 5.00 2.00

SECTION-I (i)

Q. 45 46 47 48 49 50
A. A,C B,D A,C,D B,C A,B,C,D A,B,C
 SECTION-I (ii)

Q. 51 52 53 54
A. B C A B
 SOLUTIONS

PART 1 : PHYSICS

1) Explain Question: Find the time after which rain appears to drop at 30°
Concept: Rain-main
Solution:
Initially Case-1 :

Now
Case-2 :

⇒
From Geometry :
12sin30° = 2t

6 = 2t
t = 3 seconds
Final Answer: (3.00)

2) Explain Question: Find time when particle changes its motion

Concept: Variable accelaration
Solution:
v = 6t2 – 42 t + 36
v = 0 ⇒ t2 – 7t + 6 = 0
t = 6 and t = 1
Final Answer: (5.00)

3) Explain Question: Find the life on second planet

Concept: Kepler's law
Solution:

Life years =

Final Answer: (2.96)

4) Explain Question: Calculate ratio of (i1 + i2) and i3

Concept: Circuit
Solution:
 =4+2=6

=
Final Answer: (1.15)

5) Explain Question: Find unknown resistance

Concept: Meter bridge
Solution:

Initially, …(1)

Finally, …(2)
Divide (2) by (1)

⇒
∴ x = 5P = 5 × 4 = 20 Ω
Final Answer: (20.00)

6) Explain Question: Find potential difference between the spheres

Concept: Potential difference
Solution:
potential difference due to inner 10C charge

= K 10 = 9 × 1010 (5)
= 45 × 1010 = 4.5 × 1011 V
potential difference due to outer charge = 0

∴ p.d. = 4.5 × 1011 V

Final Answer: (4.50)

7) Explain Question: Find force on dipole due to point charge

Concept: Dipole
Solution:
Force on dipole due to point charge is same as force on point charge due to dipole so

so N = 3
Final Answer: (3.00)
8) Explain Question: Find the speed of the particle
Concept: Gravitational force
Solution:

Final Answer: (4.00)

9) Explain Question: Find the surface gravitational field and escape velocity
Concept: Gravitational force
Solution:

Hence &

Also
Final Answer: (B,C,D)

10) Explain Question: Choose the correct options of spherical object

Concept: Potential
Solution:
AC = 5m

= 1.8 × 103 = 1.8 kV

VB = (VB)due to q + (VB)i
(VB)i= – 0.45 kV
So (A) and (C) are correct.
Final Answer: (A,B)

11) Explain Question: Select correct alternatives for point lying on x-axis.
Concept: Electric field and potential
Solution:
Field will be O at one point and potential at 2 points. E is towards + x between charges. Field
will be O at one point and potential at 2 points. E is towards + x between charges.
Final Answer: (A,C,D)

12) Explain Question: Find range and wall point of potentiaometer

Concept: Potentiometer
Solution:

(A) VAB =

VAB =

(C) ε' = (i)

= (i)
Final Answer: (A,C)

13) Explain Question: Galvanometer as ammeter

Concept: Galvanometer
Solution:

For ammeter &

Final Answer: (B,D)

14)

Explanation:
In this question, a lead ball is projected at an angle of 60° with initial speed 100 m/s toward a
vertical cliff 150 m away. The time taken to reach the cliff and the vertical miss distance from
the target are to be found.

Concept:
This question is based on projectile motion under gravity.
 Solution:

x = 150cos 60° = 75 m
75 = x = (ucos60°)t
75 = 50 t

= 1.5 second
vertical component of velocity = 100sin 60 = m/sec
vertical distance covered in this time

y = uyt –

y=

target height

The distance by which lead ball misses the target = 129.9 – 118.65 = 11.25m

Final Answer Option (1),(4)

15) Explain Question: Match List-I with II

Concept: x-t graph
Solution:
With particle going towards origin position decreases and vice-versa.
Final Answer: (A)

16) Explain Question: Match List I to II

Concept: Conductors
Solution:
As potential of left most plate is zero. By using Gauss law we get above options.
Final Answer: (C)

17) Explain Question: For geostationary satellite match the column

Concept: Kepler's law
Solution:
For geo-stationary satellite, time period of satellite equals to time period of rotation of planet
about its axis.
Also for it,

Any process changing ωplanet will charge the height of satellite for it to remain geo-stationary.

Total energy is directly proportional to object mass.

Final Answer: (B)

18) Explain Question: Match column I to II

Concept: Current electricity
Solution:
From the given information,

(A) When S1 is open & S2 is closed, circuit reduces to

(B) When S1 is closed & S2 is open, circuit reduces to

(C) When both are closed, circuit reduces to

(D) When both are open, circuit reduces to

 Final Answer: (B)

PART 2 : CHEMISTRY

19) Explain Question: Calculate the rate of reaction when [A] = 0.1 M
Concept: nth order kinetics
Solution:
Let initial concentration of A is [A0]

Rate =

= (n–1) 3kt

According to graph

n–1 = 3 n=4 Slope = tan45° = 1

Slope = (n–1) 3k

1=3×3×k

k=

Rate = k[A]4

= × [0. 1]4 = × 10–4

Final Answer: (0.11)

20)

Explaining the Question :- Find initial concentration

Concept:- This question is based on Zero order reaction
Solution :- Zero order reaction :
Ct = CO – Kt
CO = Ct + Kt
= 0.5 + 2 × 10–2 × 25
= 0.5 + 0.5
=1M

Final Answer : 1.0

21) Explain Question: Find the rate of disappearance of C2H6O at the same time
Concept: Rate of reaction
Solution:
=

⇒ = rate of disappearance of C2H6O.

⇒ Rate of disappearance of C2H6O = 4.005 mol/min
Final Answer: (4.00)

22) Explain Question: Calculate x given that and fill the answer as .
Concept: 1st order reaction
Solution:

Final Answer: (2.00)

23)

Explain Question: Calculate mass of CaBr2 (in gram) required in 960 gm of solution to have a
depression in freezing point of solution equal to 2K.
Concept: Depression in freezing point
Solution:
ΔTf = i Kfm

2=

960 – w = 3 × (500)
960 = 16w
w = 60 gm
Final Answer: (60.00)

24) Explain Question : Final Ecell

Concept : Metal- metal in insoluble salt
Soluiton:

= 0.0591 × 10
= 0.591 V
Final Answer: (0.59-0.60)

25) Explain Question: Find the number of correct statements

Concept: Coordination compounds
Solution:

Final Answer: (4.00)

26) Explain Question:

Calculating the oxidation state of Molybdenum in a complex.

Concept:
Oxidation State in Coordination Compounds.

Solution:
The sum of the oxidation states of all atoms in a complex equals the net charge. Oxygen is –2,
while neutral ligands like C2H4 and H2O are 0.
Calculation:
Let oxidation state of Mo be x.

Final Answer: 3

27) Explain Question: Find the correct statement(s)

Concept: Preparation of KMnO4
Solution:

∵ In acidic solution; Y undergoes disproportionation reaction

Hybridization of MnO4- and MnO42– is d3s
Final Answer: (BCD)

28) Explain the question : To find correct statement.

Concept : This question is based on electron gain enthalpy.
Solution :
is generally negative but always positive
Final answer : 1, 3

29) Explain Question: In halogens, which of the following properties increase from iodine to
fluorine
Concept: Properties of halogens
Solution:

Final Answer: (AB)

30)

Question Explanation:
Select the correct option for α-particle.

Concept:
This question is based on Rutherford model.

Solution:
(1) (K.E.)initial = (P.E.)at distance of closest approach

or 4.0 MeV = K.

or, 4 × 106 × 1.6 × 10–19

= 9 × 109 ×

∴ Distance of closest approach, r = 3.6 × 10–14 m

(2) P.E. = K.

= 9 × 109 ×

= 1025 × (1.6 × 10–19)2 J

= = 1.6 MeV
(3) P.E. = K .

=
= 3.2 MeV

∴ K.E. of α-particle at this distance

= 4.0 –3.2 = 0.8 MeV

(4) r = 2 × 10–16 m which is less than closest distance
approach ⇒ not possible

Final Answer:
The correct options are (1, 2 & 3).

31) Question Explanation:

Question is asking about following statement(s) is(are) true for the state Ψ

Concept:
This question is based on angular and radial nodes

Solution:

# –3.4 = ⇒n=4
# =2
# m=0
Angular nodes = = 2
Radial nodes = (n – – 1) = 1
For n and value so it is 4d state

Final Answer:
The correct option are (1) & (3)

32) Question Explanation:

Select correct statement(s).

Concept:
This question is based on C.F.T.

Solution:
(1) Electronic configuration of central metal atom in both cases is [Ar]3d10 4s24p6 (8 electrons
in outermost shell and 18 valence electrons respectively).
(2) These are low spin in nature due to the presence of strong field ligand
(3) As density of electron increases on the metal, extent of Synergic bonding increases hence
strengthen the metal- carbon bond
(4) As M-C bond order , CO bond length

Final Answer: Option (2, 3)

33)

Explain Question: Match list - I with list -II

Concept: Conductometric titration
Solution:
Option (P) :
On adding AgNO3 solution to KCl solution precipitation of AgCl will occur due to which Cl–
already present will be replaced by NO3– ions. So conductance of solution will decrease till
equivalence point. After complete precipitation of AgCl, further added AgNO3 will increase the
number of ions in resulting solution so conductance will increase.
Option (Q) :
On adding KCl solution to AgNO3 solution precipitation of AgCl will occur due to which already
present Ag+ ions will be replaced by K+ ions in solution. So conductance of solution will
increase. After complete precipitation of AgCl further added KCl will increase the number of
ions in resulting solution so conductance will increase further.
Option (R) :
On adding HCl solution to NaOH solution, OH– will be replaced by Cl– ions so conductance of
solution decreases. After complete neutralisation further added HCl will increase number of
ions in the solution. So conductance will increase futher.
Option (S) :
On adding CH3COOH solution to NaOH solution OH– will be replaced by CH3COO– ions, so
conductance of solution decreases. After complete neutralisation further added CH3COOH will
remain undissociated because it is a weak acid and there is also common ion effect on acetate
ions. So number of ions in solution will remain almost constant therefore conductance of
solution will remain constant.
Final Answer: (C)

34) Explain Question: Match list - I with list - II

Concept: Kinetics of zero, 1st, 2nd order reaction.
Solution:

(A) Zero order reaction → [P] tcomp. =

complete in finite time.

[Q] v/s t for zero order “n = 0”

At v/s t is straight line between “[At] ∝ t”
(B) Ist order reaction →
[S] rate of reaction change directly with change in conc. of reactant
[T] It may be elementary on complex reaction.
(C) IInd order reaction →

[Q] [At] ∝ so for n = 2 graph will show straight line.

0
[R] so t1/2 increases on decreases [A ]
[S] rate of reaction decreases during reaction.
(D) Half order reaction →
[P] Reaction completes infinite time.

[Q] At ∝ t for half order so graph between vs t will be straight line

 [S] ROR decreases during reaction.
Final Answer: (A)

35) Explain Question: Match column - I with column - II

Concept: Ideal and non-ideal solutions.
Solution:
(A) Acetone + CHCl3 –ve devation from Raoult’s law ΔS > 0
ΔH < 0 ΔV < 0
Maximum Boiling Azeotropes.
(B) Ethanol + Water +ve Deviation from Raoult’s law ΔS > 0
ΔH > 0 ΔV > 0 Minimum Boiling Azeotropes
(C) C2H5Br + C2H5I Ideal solution No Azeotropes
ΔH = 0 ΔV = 0
(D) Acetone + Benzene +ve Deviation from Raoults law
ΔH > 0 ΔV > 0 ΔS > 0
Minimum Boiling Azeotropes
Final Answer: (B)

36) Explain Question:

Matching chemical reactions with their observations or types.

Concept:
Reactions of d-Block Elements, redox reaction.

Solution:
(P)

(Q)

(R) MnO2 + conc. KOH + O2 K2MnO4 + H2O

(S)

Final Answer: Option (3)

PART 3 : MATHEMATICS

37) Explain Question : Given a polynomial f(x) bounded by two linear functions, you must
find its specific form to evaluate a limit in the form and calculate the minimum value of p
+ q.
Concept : Squeeze Theorem (Sandwich Theorem) for polynomials, limit definition of e, and
properties of polynomial functions.
Solution :

ƒ(x) is polynomial

⇒
As exist

;c=1

Final Answer : (5.00)

38) Explain Question : Find the limit as x approaches 0 for a function involving the Greatest
Integer Function [.] and fractional part of .
Concept : Limits of trigonometric functions, properties of Greatest Integer and Fractional
Part functions, and the limit form.
Solution :

Final Answer : (3.00)

39) Explain Question : Identify the total number of points in the interval [0, 2π] where the
greatest integer function of (sin x + cos x) is discontinuous.
Concept : Continuity of composite functions involving the Greatest Integer Function; points
where the inner function (sin x + cos x) results in an integer.
Solution :
f(x) = [sin x + cos x] will be discontinuous at those points,
where sin x + cos x is an integer, i.e.

∴ number of points at which f(x) is discontinuous is 5.

Final Answer : (5.00)

40) RHL

= f(0+) = f(0) = a

= f(0+) =
LHL

(1∞ form)
∴ f(0) = 6(0+) = 6(0–)

⇒a= =e

⇒ (a, b) =

∴ a2.b2 = e2 . =1

41) Explain Question : Given a, b and c as roots of a cubic equation, calculate the sum of
their reciprocals and the sum of the squares of their reciprocals.
Concept : Vieta’s Formulas (sum and product of roots) and algebraic manipulation of
symmetric polynomial expressions.
Solution :
a + b + c = 2 ; ab + bc + ca = 0 ; abc = –1

= 0 + (ab + bc + ca)2 – 2abc(a + b + c)

= 0 – 2(–1)(2) = 4
Final Answer : (4.00)

42) Explain Question : Find the value of for a quadratic equation where the roots,
after subtracting 2, become the reciprocals of the original roots.
Concept : Relation between roots and coefficients of a quadratic equation and solving radical
equations for distinct roots.
Solution :
Let α,β be roots of x2 + bx + c = 0
α + β = –b ....(1)
αβ = c ...(2)

Now, α–2 = & β–2

2
⇒ α – 2α – 1 = 0

⇒ α=

Slly,
∴ Either &
(∵ Distinct roots)
OR
&
From (1) b = (α + β)2 = (2)2 = 4
2
From (2) c2 = (αβ)2 = (12 – ( )2)2 = 1 ∴
Final Answer : (1.00)

43) Explain Question : Solve a system of three logarithmic equations for variables x, y, z to
find the product k of all possible values of a specific log expression.
Concept : Properties of logarithms (product, power, and base change) and solving systems of
non-linear algebraic equations.
Solution :

Final Answer : (5.00)

44) Explain Question : For an onto function f with defined domain and range, find the sum of
the boundary values (α + β) for the domain and range of (f(2x))2.
Concept : Domain and Range transformations, properties of onto (surjective) functions, and
the effect of squaring and horizontal scaling on functions.
Solution :

Final Answer : (2.00)

46) Explain Question : Evaluate a limit involving inverse trigonometric functions at infinity to
find possible values for y in a quadratic equation.

Concept : Limits at infinity, inverse trigonometric identities , and solving

quadratic equations.
Solution :

y2 + 4y + 5 =

=
Final Answer : (B, D)

47)

Explain Question:
Find point of discontinuity of the given function at the given points.
Concept:
Use R.H.L., L.H.L. & GIF concept.
Solution:
At x = –1

∴ Not continuous at x = –1
At x = 0

∴ Continuous at x = 0
At x = 2

∴ Not continuous at x = 2
at x = 1

∴ Not continuous at x = –1
Final Answer: Option (A), (C), (D)

48) Explain Question : Determine the possible values for α, which is the sum of two
sec-1 functions with specific constraints on variables x and y.
Concept : Range of Inverse Trigonometric functions (sec-1), trigonometric inequalities, and the
AM ≥ GM inequality for (sin x + csc x).
Solution :

As

as

Final Answer : (B, C)

49)

50) A. f(x) ≥ 0 ∀ x ∈ R D≤0 K (4K − 1) ≤ 0 .

B. K < 0 product of roots < 0
C. for roots ∈ (0, 1), D > 0 K(4K − 1) > 0,

f(0) > 0 K > 0, and f(1) > 0

D. Min. value

51) (P)

= =1

(Q)

= –

(R) (ln sin3x – ln(x4 + ex3))

= = ln = –1

(S) Let f(n) = + ...... +

Let g(n) = + ...... +

=
(substituting the value of Σn2 and Σn and simplifying)

52) (P) x = 1 + cot2 (cot–1 3) – 1 – tan2 (tan–1 2) = 9 – 4 = 5

(Q) tan–1 = tan–1 3 if 1 – x/y > 0

⇒ x + 1/y = 3(1 – x/y) ⇒ x =

y2 + y – 56 = 0 ⇒ (y + 8) (y – 7) = 0
⇒ y = – 8 or 7
⇒ x = 5 or x = 2
(R) cos–1 x = tan–1 (tan θ) where y = tan θ

⇒ x = cos θ =
⇒ x = ± 1/2

(S) sin–1 (1) – sin–1 – π/6 = 0

⇒ = sin–1

⇒ sin (π/3) = ⇒
⇒ y = 4 ⇒ x = ± 2.

53) (P) ƒ : R → R+ ƒ(x) = e[x]+{x}

= ex
one-one & onto
2
(Q) ƒ(x) = ℓn(x + 2x)
many-one
Range ≡ (–∞, ∞)
onto
(R) ƒ : [–2, 2] → [–1, 1] ƒ(x) = sinx

many-one, onto, aperiodic because domain is bounded

(S) ƒ : R → R ƒ(x) = x3 – 3x2 + 3x – 7
ƒ′(x) = 3x2 – 6x + 3
D=0
So function is one-one
onto

54) (P)
when sin2x = –1
(Q) log(2log2) + log(2log5)
= logλ + log(log2) + log(log5)
log2 + log2 = logλ ⇒ λ = 4

(R)
x2 + 1 < 3x2 – 7x + 8 ≤ 2x2 + 2
2x2 – 7x + 7 > 0 ⇒ x ∈ R ...(1)
x2 – 7x + 6 ≤ 0 ⇒ x ∈ [1,6] ...(2)
(1) ∩ (2) x ∈ [1,6]

(S)
log5 = loga ⇒ a = 5