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The document contains a series of physics and chemistry problems related to mechanics, optics, and crystallography, along with mathematical questions involving functions and relations. Each section presents multiple-choice questions that require the application of scientific principles and mathematical concepts. The problems cover a range of topics, including equilibrium of systems, projectile motion, properties of lenses, and properties of crystal structures.

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0% found this document useful (0 votes)
4 views35 pages

Solution

The document contains a series of physics and chemistry problems related to mechanics, optics, and crystallography, along with mathematical questions involving functions and relations. Each section presents multiple-choice questions that require the application of scientific principles and mathematical concepts. The problems cover a range of topics, including equilibrium of systems, projectile motion, properties of lenses, and properties of crystal structures.

Uploaded by

atlrobocreators
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

19-04-2026

1752CJA101021260006 JA

PART-1 : PHYSICS

SECTION–I (i)

1) All pulleys and strings are massless, for what ratio of m1 : m2 : m3 system will be in equilibrium

(incline is frictionless)

(A) 1 : 2 : 1
(B) 2 : 2 : 1
(C) 1 : 2 : 2
(D) 2 : 1 : 2

2) A projectile is projected at an angle of elevation . After t seconds, it appears to have an angle of


elevation as seen from the point of projection. Which of the following are incorrect:

(A) the y-coordinate of the position of the projectile at time t is , where v is the
velocity of projection
the x-coordinate of the position of projectile at time t is , where v is the velocity of
(B)
projection

(C)
, where v is the velocity of projection

(D)
velocity of projection is

3) A sphere of mass 'm' is kept in equilibrium with the help of several springs as shown in the figure.
Measurements show that one of the springs applies a force on the sphere. With what acceleration

the sphere will move immediately after this particular spring is cut?
(A) Zero

(B)

(C)

(D) Insufficient information

4)

Two particles of mass m each are tied at the ends of a light string of length 2a. The whole system is
kept on a frictionless horizontal surface with the string held tight so that each mass is at a distance
'a' from the centre P (as shown in the figure). Now, the mid-point of the string is pulled vertically
upwards with a small but constant force F. As a result, the particles move towards each other on the
surfaces. The magnitude of acceleration, when the separation between them becomes 2x, is

(A)

(B)

(C)

(D)

SECTION–I (ii)

1) The focal length of a thick glass lens in air with refractive index n, radius of curvatures r1, r2 and

vertex distance d as shown in figure is given by :

Remark : ri > 0 means that the central curvature


point Mi is on the right side of the aerial
vertex Si, ri < 0 means that the central curvature point Mi is on the left side of the aerial
vertex Si (i = 1,2). For some special applications it is required, that the focal length is independent
from the wavelength. Choose the CORRECT statement(s) :
(A) There are atmost two different wavelengths for which the same focal length can be achieved.

(B) If r1 – r2 = d , then focal length will be same for two wavelength. (n1 and n2
are refractive index for two wavelength being consider)
(C) For a given plano-convex lens, a specific focal length can be achieved by only one wavelength.
(D) There are atmost three different wavelengths for which the same focal length can be achieved.

2) A thin equiconvex spherical glass lens (μ = 3/2) of radius of curvature 30 cm is placed on the x-
axis with its optical centre at x = 40 cm and principal axis coinciding with the x-axis. A light ray
given by the equation 39y = -x + 1 (x and y are in cm) is incident on the lens, in the direction of
positive x-axis. Then choose the correct alternative(s).

(A) The equation of refracted ray is 39y = x + 1


(B) The equation of refracted ray is 130y = x - 170
The equation of refracted ray if space on right side of the lens is filled with a liquid of refractive
(C)
index 4/3 is 390 y + x + 350 = 0.
The equation of refracted ray if space on right side of the lens is filled with a liquid of refractive
(D)
index 4/3 is 390y – x + 350 = 0.

3)

For an isosceles prism of angle A and refractive index µ, it is found that the angle of minimum
deviation δm = A. Which of the following options is/are correct ?

At minimum deviation, the incident angle i1 and the refracting angle r1 at the first refracting
(A)
surface are related by r1 = (i1/2)

(B)
For this prism, the refractive index µ and the angle of prism A are related as
For this prism, the emergent ray at the second surface will be tangential to the surface when
(C)
the angle of incidence at the first surface is
(D) For the angle of incidence i1 = A, the ray inside the prism is parallel to the base of the prism.

4) The refractive indices of the crown glass for violet and red lights are 1.51 and 1.49 respectively
and those of the flint glass are 1.77 and 1.73 respectively. A narrow beam of white light is incident
at a small angle of incidence on the shown combination of thin prisms. The value of α is chosen such

that the mean deviation of the incident beam is zero.

(A) α = 4°
(B) Dispersion = 0.04°
(C) α = 2°
(D) Dispersion = 0.02°

5) In the figure shown A ring has uniformly distributed charge. Along its axis an oppositely charged
rod of small length is kept. It is released from the position shown. Only electric force due to ring acts

on the rod. Ring is kept fixed. Which of the following is wrong ?

(A) The rod will perform oscillation but not SHM.


(B) The rod will perform SHM if it is uniformly charged.
(C) The rod may perform SHM if it is non-uniformly charged.
(D) The rod will perform oscillations only if the rod is uniformly charged.

6) In the situation shown in figure, a particle having charge q = 2 C and mass = 1 kg is projected
from bottom of an inclined plane of inclination 45º at an angle 45º with horizontal, so that the
particle graze the inclined plane horizontally due to a uniform horizontal electric field E.

(A)
Particle grazes the inclined plane at t = sec
(B) Value of E = 15 N/C
(C) Value of E = 60 N/C
(D) Speed of particle at the time of grazing is

7) A cuboid of dimension [a × a × b]. Charge q is placed at the centre of edge having length ‘b’. If

flux through face ‘ABCD’ is then select the correct statement(s) :-

(A)
Flux through the entire cuboid is
(B) Flux through the face ‘ABEH is zero.
(C)
Flux through the face ‘BEFD’ is

(D)
Flux through the face ‘BEFD’ is

8) A semi-circular ring of mass m and radius R with linear charge density –λ, hinged at its centre
with the help of a massless spoke as shown is placed in a uniform electric field as shown in the
figure. If the ring is slightly rotated about O in the plane of paper and released. Take m = 8kg, λ =

2C/m and E = 2N/c.

(A) ring will perform angular SHM


(B) the time period of oscillation is 2π sec.
(C) shown position is unstable equilibrium
(D) for large angular displacement motion will still be SHM

SECTION–II

1) Two equilateral-triangular prisms P1 and P2 are kept with their sides parallel to each other, in
vacuum, as shown in the figure. A light ray enters prism P1 at an angle of incidence q such that the
outgoing ray undergoes minimum deviation in prism P2. If the respective refractive indices of P1 and

P2 are and , then q = sin−1 , where the value of β is __________.

2) In a compound microscope, the magnified virtual image is formed at a distance of 25 cm from the
eye-piece. The focal length of its objective lens is 1 cm. If the magnification is 100 and the tube
length of the microscope is 20 cm, then the focal length of the eye-piece lens (in cm) is ________.

3) A charge q is kept just outside a cube on extension of digonal GA. The magnitude of electric flux
of side ABCD is . Find value of α.

4) As shown in the figure. a configuration of two equal point charges (q0 = +2µ C) is placed on an
inclined plane. Mass of each point charge is 20 g. Assume that there is no friction between charge
and plane. For the system of two point charges to be in equilibrium (at rest) the height h = x × 10–3
m
The value of x is ____.

(Take )

5) On a smooth horizontal surface we have a point charge attached to the free end of a massless rod
hinged at other end as shown. We apply a uniform electric field (E) and slightly deflect the rod. The
force on charge accelerate it during half rotation then the direction of electric field is suddenly
reversed, so that the charge remain accelerating, assuming q = 1C, m = 1kg E = 1N/C, length of rod
L = 1m. The total angle rotated when the point charge attains a speed of 5 m/s is 38 π/n. Then the

value of n is ____.

6) μ = 0.2 at each contact surface


Find Fmin (in N) to start the motion of C towards left.

PART-2 : CHEMISTRY

SECTION–I (i)
1) Which of the following carbocation is less stable than :

(A)

(B)

(C)

(D)

2)

Identify the strongest base from the given compounds :-

(A)

(B)

(C)

(D) All have same basic strength

3) KCl crystallizes in the same type of lattice as does NaCl. Given that and
, calculate the ratio of the edge length of unit cell for KCl to that for NaCl :-

(A) 1.143
(B) 1.224
(C) 1.414
(D) None

4) Analysis shows that nickel oxide has formula Ni0.98 O1.00. What fractions of the nickel exist as
Ni+2 and Ni+3 ions respectively (approx) :-

(A) 4% and 96%


(B) 96% and 4%
(C) 92% and 8%
(D) 8% and 92%

SECTION–I (ii)

1) A metal crystallises as BCC lattice. Find the % fraction of edge length not covered and also %
fraction of edge length covered by atom is :

(A) 10.4%
(B) 13.4%
(C) 86.6%
(D) 11.4%

2) Potassium crystallizes in a body centered cubic lattice with edge length a = 5.0Å. Then choose the
correct statements in given option -

(A) The number of nearest neighbours to any K atom is 8


(B) The number of next nearest neighbours to any K atom is 6
(C) Distance between nearest neighbours is 4.33 Å
(D) Distance between next nearest neighbours is 5.0Å

3) Select the correct statement about FCC (ABCAB...) structure.

(A)
Distance between nearest octahedral void and tetrahedral void is

(B)
Distance between two nearest octahedral void is

(C)
Distance between two nearest tetrahedral void is
Distance between layer A and B is 2r
(D)

4) Select the correct statement (s) :

(A) NaCl lattice may form Schottky defect


(B) ZnO lattice may form non-stoichiometric defect
(C) One NaCl unit cell contains 4Na⊕ and 4Cl⊝ ions effectively
(D) Truncated octahedron has 24 corners.

5) Which of the following represent octahedral void?


(A)

(B)

(C)

(D)

6) Which among the following will not show anisotropy ?

(A) Glass
(B) NaBr
(C) Plastic
(D) Rubber

7) Which of the following statements is/are correct :

(A) In an anti-fluorite structure anions form FCC lattice and cations occupy all tetrahedral voids.
If the radius of cations and anions are 0.2 Å and 0.95 Å then coordinate number of cation in the
(B)
crystal is 4.
(C) Each sphere is surrounded by six voids in two dimensional hexagonal close packed layer
(D) 8 Cs+ ions occupy the second nearest neighbour locations of a Cs+ ion in CsCl structure

8) Which of following is/are correct order :

(A) –CH3 < –CD3 < –CT3 : +I effect


(B)
: –I effect
(C) –NO2 > –CN > –F : – I effect

(D)

SECTION–II

1) Find number of compound which can show tautomerism :

(I) (II) (III) (IV)

(V) CH3 – CH2 – NO (VI) (VII)

2) Find number of compound which are soluble in NaOH as well as NaHCO3 ?

(i) (ii) (iii) (iv)

(v) CH3OH (vi) (vii) (viii)

3) How many statement are true? a) (I) and (III) are modest Bronsted
bases whereas (II) is not
b) In (III) Na is more basic than Nb
c) When (II) is protonated in the presence of a strong acid, protonation occurs at C-2
d) All the nitrogen present in (I), (II), and (III) is 2 hybridised

4) How many from the following properties are correct?


(i) > (Stability order)

(ii) > (Stability order)

(iii) > > (HOC order)

(iv) > > (HOH order)

(v) > > (C=C bond length order)

5) How many of the following groups show +I effect?


(a) –NH2 (b) –CD2–CHD2 (c) –CHMe2
(d) –OCH3 (e) –N = O (f) –CH = CH2
(g) –C ≡ CH (h) (i) –COO⊖

6) An element X(atomic wt. = 125) crystallises is simple cubic structure. If diameter of the largest
atom which can be placed without disturbing unit cell is 366 pm. Find the density of pure element X
in g/cm3.
[Given: = 1.732, NA = 6 × 1023]
[Fill your answer by multiplying it with 300.]

PART-3 : MATHEMATICS

SECTION–I (i)

1) Domain of the function is -

(A)
(B)
(C)
(D)
2) If a is even natural number, b is odd natural number and

(where [x] represents greatest integer function of x), then k1 + k2 equals

(A) 2
(B) 3
(C) 4
(D) 5

3) Let R be a relation from A = {2,3,4,5} to B = {3,6,7,10} defined by R = {(a,b) | a divides b, a ∈ A,


b ∈ B}, then number of elements in R–1 will be :

(A) 0
(B) 3
(C) 4
(D) 5

4) Consider a circle on the xy-plane : x2 + y2 = 9. Then minimum distance between the circle and the
plane 2x + y + z – 16 = 0 is

(A)

(B)

(C)

(D)

SECTION–I (ii)

1) In ℝ3, consider the planes P1 : y = 0 and P2 : x + z = 1. Let P3 be a plane, different from P1 and P2,
which passes through the intersection of P1 and P2. If the distance of the point (0,1,0) from P3 is 1
and the distance of a point (α,β,γ) from P3 is 2, then which of the following relations is (are) true ?

(A) 2α + β + 2γ + 2 = 0
(B) 2α – β + 2γ + 4 = 0
(C) 2α + β – 2γ – 10 = 0
(D) 2α – β + 2γ – 8 = 0

2)

Let the unit vectors a and b be perpendicular and the unit vector c be inclined at an angle θ to both
a and b. If (α,β,γ are scalars) then

(A)
(B)
(C)
(D)

3) x1, x2, x3 are three real numbes satisfying the system of equations
x1 + 3x2 + 9x3 = 27, x1 + 5x2 + 25x3 = 125 and x1 + 7x2 + 49x3 = 343, then which of the following
options are correct

(A) Number of divisors of x1 + x3 is 16

(B)
is a prime number
(C) x3 – x2 is a prime number
(D) x1 + x2 + x3 is square of an integer

4) Let ƒ(x) = x4 – 6x2 – 8x, then-

(A) ƒ(x) = 0 have exactly 2 distinct real solution


(B) ƒ(x) = 0 have exactly 4 distinct real solution
(C) ƒ(ƒ(x)) + 24 = 0 have exactly one real solution
(D) ƒ(ƒ(x)) + 24 = 0 have exactly two distinct real solution

5) The values of x satisfying the equation is -

(A)

(B)

(C)

(D)

6) For the function ƒ(x) = |x + 3| – |x + 1| – |x – 1| + |x – 3|, identify correct option(s)

(A) Range of ƒ(x) is (–∞, 4]


(B) maximum value of ƒ(x) is 4
(C) ƒ(x) = 4 has infinite solutions
(D) ƒ(x) = 0 has infinite solutions

7) Which of the following is/are correct ?

(A) f : R → R, f(x) = 3x + sin x is bijective function


(B) f : R → R, f(x) = 3x3 – 2x2 + x is bijective function
(C)
f : R – {2} → R–{1}, is bijective function

(D)
f : R → R, is bijective function

8) Let ƒ : {1,2,3,4,5} → {1,2,3,4,5} is such that ƒ(x) is a one-one function satisfying following
condition
ƒ(x) = x + 1 if and only if x is even (i.e. ƒ(3) ≠ 4, ƒ(4) = 5 etc). Then ƒ–1(2) can be-

(A) 1
(B) 3
(C) 5
(D) 2

SECTION–II

x 2
1) Number of real solutions of the equation 2(2 – 1)x + is equal to

2) If equation e2x + (k – 1)ex+1 + k = 0 has roots of opposite sign, then [k] is equal to
(where [.] denotes greatest integer function)

3) Let ℝ. If for some , then n + a + b is equal


to.

4) Let be position vector of a variable point in xy-plane such that and

and .
Also let , , be vectors represent three co-terminus edges of a tetrahedron such that

and . If V is the volume of the


tetrahedron, then the value of (2V + 5) is

5) Let l1 be the line in xy-plane with x and y intercepts and respectively, and l2 be the line in

zx-plane with x and z intercepts and respectively. If d is the shortest distance between the
line l1 and l2, then d–2 is equal to
6) The shortest distance between (1 – x)2 + (x – y)2 + (y – z)2 + z2 = and 4x + 2y + 4z + 7 = 0 in 3-
dimensional coordinates system is equal to
ANSWER KEYS

PART-1 : PHYSICS

SECTION–I (i)

Q. 1 2 3 4
A. B C C B

SECTION–I (ii)

Q. 5 6 7 8 9 10 11 12
A. A,B,C B,C A,C,D A,B B,D A,B,D A,B,C A,B

SECTION–II

Q. 13 14 15 16 17 18
A. 12 5 7 300 6 76

PART-2 : CHEMISTRY

SECTION–I (i)

Q. 19 20 21 22
A. A A A B

SECTION–I (ii)

Q. 23 24 25 26 27 28 29 30
A. B,C A,B,C,D A,B,D A,B,C,D A,C A,C,D A,C A,C,D

SECTION–II

Q. 31 32 33 34 35 36
A. 4 4 3 3 4 500

PART-3 : MATHEMATICS

SECTION–I (i)

Q. 37 38 39 40
A. C B D A

SECTION–I (ii)

Q. 41 42 43 44 45 46 47 48
A. B,D A,D A,B,D A,D A,C,D B,C,D A,B,C B,C
SECTION–II

Q. 49 50 51 52 53 54
A. 3 0 24 21 51 2
SOLUTIONS

PART-1 : PHYSICS

1)

Explanation Question: The problem asks for the ratio of masses m1 : m2 : m3 for the system
to be in equilibrium, assuming all pulleys and strings are massless and the incline is
frictionless.

Concept: This question is based on application of forces, NLM


Solution:
T = m1g sin 30°, T = m3g, 2T = m2g

m1 : m2 : m3 =
=2:2:1
Final Answer option : (2)

2)

3) Question Explanation:
The problem asks to find acceleration of the sphere immediately after this particular spring is
cut.

Concept:
This question is based on Newton's second law, Principle of equilibrium.

Solution:
For equilibrium, we have

When spring is cut, then force by rest of spring will – F

Final Answer:
The correct option is (3).

5) (A) The refractive index n is a function of the wavelength λ, i.e. n = n (2). According to the
given formula for the focal length f (see above) which for a given f yields to an equation
quadratic in n there are at most two different wavelengths (indices of refraction) for the same
focal length. (B) If the focal length is the same for two different wavelengths, then the
equation f(λ1) = f(λ2) or f (n1) = f(n2)
holds. Using the given equation for the focal length it follows from equation (1) :
Algebraic calculations lead to :

6)
The ray is intersecting y = 0 line at x = 1 and x = 40 line at y = –1.
∴ u = 39 cm

∴ Equation of refracted ray is 130 y = x – 170 If space on the right of the lens is filled with
liquid of μ = 4/3, then

v = – 390 cm
∴ Equation of refracted ray is
∴ (B) and (C)

7)

At minimum deviation, the incident angle i1 and the refracting angle r1 at the first refracting
surface are related by r1 = (i1/2).
For this prism, the emergent ray at the second surface will be tangential to the surface when

the angle of incidence at the first surface is .


For the angle of incidence i1 = A, the ray inside the prism is parallel to the base of the prism.

8) Question Explanation:
Find the prims angle a and the set dispersion for a combination of Crown and flint glass prisms
arranged to produce dispersion without mean deviation.
Concept:
Dispersion Without Deviation The condition where the net mean deviation is zero ,
but the net dispersion is non-zero. Formula: .
Solution:
Crown Glass Parameter: Mean index:

Refractive difference:
Total Prism Angle (From diagram):

Flint Glass Parameters: Mean index:


Refractive difference:

Prism Angle
Aflint= α
Calculate Agnel α: Apply the condition for zero mean deviation (Magnitudes must be equal):

(1.50 – 1) × 6° = (1.75 — 1) × α
0.5 × 6 = 0.75 × α
3 = 0.75α
α = 4°
Calculate Net Dispersion: The net dispersion is the difference between the individual
dispersions:

Final Answer:
Option 1 and 2

9)

For S.H.M. F ∝ –x else it will oscillate.

10)

11)
Total flux through cube =

ϕABCD = ϕGFEH = & ϕBEFD = ϕCGFD & ϕABEH = ϕAHGC = 0

ϕABCD = ϕGFEH + ϕBEFD + ϕCGFD =

12)

Put I = mR2

13)
At surface BC,

sinr2 =
r2 = 45°
r1 = 60° – 45° = 15°
At surface AB,

1 sin θ =

θ=
β = 12
14)

for first lens =

also magnification |m1| =


for 2nd lens this is acting as object

so u2 = –(20 – v1) = –
and v2 = –25cm

angular magnification |mA| =


Total magnification m = m1mA = 100

⇒ 76x = 81 ⇒ x =

⇒ u2 = –
now by lens formula

15) ϕnet = 0

ϕDCGH = ϕEFGH = ϕBCGF =

ϕABCD = ϕADHE = ϕABFE =

16) For equilibrium along the plane

= 300 mm
17) At each reversal, work done by electric force = qE(2L), and KE keeps on increasing after N

reversal, work done = NqE(2L) =

work done in rotating θ angle,

F × L(1 – cos θ) = ΔKE =


so total work done,

NqE(2L) + F × L(1 – cosθ) =


& F = qE,

we get v2 =

for v = 5 ; N = 6 and θ =

so, total angle rotated is, =

PART-2 : CHEMISTRY

19) A is unstable due to anti-aromaticity.

20)
EN ↑
B.S ↓

21) Question Explanation:


Calculate the unit cell edge length ratio for KCl and NaCl.
Concept:
Radius Ratio and Unit Cell Edge Length Solution: Both NaCl and KCl crystallize in the Rock
Salt (fcc) structure. In this arrangement, the edge length of the unit cell (a) is twice the sum of
the radii of the cation and the anion. For NaCl-type structure: a = 2(r+ + r-)

Divide the numerator and denominator by rNa : +


Given: Given:

Rounding to three decimal places gives 1.143.


Final Answer: Option (1)

22) From the given formula it is clear that for every 100 oxide ions there are only 98 nickel
ions. Suppose, out of 98 nickel ions x exist as Ni+2 and the remaining (98 – x) exist as Ni+3.
Total positive charge on 98 nickel ions
= x × 2 + (98 – x) × 3 = 2x + 3 (98 – x)
Total negative charge on 100 oxide ions
= 100 × 2 = 200
Due to electrical neutrality 2x + 3 (98 – x) = 200
x = 94
∴ Fraction of nickel as Ni+2 =
and Fraction of nickel as Ni+3 = 100 – 96 = 4%

23)
also, edge length of unit cell = a
radius of atom = r
∴ Edge length not covered by atom = a – 2r

∴ Percentage fraction not covered =


∴ Percentage fraction of covered = (100 – 13.4) % = 86.6%

24) In case of B.C.C, nearest distance is while next nearest distance is a

25)

(A) Distance between nearest octahedral void and tetrahedral void is

(B) Distance between two nearest octahedral void is

(C) Distance between nearest tetrahedral void is

(D) Distance between layer A and B is 2r

26)

(A) NaCl can shows Schottky defect


(B) ZnO can shows non-stoichiometric defect
(C) NaCl unit cell contain 4Na⊕ and 4Cl⊝
(D) Truncated octahedron has 24 corners.

27) Voids are surrounded by six atoms at edge centre & body. So, (1) & (3) are correct
answers

28)

Explain the question: Identify the isotropic (non-anisotropic) substance(s).

Concept: Crystalline solids are anisotropic, whereas amorphous solids are isotropic.

Solution:
Crystalline solids, such as sodium bromide (NaBr), possess a regular and highly ordered
long-range arrangement of constituent particles. This order causes certain physical properties-
like electrical conductivity, refractive index, and mechanical strength-to show different values
depending on the direction of measurement. This property is known as anisotropy. In
contrast, amorphous solids like glass, plastic, and rubber lack such long-range order, having
a more random, liquid-like particle distribution. Due to this randomness, their physical
properties are identical in all directions, a characteristic called isotropy.
Therefore, amorphous substances do not show anisotropy.

Final Answer: Options (1), (3) and (4)

29)

(B) (Lies between 0.155 – 0.225)


(Radius Ratio) ⇓
C.N should be 3

(D) Incorrect, because only 6 Cs+ ions occupy 2nd nearest neighbour locations, at a
distance 'a'.
30)

Explaining the Question :-


Question is asking about the correct order of inductive effect
Concept:-
This question is based on memory based
Solution :-
(1) –CH3 < –CD3 < – CT3 +I effect

(2) –I effect
(3) –NO2 > – CN > – F –I effect

(4) +I effect
Final Answer :- (1, 3 and 4)

31) Explain Question: Finding number of compound that show tautomerism.


Concept: Keto-enolism or tautomerism
Solution: NOTE: Hydrogen at bridge head position does not show tautomerism.
I, IV & VI have absence of enolisuble hydrogen so they do not show tautomerism.
Final Answer: 4

32)

(iii), (iv), (vi) (vii), are soluble in both

33)
But (II) is not protonated, hence the statement (a) is true.

In
So, Nb is more basic due to the presence of LP e's.

Statement (s) :
Statement (c ) is true
2
Statement (d): Due to resonsnce all the N in I,II, and III is hybridised and hence the
statement is true
So, statement a, c, d are true.

34)

ii, iii, iv

35) b, c, h, i

36) For simple cubic unit cell


2r = a, r = radius of atom X
If Radius of the largest atom that can be placed = R
⇒ 2R = 366 pm
2r + 2R =
a + 366 =
366 =

= 5 × 10–8 cm

Given NA = 6 × 1023

∴ correct answer is × 300 = 500.

PART-3 : MATHEMATICS

37)

38) Given series

have (b – 1) terms

First term + last term =

=
=a–1
Similarly
second term + second last term
=

=
=a–1

So required sum =
⇒ k1 + k2 = 3

39)

Question Explanation: Finding the number of elements in an inverse relation.


Concept: Inverse of a Relation and Division Property.
Solution:

A. Sets: A={2,3,4,5} and B={3,6,7,10}.


B. Relation R : Defined by (a,b) such that a divides b.
C. Identifying pairs in R :
D. 2 divides 6 and 10→(2,6),(2,10)
E. 3 divides 3 and 6→(3,3),(3,6)
F. 4 divides none of the elements in B.
G. 5 divides 10→(5,10)
H. Relation R set: {(2,6),(2,10),(3,3),(3,6),(5,10)}.
I. Since the inverse relation R-1 is formed by swapping the elements of each pair in R, the
number of elements in R–1 is equal to the number of elements in R.
J. Total elements in R=5, therefore, total elements in R–1=5.

Final Answer: Option (4)

40) The point on the circle is (3cosθ, 3sinθ, 0)

0 0 0
⊥ distance of point (x , y , z ) from plan is

using maximum value of acosθ + bsinθ is

41)

P3 : x + λy + z – 1 = 0

Also ⇒ λ2 – 2λ + 1 = λ2 + 2 ⇒ λ =
And

⇒ 2α – β + 2γ – 2 = ±6
⇒ 2α – β + 2γ – 8 = 0 or 2α – β + 2γ + 4 = 0

42) |a| = |b| = 1


a· b = 0; (as a ⊥ b)
....(i)
Taking dot product by a,

Taking dot product of (i) by b

43) Roots of the equation y3 – x3y2 – x2y – x1 = 0 are 3, 5 and 7


x3 = 15, x2 = – 71, x1 = 105

44) ƒ = x(x3 – 6x – 8)
ƒ' = 4(x3 – 3x – 2)
= 4(x + 1)2(x – 2)

ƒ:

45) 83x9 + 9.82x6 + 27.8x3 – 512x + 219 = 0


(8x3)3 + 3.(8x3)2.3 + 3(8x3).(3)2 + 27 = 512x – 192
[8x3 + 3]3 = 512x – 192
8x3 + 3 = (512x – 192)1/3

⇒ ƒ(x) = ƒ–1(x)
⇒ ƒ(x) = x [∵ ƒ(x) is continuous and ↑ function]


⇒ (2x – 1) (4x2 + 2x – 3) = 0

⇒ ∴
46) Solution:
f(x) = |x + 3| – |x + 1| – |x – 1| + |x – 3|
x 3
f(x) = x + 3 – x– 1 – x + 1 + x – 3 = 0
1 x<3
f(x) = x + 3 – x – 1 – x + 1 – x + 3 = 6 – 2x
–1 x < 1
f(x) = x + 3 – x – 1 + x – 1 – x + 3 = 4
–3 x < – 1
f(x) = x + 3 + x + 1 + x – 1 – x + 3 = 2x + 6
x<–3
f(x) = – x – 3 + x + 1 + x – 1 – x + 3 = 0

Range = [0,4]
f(x)max = 4
f(x) = 4 for x ∈ [–1,1]
f(x) = 0 for x ∈ (–∞,–3] ∪ [3,∞)
Final Answer: Option (2,3,4)

47) Solution:
(1) f : R → R, f(x) = 3x + sin x
⇒ f'(x) = 3 + cos x
as cos x ∈ [–1, 1]
⇒ 3 + cos x ∈ [2, 4]
∴ f'(x) > 0
⇒ f(x) is strictly increasing function
⇒ f(x) is one-one function
Also, x → ∞ then f(x) → ∞
x → –∞ then f(x) → –∞
∴ Range of f(x) = R = co-domain
⇒ f(x) is onto.
Hence f(x) is bijective function.

(2) f : R → R, f(x) = 3x3 – 2x2 + x


f'(x) = 9x2 – 4x + 1
a = 9 and D = 16 – 4 (9) < 0
⇒ f'(x) > 0
⇒ f(x) is increasing function
⇒ f(x) is one-one function
and f(x) is odd degree polynomial ⇒ Range = R
⇒ f(x) is onto function
⇒ f(x) is bijective function

(3) f : R – {2} → R – {1},


Let f(x1) = f(x2)

⇒ x1x2 – 2x1 – x2 + 2 = x1x2 – 2x2 – x1 + 2


⇒ x1 = x2

⇒ one-one function and let


⇒ xy – 2y = x – 1

for x to be defined, y ≠ I
⇒ Range = R – {1} = co-domain ⇒ onto
∴ f(x) is bijective function.

(4)

⇒ not one-one
⇒ f(x) is not bijective function.

Final Answer: Option (1), (2), (3)

48)

ƒ(2) = 3 ƒ(1) ≠ 2
ƒ(4) = 5 ƒ(3) ≠ 4
so there are total 3 possibilities
Case-I : ƒ={(1,1), (2,3), (3,2), (4,5), (5,4)}
Case-II : ƒ={(1,4), (2,3), (3,1), (4,5),(5,2)}
Case-III : ƒ = {(1,4), (2,3), (3,2), (4,5), (5,1)}
so ƒ–1(2) can be 3 or 5

49) Rearrange the equation as

for x>1 ; LHS > 0


for x=1 ; LHS = 0
for 0 < x < 1 ; LHS < 0
for x = 0 ; LHS = 0
for –1 < x < 0 ; LHS > 0
for x = –1 ; LHS = 0
for x < –1 ; LHS < 0
So, solutions are x ∈ {–1, 0, 1}

50) Let ex = y, so f(y) y2 + (k – 1)e.y + k = 0


f(0) > 0

⇒k>0
f(1) < 0
1 + (k – 1)e + k < 0
k(1 + e) < e – 1

[k] = 0

51)

na = 48, nb = 96
na +
48 + 24b(n – 1) = 2160
48 + 24 × 96 – 24b = 2160
b = 8 and a = 4, n = 12
n + a + b = 24

52) Let


⇒ –x (8 + x) + y(10 – y) = 40
⇒ x2 + y2 + 8x – 10y + 40 = 0
⇒ (x + 4)2 + (y – 5)2 = 1
∴ lies on circle with centre (–4, 5) and radius 1

is distance of from (–2, 3)


∴ Minimum = distance between (–2, 3) and (–4, 5) – radius

and
∴ m + M = 18


Now, applying A.M. ≥ G.M.

(48)3 ≥ (4 ⋅ 3 ⋅ 2 ⋅ 36 ⋅ 2 ⋅ V2)
⇒V≤8

53)

Question Explanation: Finding the shortest distance between lines defined by intercepts in
different planes.

Concept: Shortest distance between skew lines in 3D space.

Solution:


SD =

=
=

SD =

Final Answer: 51

54) Explain Question: Find point satisfying given condition and then find distance of point
form plane.
Concept: Distance of point from plane.
Solution:
Let a = 1 – x
b=x–y
c=y–z
d=z

then a + b + c + d = 1 and a2 + b + c2 + d2 =
⇒ (a – b)2 + (a – c)2 + (a – d)2 + (b – c)2 + (b – d)2 + (c – d)2 = 0
⇒a=b=c=d

So the distance from the point

From the plane 4x + 2y + 4z + 7 = 0 is


Final Answer: (2)

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