05-05-2026

9610WJA801492250118 JA

PART 1 : PHYSICS

SECTION-II

1) A long, straight wire of negligible resistance is bent into a V shape, its two arms making an angle
α with each other, and placed horizontally in a vertical, homogeneous magnetic field of strength B. A
rod of total mass m, and resistance r per unit length, is placed on the V-shaped conductor, at a
distance x0 from its vertex A, and perpendicular to the bisector of the angle α (see figure) (α = 90°)

The rod is started off with an initial velocity v in the

direction of the bisector, and away from A. The rod is long enough not to fall off the wire during the
subsequent motion, and the electrical contact between the two is good - although the friction

0
between them is negligible. Where does the rod ultimately stop? [Given : x = 2, ]

2) The world famous car Audi logo consist of four rings of each mass m and radius R as shown. Then

moment of inertia about axis shown will be the value of 'a' is

3) A point charge Q is placed at a distance of from the center of a quarter sphere of radius R.
The point charge is in the same plane as one of the flat surfaces of the quarter sphere. Find the flux

of the electric field through the curved surface of the quarter sphere. If the flux is , find the value
of n.

4) A square frame carrying a current I = 0.90 A is located in the same plane as a long straight wire
carrying a current I0 = 5A. The frame side has a length a = 8 cm. The axis of the frame passing
through the mid-points of the opposite sides is parallel to the wire and is separated from it by a
distance h = 15 times greater than the side of the frame. Find the mechanical work (nJ) to be
performed in order to turn the frame through 180° about its axis, with the current maintained

constant. (Take : )

5) An optical system contains a thin lens, n = 1.4, with positive curvature of radius R1 = 25 cm for
surface 1 and negative curvature of radius R2 = –25cm for surface 2. This lens collects light from the
right side. To the left of the lens we want to keep a flat plate of thickness t of the same glass so that
the light that radiates from a distant object is focused on a screen 35cm to the left of the lens. What
is thickness t (in cm) ?

6) An engine–driven rocket rises from the ground vertically upwards with a uniform velocity V = 2
m/s. The engine stops functioning after some time and rocket falls back on the ground. If the total

time of its journey is t = sec, the height (in cm) at which the engine stopped functioning. (Assume
'g' to be constant).

7) The two ends of a uniform thin rod of length √2R and of mass √2 kg can move without friction
along a fixed vertical circular path of radius R. The rod is released from the vertical position (ab).
Find the force (in N) exerted by an end of the rod on the path when the rod passes the horizontal
position(cd).
8) Two planets of mass M & 4M are shown in the figure. Radius of the planets R and 2R respectively
and distance between centres of the planets in 6R. A small particle is thrown from planet of mass M
along the line joining centres of both particles. Minimum speed of the particle so that it can reach

other planet is given by . Find x.

SECTION-I (i)

1) In the circuit shown the value of L is 5H and power factor of circuit is 0.8. It is also given that

voltage drop across the capacitor is time the voltage drop across inductor :-

(A) Impedance of circuit is 1570 Ω

(B) Impedance of circuit is 1256 Ω
(C) Value of R is 1256 Ω
(D) Value of R is 502 Ω

2) One mole of an ideal monatomic gas goes through a cyclic process, shown in the graph. Mark the
correct statements :
 PV diagram for the cyclic process is

(A)

PV diagram for the cyclic process is

(B)

(C) Molar specific heat capacity for the process is same for process 1–2 and 3–4.
(D) Magnitude of change in internal energy is same for process 1–2 and 2–3.

3) Figure shows a thin tube open at one end rotating with constant angular speed ω. The other end
of the tube has a small opening. Tube contains a fluid of density ρ which effuses with a speed u
relative to the tube. Let pA be the pressure at the point in the tube just behind the opening. Assume

0
the atmospheric pressure to be p and pick correct option(s) for the instant when h = .

(A)

(B)

(C)

(D)

4) A circular beam of charge of radius a consists of electrons moving with a constant speed u along
the +z direction. The beam’s axis is coincident with the z axis and the electron charge density is
given by ρ = cr2 (C/m3) where c is a constant and r is the radial distance from the axis of the beam :-
(A) The current crossing the xy-plane is πcua4
(B) The electric field at distance r (r < a) from z axis is proportional to r3
(C) The magnetic field at distance r (r < a) from z axis is proportional to r3
(D) The electric field at distance r (r < a) from z axis is inversely proportional to r.

5) In a uniformly charged dielectric sphere a very thin tunnel has been made along the diameter as
shown in the figure below. A charge particle – q having mass m is released from rest at one end of
tunnel. For the situation described, mark out the correct statement (s) :- [Neglect gravity]

(A) Charged particle will perform SHM about centre of the sphere as mean position

(B)
Time period of the particle is .
(C) Particle will perform oscillation but not SHM.
Speed of the particle while crossing-mean position is
(D)

6) A car moves towards a hill with speed VC. It blows a horn of frequency f which is heard by an
observer following the car with speed V0. The speed of sound in air is V.

(A) The wavelength of sound reaching the hill is V/f

(B)
The wavelength of sound reaching the hill is
The wavelength of sound of horn directly reaching the observer is
(C)

(D)
The beat frequency observed by the observer is

SECTION-I (ii)

1) When a point object, in a medium of refractive index µ2 is observed by an observer in medium of

refractive index µ1, along the normal incidence, then apparent distance . Hence,

velocity of image of object as directly seen by observer is

Answer the following by appropriately matching the lists based on the information given in
the paragraph. A bird in air is diving vertically over a tank with speed 6 m/s and a fish in the tank
is rising upward along the same line with speed 4 m/sec. Base of tank is silvered. [Take µ = 4/3]

List-I List-II

Speed of the image of fish as seen by bird

(I) (P) 3 m/s
directly

Speed of image of fish formed after

(II) (Q) 4 m/s
reflection from the mirror as seen by bird

Speed of image of bird relative to fish

(III) (R)
looking upwards m/s

Speed of image of bird relative to the fish

(IV) (S) 9 m/s
looking downward in the mirror

(T) 12 m/s

(U)

(A) I → S;II → P;III → T;IV → R

(B) I → S;II → P;III → T;IV → Q
(C) I → U;II → P;III → S;IV → Q
(D) I → U;II → P;III → T;IV → R

2) Bodies X and Y have the same initial temperature and kept in same surrounding.

List-I List-II

Solid sphere (X) and hollow sphere (Y) of Initial rate of heat loss of
(P) (1)
same radius and material X is equal to that of Y.

Initial rate of heat loss of

Solid sphere (X) and solid cube (Y) of
(Q) (2) X is greater than that of
same material and volume
Y.
 Thin hollow sphere (X) and disc (Y) of Initial rate of heat loss of
(R) same thickness t and same material and (3) Y is greater than that of
same radius r (r >> t) X.

Two solid spheres (X, Y) of same material

Initial rate of cooling of X
(S) and same radius. X has black coating, Y (4)
is greater than that of Y.
has silver coating.

Initial rate of cooling of Y

(5)
is greater than that of X.
(A) P → 1,5;Q → 3,5;R → 2,5;S → 2,4
(B) P → 2,5;Q → 1,4;R → 1,5;S → 1,3
(C) P → 1,4;Q → 2,5;R → 3,4;S → 2,5
(D) P → 3,5;Q → 1,2;R → 4,5;S → 1,2

3) List-I, shows four system of rod + particle undergoing collision on a smooth horizontal floor. Mass
of particle & rod in each case is m, & M respectively. In List-II relationships between velocity (v) of
centre of rod and angular velocity (ω) of the rod just after the collision are given. Choose
appropriate option (length of rod is l)

List-I List-II

(P) (1)

(Q) (2)
 (R) (3)

(S) (4)

(A) P → 4;Q → 3;R → 1;S → 2

(B) P → 2;Q → 1;R → 3;S → 2
(C) P → 3;Q → 3;R → 3;S → 1
(D) P → 1;Q → 2;R → 3;S → 4

4) Assume that a universe exists where plank's constant h, mass of electron, permittivity of free
space, electronic charge may be different from our universe. Predict the effect of each of the
constant on parameters of hydrogen atom.

List-I List-II

(P) h is more (1) Radius of atom is more

(Q) me is lesser (2) Radius of atom is less

(R) ∈0 is lesser (3) Wavelength of first line of lyman series is larger.

(S) e is more (4) Speed of electron in 1st orbit is more.

(5) Angular momentum in ground state is more

(A) P → 1,3,5;Q → 1,5;R → 2,4;S → 2,4
(B) P → 1,3;Q → 1,3;R → 2,4;S → 2,4
(C) P → 1,3,5;Q → 1,3;R → 2,3,4;S → 2,3,4
(D) P → 1,3,5;Q → 1,3;R → 2,4;S → 2,4

PART 2 : CHEMISTRY

SECTION-II
1) The sum of oxidation states (with sign) of sulphur in following compounds will be.
Cu2S, FeS2, Na2S2O3, Na2S2O4

2) How many of the following chemical reagents impart brick red colouration to the flame during
flame test? Dolomite, bleaching powder, rock salt, nitrolim, lime-stone, carnallite, Potash alum,
gypsum.

3) The compression factor (compressibility factor) for one mole of a vander Waals gas at 0°C and
100 atmosphere pressure is found to be 0.5. Assuming that the volume of a gas molecule is
negligible, calculate the vander waals constant ‘a’ (atm lt2 mol–2).

4) The complex reacts with water according to the equation.

The rate of the reaction . The reaction is acid catalysed i.e.

does not change during the reaction.
Thus rate = where , calculate ‘a’ and ‘b’ given from the following data at
25°C. Represent your answer as (a+b)

[Complex]M [H+]M t1/2​(hr) t3/4​(hr)

0.1 0.01 1 2
0.2 0.02 0.5 1

5) 24 gm of carbon and 48 gm of oxygen reacts completely to form CO(g) and CO2 (g) . Calculate
density of gaseous mixture (in gm per litre) at 1.642 atm pressure and 360 K temperature.

6) How many of the given species are chiral (Assuming these compound exist in nature)
(I) (II) (III) (IV) trans - (V)

7) Observe the following flow chart and find the value of X + Y – Z.

8) Total number of β-Keto monocarboxylic acids (including stereoisomers) which on heating give

SECTION-I (i)

1) Which of the following statements are correct

(A) Tendency to form complex : Sc+3 > Y+3 > La+3

(B) Most of Ln3+ are coloured.
(C) Ln(II) hydroxides are mainly basic in character
(D) Lanthanoids release H2 on reaction with strong acids

2)

In an evacuated vessel of capacity 112 L, 4 moles of Ar(g) and 5 moles of PCl5(g) were introduced
and the temperature is maintained at 273°C. At equilibrium, the total pressure of the mixture was
found to be 4.8 atm.

(A) The degree of dissociation of PCl5(g) into PCl3(g) and Cl2(g) is 0.6
(B) KP for the reaction: is 2.7 atm
(C) At equilibrium, the total moles of gases are 12
On removing Ar(g) from the equilibrium mixture at constant pressure and temperature, the
(D)
extent of dissociation of PCl5 will increase

3) Select the correct statement(s) regarding SNAr the given molecules ?

(A) The rate difference between III and IV is more compare to I and II with NaOH
(B) The rate difference between III and IV is less compare to I and II with NaOH
(C) I and III react with same rate with NaOH
(D) Resonance effect is more in I than II

4) The correct statement/s among the following is/are

(A) Intermolecular forces in n-heptane are stronger than those in 2-methylheptane

(B) Boiling point of 2,2-dimethylpentane is higher than that of 2, 2-dimethylbutane
(C) Melting point of cis-2-butene is higher than that of trans-2-butene
(D) Melting point of cis-2-butene is higher than that of trans-2-butene

5) Aluminium metal has a density of 2.72 g/cm3 and crystallizes in a lattice with an edge length of
404 pm. Which of the following alternatives are correct?

(A) It forms simple cubic lattice

(B) Lattice has face cantered cubic unit cell
(C) There are 12 nearest aluminium atoms for each aluminium atom
There are 6 second nearest aluminium atoms for each aluminium atom each at a distance of
(D)
202 pm

6) Which is/are correct statement?

(A) One of the monomer of Terylene is ethylene glycol

(B) Terylene is a thermosetting polymer
(C) Nylon-2-nylon-6 is a biodegradable polymer
(D) Natural rubber is all cis-polyisoprene

SECTION-I (ii)

1)

Column – I Column – II
I > II > III ( decreasing order of stability for
(A) (p)
complexes
(B) (q) At least one complex shows stereoisomerism

(C) (r) All complexes has EAN ≥ 36

(D) (s) At least two complexes are d2 sp3 or dsp2 hybridised
(t) At least one complex is paramagnetic in nature
(A) A → st;B → pt;C → pqt;D → pqs
(B) A → pqt;B → pqs;C → st;D → pt
(C) A → pt;B → st;C → pqst;D → pqt
(D) A → pqs;B → pqt;C → pt;D → st

2)

List - I List-II
(P) (1) Tetragonal
(Q) (2) Monoclinic
(R) (3) Orthorhombic
(S) (4) Hexagonal
(5) Cubic
(A) P → 4;Q → 3;R → 2;S → 1
(B) P → 4;Q → 2;R → 3;S → 5
(C) P → 1;Q → 2;R → 3;S → 4
(D) P → 2;Q → 5;R → 1;S → 4

3) Match list I with list II and select the correct answer :

List I List II
A Coagulation p Scattering of light
B Dialysis q Washing of precipitates.
C Peptization r Purification of colloids
D Tyndall effect s Electrolyte
t Visibility of tail of comets
(A) A → r;B → q;C → rs;D → t
(B) A → s;B → r;C → q;D → pt
(C) A → q;B → pt;C → r;D → s
(D) A → p;B → q;C → rs;D → t

4) Match the reactions mentioned in column-I with the nature of the reaction/characteristic(s) of the
products mentioned in column-II.

Column–I Column–II
(A) (NH4)2S2O8 + H2O (p) Hydrolysis
One of the products has
(B) NaBO2 + H2O + H2O2 (q)
peroxide linkage

(C) (r) Disproportionation

Na2SO3
In one of the products the
(D) 2–Ethylanthraquinol + air → (s) central atom has sp3
hybridisation.
One of the products is used as
(t)
brightener in washing powder.
(A) A → pqr;B → qrst;C → rs;D → pqrs
(B) A → pqt;B → pqs;C → pqs;D → pqr
(C) A → pqs;B → pqst;C → rs;D → qs
(D) A → rs;B → qs;C → pqst;D → pqs

PART 3 : MATHEMATICS

SECTION-II

1) The differential equation determines a curve y = f(x) and f(0) = 1, then

|f(3)| is equal to :

2) The straight line intersects the ellipse at two points A and B, there is a point

P on this ellipse such that the area of ΔPAB is equal to . Then the number of such points P
is _____.

3) If ,

then maximum value of determinant is :

(where [.] denotes greatest integer function)

4) If the sum of all the solutions of the equation

is kπ,
then k is equal to :

5) A line L in the Argand plane is called as the mean line for points α1, α2, α3,......αn, if there exist

points β1, β2, β3,......βn on line L such that . If the line L passes through the point –5 +
6i, then the slope of the mean line L for points –2 + 3i, 5 + 8i, –6 + 60i, 5 – 581i is λ, then value of
[λ] is : (Where [.] greatest integer function)

6) A student can take only unit steps and each step in North, East, West and South with equal
probability. He wants to go from his home at (2, 3) to his coaching at (4, 5). If he reaches by taking
less than 7 steps with probability P, then 32P is ?

7) Number of ways in which 8 letters of word KATAPPAA can be placed in squares of the figure so
that no row remains empty is λ, then is :

8) If p, q, r and s are non-zero numbers such that 'r' and 's' are roots of x2 + px + q = 0 and p, q are
roots of x2 + rx + s = 0, then value of (3p + 5q + 11r + 15s) is ?

SECTION-I (i)

1) A and B are the points (3, 0) and (0, 3) respectively. The coordinates of the point P on the line 3x
+ 4y + 1 = 0 is/are :

(A) (13, –10) if |PA – PB| is maximum.

(B)
if |PA – PB| is minimum.
(C) (13, –10) if |PA – PB| is minimum.

(D)
if |PA – PB| is maximum.

2) Given that ƒ(x) is a function defined on R, satisfying ƒ(1) = 1 and for any x ∈ R,
ƒ(x + 5) ≥ ƒ(x) + 5 and ƒ(x + 1) ≤ ƒ(x) + 1. If g(x) = ƒ(x) + 5 – x, then g(2013) is greater than or equal
to -

(A) 3
(B) 4
(C) 5
(D) 6

3) Let , then :

(A) f(x) is continuous but not differentiable at x = 2.

(B) f(x) is not continuous at x = 2.
(C) f(x) is differentiable everywhere ∀ x ∈ (2, ∞)
(D) The right hand derivative of f(x) at x = 3 does not exist.
4) Let a plane perpendicular to the plane 2x + 3y + 4z – 5 = 0 contains the line
and line L where line L is contained in the plane 2x + 3y + 4z – 5 = 0, then :

(A)
Line L passes through point
(B) Line L passes through point (0, 1, –1)
(C) One of the direction ratios of line L is (–25, 6, 8)
(D) One of the direction ratios of line L is (–25, –6, –8)

5) Which of the following is/are incorrect statement(s) ?

If A is non-singular square matrix of order (n × n) and k is scalar (k, n) ≠ (0, 1) then |k adj(kA)|
(A)
is equal to .
(B) Let A and B be 3 × 3 order matrices. If |A| = 0, AB = 0 and AC = 0, then B = C.
A and B are two square matrices of order n × n such that AB = 0 and A is non-singular then B
(C)
must be null matrix.
If AB is non-singular and A, B are square matrices then A and B both must be non-singular
(D)
matrices.

6) If f(x) is a polynomial of degree three with leading coefficient as unity such that f(1) = 1, f(3) = 9
and f'(1) = 2, then :

(A) f'(x) = 2x has atleast one root between (1, 3).

(B) f"(x) = 2 has atleast one root between (1, 7/3).
(C) Product of roots of f(x) = 0 is 3.
(D) Sum of roots of f(x) = 0 is 4.

SECTION-I (ii)

1) Match the list.

List-I List-II

The value of λ such that the planes x – 2y – z = 10,

(I) and 2x – y + 2z = k, are not able to (P) 8
make faces of tetrahedron.

(II) The remainder when 3113 is divided by 13 is : (Q) 6

Number of rational terms in the expansion of

(III) (R) 9
is :

Let be the sides of a regular

polygon inscribed in a circle if
(IV) (S) 10
,
then smallest possible value of n is :
 (T) 81
(A) I → T;II → R;III → Q;IV → P
(B) I → R;II → Q;III → P;IV → S
(C) I → S;II → R;III → Q;IV → P
(D) I → T;II → R;III → P;IV → S

2) Match the list.

List-I List-II

(I) If the mid-point of chord of ellipse is (0, (P)

2), then the length of the chord is :

The line 2x + y = a touches the hyperbola x2 – 2y2 =

(II) (Q)
9, if |a| is equal to :

If y = –2x + λ is a normal to the parabola y2 =

(III) (R)
4x, then value of is :

The product of length of the perpendicular from the

(IV) two focii on any tangent to the (S)
hyperbola is k, then is :

(T)
(A) I → S;II → Q;III → P;IV → T
(B) I → R;II → Q;III → T;IV → P
(C) I → P;II → T;III → Q;IV → S
(D) I → R;II → P;III → Q;IV → T

3) Match the List :

List-I List-II

(I) (P)
If then value of is :

(II) (Q)
The value of is :

If form a
(III) triangle, then internal angle of the triangle between (R) π
and is :

(IV) (S)

(T)
(A) I → R;II → S;III → T;IV → P
(B) I → Q;II → R;III → T;IV → S
(C) I → P;II → R;III → S;IV → T
(D) I → P;II → R;III → T;IV → S

4) Match the list.

List-I List-II

If f(x) + f"(x) = –xg(x)f'(x) and g(x) > 0, ∀ x ∈ R then

(I) (P) 12
(f(x))2 + (f'(x))2 has its maxima at x = k, then (k2 + 9) is :

If f2(x) + f(x) = g(x) and g(x) is always increasing,

(II) then the minimum value that f(x) can attain so that f(x) (Q) 4
is also increasing is k. Then |8(k – 1)| is :

(III) (R) 10
If is non-increasing function and f(x)
is continuous in R, then (f(1.5) + 4) is :

If f(x) is differentiable function and

(IV) (S) 9

, then , then k is :

(T) 20
(A) I → R;II → P;III → T;IV → Q
(B) I → S;II → Q;III → P;IV → T
(C) I → S;II → P;III → Q;IV → T
(D) I → S;II → P;III → R;IV → T
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-II

Q. 1 2 3 4 5 6 7 8
A. 2.23 to 2.25 3.00 0.05 9.55 to 9.65 13.12 to 13.13 300.00 25.00 3.00

SECTION-I (i)

Q. 9 10 11 12 13 14
A. A,C A,C,D B,D B,C A,B,D B,C,D

SECTION-I (ii)

Q. 15 16 17 18
A. B A C D

PART 2 : CHEMISTRY

SECTION-II

Q. 19 20 21 22 23 24 25 26
A. 2.00 5.00 1.25 2.00 2.00 1.00 7.00 6.00

SECTION-I (i)

Q. 27 28 29 30 31 32
A. A,B,C,D A,C B,D B B,C A,C,D

SECTION-I (ii)

Q. 33 34 35 36
A. C A B C

PART 3 : MATHEMATICS

SECTION-II

Q. 37 38 39 40 41 42 43 44
A. 12.50 3.00 52.00 4.50 -25.00 1.50 5040.00 -26.00

SECTION-I (i)

Q. 45 46 47 48 49 50
A. A,B A,B,C A,C A,C A,B A,B,C,D
 SECTION-I (ii)

Q. 51 52 53 54
A. A D B C
 SOLUTIONS

PART 1 : PHYSICS

1) Explain Question : Find the distance where rod stops

Concept : Motional emf
Solution :

= 2.24
Final Answer : (2.23-2.25)

2) Explain Question : Find the MOI about the axis

Concept : MOI
Solution :

I=

+ +

= mR2

= (2 + 4 + 2 + 25 + 2 + 64 + 2 + 121)

=
Final Answer : (3)

3) Explain Question : Find the flux of the electric field through the curved surface.
Concept : Flux calculation
Solution :

θ = 37°

ϕquarter = 0 & ϕvertical face = 0

ϕbase =
Final Answer : (0.05)

4) Explain Question : Find mechanical work to be performed in order to turn the frame.
Concept : Motional emf
Solution :

τ=

[let (1.2 – 0.04 cosθ = t)]

Final Answer : (9.55-9.65)

5) Explain Question : Find thickness of flat plate

Concept : Lens
Solution :

f = 31.25

NS = 35 – 31.25 = 3.75 =
t = 3.75 × 3.5 = 13.125 cm
≈ 13.12
Final Answer : (13.12-13.13)

6) Explain Question : Find the height when engine stops functioning

Concept : Variable mass
Solution :

From A to B motion is uniform

so
h = Vt1 ... (1)
Time intend from A to B
From B to C motion of uniform acceleration taking 'B' on origin upward direction positive

After time t2 from point B

y = –h

... (2)
For that total time
t = t1 + t2 ... (3)
By (1) & (2) we get

... (4) (As t1 + t2 = t)

Now using (1) (3) & (4) we get

Final Answer : (300.00)

7) Explain Question : Find force exerted by the rod

Concept : Energy conservation
Solution :
By energy conservation
 = ⇒ ω2 =

Now, 2Ncos 45° – mg =

⇒N= = 25
Final Answer : (25.00)

8) Explain Question : Minimum speed so that particle reaches other planet.

Concept : Gravitational energy
Solution :
Consider mass of the particle is m. We have to give speed to particle so that it can reach to
neutral point of system. As particle crosses NP it will be pulled by 4M.

At N.P, gravitational field is zero.

therefore,

⇒ ⇒
Now applying energy conservation for initial and final positions.

Ei = Ef

⇒ =

⇒ =

⇒ ⇒ v2 =

⇒ ⇒
Final Answer : (3.00)

9) Explain Question : For voltage drop across capacitor find correct options.
Concept : LCR circuit
Solution :
 R = 1256 Ω

c=
Final Answer : (A,C)

10) Explain Question : Mark the correct options from the graph
Concept : P-V diagram
Solution :
Process 4 → 1 and 2 → 3 are isochoric.
Equation of processes 1 → 2 and 3 → 4 is PV–1 = constant.

Molar specific heat capacity for 1 → 2 and 2 → 3 is C = CV + , since T1 = T3

|ΔU12| = |ΔU23|
Final Answer : (A,B,D)

11) Explain Question : Pick correct options for the instant

Concept : Bernoulli's equations
Solution :
By Newton’s second law;

By Bernoulli’s equation;
Final Answer : (B,D)

12) Explain Question : Choose correct options

Concept : Electric and magnetic field
Solution :

(a)
(b)

(c) B × 2πr =

Final Answer : (B,C)

13) Explain Question : For uniformly charged dielectric sphere choose correct options
Concept : Changed dielectric
Solution :
At a centre, the force experienced by the charge particle is zero, so it is a position of
equilibrium. As we displace the charge from the equilibrium position, electric force starts
acting on it towards equilibrium position and hence equilibrium is a stable one.
At a distance x from the centre of sphere (equilibrium position), force experienced by the
charged particle is,

As F ∝ x, so it performs SHM about the centre.

Time period can be calculated by using
F = mω2 x

To calculate speed at the mean position, use energy conservation law.

Final Answer : (A,B,D)

14) Explain Question : Choose correct options based on car motion

Concept : Doppler effect
Solution :

beat frequency = fR – fD =
Final Answer : (B,C,D)
15) Explain Question : Match the column
Concept : Refraction from plane surface
Solution :

= 9 m/s

Final Answer : (B)

16) Explain Question : Match the column

Concept : Radiation
Solution :

(P)

for my < mx

P → 1,5

(Q)
 Q → 2, 4

(R)

R → 2, 5

(S)

S → 2, 4
Final Answer : (A)

17) Explain Question : Match the column for collision

Concept : Collision
Solution :

(P)
Angular momentum conservation

(Q) Angular momentum conservation

(R) Angular momentum conservation

 (S) Angular momentum conservation

Final Answer : (C)

18) Explain Question : Match the column

Concept : Atomic structure
Solution :

Final Answer : (D)

PART 2 : CHEMISTRY

19)

Explain Question: Find the sum of oxidation states (with sign) of sulphur in following
compounds
Concept: Oxidation state
Solution:
In Cu2S (–2), In FeS2 (–1), In Na2S2O3 (+2)
In Na2S2O4 (+3)
Final Answer: (2.00)

20)

Explain Question: Find how many of the following chemical reagents impart brick red
colouration to the flame during flame test
Concept: Flame test
Solution:
All Ca containing compounds impart brick red colouration to the flame. Except carnallite, alum
& rock salt all other are Ca containing compounds.
Final Answer: (5.00)

21)

Explain Question: calculate the vander waals constant ‘a’ (atm lt2 mol–2)
Concept: Compressibility factor
Solution:
Final Answer: (1.25)

22)

Explain Question: calculate ‘a’ and ‘b’ given from the following data at 25°C
Concept: Order of reaction for a complex reaction
Solution:
Since does not change during reaction

order of reaction with respect to complex is 1.

b=1
Ans: a+b = 2.00
Final Answer: (2.00)

23)

Explain Question: Calculate density of gaseous mixture (in gm per litre) at 1.642 atm
pressure and 360 K temperature

Concept:
Solution:

d = 2.00
Final Answer: (2.00)
24) Explain Question: Find the chiral species
Concept: Chirality in square planar and octahedral compounds.
Solution:
is chiral

Have COS so not chiral

Final Answer: (1.00)

25) Explain Question: Find the value of X + Y – Z

Concept: Chlorination, SN2. isomerism
Solution:

Ans is X + Y – Z = 4 + 6 – 3 = 7
Final Answer: (7.00)

26) Explain Question: Find the total number of β-Keto monocarboxylic acids (including
stereoisomers) which on heating give
Concept: Decarboxylation of β-keto acids.
Solution:

Final Answer: (6.00)

27)
Explain Question: Find the correct statements
Concept: Properties of lanthanoids
Solution:
(A) As size ↑ , charge density ↓ , complex formation tendency ↓
Final Answer: (ABCD)

28) Explain Question: Find the correct statements

Concept: KP and degree of dissociation
Solution:
⇒ PCl5(g) PCl3(g) + Cl2(g)
at equilibrium nT = 9 + x ⇒ 4.8 × 112 = nT × 0.0821 × 546
nT = 9 + x = 12 ⇒ x = 3 = neqm

α=
⇒ KP = 1.8 atm
Final Answer: (AC)

29) Explain Question: Select the correct statement(s) regarding SNAr the given molecules
Concept: SNAr reaction
Solution:
Rate of nucleophilic substitution ∝ EWG
NO2 is more EWG compare to CN
Final Answer: (BD)

30) Explain Question: Select the correct statement/s among the following
Concept: Physical properties of hydrocarbons
Solution:

Boiling Point ∝
Boiling point ∝ intermolecular force ∝ Molecular weight.
Final Answer: (B)

31) Explain Question: Find the correct statement

Concept: SCC, FCC lattice
Solution:
d = 2.72 g/cm3
a = 404 pm

2.72 =

Z=
Z = 3.99 = 4
It forms fcc lattice
Final Answer: (BC)

32) Explain Question: Find the correct statement

Concept: Properties of polymers
Solution:
(B) Terylene is a thermoplastic polymer
Final Answer: (ACD)

33)

Explain Question: Match the column - I with column-II

Concept: EAN rule, isomerism, hybridisation and magnetic nature
Solution:
(A) → p, t; (B) → s, t; (C) → p, q, s, t; (D) → p, q, t
CFSE ∝ Field strength
Final Answer: (C)

34) Explain Question: Match list - I with list - II

Concept: Bravais lattice
Solution:
(P) a = b ≠ c → Hexagonal
(Q) a ≠ b ≠ c → orthorhombic
α = β = γ = 90°
(R) a ≠ b ≠ c, β ≠ 90° → Monoclinic
(S) a = b ≠ c, α = β = γ = 90° → Tetragonal
Final Answer: (A)

35)

Explain Question: Match list - I with list - II

Concept: Properties of colloids
Solution:
(A) Coagulation is known as accumulation of colloidal sols.
(B) Dialysis is purification of colloids.
(C) Peptization is formation of colloidal solution from precipitates.
(D) Tyndall effect is scattering of light by colloidal and also visibility of tail of comets is due to
Tyndall effect.
Final Answer: (B)

36)

Explain Question: Match column - I with column - II

Concept: Preparation and reactions of H2O2
Solution :
(A) (NH4)2S2O8 + H2O 2NH4HSO4 + H2O2
(B) 2NaBO2 + H2O2 + 6H2O Na[(OH)2B2(O—O)2(OH)2]6H2O
Peroxoborate is used as brightener in washing powder.
(C) 4Na2SO3 Na2S + Na2SO4
(D) 2-Ethylanthraqunol + air(O2) → 2-ethylanthraquinone + H2O2
Final Answer: (C)
PART 3 : MATHEMATICS

37) Explain Question : Solve the given first-order differential equation for a curve passing
through (0, 1) and determine the value of the function f(x) at x = 3.
Concept : Solving Differential Equations using substitution (Homogeneous form), Variable
Separable method, and Initial Value Problems.
Solution :
Let Y = y – 5, X = x + 2

Let

ln(1 + v) = lnX + lnC

Final Answer : 12.50

38) Explain Question : Find how many points P exist on a specific ellipse such that a triangle
formed with the intersection points of a given line has a specific area.
Concept : Area of Triangles in Coordinate Geometry, Ellipse-Line intersection, and Tangents
to Ellipses parallel to a given line.
Solution :
Let perpendicular distance of P from the line be h

Now distance of tangent parallel to AB i.e. 4y + 3x =

,

from line AB is . There are just three such

points.
Final Answer : 3.00

39) Explain Question : Determine the maximum possible value of a 3\times3 determinant
where the elements are related to the greatest integer functions of x, y, and z within given
ranges.
Concept : Properties of Determinants (Row operations), Greatest Integer Function [x], and
Maximization of linear expressions.
Solution :

= 52
Final Answer : 52.00

40) Explain Question : Find the sum of all solutions for a complex trigonometric equation
involving secant, tangent, and cosine functions within the interval .
Concept : Trigonometric Identities, Solving Trigonometric Equations, and Sum of solutions in
a periodic range.
Solution :

Sum of common solution

⇒ kπ =

Final Answer : 4.50

41) Explain Question : Calculate the floor value of the slope (\lambda) for a "mean line" L
that satisfies a specific complex summation property for four given points in the Argand plane.
Concept : Complex Numbers in Geometry, Parametric form of a line in the Argand plane, and
Summation of complex vectors.
Solution :
Let line L in parametric form be

where slope is b/a.

where
–20 + 24i + ka + kbi = 2 – 510i
ka – 20 = 2, kb + 24 = –510
ka = 22, kb = –534

=λ
⇒ [λ] = [–24.27] = –25.00
Final Answer : -25.00

42) Explain Question : A student moves in unit steps (N, E, W, S). Calculate the probability P
of reaching a destination in fewer than 7 steps, then find 32P.
Concept : Probability, Combinatorics (Permutations of multisets), and Random Walks on a 2D
grid.
Solution :
He can reach coaching by either 4 or 6 steps.

Final Answer : 1.50

43) Explain Question : Determine the number of ways to arrange the letters of "KATAPPAA"
into a specific grid so that every row contains at least one letter.
Concept : Permutations with Identical Objects and Inclusion-Exclusion Principle for restricted
arrangements.
Solution :
Total – (Row 1 is empty) – (Row 2 is empty) – (Row 3 is empty)

=
Final Answer : 5040.00

44) Explain Question : Given two quadratic equations where the roots of one are the
coefficients of the other, find the value of a specific linear combination of those variables.
Concept : Theory of Equations, Relations between Roots and Coefficients, and solving systems
of algebraic equations.
Solution :
p + q = –r ....(i)
r + s = –p ....(ii)
pq = s ....(iii)
rs = q ....(iv)
adding (i) & (ii)
⇒ p + q + r + s = –(p + r)
⇒ 2(p + r) + (q + s) = 0
⇒ (q + s) = –2(p + r) ....(v)
Also r is a root of x2 + px + q = 0
r2 + pr + q = 0 ....(vi)
Similarly
p2 + pr + s = 0 ....(vii)
by (vi) + (vii)
p2 + r2 + 2pr + q + s = 0
using (v)
(p + r)2 – 2(p + r) = 0
p + r = 0( ), (2) ( )
by (iii) × (iv)
pr = 1
p = 1, r = 1
q = –2, s = –2
Final Answer : -26.00

45) Explain Question : Identify the coordinates of point P on a specific line that either
maximizes or minimizes the difference in distances from two fixed points A and B.
Concept : Locus properties, Triangle Inequality (|PA - PB| \le AB), and Perpendicular
Bisectors.
Solution :
|PA – PB|max = AB

AB : x + y = 3, L : 3x + 4y + 1 = 0
P(13, –10)
|PA – PB|min = 0.

⊥ bisector of AB
y=x

Final Answer : A, B

46) Explain Question : Given functional inequalities for f(x), determine the properties or
values of a derived function g(x) = f(x) + 5 - x at a specific point.
Concept : Functional Equations, Sandwich Theorem/Squeeze Principle application to
functions, and Monotonicity.
Solution :
Given ƒ(x + 5) ≥ ƒ(x) + 5 ...(1)
ƒ(x + 1) ≤ ƒ(x) + 1 ...(2)
from (1) and (2), we can write
ƒ(x) + 5 ≤ ƒ(x + 5) ≤ ƒ(x + 4) + 1
≤ ƒ(x + 3) + 2
≤ ƒ(x + 2) + 3
≤ ƒ(x + 1) + 4
≤ ƒ(x) + 5
∴ equality exist everywhere
∴ ƒ(x + 1) = ƒ(x) + 1 ∵ ƒ(1) = 1
⇒ ƒ(2) = 2, ƒ(3) = 3 ... ƒ(2013) = 2013.
Now g(x) = ƒ(x) + 5 – x ⇒ g(2013) = 5
Final Answer : A, B, C

47) Explain Question : Analyze a piecewise function defined by a linear term and an integral
to determine its continuity and differentiability at critical points.
Concept : Definite Integrals with Absolute Values, Leibniz Rule, Continuity, and
Differentiability of piecewise functions.
Solution :

Continuous at x = 2 but not differentiable at x = 2.

Final Answer : A, C

48) Explain Question : Find the properties (points and direction ratios) of a line L that is the
intersection of a given plane and a new perpendicular plane.
Concept : Three-Dimensional Geometry, Equations of Planes and Lines, and Cross Product for
finding Direction Ratios.
Solution :
Plane is perpendicular to and
Plane passes through point (0, 1, 2)
(x – 0)0 + (y – 1)4 + (z – 2)(–3) = 0
4y – 3z + 2 = 0
Line L is line of intersection of both planes.

D.r. of Line =
Point on line is common point of 2 planes.
x = 0, 3y + 4z = 5
4y – 3z = –2
25y = 7

Final Answer : A, C

49) Explain Question : Identify which statements regarding non-singular square matrices,
adjoints, and matrix multiplication are mathematically incorrect.
Concept : Matrix Algebra, Properties of Adjoints and Determinants , and
Singular vs. Non-singular matrices.
Solution :
(A) |k adj(kA)| = kn.|adj(ka)|
= kn.|kn–[Link]

(B) Order of C is not mentioned.

(C)
(D) If |AB| ≠ 0 ⇒ |A| ≠ 0 and |B| ≠ 0
Final Answer : A, B

50) Explain Question : For a third-degree polynomial with specific values at certain points,
evaluate roots, their products, and application of the Mean Value Theorem.
Concept : Polynomial Theory, Vieta’s Formulas, and Rolle's Theorem/Mean Value Theorem.
Solution :

Let Q(x) = f(x) – x2

f(x) = (x – 1)(x – 3)(x – α) + x2
f'(1) = 2
α=1
f(x) = (x – 1)2(x – 3) + x2
= (x2 – 2x + 1)(x – 3) + x2
f(x) = x3 – 4x2 + 7x – 3
Final Answer : A, B, C, D

51) Explain Question : Match four independent mathematical problems (geometry,

remainders, binomial expansion, and polygons) to their respective numerical answers in List-
II.
Concept : Coplanar Planes, Binomial Theorem (Remainders and Rational Terms), and Vector
properties of Regular Polygons.
Solution :

(I) ⇒ λ = 81
37 2
(II) = (26 + 1) .3

Remainder = 9.

(III) General term =

p + q + r = 12
Possible triplets
(0, 6, 6) → 3, (0, 0, 12) → 3
p → 0, 2, 4, 6, 8, 10, 12
q → 0, 3, 6, 9, 12
r → 0, 6, 12
Total = 6 terms.

(IV)

&

put these values in given equation, we will get

So,

, m ∈ I ⇒ nmin = 8.
Final Answer : (A)

52) (I) Equation of chord

y=2
Put in ellipse

Length of chord =
(II) x2 – 2(a – 2x)2 = 9
–7x2 + 8ax – 2a2 = 9
7x2 – 8ax + 2a2 + 9 = 0
D=0
64a2 – 28(2a2 + 9) = 0
8a2 = 289

(III) y = mx – 2m – m3
y = –2x + 4 + 8
y = –2x + 12

(IV) P1.P2 = b2 = 15 = k

53) Explain Question : Match definite integrals and vector geometry problems to their
specific results or angles.
Concept : Definite Integration (Substitution and Symmetry), and Vector Algebra (Angles
between vectors).
Solution :

(I)

f(x) = x

(II)

=π
(III)

(IV) ....(1)

....(2)
by (1) + (2)

Final Answer : B

54) Explain Question : Match conditions on differentiable functions and their derivatives to
specific numerical constants k.
Concept : Applications of Derivatives, Maxima/Minima, Monotonic Functions, and Differential
Equations.
Solution :
(I) h(x) = f(x)2 + (f'(x))2
h'(x) = 2f(x).f'(x) + 2f'(x).f"(x)
= 2f'(x) (f(x) + f"(x))
= –2xg(x).f'(x)2
as h'(0–) > 0, h'(0+) < 0 & h(0) = 0
∴ h(x) has its maxima at x = 0
⇒ k = 0 ⇒ k2 + 9 = 9
(II) g(x) = f2(x) + f(x)
g'(x) = 2f(x).f'(x) + f'(x)
= f'(x) (2f(x) + 1)
given that g'(x) ≥ 0
⇒ f'(x).(2f(x) + 1) ≥ 0
also given that f'(x) ≥ 0
⇒ 2f(x) + 1 ≥ 0

|8(k – 1)| = 12
(III) Let

G'(x) = 2g(x) and g(0) = 0 = G'(0)

g(x) is non increasing.

But G(0) and G(x) ≥ 0

⇒ G(x) = 0 ∀ x ∈ R

f(x) = 0 f(1.5) + 4 = 4.

(IV)

f'(x) = 2x + x2

f(0) = 0 ⇒ c = 0

k = 20
Final Answer : C