03-05-2026

2202CJA101021250058 JA

PHYSICS

SECTION-I(i)

1) Three small dipoles of dipole moment p each are placed at the three vertices of an equilateral

triangle of side a as shown. The total potential at the centroid G is given by

(A)

(B)

(C) Zero
(D) None of these

2) N fundamental charges each of charge 'q' are to be distributed as two point charges separated by
a fixed distance, then the maximum to minimum force bears a ratio (N is even and greater than 2)

(A)

(B)

(C)

(D)

3) A large flat metal surface has uniform charge density +σ. An electron of mass m and charge e
leaves the surface at some angle at point A with speed v, and return to it at point B. The maximum
value of AB is ____

(A)

(B)
(C)

(D)

4) A charge Q is placed at a distance a/2 above the centre of the square surface of edge a as shown

in the figure. The electric flux through the square surface is :

(A)

(B)

(C)

(D)

SECTION-I(ii)

1) The potential in x-y plane is given by . Potential at point (3, 3) is taken as zero.
Then :-

(A) Work done in moving a test charge q slowly from a point (a, b) to a point (b, a) is zero.
(B) Potential at any point on x-y plane can't exceed 18 unit for x & y in 1st quadrant.
(C) Value of C is 18
(D) The corresponding electric field is

2) In a uniformly charged non-conducting sphere a very thin tunnel has been made along the
diameter as shown in the figure below. A charge particle – q having mass m is released from rest at
one end of tunnel. For the situation described, mark out the correct statement (s) :-
Given that electric field due to a uniformly charged solid sphere having charge Q and radius R at a

distance 'r' from center is given by

[Neglect gravity]

(A) Charged particle will perform SHM about centre of the sphere as mean position

(B)
Time period of the particle is .
(C) Particle will perform oscillation but not SHM.
Speed of the particle while crossing-mean position is
(D)

3) Choose the correct option(s) for physical quantities with their MKS units

(A) Electric flux, volt-m

(B) Electric field, volt/m
(C) Relative permittivity, none
(D) Dipole moment, C-m

SECTION-I(iii)

1) List-I shows four configurations, each consisting of a pair of ideal electric dipoles. Each dipole has
a dipole moment of magnitude , oriented as marked by arrows in the figures. In all the
configurations the dipoles are fixed such that they are at a distance 2 apart along the direction.
The midpoint of the line joining the two dipoles is . The possible resultant electric fields at are
given in List-II.
Choose the option that describes the correct match between the entries in List-I to those in List-II.

List-I List-II

(P) (1)

(Q) (2)
 (R) (3)

(S) (4)

(5)

The correct option is

(A) P → 3;Q → 1;R → 2;S → 4
(B) P → 4;Q → 5;R → 3;S → 1
(C) P → 2;Q → 1;R → 4;S → 5
(D) P → 2;Q → 1;R → 3;S → 5

2) As shown in List-I their are graphs of electric field (E) and potential (V) along the line joining
charges Q1 and Q2 are drawn against distance (r) on x-axis for charges Q1 and Q2. Take potential at
infinity equal to zero. [Take direction of E in rightward direction as positive]

List-I List-II

(P) (1) Q1 < 0, Q2 > 0

(Q) (2) Q1 > 0, Q2 < 0

(R) (3) Q1 > 0, Q2 > 0

 (S) (4) Q1 < 0, Q2 < 0

(5) Q1 = 0, Q2 > 0
The correct option is
(A) P → 2;Q → 2;R → 4;S → 5
(B) P → 2;Q → 2;R → 5;S → 1
(C) P → 2;Q → 2;R → 4;S → 1
(D) P → 3;Q → 2;R → 4;S → 1

3)

List-I List-II

(P) (1)

Uniformly positively charged ring in yz plane with

axis along x axis

(Q) (2)

Two identical positively charged particle placed on

y axis symmetrical to x axis

(R) (3)

Uniformly positively charged

non conducting disc in yz plane with axis along x
axis.
 (S) (4)

Uniformly positively charged (charge distributed

throughout its volume) non conducting sphere with
diameter axis along x-axis.

(5)

The correct option is

(A) P → 3;Q → 5;R → 2;S → 1
(B) P → 2;Q → 2;R → 4;S → 3
(C) P → 1;Q → 3;R → 4;S → 5
(D) P → 5;Q → 1;R → 2;S → 4

4) There is a conductor with cavity in side as shown in List-I and charge distribution type in List-II,
match the correct entries

List-II (Conductors with

List-I (Charge distribution type)
cavity)

Uniform in inner surface, non

(P) (1)
uniform in outer surface

Uniform in inner surface and in

(Q) (2)
outer surface also

Non uniform in inner surface

(R) (3)
uniform in outer surface
 Non uniform in inner and outer
(S) (4)
surface

(5)

(A) P → 5;Q → 2;R → 1;S → 3

(B) P → 1;Q → 5;R → 3;S → 4
(C) P → 3;Q → 4;R → 2;S → 1
(D) P → 1;Q → 3;R → 2;S → 5

SECTION-II

1) Two identical charged spheres are suspended by strings of equal lengths. The strings make an
angle of 30° with each other. When suspended in a liquid of density 0.8 g cm−3, the angle remains the
same. If density of the material of the sphere is 1.6 g cm−3, the dielectric constant of the liquid is:

2) Two charged large conducting plates are placed parallel to each other. Find the ratio of electric
field at P to the field at R.

3)

A long wire of linear charge density λ is bent in U-shape of radius R as shown. The electric field at

centre of curvature O is given by . The value of n is

4) Two identical balls of mass m = 0.9 g each are charged by the same charges, joined by a thread
and suspended from the ceiling (figure). Find the charge (in µC) that each ball should have so that
the tension in both the threads are same? The distance between the centers of balls is R = 3m.

5)

At distance of 5 cm and 10 cm outwards from the surface of a uniformly charged solid sphere, the
potentials are 100 V and 75 V respectively. Then electric potential on the surface in volt.

6) Find the x-coordinates between two points of zero potential due to charges +2q and –3q fixed
at (4, 0, 0)m and (9, 0, 0)m respectively. (Assume V = 0 at infinity)

CHEMISTRY

SECTION-I(i)

1) Consider the reaction : A → B

Which of the plots is NOT correct against the orders indicated ?
Note : Symbols have usual meaning
(i) (2nd order)

(ii) (1st order)

(iii) (1st order)

(iv) (zero order)

(A) (i)
(B) (ii)
(C) (iii)
(D) (iv)

2)

In the reaction ;
Calculate total order of given reaction.

(A) 1
(B) 3
(C) 2
(D) 5

3) Heat of combustion for the given compound is

(I) (II) (III) (IV)

(A) II > IV > I > III

(B) II > IV > III > I
(C) IV > II > I > III
(D) I > III > IV > III

4) In which of the pair of carbanion have first more stable than second.

(1) (2)

(3) (4)

(A) 1,2,4
(B) 2,3,4
(C) 2,3
(D) 1,2,3

SECTION-I(ii)

1) Which of the following is/are true statement(s)

 For a zero order reaction, on halving the initial concentration of reactant, the rate remains
(A)
unaffected, whereas, the half life gets halved
(B) Rate of reaction is fastest at the beginning for a zero order reaction
For a complex reaction P + 3Q → R; the differential form of rate law may be written as
(C)

(D) Order of a reaction may be a whole or a fractional number

2) In which of the following compounds can give white ppt with AgNO3.

(A) PhCl
(B) PhCH2Cl

(C)

(D)

3) C—C and C=C bond lengths are unequal in :

(A) Benzene
(B) 1,3-buta-di-ene
(C) 1,3-cyclohexa-di-ene

(D)

SECTION-I(iii)

1)

List-I List-II

(P) (1) rate = k

(Q) (2) rate = k[A]2

(R) A → B ; t1/2 vs [A]0 is linear (3) t1/2 is constant

(S) A → B ; t1/2 vs [A]0 is non-linear (4) rate decreases with time

 (5) rate = k[A]1
(A) P → 4;Q → 1;R → 5;S → 2
(B) P → 2;Q → 4;R → 5;S → 2
(C) P → 5;Q → 1;R → 4;S → 3
(D) P → 3;Q → 4;R → 1;S → 5

2) Assumption : Reaction obeying rate law, rate = k[A]n

List-I
List-II
(Order of
reaction)

(P) 0 (1) Reaction may be elementary

Half life decreases with increase in

(Q) 1 (2)
initial concentration

Reaction can be completed (100%) in

(R) 2 (3)
finite time

Rate constant increases with increase in

(S) 4 (4)
temperature

Greater the amount of [A] at an instant t

(5) = t, greater will be reaction rate at that
instant
(A) P → 2;Q → 5;R → 1;S → 3
(B) P → 5;Q → 4;R → 2;S → 3
(C) P → 4;Q → 1;R → 2;S → 5
(D) P → 1;Q → 2;R → 3;S → 4

3) Match the List :

List-I List-II

(P) Group donate e– inductively but does not donate / withdraw by resonance (1) –OH

Group withdraw e– inductively but does not donate / withdraw by

(Q) (2) –NO2
resonance

(R) Group withdraw e– inductively & donate e– by resonance (3) –CH2–CH3

(S) Group withdraw e– inductively & withdraw e– by resonance (4)

(5) –NH2
(A) P → 3;Q → 4;R → 5;S → 2
(B) P → 3;Q → 4;R → 2;S → 3
(C) P → 3;Q → 5;R → 1;S → 2
(D) P → 1;Q → 4;R → 5;S → 2

4)
Answer the following by appropriately matching the lists based on the information given in the
paragraph.

List-I List-II

(P) (1) Correct order of stability of alkene

(Q) (2) Correct order of heat of combustion

(R) (3) Correct order of heat of hydrogenation

(S) (4) Correct order of C=C bond length

(5) Correct order of no of α-H

(A) P → 1;Q → 5;R → 3;S → 2
(B) P → 1;Q → 2;R → 4;S → 5
(C) P → 1;Q → 4;R → 1;S → 4
(D) P → 1;Q → 4;R → 1;S → 2

SECTION-II

1) For a zero order reaction, 5A(g) → 2B(g) + 4C(g) ; rate of reaction = 0.2 atm/s. Initially only A is
present and its pressure = 4 atm. Find total pressure at t = 6 sec.
Assumption : There is no leakage in the flask and volume and temperature are constant

2) Consider the reaction :

A(g) → B(g), K = 1.386 min–1
Calculate in min.

Note : = time for fraction of A to decompose

3) Consider the reaction :

H2(g) + I2(g) → 2HI(g)
The proposed mechanism is :

(i) [fast equilibrium]

(ii) [slow]

Let Ea1 = 10 kJ/mol

Ea2 = 20 kJ/mol
Ea3 = 50 kJ/mol
Find Ea of given complex reaction in kJ/mol

4) Find number of compound which are aromatic in nature :

5) Number of hyperconjugative structure involving (C–H) bond for carbocation :

6) The total number of compounds which contains equal (C–O) bond length are:

(I) (II) (III) (IV) (V)

MATHEMATICS

SECTION-I(i)

1) Range of the function y = is -

(A)

(B)

(C)

(D)

2) Domain of the function is -

(A)
(B)
(C)
(D)

3) If function ƒ : [–4, ∞) → B defined as ƒ(x) = x2 + 8x + 18 is bijective then set B is :-

(A) R
(B) [–2, ∞)
(C) [2, ∞)
(D) [–8, 2]

4) Which of the following function is odd function ?

(A) ƒ : R → R, ƒ(x) = ex
(B) g : R → R, g(x) = [x], (where [.] denotes greatest integer function)
(C) p : R → R, p(x) = sgn(x), (where sgn(.) denotes signum function)
(D) h : R → R, h(x) = |x|

SECTION-I(ii)

1) If ƒ : R → [0, ∞), ƒ(x) = min(|x|, ex), then which of the following is/are not true?

(A) ƒ is a many-one function

(B) ƒ is surjective function
(C) ƒ is periodic function
(D) ƒ is even function

2) Which of the following functions are defined nowhere. (Where [.] is greatest integer function and
{.} fractional part of function)

(A)

(B)

(C)

(D)

3) Let f : R → R where then which of the following is/are false

(A) f(x) is one-one and onto

(B) f(x) is many one & onto
(C) f(x) is one-one & into
(D) f(x) is many one & into

SECTION-I(iii)

1) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II
 (P) ƒ : R → R ; ƒ(x) = x + [x] (1) Injective Mapping

ƒ : R → (0,∞)
(Q) (2) Surjective Mapping

(R) (3) Non injective mapping

ƒ(x) = x3 – 2x2 + 2x + log x

ƒ : [–3,0] → [cos3,1]
(S) (4) Non surjective mapping
ƒ(x) = cosx
(A) P → 1;Q → 3;R → 2;S → 1
(B) P → 1;Q → 3;R → 2;S → 3
(C) P → 1;Q → 4;R → 2;S → 3
(D) P → 1;Q → 3;R → 1;S → 4

2) If 'n' is number of solution for ||x| – 10| = k, List-I contains value of 'n'. List-II contains range of 'k'.

List-I List-II

(I) n=0 (P) k ∈ (–∞, 0)

(II) n=2 (Q) k ∈ (–∞, 0]

(III) n=3 (R) k ∈ (0, 10)

(IV) n=4 (S) k ∈ {10}

(T) k ∈ (10, ∞)

(U) k ∈ (10, ∞) ∪ {0}

Which of the following is the only CORRECT combination ?
(A) I → U;II → P;III → S;IV → R
(B) I → U;II → P;III → R;IV → S
(C) I → P;II → U;III → S;IV → R
(D) I → P;II → U;III → R;IV → S

3) Let f(x) = ℓn x and g(x) = x2 – 1 List-I contains composite functions and List-II contains their
exhaustive domain.

List-I List-II

(I) fog (P) (1, ∞)

(II) gof (Q) (–∞, ∞)

(III) fof (R) (–∞, –1) ∪ (1, ∞)

(IV) gog (S) (0, ∞)

(T) (2, ∞)
(A) I → R;II → S;III → P;IV → Q
(B) I → T;II → S;III → P;IV → R
(C) I → Q;II → P;III → R;IV → T
(D) I → P;II → R;III → Q;IV → T

4) Let {x} & [x] denotes the fraction and integral part of a real number x respectively, then match
the List.

List-I List-II

(I) [x] ≥ 4 (P) x ∈ {0}

(II) [x]2 – 7[x] + 12 = 0 (Q) x ∈ [3, 5)

(III) 2x = 3{x} (R) x ∈ [4, ∞)

(IV) –2 < [x] ≤ 1 (S) x ∈ [–1, 2]

(T) x ∈ [–1, 2)
(A) I → R;II → Q;III → P;IV → T
(B) I → T;II → S;III → Q;IV → R
(C) I → S;II → T;III → R;IV → Q
(D) I → Q;II → R;III → T;IV → S

SECTION-II

1) If , then value of 'a' which satisfies is

2) Given . If k represents sum of all real numbers which are not in the range of
f(x) then 16k is

3) The fundamental period of function

is 10k, then value of k is (where [.] denotes greatest integer function).

4) Let f : → be a function such that f (x + y) = f (x) + f (y) for all x, y ∈ , and g : → (0, ∞) be a

function such that g(x + y) = g(x) g(y) for all x, y ∈ . If and , then the

value of is ________ .

5) A polynomial function satisfies f(x) f = f(x) + f , x ≠ 0 and f(3) = –80 then value of |f(5)| is

6) If the number of solutions of |3[x] – 4x|= 4 is λ, then value of λ is (where [.] is greatest integer
function)
 ANSWER KEYS

PHYSICS

SECTION-I(i)

Q. 1 2 3 4
A. A C B B

SECTION-I(ii)

Q. 5 6 7
A. A,B,C,D A,B,D A,B,C,D

SECTION-I(iii)

Q. 8 9 10 11
A. C C B B

SECTION-II

Q. 12 13 14 15 16 17
A. 002 002 000 003 150 006

CHEMISTRY

SECTION-I(i)

Q. 18 19 20 21
A. C A C C

SECTION-I(ii)

Q. 22 23 24
A. A,D B,C B,C,D

SECTION-I(iii)

Q. 25 26 27 28
A. B C A B

SECTION-II

Q. 29 30 31 32 33 34
A. 004 002 040 004 005 003

MATHEMATICS
 SECTION-I(i)

Q. 35 36 37 38
A. D C C C

SECTION-I(ii)

Q. 39 40 41
A. C,D A,B,D B,C,D

SECTION-I(iii)

Q. 42 43 44 45
A. A C A A

SECTION-II

Q. 46 47 48 49 50 51
A. 003 034 006 051 624 008
 SOLUTIONS

PHYSICS

1)

2)

For max. force charges must be equal

and for min. force

3)
max. range

4)

By adding 5 more sheets symmetrically this charge is enclosed by cube

So flux through each of the sheet =

5)
W = ΔU = qΔV

at
C = 18

Vmax = 18 – 0 = 18

and

6) At a centre, the force experienced by the charge particle is zero, so it is a position of

equilibrium. As we displace the charge from the equilibrium position, electric force starts
acting on it towards equilibrium position and hence equilibrium is a stable one.
At a distance x from the centre of sphere (equilibrium position), force experienced by the
charged particle is ,

As F ∝ x, so it performs SHM about the centre. Time period can be

calculated by using F = mω2 x

To calculate speed at the mean position, use energy conservation law.

7)

p=q. =C–m

8) (P)
(Q) Enet = 0

(R)

(S)
P → 2, Q → 1, R → 4, S → 5

9) (P) New Q1, potential is positive ⇒ Q1 is positive

New Q2, potential is negative ⇒ Q2 is negative
For v = 0 and r1 > r2

(Q)
Emis is at midpoint ⇒

Near Q1 : , So, Q1 is positive

Near Q2 : , So, Q2 is negative

(R) Near Q1 : , So, Q1 is positive

Near Q2 : , So, Q2 is negative

 For, E = 0, x1 < x2
E1 – E2 = 0

(S) Near Q1 : , So, Q1 is positive

Near Q2 : , So, Q2 is positive

E = 0 is near Q1
E1 – E2 = 0

10) Explaining the Question :- Drawing field due to different arrangements.

Concept :- Variation of field due to different arrangements.
Solution :-
Final Answer :- Option 2

11)

Charge inside does not affect distribution outside the conductor and charge outside does not
affect distribution inside the conductor

12)

In air :

In liquid :
Equating

13)

14)
So Enet = 0
 15)

Fe = mg

9 × 109 = 0.9 × 10–3 × 10

⇒ q = 3 × 10–6 C
= 3 µC

16)

Dividing R = 10 cm = 0.1 m

and

17)

18 – 2x = 3x – 12
30 = 5x
x=6

⇒ 10 + 2y = 3y
y = 10
dia = 12 m

r=6m

CHEMISTRY
18)

19)

In a reaction : A + B → C + D
Given graph

For a zero order reaction

[B] = [B0] – Kt
So with respect to B, order = O
For A :-

For first order reaction :

Rate rA = K[A]1
rA = KAoe–Kt
ln(rA) = ln (KAo) – Kt
ln (rA) = ln(rAo) – Kt
So with respect to A , order = 1

20)

H.O.C α No. of carbons

(If no. of carbons same)

21)

22)

Explanation : Find true statement(s)

Concept: Order and Molecularity of Reactions

Solution:

0
Step 1: For zero-order, Rate =k (constant) and t1/2 . Halving [A] leaves rate unchanged
but halves t1/2, so statement 1 is true.

Step 2: In zero-order, the rate is constant until the reactant is fully consumed, not "fastest" at
the start.
Statement 2 is false.

Step 3: The stoichiometric rate relation is . The given expression

has an incorrect sign for the product R. Statement 3 is false.

Step 4: Order is an experimental value that can be zero, a whole number, or a fractional
number.
Statement 4 is true.

Final Answer : Option (1, 4)

23) PhCH2Cl + AgNO3 → + AgCl

+ AgNO3 → Aromatic compound

25)

Units of
 except for zero order, rate decreases with time
t1/2 vs [A0] is linear for both zero and first order reactions

26)

Only zero order reactions can be complete (100%) in finite time

Except for zero order, greater [A] value implies greater rate
Zero order reactions can never be elementary

27)

Fact

28)

Fact

29) Tcompletion =
5A(g) → 2B(g) + 3C(g)

t = 0 P0

t=4 0

30)

31) From given mechanism,

rate of reaction =

⇒ Ea = Ea3 + Ea1 – Ea2

= 50 + 10 – 20 = 40 kJ/mol–1

32)

Explaining the Question :-

Question is asking about the aromatic in nature.
Concept:-
This question is based on cyclic, planner, conjuagted system having (4n + 2) πeΘ are aromatic
Solution :-
(1)

(2)

(3)

(4)

(5) due to replusion between H-atom its plannarity distroy and it becomes non-
aromatic in nature

(6)
Final Answer :- (4)

33) Number of hyper conjugative (involving (C – H) bond structure are)

5(As there are 5 ∝ H)

34) Question Explanation: Counting compounds that contain equal C−O bond length.

Concept: Bond Length and Resonance.

Solution:

equivalent R.S. ⇒ All C–O B.L. are equal

Non- equivalent R.S ⇒ All C–O B.L. not equal

⇒ Equivalent R.S.
⇒ All C–O B.L. equal
 ⇒ All C–O B.L. not equal

Final Answer: 3.

MATHEMATICS

35) y =
⇒ y = sinx but sin4x ≠ 0 ⇒ 4x ≠ nπ

36)

37) ƒ(x) = (x + 4)2 + 2

as x ≥ –4 ⇒ ƒ(x) ≥ 2

38)
39)
ƒ is not a function as ƒ(0) is not defined.

40)

(A)
{x} ≠ 0 and {x} ∈ (0,1) ∴ x = ϕ

(B) Domain is R – Z
(C) ∴ Domain = {2024}

(D) Domain is ϕ

41) f'(x) = x2 + x + 1 = 0
Not possible and it is odd degree polynomial

42) (P) f(x) = x + [x] =

f(x) is injective but not surjective.

(Q) f : R → (0, ∞)
Non injective surjective.
(R) f : (0, ∞) → R
f(x) = x3 – 2x2 + 2x + logx

⇒ f'(x) > 0
∴ Always +ve
∴ f(x) is increasing ⇒ one one
Also Range of f(x) is R
∴ f(x) is one one onto
(S) f : [–3, 0] → [cos3, 1]
f(x) = cosx

one one onto

43) Explain question: In this question we have to match number of solutions 'n' in List-I with
range of 'k' in List-II for given equation.

Concept: Based on transformation of graph of function.

Solution: Let f(n) = ||x| – 10| = k

f(n) = ||x| – 10|
f(n) = k

Number of solutions = number of intersections of two curves

f(n) = ||x| – 10| and f(n) = k
Now from graph
(I) For n = 0 (No solution); k ∈ (–∞, 0) (I) (P)
(II) For n = 2 (Two solutions); k ∈ (10, ∞) ∪ {0} (II) (U)
(III) For n = 3 (Three solutions); k ∈ {10} (III) (S)
(IV) For n = 4 (Four solutions); k ∈ (0, 10) (IV) (R)

Final answer: Therefore correct matching list is

(I) (P), (II) (U), (III) (S), (IV) (R)

44) (II) gof(x) = (ℓnx)2 – 1 Domain = (0, ∞)

(III) fof(x) = ℓn(ℓn x)
ℓnx > 0 ⇒ x ∈ (1, ∞)
(IV) gog(x) = (x2 – 1)2 – 1
Domain x ∈ (–∞, ∞)

45)

(I) [x] ≥ 0 ⇒ x ≥ L
(II) [x] = 3, 4 ⇒ x ∈ [3, 5]
(III) x = I + f
2I + 2f = 3f
f = 2I ∈ [0, 1]
f=0
I=0
x=0
(IV) –2 < [x] ≤ 1 ⇒ x ∈ [–3, 2]

46) ∵ ⇒

2 = 2a – 4
a=3

47) ....(1) (x ≠ 6)
∴ Range of f(x) = R – {1} but if x = 6

then (1)
∴ Range

∴ sum

48)
LCM (3, 4, 5) = 60

49)

50) f(x) = 1 + xn or f(x) = 1 – xn 1 + 3n = –80 1 – 3n = –80

3n = –81 3n = 81
n=4
f(x) = 1 – x4
f(5) = 1 – (5)4
= 1 – 625
f(5) = –624

51) 3[x] – 4x = 4 or 3[x] – 4x = –4

–8 < [x] ≤ –4 0 < [x] ≤ 4

[x] = –4, –5, –6, –7 [x] = 1, 2, 3, 4

4 solutions 4 solutions .