03-05-2026

2202CJA101021250059 JA

PHYSICS

SECTION-I(i)

1) A circle of radius R is drawn in a uniform electric field E as shown in the fig. VA, VB, VC and VD are

respectively the potentials of points A, B, C and D on the circle then :-

(A) VA > VC, VB = VD

(B) VA < VC, VB = VD
(C) VA = VC, VB < VD
(D) VA = VC, VB > VD

2) A solid sphere of radius R is charged uniformly. At what distance from its surface is the
electrostatic potential half of the potential at the centre ?

(A) R
(B) R/2
(C) R/3
(D) 2R

3) A point charge having charge '–q' and mass 'm' is released at rest on the axis of a uniformly
charged fix ring of total charge 'Q' and radius 'R' from a distance . Find out its velocity when it

reaches to centre of ring.

(A)

(B)
(C)

(D)

4) A short electric dipole is placed at origin of coordinate system as shown in figure, find the electric

field at point P(0, y) :

(A)

(B)

(C)

(D)

SECTION-I(ii)

1) Electric field in a region is given as /. A charge particle of mass 5 kg and charge Q

(=1C) is situated at origin and free to move in given electric field. Then choose the correct options
(Neglect gravity):-

(A) Motion of charge particle is Oscillatory

(B) Maximum displacement of charge particle from origin is 4 SI units
(C) Maximum velocity gain by charge particle is 2 SI units
(D) The position of charge particle, when velocity gained by particle is maximum, is 2 SI units

2)

A point charge +Q is placed just outside an imaginary hemispherical surface of radius R as shown in
the figure. Which of the following statements is/are correct ?
(A) The circumference of the flat surface is an equipotential
The electric flux passing through the curved surface of the hemisphere is
(B)

(C)
Total flux through the curved and the flat surfaces is
(D) The component of the electric field normal to the flat surface is constant over the surface.

3) X and Y are large, parallel conducting plates closed to each other. Each face has an area A. X is
given a charge Q. Y is without any charge. Points A, B and C are as shown in figure :

(A)
The field at B is

(B)
The field at B is
(C) The fields at A, B and C are of the same magnitude
(D) The field at A and C are of the same magnitude, but in opposite directions

SECTION-II(i)

Common Content for Question No. 1 to 2

The electric potential varies in space according to the relation V = (3x + 4y +5) volts where x and y
are in meters. A particle of mass 10 g starts from point (2m, 3.2 m, 0) under the influence of this
field. The charge on the particle is 10 μC. (Neglect gravity)

1) Find the magnitude of component of electric field in X–direction (in Vm–1).

2) The magnitude of acceleration of particle is k × 10–3 m/s2. Find value of k.

Common Content for Question No. 3 to 4

A charge Q is placed at the corner of cube as shown.

3) If electric flux through EFGH is , what is m ?

4) If electric flux through ABCD is , what is n ?

SECTION-II(ii)

1) A dipole × 10–9 C m is placed at origin. Calculate potential (in volt) at a point having
coordinate (1m , m)

2) Five positive equal charges are placed at vertices of a regular hexagon and net electric field at
the centre is E1. A negative charge having equal magnitude is placed sixth vertex and then net

electric field is E2. Find .

3) A solid sphere of radius R has a charge Q distributed in its volume with a charge density ρ = kra,
where k and a are constants and r is the distance from its centre. If the electric field at r
= is times that at r = R, find the value of a.

4) A point charge q is placed inside a conducting spherical shell of inner radius 2R and outer radius
3R at a distance of R from the centre of the shell. The electric

potential at the centre of shell will be Then the value of x is ___.

5) Dipole is placed parallel to the electric field. If W is the work done in rotating the dipole by 60º
and work done in rotating it by 180º is N time W. Fill the value of N.

6) A metal sphere of radius m is electrically neutral. A point charge 9 × 10–9 C is brought near the
conducting sphere and placed at a distance L = 1 m from the centre of the sphere. Find the electric
field (in v/m) at the centre of the sphere due to charges induced on the sphere.

CHEMISTRY

SECTION-I(i)
1) (A). Most stable resonating structure for (A) is :-

(A)

(B)

(C)

(D)

2) The dominating factor for stability of t-Butyl carbocation is :

(A) Resonance effect of CH3

(B) Inductive effect of CH3
(C) Hyper conjugation of CH3
(D) Electromeric effect of CH3

3) The half-life of a zero order reaction : A → Product is 1 hour when initial concentration of reactant
is 2 mol/lit. The time required to decrease concentration of A from 0.50 to 0.35 mol/lit. is __________.

(A) 15 min.
(B) 9 min.
(C) 21 min.
(D) 4.5 min

4) A → D is an endothermic reaction occurring in three steps (elementary).

(i) A → B ΔHi = +ve
(ii) B → C ΔHii = –ve
(iii) C → D ΔHiii = –ve
Which of the following graphs between potential energy (y-axis) vs reaction coordinate (x-axis)
correctly represents the reaction profile of A → D ?

(A)

(B)

(C)

(D)

SECTION-I(ii)

1) Hyperconjugation can be possible in

(A)

(B)
(C)

(D)

2) For a first order reaction : R → B + C ; the correct option (s) is/are :

(A) The pre exponential factor (A) in Arrhenius equation has unit of time-1.
(B) It takes infinite time for completion.
(C) The degree of dissociation of Reactant is equal to (1 – ekt).
(D) The reaction can be bimolecular.

3) 2X (g) + Y(g) + 3Z (g) → Products The rate equation of above reaction is given by
0
Rate = K [X]1 [Y] [Z]2
Choose the correct statement(s).

(A) If 75% of X undergoes reaction in 20 sec, 50% of X will react in 10 sec when [z] >> [x]
(B) Rate of reaction decreases by reducing the concentration of Y to half of the original value
(C) The half life of Z increases by increasing its concentration when [x] >> [z]
(D) On doubling the concentrations of X,Y & Z, rate of reaction becomes 8 times

SECTION-II(i)

Common Content for Question No. 1 to 2

A student conducted an experiment to investigate the chemical kinetics of a particular bacterial

growth. In this experiment, approximately 100 bacteria were initially placed in a flask containing
nutrients at a temperature of 35ºC.
The number of bacteria was recorded at various time intervals, and the results were as follows :

Time (in min.) 0 5 10 15 20

Number of bacteria 100 200 300 400 500

[log10 2 = 30, log10 2.75 = 0.44]

1) How much time (in min.) it would take for number of bacteria to become 275?

2) What is rate of reaction (in terms of number of bacteria per second )at 5 min?

Common Content for Question No. 3 to 4

Identify following compounds
(a) (b) (c)

(d) (e) (f)

(g) (h)

3) Number of (+M) group attached with phenyl ring?

4) Number of (–M) group attached with phenyl ring?

SECTION-II(ii)

1) In how many of the following compounds Hyperconjugation effect is observed –

2) The carbocation among following which are more stable than allyl carbocation

( )

(i) (ii) (iii) (iv) (v)

(vi) (vii) (viii) (ix) (x)

3) The reaction : A(g) + 2B (b) → C(g) + D(g) is an elementary process. In an experiment, the initial
partial pressure of A and B are PA = 0.60 atm and PB = 0.80 atm. When PB = 0.20 atm, the rate of
reaction, relative to the initial rate is _______.
4) For the following parallel first order gaseous reactions:

Initially only A(g) is present in the rigid vessel at 1 atm. After 15 seconds the total pressure inside
the vessel is 2.1 atm. At infinite time the pressure inside the vessel becomes 3.2 atm. What is the
value of k1.
Given [ln 2 = 0.7]
y k = x.10–y
Find gretest integer value of x and then calculate x + y :

5) For the reaction A(g) → nB(g), the rate constant is 6.93 × 10-4 s-1. The reaction is performed at
constant volume and temperature, starting with pure A(g). If after 1000 s from the start of reaction
the pressure of system becomes 2.3 times the initial pressure, the value of n is _________.

6) The rate of a reaction quadruples when the temperature changes from 293 K to 313 K. Caculate
the energy of activation in KJ mol-1 . Assuming that it does not change with temperature.

MATHEMATICS

SECTION-I(i)

1) Let , such that ƒ(x) = 0 for every x

∈ R, then the number of values of θ in [0,10π] is equal to (where sgn x denotes signum function of x)

(A) 10
(B) 5
(C) 11
(D) 6

2)

If , then the maximum value of is equal to-

(A)
(B)
(C) 1
(D)

3) If ƒ(x) is defined in [–1,2], then find the number of integer in the domain of function y =
ƒ([|x|]) (where [.] is greatest integer function)

(A) 3
(B) 5
(C) 6
(D) 7

4) Let f : [–1, 3] → [–40, 27] be a function

given by f(x) = 2x3 – 6x2 – 18x + 17,
then f(x) is

(A) one-one and onto

(B) many-one and onto
(C) one-one and into
(D) many-one and into

SECTION-I(ii)

1) If ƒ : R → R be a function such that , then ƒ(x) is

(where Q is the set of rational numbers)

(A) one-one function

(B) many-one function
(C) into function
(D) onto function

2) Which of the following functions is/are an odd function ?

(A)

(B)

(C) ƒ(x) = (x3 + x)|sinx|

(D) ƒ(x) = 2

3) Which of the following pair of functions are NOT identical ?

(A) and

(B)
and

(C)
ƒ(x) = tanx and

(D)
and g(x) = sgn(x)
 SECTION-II(i)

Common Content for Question No. 1 to 2

The number of solution of the equation f(x) = g(x) is the number of points of intersection of the
graphs y = f(x) and y = g(x).

1) Number of roots of the equation |sin 2x| = cosx in -

2) Number of roots of the equation |x2 – 2x – 5| = λ, where 0 < λ < 6 is -

Common Content for Question No. 3 to 4

Let f (x) = | x + 1 | – | x – 4 | , x ∈ R.

3) If the equation f (x) = b has atleast one real solution then the number of integral values in the
range of b, is

4) If the equation has exactly two real solutions then the number of integral values in the
range of b, is

SECTION-II(ii)

1) Number of integers present in the range of function is....

2) If and ƒ(x) = k has four distinct solutions. If k1 and k2

be smallest and largest integral values of k respectively then is :-

3) Number of integral value(s) of x satisfying the given inequality is (where [.] denotes
greatest integer function)

4) Let f(x) = then find the value of the sum

5) The maximum value of ƒ(x) = log5(3sinx + 4cosx + 20) ∀ x ∈ R is

6) Number of integral points in the domain of ƒ(x) = is:

 ANSWER KEYS

PHYSICS

SECTION-I(i)

Q. 1 2 3 4
A. C C D A

SECTION-I(ii)

Q. 5 6 7
A. A,B,C,D A,B A,C,D

SECTION-II(i)

Q. 8 9 10 11
A. 3.00 5.00 0.00 24.00

SECTION-II(ii)

Q. 12 13 14 15 16 17
A. 3.00 2.00 2.00 24.00 4.00 81.00

CHEMISTRY

SECTION-I(i)

Q. 18 19 20 21
A. C C B C

SECTION-I(ii)

Q. 22 23 24
A. A,B,C A,B A,D

SECTION-II(i)

Q. 25 26 27 28
A. 8.75 0.33 4.00 4.00

SECTION-II(ii)

Q. 29 30 31 32 33 34
A. 3.00 2.00 0.03 6.00 3.60 105.38

MATHEMATICS
 SECTION-I(i)

Q. 35 36 37 38
A. B C B C

SECTION-I(ii)

Q. 39 40 41
A. B,C A,C A,B,C,D

SECTION-II(i)

Q. 42 43 44 45
A. 4.00 4.00 11.00 7.00

SECTION-II(ii)

Q. 46 47 48 49 50 51
A. 1.00 0.50 0.00 1003.50 2.00 3.00
 SOLUTIONS

PHYSICS

1) Along E, V ↓ and ⊥r to E, V → same

2) VC =

V' =

r=

From surface =

3)

Explain the question : Question is asking for velocity of the charge particle when it reaches
to the center of the charged ring after being released along its axis.
Concept : This question is based onconservation of energy and Electrostatic potential energy.
Solution :-

By law of conservation of energy

+0 =

Final answer :- The correct answer is option (4)

4) EP =

E1 =
E2 =

Ep =

∴ EP =

5)
m = 5kg

(a) F ∝ – x
so motion of charge particle is oscillatory
(b) F = 0 at x = 2
oscillation about x = 2
so maximum displacement is 4
F = 10 – 5x

a=2–x
a = –(x – 2)
so ω2 = 1
ω=1
(c) vmax = Aω
A=2
ω=1
vmax = 2
(d) velocity at mean position
at x = 2

6)

Every point on circumference of flat surface is at equal distance from point charge
Hence circumference is equipotential.
Flux passing through curved surface = – flux passing through flat surface.

(dϕ)through the ring = E cosθ. dA

∴

∴ Flux through curved surface =

Note : Flux through surface can be calculated using concept of solid angle.

Ω = 2π(1 – cos θ) = 2π

∴ Solid angle subtended =

ϕ for 4π solid angle =

∴ f for 2π solid angle =

7) (A)
At point B field will be due to plate X only since net charge on y is zero.

(C) Field at A, B, C will have same magnitude i.e. and direction at B & C will be
in right whereas at A it will be in left.

(D) Magnitude at A, C will be but on C direction will be rightward whereas for A it will
be leftward.

8)

9) |E| = 5
 |E| = 5​​

10) Flux through whole cube

because charge is at corner.

because field line will be parallel to surface.

Also

So,

11) Flux through whole cube

because charge is at corner.

because field line will be parallel to surface.

Also

So,

12) = 3 V.

13)

14)
E(R/2) =

2a+1 = 23
a=2

15) Induced charges will be -q and +q as shown in figure.

16) Work (W) = pE ( cos 0 – cos 60) = pE ( 1 – ½) = pE/2

Work (W’) = pE ( cos 0 – cos 180) = pE ( 1- (-1)) = 2pE = 2(2W) = 4W

17)
CHEMISTRY

18) Stability of R.S ∝ no of π bond.

19)

Explaining the Question :-

Question is asking about the dominating factor for stability of f-Butyl carbocation is
Concept:-
This question is based on hyper-conjugation
Solution :-

total 9 ∝–H, compound is stabilized by hyper conjugation.

Final Answer :- (3)

20) For zero order,

21) Given :
A → D ; ΔrH = (+)ve = ED – EA \ ED > EA
Mechanism
A → B ; ΔrH = (+)ve ⇒ EB > EA
B → C ; ΔrH = (–)ve ⇒ EC < EB
C → D ; ΔrH = (–)ve ⇒ ED < EC

22) Question Explanation: Identifying the species in which hyperconjugation is possible.

Concept: This question is based on condition of hyperconjugation.

Solution:

Hyperconjugation requires the presence of at least one α-hydrogen attached to an sp³-

hybridized carbon that is adjacent to:
 A. a multiple bond (C=C or C≡C),

B. a carbocation (C⁺), or

C. a free radical (C∙).

However, in option 4, there is no α-hydrogen attached to an sp³ carbon adjacent to the

unsaturated center. Therefore, hyperconjugation is not possible in that case.

Final Answer:
The correct options are (1, 2, 3)

23) Ans. (A, B, D)

x = [A]0 – [A]t
x = [A]0 – [A]0 e-kt
x = [A]0 (1 - e-kt)

degree of dissociation of

24) 2X(g) + Y(g) + 3Z(g) → Product

0
Rate = K[X]1 [Y] [Z]2
(A) If [Z] > > [X]
It means [Z] does not react as compare to [X]
0
Rate = K[Z]2 [X]1 [Y]
K[Z]2 = K1 = new rate constant
So new rate law
Rate = K1[X]1 (First order reaction)

0
(B) Rate = K[X]1 [Y/2] [Z]2 = K[X] [Z]2
(C) It [X] > > [Z]
It means [X] does not react as compare to [Z]
So [X] (Neglected in rate law)
So new rate law
0
Rate = (K[X]) [Y] [Z]2
K[X] = K” = new rate constant
Rate = K’[Z]2 (second order)

half life t1/2 =

 A0 ↑ t1/2 ↓
0
(D) Rate = K[X]1 [Y] [Z]2
if [X], [Y], [Z] double
0
Rate1 = K[2X] [2Y] [2Z]2
0
= K2[X] [Y] 4[Z]2 ⇒ 8K[X] [Z]2

25) Ans. 8.75

26) By observing data, reaction is of zero order.

200 = 100 + k (5) ……. (i),

275 = 100 + k(t) …….. (ii)
Form equation (i) and (ii), k = 20 (bacterial/min)
and t = 8.75 min.

rate of rxn = k

27) Explanation:
To identify groups showing +M.E.
Concept:
This Question is based on Mesomeric effect.
Solution:
Groups having l.p. or –ve change on connecting atom will show +ME.

a)
b)

e)
f)
Final Answer: 4

28) Question Explanation:

The question asks how many substituents attached to a phenyl ring show −M (−Mesomeric)
effect, i.e., withdraw electrons through resonance.

Concept:
Mesomeric Effect, Electron Withdrawing Groups, Resonance Effect.

Solution:
Groups showing −M effect withdraw electron density from the benzene ring by resonance (π-
 electron withdrawal).Analyse each substituent:

A. (a) –OH → +M (lone pair donation)

B. (b) –NH2 → +M
C. (c) –NO2 → −M
D. (d) –COCH3 → −M (carbonyl group)
E. (e) –OCH3 → +M
F. (f) –NHCH3 → +M
G. (g) –SO3H → −M
H. (h) –CHO → −M

So, −M groups are (c), (d), (g), and (h).

Final Answer: 4

29) Hyperconjugation effect is observed in B, C and G compounds.

30) Carbocation (i) & (vi) are more stable, than allyl carbocation stability order : →

> >

31)

32) ln 2 = 0.7

37.33 × 10–3
3.733 × 10–2
3.7 × 10–2
 33)

34)

Ea = 52863 J mol-1

MATHEMATICS

35)

Question Explanation: Finding the number of solutions for \theta when a signum function is
identically zero.

Concept: Signum Function and Trigonometric Equations

Solution: Given for all x.

This implies:

For and , the general solution is:

In the interval :
 For

For

For

For

For

(The next value exceeds the range).

Total number of values = 5.

Final Answer: 5

36)

Question Explanation: Finding the maximum value of a trigonometric fraction using

identities.

Concept: Trigonometric Transformation Formulae

Solution:

∴ ƒ(x)max = 1

Final Answer: 1

37) –1 ≤ [|x|] 2
⇒ –1 ≤ |x| < 3
⇒ 0 ≤ |x| < 3
⇒ –3 < x < 3
⇒ Number of integer in the domain = 5.

38) ƒ(x) = 2x3 – 6x2 – 18x + 17

Range of ƒ(x) ∀ x ∈ [–1, 3] is [–37, 27]
⇒ ƒ is into.
Also ƒ'(x) < 0 ∀ x ∈ [–1, 3]
⇒ ƒ is one one.
39) ƒ(3) = ƒ(51/6) = 0

Hence manyone
ƒ(x) ≠ –51/2 Hence into

40) ƒ(x) + ƒ(–x) = log + log

2 2
= log(1 + x – x ) = 0, odd function

(B) ƒ(x) =

ƒ(–x) = = ƒ(x), even function

3
(C) ƒ(x) = (x + x) |sinx|
ƒ(–x) = –(x3 + x) |sinx| = –ƒ(x), odd function
(D) ƒ(x) = 2

41) (A) ƒ(x) = |x| , g(x) = x NOT Identical

(B) , NOT Identical

x ∈ (–∞, 2) ∪ (3, ∞), x ∈ (3,∞)

(C) ƒ(x) = tanx ,

NOT Identical

(D) , g(x) = sgnx

NOT Identical

42)
Number of roots = 4

43)
∴ Number of roots = 4

44) f (x) =

Range of f (x) is [–5, 5]

∴ for atleast one solution b ∈ [–5, 5]
∴ Number of integers are 11.

45) ∴ For exactly two solution b ∈ [–3, 5]

∴ Number of integers are 7.

46)

Domain -1≤x≤2

range

47)
So, k ∈ (0, 3)
k1 = 1, k2 = 2

48)

not possible

49) If
then f(x) + f(1 – x) = 1 ∀ x ∈ R

50) y = log5(3sinx + 4cosx + 20)

maximum value of 3sinx + 4cosx is '5'
⇒ ymax = log5(5 + 20) = log5(25) = 2

51)

⇒ integral values of x are 2,3,4