25-04-2026

1001CJA101021260010 JA

PART-1 : MATHEMATICS

SECTION-I

1) Tangent from to y2 = x3 passes through -

(A) (4, 8)
(B) (1, –1)
(C) (1, 1)
(D) (3, 4)

2) If and y(1) = 1, then

(A)
(B)

(C)

(D)

3) In a triangle ABC, if B = 30o and , then A can be equal to –

(A) 30o
(B) 60o
(C) 90o
(D) 120o

4) If tangent to curve 2y3 = ax2 + x3 at point (a,a) cuts off intercepts α, β on co-ordinate axes, where
, then the value of 'a' is equal to

(A) 20
(B) 25
(C) 30
(D) –30

5) If f(x) = . Range of f(x) is [α, β] then

(A) 32 (α + β) is a prime number .

(B) Number of integers in range of f(x) is 0
(C) Posible integeral values of f(x) is 0 or 1

(D)
β–α=

SECTION-II (i)

Common Content for Question No. 1 to 2

Consider the function . Let ƒ1(x) = |ƒ(|x|)|.

1) If ƒ(x) is continuous in [–2,10] then the value of (α + k) is-

2) If ƒ(x) is continuous in [–2, 10], then the number of points where ƒ1(x) is NOT differentiable be -

Common Content for Question No. 3 to 4

Let A = {1, 3, 5, 7} and B = {2, 4, 6, 8} are two sets and let be a function, then number of
functions 'f' possible for

3) f(i) i +1 , is

4) f(i) 6 , is

Common Content for Question No. 5 to 6

Consider the function (where [.] denotes greatest integer function)

5) Number of real solution(s) of equation ƒ(x) = 3 – (x – 3)2 is -

6) Number of integers in the domain of ƒ(x) is-

SECTION-II (ii)

1) If a, b, c are sides of the , then value of sin2A + sin2B + sin2C is equal to

2) Let f(x) = x5 + 2ex/4 for all x ∈ R. consider a function g(x) such that gof (x) = x for all x ∈ R. Then
the value of 8g'(2) is

3) If the solution set of is then

is

4) If f and g are two real valued differentiable functions such that

f(x) = x2 + g'(0)x + g''(1) and
g(y) = y2 + f"(y) + f'(y) – 2 then

is equal to

SECTION-IV

1) Match Column-I with Column-II.

Column-I Column-II

If the exhaustive set of x satisfying

(A) is then an integer belongs to is (where [.] (P) 3
is greatest integer function)

Number of point of non-differentiability of f(x) = max{1 –

(B) (Q) 5
x, 1 + x, 2} is less than or equal to

(C) (R) 8
For the function then number
points of discontinuity of in

(D) The value of x for which is (S) 1

always less than or equal to

(T) 4

2) Let ƒ(x) = , then

Match Column-I with Column-II.

Column-I Column-II

(A) y = ƒ(x) is (P) Continuous at x = 0

(B) y = xƒ(x) is (Q) Discontinuous at x = 0

(C) y = x2ƒ(x) is (R) Differentiable at x = 0

(D) (S) Non-differentiable at x = 0

is

(T) Periodic function

PART-2 : PHYSICS
 SECTION-I

1) Two small steel balls are suspended on weightless inextensible threads, as shown in figure. Mass
of the balls 'm' are equal, the lengths of the thread is ℓ1 and ℓ2 (ℓ1 > ℓ2) respectively. The first ball m1
is deflected by an angle θ and released. The collision is perfectly elastic. The air resistance can be

neglected. [The questions asked are in regard to first collision only].

(A) The speed of m1 before it collides with m2 is

(B) The magnitude of change in momentum of m1 due to collision with m2 is

The momentum of m2 just after collision is
(C)

(D) The angle α deviated by m2 after being hit by m1 is θ.

2) The displacement-time graph of a particle executing SHM is shown. Which of the following

statements is/are true?

(A) The velocity is maximum at t = T/2

(B) The acceleration is maximum at t = T
(C) The force is zero at t = 3T/4
(D) The potential energy equals the oscillation energy at t = T/2.

3) Light rays are incident on a interface separating two medium parallely. Then which of the
following will be true?
(A) In figure-1, rays will converge if µ2 > µ1.
(B) In figure-1, rays will diverge if µ2 > µ1.
(C) In figure-2, rays will converge if µ2 > µ1.
(D) In figure-2, rays will diverge if µ2 > µ1.

4) Two conducting spheres of radii R and 3R carry charges Q and –2Q. Between these spheres a
neutral conducting sphere of radius 2R is connected. The separation between the sphere is

considerably large then :

(A)
The final charge on initially neutral conducting sphere is .

(B)
The decrease in electric potential energy of sphere of radius R is .

(C)
The decrease in electric potential energy of sphere of radius R is .

(D)
The final electric potential of sphere of radius 3R will be .

5) Figure shows two uniform charged concentric spherical shells. Both charges are positive. Select

correct statement(s).

(A) Electric field intensity at B may be greater than electric field intensity at C.
(B) Electric field intensity at B must be greater than electric field intensity at C.
(C) Potential at A is greater than potential at B.
(D) If a charge moves from B to C work done by electric force must be positive.

SECTION-II (i)

Common Content for Question No. 1 to 2

Acceleration vs position graph for a particle whose mean position is at x = 0 is given as shown
below, answer the following questions.

1) Time period (in sec) of SHM of particle is :

2) Maximum possible velocity (in m/s) of particle during the SHM is

Common Content for Question No. 3 to 4

A semi cylinder made of a transparent plastic has a refraction index of n = √2 and a radius of R.
There is a narrow incident light ray perpendicular to the flat side of the semi cylinder at d distance

from the axis of symmetry.

3) What can the maximum value of d (in cm) be so that the light ray can still leave the other side of
the semi cylinder? [Take : R = 10 cm]

4) When the value of d chosen is such that TIR just takes place then time (in nanoseconds) for which
light remains inside the cylinder is (take R = 9cm & C = 3 × 108 m/s)

Common Content for Question No. 5 to 6

In a uniformly charged fixed nonconducting sphere, a very thin tunnel has been made along the
diameter as shown in figure. A charge particle –q having mass m is released from rest at t = 0 at one
end of the tunnel. Total charge Q of sphere is uniformly distributed in its volume. Charge particle

reaches at the centre of solid sphere first time at with speed .

5) The value of N is______

6) The value of α is ________

SECTION-II (ii)

1) A bead can slide on a smooth straight wire and particle of mass m is attached to the bead by a
light string of length L. The particle is held in contact with the wire with the string taut and is then
let fall. The bead has mass 2m. Then, when the string makes an angle θ = 60°, determine the

distance (in m) which the bead slips on the string if L = 12 m.

2) A curved thick glass surface is silvered at curved face & not silvered on plane surface. Object is
placed at A as shown in figure. Considering P (pole of the silvered surface) as origin, if x - co-
ordinate of final image is 'n' cm then find n.

3) From a uniformly charged solid sphere a cavity is removed as shown in the figure. Now a tiny
dipole of dipole moment is kept at the centre of cavity. If the work done in rotating the dipole by
180° is find x. (ρ is volume charge density)

4) The initial velocity vi required to project a body vertically upward from the surface of the earth to
reach a height of 10R, where R is the radius of the earth, may be described in terms of escape

velocity ve such that . The value of n will be ________.

SECTION-IV

1) Using the lens maker formula, relate the focal length of thin lens in Column-I with value in
Column-II. (Consider positive for converging and negative for diverging.)

Column-I Column-II

(A) (P) 4R

(B) (Q) –2R

(C) (R) –4R

 (D) (S) 2R

(T) R

2) Variation of electric field along the line joining two charges is given in Column-I. Relation
between charges is given in Column-II. Match the proper variation. Take electric field along right
as positive.

Column-I Column-II

|q1| > |q2|

(A) (P)
q1 < 0; q2 > 0

|q1| = |q2|
(B) (Q)
q1 > 0; q2 > 0

|q1| = |q2|
(C) (R)
q1 < 0; q2 > 0

|q2| > |q1|

(D) (S)
q1 > 0; q2 > 0

(T) None of these

PART-3 : CHEMISTRY

SECTION-I
1) An ionic solid consists of A+2 and B–2 ion, having formula of AB. Identify the correct
statement(s) regarding unit cell and location of ions.

(A) Simple cubic of B–2 ions and A+2 occupying all the body centered voids or cubic voids.
(B) Face centered cubic of B–2 ions and A+2 occupying all tetrahedral voids.
(C) Face centered cubic of B–2 ions and A+2 occupying 50% tetrahedral voids.
(D) Face centered cubic of A+2 ions and B–2 occupying all tetrahedral voids.

2) Which of the following solution(s) is/are isotonic with respect to 0.5 M aqueous NaCl solution in
which NaCl is 80% ionized ? [Atomic mass : Na = 23, S = 32]

(A) 153.9gm of Sucrose dissolved in 500ml of solution.

(B) 0.3 M aqueous Na2SO4 solution undergoing 100 % ionization
(C) 1.8 % (w/v) aqueous NaOH solution undergoing 100 % ionization.
(D) 1.2 M benzoic acid in a solution of benzene where the acid dimerizes to an extent of 50 %.

3) If (P) and (Q) are major products, then find incorrect statement for given reaction sequence :

(A) Formation of (Q) from (P) is an example of syn addition

(B) Formation of (P) is an example of unimolecular elimination reaction.
(C) Product (P) does not give bromine water test.
(D) Product (Q) is optically inactive due to external compensation.

4) For the reaction sequence given below

If x, y and z are possible alkenes in the reaction and stability order is x > y > z, then correct
statement(s) is/are :

(A) Product x, y and z can be distinguish by test of unsaturation.

(B) Product x gives meso product on reaction with HCl/CCl4
(C) Product y gives Markovnikov product as major product on reaction with H–Br/CCl4
(D) Product Z is major product in given reaction

5) When H2 is adsorbed on a metallic surface, electron transfer occurs from the metal to H2. The
TRUE, statement(s) regarding this adsorption is (are)

(A) H2 is chemisorbed.
(B) heat is released
(C) occupancy of σ* of H2 is increased
(D) bond length of H2 is increased

SECTION-II (i)

Common Content for Question No. 1 to 2

Initially at t = 0, gas A was present along with some amount of gas C, and initial pressure of gas A is
same as that of gas C. After some time t = t1, total pressure is found to be 22.5 bar and after very
long time total pressure is 40 bar. Assume this decomposition is a first order, at a constant
temperature. (Take ℓn10 = 2.3)

1) If t1 = 1.15 seconds and rate constant is then value of 'X' is _______

2) At t = t1 partial pressure of gas B (in bar) is :

Common Content for Question No. 3 to 4

Dehydrohalogenation of alkyl halide in presence of base gives Saytzeff's product as major product by
E2-elimination reaction which is one step reaction and it is example of anti-elimination.

products
Consider the above reaction and give answer of following questions.

3) Possible number of alkenes is :

4) Number of α-hydrogen in Saytzeff alkene is -

Common Content for Question No. 5 to 6

Total number of electrons on central metal including those transferred from ligands is known as
EAN.
The EAN generally coincides with the atomic with the atomic number of next inert gas except in
some cases.

5) EAN value for brown ring complex is

6) The maximum number of CO ligands having same bond length in Fe2(CO)9.

 SECTION-II (ii)

1) Calculate mass of CaBr2 (in gram) required to prepare 960 gm of aqueous solution having
depression in freezing point of solution equal to 2K. (Kf of H2O = 2K-kg/mole) (Atomic mass of Ca =
40, Br = 80) ?

2) An electron practically at rest is initially accelerated through a potential difference of 100 volts.
Then it had de-Broglie wave length . When electron is accelerated from rest by potentials of 81
volts and 49 volts its de-Broglie wavelength was found to be respectively. If

then value of X is ______

3)

How many moles of ions will form on dissociation of Pentaamminechloroplatinum (IV) chloride in
aqueous solution.

4) Number of π bonds in o-phen is x.

Number of chiral centres in 'pn' and 'bn' are respectively 'y' & 'z'

Find value for :

SECTION-IV

1) Match the column :

Column-I Column-II
(Name of reaction/Test) (Reagent)

(A) Finkelstein reaction (P) SbF3

(B) Swart reaction (Q) HCl + Anhy. ZnCl2

(C) Darzen's halogenation reaction (R) NaI/acetone

(D) Lucas test (S) SOCl2

(T) NaOH/Δ
Match correct reagent/with given reaction/test.

2) Match the column

Column-I Column-II
(molecules) (molecules)

(A) H2S2O5 (P) Central atom is sp3 hybridised

2–
(B) H6B2O7 (Q) M–O–M i.e. oxo linkage is present
 H4P2O6
(C) (R) M–M linkage is present
(tetrabasic)

(D) H6Si2O7 (S) Non planar

(T) Monoprotic acid

 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I

Q. 1 2 3 4 5
A. C,D A,C A,C C,D A,B

SECTION-II (i)

Q. 6 7 8 9 10 11
A. 4.00 9.00 81.00 16.00 0.00 2.00

SECTION-II (ii)

Q. 12 13 14 15
A. 2.25 16.00 4.00 17.10

SECTION-IV

Q. 16 17
A. A->PQRT,B->PQRT,C->T,D->PQRST A->QS,B->PS,C->PR,D->QS

PART-2 : PHYSICS

SECTION-I

Q. 18 19 20 21 22
A. A,B,C B,C,D A,C A,B,D A,C

SECTION-II (i)

Q. 23 24 25 26 27 28
A. 3.14 10.00 7.00 to 7.08 1.20 4.00 1.00

SECTION-II (ii)

Q. 29 30 31 32
A. 2.00 14.00 3.00 10.00

SECTION-IV

Q. 33 34
A. A->S,B->P,C->Q,D->R A->S,B->R,C->Q,D->P

PART-3 : CHEMISTRY
 SECTION-I

Q. 35 36 37 38 39
A. A,C A,B,C,D A,C,D C,D A,B,C,D

SECTION-II (i)

Q. 40 41 42 43 44 45
A. 49.00 2.50 3.00 9.00 37.00 6.00

SECTION-II (ii)

Q. 46 47 48 49
A. 60.00 20.00 4.00 4.00

SECTION-IV

Q. 50 51
A. A->R,B->P,C->S,D->Q A->PRS,B->PQS,C->PRS,D->PQS
 SOLUTIONS

PART-1 : MATHEMATICS

1) Let tangent at (t2, t3) passes through

⇒ 2t3 + 1 = 3t3 ⇒ t = 1

⇒ Equation of tangent is
⇒ 2y – 2 = 3x – 3 ⇒ 3x = 2y + 1

2)
Differentiating w.r.t.x, we get

3)

Given ;

⇒ sinC =

or 120°
or 30°
Hence, answer is option (1) & (3).

4)
Tangent at (a,a) is 5x– 6y = – a
(a,a) 5x – 6y = –a

α= ,β =

5) (sin–1 x)3 + (cos–1 x)3 = (sin–1 x + cos–1 x)3 – 3sin–1 x cos–1 x (sin–1 x + cos–1 x)

Hence

6) ƒ(4–) = 2, ƒ(4+) = k ⇒ k = 2
& ƒ(5–) = k – 1, ƒ(5+) = log10(5α)
⇒ log10(5α) = 1
⇒ 5α =10 ⇒ α = 2
∴k+α=4

7) ƒ(4–) = 2, ƒ(4+) = k ⇒ k = 2 & ƒ(5–) = k – 1, ƒ(5+) = log10(5α)

⇒ log10(5α) = 1
⇒ 5α =10 ⇒ α = 2
∴k+α=4

8) for any i ∈ A, we have 3 choices.

9) For 1,3,5,7 ∈ A we have 2,2,2,2 choice respectively.

10)

If x ∈ [2,3), then ƒ(x) = 3

x ∈ [3,4), then ƒ(x) = 2
11) where [x] > 0, [x] ≠ 1
⇒

12)

13) f(x) = 2
when x = 0
∵ g'(f(x)) f '(x) = 1

∵
g'(2) = 2

14)

.....(i)
All terms on LHS are , so (i) is

valid when

15) Let g'(0) = a, g''(1) = b

∴ f(x) = x2 + ax + b
 f'(x) = 2x + a
f''(x) = 2
∴ g(y) = y2 + 2 + (2y + a) – 2
g(y) = y2 + 2y + a
g'(y) = 2y + 2 ⇒ g'(0) = 2 = a
g''(y) = 2 ⇒ g''(1) = 2 = b
∴ f(x) = x2 + 2x + 2 a = 2, b = 2
g(y) = y2 + 2y + 2

16) (A) [5x] + [4x] + [3x] = 2

⇒ [3x] = 0, [4x] = 1, [5x] = 1
⇒ 0 ≥ 3x < 1, 1 ≤ 4x < 2, 1 ≤ 5x < 2

∴
[8a,27b) = [2,9)

(B)
Not differentiable at x = 1,–1

(C)

Discontinuous at x = –2, –1, 0, 1

4 points
 (D) (sin–1 x)2 – (cos–1 x)2 ≥

⇒ sin–1 x – cos–1 x ≥

⇒ sin–1 x ≥

⇒ sin–1 x =
⇒ x=1

17)
L.H.L. at x = 0

R.H.L. at x = 0

L.H.L. ≠ R.H.L. ≠ ƒ(0)

⇒ discontinuous at x = 0

y = xƒ(x) =
L.H.L. at x = 0

R.H.L. at x = 0

continuous at x = 0
Now
L.H.D. at x = 0

R.H.D. at x = 0

⇒ Not differentiable at x = 0
Similarly (R) and (S) options can be checked.

PART-2 : PHYSICS

18) In D ; because ℓ1 > ℓ2 so θ will not be the same.

19) Question Explanation:
Identifying true statements about a particle's SHM from its displacement-time graph.
Concept:
This question is based on relationship between displacement, velocity, acceleration, force, and
energy in SHM.
Solution:
Velocity is maximum at mean position & acceleration is maximum at extreme position. At
mean position acceleration is zero.
The force is zero at t = 3T/4, This statement is correct because 3T/4 is the mean position.
The potential energy equals the oscillation energy at t = T/2. This statement is correct because
T/2 is extreme position so velocity is zero.
Final Answer :
The correct option is (2), (3) and (4).

20) Power of the surface =

If µ2 > µ1 ⇒ Power = +ve
⇒ Rays will be converged.
If µ2 < µ1 ⇒ Power = –ve
⇒ Ray will diverge

21) Finally potential on all sphere will be equal

and

, ,

22) Since, both charge are positive Þ potential at A > potential at B. Also, may be greater

than .

23) Aω2 = 20; A = 5

ω2 = 4
ω=2

24) Vmax = Aω = 5 × 2 = 10 m/s

25)

26)
Total distance travel in the semi cylinder =

optical path travel = ,

time = =

27)

⇒ SHM with MP at the centre of sphere

v = vmax = Aω =

28)

⇒ SHM with MP at the centre of sphere

v = vmax = Aω =

29)
2M rightward

30) cm

cm.
for final image (refraction through plane surface) we can write.

x = 10 cm
so distance from P is 14 cm.

31)

x=3

32) Question Explanation : Find launch speed to reach height 10R

Concept: Gravitational potential energy Solution: The body is projected upward from Earth's
surface (radius R) to a maximum height 10 R above the surface, so the final distance from
Earth's center is 11 R. Using energy conservation, initial mechanical energy equals final

mechanical energy.

Final Answer : n = 10

33)
for plane surface, R → ∞

P→
Q → f = 4R

R→

S→
 34) Apply the following tests :-
(1) Electric field will be zero in between the charges only if the charges are of same nature.
(2) E.F. will be zero in between the charges, closer to the smaller charge
(3) E.F. may be zero on outer side of charges (on the line joining them), if they are unequal,
closer to the smaller charge.

PART-3 : CHEMISTRY

35) Required formula of AB only exist in option (A) and (C).

(A) B–2 → simple cubic → 1
A+2 → cubic voids → 1
(C) B–2 → FCC → 4
A+2 → 50% of tetrahedral voids → 4

36) For NaCl :-

ic = 0.5 × [l + (2 – l) 0.8] = 0.9 M
For Sucrose solution :–

For Na2SO4 solution :–

ic = 0.3 × 3 = 0.9 M
For NaOH :-

For Benzoic acid :-

37) The correct answer is option (A, C, D)

38)

39)

The correct answer is option (A),(B),(C),(D)

40) A —→ 2B + C
P0 P0
P0 – p 2p p + P0
– 2P0 P 0 + P0
2P0 + P0 + P0 = 40
P0 = 10 bar
P0 – p + 2p + p + P0 = 22.5
p = 1.25 bar

41)

42) The correct answer is (3)

43)

44)

The correct answer is 37.00

45)

The correct answer is 6.00

46)

ΔTf = i Kpm

2=

960 – w = 3 × (500)
960 = 16w
w = 60 gm

47)
By retardation through 19 volts the original accelerating voltage is reduced to 81 volts.

By further retardation through 32 volts.

 48) Explain Question:
Ionization of coordination compounds in water.

Concept:
Werner's Coordination Theory.

Solution:
First, determine the formula from the name. The coordination sphere (entity in brackets)
remains intact as one ion, while the counter ions outside the bracket dissociate completely in
the solution.
Calculation:
• Central metal:
• Ligands:
• Charge on coordination sphere
• Formula:
Ionization reaction:

• Total moles of ions = 1 (cation) + 3 (anions) = 4

Final Answer: 4

49) x = 7, y = 1, z = 2

50) The correct match :

Finkelstein reaction → NaI/acetone
Swart reaction → SbF3
Darzen's halogenation reaction → SOCl2
Lucas test → HCl + Anhy. ZnCl2

51)

Explain Question:
Analyzing chemical structure of specific acid and determine the correct properties

Concept:
Chemical bonding and molecular structure.

Solution:

(A) H2S2O5
 Central atom sp3 M–M linkage Non-planar Central atom sp3 M-O-M linkage Non-planar

P,R,S P,Q,S

(C) H4P2O6(tetrabasic) (D) H6Si2O7

Central atom sp3 M–M linkage Non-planar Central atom sp3 M-O-M linkage Non-planar

P,R.S P,Q,S

Final Answer: A-(P,R,S); B-(P,Q,S); C-(P,R,S); D-(P,Q,S)