16-06-2025

2302CJA101032250001 JM

PART-1 : PHYSICS

SECTION-I

1) If then what is the approximate value of y. Choose the appropriate option :

(A)

(B)

(C)

(D)

2) If y = 3x2 + x + 5, then find value of at x = 1.

(A) 11
(B) 9
(C) 7
(D) 5

3)

A particle is moving along x-axis, its “v2–t” graph is shown below. The acceleration at t = 1sec is :

(A) m/s2

(B)
m/s2

(C)
m/s2
(D) 2 m/s2

4)

A particle moves m in South–West direction, 12m in upward direction and then 1m in East
direction. Find the net displacement.

(A) 13 m
(B) 17 m
(C) 14 m
(D) 18 m

5) An object is dropped from some height on earth. Air produces a constant acceleration in
horizontal direction then path of the object in ground frame will be :-

(A) Parabola
(B) Vertical straight line
(C) Horizontal straight line
(D) Straight line inclined from vertical

6)

A particle (initially in motion) is subjected to different accelerations separately. These acceleration

vary with time as shown. In which of these cases particle will definitely return to its initial position.

(i) (ii) (iii)

(A) (i) only
(B) (ii) & (iii) only
(C) in all cases
(D) in no case

7) Which of the following graph represents particle moving with constant velocity :-

(A) A, B only
(B) A only
(C) C only
(D) A, B, C

8) If a particle moves in a straight line according to the law x= t3 – 6t2 – 15t, the time interval during
which velocity is negative and acceleration is positive, is

(A) t < 2 and t > 5

(B) 2 < t < 5
(C) –1 < t < 5
(D) –1 < t < 2

9) A ball is released from the top of a tower of height h. It takes time T to reach the ground. What is
the position of the ball (from ground) after time T/3?

(A)

(B)

(C)

(D)

10) A bird flies in xy plane with velocity . Assume SI units. The acceleration of
bird at t = 3 s is :

(A)
(B)
(C)
(D)

11) A ball is projected at an angle of 45° so as to pass a wall at a distance a from the point of
projection and falls at a distance b on the other side of the wall. If h is height of wall then :

(A)
(B)

(C)

(D)

12)

If and , then the vector whose magnitude is equal to and parallel

to is :

(A)

(B)

(C)
(D)
13) Which of the following is correct regarding these four vectors?

(A)
(B)
(C)
(D)

14) E, m, J, and G denote energy, mass, angular momentum, gravitational constant, then the

dimension of are

(A) Angle
(B) Length
(C) Mass
(D) Time

15) Young’s modulus of steel is 1.9 × 1011 N/m2. When expressed in CGS units of dynes/cm2, it will be
equal to (1N = 105 dyne, 1m2 = 104 cm2)

(A) 1.9 × 1010

(B) 1.9 × 1011
(C) 1.9 × 1012
(D) 1.9 × 1013

16) In a new system, the unit for mass is α kg, unit of length is β meter, and unit of time is γ second.
The value of 1 unit of power in this new system will be :

(A) αβ2γ–2 Watt

(B) αβ3γ–3 Watt

(C)
Watt
2 –3
(D) αβ γ Watt

17) The position of a particle at time t is given by the equation where v0 is a

constant and (α > 0). The dimensions of v0 and α are respectively :-

0 0
(A) M LT and T–1
0
(B) M L1T–1 and T
0
(C) M LT–1 and T–1
(D) M1L1T and T–2

18) A bird starts from (1, 0, 0) in the direction with a speed 21 m/s for 5 sec, then along

the direction with a speed for 5 sec. Find the final displacement of the bird so
that it reaches the origin?

(A)
(B)
(C)
(D)

19) Velocity of a particle changes with position according to following curve. Acceleration of the
particle at x = 1 m :-

(A) 24 m/s2
(B) 2 m/s2
(C) 20 m/s2
(D) 3 m/s2

20) A gun is hidden under an inclined roof of angle of inclination 30° with horizontal as shown. L =
m and its initial velocity is 20 m/s. What can be the maximum range (approximate) of the gun on

the level ground? The roof is long enough.

(A) 36 m
(B) 40 m
(C) 32 m
(D) 44 m

SECTION-II

1) A bird flies for 4 s with a velocity of |t – 3| m/s in a straight line, where t = time in seconds. It
covers a distance of x meter. Find x.
2) A balloon is ascending vertically with an acceleration of 0.4 m/s–2. Two stones are dropped from it
at an interval of 2 sec. If the distance between them 1.5 sec. after the second stone is released is
(14P – 4)m. Then find value of P. (g = 10 m/sec2)

3) A particle is projected from inclined plane perpendicularly as shown. The speed (in m/s) of
projectile at the moment when it is moving parallel to inclined plane is:

4) Water runs into a conical tank kept with vertex downwards at the rate 9 cm3/sec. If water level is

rising at the rate of cm/sec when the height of water level in tank is 6 cm, find x. Height of cone is

10 cm and radius is 5 cm. (Take : π = )

5) In a new system of units, the unit of mass is 100g, unit of length is 4 m and unit of time is 2 s. If
the numerical value of 10 J in this system is N fill the value of N.

PART-2 : CHEMISTRY

SECTION-I

1) The orbital angular momentum of electron in 'd' orbital is equal to :-

(A)
(B)
(C) 0 h
(D)

2) What is the shortest wavelength in the Pfund series of He+ ion :-

(A)

(B)

(C)

(D)

3) The orbital angular momentum of a p-electron is given as :-

(A)

(B)

(C)

(D)

4) According to Bohr's atomic theory :-

(A) Kinetic energy of electron is ∝ .

(B) The product of velocity (v) of electron and principal quantum number (n), 'vn' ∝ Z2

(C) Frequency of revolution of electron in an orbit is ∝

(D) Coulombic force of attraction on the electron is ∝

Choose the most appropriate answer from the options given below :

(A) (C) Only

(B) (A) Only
(C) (A), (C) and (D) only
(D) (A) and (D) only

5) Which configuration does not obey Pauli's exclusion principle :-

(A)

(B)

(C)

(D)

6) Which of the following sets of quantum numbers represents an impossible arrangement

(A)
n : 3, I : 2, m : –2, s :

(B)
n : 4, I : 0, m : 0, s :

(C)
n : 3, I : 2, m : –3, s :

(D)
n : 5, I : 3, m : 0, s :

7) The nucleus of an atom can be assumed to be spherical. The radius of the nucleus of mass number
A is given by 1.25 × 10–13 × A1/3 cm. Radius of atom is one Å. If the mass number is 64, then the
fraction of the atomic volume that is occupied by the nucleus is

(A) 1.0 × 10–3

(B) 5.0 × 10–5
(C) 2.5 × 10–2
(D) 1.25 × 10–13

8) Which of the following has the smallest number of molecules. [C = 12, O = 16, N = 14, H = 1] :-

(A) 1 g of O2
(B) 1 g of CO2
(C) 1 g of NH3
(D) 1 g of N2

9) A pure gas that is 14.3% hydrogen and 85.7% carbon by mass has a density of 2.5g L–1 at 0°C and
1 atm pressure. What is the molecular formula of the gas :

(A) CH2
(B) C2H4
(C) C4H8
(D) C6H12

10) The molality of 1 litre solution of 93% (w/v) H2SO4 will be [dsolution = 1.84 g/mL]

(A) 8.7
(B) 3.67
(C) 10.42
(D) 4.82

11) What volume of 0.2M - KMnO4 solution is required for complete reaction with 20 ml 0.4 M -
FeC2O4 solution in presence of H2SO4 ?

(A) 24 ml
(B) 8 ml
(C) 16 ml
(D) 120 ml

12) In basic medium, CrO42– oxidizes S2O32– to form SO42– and itself changes to Cr(OH)4–. How many ml
of 0.154 M CrO42– are required to react with 40 ml of 0.246 M S2O32– ?

(A) 200 ml
(B) 156.4 ml
(C) 170.4 ml
(D) 190.4 ml
13) 3 moles of FeSO4 are oxidised by "a" mole of K2Cr2O7 in acidic medium whereas 3 moles of
FeC2O4 are oxidised by "b" mole of K2Cr2O7 in acidic medium, the ratio of "a" and "b" is :-

(A)

(B)

(C)

(D)

14) Moles of MnO4– ions required to oxidize 2 moles of Cu2S in acidic medium according to given
reaction,
Cu2S → Cu2+ +SO2 will be :

(A) 3.2
(B) 2.4
(C) 2.6
(D) 4.8

15) I2 + OH– → I– + IO3– + H2O η-factor of I2 in the above reaction will be :

(A) 10

(B)

(C)

(D) 1

16) In the process Cl(g) + e– Cl–(g), ΔH is

(A) Positive
(B) Negative
(C) Zero
(D) None

17) Which of the given reactions is not an example of disproportionation reaction ?

(A) 2H2O2 → 2H2O + O2

(B) 2NO2 + H2O → HNO3 + HNO2
(C)
(D)

18) Select iso electronic set :-

(a)
(b)
(c)
(d)

(A) a, b, d
(B) b, c, d
(C) a, b, c, d
(D) a, b, c

19) Given, uncertainty in momentum of an electron = 3 × uncertainty in position. What would be

uncertainty in velocity of that electron.

(A)

(B)

(C)

(D)

20) In the reaction ; As2S3 + HNO3 → H3AsO4 + H2SO4 + NO, the element oxidised is/are :-

(A) As only
(B) S only
(C) N only
(D) As and S both

SECTION-II

1) One litre of a sample of hard water contains 11.1 mg of CaCl2 & 9.5 mg of MgCl2. What is degree
of hardness in terms of ppm of CaCO3 ?

2) A quantity of 0.70 g of a sample of Na2CO3.xH2O was dissolved in water and the volume was made

to 100 ml. Twenty millilitres of this solution required 19.8 ml of HCl for complete neutralization.
The value of x is ___. (Nearest Integer)

3) Oxidation number of Cr in CrO5 is x and Fe in Fe(CO)5 is y then calculate the value of x + y.

4) If the effective nuclear charge on the valence electron in carbon be x, then the value of 100x is
___.

5) HNO3 oxidises ions to nitrogen and itself gets reduced to NO2. The moles of HNO3 required
by 1 mol of (NH4)2SO4 is :-
 PART-3 : MATHEMATICS

SECTION-I

1) The number of integral solutions of

is

(A) 2009
(B) 2010
(C) 2011
(D) 2012

2) has the value equal to

(A) 1/2
(B) 1
(C) 2
(D) 4

3) The incorrect statement for the equation

|x – 1| + |x – 2| + |x – 3| = k is

(A) one solution if k = 2

(B) 2 solutions if k > 4
(C) no solution if k < 1
(D) 2 solutions ∀ k < 3

4) (x2 – x – 1)(x2 – x – 7) < – 5 ; then x ∈

(A) x∈(–2, –1)∪(2, 3)

(B) x∈(–∞, –1)∪(2, ∞)
(C) x∈(2, 3)
(D) x∈(–∞, ∞)

5) The set of values of x which satisfying the inequality log0.5 < 0 is

(A) (0, ∞)
(B) (3, 8)
(C) (–4,–3) ∪ (8,∞)
(D) (3,4) ∪ (8,∞)
6) Simplified value of the expression is

(A) greater than

(B) less than

(C) greater than log4 16

(D) less than

7) Given that log (2) = 0.3010, then the number of digits in the number 20002000 is

(A) 6601
(B) 6602
(C) 6603
(D) 6604

8) Solution set of |x + 3| + |2x – 1| – |3x + 2| = 0

(A) x ∈ (–∞, –3) ∪ [1/2, ∞)

(B) x ∈ (–∞, –3) ∪ (1/2, ∞)
(C) x ∈ (–∞, –3] ∪ (1/2, ∞)
(D) x ∈ (–∞, –3] ∪ [1/2, ∞)

9) Solve

(A) 5 ≤ x ≤ 10
(B) 1 ≤ x ≤ 10
(C) 10 ≤ x < ∞
(D) 5 ≤ x ≤ 15

10) If the equation = 4 can have real solution for x then a∈

(A) (– ∞, 4]
(B) [4, ∞)
(C) [– 4, 9]
(D) None

11)

If a,b,c ∈ R+ then minimum value of is :-

(A) 120
(B) 210
(C) 140
(D) 112

12) The value of is :-

(A) 4
(B) log4
(C) log2
(D) log8

13) If nth term of geometric progression of positive numbers is an and let and

such that α ≠ β , then common ratio of G.P. is :-

(A)

(B)

(C)

(D)

14) If (10)9 + 2(11)1 (10)8 + 3(11)2 (10)7 + ......+ 10 (11)9 = k (10)9 , then k is equal to :

(A)

(B)

(C) 100
(D) 110

15) For any three positive real numbers a, b and c, 9(25a2 + b2) + 25(c2 – 3ac) = 15b(3a + c). Then :

(A) a, b and c are in G.P.

(B) b, c and a are in G.P.
(C) b, c and a are in A.P.
(D) a, b and c are in A.P.

16) The largest common term to the sequence

1, 11, 21, 31, .... 100 terms and
31, 36, 41, 46, ... 100 terms is :-

(A) 381
(B) 471
(C) 281
(D) 521

17) Sum of infinite terms of the series

(A)

(B) 4

(C)

(D) None

18) equals :-

(A)

(B)

(C)

(D)

19) Suppose a, b, c are in A.P and a2, b2, c2 are in G.P. If a < b < c and a + b + c = , then the value
of a is :-

(A)

(B)

(C)

(D)

20) The sum of 50 terms of the series is –

(A)

(B)
(C)

(D)

SECTION-II

1) In an infinite G.P., the sum of first three terms is 70. If first & third terms are multiplied by 4 and
second term is multiplied by 5, the resulting terms form an A.P., then the sum of infinite G.P. is :-

2) The interior angles of a convex polygon form an arithmetic progression with a common difference
of 4°. Determine the number of sides of the polygon if its largest interior angle is 172° :-

3) If a1, a2, a3, .... a21 are in A.P. and a3 + a5 + a11 + a17 + a19 = 10 then the value of is

4) Number of integral value of x for which (5x –1) < (x + 1)2 < (7x – 3) is

5) Value of
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B C B A D D B B C B D B B A C D C C A B

SECTION-II

Q. 21 22 23 24 25
A. 5 4 15 1 25

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D D C D B C D B C C A C A A C B C D B D

SECTION-II

Q. 46 47 48 49 50
A. 20 2 6 325 6

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B B D A C B C D A A B A A C C D A D D A

SECTION-II

Q. 71 72 73 74 75
A. 80 12 42 1 4
 SOLUTIONS

PART-1 : PHYSICS

1)

2)

At x = 1, =7

3)

From the given graph

v2 = 2t

va = 1

v at t = 1 sec is

m/sec2

4)

South-West = ; = 12 m upward = 12 , = 1 m East = 1

, = 13m

5) If initial velocity is zero & acceleration is constant then path of particle will be straight line
along the acceleration.

6) In question it is clearly written that "definitely return". Since scaling is not done, in all the
cases we can find atleast a situation in which the particle can not return to its initial position.

7)

Slope of (x – t) graph in (A) is constant.

8)

⇒ required interval
2<t<5

9) We have h =

In T/3 second, distance fallen =

So position of the ball from the ground is

H–

10)
at t = 3 s

11) y = xtanθ

h = a(1) =

12)

Required vector =

13) (according to polygon law)

14) =moLoTo angle

15)

16) Power = [ML2T–3]

n1u1 = n2u2

17)
αt is dimensionless

and
⇒ [v0] = [LT–1]
0 0 0
∴ [v0] = [M L1T–1] and [α] = [M L T–1]

18)

19)

v = 12

∴ a=
20)
Maximum height for incline plane

sin2 (θ – α) = 3/80

sin (θ – α) =
by small angle approximation
θ – α = 11°
θ = α + 11°
θ = 41°

&
= 40sin82°
R = 40 (Because sin82 = 0.99)

21)

Area =
22)
VB = u0 + (0.2)2 = u0 + 0.8

0 0
SB = u (2) + (0.4)(2)2 = 2u + 0.8
S1 = u0 (3.5) – 5 (3.5)2 = 3.540 – 61.25
S2 = (u0 + 0.8) (1.5) – 5(1.5)2 = 1.5u0 = 1.5u0 + 1.2 – 11.25
∴ Distance between both stories =
=
= 52

23) = g cos 37° = = 8 m/s2

a11 = gsin37° = = 6 m/s2

vy = uy – ayt

O = 20 – 8t ⇒ t = sec.

Vx = ux + axt = 0 + 6 × = 15 m/s

24)

Also

25) [Energy] = ML2T–2

In new system

1 unit of energy =

= kgm2/s2 = J
 Now J = 1 unit energy in new system

1J = unit

10 J = unit
= 25 unit

PART-2 : CHEMISTRY

26)

For d orbital ℓ = 2

⇒ = =

27) Shortest wavelength in the Pfund series

28) Orbital angular moment =

for p orbital ℓ = 1

29) According to Bohrs theory

(A) KE = – TE = 13.6 ×

(B)

(C)

(D) force of attraction

 30)
Pauli's exclusion principle
No two electrons in the same can have identical values for all four of their quantum numbers
→ no more than two electrons can occupy the same orbital.
→ two electrons in the same orbital must have opposite spin.

31)

The value of (m) is wrong in the given option (3)

For l = 2, m = –2, –1, 0, +1, +2

32)
0
Radius of atom ra = 1A = 10–10m = 10–8 cm
Radius of Nucleus rN = 1.25 ×10–13 × A1/3 cm
= 1.25 × 10–13 × (64)1/3 cm
= 5.00 × 10–13cm

=
= 125 × 10–15
= 1.25 × 10–13

33)

1 g of O2 ⇒ No. of molecules =

1 g of CO2 ⇒ No. of molecules =

1 g of NH3 ⇒ No. of molecules =

1 g of N2 ⇒ No. of molecules =

34)

Empirical formula of gas = = C1H2

Molar mass of gas = 2.5 × 22.4 = 56
∴ Molecular formula = (C1H2)4 = C4H8

35)
100 ml solution contains 93 g H2SO4
∴ Mass of solution = 1.84 × 100 = 184 g
∴ Mass of solvent = 184 – 93 = 91 g

36)

MnO4– → Mn2+ (n-factor = 5)

FeC2O4 → Fe+3 + CO2 (n -factor = 3)
neq KMnO4 = neq FeC2O4

or, ⇒ V = 24 ml

37)
(meq. of = meq. of )
40 × 0.246 × 8 = V × 0.154 × 3
∴ V = 170.4 ml

38) geq of FeSO4 = geq of K2Cr2O7

∵ mole × n factor = geq
∴ 3 × 1 = a × 6 ...(i)
similarly geq of FeC2O4 = geq of K2Cr2O7
3 × 3 = b × 6 ...(ii)

39)

equ. of Cu2S = equ. of MnO4–

8×2=5×n

40) 6I2 + 12OH– → 10I– + 2IO3– + 6H2O

no. of electrons involved = 10

η-factor of I2
41)

Ans is (B)

∆ He is negative

42) : Disproportionation

: Disproportionation
: reduction

: Disproportionation

43)

44) Given 3 Δx = ΔP, ΔX. ΔP ≥

45) As2S3 → H3AsO4 + H2SO4 (+3) (–2) (+5) (+6)

46)

Moles of CaCl2 = = 10–4

⇒ equivalent moles of CaCO3 = 10–4

Moles of MgCl2 =
⇒ equivalent moles of CaCO3 = 10–4

∴ Total moles of CaCO3 = 2 × 10–4

⇒ Weight of CaCO3 = 2×10–4 × 100 = 2×10–2 g

Also, weight of solution = 1000 g

∴ ppm of CaCO3 =
 47)

280 = 198 + 35.64x

48) Cr = +6 x = +6
Fe(CO)5 y=0 x+y=6

49) Z* = Z – σ
σ = 1s2, 2s2, 2p2
(1s)2 (2s, 2p)4
σ = (3 × 0.35) + (2 × 0.85)
= 1.05 + 1.70 = 2.75
Z* = Z – σ
= 6 – 2.75
= 3.25

50)

PART-3 : MATHEMATICS

51) Zeros = –1234, 0, 775

poles =
number of integers = 2010

52)

53)

54) (x2 – x – 1)(x2 – x – 7) < – 5

Let x2 – x = y
⇒ ( y – 1) (y – 7) + 5 < 0
or y2 – 8y + 12 < 0
or (y – 6) (y – 2) < 0
⇒2<y<6
⇒ 2 < x2 – x < 6
Now, x2 – x > 2
or x2 – x – 2 > 0
or (x – 2)(x+1) > 0
⇒ x ∈ (–∞, –1)∪(2, ∞) ....(1)
x2 – x – 6 < 0
⇒ (x – 3)(x + 2) < 0
x ∈ (–2, 3) ....(2)
From (1) and (2), common values of x are
x∈(–2, –1)∪(2, 3)

55) log6 > (0.5)

⇒ log6 >1

⇒ >6

⇒ >0
x ∈ (–4, – 3) ∪ (8, ∞)

56) Expression

Now

57) Let, x = 20002000

log x = 2000 log10 (2000)
= 2000 (log10 2 + 3)
= 2000 (3.3010) = 6602
Therefore, the number of digits is 6603.

58)

|a| + |b| = |a + b|
(x + 3) (2x – 1) ≥ 0

x ∈ (–∞, –3] ∪ [1/2, ∞]

59)

or

or
or
or =
⇒ and
⇒ ⇒4≤x–1≤9
⇒

60) +a=±4
=±4–a
For to be solution
4 – a ≥ 0 or – 4 – a ≥ 0
a≤4 or a ≤ – 4
i.e. a ∈ (– ∞ , 4]
61)

⇒
⇒ ymin = 5.6.7 = 210

62)

63)
{common ratio = r2}

.....(i)

⇒ a1 + a3 + a5 +………..+ a199 = β

…(ii)
eqn (i)/(ii)

64) S=109 + 2(11)1(10)8 + 3(11)2 (10)7 ... 10(11)9...(1)

S = 11(10)8 + 2(11)2 (10)7 + ... 1110 ...(2)

Sub (1) – (2)

– = 109 + 11 . 108 + 112 . 107 + ... 119 – 1110

⇒ S = 1011 = K109
⇒ K = 100

65) (15a)2 + (3b)2 + (5c)2 – (15a) (15c) – (15a) (3b) – (3b) (5c) = 0

= [(15a – 3b)2 + (3b – 5c)2 + (5c – 15a)2] = 0

it is possible when 15a = 3b = 5c

a + b = 2c b, c, a in A.P.
66) Given series
1, 11, 21, 31, .... , 991 → A.P.
& 31, 36, 41, 49, ....,526 → A.P.
for common series
a = 31, d = 10, Tn = last common term

31 + (n – 1) 10 526

67) Tn =
Sn = ΣTn

68)

69) a + c = 2b ....(1)
Also a + b + c = 3/2 ....(2)
from (1) and (2)
b = 1/2 and a + c = 1 ....(3)
Also a2,b2,c2 are in G.P
a2c2 = b4 ⇒ ac = ± b2 = ± 1/4 (∴ c –a ≠ c > a)
⇒ c–a = ....(4)
Solving (3) and (4)

a
70) Tn =

S50 = 6 =

71) a, ar, ar2, ....

a(1 + r + r2) = 70 ... (i)
2
4a, 5ar, 4ar are in A.P.
⇒ 10ar = 4a + 4ar2
⇒ 2r2 – 5r + 2 = 0 ⇒ r = 2, 1/2
(r = 2 is impossible)
putting r = 1/2 in (i) ⇒ a = 40

so

72)

⇒
ℓ = 172º and d = 4º
∴ On solving n = 12

73) Let a3 + a19 = a5 + a17 = 2a11 = k

given a3 + a5 + a11 + a17 + a19 = 10

⇒ k = 10 ⇒ k = 4
so a1 + a21 = 4 _(1)

= 42

74) 5x -1 < x2 + 1 + 2x
0 < x2 – 3x + 2
0 < (x – 1) (x – 2)
x ∈ (– ∞, 1) ∪ ( 2, ∞) …. (1)
x2 + 2x + 1 < 7x – 3
x2 – 5x + 4 < 0
(x – 1) ( x – 4) < 0
x ∈ (1, 4) …….(ii)
(i) ∩ (ii)
x ∈ (2, 4)
only one integer 3
So number of integer = 1
75)
= log3 81 = log3 34 = 4