29-03-2026

0999DJM262103250016 JM

PART-1 : PHYSICS

SECTION-I

1) Find the equivalent resistance across the terminals of source of e.m.f. 24 V for the circuit shown

in figure:-

(A) 15 Ω
(B) 10 Ω
(C) 5Ω
(D) 4Ω

2) A rigid conducting wire bent as shaped in the figure, is released to fall freely in a horizontal
magnetic field which is perpendicular to the plane of the conductor. If the magnetic field stength is
B, then the emf induced across the points A and C when it has fallen through a distance h will be :-

(A)
(B)
(C)
(D)

3)

Choose correct option regarding given circuit.

(A) Potential difference across 4μF is 20V
(B) Charge at 3μF is 8μc.
(C) Energy stored in 2μF is 32μJ.
(D) Ratio of charges on 3μF & 11μF are 3 : 11

4) A copper ball of density ρc and diameter d is immersed in oil of density ρ0. What charge should be
present on the ball, so that it could be suspended in the oil, if a homogeneous electric field E is
applied vertically upward ?

(A)

(B)

(C)

(D)

5) The charge in an LC circuit with negligible resistance oscillates as given by equation

. If the charge is maxiumum equal to 24 μC at t = 0, find the charge at

(A)
(B)
(C)
(D) Zero

6) If electric field in a non-magnetic medium for E.M. wave is given by

v/m then is :-

4 × 10–6 sin(108t + 2Z)

(A)

(B) 2 × 10–6sin(108t + 2Z)

(C) 5 × 10–7sin(108t + 2Z)
(D) 2 × 10–6sin(108t + 2Z)

7) Given below are two statements : one is labelled as Assertion (A) and the other is labelled as
Reason (R).

Assertion (A) : The density of the copper nucleus is greater than that of the
carbon nucleus.
Reason (R) : The nucleus of mass number A has a radius proportional to A1/3.
In the light of the above statements, choose the most appropriate answer from the options given
below :

(A) (A) is correct but (R) is not correct

(B) (A) is not correct but (R) is correct
(C) Both (A) and (R) are correct and (R) is the correct explanation of (A)
(D) Both (A) and (R) are correct but (R) is not the correct explanation of (A)

8) A small mirror of mass m is suspended by a massless thread of length ℓ. Then the small angle
through which the thread will be deflected when a short pulse of laser of energy E falls normal on
the mirror (c = speed of light in vacuum and g = acceleration due to gravity)

(A)

(B)

(C)

(D)

9) An electron with mass 'm' with an initial velocity (t = 0) (v0 > 0) enters a magnetic field
. If the initial de-Broglie wavelength at t = 0 is λ0 then its value after time 't' would be :

(A)

(B)

(C)

(D) λ0

10) During the transition of electron from state A to state C of a Bohr atom, the wavelength of
emitted radiation is 2000 Å and it becomes 6000 Å when the electron jumps from state B to state C.
Then the wavelength of the radiation emitted during the transition of electrons from state A to state
B is :-

(A) 3000 Å
(B) 6000 Å
(C) 4000 Å
(D) 2000 Å

11) Diameter of a plano-convex lens is 6cm and thickness at the centre is 3 mm. If speed of light in
material of lens is 2 × 108 m/s, the focal length of the lens is :

(A) 15 cm
(B) 20 cm
(C) 30 cm
(D) 10 cm

12) In a compound microscope, the intermediate image, in normal use is

(A) Virtual, erect and magnified

(B) Real, erect and magnified
(C) Real, inverted and magnified
(D) Virtual, inverted and magnified

13) A hollow metallic tube of length L and closed at one end produce resonance with a tuning fork of
frequency n . The entire tube is then heated carefully so that at equilbrium temperature its length
changes by ℓ . If the change in velocity V of sound is v, the resonance will now be produced by
tuning fork of frequency.

(A) (V + v) / [4(L + ℓ)]

(B) (V + v) / [4(L – ℓ)]
(C) (V – v) / [4(L + ℓ)]
(D) (V – v) / [4(L – ℓ)]

14) The density of a cube is measured by measuring its mass and the length of its side. If the
maximum errors in the measurement of mass and length are 4% and 3% respectively, the maximum
error in the measurement of the density is

(A) 9%
(B) 13%
(C) 12%
(D) 7%

15) The sum of magnitudes of two forces acting at a point is 16N. If the resultant force is 8N and its
direction is perpendicular to smaller force, then the forces are :–

(A) 6N and 10N

(B) 8N and 8N
(C) 4N and 12N
(D) 2N and 14N

16) A particle moving in a straight line covers half the distance with speed of 3 m/s. The other half of
the distance is covered in two equal time intervals with speed of 4.5 m/s and 7.5 m/s respectively.
The average speed of the particle during this motion is

(A) 4.0 m/s

(B) 5.0 m/s
(C) 5.5 m/s
(D) 4.8 m/s

17) A helicopter is flying horizontally with a speed 'v' at an altitude 'h' has to drop a food packet for a
man on the ground. What is the distance of helicopter from the man when the food packet is
dropped?

(A)

(B)

(C)

(D)

18) The boxes of masses 2 kg and 8 kg are connected by a massless string passing over smooth
pulleys. Calculate the time taken by box of mass 8 kg to strike the ground starting from rest. (use g

= 10 m/s2)

(A) 0.34 s
(B) 0.2 s
(C) 0.25 s
(D) 0.4 s

19)
Shown in the figure is rigid and uniform one meter long rod AB held in horizontal position by two
strings tied to its ends and attached to the ceiling. The rod is of mass 'm' and has another weight of
mass 2 m hung at a distance of 75 cm from A. The tension in the string at A is :

(A) 2 mg
(B) 0.5 mg
(C) 0.75 mg
(D) 1 mg

20)

One mole of an ideal gas is taken through an adiabatic process where the temperature rises from
27°C to 37°C. If the ideal gas is composed of polyatomic molecule that has 4 vibrational modes,
which of the following is true? [R = 8.314 J mol–1 k–1]

(A) work done by the gas is close to 332 J

(B) work done on the gas is close to 582 J
(C) work done by the gas is close to 582 J
(D) work done on the gas is close to 332 J

SECTION-II

1) A solid cylinder of radius R and having current density has a cavity of radius as shown in
figure (Top view). If magnetic field at point P which is at a distance of 2R from the axis of the

cylinder towards cavity is , fill value of x.

2) The number of spectral lines emitted by atomic hydrogen that is in the 4th energy level, is

3) Water (with refractive index = ) in a tank is 18 cm deep. Oil of refractive index lies on water
making a convex surface of radius of curvature ‘R = 6 cm’ as shown. Consider oil to act as a thin
lens. An object ‘S’ is placed 24 cm above water surface. The location of its image is at ‘x’ cm above

the bottom of the tank. Then ‘x’ is

4)

A steel rod with y = 2.0 × 1011 Nm–2 and a = 10–5 °C–1 of length 4 m and area of cross-section 10 cm2
is heated from 0° C to 400°C without being allowed to extend. The tension produced in the rod is x ×
105 N where the value of x is .............

5)

A body rotating with an angular speed of 600 rpm is uniformly accelerated to 1800 rpm in 10 sec.
The number of rotations made in the process is___.
 PART-2 : CHEMISTRY

SECTION-I

1)

Product (D) will be -

(A)

(B)

(C)

(D)

2) In which of the following reaction, a significant amount of meta product is obtained ?

(A)

(B)

(C)
(D)

3) The final product 'C' is the following series series of reactions is

(A)

(B)

(C)

(D)

4) The following sequence of reactions gives

(A)

(B)
(C)

(D)

5) Identify the compound which in not aromatic :-

(A)

(B)

(C)

(D)

6) 0.20 g of organic compound gave 0.5544 g of [Link] percentage of S is

(A) 38%
(B) 19%
(C) 18%
(D) 83%

7) Which of the following possess two lone pair of electrons on the central atom and square planar
shape ?
(I) SF4 (II) XeO4 (III) XeF4 (IV)

(A) I, III
(B) II, IV
(C) III, IV
(D) All

8) Select appropriate ligand for given complex ; μ = 0 BM

2–
(A) C2O4
(B) en
(C) H2O
(D) F–

9) Which one of the following does not correctly represent the correct order of the property
indicated against it ?

(A) Ti < V < Cr < Mn : increasing melting points

(B) Ti < V < Mn < Cr : increasing 2nd ionization enthalpy
(C) Ti < V < Cr < Mn : increasing number of oxidation states
(D) Ti3+<V3+ < Cr3+< Mn3+ : increasing magnetic moment

10) Consider the following statement which of the following is not true

(A) Eu+2 is a strong reducing agent (Z of Eu = 63)

(B) Ce+4 is a strong oxidising agent (Z of Ce = 58)
(C) Curium have electronic configuration [Rn] 5f7 6d1 7s2 (Z of Cm = 96)
(D) Yb+2 is a oxidising agent (Z of Yb = 70)

11) Select incorrect statement ?

(A) Element [Rn] 7s2 6d2 belongs to f-block.

(B) Ions Ti4+, V4+, Cr+6, Mn7+ all have equal magnetic moments.
(C) Total number of gaseous non-metals are 5.
(D) hydrolysis of ferric salts is easier than ferrous salts.

12) Which order of stability of oxidation state is incorrect :-

(A) Al+2 < Al+ < Al+3

(B) Pb+2 > Pb+4
(C) Ga+ < In+ < Tl+
(D) Ge+4 < Sn+4 < Pb+4

13) Which of the following statements is false ?

(A) has a Cr – O – Cr bond

(B) is tetrahedral in shape
(C) K2Cr2O7 is less soluble in water than Na2Cr2O7
(D) In , there are 8 equivalent Cr – O bonds are present.

14) In which of the following reaction product formation is favoured by decrease in temperature and
pressure

(A)
CO2(g) + C(s) 2CO(g); ΔHº=172.5kJ

(B)
CO(g) + 2H2(g) CH3OH(l); ΔHº= – 21.7kJ
(C)
2O3(g) 3O2(g); ΔHº = –285 kJ

(D)
H2(g) + F2(g) 2HF(g) ΔHº = –541 kJ

15) For a gaseous reaction

CH3CHO(g) CO(g) + CH4(g)
initial pressure is 80 mm of Hg and total pressure at the end of 20 minutes is 120 mm of Hg. The
rate constant of the reaction assuming first order kinetics is -

(A) 3.465 × 10–2 min–1

(B) 34.65 min–1
(C) 3.465 min–1
(D) 0.3465 min–1

16) In what mole ratio, a mixture of N2 and NH3 gases should be taken such that the mole - fraction
of N2 at any instant remains constant , even after dissociation of NH3 into N2 and H2 ? Mole fraction
is the ratio of mole of that gas and the total mole of gases.

(A) 1 : 1
(B) 1 : 2
(C) 1 : 3
(D) 3 : 2

17) A 2kg copper block is heated to 500°C and then it is placed on a large block of ice at 0°C. If the
specific heat capacity of copper is 400 J/kg/°C and latent heat of fusion of water is 3.5 × 105 J/kg, the
amount of ice, that can melt is :-

(A) (7/8) kg
(B) (7/5) kg
(C) (8/7) kg
(D) (5/7) kg

18) Pt(s)|Fe+2(10–2 M, aq), Fe+3(10–3 M, aq) || MnO4–(10–3 M, aq), Mn+2 (10–2 M, aq)| Pt(s)
At 298K, E°cell for cell is –2.31V, what will be the Ecell at pH = 1 ?

(A) – 2.36 Volt

(B) – 2.26 Volt
(C) – 2.78 Volt
(D) – 1.837 Volt

19) A solute 'S’ undergoes a reversible trimerization when dissolved in a certain solvent. The boiling
point elevation of its 0.1 molal solution was found to be identical to the boiling point elevation in
case of a 0.08 molal solution of a solute which neither undergoes association nor dissociation. To
what percent had the solute ‘S’ undergone trimerization ?

(A) 30%
(B) 40%
(C) 50%
(D) 60%

20)

The volume of 0.2M H2SO4 required to produce 34 mg of H2S by the reaction is:

8KI + 5H2SO4 → 4K2SO4 + 4I2 + H2S + 4H2O [At wt. of S = 32]

(A) 100 ml
(B) 50 ml
(C) 25 ml
(D) 10 ml

SECTION-II

1) How many compounds gives +ve tollen's test and also show mutarotation :

(i)

(ii)

(iii)
(iv) Starch (v) Glycogen

2)

How many total monobrominated products are formed in following reaction :

3) NCl3, PCl3, BCl3, BeCl2, PCl5, SF6, find number of electron deficient compounds.
4) 12.5 millimole of NH4NO3 is dissolved in enough water to make 25.0 mL of solution. The initial
temperature is 25.8ºC & final temperature after solid dissolves is 21.8ºC. Calculate the enthalpy of
solution for the NH4NO3(s) in kcal / mol is. Given : density of the solution = 1gm/ml and heat

capacity of solution =

5) Molar heat capacity of an ideal gas at constant volume is given by CV = (16.5 + 10–2 T) . If
3.5 moles of this ideal gas are heated at constant volume from 300K to 400K. Then the change in
internal energy (in kJ) will be approximately.

PART-3 : MATHEMATICS

SECTION-I

1) Let the position vectors of the vertices A, B and C of a triangle be , and

respectively. Let ℓ1, ℓ2 and ℓ3 be the lengths of perpendiculars drawn from the ortho
center of the triangle on the sides AB, BC and CA respectively, then equals :

(A)

(B)

(C)

(D)

2) Let x = 2t, be a conic. Let S be the focus and B be the point on the axis of the conic such
that SA ⊥ BA, where A is any point on the conic. If k is the ordinate of the centroid of ΔSAB,
then k is equal to

(A)

(B)

(C)

(D)

3) A line segment AB of length λ moves such that the points A and B remain on the periphery of a
circle of radius λ. Then the locus of the point, that divides the line segment AB in the ratio 2 : 3, is a
circle of radius
(A)

(B)

(C)

(D)

4) Let the line 2x + 3y – k = 0, k > 0, intersect the x-axis and y-axis at the points A and B,
respectively. If the equation of the circle having the line segment AB as a diameter is x2 + y2 – 3x –

2y = 0 and the length of the latus rectum of the ellipse x2 + 9y2 = k2 is , where m and n are
coprime, then 2m + n is equal to

(A) 10
(B) 11
(C) 13
(D) 12

5) Let the mean and variance of 12 observations be and 4 respectively. Later on, it was observed
that two observations were considered as 9 and 10 instead of 7 and 14 respectively. If the correct

variance is , where m and n are co-prime, then m + n is equal to

(A) 316
(B) 314
(C) 317
(D) 315

6) Consider 10 observation x1, x2,…., x10. such that and , where α, β

are positive integers. Let the mean and the variance of the observations be and respectively.

The is equal to :

(A) 2

(B)

(C)

(D) 1

7) If the value of If the value of is , where a, b, c are natural

numbers and gcd(a, c) = 1, then a + b + c is equal to :
(A) 50
(B) 40
(C) 52
(D) 54

8) Let f(x) be a function such that f(x + y) = f(x) · f(y) for all x, y ∈ N. If f(1) = 3 and = 3279,
then the value of n is :

(A) 6
(B) 8
(C) 7
(D) 9

9) Let A be a 3 × 3 matrix such that = 124. Then | A–1adj A | is equal to

(A)
(B)
(C) 12
(D) 1

10) The sum of all the roots of the equation is:

(A)
(B)
(C)
(D)

11) If

then λ, are the roots of the equation

(A) 4x2 + 24x – 27 = 0

(B) 4x2 – 24x + 27 = 0
(C) 4x2 + 24x + 27 = 0
(D) 4x2 – 24x – 27 = 0

12) If , then the ratio is

(A) 35:16
(B) 65:37
(C) 27:11
(D) 2:1

13) The number of arrangements of the letter of the word “INDEPENDENCE” in which all the
vowels always occur together is

(A) 16800
(B) 14800
(C) 18000
(D) 33600

14) Function

(A) is always increasing

(B) is always decreasing
(C) has exactly one point of minima
(D) has exactly one point of maxima

15) The domain of the function

is :-

(A) (–3, 3)
(B) [–3, 3]
(C) (–∞, –3)∪ (3, ∞)
(D) (–∞, –3] ∪ [3, ∞)

16) If y = cot–1 ; 0 < x < π/2 then equals :-

(A) – 1/2
(B) 1/2
(C) 2
(D) 0

17) Let y = y (x) be the solution of the differential equation xdy = (y + x3 cosx)dx with y(π) = 0,

then is equal to

(A)

(B)
(C)

(D)

18) Let

and
Then the ratio of the area of A to the area of B is

(A)

(B)

(C)

(D)

19) If f and g(x) = logex, (x > 0) then the value of integral is :

(A) loge3
(B) loge2
(C) logee
(D) loge1

20) The integral is equal to

(A)

(B)

(C)

(D)

SECTION-II

1) Let the co-ordinates of one vertex of ΔABC be A(0, 2, α) and the other two vertices lie on the line

For α ∈ ℤ, if the area of ΔABC is 21 sq. units and the line segment BC has
length units, then α2 is equal to ________.
2) The mean and standard deviation of 15 observations were found to be 12 and 3 respectively. On
rechecking it was found that an observation was read as 10 in place of 12. If µ and σ2 denote the
mean and variance of the correct observations respectively, then is equal to ………...

3) A bag contains 4 white and 6 black balls. Three balls are drawn at random from the bag. Let X
be the number of white balls, among the drawn balls. If σ2 is the variance of X, then 100 σ2 is equal
to

4) Let the given function is differentiable at x = 1

the value of |a + p| is :

5) Let f : R → R is a function defined as f(x) = where [.] denotes the

greatest integer function,

then dx is equal to
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C C B B B A B D D A C C A B A A C D D B

SECTION-II

Q. 21 22 23 24 25
A. 6 6 2 8 200

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B C C C D A C C A D B D D C A A C A A C

SECTION-II

Q. 46 47 48 49 50
A. 2 8 2 8 7

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B D D B C A C C A A B D A C B B A A D B

SECTION-II

Q. 71 72 73 74 75
A. 9 2521 56 6 3
 SOLUTIONS

PART-1 : PHYSICS

1) Given circuit can be reduced to a simple circuit as shown in figures below

i.e. Req = 5Ω.

2)

e = Bvℓ
effective length =

v=

3)

V2 = ∴ V1 = 8V = 24 V
∴ Charge at 3μf = CV = 1μF × 8V = 8μc

4)
Let Fe = electrostatic force
FB = buoyancy force
∴ mg = Fe + FB

mg =

FB = and Fe = QE

∴ Q=

5) ω2 = 16 π2 ⇒ ω = (4π)
Q = Q0 cos (ωt)
Q = 24 × 10–6 cos (4πt)

at

6) Explanation question:
Given sin(108 t + 2z)j V/M
Find
Concept:
Equation of and .
Solution:

0
B =

Here,

Now,
So, = sin(108 t + 2z)
Final Answer: option (A)

7)
So ρ is almost is constant
R = R0A1/3
R ∝ A1/3
8)
Force due to beam assuming complete reflection

; P is power
So change in momentum of mirror.

m (V–0) =
Now using work energy theorem ….(1)

Wg = Δk

–mgℓ(1–cosθ) =

as θ is small

(from eq. (1))

9) Magnetic field does not work

∴ Speed will not charge, so De-Broglie wavelength remains same.

10)

….. (i)

and ….. (ii)

Now
λAB = 3000Å

11)
R2 = r2 + (R – t)2
= r2 + R2 + t2 – 2Rt

R= ≃

=
= 15 cm

12)

The Correct Answer is (C)

13)

The Correct Answer is (A)

14) d =

= +3 = 1 (4) + 3(3) = 13%

15) F1 + F2 = 16

∴ F2 = 10 N

16) Half distance is covered with v1 the other half is covered with v2 & v3
 = ⇒ vav = = 4 m/s

17)

Option (C) is correct

18)
(m1g – 2T) = m1a – (1)
T – m2g = m2(2a)
2T – 2m2g = 4m2 a – (2)
m1g – 2m2g = (m1 + 4m2) a

a=

S= at2

t = 0.4 sec
19)

tB = 0 (torque about point B is zero)

(TA) × 100 – (mg) × 50 – (2mg) × 25 = 0
100 TA = 100 mg
TA = 1 mg

20)

Since, each vibrational mode, corresponds to two degrees of freedom, hence, f = 3

(trans.) + 3(rot.) + 8 (vib.) = 14

& g=

γ=

W=
As W < 0. work is done on the gas.

21) BP = Bcylinder – Bcavity

= –

22)
Total possible transition = 6

23)

24)

Thermal force F = Ay∝ΔT

F = (10 × 10–4) (2 × 1011) (10–5)(400)
 F = 8 × 105 N ⇒ x = 8

25)

ωf = ω0 + at
α = 1200 × 6

=
θ = 200

PART-2 : CHEMISTRY

26)

27)

Due to formation of Anilium ion

28)

Question Explanation:
Determine the final product ‘C’ in the given reaction sequence starting from nitrobenzene.
Concept:
This question is based on Organic chemistry, aromatic substitution, reduction, diazonium salt
formation, coupling reaction, azo coupling.
Solution:
Final answer : Option(C)

29)

Explain Question:
Identify the product of the reaction between a substituted aromatic compound containing both
an amide and an ester group when treated with Br2NaOH and heat.
Concept:
This question is based on Hofmann Bromamide Degradation and intramolecular amide
formation.
Solution:

Final Answer: The correct option is (C).

30) Non-aromatic

31) Question Explanation: Calculating the percentage of sulfur from a Carius test result.

Concept: Carius method.

Solution:
Molecular mass of BaSO4 233.38 g/mol.
233.38g of BaSO4 32 gm of S.

0.5544 g of BaSO4
= 0.076

= 38%

32)

33) [CO( )6]±x

C.N. = 6
Co+3 H2O act SFL
— —

μ = BM =
no. of unpaired e– = 0
0
Co+3 = [Ar] 3d64s

34) Explain Question:

Identify the incorrect order of given properties for 3d-series elements.
Concept:
Periodic trends in transition metals: melting points, ionization enthalpy, oxidation states, and
magnetic moments.
Solution:
• Option A: Ti < V < Cr > Mn —Melting points incorrect.
• Option B: Ti < V < Mn < Cr—2nd ionization enthalpy order is correct ; Cr (half-filled 3d5)
has unusually high 2nd IE, Mn,< Cr, so order is correct.
• Option C: Ti < V < Cr < Mn — Number of oxidation states increases towards middle of 3d
series; correct.
• Option D: Ti3+ < V3+ < Cr3+ < Mn3+ — Magnetic moment depends on unpaired electrons;
correct.
Final Answer: Option (A)

35)
is more stable Yb+2 is reducing agent.

36) Ti4+, Cr+6, Mn7+ have zero unpaired electron while V+4 has one unpaired electron.

37) Correct order is

Ge+4 > Sn+4 > Pb+4

38) In , all 8 bonds are not equivalent.

39)

The Correct Answer is (C)

40) CH3CHO(g) → CH4(g) + CO(g)

t=0 80 0 0
t = 20min 80 – x x x
(80 –x) + x + x = 120 ⇒ x = 40
t1/2 = 20min
 K= = 3.465 × 10–2 min–1

41) 2NH3 N2 + 3H2

t=0 a mole b mole 0

t=t a–x b+

= ⇒

42) Heat gained by ice = heat lost by copper

m × 3.5 × 105 = 2 × 400 × (500 – 0)
where, m is the mass of ice melts

Thus,

43)

44) 3S ⇌ S3
1 0

1–α ⇒ i=1–

Now 0.1 = 0.08

⇒ a = 0.3
⇒ 30% trimerization.

45) (0.2 × r) mole

8KI + 5H2SO4 → 4K2SO4 + 4I2 + H2S + 4H2O
 V = 25 ml

46) Question Explanation:

Identify the number of carbohydrate compounds from the given list that test positive with
Tollen's reagent and exhibit mutarotation.

Concept:
This is based on Reducing Sugars, Hemiacetal Linkage, Mutarotation and Tollen's Test.

Solution:
Compounds with a free hemiacetal group (anomeric carbon bonded to -OH) can open into a chain
form with an aldehyde group, making them reducing sugars that give a positive Tollen's test and
show mutarotation.

Final Answer: 2

47)
Total = 2 + 2 + 2 + 2 = 8
 48) BeCl2, BCl3 are e– deficient.

49) Question Explanation: Calculating molar enthalpy of solution from temperature change.
Concept: Enthalpy of Solution. Solution: Use q = mcΔT to find heat absorbed/released by the
water, then convert it to molar value for the solute. Calculation:

NH4NO3(s) + heat + NO3– (aq.)

Heat absorbed = ms ΔT
= 25 × 1 × 4 = 100 cal.

ΔHSolution =
Final Answer: 8

50) ΔU = 3.5 ×

= 3.5

= 3.5
7000 J = 7 kJ

PART-3 : MATHEMATICS

51) ΔABC is equilateral

Orthocentre and centroid will be same

Mid-point of AB is
52) parabola x2 = 12y
SA ⊥ SB
so, mAS · mAB = – 1

by solving 3α =

ordinate of centriod of ΔSAB = K =

k=

53)

54) Centre of the circle =

Equation of diameter = 2x + 3y – k = 0

⇒k=6
Now, Equation of ellipse becomes
x2 + 9y2 = 36
length of LR
∴ 2m + n = 2(4) + 3 = 11

55) Given mean

Given, σ2 = 4

Now,

(from eq. (i))

56) x1, x2…….x10

Mean
∴ Σxi = 12
10α + 2 = 12 ∴ α = 1

Now Let yi = xi – β

6–5b=±4⇒ (not possible) or β = 2

Hence

57)

⇒ a = 17, b = 27, c = 11
a + b + c = 52

58) f(x + y) = f(x) × f(y) , f(1) = 3

f(2) = f2(1) = 32
f(3) = f(1) f(2) = 33
f(4) = 34
f(k) = 3k

f(1) + f(2) + f(3) + ……….+ f(k) = 3279

3 + 32 + 33 + ……….3k = 3279

3k – 1 = 2186
3k = 2187

59) Given |adj(adj(adj.A))| = 124

Given n = 3

We are asked

60) For

For ,
x=4
Hence sum =

61) Put x = 0

62)
n=8
So

63) Vowels: I, 4E
Consonants: 3N, 2D, P, C
Total ways of arrangements taking vowels together

= 16800

64)

Sign of f'(x) changes from – to + i.e. minima at x = 0.

65) , –1 ≤ ≤1
⇒ –2 – 1 ≤ – |x| ≤ 2 – 1
⇒ –3 ≤ – |x| ≤ 1
⇒ –1 ≤ |x| ≤ 3 ⇒ x ∈ [–3, 3]
66)

⇒ y' =

67)

Solution :
xdy = (y + x3cosx)dx
xdy = ydx + x3cosxdx

= xsinx + cosx + C
⇒ 0 = –1 + C
⇒ C = 1, x = π, y = 0

so = xsinx + cosx + 1
y = x2sinx + xcosx + x

Put

Final Answer : Option (1)

68)

shaded portion = circular (OABC)

Area B = Ar Area of arc of circle (ABC)

69)

70)

71) A. (O, 2, α)

⇒ α = 3 ⇒ α2 = 9

72)

Let the incorrect mean be μ' and standard deviation be σ'

We have

As per given information correct

= 180 – 10 + 12

⇒ μ (correct mean) =
Also
Correct = 2295 – 100 + 144 = 2339

σ2 (correct variance) =
Required value

= 2521

73)

74) Question Explanation:

Determine |a + p| for differentiability at x = 1.

Concept:
Differentiability of Limit-defined Functions.

Solution:
The function simplifies based on the interval of x :

For . Dividing by this term gives .

For . This gives .

At x = 1, the given value is f(1) = 0.
Continuity at x = 1 requires RHL = f(1) :

For differentiability, equate the Left and Right Hand Derivatives:

Equating both gives .

The required value is .

Final Answer: 6.
75)
We know that,
x–[x] = {x}
⇒ x – [x + 1] = {x} –1

Hence,