Faraday’s Laws of Electrolysis
Q1. A current of 3.0 A is passed for 2 hours through molten NaCl. Calculate the mass of
sodium deposited at cathode.
Q2. How long must a current of 2.5 A be passed through CuSO₄ solution to deposit 5.0 g of
copper? (Atomic mass of Cu = 63.5)
Q3. A current deposits 0.635 g of copper in 50 minutes. Calculate the current used.
Q4. Calculate the charge required to liberate 2.24 L of H₂ gas at STP during electrolysis of
acidified water.
Q5. 0.5 A current is passed for 1 hour through AgNO₃ solution. Calculate the mass of silver
deposited. (Ag = 108)
Q6. Calculate the time required to deposit 1.08 g of Ag using a current of 0.5 A.
Q7. How much aluminium is deposited when a current of 10 A is passed for 1 hour through
molten Al₂O₃? (Al = 27)
Q8. Calculate the volume of O₂ liberated at STP when 19300 C of charge is passed through
acidified water.
Q9. A current is passed through two electrolytic cells connected in series containing AgNO₃
and CuSO₄. If 1.08 g of Ag is deposited in the first cell, calculate the mass of Cu deposited in
the second cell.
Q10. Calculate the current efficiency if 0.9 g of Cu is deposited when theoretically 1.2 g
should be deposited.
Q11. A current of 5 A is passed through molten MgCl₂ for 30 minutes. Calculate: (a) Mass of
Mg deposited (b) Volume of Cl₂ liberated at STP
Q12. During electrolysis of water, 1 L of H₂ is collected. Calculate the volume of O₂ collected
at the same conditions.
Q13. A solution of CuSO₄ is electrolysed using 2 A current for 1 hour. If only 80% current
efficiency is achieved, calculate the actual mass of Cu deposited.
Q14. Calculate the time required to produce 10 g of chlorine gas by passing a current of 5 A
through molten NaCl.
Q15. In an electrolysis experiment, 0.2 mol of electrons are passed. Calculate: (a) Mass of Cu
deposited (b) Volume of H₂ evolved at STP
Q16. Two electrolytic cells containing AgNO₃ and Al₂(SO₄)₃ are connected in series. If 10.8 g
of Ag is deposited, calculate the mass of Al deposited.
Q17. A current is passed through a solution of NiSO₄. If 2.95 g of Ni is deposited by passing
9650 C charge, calculate the valency of Ni. (Ni = 58.7)
Q18. Calculate the volume of gases liberated at both electrodes when 0.5 F of electricity is
passed through acidified water.
Q19. A student passes current through CuSO₄ solution using inert electrodes. After passing
2F charge: (a) Mass of Cu deposited (b) Change in concentration of Cu²⁺ ions
Q20. An unknown metal M³⁺ requires 19300 C to deposit 3.0 g of metal. Calculate the atomic
mass of the metal.