11-05-2025

1803CJA101016250008 JM

PART-1 : PHYSICS

SECTION-I

1) A person travels x distance with velocity and then x distance with velocity in the same
direction. The average velocity of the person is , then the relation between , and will be :

(A)

(B)

(C)

(D)

2) The position vector of a particle is given as . The time after which velocity
vector and acceleration vector becomes perpendicular to each other is equal to :-

(A) 1 sec
(B) 2.5 sec
(C) 2 sec
(D) 1.5 sec

3) For a particle moving in a straight line the position of the particle at time (t) is given by x = – t2
– 9t + 18 m. What is the velocity of the particle when its acceleration is zero :-

(A) 18 m/s
(B) –9 m/s
(C) –11 m/s
(D) 6 m/s

4) A particle is moving on a straight line represented by x-axis. When its velocity (v) and position
coordinate (x) have opposite signs

(A) its speed is decreasing

(B) its speed is increasing
(C) it is moving towards the origin
(D) neither of the above statements can be true

5) A ball is thrown vertically upwards from the ground. It crosses a point at the height of 25 m twice
at an interval of 4 secs. The ball was thrown with the velocity of
(A) 20 m/s
(B) 25 m/s
(C) 30 m/s
(D) 35 m/s

6) A person throws balls into air vertically upward in regular intervals of time of one second. The
next ball is thrown when the velocity of the ball thrown earlier becomes zero. The height to which
the balls rise is : (Assume, g = 10 ms–2)

(A) 5 m
(B) 10 m
(C) 7.5 m
(D) 20 m

7) Figure shows the path followed by a particle. Its velocity is shown at points A and B.

Which of the vectors in the given options best represents the average
acceleration of the particle for its motion from A to B ?

(A)

(B)

(C)

(D)

8) Statement-I : In rectilinear motion positive and negative accelerations increases and decrease
speed respectively. Statement-II : If acceleration and velocity are in same direction, speed
increases and if they are in opposite direction speed decreases.

Statement-I is True, Statement-II is True ; Statement-II is a correct explanation for

(A)
Statement-I.
Statement-I is True, Statement-II is True ; Statement-II is NOT the correct explanation for
(B)
Statement-I.
(C) Statement-I is True, Statement-II is False.
(D) Statement-I is False, Statement-II is True.

9)
The wavelength associated with a moving particle depends upon pth power of its mass m, qth power of
its velocity v and rth power of Planck's constant h. Then, the correct set of values of p, q and r is (E =
hν, E is the energy of a wave, ν is frequency & h is planks constant)

(A) p = 1, q = –1, r = 1
(B) p = 1, q = 1, r = 1
(C) p = –1, q = –1, r = –1
(D) p = –1, q = –1, r = 1

10) A vector of magnitude 10 m in the direction 37° south of west has its initial point at (5 m, 2 m).
if positive x–axis represents the east and positive y–axis the north, the coordinates of its terminal
point are

(A) (–3 m, –4 m)
(B) (3 m, 4 m)
(C) (–4 m, 6 m)
(D) (–4 m,–6 m)

11) Given the vectors ; and . Find the angle between

and

(A)

(B)

(C)

(D) none of these

12) If and are two unit vectors such that and are perpendicular to each other,
then the angle between and is

(A) 45°
(B) 60°
cos–1
(C)

cos–1
(D)

13) Which of the following graph can represent the equation y = –3x2 + 5:-
(A)

(B)

(C)

(D)

14) is equal to–

(A) 2x + ex
(B) ex (x + 2)
(C) xex (1 + x)
(D) xex (x + 2)

15) Value of is :

(A)

(B)
2
(C) x + logex + 2x + C

(D)

16) If x = a cos t, y = b sin t then equals :

(A)
tan t
(B)
cot t

(C)
tan t

(D)
cot t

17) A force of 100 N is acting on a block as shown in figure. Its horizontal and vertical component

are respectively.

(A)
(B)
(C)
(D)

18) Figure shows the velocity time graph of a particle moving along straight line (v is m/s and t is in

seconds). Its average velocity in 20 seconds will be:

(A) 10 m/s
(B) zero
(C) 3.75 m/s
(D) 7.5 m/s

19) An object starts at the origin in a straight line. Its velocity versus time graph is shown in
the figure. Which one of the following choices best gives the proper intervals(s) of time for which the

object is moving away from the origin?

(A) Only for times 0 s < t < 3s

(B) Only for times 0 s < t < 5 s
(C) Only for times 3 s < t < 5s
(D) Only for times 0 s < t < 7 s

20) Starting from rest at t = 0, a car moves in a straight line with an acceleration given by the

accompanying graph. The speed of the car at t = 3 s is :

(A) 1 m s-1
(B) 2 m s-1
(C) 6.0 m s-1
(D) 10.5 m s-1

SECTION-II

1) A body starts from rest with uniform acceleration. Its velocity after 2n seconds is V0 the

displacement of body in last 'n' seconds is value of β =

2) The relation describes the position of a particle moving in a straight line where x is in
meters and t in seconds. The acceleration of the particle (in m/s2) when it attains a velocity of 16 m/s
is :-

3) A car, moving with a speed of 50 km/hr, can be stopped by brakes after at least 6 m. If the same
car is moving at a speed of 100 km/hr, the minimum stopping distance is x. Calculate x. (in meter)

4)

A dust particle oscillates in air with a time period which depends on atmospheric pressure P, density
of air d and energy of particle E. Time period is proportional to (P)a (d)b (E)c. Find the value of (–6a +
2b + 3c).

5)

approximate value of (1.002)100 is n then 5n is__________.

PART-2 : CHEMISTRY

SECTION-I

1)
The successive ionisation energies for an element X are given below
IE1 = 410 kJ / mole
IE2 = 820 kJ / mole
IE3 = 1100 kJ / mole
IE4 = 1500 kJ / mole
IE5 = 7000 kJ / mole
Find out the number of valence electron for the atom X

(A) 4
(B) 3
(C) 5
(D) 2

2) In which of the following process maximum energy releases

(A) O+2 → O
(B) N → N¯
(C) F → F¯
(D) Be+ → Be

3) X, Y and Z are consecutive elements in a period & order of their size is X < Y < Z. What will be
the order of ionic mobility of respective ions i.e. Z+(aq) , Y+2(aq) and X+3(aq) is

+ +2 +3
(A) Z (aq) > Y (aq) > X (aq)
+ +2 +3
(B) Z (aq) < Y (aq) < X (aq)
+ +2 +3
(C) Z (aq) = Y (aq) = X (aq)
+3 + +2
(D) X (aq) > Z (aq) >Y (aq)

4) Which of the following order is correct against mentioned properties :

(A) P3– < S2– < Cl¯ (Ionic size)

(B) He+ < H+ < H¯ (Ionic size)
(C) Se < O < S (Electron affinity)
Cr = Fe = Zn (Number of fully vacant orbitals up to shell having highest principal quantum
(D)
number)

5) Three different elements along with their respective ionisation energies are given below

Element IE1(eV/atom) IE2(ev/atom)

X 302 2590

Y 542 989

Z 1246 2140
Based on the above information , element which may be alkali metal and non-metal respectively are :
(A) Y, Z
(B) X, Y
(C) X, Z
(D) Can not be predicted

6) For the hydroxide of two elements A and B i.e AOH and BOH, if ΔEN (A–O) bond is lesser than
ΔEN of (B–O) bond. Then which is incorrect statement regarding this (ΔEN = difference between
electronegativity of element and oxygen) ?

(A) BOH reacts more readily with an acid than AOH

(B) AOH reacts more readily with an acid than BOH
(C) BOH has more basic strength than AOH
(D) Both (A) and (C) are correct statements

7) Option representating incorrect relation between various scales of electronegativity (EN) is :-

(A)
= EN (Allred Roschow)
(B) EN (pauling) + 0.744 = EN (Allred Roschow)

(C)
EN (Pauling) =
(D) EN (Pauling) – 0.744 = EN (Allred Roschow)

8) The correct statement among following is (consider sign also)

IE1 = First ionisation energy
EGE1 = First electron gain enthalpy
EA1 = First electron affinity

(A) IE1 of element M(g) = EGE1 of M(g)

(B) IE1 of element M(g) = EA1 of M(g)
+
(C) IE1 of element M(g) = |EGE1 of M (g)|
+
(D) IE1 of element M(g) = EGE1 of M (g)

9)

In which of the following pair, the first one is large in size than the second ?

(A) (Cl–, S2–)

(B) (Sc, Zn)
(C) (Sn4+, Sn2+)
(D) (Sn, Pb)

10) Which of the following is smallest anion.

(A)

(B)

(C)
(D)

11) Two elements have set of quantum numbers of their last filled subshell of valence shell as follows
:
'X' → n = 4 ℓ = 1
'Y' → n = 5 ℓ = 2
Then which statement is INCORRECT

(A) Element 'Y' has greater atomic number than atomic number of element 'X'
(B) Element 'X' has 10 electrons in 'd' subshell
(C) Element 'X' is not a transition element
(D) Atomic size of element 'Y' is equal to the atomic size of element 'X'

12) Process I X(g) X–3(g)

Process II X(g) X+3(g)
Which of the following is NOT changed during both processes :

(A) Total number of protons

(B) Number of neutron
(C) Both (1) and (2)
(D) Total number of electrons

13) Which of the following species are hypervalent?

(1) PC15, (2) BF3, (3) XeF2, (4) CO32–

(A) 1, 2, 3
(B) 1, 3
(C) 3, 4
(D) 1, 2

14) The set of species that involve all "p" orbitals of central atom in bonding is.

(A) PH3 , SO2 , BeF2 , NH3

(B) SbH , , , N2
3

(C) HIO3 , SO3 , NOF3 , AsH3

(D) H2Se , OF2 , Be(OH)2 , NCl3

15) In which of the following pairs of species the central atoms do NOT have same hybridisation ?

(A) XeOF2, XeO2F2

+1
(B) (ClO2) , SnCl2
(C) XeO3F2, SOCl2
–1 –1
(D) (XeF3) , (ClF4O)

16) In which of the following species maximum atom can lie in same plane?
(A) C2H4
(B) SF4
(C)
(D) XeF4

17) In which of the following molecular shape must not be involved in bonding?

(A) Pentagonal plnar

(B) Trigonal planar
(C) Linear
(D) Square planar

18) Formal charge on I, II and III nitrogen atom respectively in is:

(A) –2, +1, 0

(B) 0, +1, –2
(C) +1, 0, –2
(D) 0, –2, +1

19) The types of bond present in are

(A) only covalent

(B) only ionic
(C) ionic and covalent
(D) covalent & coordinate

20) Consider the following graph representing potential energy and internuclear distance between

two H-atoms. Select the incorrect statement-

(A) Magnitude of x gives the bond energy as well as bond dissociation energy
Moving from a to d, the magnitude of x decreases to z due to increase in internuclear repulsion
(B)
hence potential energy increases
moving from a to b the value of x decreases to y as attractive forces becomes dominant over
(C)
repulsive forces
At distance c which tends to infinity, the potential energy would be only due to H-atom
(D)
themselves, not because of any interaction between two atoms

SECTION-II
1) Out of given seven species, how many specie(s) is/are hypervalent?
BF3, SF4, ClF3, CH4, SiCl4, ,

2)

In which of the following orbital will take part in hybridisation

PCl5, SF4, IF7, XeF6, ,

3) In which of the following molecules, pπ– dπ bond is not possible ?

4) What is the group of element (unu) in modern periodic table.

5) Numbers of elements from the following having higher IE than oxygen are.
He, Ne, N, Be, C, F

PART-3 : MATHEMATICS

SECTION-I

1) If the roots of ax2 + bx + c = 0 are α,β and the roots of Ax2 + Bx + C = 0 are α – k, β – k, then

is equal to

(A) 0
(B) 1

(C)

(D)

2) If α, β are the roots of the equation x2 – 3x + 1 = 0, then the equation with roots
will be

(A) x2 – x – 1 = 0
(B) x2 + x – 1 = 0
(C) x2 + x + 2 = 0
(D) None of these

3) If the roots of the quadratic equation x2 + 6x + b = 0 are real and distinct and they differ by
atmost 4 then the least value of b is -
(A) 5
(B) 6
(C) 7
(D) 8

4) If equation 2x2 + 5x + 1 = 0 and x2 + bx + c = 0, b, c ∈ Q have a common root then value of b + c

is

(A) 5
(B) 2
(C) –4
(D) 3

5) If the solution for the inequality is (–∞, a) ∪ (b, c) ∪ (d, ∞) then -

(A) 3a + 4b + c + d = 0
(B) a + b + c + d = 3
(C) 2a + b + c + d = 0
(D) 3a + 2b + c + d = 2

6) The sum of all integers satisfying the inequality x2 − 6x + 8 < 0 is

(A) 9
(B) 10
(C) 11
(D) 8

7) If α2 = 5α – 3, β2 = 5β – 3 then the value of + is-

(A) 19/3
(B) 25/3
(C) –19/3
(D) none of these

8) If the quadratic equation ax2 + bx + 6 = 0 does not have two distinct real roots, then the least
value of 2a + b is -

(A) 2
(B) – 3
(C) – 6
(D) 1

9)

The quadratic equations x2 – 6x + a = 0 and

x2 – cx + 6 = 0 have one root in common. The other roots of the first and second equations are
integers in the ratio 4 : 3. Then the common root is

(A) 1
(B) 4
(C) 3
(D) 2

10) The solution set for |x| > 7

(A) (–∞, –7) ∩ (7, ∞)

(B) (–7, ∞)
(C) (7, ∞)
(D) (–∞, –7) ∪ (7, ∞)

11) The value of k for which the equation (k – 2) x2 + 8x + k + 4 = 0 has both roots real, distinct and
negative is :

(A) 4
(B) 3
(C) 6
(D) 1

12) The roots of the quadratic equation x2 – 2 x – 22 = 0 are

(A) imaginary
(B) real, rational and unequal
(C) irrational roots
(D) none of these

13) If α and β are roots of the equation x2 + px + = 0, such that |α – β| = , then p belongs to
the set :

(A) {2, –5}

(B) {–3, 2}
(C) {3, –5}
(D) {–2, 5}

14) If two roots of the equation (x – 1) (2x2 – 3x + 4) = 0 coincide with roots of the equation
x3 + (a + 1) x2 + (a + b) x + b = 0 where a, b ∈ R then 2(a + b) equals

(A) 4
(B) 2
(C) 1
(D) 0
15)

Consider the equation x2 – 5x – 3 = 0, having roots α and β then the equation with roots 2α + 1 and
2β + 1 is -

(A) x2 – 12x – 1 = 0
(B) x2 + x – 1 = 0
(C) x2 + x + 2 = 0
(D) None of these

16) The set of values of ‘a’ for which the inequality (x – 3a) (x – a – 3) < 0 is satisfied for all x in the
interval 1 ≤ x ≤ 3

(A) (1/3, 3)
(B) (0, 1/3)
(C) (–2, 0)
(D) (–2, 3)

17) The minimum value of the expression x2 – kx + a is 6 which is obtained at x = 3. Find the value of
α/3.

(A) 5
(B) 10
(C) -5
(D) -10

18) Quadratic equation x2 – 4x – 4 = 0 has roots α, β.

Equation whose roots are is

(A) 4x2 + 4x – 1 = 0
(B) 4x2 – 4x – 1 = 0
(C) x2 + 4x – 4 = 0
(D) x2 + 4x + 4 = 0

19) Let p and q be real numbers such that p ≠ 0, p3 ≠ q and p3 ≠ –q. If α and β are nonzero complex

numbers satisfying α + β = – p and α3 + β3 = q, then a quadratic equation having and as its

roots is :

(A) (p3 + q)x2 – (p3 + 2q)x + (p3 + q) = 0

(B) (p3 + q)x2 – (p3 – 2q)x + (p3 + q) = 0
(C) (p3 – q)x2 – (5p3 – 2q)x + (p3 – q) = 0
(D) (p3 – q)x2 – (5p3 + 2q)x + (p3 – q) = 0

20) If the equations and have a common root and the other
root of the second equation is the reciprocal of the other root of the first, then

(A)
(B)
(C)
(D)

SECTION-II

1) Find the sum of all integral values of 'a' for which the equation x2 + ax + 1 = 0, has only integral
roots

2) α,β are roots of the equation 2x2 – 35x + 2 = 0 then the value of (2α – 35)3(2β – 35)3 is equal to

3) If are roots of x2 – 2x + 4 = 0; then is equal to ?

4) If α,β are roots of the equation , α > β and Pn = αn – βn for each positive

integer n, then the value of is equal to

5) If the equations x2 – px = 0 & x2 + px – p = 0 have a common root (where p ≠ 0), then the
reciprocal of sum of all possible value(s) of p is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C C C C C A A D D A C B B D A B A D D D

SECTION-II

Q. 21 22 23 24 25
A. 4 32 24 7 6

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A A A D C B B C B A D C B C C A B B D C

SECTION-II

Q. 46 47 48 49 50
A. 3 4 2 3 4

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C A A D A A A B D D B C D C A B A A B C

SECTION-II

Q. 71 72 73 74 75
A. 0 64 32 1 2
 SOLUTIONS

PART-1 : PHYSICS

2)

4t – 16 + 4 t = 0
t = 2 sec

3) V =

a=
t=2
V(2) = 2 – 4 – 9 = –11 m/s

4) Draw motion diagram

5) Max. height attained = 25 + (10) (2)2 = 45m

Initial velocity = = 30 m/s

6)

7)
 .

9)

Given The dimensions of right hand side and left hand side terms should be
equal.

So,

or
Now, comparing powers M, L and T, we get
p + r = 0 (i), q + 2r = 1 (ii), – q – r = 0 (iii)
After solving, p = –1, q = –1 and r = 1.
Putting these values, we get

which is the required relation.

10)

tan 37° =

11) Let's say

Unit vector in direction of

= cos θ where θ is angle between and

= cosθ

cosθ =

θ = cos–1

12)
as,

⇒ ⇒

⇒ ⇒ ⇒ θ = 60°

14) =
2 x x
= x e + 2xe
= xex (x + 2)

15)

16) x = a cos t, y = b sin t

18) Vav =
Displacement = area of curve

Vav = = m/s

20) Vt = 3 – Vt = 0 = area under

a – t curve
∴ Vt = 3 = 10.5 m/s

21)

22)
x = (2 + 4t)2
x = 16t2 + 16t + 4

∴ Acceleration is always 32 m/s2

23) 0 = u2 – 2as
 = 24 m.

24)

T = k[P]x[d]y[E]z = k[ML–1T–2]x[ML–3]y[ML2T–2]z
0 0
M L T1 = k[M]x + y + z[L]–x – 3y + 2z[T]–2x–2z
on comparing
x+y+z=0 ......(i)
–x – 3y + 2z = 0 ......(ii)
–2x – 2z = 1 ......(iii)

25) ⇒ (1 + 0.002)100
(1 + x)n ≈ 1 + nx
1 +100 × 0.002
1 + 0.2 ≈ 1.2
5 × 1.2 = 6

PART-2 : CHEMISTRY

37)

Only addition and removed of e– takes plan in both the process so proton and neutron are not
changed.

38)

40) SOCl2 → sp3

45) Intamoleculer distance increases attraction decreases.

PART-3 : MATHEMATICS

52) and αβ =

=0

=0

=0
 =0
2
x –x–1=0

53)

x2 + 6x + b
For real and distinct roots
D>0
36 – 4b > 0
9–b>0
9>b
Difference of roots ≤ 4

≤4
≤4
36 – 4b ≤ 16
5≤b
So least value of b is 5

54) For a common root

55)

Ans.

a = –2, b = , c = 1, d = 4

57) Since, α2 = 5α – 3 ⇒ α2 – 5α + 3 = 0
and β2 = 5β – 3 ⇒ β2 – 5β + 3 = 0
These two equations shows that a and b are the roots of the equation
x2 – 5x + 3 = 0
∴ α + β = 5 and αβ = 3

Now

58)
ax2 + bx + 6 = 0
for x = 2 4a + 2b + 6 = 0
2(2a + b) = – 6
2a + b = – 3
So least value is –3

59) x2 – 6x + a = 0 ...(i)
2
x – 6x + 6 = 0 ...(ii)
Let they have common root α and other roots are 4β and 3β of (i) and (ii) respectively
From (i) α + 4β = 6
4αβ = a ...(iii)
From (ii) α + 3β = c
3αβ = 6
αβ = 2
By (3) a = 8
So x2 – 6x + 8 = 0
(x – 4)(x – 2) = 0
x = 2, 4
So α = 2
common root is 2

61)

D>0
64 – 4(k + 4)(k – 2) > 0
(k – 4) (k + 6) < 0
k ∈ (–6, 4)

k ∈ (–∞, –4) ∪ (2, ∞)

k ∈ (2, ∞)
So k = 3

62)
= 12 + 88 = 100 = 102

Irrational roots

63)
p2 – 3p = 10
(p – 5) (p + 2) = 0
so p = {–2, 5}
66) (x – 3a) (x – a – 3) < 0 for all 1 ≤ x ≤ 3
for x = 1 (1 – 3a) (1 – a – 3) < 0
(1 – 3a) (–a – 2) < 0

for x = 3 (3 – 3a) (–a) < 0

(1 – a) (–a) < 0
0<a<1

So

67) The minimum value of expression ax2 + bx + c is obtained at

Hence ⇒ k = 6.
hence the value of x2 – 6x + α is 6 for x = 3.
⇒ 9 – 18 + α = 6 ⇒ α = 15

Hence .

68) α, β are roots of ax2 + bx + c = 0 then are roots of cx2 + bx + a = 0.

70) According to the equation are roots of equation and are roots
of equation

Therefore, we have and

71) D = a2 – 4 = k2 ; k ∈ Z
⇒ a2 – k2 = 4
⇒ (a – k)(a + k) = 2 × 2 = (–2) × (–2)
⇒ a = 2, –2

73)

= 64 – 32 = 32
74)
and pn = αn – βn (Given) ∴

Now
=1

75)

⇒ p = 0 & x = 0 or