08-06-2025

2401CJA101021250011 JM

PHYSICS

SECTION - I

1) In a winter season (temperature 10°C), take a container and pour 200 gm ice at –20° C and 100
gm water at 40° C in it. What will be the final constituent of water in container if we assume no heat
transfer to atmospher (water equivalent of container is 200 gm, specific heat of ice = sw/2, sw = 1
cal/gm ºC, latent heat of ice = 80 cal/gm):-

(A) 100 gm
(B) 200 gm
(C) 150 gm
(D) 300 gm

2) Among the following four cylindrical rods, in which rod the rate of conduction of heat will be
maximum, if the temperature difference between their ends is same ?

(A) Length 2 m, radius 1 cm

(B) Length 4 m , radius 2 cm
(C) Length 2 m, radius 2 cm
(D) Length 2 m, radius 4 cm

3) A spherical black body with a radius of 12cm radiates 450W power at 500K. If the radius were
halved and the temperature doubled, the power radiated in watt would be :-

(A) 225
(B) 450
(C) 900
(D) 1800

4)
What is the temperature of steel-copper junction at steady state. The length, and area of cross
section of steel is double that of copper and thermal conductivity of copper is nine times that of steel
:-

(A) 10°C
(B) 20°C
(C) 30°C
(D) 40°C

5) If 10 gm ice at 0°C is mixed with 10 gm water at 20°C, the final temperature will be

(A) 50°C
(B) 10°C
(C) 0°C
(D) 15°C

6) If two metallic plates of equal thicknesses, equal areas of cross section and thermal conductivities
K1 and K2 are put together face to face and a common plate is constructed, then the equivalent

thermal conductivity of this plate will be :-

(A)

(B)

(C)

(D)

7) A uniform electric field E = (8m/e) V/m is created between two parallel plates of length 1m as
shown in figure, (where m = mass of electron and e = charge of electron). An electron enters the
field symmetrically between the plates with a speed of 2m/s. The angle of the deviation (q) of the

path of the electron as it comes out of the field will be ……….

(A) tan–1 (4)

(B) tan–1 (2)

(C)

(D) tan–1 (3)

8) Charge Q coulombs is uniformly distributed throughout the volume of a solid hemisphere of

radius R metres. Then the potential at centre O of the hemisphere in volts is
(A)

(B)

(C)

(D)

9) A dipole comprises of two charged particles of identical magnitude q and opposite in nature. The
mass 'm' of the positive charged particle is half of the mass of the negative charged particle. The two
charges are separated by a distance 'ℓ' . If the dipole is placed in a uniform electric field ; such a
way that dipole axis makes a very small angle with the electric field, . The angular frequency of
the oscillations of the dipole when released is given by :

(A)

(B)

(C)

(D)

10) Electric field in a region is found to be . The total energy stored in electric field inside the

cube shown will be

(A)
(B)

(C)

(D) 0
11) In an electric field the potential at a point is given by the following relation V = . The electric
field at is :

(A)
(B)

(C)

(D)

12) The surface density on the copper sphere is σ. The electric field strength on the surface of the
sphere is

(A) σ
(B) σ/2
(C) σ/ε0
(D) σ/2ε0

13) With what angular velocity the earth should spin in order that a body lying at 30° latitude may
become weightless [R is radius of earth and g is acceleration due to gravity on the surface of earth]

(A)

(B)

(C)

(D)

14) A body attains a height equal to the radius of the Earth when projected from Earth' surface. The
velocity of the body with which it was projected is :–

(A)

(B)

(C)

(D)

15)

Calculate energy needed for moving a mass of 4kg from the centre of the earth to its surface. If
radius of the earth is 6400 km and acceleration due to gravity at the surface of the earth is g = 10
m/sec2

(A) 1.28 × 108 J

(B) 1.28 × 106 J
(C) 2.56 × 108 J
(D) 2.56 × 1010 J

16) Time taken by the planet to cover path ABC is t1 & time taken by the planet to cover path C D A

is t2 :-

(A) t1 = t2
(B) t2 > t1
(C) t1 > t2
(D) cannot be determined

17) In the circuit shown below, find the decrease in power dissipated in 2Ω resistance after switch is

closed. The battery is ideal :-

(A) 8.34 W
(B) 21.21 W
(C) 3.68 W
(D) 14.72 W

18) A battery of internal resistance 8Ω is connected to network as shown. In order to deliver

maximum power to network R should be :

(A) 8 Ω
(B) 4Ω
(C) 2 Ω
(D) None of these

19) A hollow spherical conductor have inner radius ‘a’ and outer radius ‘b’. A constant potential
difference is applied across inner and outer shell, due to which current flows radially. Select the

correct statement :-

(A) Drift velocity remains constant

(B) Drift velocity increases radially
(C) Drift velocity decreases radially
(D) Potential gradient [electric field] increases radially

20)

‘n’ identical bulbs, each designed to draw a power P from a certain votage supply are joined in series
across the supply. The total power which they will draw is:

(A) P
(B) nP

(C)

(D)

SECTION - II

1) A current of 2A flows through 6Ω resistance shown in figure. The power dissipated in the 2Ω

resistor is :-

2) A particle is projected radially outwards from the surface of a planet with an initial speed of 4.0
km/s. Maximum height attained by the particle is h = 900 km from the planet’s surface. Find the
radius R (in km) of the planet taking g = 10 m/s2 on the surface of the planet. Fill R/900.
3) In the given figure if α > β, then the net electric field will be in the direction :

4) An electric field Vm–1 exists in the space. If potential at the origin is zero then find the
potential at (5m,3m) in volts.

5) Three rods of the same dimensions have thermal conductivities 3 k, 2 k and k. They are arranged
as shown, with their ends at 100°C, 50°C and 0°C. The temperature of their junction in °C is in

nearest integer.

CHEMISTRY

SECTION - I

1) If {–d [A]/ dt} = 2k1 [A]2 [B] – 2k–1 [C]3 [D] – 3k2 [C]2 then the possible reaction steps are :

(A)

(B)

(C)

(D) None of these

2) 1In the reversible reaction 2NO2 N2O4 the rate of disappearance of NO2 is equal to :

(A) [(2k1 / k2) (NO2)2]

(B) 2k1[NO2]2 – 2k2 [N2O4]
(C) 2k1 [NO2]2 – k2 [N2O4]
(D) (2k1 – k2)[NO2]

3) In the given first order reaction NH4NO2(aq.) → N2(g) + 2 H2O(l) the volume of N2 after 20 min
after a long time is 40 ml and 70 ml respectively The value of rate constant is :

(A) (1/20) ln (7/4) min–1

(B) (2.303/1200) log (7/3) sec–1
(C) (1/20) log (7/3) min–1
(D) (2.303/20) log (11/7) min–1

4) The following data were obtained for a gaseous reaction A2 + 2B → 2AB

A2 B –d[A2]/dt
(mole/It) (mole/It) mole lt–1 min–1
0.1 0.01 0.072
0.1 0.04 0.288
0.2 0.01 0.144.
The rate constant and rate of formation of AB, when [A2] = 0.01M and [B] = 0.02 M will be
(A) 72 (mol L–1)–1 min–1, 0.0288 M min–1
(B) 36 (mol L–1)–1 sec–1, 0.0144 M min–1
(C) 36 sec–1, 0.0144 M min–1
(D) 72 (mol L–1)–1 min–1, 0.0144 M min–1

5) In the following questions, two statements are given :

One labelled as Assertion A and the other as Reason R. Examine the two statements carefully and
mark the correct choice (A), (B), (C) and (D) according to the instructions given below
Assertion A : On increasing the temperature, the value of rate constant (k) of an a elementary gas
reaction always increases.
Reason R : On increasing the temperature, the value of equilibrium constant (Keq) of a reaction
always increases.

(A) if both A and R are correct and R is correct explanation of A.

(B) if both A and R are correct but R is not the explanation of A.
(C) if A is correct but R is wrong
(D) if A is wrong but R is correct

6) The rate of a reaction A doubles on increasing the temperature from 300 to 310 K. By how much,
the temperature of reaction B should be increased from 300 K so that rate doubles if activation
energy of the reaction B is twice to that of reaction A :

(A) 2.45 K
(B) 4.92 K
(C) 9.84 K
(D) 19.67 K
7) Select the option in which all parameters are intensive properties of a system :

(A) Entropy, volume, boiling point.

(B) Molar enthalpy, heat capacity, molarity
(C) Temperature, molarity, melting point
(D) Mass, pressure, molar entropy

8) Match the lists:

List-I List-II

(P) A process carried out infinitesimally slowly (1) Adiabatic

A process in which no heat enters or leaves

(Q) (2) ΔU = 0
the system

A process carried out at constant

(R) (3) Reversible
temperature

(S) Cyclic process (4) Isothermal

(5) Irreversible
(A) P → 3;Q → 1;R → 4;S → 2
(B) P → 5;Q → 4;R → 1;S → 3
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 5;Q → 1;R → 4;S → 3

9) In the redox reaction –

10FeC2O4 + x KMnO4 + 24H2SO4 → 5Fe2 (SO4)3 + 20CO2 + y MnSO4 + 3 K2SO4 + 24H2O.
The values of x and y are respectively –

(A) 6, 3
(B) 3, 6
(C) 3, 3
(D) 6, 6

10) How many mililiters of 0.1 M H2SO4 must be added to 50 ml of 0.1 M NaOH to give a solution
that has a concentration of 0.05 M in H2SO4.

(A) 40 ml
(B) 50 ml
(C) 200 ml
(D) 100 ml

11)

Arrange following carbocations in their stability order :

(A) IV > III > I > II
(B) III > IV > I > II
(C) II > IV > III > I
(D) IV > II > III > I

12) Which of the following is correct order of nucleophilicity in polar protic solvent

(A) I– > Br– > Cl– > F–

(B) Br– > Cl– > I– > F–
(C) Cl– > Br– > F– > I–
(D) I– > F– > Cl– > Br–

13) Which among the following carbocation has the maximum stability.

(A)

(B)

(C)

(D)

14) The increasing order of nucleophilicity of the following nucleophiles is :

(a) (b) H2O

(c) (d)

(A) (b) < (c) < (a) < (d)

(B) (a) < (d) < (c) < (b)
(C) (d) < (a) < (c) < (b)
(D) (b) < (c) < (d) < (a)

15) Correct order of leaving group tendency is :

(A) I– > Br– > Cl– > F–
(B) F– > Cl– > Br– > I–
(C) Cl– > F– > Br– > I–
(D) I– > Cl– > Br– > F–

16) Consider the following anions.

(I) (II)

(III) (IV)
When attached to sp3- hybridized carbon, their leaving group ability in reactions decreases in the
order

(A) I > II > III > IV

(B) I > II > IV > III
(C) IV > I > II > III
(D) IV > III > II > I

17) Which one of the following has maximum nucleophilicity?

(A)

(B)
⊖
(C) CH3O

(D)

18) The best leaving group is :

(A)
(B)

(C)

(D)

19) Which of the following will not give precipitate with aq. AgNO3 ?

(A)

(B)

(C)

(D)

20) The strongest nucleophile as well as best leaving group amongst the following is:

(A)

(B)

(C)
(D)

SECTION - II

1) Given :
X(g) —→ 3Y(g)
Pt = 400 mmHg : Total pressure after time 70 min
P∞ = 600 mmHg : Total pressure after completion
t0.75 = 2 × t0.5
Calculate rate constant of appearance of Y in minute–1 -
given ln2 = 0.7

2)

For reaction A→B, the rate constant and for the reaction X→Y, the rate constant
9 10
. If A1 = 10 , A2 = 10 , = 1200 cal/mol and = 1800 cal/mol, then

temperature at which k1 = k2 is K. Find . (Given : R = 2 cal/K-mol)

3) Which is the strongest nucleophilic site in the following species ?

4)

Identify the electrophilic species among followings

(a) H2O

(b)
(c) NH3
(d) CO2
(e) :CH2
(f) Cl⊕
(g) H⊕
(h) SbCl5
(i) AlCl3

5) Total number of pairs of resonating structure in which second is more stable than first. (a)

(b)

(c)

(d)
(e)

(f)

(g)

MATHEMATICS

SECTION - I

1) If y = , then the value of (1 +x2) is equal to:

(A) –y
(B) –n2y
(C) n2 y
(D) –ny2

2) If g is inverse of , then =

(A)

(B) –1

(C)

(D)

3) If f(x) = (2x – 3π)5 + x + cosx and g is the inverse function of f, then g ′ (2π) is equal to

(A)

(B)

(C)

(D)

4) equals :-
(A)

(B)

(C)

(D)
–

5) For x > 0, is :-

(A) 0
(B) –1
(C) 1
(D) 2

6) Let then at is

(A) –1
(B) 3
(C) π
(D) 0

7) Given: f(x) = 4x3 - 6x2 cos 2a + 3x sin 2a . sin 6a + then

(A) f(x) is not defined at x = 1/2

(B) f′ (1/2) < 0
(C) f′(x) is not defined at x = 1/2
(D) f′ (1/2) > 0

8) If and then

(A)

(B)

(C)
(D)

9) If f(0) = 0 and f′(0) = 2, then the derivative of y = f(f(f(f(x)))) at x = 0 is

(A) 2
(B) 8
(C) 16
(D) 4

10) If y(x) = , then at x = is :

(A)

(B) –1

(C)

(D) 0

11) If , then at , y" + y' + y is equal to:

(A)

(B) 1

(C)

(D) 2

12) Let f(x) = , 0 < x < 1. Then :

(A) (1 – x)2 f'(x) – 2(f(x))2 = 0

(B) (1 + x)2 f'(x) + 2(f(x))2 = 0
(C) (1 – x)2 f'(x) + 2(f(x))2 = 0
(D) (1 + x)2 f'(x) – 2(f(x))2 = 0

13) Let and , Then at is

equal to

(A)
(B)

(C)

(D)

14)

If , then the value of the expression is

(A)
–cot
cot
(B)

tan
(C)

– tan
(D)

15) For θ ∈ (0, π/2), the maximum value of is attained at q =

(A)

(B)

(C)

(D)

16) The most general values of x for which sinx + cosx = {1, a2 – 4a + 6} is given by -
where n ∈ I

(A) 2nπ
2nπ +
(B)

nπ + (–1)n.
(C)

(D) None of these

17) The length of the perpendicular from the origin, on the normal to the curve, x2 + 2xy – 3y2 = 0 at
the point (2, 2) is:

(A)
(B)
(C) 2
(D)

18) If , then f(x) is-

(A) strictly decreasing in (–∞, 10] and strictly increasing in [10, ∞)

(B) strictly increasing in (–∞, 10] and strictly decreasing in [10, ∞)
(C) strictly increasing for every value of x
(D) strictly decreasing for every value of x

19) Complete set of values of K in order that f(x) = sin x – cos x – Kx + b decreases for all real values
is given by -

(A) K < 1
(B) K ≥ 1
(C)
(D)

20) The function f (x) = tan–1 is -

(A) strictly increasing in its domain

(B) strictly decreasing in its domain
(C) strictly decreasing in (– ∞, 0) and strictly increasing in (0, ∞)
(D) strictly increasing in (– ∞, 0) and strictly decreasing in (0, ∞)

SECTION - II

1) If ƒ(x) = x3 + 3ax2 + (11a – 6)x – 2 is increasing function for all x ∈ R, then number of possible
integral value(s) of 'a' is/are-

2) Water is being poured on to a cylindrical vessel at the rate of 1 m3/min and the vessel has a

circular base of radius 3 m. If the rate at which the level of water is rising in the vessel is
m/min, then the value of 'k' is

3) If the sum of greatest & the least values of the function in the interval x ∈ [–1,
1], if they exist, is then the value of 4 is

4) The two curves and cut orthogonally, then is equal to

5) The set of all values of a for which the function possesses
critical points is when a, b, c then a + b + c is equal to
 ANSWER KEYS

PHYSICS

SECTION - I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C D D C C B B D C C B C D A A C D B C D

SECTION - II

Q. 21 22 23 24 25
A. 72.00 8.00 2.00 90.00 67.00

CHEMISTRY

SECTION - I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B B B A C B C A D D A A A A A B A A D D

SECTION - II

Q. 46 47 48 49 50
A. 0.03 3.00 4.00 7.00 4.00

MATHEMATICS

SECTION - I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C C B D C D D B C A D C D D A C B C C D

SECTION - II

Q. 71 72 73 74 75
A. 3.00 9.00 63.00 0.50 5.00
 SOLUTIONS

PHYSICS

1) Heat given by container and water = heat gained by Ice

100 × 1 × 40 + 200 × 1 × 10

= 200 × × 20 + m × 80
(Let 'm' gm ice melts)
m = 50 gm
∴ Total water = 150 gm

2) r =
one having lowest 'r' have highest conduction.

3) = σAT4 = σ.4πR2.T4

4) New Ans. (D) By Hemant Sahu Sir

5)

to dissolve all ice we need latent heat = mL = 10 × 80

= 800
but water can give = msΔt amount if energy = 10 × 20 × 1
= 200
so all ice cannot dissolve and final temperature is 0°C

6)

7)

sx = uxt
1=2×t
vy = uy + ayt

vy = 0 + 8 ×
vy = 4 m/s

8) The potential at centre of sphere in which q charge is uniformly distributed throughout the

volume is by symmetry the potential at centre due to half sphere will be half of
the complete sphere.

9) Note: Dipole will rotate about COM but no option is matching with this calculation.
If we assume dipole to oscillate about midpoint

10)

Energy stored
Energy stored

11)

12)

13) g' = g – ω2Rcos230° = 0

14) By applying conservation of energy

KEi + PEi = KEf + PEf

15)

4E =

16)

From kepler's 2nd law

= constant
Thus ABC, area concept is more ⇒ more time

0
17) i =
P0 = 50 W

iT =

i2 = 7 × = 4.2 A
P = 4.22 × 2 = 35.28 W. ΔP = 14.72 W

18) Wheatstone bridge

2R = 8
⇒ R = 4Ω

19)

i = ne AVd

20)

Let resistance of each bulb is R

In 1st case, power consumed =

In 2nd case,

So, power consumed by all bulb =

21)

22)

(R + 900 × 103) × 8 × 106 = 10 × R × 900 × 103

R = 72 × 105 m ⇒ 7200 km

23)

Since α > β, field due to upper part of the line charge will be greater than field due to lower
part. So vertical component will be in – direction and horizontal component for both the parts
is in ( ) direction. So resultant will be in direction.
 24) = 30dx – 20dy

⇒V = (30x)05–(20y)03 = 150 – 60 = 90 volt

25)
T = 66.67°C

CHEMISTRY

26)

Ans. (B)

27)

Ans. (B)

28)

Ans. (B)
B is the correct answer

29)

Ans. (A)

30)

Ans. (C)

31)

T2 = 304.92 K
(T2 – T1)B = 4.92 K
 32)

Ans. (C)

33)

(P) A process carried out infinitesimally slowly is called reversible process

(Q) A process in which no heat enters or leaves the system is called adiabatic process
(R) A process carried out at constant temperature is called isothermal process
(S) In a cyclic process, state function have no change in their value. So, ΔU = 0

34)

Ans. (D)
K : x=3×2 =6
Mn : x = y = 6

35) H2SO4 + 2NaOH → Na2SO4 + 2H2O

0.1 × V 50 × 0.1 – –
0.1 × V – 2.5 5 – 5 2.5 5

= 0.05
0.1 V – 2.5 = 0.05 V + 0.05 × 50
(0.1 – 0.05)V = 2.5 + 2.5

V= = 100 ml

36)

H effect : – CH3 > CD3

–OCH3 shows + M and – I effect.

37)

Ans. (A)
Explain Question :
Asking the nucleophilicity order of halides in polar protic solvents.
Concept :
Nucleophilicity is the tendency of bond formation with electron deficient atom (other than H+)
through donating the lone pair.
Solution :
Nucleophilicity depends upon electron density and polarisability of lone pair donor atom.
In polar protic solvent smaller anion solvate effectively and decreases charge density by
solvation.
F– is more solvated than I– in polar protic solvent.
Hence nucleophilicity order will be I– > Br– > Cl– > F–
Final Answer : ( 1)
I– > Br– > Cl– > F– due to strong ion dipole interaction with smaller ion

38) Due to σ - resonance

39)
ione pair donating tendency on oxygen is reduced, nucleophilicity reduced b < c < a < d

40)

Ans. (A)

41)

Ans. (B)

42)

Ans. (A)

43) NO2 has strogest electron withdrawing power among NO2, Br, CH3 and H hence potion (A)
is correct.

44) Comp. (4) form antiaromatic (unstable) carbcation.

45)

Ans. (D)

46)

Reaction belongs to first order kinitcs

X(g) —→ 3Y(g)
0
P 0
0
P –P 3P Pt
 0 0
3P = 600 ⇒ P = 200
0
P – P + 3P = Pt = 100

Kx =
KY = 3 × Kx = 3 × 0.01 = 0.03 min–1

47)

Ans. (3.00)

48) The electron pair at position (4) is not delocalised other are delocalised, hence position 4 is
strongest nucleophile.

49)

Ans. (7.00)
b,d,e,f,g,h,i,j are e- deficient so electrophile

50)

Ans. (4.00)

MATHEMATICS

51)

52)

Put
Let

53) g(f(x)) = x
54)

Let y = f(x) and

Now, to find

...(1)
⇒ Differentiating equation (1) w.r.t. to 'x' :-

[Multiply and divide by 'dy' operator]

option (4)

55)
⇒

⇒
⇒ Now,

⇒ using 'LH' Rule :-

option (3)

56)

57)

Ans. (D)

For to be defined
2
2a - a > 0
a ∈ (0, 2)
and ln (2a - a2) ≥ 0
2a - a2 ≥ 1
a2 - 2a + 1 ≤ 0
So a = 1
Now f(x) = 4x3 - 6x2 cos 2 + 3x sin 2 sin 6 + 0
f'(x) = 12x2 - 12 x cos 2 + 3 sin 2 sin 6

cos 2 < 0, sin 2 > 0 sin 6 < 0

58)
⇒

⇒ ......(1)

Also, or x3 + y3 =

Hence, from equation (1),

59)

y'(x) = f'(f(f(x))))f'(f(f(x)))f'(f(x))f'(x)
so y'(0) = f'(f(f(f(0))))f'(f(f(0)))f'(f(0))f'(0)
=f'(f(f(0)))f'(f(0))f'(0)f'(0)
= (f'(0))4 = 24 = 16

60)

61)

y = 1.
62) (0 < x < 1)

f(x) =

Now f '(x) =

∴ f '(x) (1 – x)2 = –
∴ (1 – x)2 f'(x) + 2(f(x))2 = 0

63)

64) On rationalizing ; we get

65)

Emax at

66) sinx + cosx = {1, a2 – 4a + 6}

min(1, a2 – 4a + 6) = 1
sinx + cosx = 1
divide by both side

n∈I

67)

x2 + 2xy – 3y2 = 0 ⇒ (x + 3y)(x – y) = 0

(2, 2) lies on x – y = 0
N at (2, 2) to the line y = x is x + y = 4

Distance from (0, 0) is

68)
⇒
⇒ ∀
⇒ f(x) is strictly increasing ∀ x.

69)
{∵ f(x) decreases}

70) f(x) = ⇒ f(x) =

⇒ f(x) = tan–11 – tan–1 x2 ⇒ f(x) =

⇒ f'(x) =
⇒ f(x) : strictlty ↑ in (–∞, 0) ; strictlty ↓ in (0, ∞)
71)

ƒ(x) ≥ 0 ∀ x ∈ R
3x2 + 6ax + 11a – 6 ≥ 0 ∀ x ∈ R

∴D≤0⇒

72)
Vt = π (3)2h

73)

74) For two curves cut orthogonally

75)

but

or

Hence
a+b+c=0+1+4=5