25-03-2025
Modern Display
Technologies
EE 614
Course Instructor: Dr. Debabrata Sikdar
310, Third Floor, EEE Extension Building
Email: [Link]@[Link]
Teaching Assistants:
Sourodipto Das (Research Scholar)
Tushar Shah (Research Scholar)
Email: [Link]@[Link]
[Link]@[Link]
Light Emitting Diode
Introduction:
Operation Principle of Light Emitting Diodes (LEDs)
Electrons and holes recombine in a semiconductor, generating photons.
The emission wavelength depends on the material, active-layer design, and
device structure.
1960s: GaAsP-Based Red LEDs
Red LEDs manufactured using GaAsP on a GaAs substrate.
Challenge: Lattice mismatch (GaAs: 5.65 Å, GaAsP: 5.45 Å) → misfit
dislocations → higher non-radiative recombination.
Increasing phosphorus shifts emission to blue but reduces efficiency due to a
direct-to-indirect bandgap transition at 50% P mole fraction.
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Light Emitting Diode
Introduction:
1970s: Isoelectronic Impurity-Enhanced LEDs:
Introducing impurities (N, Zn:O) into indirect bandgap materials (GaP, GaAsP)
created trap levels, allowing emission in orange, yellow, and green.
1980s: AlGaAs-Based LEDs:
Advantage: Low lattice mismatch (AlAs: 5.66 Å, GaAs: 5.65 Å) → high-
quality crystalline films → reduced non-radiative recombination.
Impact: Enabled heterojunctions and quantum wells for better carrier
confinement and emission tuning.
Limitation: Direct-to-indirect transition occurs at 621 nm when Al content
reaches 45%, restricting AlGaAs/GaAs LEDs to red wavelengths.
Light Emitting Diode
Introduction:
1990s: Introduction of AlGaInP LEDs:
Key benefits: Lattice matching to GaAs by adjusting Al/Ga ratio.
Shorter direct-indirect transition wavelength (555 nm; yellow-green),
improving efficiency.
Current Standard: AlGaInP used for long-wavelength (red, orange, yellow) LEDs.
Introduction to Group III-Nitride Materials: GaN, InGaN, and AlGaN are key
Group III-nitride semiconductors used in short-wavelength LEDs.
They cover the spectrum from UV to blue and green.
Challenges in Group III-nitride LEDs:
Lattice mismatch (lack of a suitable substrate).
Difficulties in p-type doping due to hydrogen passivation.
Indium incorporation issues at high growth temperatures.
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Light Emitting Diode
Introduction:
Figure 5.1: Power efficiencies of LEDs with time for “long wavelength (GaAsP, AlGaAs, and AlInGaP),” and “short
wavelength (nitride)” materials, and for white lighting systems
Light Emitting Diode
Introduction:
Overcoming Growth and Doping Challenges
(i) Lattice Mismatch and Epitaxial Growth
Issue: No native substrate for III-nitrides (unlike GaAs for III–P LEDs).
Solution: Low-temperature buffer layer (AlN or GaN) grown on sapphire
(Al₂O₃) substrate to improve epitaxial quality.
(ii) p-Type Doping in Nitride Semiconductors
Issue: Acceptor dopants (Mg) in GaN are passivated by hydrogen atoms during
growth.
Solution: High-temperature annealing in nitrogen ambient removes hydrogen,
activating p-type conductivity.
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Light Emitting Diode
Introduction:
Overcoming Growth and Doping Challenges (contd):
(iii) Indium Incorporation for Blue Emission
Issue: High vapor pressure of indium at GaN growth temperatures (~1000°C)
makes In incorporation difficult.
Solution: Redesigning epitaxial growth equipment to improve InGaN film
quality.
Impact: Enabled high-efficiency blue LEDs, leading to the 2014 Nobel Prize in
Physics for Akasaki, Amano, and Nakamura.
Light Emitting Diode
Introduction:
White Light Generation Techniques
Since GaN-based LEDs emit in the UV or blue range, white light requires color
mixing:
(i) Multi-Color LED Mixing
Uses red, green, and blue LEDs to create white light.
Pros: High efficiency, tunable color temperature.
Cons: Expensive, complex control circuits, potential color shift over time.
(ii) Phosphor-Based Down-Conversion
A blue or UV LED pumps a phosphor, which absorbs high-energy light and re-
emits yellow/orange light, creating white light.
Pros: Cost-effective, compact, widely used in commercial LEDs.
Cons: Some efficiency loss due to Stokes shift (energy loss when converting
blue to longer wavelengths).
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Light Emitting Diode
Introduction:
Key Factors for High-Performance LEDs
(i) Efficient Carrier Injection & Transport
Minimizing injection barriers & ohmic losses is crucial.
p–n diode structures with low resistance are preferred.
Ohmic contacts are essential for efficient carrier flow, avoiding Schottky
barriers.
(ii) Maximizing Radiative Recombination
Radiative recombination must be greater than non-radiative recombination.
Heterojunctions, electron-blocking layers (EBLs), and quantum structures
confine carriers in the active region for higher efficiency.
(iii) Efficient Light Extraction
Light trapped inside the LED can be lost due to internal reflections.
Surface texturing, patterned substrates, and transparent contacts improve light
extraction.
Light Emitting Diode
Introduction:
Active Layer Engineering for Wavelength Control
The bandgap of the active layer defines the LED’s emission wavelength.
Quantum structures allow tuning of the emission spectrum beyond the bulk
bandgap energy.
Density of States (DOS) in Quantum Structures:
Bulk semiconductors: Continuous energy states → Broad emission spectrum.
Quantum Wells, Wires, and Dots: Discrete energy states → Narrower spectral
width, tunable emission.
Full-Width at Half-Maximum (FWHM) & Temperature Stability:
Quantum structures modify the FWHM of the emission peak and temperature
dependence of the emission wavelength.
Quantum dots provide the best spectral purity and stability.
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Light Emitting Diode
Introduction:
Table- 1. Comparison of Quantum Wells, Wires, and Dots in Light Emission
Structure Effect on Emission Advantages
Confinement in 1 Improved efficiency, wavelength
Quantum Wells(2D)
dimension tunability
Confinement in 2 Further spectral tuning, increased
Quantum Wires(1D)
dimensions radiative recombination
Confinement in all 3 Sharp emission peaks, reduced
Quantum Dots (0D)
dimensions temperature sensitivity
Carrier confinement (heterojunctions, quantum wells, wires, dots) enhances LED
efficiency and spectral control.
Future research focuses on quantum-dot LEDs, micro-LEDs, and perovskite-based
LEDs for higher efficiency and better color control.
Light Emitting Diode
Introduction:
Photon Extraction & Efficiency Optimization in LEDs
Once photons are generated in the active layer of an LED, the next challenge is to
efficiently extract them from the semiconductor and radiate them outward.
Several optical and material-related factors influence the light extraction efficiency.
Challenges in Photon Extraction
(i) Isotropic Emission & Optical Losses
Spontaneous emission in LEDs is isotropic, meaning photons are emitted in
all directions.
Photons may experience:
Absorption by defect states.
Reabsorption through band-to-band or free carrier absorption.
Scattering at defects or material interfaces.
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Light Emitting Diode
Introduction:
Challenges in Photon Extraction (contd):
(ii) Substrate Absorption
If the substrate has a smaller bandgap than the emitted light, it can absorb
photons.
Example: GaAs substrate (Eg = 1.424 eV, 870 nm) absorbs infrared and visible
light → up to 50% light loss.
(iii) Total Internal Reflection (TIR)
When photons travel from a high-refractive-index semiconductor (n ≈ 3.5) into
a low-refractive-index epoxy layer (n ≈ 1.5), they can be totally internally
reflected.
Critical angle from Snell’s Law ≈ 25° → Light at greater incidence angles is
reflected back into the LED, reducing extraction efficiency.
Trapped photons may be reabsorbed by defects or the substrate, reducing efficiency.
Light Emitting Diode
Introduction:
Improving LED Emission Efficiency
Several techniques help increase light extraction and reduce optical losses:
(i) Surface Texturing & Reflectors
Disrupts waveguiding effects and redirects light outward.
Increases scattering, allowing more light to escape.
(ii) Transparent Substrates (e.g., GaP)
Prevents absorption of emitted photons by the substrate.
GaP is transparent to visible light, improving external quantum efficiency.
(iii) Transparent Electrodes (e.g., Indium Tin Oxide - ITO)
Replaces reflective metal electrodes, allowing light to pass through.
Enhances light extraction efficiency without obstructing emission.
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Light Emitting Diode
Introduction:
LED Fabrication & Efficiency Optimization
1. Epitaxial Growth for LEDs
LPE & VPE: Growth from liquid-phase or gas-phase sources.
MOCVD: Most common method using organometallic precursors for ultra-thin,
high-quality layers.
Controls: Doping, defect density, and alloy composition for bandgap tuning.
2. Device Design & Fabrication
Low Contact Resistance: Thermal annealing minimizes power loss.
Optimized Contact Layout: Ensures uniform current flow and better light
extraction.
Etching for Light Extraction: Enhances efficiency but requires post-etch
annealing to prevent defects.
Light Emitting Diode
Introduction:
LED Fabrication & Efficiency Optimization (contd):
3. LED Packaging & Thermal Management
Protection: Shields LEDs from damage and contaminants.
Light Extraction: Uses reflectors, lenses, and phosphors.
Heat Dissipation: Heat sinks and conductive materials prevent overheating.
Applications of LEDs in the Display Industry
1) Traffic Signals:
Higher power efficiency and lower power consumption than incandescent
lamps.
Longer lifetime reduces maintenance costs.
2) Electronic Signage & Large Displays: Used in very large area displays
(several hundred inches diagonal).
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Light Emitting Diode
Introduction:
Applications of LEDs in the Display Industry (contd):
3) LCD Backlighting:
Replaces cold cathode fluorescent lamps (CCFL), which contain harmful Hg.
Provides a wider color gamut and better efficiency.
Offers long lifetime and fast response times.
High power efficiency and long lifespan.
Operates at low voltage (<5V), making them safer and easier to use.
4) Micro-LED Technology:
Uses miniaturized LEDs for high-resolution displays.
High efficiency, brightness, and fast response for various applications (e.g.,
projectors, watches, TVs).
Enables flexible, wearable, and stretchable displays by transferring LEDs to
different substrates.
Material Systems
The material system used in an LED plays a crucial role in:
Emission wavelength (color of light emitted).
Radiative recombination efficiency (how effectively electrons and holes
recombine to emit photons).
Key factors:
Epitaxial active layer:
The light-emitting layer, which determines the bandgap energy and thus the
wavelength of emitted light.
Can be made of binary, ternary, or quaternary compound semiconductors.
Direct bandgap materials are preferred for higher efficiency.
Substrate selection:
Must be lattice-matched to the epitaxial layer to minimize defects and non-
radiative recombination (which lowers efficiency).
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Material Systems
Direct vs. Indirect Bandgap Materials
Direct bandgap materials: Efficient radiative recombination → Suitable for
LEDs.
Indirect bandgap materials: Low photon emission efficiency → Not suitable for
LEDs.
1. Elemental Semiconductors (Group IV) – Indirect Bandgap
Ge (Germanium), Si (Silicon), C (Diamond) → Not suitable for LEDs.
2. III–V Compound Semiconductors – Direct Bandgap
Used for LEDs, as they allow direct electron-hole recombination with high
photon emission efficiency.
Binary compounds (e.g., GaAs, GaP), Ternary compounds (e.g., GaInP,
AlInP) Quaternary compounds (e.g., AlGaInP) forms the basis of LED
materials.
Material Systems
Ternary and Quaternary Compound Semiconductors
Ternary compounds: Created by alloying two binary
materials (e.g.: GaInP, AlInP).
Quaternary compounds: Formed by combining two
ternary materials that differ in one atom type
(e.g., AlGaInP).
Benefit: Enables precise tuning of bandgap and
lattice constant, optimizing emission efficiency and
color range.
• Figure 5.2 shows the relationship between
bandgap, emission wavelength, and lattice
constant for these materials. Figure 5.2: Bandgap and emission wavelength
versus lattice constant for III–V semiconductors of
(a) AlInGa-P and (b) AlInGa-N material systems
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Material Systems
Bandgap Trends & Emission Wavelength
Bandgap vs. Atomic Size
Bandgap energy (Eg) is higher for smaller atoms due to stronger bonding.
General trend: As lattice constant increases, bandgap decreases, and emission
wavelength increases.
Example (Group V elements in III-V compounds):
GaAs < GaP < GaN → Bandgap increases as atom size decreases (As > P > N).
InN < GaN < AlN → Bandgap increases as atom size decreases (In > Ga > Al).
Emission Wavelength Control by Material Choice
As- and P-based semiconductors: Emit in red, orange, yellow, and green regions.
Nitrides (e.g., GaN, InGaN): Used to achieve shorter wavelengths (blue and UV
emission), due to the smallest Group V atoms (N).
Material Systems
Lattice Matching in LEDs
Lattice mismatch (Δa/a₀) = The difference in lattice constants between the
substrate and epitaxial layer, normalized to the substrate value.
Ideal lattice mismatch: ≤ 0.1% for high-quality epitaxial growth.
Why is lattice matching important?
This prevents residual strain in the epitaxial layer.
It reduces formation of dislocations, which increase non-radiative
recombination and decrease efficiency.
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Material Systems
Table- 2. Common Substrate Materials
Substrate Bandgap Pros & Cons
1.424 eV (IR) Lattice-matched to AIGaAs & (AIGa)0.5 In0.5 P, but
GaAs
absorbs visible light, reducing efficiency.
𝐈𝐧𝐏 Low bandgap Not lattice-matched to suitable ternary/quaternary P-
based materials.
High bandgap Not lattice-matched to suitable ternary/quaternary P-
GaP
based materials.
- Used for GaN growth despite lattice mismatch (low-
Sapphire Al2 O3
temperature pre-growth of GaN overcomes this issue).
Material Systems
Direct vs. Indirect Bandgap Materials in LED Efficiency
Figure 5.3: Energy versus momentum curves for semiconductors with (a) direct, (b) indirect, and
(c) near direct-indirect bandgaps
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Material Systems
Direct vs. Indirect Bandgap Materials in LED Efficiency (contd):
Direct Bandgap Materials: Conduction band minimum and valence band
maximum align in momentum space → Efficient radiative recombination.
Optical transitions are vertical (photon emission occurs without momentum
change).
Indirect Bandgap Materials:
Conduction band minimum does not align with valence band maximum.
Requires phonons (lattice vibrations) to conserve momentum, reducing
emission efficiency.
Direct–Indirect Bandgap Transition
As Al concentration increases in AlGaAs and (InGa)₀.₅Al₀.₅P, a direct-to-
indirect bandgap transition occurs, lowering efficiency.
No abrupt efficiency drop—some electrons may still occupy indirect states near
the transition region (Boltzmann distribution effect).
Material Systems
Material Choices for Different LED Colors
(AlGa)₀.₅In₀.₅P LEDs:
Lattice-matched to GaAs.
Direct bandgap for red to amber emission.
To improve external quantum efficiency (EQE), the GaAs absorbing substrate
can be removed and replaced with transparent GaP.
InGaN LEDs:
Increasing “In” concentration shifts emission from blue to green.
Used for shorter wavelength LEDs (high efficiency from blue to green).
LED Spectrum Coverage:
III–N (blue-green) + III–P (amber-red) LEDs can cover the entire visible
spectrum.
Different substrates (sapphire for III–N, GaAs for III–P) make it difficult to
produce broadband white light from a single LED chip.
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Material Systems
White LED Generation Techniques
Since a single LED chip cannot efficiently emit white light, two major techniques are
used:
(i) Multi-LED Assembly
Advantages:
Combines red, green, and blue LEDs to create white light.
Each LED can be optimized individually for efficiency, voltage, and
wavelength.
Disadvantages:
Expensive and bulky.
Color shift issues due to different lifetime performance of each LED over time.
Material Systems
(ii) Phosphor-Coated White LEDs
Advantages:
Uses a blue LED with a yellow phosphor coating, which absorbs blue light and
re-emits yellow light, creating white light.
Compact, cost-effective, and stable color output.
Disadvantages:
Lower efficiency than multi-LED systems due to Stokes energy loss (phosphor
emission wavelength is longer than absorption wavelength).
White LED Optimization
White LEDs must achieve specific CIE coordinates in the chromaticity diagram
to appear as true white.
High Color Rendering Index (CRI) is required to ensure colors appear natural
under LED lighting.
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Diode Characteristics
Formation of a p–n Junction :
When p-type and n-type layers contact, a p–n
junction forms.
Carrier movement:
Holes diffuse from p-side to n-side.
Electrons diffuse from n-side to p-side.
Recombination at the junction creates negative &
positive space charges, forming an internal electric
field (E-field) from n → p. Figure 5.4: Band diagram of a p–n
junction under thermal equilibrium
Diode Characteristics
Depletion Region & Band Bending:
Depletion region: Nearly free of carriers under thermal equilibrium.
The Poisson equation relates dopant concentration to built-in voltage.
Fermi levels align due to band bending at equilibrium.
Forward Bias: Reduces built-in voltage; current flows exponentially above threshold
voltage (Vth ≈ Eg in eV).
Efficiency Loss & Solutions:
Carrier leakage reduces recombination efficiency.
Heterojunctions & Electron-Blocking Layers (EBLs) prevent leakage.
Quantum structures (wells, wires, dots) improve confinement & wavelength
tuning.
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Diode Characteristics: p- and n-Layer
Doping & Carrier Mobility in LEDs
n-Type Doping:
Group IV (Ge, Si) & Group VI (S, Se, Te)
dopants replace Group III/V atoms.
Example: Se in GaAs donates an electron,
forming a donor state near the conduction
band.
p-Type Doping:
Group II (Cd, Zn, Mg, Be) & Group IV (C,
Si) dopants create acceptor states near the
valence band.
Example: Zn in GaAs replaces Ga, creating
Figure 5.5: Schematic diagram of bonding of
holes in the valence band. GaAs with (a) Se and (b) Zn impurities
Diode Characteristics: p- and n-Layer
Doping & Carrier Mobility in LEDs (contd):
Doping Challenges:
p-Doping is less efficient (higher ionization energy).
Impurity contamination (e.g., oxygen in AlGaAs, hydrogen passivation in
nitrides) requires post-annealing.
Site mismatch issues (e.g., Mg in GaN needs Low Energy Electron Beam
Irradiation (LEEBI) to enhance hole concentration).
Carrier Mobility & Resistance Trade-Off:
Electron mobility > Hole mobility in III–V compounds (e.g. GaAs: μn = 5000
cm²/V-s, μp = 300 cm²/V-s).
Higher doping → Lower mobility due to impurity scattering.
Reducing resistance: Increasing carrier concentration compensates for lower
mobility.
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Diode Characteristics: Depletion Region
In this section, describes two important parameters of the depletion region, the
built-in voltage and the depletion width.
The built-in voltage originates from the band bending in the depletion region.
On the other hand, in the p- and n-layers, the band is still flat.
Assuming that the acceptors and donors are fully ionized, the hole and electron
concentrations can be represented as:
𝐸i − 𝐸Fp 𝐸Fn − 𝐸i
𝑝 = 𝑛i exp = 𝑁A 𝑛 = 𝑛i exp = 𝑁D
𝑘 𝑇 Τ𝑞 𝑘 𝑇 Τ𝑞
where p and n are hole and electron concentrations far away from the
depletion region, respectively.
ni is the intrinsic concentration.
Ei, EFp, and EFn are the Fermi energies of intrinsic, p-doped, and n-doped
layers respectively, in units of eV.
Diode Characteristics: Depletion Region
Flat Fermi Level:
In equilibrium (no external bias), the Fermi level
(EF) remains constant throughout the junction.
However, the conduction band (EC) and valence
band (EV) are at different energy levels in the p-
type and n-type regions.
Band Bending:
Due to the difference in carrier concentrations, the
bands bend to maintain thermal equilibrium. Figure 5.4: Band diagram of a p–n
The conduction and valence bands shift relative to junction under thermal equilibrium
the Fermi level on both sides.
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Diode Characteristics: Depletion Region
Electrostatic Potential (ψp & ψn):
ψp (in p-region) and ψn (in n-region) represent the electrostatic potential in each
region.
The potential difference between these regions defines the built-in voltage:
𝑘𝑇 𝑁 𝑘𝑇 𝑁
Vbi=ψn−ψp ; 𝜓P = − 𝐸i − 𝐸Fp = −
𝑞
ln A
𝑛i
and 𝜓n = − 𝐸i − 𝐸Fn =
𝑞
ln D
𝑛i
Therefore; the built-in voltage depends on the acceptor (NA) and donor (ND)
concentrations:
𝑘𝑇 𝑁 𝑁
𝑉bi = 𝜓n − 𝜓p = 𝑞
ln A𝑛2 D ……eq. (1)
i
where, k is the Boltzmann constant, T is the temperature, and ni is the
intrinsic carrier concentration.
This built-in potential prevents further diffusion of majority carriers.
Diode Characteristics: Depletion Region
Effect of Increased Doping:
Higher dopant concentrations increase built-in voltage (Vbi).
In LEDs, heavily doped p–n layers reduce resistance and power consumption.
The Fermi levels in the p- and n-layers shift close to the valence and conduction
bands, respectively.
Forward Bias Condition:
Applying a voltage V >Vbi reverses the band bending.
Holes and electrons move freely across the junction, leading to exponential
current increase.
Electrostatic Theory:
𝜌
Gauss's Law: 𝛻 ⋅ 𝜀𝐸 = 𝜌 and Poisson's Equation: 𝛻 2 𝑉 = − 𝜀
where 𝐸 = Electric field, 𝜖 = Permittivity, 𝜌 = Charge density.
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Diode Characteristics: Depletion Region
Electric Field Distribution:
Charge distribution in depletion region:
−𝑞𝑁𝐴 , −𝑥𝑝 < 𝑥 < 0
𝜌(𝑥) = ቊ
+𝑞𝑁𝐷 , 0 < 𝑥 < 𝑥𝑛
Maximum Electric Field at the junction:
𝑞 𝑞
𝐸max = 𝜖 𝑁𝐷 𝑥𝑛 = 𝜖 𝑁𝐴 𝑥𝑝
Total depletion width : 𝑥𝑛 + 𝑥𝑝 = 𝑊
The built-in voltage can be given by:
𝑉bi = (1/2)𝐸max 𝑊
or by solving for 𝑊 using above eq. : Figure 5.6: Charge density, electric field and
2𝜀 𝑁A + 𝑁D voltage distribution of an LED under thermal
𝑊= 𝑉bi equilibrium
𝑞 𝑁A 𝑁𝐷
Diode Characteristics: Depletion Region
Effect of Bias on Depletion Region:
Forward Bias (𝑽) :
𝑉𝑏𝑖 is reduced to (𝑉𝑏𝑖 − 𝑉).
Depletion width narrows, making carrier movement easier → high current
density.
Reverse Bias:
𝑉𝑏𝑖 is increased to (𝑉𝑏𝑖 + 𝑉).
Depletion width increases, blocking carrier flow.
This causes rectification, allowing current flow in one direction only.
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Diode Characteristics: J–V Characteristics
Carrier transport in a semiconductor can be divided into carrier diffusion and drift.
Diffusion means that carriers move from high to low concentration regions.
Drift current means carrier transport driven by an electric field.
The total current density is the sum of the electron and hole contributions. Take
the hole current density Jp. This can be described by the expressions:
𝐽p = 𝐽p,diff + 𝐽p,drift
𝐽p,diff = 𝑞Dp (d pΤd 𝑥 ൯
𝐽P,drift = P𝑞𝜇p E
where Jp,diff and Jp,drift are the hole diffusion and drift current densities,
respectively. Dp is called the diffusivity; μp is the hole mobility.
The hole mobility defined as the velocity (in terms of cm/s) over the electric field (V/cm).
Diode Characteristics: J–V Characteristics
Thermal Equilibrium:
Hole diffusion (p → n) is balanced by hole
drift (n → p) due to E-field.
No drift current outside the depletion region
(flat bands).
(a)
Forward Bias Effect:
Reduces energy band offset q(Vbi−V).
Diffusion current dominates as carrier
barrier decreases.
Net current flows from p to n region. (b)
Figure 5.7 Band diagram of a LED under
(a) thermal equilibrium and (b) forward bias
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Diode Characteristics: J–V Characteristics
Carrier Distribution in LED under Forward Bias:
Minority carrier concentrations (pn, np) increase near depletion boundary.
Leads to diffusion current in both layers.
Current Density (J) Approximation:
𝐷𝑝 𝐷𝑛 𝑞 𝑉−𝑉𝑏𝑖
J=𝑞 𝑁𝐴 + 𝑁 exp
𝜏𝑝 𝜏𝑛 𝐷 𝑘𝑇
where 𝜏𝑛 , 𝜏𝑝 = minority carrier lifetimes.
Exponential current increases when 𝑉 > 𝑉𝑏𝑖 .
Threshold Voltage & Photon Emission:
𝑉𝑡ℎ𝑟𝑒𝑠ℎ𝑜𝑙𝑑 ≈ 𝐸𝑔 /𝑞 (energy gap determines LED color). Figure 5.8: Carrier distribution
The LED emits a photon at a wavelength 𝜆 = ℎ𝑐/𝐸𝑔 under forward bias
Diode Characteristics:
Heterojunction Structures in LEDs
Homojunction LED:
Uses a single material with a fixed bandgap.
Recombination zone depends on depletion region width.
Heterojunction LED:
Composed of different bandgap materials.
Carrier confinement in the active region enhances recombination efficiency
(IQE increase).
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Diode Characteristics:
Heterojunction Structures in LEDs
Single Heterojunction (SH) LED
p-layer has a smaller bandgap than the n-layer.
Band offset effects:
ΔEv (valence band offset) blocks hole
flow into the n-region.
ΔEc (conduction band offset) traps
electrons, forming an energy well.
High carrier concentration near the SH interface
Figure 5.9: Band structures of single-
→ enhanced recombination. heterojunction LEDs
Diode Characteristics:
Heterojunction Structures in LEDs
Double Heterojunction (DH) LED
Active layer (smallest bandgap) is sandwiched
between two wide-bandgap cladding layers.
Carrier confinement further increases
recombination rate. Figure 5.15: Band structures of
Electron Blocking Layer (EBL) prevents double-heterojunction LEDs
electron leakage into the p-side due to higher
electron mobility (μn ≫ μp).
Figure 5.10: Band structures of LED with EBL
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Diode Characteristics:
Quantum-Well, -Wire, and -Dot Structures in LEDs
Quantum Well (QW) LEDs:
Thin low-bandgap layer (< 20nm) in the active
region defines the emission zone.
Higher recombination rate (localized electron-hole
interactions).
Reduces reabsorption probability due to small
bandgap & thin layer.
Forms quantized energy levels due to layer being Figure 5.11: Band diagram of a
QW structure
smaller than electron/hole de Broglie wavelength.
Precise emission wavelength tuning by adjusting
QW composition & thickness control.
Strained layers possible without relaxation due to
ultra-thin nature.
Diode Characteristics:
Quantum-Well, -Wire, and -Dot Structures in LEDs (contd):
Quantum Wires & Quantum Dots (QD):
Quantum Wires: Carrier confinement in
one dimension (1D).
Quantum Dots: Carrier confinement in zero
dimensions (0D) → Discrete energy levels.
Higher recombination efficiency due to
stronger quantum confinement.
QD formation in nitrides can occur
spontaneously due to In-cluster fluctuations.
More difficult fabrication (requires high-
resolution patterning & epitaxial regrowth). Figure 5.12: Structures of (a) Quantum Well,
(b) Quantum Wire, and (c) Quantum Dot.
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Light-Emitting Characteristics
Radiative & Non-Radiative Recombination in LEDs
In Radiative recombination, electron-hole pair emits photons (desired for LEDs).
In Non-radiative recombination, energy lost due to defects → reduces efficiency.
Minimizing non-radiative losses:
High-quality epitaxial layers to reduce defects.
Annealing to repair damage from fabrication & improves efficiency.
Recombination Process & Light Output:
Langevin recombination rate ∝ (electron & hole concentrations).
Injection current & light output follow a near-linear relationship under certain
conditions.
Emission spectrum depends on DOS (Density of States) in bulk, Quantum Well
(QW), Quantum Wire, Quantum Dot (QD) structures.
Carrier distribution affects wavelength & spectral width (FWHM).
Light-Emitting Characteristics
Photon Extraction Challenges:
Total Internal Reflection (TIR): Limits light escape due to high refractive index
(n > 3).
GaAs substrate absorption in III-P LEDs further reduces efficiency.
Recombination Model
Radiative Recombination in LEDs involves electrons & holes meeting in the
spatial domain.
Emission occurs, when carriers recombine and release energy as photons.
Two-particle process governed by the Langevin formula: 𝑅rad = 𝑟rad 𝑛𝑝
where 𝑅rad is the radiative recombination rate;
n and p are electron and hole concentrations, respectively and
rrad is called the bimolecular recombination coefficient.
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Light-Emitting Characteristics: Recombination Model (contd.)
When the semiconductor is excited, electrons moves from valance band to the
conduction band, creating holes in the valence band.
Excess carriers: Equal number of excited electrons & holes → Δ𝑛 = Δ𝑝.
Where Δ𝑛 and Δ𝑝 are excess electron and hole concentrations, respectively.
For a p-type semiconductor: Majority carriers are holes under thermal
equilibrium, hence: 𝑝0 ≫ 𝑛0 ;
Where 𝑝0 and 𝑛0 are the hole and electron concentrations under thermal
equilibrium, respectively.
Low-Level Excitation ( 𝜟𝒑 ≪ 𝒑𝟎 ) case:
Radiative recombination rate: 𝑅rad = 𝑟rad 𝑛𝑝 = 𝑟rad 𝑛 𝑝0 + Δ𝑝 ∼ 𝑟rad𝑛𝑝0 = 𝑛/𝜏rad
Radiative lifetime: 𝜏rad = 1/𝑟rad 𝑝0
Higher doping →Shorter radiative lifetime → faster recombination.
Light-Emitting Characteristics: Recombination Model (contd.)
Non-Radiative Recombination & SRH Theory
Non-Radiative Recombination:
Energy relaxation via phonons (lattice vibrations), no light emission.
Main cause: Defects in the crystal structure introduce trap states in the
bandgap.
Trap-mediated transitions:
Electrons/holes jump between bands
via phonons or photons.
Figure 5.13: Non-radiative
Shockley–Read–Hall (SRH) Recombination: recombination via deep-level traps
Electrons & holes captured by traps → Recombination occurs.
Shallow traps: Easily capture electrons, but holes recombine slowly.
Deep traps (mid-gap): Higher recombination rate, affecting minority carrier
lifetime.
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Light-Emitting Characteristics: Recombination Model (contd.)
Minority Carrier Lifetime & Recombination Rate:
Non-radiative recombination rate: 𝑅non−rad = 𝑛/𝜏non−rad .
Total recombination rate:
1 1 𝑛
𝑅 = 𝑅rad + 𝑅non−rad = 𝜏
+𝜏 𝑛= 𝜏
rad non−rad
where 𝑅rad , 𝜏rad and 𝜏non−rad are the radiative recombination rate,
radiative lifetime and the non-radiative lifetime, respectively.
Minority carrier lifetime: 𝜏 represents the combined effect of radiative &
non-radiative recombination.
Minority carrier lifetime (𝜏 ) depends on defect density & doping.
Light-Emitting Characteristics: L-J Characteristics
Carrier Continuity Equation
Describes change in carrier concentration under electrical & optical excitation.
For electron concentration in a p-type semiconductor under low injection:
𝜕𝑛 1 𝜕𝐽𝑒 𝑛
= + 𝐺0 + 𝐺𝑒𝑥𝑡 −
𝜕𝑡 𝑞 𝜕𝑥 𝜏
where 𝑞 = Electron charge; 𝐽𝑒 = Electron current density; 𝜏 = Carrier lifetime;
𝐺𝑒𝑥𝑡 = Excess generation rate from optical excitation and
𝐺0 = Thermal equilibrium generation rate = recombination rate (𝑅0 = 𝑛0 /𝜏 )
Rewriting the equation in terms of excess carrier concentration (Δ𝑛) :
𝜕Δ𝑛 1 𝜕𝐽𝑒 Δ𝑛
= + 𝐺𝑒𝑥𝑡 −
𝜕𝑡 𝑞 𝜕𝑥 𝜏
It shows how external excitation and current flow affect carrier concentration
over time.
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Light-Emitting Characteristics: L-J Characteristics (contd.)
Steady-State Electrical Pumping in LEDs
Under steady-state conditions, the continuity equation simplifies to:
1 𝜕𝐽𝑒 Δ𝑛
0= −
𝑞 𝜕𝑥 𝜏
Optical Power Emission in LEDs
Optical power output ( 𝑃out ) is given by:
Δ𝑛
𝑃out = 𝜂ext 𝑃generated = 𝜂ext ℎ𝜈𝐴 𝑑𝑥
𝜏𝑟𝑎𝑑
Where 𝜂ext = Photon extraction efficiency; 𝑃generated = Power generated inside the
LED; ℎ𝜈 = Photon energy; and 𝐴 = Device cross-section area.
By substituting the relation for 𝐽𝑒 , the equation simplifies to:
ℎ𝜈𝐴 𝜏
𝑃out = 𝜂ext 𝐽𝑒 ( in ) − 𝐽𝑒 ( out )
𝑞 𝜏𝑟𝑎𝑑
Light-Emitting Characteristics: L-J Characteristics (contd.)
Impact of Carrier Recombination
If all injected electrons recombine with an equal number of holes, the equation
simplifies further:
ℎ𝜈 𝜏
𝑃out = 𝜂ext 𝐼
𝑞 𝜏𝑟𝑎𝑑
where I (= J*A) is electrical current.
Key Insight: Optical power output is proportional to the electrical current.
Methods to Enhance Optical Power Output
Increase extraction efficiency 𝜂ext
Use wide-bandgap materials (higher photon energy, ℎ𝜈 )
Reduce radiative recombination lifetime (smaller 𝜏𝑟𝑎𝑑 )
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Light-Emitting Characteristics: L-J Characteristics (contd.)
Challenges & Solutions for Light Extraction
Total internal reflection at the semiconductor-air
interface limits efficiency (governed by Snell’s law).
Figure 5.14: Light escape cone of
LED due to the total internal reflection
Solutions to improve light extraction:
Corrugated structures: Disrupt planar geometry to enhance light
coupling.
Die shaping: Redirects light out of the LED.
Epoxy dome & reflector: Protects the LED and enhances extraction
efficiency.
Transparent substrates: Replacing optically absorbing GaAs substrates
improves output in group III–P material systems.
Light-Emitting Characteristics: Spectral Characteristics
Emission Wavelength of an LED is determined by:
Product of Density of States (DOS) and number of carriers at each energy level.
DOS (Density of States):
Represents the number of available recombination states at a given
energy.
In a bulk semiconductor, DOS increases from zero at the band edge as
energy increases.
Carrier Distribution: Decreases exponentially as energy increases.
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Light-Emitting Characteristics: Spectral Characteristics (contd.)
Emission Spectrum Characteristics
Emission Peak Wavelength: Slightly
shorter than the bandgap wavelength.
Spectrum Asymmetry:
Long-wavelength side: Sharp cutoff
due to forbidden states within the
bandgap.
Short-wavelength side: Smooth tail due
to the exponential carrier distribution. Figure 5.15: Emission spectrum from a LED
Light-Emitting Characteristics: Spectral Characteristics (contd.)
Quantum Well (QW) and Quantum Dot (QD) Structures
Energy Quantization: Alters the DOS compared to
bulk semiconductors.
DOS Behaviour:
Bulk Semiconductor: Continuous increase.
Quantum Well (QW): Step-function DOS.
Quantum Dot (QD): Delta-function DOS
(discrete energy levels).
Figure 5.16: DOS of bulk,
Impact on Emission Spectrum: QW and QD structures
Narrower Full Width at Half Maximum
(FWHM).
Wider color gamut (useful for display
applications).
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Light-Emitting Characteristics: Efficiency Droop
Light Output and Current Density
Light output increases linearly with rising current density as per equation:
ℎ𝜈 𝜏
𝑃out = 𝜂ext 𝐼
𝑞 𝜏𝑟𝑎𝑑
Theoretically, a small LED could achieve high light output by increasing
current indefinitely, but practical limitations exist.
Limitations of High Current Density
Increased current density raises temperature, reducing LED efficiency.
Even without temperature effects, efficiency drops at high optical power levels
(e.g., III-N LEDs for general lighting).
External Quantum Efficiency (EQE) initially rises with current but later
declines. This is the "droop effect”.
Light-Emitting Characteristics: Efficiency Droop (contd.)
External Quantum Efficiency (EQE) initially
rises with current but later declines. This is the
"droop effect" (Figure 5.17(a)).
Types of Droop
Temperature Droop: EQE decreases as
(a)
temperature increases.
Current Droop: At fixed temperatures,
EQE rises sharply at first but gradually
declines at high current densities.
(b)
Figure 5.17: (a) EQE versus electrical current
for the LED at different temperatures.
(b) Schematic diagram of Auger recombination.
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Light-Emitting Characteristics: Efficiency Droop (contd.)
Carrier Density and Recombination
At high current densities, excess carrier density surpasses majority carrier
density.
Recombination rate equation modifies to: 𝑅rad = 𝑟rad𝑛𝑝 = 𝑟rad𝑛 𝑝0 + Δ𝑝 ≈ 𝑟rad 𝑛(Δ𝑝)
𝑅rad ≈ 𝑟rad 𝑛2
Auger Recombination: A multi-electron process observed in semiconductors.
Energy transfer occurs when an electron relaxes from conduction to valence
band, boosting another electron to a higher energy level (hot electron).
Energy and momentum conservation require three carriers: an electron, a hole,
and a second electron.
Under high current conditions, total recombination rate follows:
𝑅rad = 𝐴𝑛 + 𝐵𝑛2 + 𝐶𝑛3 ; where A, Bn, and 𝐶𝑛2 represents
the rates of SRH recombination, radiative recombination, and Auger recombination.
Light-Emitting Characteristics: Efficiency Droop (contd.)
Internal Quantum Efficiency (IQE) Formula:
𝐵𝑛2 𝐵
IQE = 𝐴𝑛+𝐵𝑛2 +𝐶𝑛3 = 𝐴/𝑛+𝐵+𝐶𝑛
At low current density (small 𝑛 ), SRH recombination dominates, increasing
IQE.
At high current density (large 𝑛 ), Auger recombination reduces efficiency.
Factors Contributing to Efficiency Droop:
Electron Leakage: Electrons overflow from the quantum well (QW) region to
the p-side.
Current Density Distribution: Uneven current flow worsens droop in high-
density regions.
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Light-Emitting Characteristics: Efficiency Droop (contd.)
Strategies to Reduce Efficiency Droop:
1. Lower Current Density in the active region (increase QW thickness and
number).
2. Prevent Electron Leakage with:
Optimized Electron Blocking Layer (EBL) and improved hole injection.
Controlled polarization in epi-layers to confine carriers efficiently.
3. Improve Current Spreading to avoid carrier crowding in the lateral direction.
Light-Emitting Characteristics: Device Fabrication
LED Fabrication Process
Epitaxial Growth on a Crystalline Substrate
Grown on a crystalline substrate using techniques like LPE, VPE, and MOCVD.
LPE (Liquid Phase Epitaxy): Simple, cost-effective, but limited to lattice-
matched compositions; struggles with thin layers.
VPE (Vapor Phase Epitaxy): More flexibility in alloy composition;
includes chloride, hydride, and organometallic sub-types.
MOCVD (Metal-Organic Chemical Vapor Deposition): A common VPE
method for precise layer thickness, composition, and doping.
Fabrication of p–n Junction
Simpler than laser diodes or transistors.
Requires proper electrode materials, annealing for ohmic contacts, and low serial
resistance.
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Light-Emitting Characteristics: Device Fabrication
LED Fabrication Process (contd.)
Light Extraction & Efficiency Improvements
Escape Cone Design: Allows light emission from bottom, top, and side walls.
Chip Shaping & Surface Engineering: Prevents waveguiding light loss.
Epoxy Encapsulation:
High refractive index increases critical angle for better light extraction.
Curved shape improves transition from epoxy to air.
Packaging Process
Protects LED chips.
Also; it enhances light extraction, and improves thermal dissipation for high-
power applications.
LED Fabrication Process: Epitaxial Growth
Liquid Phase Epitaxy (LPE) for LED Production
LPE Process: Uses high-temperature solvent (molten
metal or salt) with different saturated solutions for layer
growth.
Growth Mechanism: GaAs substrate contacts different
melts, and layers grow under thermal equilibrium as
temperature decreases.
Control Factors: Layer thickness depends on temperature
difference and contact time; oxidation must be minimized
Figure 5.18: Schematic
during melt transfers. diagram of LPE system.
Advantages & Limitations: High growth rate (up to 2
μm/min) suits mass production but struggles with thin layer
growth, like quantum wells
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LED Fabrication Process: Epitaxial Growth (contd.)
Vapor Phase Epitaxy (VPE) for LED Growth
Uses gas sources instead of liquid sources.
Allows better control over thickness, doping, and multilayer growth.
Types of VPE: distinguished by source materials.
1. Chloride VPE: Uses solid group III sources and gaseous group V sources.
Chemical reactions shift equilibrium to deposit epitaxial layers.
2. Hydride VPE: Uses gaseous AsH₃ and PH₃ for group V elements.
More flexible than chloride VPE but involves toxic gases (arsine &
phosphine).
LED Fabrication Process: Epitaxial Growth (contd.)
Vapor Phase Epitaxy (VPE) for LED Growth
Figure 5.19: Schematic diagram of (a) chloride and (b) hydride VPE systems
Advantages:
Hydride VPE offers more flexibility
Precise composition and thickness control.
More flexible than LPE, especially for multilayer growth.
Drawbacks: it involves toxic gases (arsine, phosphine).
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LED Fabrication Process: Epitaxial Growth (contd.)
MOCVD (Metal-Organic Chemical Vapor Deposition) in LED Fabrication
MOCVD : Uses metal alkyls (liquids/waxy solids) and hydrides as sources.
Controlled gas flow allows precise composition and thickness control.
Enables abrupt junctions, quantum structures, and varied emission wavelengths.
Growth is non-equilibrium, offering more flexibility but low growth rates
(0.1–10 μm/h).
Figure 5.20: Schematic diagram of MOCVD systems
LED Fabrication Process: Epitaxial Growth (contd.)
MOCVD in LED Fabrication (contd.)
Challenges: High dislocation density (~10⁸ cm⁻²) in
nitride-based materials.
Solutions: Two-flow MOCVD system (horizontal &
vertical gas flow) reduces dislocations.
Epitaxial Lateral Overgrowth (ELOG):
Uses a patterned rod morphology to (a)
improve film quality.
Lowers dislocation density (<10⁷ cm⁻²)
but requires extra processing.
Patterned Sapphire Substrate (PSS):
Pre-patterned sapphire substrate enhances
lateral growth. (b)
Figure 5.21: (a) Two-flow MOCVD
Improves film quality and light extraction. systems, and (b) gas flow in this system
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LED Fabrication Process:
Process Flow and Device Structure Design
Figure 5.22(a), (b) shows typical device
structures of III–P and III–N LEDs,
respectively.
LED Electrode Design and Efficiency
Carrier Injection & Light Emission:
Electrons and holes recombine in the
active region, generating photons.
III–P LEDs emit light from the top,
while III–N LEDs emit from top and (a) (b)
sides. Figure 5.22: Device structures of (a) III-P and
(b) III-N LEDs
LED Fabrication Process:
Process Flow and Device Structure Design
LED Electrode Design and Efficiency (contd.)
Material Choices for Ohmic Contacts:
III–V (AlInGaP, AlGaAs) LEDs:
n-type contacts: Au–Ge alloy
p-type contacts: Au–Zn or Au–Be alloy
Heavy doping improves conductivity.
Nitride LEDs (GaN-based):
n-type contacts: Ti/Al (TiN formation aids conduction).
p-type contacts: Ni/Au (reduces Schottky barrier).
Achieving heavily doped p-type layers is difficult.
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LED Fabrication Process:
Process Flow and Device Structure Design
Current Spreading Techniques:
Challenges:
Non-uniform hole distribution lowers recombination efficiency.
Recombination mostly occurs under the opaque metal, blocking light.
Solutions:
Increase p-cladding thickness (better current flow, but increases resistance).
Finger electrode patterns for improved current spreading.
Transparent/semi-transparent electrodes (e.g., ITO, Ni/Au, Pt) for better
light extraction.
III–P LEDs need thin GaAs cladding to reduce visible light absorption.
LED Fabrication Process:
Light Extraction Efficiency Improvement in LEDs
Challenges in Light Extraction
Limited by internal reflection at semiconductor boundaries.
Photons in III–P devices may be absorbed by the GaAs substrate.
Metal electrodes can impede light output.
Methods to Enhance Light Extraction:
1. Optimizing Device Shape: Redesigning the LED geometry redirects light for
better extraction.
2. Using Non-Planar Structures: Helps couple out waveguided modes.
3. Package Design Improvements:
Increases critical angle.
Redirects light more efficiently.
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LED Fabrication Process:
Light Extraction Efficiency Improvement in LEDs
Methods to Enhance Light Extraction (contd.):
4. Using a Distributed Bragg Reflector (DBR):
Reflects light back into the LED, preventing substrate absorption.
Acts as a wavelength selector, but adds cost and complexity.
5. Fabricating Transparent Substrates: Prevents photon absorption compared
to traditional GaAs substrates.
Critical Angle & Escape Cone:
Defined by Snell's Law: Light escapes if emitted within a specific angle.
For standard materials with refractive indices: Semiconductor (𝑛 ≈ 3.5) and
epoxy resin packaging material (𝑛 ≈ 1.5), the critical angle (θc) is ≈ 25.38°.
If the substrate absorbs light, the downward escape cone is lost, reducing
efficiency.
LED Fabrication Process:
Light Extraction Efficiency Improvement in LEDs
Enhancing Light Extraction in III–P/GaAs
Cladding Layer & Substrate:
Transparent GaP is used for upper
cladding and substrate.
MOCVD limits cladding thickness to
15 μm, insufficient for full side cone
extraction.
VPE growth can add an upper
cladding layer up to 50 μm. Figure 5.23: (a) Absorbing substrate with a thin cladding
layer which has one full (upward) plus four partial
GaAs substrate can be removed via (sidewall) escape-cones, and
etching and replaced with GaP using (b) Transparent substrate with thick cladding layers
which has six large escape-cones.
high-temperature annealing.
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LED Fabrication Process:
Light Extraction Efficiency Improvement in LEDs
Enhancing Light Extraction in III-Nitride LEDs
Challenges:
Difficulties in doping technology make thick cladding impractical.
Internal absorption losses in the active layer reduce emitted light before it
escapes.
Metal mesh electrodes improve conductivity but block light emission.
LED Fabrication Process:
Light Extraction Efficiency Improvement in LEDs
Enhancing Light Extraction in III-Nitride LEDs
Flip-Chip Structure:
Inverted design emits light through
transparent sapphire substrate.
Improves both conductivity & extraction
efficiency.
Refractive index difference (GaN: 2.45,
Sapphire: 1.78) leads to total internal
reflection.
Patterned Sapphire Substrate (PSS)
redirects light to enhance extraction.
Figure 5.24: (a) Mesh electrode providing a metallic
current spreading layer, (b) flip-chip III-nitride LEDs
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LED Fabrication Process:
Light Extraction Efficiency Improvement in LEDs
Enhancing Light Extraction with Structural Modifications
1. Edge Facets & Die Shape Adjustments:
Side cones extract more light than expected due to imperfect planar
structures.
Trapezoidal die structures reflect sidewall emission upwards, increasing
efficiency.
2. Reducing Total Internal Reflection:
Surface roughening causes light scattering instead of reflection.
Photonic micro- & nanostructures enable diffraction/plasmonic coupling
for better light extraction.
Processing, cost, and layout remain challenges for integrating advanced
structures.
LED Fabrication Process: Packaging
Main Functions of LED Packaging
1. Protection : Shields LED and electrodes from mechanical and environmental
damage.
2. Improving Optical Extraction Efficiency
Reflector cup redirects emitted light upwards.
Epoxy encapsulation designed in hemisphere shape to enhance light extraction.
High refractive index epoxy (1.5–1.8) minimizes internal reflection losses at
semiconductor-epoxy interface.
3. Heat Dissipation for High-Power LEDs
Increased current → Higher temperature → Lower efficiency & red-shifted
emission.
Thermal resistance of packaging must be optimized for high-power applications.
Direct mounting on a heatsink improves heat dissipation.
Silicone encapsulant preferred over epoxy due to better thermal stability.
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LED Fabrication Process: Packaging
Main Functions of LED Packaging (contd.)
1. Protection : Shields LED and
electrodes from mechanical and
environmental damage.
2. Optical Efficiency: Reflector cup
redirects light; epoxy encapsulation
enhances extraction.
Figure 5.25: Illustration of a packaged LED
3. Heat Dissipation: Heatsink &
silicone encapsulant improve thermal
management for high-power LEDs.
Applications of LEDs
Early Applications (1960–1980)
Limited to indicators, alphanumeric displays, and dot matrix displays.
Used mainly in consumer products and industrial equipment.
Emitted only long-wavelength colors (e.g., red) due to material limitations.
Modern Applications:
Improved efficiency & wavelength range allow broader applications:
1. Direct-View Displays: Traffic signals, signage, stadium screens—require
high efficiency & accurate color.
2. LCD Backlighting: Replaces CCFLs, offering Hg-free, high color gamut,
long life, and fast response.
3. General Lighting & Reflective Displays: Requires accurate color
rendering (high CRI) & efficiency balance.
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