27-07-2025

5001CJA106216250005 JA

PHYSICS

SECTION I

1) A particle of mass m is dropped from a height R equal to the radius of the earth above the tunnel
dug through the earth as shown in the figure. Hence the correct statement is :-

(A) Particle will oscillate through the earth to a height h = R on both sides
(B) Motion of the particle is periodic
(C) Motion of the particle is simple harmonic
(D) Both (1) & (2)

2)

The gravitational field due to a mass distribution is E = K/x3 in the x-direction. (K is a constant).
Taking the gravitational potential to be zero at infinity, its value at a distance x is

(A) K/x
(B) K/2x
(C) K/x2
(D) K/2x2

3) A cylindrical piston of mass M and cross-sectional area A slides smoothly inside a long cylinder
closed at one end, enclosing a certain mass of a gas. The cylinder is kept with its axis horizontal. If
the piston is disturbed from its equilibrium position, it oscillates simple harmonically. The period of

oscillation will be. Assume the process to be isothermal.

(A)
(B)

(C)

(D)

4) The motion of a mass on a spring, with spring constant K is as shown in figure.

The equation of motion is given by x(t) = Asinωt + Bcosωt with

Suppose that at time t = 0, the position of mass is x(0) and velocity v(0), then its displacement can
also be represented as x(t) = Ccos(ωt – ϕ), where C and ϕ are :

(A)

(B)

(C)

(D)

5) A ring of mass m can freely slide on a smooth vertical rod. The ring symmetrically attached with
two springs (as shown in the figure). Each of spring constant k, each spring makes an angle θ with
the horizontal. If the ring is slightly displaced vertically, its time period is :-

(A)

(B)

(C)

(D)

6) Find the angular frequency for small oscillation of block of mass m in the arrangement shown in
the figure. Neglect the mass of the rod (system is in vertical plane).

(A)

(B)

(C)

(D)

7) A simple pendulum is hanged inside a lift. It has a time period T1 when lift was moving with
constant velocity, and when the lift moves vertically up according to equation y = 2t2, (where t is

time in second) it has a time period T2, then .

(A)

(B)

(C)

(D)

8) Three masses 700g, 500g, and 400 g are suspended at the end of a spring a shown and are in
equilibrium. When the 700 g mass is removed, the system oscillates with a period of 3 seconds, when
the 500 g mass is also removed, it will oscillate with a period of :-

(A) 1 s
(B) 2 s
(C) 3 s

(D)

9) A uniform bar of mass M and length L is hinged to a shaft which is rotating with constant angular

velocity ω. Find angle made by bar with vertical in equilibrium position.

(A)

(B)

(C)

(D)

10) Below shown is heat insulating piston cylinder arrangement having ideal gas of adiabatic
exponent enclosed. A point charge q having negligible mass is attached to centre of freely movable
piston of mass M. The system is kept in uniform electric field as shown. Atmospheric pressure is P
and when the piston is in equilibrium volume is V0 . On disturbing the piston from equilibrium

position (Assume system to have cross-sectional area as A)

(A)
The system executes S.H.M. with time period
(B) The system does not executes S.H.M.
(C) The system will not execute S.H.M. if magnitude of charge is increased.

(D)
The system executes S.H.M. with time period
11) A particle is performing simple harmonic motion with time period T. At an instant its speed is
60% of its maximum value and is increasing. After an interval Δt its speed becomes 80% of its
maximum value and is decreasing. The smallest value of Δt in terms of T will be :-

(A)

(B)

(C)

(D)

12) A bob B of mass 1 kg is suspended from the ceiling of a toy train as shown in the figure. The
train oscillates simple harmonically in horizontal direction with angular frequency w = 5 rad/s and
amplitude a = 0.1m. What is the ratio of maximum and minimum tension in the string AB during the
motion

(g = 10 ms–2 & tan 37° = 3/4)

(A) 2
(B) 3
(C) 4
(D) 1

13) A body is executing Simple Harmonic Motion. At a displacement x its potential energy is E1 and
at a displacement y its potential energy is E2. The potential energy [E] at displacement [x + y] is –

(A)
(B)
(C)
(D)

14) An equilateral prism of mass m is kept on a smooth table between two identical springs each
having a force constant of k. The two springs have their lengths perpendicular to the inclined faces
of the prism and are constrained to remain straight. The ends of the springs have light pads aligned
parallel to the faces of the prism, and distance between pads and the incline faces is d. The prism is

imparted a velocity v to the right.

(A)
The period of its oscillation is
(B) The motion followed by the prism is a periodic function
(C) The energy of the system is constant
(D) All of the above

15) In the figure shown, a block of mass m is rigidly attached to two identical springs of stiffness k
each with other ends of the springs connected to the fixed walls. When the block is in equilibrium,
length of each spring is b, which is greater than the natural length l of the spring. The time period of
the oscillation of the block if it is displaced by small distance x perpendicular to the length of the
spring and released (motion of the block is unaffected from gravity) is :-

(A)

(B)

(C)

(D)

16) A solid sphere of radius R is floating in a liquid of density with half of its volume submerged. If
the sphere is slightly pushed and released, it starts performing simple harmonic motion. The
frequency of these oscillations is

(A)

(B)

(C)

(D)

17) Three particles, each of mass are situated at the vertices of an equilateral triangle of side a. The
only forces acting on the particles are their mutual. gravitational forces. It is desired that each
particle moves in a circle while maintaining their original separation a. The initial velocity that
should be given to each particle and time period of circular motion are respectively-

(A)

(B)
(C)

(D)

0
18) If the particle shown is the figure is projected with orbital speed v = , it returns after
time T. If it is projected from the same location, such that time period of revolution is 8T then what

is maximum distance of the particle from the centre of the earth ?

(A) 7R
(B) 3R
(C) 14R
(D) 15R

19) Mass of a planet is and radius is . The energy needed to send a 2 kg

body into space from its surface, would be

(A) 9 joule
(B) 18 joule
(C)
(D)

20) If the three point masses are released simultaneously to move under influence of mutual
gravitational attraction, speed of each particle when each one of them has moved a

distance , is:-

(A)

(B)
(C)

(D) None of these

SECTION II

1) Figure shows a binary star system revolving about their COM. The masses of star A & B are 15 ×
1030 kg and 45 × 1030 kg respectively . Find the ratio of area swept by star A to area swept by star B

in a common time interval.

2) A small bead can slide without friction on a wooden rod of length ℓ = 10.0 m. Initially the rod and
the bead both are held motionless with the rod aligned2.40 radially with the earth. The left end of
the rod is at a distance r0 = 4 × 108 m from the earth centre and the bead is at a distance x0 = 2.0
cm away from the left end. Both the bodies are released simultaneously. Considering gravitational
interaction only with the earth, if time after the release, the bead will separate from the rod is P ×
104 sec. Find P. Radius of the earth is R = 6400 km and acceleration due to gravity on the earth is g

= 10 m/s2.

3) A cart consists of a body of mass m and two wheels, each of mass m and radius R. The cart is
attached to a spring of constant k. The other end of the spring is fixed to a wall as shown in figure. If

time period of oscillation is then find the value of β. (Assume pure rolling)

4) A disc of mass m is connected to an ideal spring of force constant 'k'. If disc is released from rest,
then what is maximum friction force on disc (in N)? Assuming friction is sufficient for pure rolling
5) Two rods A and B (mass m and length ℓ each) are connected as shown. Rod A is free to rotate
about O. Mid point of rod B is connected to lower end of rod A and free to rotate relative to A in the

plane of paper. Angular frequency of oscillation of small angular amplitude of rod A is . Find

the value of N.

CHEMISTRY

SECTION I

1) A vessel of uniform cross-section of length 500 cm as shown in fig. is divided in two parts by a
weightless and frictionless piston. One part contains 5 moles of He(g) and other part contains 2
moles of H2(g) and 4 moles of O2 (g), at the same temperature and pressure. A reaction takes place
in other part and finally vessel is cooled to 300K and 1 atm. What is the length of He compartment ?
(Assume volume of piston and vol. of H2O(ℓ) formed are negligible).

(A) 187.5
(B) 300 cm
(C) 312.5 cm
(D) 250 cm

2) The density of the gaseous mixture in a vessel (CH4 and He) at 2 atmosphere pressure and 300 K
is 0.9756 g/lit. If a small pin-hole is made on the wall of the vessel, through which gases effuse, then
which of the followings is the correct composition (by volume) of the gases CH4 and He effusing out
initially ?

(A) 1 : 1
(B) 2 : 1
(C) 3 : 1
(D) 1 : 4

3) Match the correct graph in List-II for a particular amount of ideal gas at constant pressure, with
List-I containing the quantities to be plotted.
 List-I (Y-axis v/s X-axis) List-II

(P) (1)
V2T v/s

(Q) (2)
log V v/s log

(R) V2T v/s V3 (3)

(S) V2T v/s V (4)

(A) (P) → (1); (Q) → (2); (R) → (4); (S) → (3)

(B) (P) → (2); (Q) →(3); (R)→(4); (S) → (1)
(C) (P) → (3); (Q) → (4); (R) → (2); (S) → (1)
(D) (P) → (1); (Q) →(2); (R)→(3); (S) →(4)

4) Consider a 1.0-L of neon gas initially at STP, will the average kinetic energy and frequency of
collisions of gas molecules with the walls of the container increase, decrease, or remain the same
under each of the following condition ?

List-I List-II

The temperature is increased to Average kinetic energy per mol

P. 1.
100°C (at constant V) increase

The temperature is decreased to Same average kinetic energy per

Q. 2.
–50°C, (at constant V) mol

The volume is decreased to 0.5 L,

R. 3. Wall collision frequency increase
(at constant T)

The number of moles of neon is

S. 4. Wall collision frequency decrease
doubled, (at constant T and V)

Average kinetic energy per mole

5.
decrease
(A) P→1,3; Q→4,5; R→2,3; S→2,3
(B) P→2,3; Q→4,5; R→3,4; S→1,3
(C) P→1,4; Q→2,3; R→4,5; S→3,5
(D) P→1,3; Q→1,4; R→1,4; S→2,5

5) Three closed vessels A, B and C are at the same temperature T and contain gases which obey the
Maxwellian distribution of velocities. Vessel A contains only O2, B only N2 and C a mixture of equal
quantities of O2 and N2. If the average speed of the O2 molecules in vessel A is V1, that of the N2
molecules in vessel B is V2, the average speed of the O2 molecules in vessel C is -

(A)

(B) V1
1/2
(C) (V1 V2)
(D)

6) Knowning that average kinetic energy of an ideal gas (X) is directly proportional to absolute

temperature, if T1 = 273 K, which statement is incorrect?

(A) Curve A is for heavier gas at same temperature

(B) Curve B is for the same gas at 373 K
(C) Curve A is for the same gas at 373 K
(D) Curve B is for lightier gas at same temperature.

7) One mole of N2(g) is taken in 1 litre empty container fitted with a movable piston at 300K. If it is
heated to 1200K at constant pressure then match the ratio of final to that of initial value (List-II) of
parameters (List-I) of gas & select the correct code.

List-I List-II
(Parameter) (Ratio)

(P) Z1 (number of collision made by a molecule per unit time) (1) 1/8

(Q) Z11 (collision frequency) (2) 2

(R) λ (mean free path) (3) 1/2

(S) Urms (root mean square speed) (4) 4

(5) 3
(A) P-3, Q-1, R-4, S-2
(B) P-1, Q-5, R-4, S-3
(C) P-3, Q-4, R-1, S-5
(D) P-2, Q-1, R-4, S-3

8) A gas obeys P(V – b) = RT. Which of the following are correct about this gas?

I. Isochoric curves have slope =

II. Isobaric curves have slope and intercept b.

III. For the gas compressibility factor =

IV. The attraction forces are overcome by repulsive forces.

(A) I
(B) II, III
(C) III
(D) I, II, III, IV

9) Match gases under specific conditions listed in Column I with their properties / laws in Column II.
Indicate your answer by darkening the appropriate bubbles of the 4 × 4 matrix given in the ORS.

Column I Column II

Hydrogen gas Compressibility

(A) (P)
(P = 200 atm, T = 273 K) factor ≠ 1

Hydrogen gas Attractive forces

(B) (Q)
(P ~ 0, T = 273 K) are dominant

CO2
(C) (R) PV = nRT
(P = 1 atm, T = 273 K)

Real gas with very

(D) (S) P (V– nb) = nRT
large molar volume
(A) (A) → (P), (R); (B) → (P); (C) → (R), (Q); (D) → (Q)
(B) (A) → (Q), (S); (B) → (Q); (C) → (R), (S); (D) → (P)
(C) (A) → (R), (S); (B) → (S); (C) → (P), (R); (D) → (S)
(D) (A) → (P), (S); (B) → (R); (C) → (P), (Q); (D) → (R)

10) For the balanced redox reaction

aNO3– + b Cu2O + cH+ → dNO + e Cu2+
where a, b, c, d & e are stoichiometric coefficients if c is 14 then the value of 'e' is -

(A) 2
(B) 3
(C) 6
(D) 7

11)
Match equivalent mass of underlined species, assume M is the required molar mass.

List - I (Reaction) List - II (Equivalent masss)

(I) Zn + HNO3 → Zn(NO3)2 + NH4NO3 + H2O (P)

(II) H2O2 → H2O + O2 (Q)

(III) (NH4)2Cr2O7 → N2 + Cr2O3 + H2O (R)

(IV) P4 + NaOH + H2O → PH3 + NaH2PO2 (S)

(A) I-P, II-Q, III-S, IV-R

(B) I-P, II-Q, III-S, IV-T
(C) I-R, II-P, III-S, IV-Q
(D) I-R, II-Q, III-S, IV-T

12) An equimolar mixture of Na2C2O4 and KHC2O4.3H2C2O4 required V1 litre 0.1M KMnO4 in acidic
medium for complete oxidation. The same amount of mixture required V2 litre of 0.2M NaOH for
complete neutralization. What is the ratio of V1 : V2

(A) 4 : 7
(B) 10 : 7
(C) 8 : 7
(D) 2 : 7

13) Calculate the temporary and permanent hardness of water sample having the following
constituents per litre respectively.
Ca(HCO3)2 = 162 mg, MgCl2 = 95 mg
NaCl = 585 mg, Mg(HCO3)2 = 73 mg
CaSO4= 136 mg

(A) 200 ppm, 150 ppm

(B) 100 ppm, 150 ppm
(C) 150 ppm, 200 ppm
(D) 150 ppm, 150 ppm

14)

List-I List-II

d-orbital with zero nodal plane is

(P) (1)
used in hybridisation

Non-axial d-orbital is used in

(Q) (2)
hybridisation

(R) IOF3 (3) Planar species

Bond angle 109°28' or less than

(S) (4)
109°28'
The correct option is :
(A) P→1,2,3,4 ; Q→4 ; R→1,4 ; S→3,4
(B) P→2,3 ; Q→2 ; R→3 ; S→3,4
(C) P→1,4 ; Q→3 ; R→2 ; S→1,2
(D) P→1,2,4 ; Q→3,4 ; R→1,4 ; S→1,3
15) Select the correct bond length order.

(A) dO–O (O2) > dO–O (O3)

(B) dN–O ( ) > dN–O ( )

(C) dC–O (CO2) > dC–O ( )

(D) None of these

16) Which of the following option is incorrect?

(A) H2O > H2O2 (H-bond strength order)

(B) H2O2 > H2O (Boiling point order)
(C) In Chloral H-bonding is not present
(D) NH3 > SbH3 > AsH3 > PH3 → (Boiling point order)

17) s-p mixing will occur in :-

(A)
(B)
(C)
(D)

18) Which of the following is not the CORRECT relationship ?

(A) (i) and (ii) are functional isomers

(B) (ii) and (iv) are metamers
(C) (i) and (iv) are positional isomers
(D) (i) and (iii) are chain isomers

19) Given below are two statements :

Statement (I) : are isomeric compounds.

Statement (II) : are functional group isomers.
In the light of the above statements, choose the correct answer from the options given below :

(A) Both Statement I and Statement II are false

(B) Both Statement I and Statement II are true
(C) Statement I is true but Statement II is false
(D) Statement I is false but Statement II is true

20) Identify compound which can show geometrical isomerism :

(A)

(B)

(C)

(D)

SECTION II

1) Number of compounds having z-configuration:

(i) (ii)

(iii) (iv)

(v) (vi)

(vii)

2) Calculate the number of Benzenoid isomers possible for C6H3ClBrI.

3) How many of the underlined atoms in the molecules shown below have sp hybridisation?
(a) CH2CHCH3 (b) CH2CCHCl (c) CH3CH2+
(d) HCCCH3 (e) CH3CN (f) (CH3)2CNNH2

4) The molarity of O2 gas at 72 atm and 300K is 6M. Calculate the value of Z for O2.
(Use : R = 0.08 atm-litre/K-mole). (Write your answer in terms of 1000 × Z)

5) A mixture of H2SO4 and H2C2O4 (oxalic acid) and some inert impurity weighing 3.185 g was
dissolved in water and the solution made up to 1 litre, 10 mL of this solution required 3 mL of 0.1 N
NaOH for complete neutralization. In another experiment 100 mL of the same solution in hot
condition required 4 mL of 0.02M KMnO4 solution for complete reaction. The wt. % of H2SO4 in the
mixture is :-

MATHEMATICS

SECTION I

1)

The set of values of x for which the inequality is satisfying

(A) (–∞, 2)
(B) (–2, 2)
(C) (2, 6)
(D) (2, ∞)

2) Let α, β be the distinct roots of the equation and .

Then the maximum value of is

(A) –1
(B) 1
(C) –2
(D) 2

3) If α, β, γ are the roots of the equation x3 – x – 1 = 0, then the value of

is equal to

(A) –7
(B) –5
(C) –3
(D) –1
4) The sum of all the positive integers greater than 1 and less than 1000, which leave a remainder of
1, when divided by 2,3,4,5 and 6 is

(A) 8176
(B) 7936
(C) 8167
(D) 7967

5) The set of values of 'k' for which exactly one root of the quadratic equation kx2 + (k + 1)x + (k –1)
= 0 lies in the interval (–2,1], is

(A)
(B)
(C)
(D)

6) If α, β are the roots of ax2 + bx + c = 0, if α < 0 < β and |α| > |β|, then

(A) a > 0, b > 0, c > 0

(B) a > 0, b < 0, c > 0
(C) a < 0, b < 0, c < 0
(D) a < 0, b < 0, c > 0

7)

In a G.P., first term is 1. If 4T2 + 5T3 is minimum then its common ratio is

(A)

(B)

(C)

(D)

8) The minimum value of the quantity , where a, b, c ∈ R+,

is

(A)

(B) 125
(C) 25
(D) 27

9) Let a1, a2, a3..... be a G.P. of increasing positive terms. If a1a5 = 28 and a2 + a4 = 29, the a6 is
equal to

(A) 628
(B) 526
(C) 784
(D) 812

10) A line inclined at an angle of 135° with positive direction of x-axis passes through the
point A(3,4). There are two points P and Q on the line such that AP = AQ = . The co-ordinates
of P and Q are respectively :

(A) (1,6) and (5,–2)

(B) (–1,–6) and (5,2)
(C) (1,6) and (5,2)
(D) (1,–6) and (–5,2)

11) A ray of light is sent along the line x – 2y + 5 = 0. Upon reaching the line 3x + 2y + 7 = 0, the
ray is reflected from it. Then the equation of the line containing the reflected ray is

(A) 19x – 22y + 79 = 0

(B) 22x + 19y + 11 = 0
(C) 11x – 13y + 9 = 0
(D) 19x + 22y + 11 = 0

12) If roots of the equation ax2 + bx + c = 0 are α,β. Then is

equal to -

(A) a2
(B) c2

(C)

(D)

13)

If in triangle ABC, A (1, 10), circumcentre and otheocentre then the

co-ordinates of mid-point of side opposide to A is

(A)

(B) (1, 5)
(C) (1, -3)
(D) (1, 6)
14) If θ is the angle between the lines represented by x2 - 3xy + λy2 + 3x - 5y + 2 = 0, where λ is a
real number, then cosec2 θ equals :

(A) 9
(B) 3
(C) 10
(D) 100

15) Let (2, –1) be the point P and x – y + 1 = 0 be the straight line ℓ. If Q is image of point P about
line ℓ, then image of point Q about y-axis is

(A) (–2, 3)
(B) (2, 3)
(C) (3, 4)
(D) (–3, 4)

16) Let PS be the median of triangle with vertices P(2, 2), Q(6, –1) and R(7, 3). The equation of line
passing through (1, –1) and perpendicular to PS, is -

(A) 2x – 9y – 7 = 0
(B) 9x – 2y – 11 = 0
(C) 2x + 9y – 11 = 0
(D) 2x + 9y + 7 = 0

17) Let f(x) = x2 + px + q and g(x) = x2 + rx + s where real roots of f(x) = 0 are α, β and real roots of

g(x) = 0 are α + δ, β + δ such that minimum value of f(x) be and least value of g(x) occurs at

, then correct option is –

(A)
Least value of g(x) is
Least value of g(x) is
(B)

(C) Roots of the equation g(x) = 0 are 3, 4

Roots of the equation g(x) = 0 are
(D)

18) The number of integral values of m, for which the x-coordinate of the point of intersection of the
lines 3x + 4y = 9 and y = mx + 1 is also integer is

(A) 2
(B) 0
(C) 4
(D) 1
19) 150 Scientists from all over the world are engaged to find vaccine for COVID and it is known
that if they all work together the vaccine will get prepared in a certain number of days. However,
after the first day of work 4 scientists fell ill and left the task permanently. After the second day,
another 4 fell ill and left permanently. This pattern continues until the vaccine is finally made, 8 days
over schedule.
Then the number of days in which the vaccine is made, is:

(A) 75
(B) 25
(C) 32
(D) 17

20) The value of is equal to

(A)

(B)

(C)

(D)

SECTION II

1) If α, β are roots of equation 3x2 – 2x + 1 = 0, then value of

2) The equation of the perpendicular bisectors of the sides AB and AC of a triangle ABC are
respectively x – y + 5 = 0 and x + 2y = 0. If the coordinate of A are (1, –2) then equation of BC is ax

+ by = 40. The value of is

3) If (1 + x)(1 + x2)(1 + x4)(1 + x8)........ (1 + x128) then n is equal to

4) The first term of an arithmetic progression is 1 and the sum of the first nine terms equal to 369.
The first and the ninth term of a geometric progression coincide with the first and the ninth term of
the arithmetic progression. Find the seventh term of the geometric progression.

5)

The line 3x + 2y = 24 meets the y-axis at A and the x-axis at B. The perpendicular bisector of AB
meets the line through (0, -1) parallel to x-axis at C. If the area of the triangle ABC is A then the
value of A/13 is
 ANSWER KEYS

PHYSICS

SECTION I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D D A D D A B B B A A A B D B A C C D B

SECTION II

Q. 21 22 23 24 25
A. 9.00 2.40 2.00 2.00 9.00

CHEMISTRY

SECTION I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C A B A B C A D D C C A C A B D B C B C

SECTION II

Q. 46 47 48 49 50
A. 3.00 10.00 3.00 489 40.00

MATHEMATICS

SECTION I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C C D A C D B B C C A C A C B B C A B B

SECTION II

Q. 71 72 73 74 75
A. 2.00 3.70 255.00 27.00 7.00
 SOLUTIONS

PHYSICS

1) When the particle is outside the tunnel force acting on it is ∝ where, r is the distance
from the centre of the earth.

When the particle is inside the tunnel force acting on it is ∝ where, r is the distance from the
centre of the earth.
In both cases, force is always directed towards the centre of the earth.
Thus motion is oscillatory and also periodic but not SHM.

2)

Gravitation potential

Given,

3) Let piston be displaced 'x' towards left than volume decreases and pressure increases
PV = constant {As isothermal}
Let P, & V are initial pressure & volume
PV = (P + ΔP) (V – ΔV) {ΔP is increase in pressure}
PV = PV + ΔPV – PΔV – ΔPΔV [neglect ΔP·ΔN]
⇒ ΔPV = PΔV

ΔP (Ah) = PAx ⇒ ΔP = P

[a = –ω2x]
By comparing

Method-2
Dimension analysis can be done

4) x = A sinωt + Bcosωt

v= = Aω cosωt – Bω sinωt
At t = 0, x (0) = B
v (0) = Aω
x = A sin ωt + B sin (ωt + 90°)
Anet =

x = C cos (ωt – ϕ)

ϕ = 90 – α

5)

FBD of ring O'

∴ ma = 2Fsinθ ....(1)
But, F = kΔx = kΔysinθ ....(2)

(2) in (1) ⇒

6) k3 can be replaced by k'3 at centre of rod, such that

also k2, k3' are in series and their net in parallel with k1

7)

y = 2t2

8) When mass 700 g is removed, the left out mass (500 + 400)g oscillates with a period of 3 s

∴ 3 = 2π …(i)
When 500 g mass is also removed, the left out mass is 400g.

∴ t´ = 2π …(ii)

⇒
⇒ t´= 2s

9) Taking torque about hinge

⇒

10)

11) Velocity is 60% of maximum

⇒ v = 0.6 Aω = 3/5 Aω
∴

A2ω2 = ω2A2 – ω2x2

ωx2 = ω2A2 × ⇒
For second condition velocity becomes 80% of vmax

∴ Particle moves from to in time Δt (t2 – t1)

cos θ1 = and cos θ2 =

So phase content is = 37° + 53° =

So time interval = T/4

12) Concept : Concept of FBD and maximum acceleration during SHM.

Solution : amax = ω2A = 2.5 m/s2, m = 1 kg
Case I : Acceleration is in left

∴ (1) T1cos37° = mg
(2) T2 – T1sin37° = mamax

T2 – mg × = m × 2.5
T2 = 2.5 + 7.5 = 10N
Case II : Acceleration is in right

∴ (1) T1'cos37° = mg
(2) T1' sin37° – T2' = mamax

mg × – T2' = m × 2.5
T2' = 5N

∴
13)

14)

Correct answer
(D) All of the above

15)
For small displacement x of the block in the given direction,
2T cosθ = ma

⇒ ⇒a=

∴ T=

16)

After dipping 'x' more

For half submerged

17)

18)

By kepler's third law

T2 ∝ a3

T1 = T a1 = 2R ; T2 = 2T a2 = ?

a2 = (64 × 8R)1/3 = 8R
If rmin & rmax are minimum & maximum distance from centre of earth then
rmin + rmax = 2a2
2R + rmax = 16R
rmax = 14R

19)

20)

By Conservation of total mechanical energy

21)

Rate of area swept

(r = distance from COM)

22)

Bead will move towards left relatively.

arel =

r0 is very large and hence r0 can taken constant.

23) From energy conservation

⇒ kx2 + 4m v2 = 0

⇒a=–
 ⇒w=

24)
From work energy theorem maximum extension of spring is xm

mgxm sinθ = or
At lower extreme
kxm – mgsinθ – F = ma ...(i)
a = Rα ...(ii)

FxR = ...(iii)

Thus F =

25) τ = (mg + mgℓ) sin θ =

I=

∴α=

(for small oscillation sin θ ≈ θ )

CHEMISTRY

26) Moles of O2 remaining after reaction = 4 – 1 = 3

V ∝ n is due to same T and P and each compartment after reaction
∴ Length of He compartment

27)

d = 0.9756g/L
∴ x × 16 + (1 – x) × 4 = 12
or, 16x + 4 – 4x = 12

or, 12x = 8 ⇒
∴ CH4 = 2/3 mole

He =

28)

29)

Avg. KE ∝ n
∝T

Collision frequency ∝ average velocity

30)

Correct answer
(B) V1

31)
Speed of molecule

Speed of molecule

32) , , λ ∝ T, Urms ∝

33) (I) P(V – b) = RT

(II) PV – Pb = RT

slope = and intercept b

(III) ;Z>1
i.e., repulsive forces predominate.

34)

Matching
(A) → (P), (S)
[Because 200 atm pressure is very large for H2 gas, at very high pressure Z > 1]
(B) → (R)
[Since p ~ 0 it means very low pressure so ideal behaviour is observed]
(C) → (P) & (Q)
[Since P is 1 atm, Z for CO2 would be less than 1]
(D) → (R)
In real gas with very high molar volume, molecules will be very far apart from each other due
to which Vander Waals forces as well as actual vol. occupied by molecule will be negligible.

35)
3e– + N+5 → N2+ .....(1)

.........(2)
(1) × (2) + (2) × (3)
2N+5 + 3Cu2+1 → 2N2+ + 6Cu2+
14H+ + 2NO3– + 3Cu2O → 2NO + 6Cu2+ + 7H2O

36)

(I) nf of HNO3 = , eq. wt. =

(II) nf of H2O = 1, eq. wt. = M

(III) nf of (NH4)2 Cr2O7 = 6, eq. wt. =

(IV) nf of P4 = 3, eq. wt. =

37) Let moles of each compound –x

2x + 8x = 0.5V1 ...(1)
7x = 0.2V2 ...(2)
from (1) and (2);

38)

Mole of Ca(HCO3)2 = mole

Mole of Mg(HCO3)2 = = 5 ×10–4 = 0.5 × 10–3 mole

Mole of CaCO3 = 1.5 × 10–3 mole
–3
Mass of CaCO3 = 1.5 × 10 × 100
= 0.150 gm

Temperature hardness (ppm) = ppm

Mole of MgCl2 = mole

Mole of CaSO4 = mole

–3
Mole of CaCO3 = 2 × 10 mole
Mass of CaCO3 = 2 × 10–3 × 100 = 0.20 g

Permanent hardness (ppm) = ppm

39)

P → 1, 2, 3, 4
Q→4
R → 1, 4
S → 3, 4
40) (a)

(b)

(c)

41)

(1) In H2O more electron density is induced on oxygen atom hence, it has more H-Bond
strength as compared to H2O2.
(2) H2O2 has more extend of Hydrogen bonding than H2O and hence H2O2 has more boiling
point than H2O.
 (3) no H-Bonding is present.
(4) The correct order for boiling point of group 15th Hydride is
SbH3 > NH3 > ASH3 > PH3

42)

sp mixing is observed in species which have protons ≤ 15.

(B)

43) (i) and (iv) are functional isomers . (1° and 2° amine)

44) Statement - I → True

Both are ring chain isomers

Statement - II → True

1° Amine and 2° Amine are different functional groups, hence both are functional group
isomers.

45)

46)

(i) (ii) (iii)

 Z Z E

(iv) (v)

E E

(vi) (vii)

E Z

47)

48)

49)
 Molarity = 6 mol/l
P = 72 atm
T = 300 K

Z= = 0.4891

50) (H2SO4 + H2C2O4 + inert) → 3.185 g.

↓ ↓
a m mole b m mole (say)
eq. of acids = eq.e

or, 2a + 2b = 30
or, a + b = 15 ...(1)
KMnO4 is an oxidising agent so H2C2O4 will act as a reducing agent.

0.02M, 4ml
equivalent of KMNO4 = eq. of H2C2O4

or, 0.02 × 4 × 5 =
or, ∴ from (1), a = 15 – 2 = 13 m mole.
∴ H2SO4 = a m mole = 13m mole = 13 × 10–3 × 98g = 1.274g

∴ wt% of H2SO4 in the mixture = = 40% Ans.

MATHEMATICS

51)

or

or

> –2
Case(i) when x < –2

⇒
⇒ –1 < –2 which is not true
Case(ii) when –2 ≤ x < 0

⇒
⇒ 1 < –2, which is not true
Case(iii) when x ≥ 0
⇒

or

or <0
⇒ 2 < x < 6,
Hence, solution is (2, 6).

52) Let

similarly
,

≤ –2

53)

x3 – x – 1 = 0

y – αy = 1 + a

y – 1 = αy + a

(y – 1)3 – (y – 1)(y + 1)2 – (y + 1)3 = 0

y3 – 1 + 3y – 3y2 – (y – 1)(y2 + 1 + 2y) – y3 – 1 – 3y – 3y2 = 0

–2 – 6y2 – [y3 + y + 2y2 – y2 – 1 – 2y] = 0

–2 – 6y2 – y3 + y – y2 + 1 = 0

–y3 – 7y2 + y – 1 = 0

y3 + 7y2 – y + 1 = 0

Option D is correct

54) 61 + 121 + 181 + ..... + 961

No. of terms = 16
= 8 × 1022 = 8176

55) ƒ(–2)ƒ(1) < 0

⇒ (4k – 2k – 2 + k – 1)(k + k + 1 + k – 1) < 0
⇒ (3k – 3)(k) < 0 k ∈ (0, 1)
Checking boundary condition at k = 1
x2 + 2x = 0 ⇒ x = –2 or 0
Hence k ∈ (0, 1]

56) α + β ⇒ ⇒

αβ < 0 ⇒

57)

4T2 + 5T3 = 4r + 5r2

2
5r + 4r is minimum at

58) Let A =

,
+
where a, b, c ∈ R

Applying AM ≥ GM on a and ,

a+ ≥2 ⇒a+ +3≥5

Similarly, b + ≥2 ⇒b+ +3≥5

and c + ≥2 ⇒c+ +3≥5

∴
So, A ≥ 5 ⋅ 5 ⋅ 5 ⇒ A ≥ 125
Minimum value of A is 125.

59) a1 .a5 = 28 ⇒ a.ar4 = 28 ⇒ a2r4 = 28 …(1)

a2 + a4 = 29 ⇒ ar + ar3 = 29
⇒ ar(1 + r2) = 29
⇒ a2r2(1 + r2)2 = (29)2 …(2)
By Eq. (1) & (2)
60)
where θ = 135°
x=3±2;y=4±2
x =1 , 5 ; y = 6, 2

61)
First we will find the intersection points of these two lines,
x – 2y + 5 = 0 ..(1)
3x + 2y + 7 = 0 ..(2)
from eqn. (1) & eqn. (2), x = –3 & y = 1
hence coordinate of P is (–3, 1)
To find the eqn. of the reflected ray, we have to find the slope of the reflected ray

slope m1 = , slope m3 =
Line T is perpendicular to 3x + 2y + 7 = 0
hence, m × m3 = –1

m= =
As angle between the incident ray & line T is same as angle between reflected ray & line T

tan θ =

⇒ ⇒

⇒ ⇒±
by taking +ve sign by taking –ve sign→
3+2m2 =16–24m2 –3–2m2 =16–24m2
26m2 = 13 22m2 = 19

This is not possible as incident & reflected rays cannot be parallel

So, the eqn of the reflected ray having point p(–3,1) & slope m2 =

(y–1) = , y–1 = 19 (x + 3)
22y – 22 = 19x + 57, 22y = 19x + 79

62) ax2 + bx + c = 0
x(ax + b) = –c

ax + b =

63)

Circumcentre O and orthocentre H

coordinate of G are (1, )

A(1, 10), G

AG : GD = 2 : 1

D=

coordinate of the mid point is BC are

64) Since given equation represents a pair of lines, therefore applying
abc + 2fgh - af2 - bg2 - ch2 = 0,

Here a = 1, b = λ, c = 2, h = g= f
we get

Now
cosec2θ = 1 + cot2θ = 1 + 9 = 10

65)

66)

Slope of PS :

Slope of line perpendicular to PS is

equation passing through (1, –1) is

y+1=
2y + 2 = 9x – 9
9x – 2y – 11 = 0

67) As the difference of roots of

f(x) = 0 and g(x) = 0 are equal

then
⇒ p2 – 4q = r2 – 4s
Now minimum value of

f(x) =

⇒ r2 – 4s = 1 ...(1)
Least value of g(x) occurs at
x=
⇒ s = 12 ⇒ g(x) = x2 – 7x + 12 = 0
⇒ x = 3, 4

68) x-coordinate of the point of intersection is

3x + 4(mx + 1) = 9

For x to be an integer 3 + 4m should be a divisor of 5,

i.e., 1, – 1, 5 or – 5.
Hence,
3 + 4m = 1 m = –1/2 (not integer)
3 + 4m = –1 m = –1 (integer)
3 + 4m = 5 m = 1/2 (not an integer)
3 + 4m = - 5 m = – 2 (integer)
Hence, there are two integral values of m.

69) Let x be the number of days in which 150 scientists make the vaccine.
According to the given information.
150x = 150 + 146 + 142 + ...+(x + 8)terms
The series 150 + 146 +142 + ... + (x + 8) terms is an A.P. with first term 150. common
difference – 4 and number of terms as (x+8)

⇒ 150x = [2(150) + (x + 8 – 1)(–4)]

⇒ 150x = (x + 8) [(150) + (x +7)(–2)]
⇒ 150x = (x + 8) (150 – 2x – 14)
⇒ 150x = (x + 8) (136 – 2x)
⇒ 75x = (x + 8)(68 – x)
⇒ 75x = 68x – x2 + 544 – 8x
⇒ x2 + 75x – 60x – 544 = 0
⇒ x2 + 15x – 544 = 0
⇒ x2 + 32x – 17x – 544 = 0
⇒ x (x + 32) –17(x + 32) = 0
⇒ (x – 17)(x + 32) = 0
⇒ x = 17 or x = – 32
Since, x cannot be negative. So. x = 17
So. the number of days in which the vaccine was to be completed by 150
Scientists is 17.
So. required number of days = (17 + 8) = 25

70)
 =

∵ Sn =

∴ S∞ =

Option (B)

71)
⇒

=2

72) B is the image of A in x – y + 5 = 0 C is the image of A in x

+ 2y = 0

B ≡ (–7, 6)

Similarly
equation of BC is 14x + 23y = 40

73)

(1+x) (1+x2) (1+x4) ........ (1+x128)

= 1 + x + x2 + ........ xn

=
⇒ (1–x) (1+x) (1+x2) (1+x4) ... (1+x128)
= (1–xn+1)
⇒ (1–x) (1+x2) (1+x4) .... (1+x128) = 1–xn+1
⇒ 1–x256 = 1–xn+1
⇒

Ans. (255)
 74)

Let T1 = a = 1
S9 = 369

S9 = 369 = [T1 + T9]

⇒ 369 = [1 + T9]

For G.P.
T1 = 1, T9 = 81
a.r9–1 = 81
1.(r)8 = 81

(r)8 = (3)4

T7 = a.r6 = 1 × = 27
Ans. (27)

75)

Line 3x + 2y = 24 meets the axis at B(8, 0) and A(0, 12). midpoint of AB is D(4, 6)