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The document contains a series of physics, chemistry, and mathematics questions, primarily focusing on concepts such as dimensions, units of measurement, gas laws, vector components, periodic table elements, and quantum numbers. Each section presents multiple-choice questions that require knowledge of fundamental principles in these subjects. The questions are designed to test the understanding and application of scientific concepts and mathematical reasoning.

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0% found this document useful (0 votes)
22 views20 pages

Solution

The document contains a series of physics, chemistry, and mathematics questions, primarily focusing on concepts such as dimensions, units of measurement, gas laws, vector components, periodic table elements, and quantum numbers. Each section presents multiple-choice questions that require knowledge of fundamental principles in these subjects. The questions are designed to test the understanding and application of scientific concepts and mathematical reasoning.

Uploaded by

soham.022009
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

27-04-2025

1803CJA101016250005 JM

PART-1 : PHYSICS

SECTION-I

1) The velocity of a body moving in viscous medium is given by V = where t is time, A &
B are constants. Then the dimensions of A are

0 0 0
(A) M L T
0 0
(B) M L1T
0
(C) M L1T–1
(D) M1L1T–1

2)

In a system of units, unit of mass is 10 kg, unit of length is 5m and unit of time is 1sec what will be
unit of force ?

(A) 25 N
(B) 50 N
(C) 0.5 N
(D) 2500 N

3) Find the dimensions of the constant a & b respectively in vander wall's gas equation [V –
b] = RT (where, P = Pressure, V = Volume, T = Temperature, R = Gas constant)

0 0
(A) M1L5T–2, M L3T
0 0
(B) M L T–1, M1L3T1
0 0
(C) M2L5T–2, M L3T
0 0 0
(D) M L5T–2, M L–3T

4) In a new unit system, 1 unit of time is equal to 20 second, 1 unit of mass is 15 kg and 1 unit of
length is 20 m. In this new system of units, 1 unit of energy is equal to :-

(A) 15 Joule

(B)
Joule
(C) 4 Joule
(D) 16 Joule

5) An ideal gas enclosed in a vertical cylindrical container supports a freely moving piston of mass
M. The piston and the cylinder have equal cross sectional area A. When the piston is in equilibrium,
the volume of the gas is V0 and its pressure is P0. The piston is slightly displaced from the
equilibrium position and released. Assuming that the system is completely isolated from its
surrounding, the piston executes a simple harmonic motion with frequency.

(A)

(B)

(C)

(D)

6) If instead of mass, length and time as fundamental quantities, we choose velocity, acceleration
and force as fundamental quantities and express their dimensions by V, A and F respectively, then
the dimensions of pressure will be expressed as :-

(A) [FA2V–1]
(B) [F2V–1A]
(C) [FA2V–4]
(D) [FAV–2]

7) A gas bubble from an explosion under water oscillates with a time period proportional to PadbEc
where P is the static pressure, d is the density of water and E is the energy of explosion. Then a, b
and c are :

(A)

(B)

(C)

(D) 1, 1, 1

8)

Match the List-I to List-II

List-I List-II
–1 –2
(P) Angle (1) ML T
0
(Q) Pressure (2) M LT–2
0 0 0
(R) Force (3) M L T
(S) Acceleration (4) MLT–2
(A) (P) - (3) ; (Q) - (1) ; (R) - (4) ; (S) - (2)
(B) (P) - (2) ; (Q) - (4) ; (R) - (3) ; (S) - (1)
(C) (P) - (4) ; (Q) - (2) ; (R) - (1) ; (S) - (3)
(D) (P) - (3) ; (Q) - (1) ; (R) - (2) ; (S) - (4)

9)

A vector a of magnitude 8 units has two components. One is perpendicular to a and is of magnitude
6units. What is the magnitude of the other component?

[Hint : They are ‘components’ not ‘rectangular component’]


(A) 5 units
(B) 10 units
(C) 15 units
(D) 20 units

10) Given and , which of following statement is correct?

(A)

(B)

(C)

(D)

11) The unit vector parallel to the resultant of the vectors and is

(A)

(B)

(C)

(D)

12) Vector in the xy-plane has a magnitude of 40 units, a y-component of +20 units and an
unknown x-component in the positive x-direction. If it is added to vector . The resultant vector
is 40 units along negative x-direction. The x-component of vector is :

(A) –54.6 units


(B) –74.6 units
(C) +54.6 units
(D) +108.5 units

13) It is given that with and and Then is

(A)
(B) 10
(C) 20
(D)

14) Consider three vectors , and . A vector of the form


( are numbers) is perpendicular to . The ratio of is

(A) 1 : 1
(B) 2 : 1
(C) –1 : 1
(D) 3 : 1

15) Three forces are acting on an object shown in diagram. Their resultant is zero. The is.


(A)

(B) –
(C)
(D)

16) Three forces , and are represented as shown. Each of them is of equal magnitude.

List–II
List–I
(Approximate
(Combination)
Direction)

(P) (A)
(Q) (B)

(R) (C)

(S) (D)

(A) P-1, Q-2, R-3, S-4


(B) P-2, Q-1, R-4, S-3
(C) P-2, Q-3, R-1, S-4
(D) P-4, Q-1, R-2, S-3

17) The velocity of a particle is . The component of the velocity of the particle parallel to
vector is.

(A)
(B)
(C)
(D)

18) If y = sin(x) + ln(x2) + e2x then will be :

(A)
cos x + + e2x

(B)
cos x + + 2e2x

(C)
–cos x + + e2x

(D)
–cos x – + 2e2x

19) If y = x2 – x ; find y when is equal to 1.

(A) 2
(B) –1
(C) 1
(D) 0

20) is equal to :-
(A)

(B) logex + x + c
(C) x2 + 1 + c

(D)

SECTION-II

1) =

2) A river, while flowing, sweeps along with it few boulders (stones). Assume that the maximum
mass m, of a boulder swept along by a river, depends on the speed v of the river, the acceleration
due to gravity g and the density ρ of the boulder. If m = kvagbρc where k is some dimensionless
constant, the value of (a + b + c) is ______.

3) In a new system of units, unit of mass is 2 kg, unit of length is 4 m and unit of time is 2 second.
How much joule is equal to 1 unit of energy in this new system?

4) If the unit of velocity is 4 m/s, the unit of acceleration is 24 m/s2 and the unit of force is 6N, find
the unit of energy in J.

5) Find the value of

PART-2 : CHEMISTRY

SECTION-I

1) In Moseley’s experiment, a plot of against atomic number (z) of element gave a : (v =


frequency of X-rays emitted)

(A) Straight line


(B) Parabola
(C) semicircle
(D) Non-linear curve

2) What is the correct IUPAC name of element having atomic number 113?

(A) Ununtriium
(B) Unniltrium
(C) Ununbium
(D) Ununtrium

3) Select the correct comparison of size

(A) N–3 > O–2 > F– > Na+


(B) N–3 > F– > Na+ > O–2
(C) Na+ > F– > O–2 > N–3
(D) F– > O–2 > N–3 > Na+

4) Which of the following isoelectronic ion has the lowest ionisation energy ?

(A) K+
(B) S–2
(C) Ca+2
(D) Cl–

5) Which of the following species has maximum electron affinity among given ?

(A) S+
(B) He+
(C) Cl+
(D) O+

6) Identify from the given options, the element that was present in original Mendeleev's periodic
table.

(A) Ga (Z = 31)
(B) Sc (Z = 21)
(C) Tc (Z = 43)
(D) Mn (Z = 25)

7) The increasing order of atomic radii of the following group 13 elements is

(A) Al < Ga < In < Tl


(B) Ga < Al < In < Tl
(C) Al < In < Ga < Tl
(D) Al < Ga < Tl < In

8) Correct order of ionisation energy.

(A) Li > Be (IE1)


(B) Li > Na (IE1)
(C) Al > Mg (IE1)
(D) N < O (IE1)
9) Increasing order of second ionization energy is :-

(A) Ne > F > O > B > N > C > Be


(B) Be < C < B < N < F < O < Ne
(C) Be < B < C > N < F < O < Ne
(D) B < C < N O < F < Be < Ne

10)

List-II
List-I
(Electron Affinity in eV / atom and
(Atom / Ions)
where EA = –ΔHe.g.)

(P) F (1) 3.4

(Q) F+ (2) 17.4

(R) Cl (3) 13

(S) Cl+ (4) 3.6


(A) P → 1;Q → 3;R → 4;S → 2
(B) P → 2;Q → 1;R → 3;S → 4
(C) P → 1;Q → 2;R → 4;S → 3
(D) P → 3;Q → 1;R → 2;S → 4

11) In halogens, which of the following increases from fluorine to iodine?

(A) Bond length


(B) Electronegativity
(C) The ionization energy of the element
(D) Number of valence shell electrons

12) Which of the following can be associated with the concept of Lanthanoid contraction?

(A) Size of Zr ≈ Hf
(B) Shielding of one 4f electron by another is less than that of one d-electron by another
(C) Similar chemical and physical properties of Nb and Ta
(D) All of the above

13) Which of the following order is incorrect?

(A) Cl– < K+ < Ca+2 (I.E.)


(B) Pd < Ag (I.E.)
(C) Li+ > Na+ (E.A.)
(D) Mg+2(aq) < Ca+2(aq) (ionic mobility)

14) Which of the following statement is NOT CORRECT for an electron that has the quantum
number n = 4 and m = 2.
(A)
The electron may have quantum number S =
(B) The electron may have quantum number ℓ = 2
(C) The electron may have quantum number ℓ = 3
(D) The electron may have quantum number ℓ = 0, 1, 2, 3

15)

List-I
List-II
(Violation of)
Only
(P) Aufbau's (1)
principle
Only Pauli's
(Q) exclusion (2)
principle

Only Hund's
(R) (3)
rule

Aufbau's &
(S) (4)
Hund's rule

(A) P → 1;Q → 2;R → 3;S → 4


(B) P → 3;Q → 4;R → 2;S → 1
(C) P → 2;Q → 4;R → 1;S → 3
(D) P → 2;Q → 1;R → 4;S → 3

16) Consider two cations 'X' and 'Y' which have 8 and 18 electrons respectively in their
outermost shell (both belong to 3d-series). Select the INCORRECT statement:

(A) Cation 'X' and 'Y' both have 8 electrons in their penultimate shell
(B) Difference between total number of electrons of 'X' and 'Y' is 10
(C) Cation 'Y' may be of element 'Ni'
(D) Cation 'X' may be of element Sc

17) In Palladium (Atomic no.-46), number of electron occupying orbitals with no any nodal plane will
be -

(A) 20
(B) 18
(C) 12
(D) 22

18) Value of n + ℓ for last electron entered in Argon


(A) 4
(B) 5
(C) 6
(D) 7

19) If spin quantum number have the values and but all other quantum number have
values as they have, then the maximum number of electrons in 5th orbit should be

(A) 25
(B) 50
(C) 75
(D) 33

20) Which of the following set of Quantum numbers is not possible?

(A) n = 4, = 3, m = + 2, s = +1/2
(B) n = 4, = 2, m = + 2, s = –1/2
(C) n = 4, = 2, m = – 2, s = +1/2
(D) n = 4, = 1, m = – 2, s = –1/2

SECTION-II

1) Total number of elements which can accomodate in the 10th period of periodic table if present.

2) The first four I.E. values of an element are 284, 412, 656 and 3210 kJ mol–1. The number of
valence shell electrons in the element.

3) How many of the following elements are more electronegative than carbon ?
B N O F P Si Cl

4) Total number of orbitals that are to be filled completely before entering into the 6s subshell for
filling of electrons

5) How many unpaired electrons are present in Co3+ ion ?

PART-3 : MATHEMATICS

SECTION-I

1)
(A) 3
(B) 6
(C) 5
(D) 4

2) Number of positive integral solutions of the equation

(A) 4
(B) 6
(C) 8
(D) 10

3) The value of + + , (where x > 0) is

(A) 0
(B) 1
(C) 2
(D) 3

4) If x + y = 8 and x2 + y2 = 10, then value of x3 + y3 is

(A) 117
(B) –136
(C) 124
(D) –138

5) If where a and b are natural number then a + b = .....

(A) 4
(B) 6
(C) 8
(D) 10

6) The polynomials P(x) = kx3 + 3x2 – 3 and Q(x) = 2x3 – 5x + k, when divided by (x – 4) leave the
same remainder. Then the value of k is

(A) 2
(B) 1
(C) 0
(D) –1
7) Which of the following number is irrational

(A)

(B)

(C)

(D)

8) The value of is

(A) –1
(B) i
(C) 1
(D) –i

9) Which of the following is correct ?

(A)
(B)
(C)
(D)

10) Difference of two different irrational numbers

(A) cannot be an integer


(B) cannot be a rational number
(C) can be a rational number
(D) cannot be a prime.

11) If p(x) = x(x – 1)(x – 2)(x – 3), then find the remainder when p(x) is divided by (x + 1).

(A) 12
(B) –12
(C) 24
(D) –24

12) If a + b = –3 and ab = –2, then find a3 + b3.

(A) 5
(B) –5
(C) 45
(D) –45
13) If then x equal to

(A) –2
(B) 4
(C) –6
(D) –4

14) If 3(x–y) = 27 & 3(x+y) = 243, then x equals :-

(A) 0
(B) 2
(C) 4
(D) 6

15) If ax = b, by = c, cz = a, then value of xyz is

(A) 0
(B) 1
(C) 2
(D) 3

16) The value of 8 terms is

(A) 2
(B) –2
(C)
(D)

17) If and then

(A) a = b
(B) a + b = 0
(C) a > b
(D) a < b

18) If (where x > 0) then

(A) x3 + x–3 = –18


(B) x3 + x–3 = 9
(C) x5 + x–5 = 123
(D) x5 + x–5 = –123
19) The value of is

(A) 1
(B) 3
(C) 10
(D) 25

20) If a five digit number 2785x is divisible by 11, then the value of x is

(A) 1
(B) 2
(C) 5
(D) 7

SECTION-II

1)

The value of (4 + 1)(42 + 1)(44 + 1)(48 + 1) + where λ ∈ then find the value of 'λ' is equal
to :

2) If P(x) is a cubic polynomial such that P(1) = 1; P(2) = 2; P(3) = 3 with leading coefficient 3 then
find the value of P(4).

3) If , then is equal to

4) If can be expressed as , (a, b, c, d ∈ ) then find the value of a3 + b3 + c3 + d3 is


equal to

5) The value of is :
ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B B A A C C A A B B A B A A A C A B D B

SECTION-II

Q. 21 22 23 24 25
A. 21 4 8 4 1

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A D A B B D B B B C A D B D C C C A C D

SECTION-II

Q. 46 47 48 49 50
A. 72 3 4 27 4

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C B B B C B C C C C C D D C B A D C A B

SECTION-II

Q. 71 72 73 74 75
A. 32 22 198 32 60
SOLUTIONS

PART-1 : PHYSICS

1) e–t/B is dimensionless
[B] = T
[A/B] = LT–1
[A] = L

2) In new system,

Force unit = 50 kgm/s2 = 50 N

3) ∵ = [P]
∴ [a] = [P] [V2] = ML–1T–2 × L6 = M1L5T–2

4)

new S.I.
n1u1 = n2u2
n1(M1L12T1–2) = n2(M2L22T2–2)

n1 =

= = 15

5) Check dimensionally for frequency i.e. [T–1]

6) ...(i)
V = LT–1 and A = LT–2

....(ii)
Form (i) & (ii)
⇒ [P] = [FA2V–4]
9)

10)

14)

18) y = sin x + ℓnx2 + e2x

= cos x + + 2e2x

= cos x + + 2e2x

21) I =

I=
= [16 – (–5)] = 21

22) [m] = [vagbρc]


0 0
M1L T = (LT–1)a(LT–2)b(ML–3)c
⇒ a + b – 3c = 0 .....(1) comparing L
a + 2b = 0 ......(2) comparing J
C = 1 .......(3) Comparing M
From (1), (2) and (3)
a = 6, b = –3, c = 1
a+b+c=4

25)
sin(15°) = sin (45° – 30°)
= sin45° cos30° – cos45° sin30°

=
= 2(4 + 2 ) × (4 – 2 )/8
PART-2 : CHEMISTRY

33) Theory based.

46) 2M2 ⇒ M =
2 × (6)2 = 72

47) I.E.1 = 284 KJ/mol


I.E.2 = 412 KJ/mol
I.E.3 = 656 KJ/mol
I.E.4 = 3210 KJ/mol
sudden jump after I.E.3 therefore number of valence will be 3.

48) N, O, F and Cl, are more electronegative than carbon.

PART-3 : MATHEMATICS

51)

= 51

52) ⇒

x 36 20 12 8 6 5

y 9 10 12 16 24 40
Since x and y ar positive integers
⇒ y ≥ y – 8 must divisible by 32
y – 8 = 1, 2, 4, 8, 16, 32

53)

54)

x+y=8 ...(1)
2 2
x + y = 10 ...(2)
2
(1) – (2) ⇒ xy = 27
x3 + y3 = (x + y)(x2 + y2 – xy)
= 8(10 – 27)
= –136

56) P(4) = 64k + 48 – 3 = 64k + 45


Q(4) = 128 – 20 + k = k + 108
Given P(4) = Q(4)
∴ 64k + 45 = k + 108
⇒ 63k = 63 ⇒ k = 1

58)

59)
|3 – π| = π – 3

60) e.g.

68)

∴ = ±3 ...(1)

Now
= (3)(7 – 1)
= 18

= (18) (7) – 3
= 123

69)

Hence

70) 2785x
Sum of digit at odd places = 10 + x
Sum of digit at even places = 12
Divisible by 11
∴ (2 – x) = 0 ∴ x = 2

73)

= (6)3 – 3(6)
⇒ 216 – 18 = 198

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