12-04-2026

9610ZJA801912250028 JA

PART 1 : PHYSICS

SECTION-II

1) A long container has air enclosed inside at room temperature and atmospheric pressure (105 pa).
It has a volume of 20,000 cc. The area of cross section is 100 cm2 and force constant of spring is
kspring = 1000N/m. We push the right piston isothermally and slowly till it reaches the original
position of the left piston which is movable. What is the final length of air column in cm ? Assume

that spring is initially relaxed.

2) An audio transmitter (T) and a receiver (R) are hung vertically from two identical massless strings
of length 8 m with their pivots well separated along the ฀ axis. They are pulled from the equilibrium
position in opposite directions along the ฀ axis by a small angular amplitude θ0 = cos–1 (0.9) and
released simultaneously. If the natural frequency of the transmitter is 660 Hz and the speed of sound
in air is 330 m/s, the maximum variation in the frequency (in Hz) as measured by the receiver (Take
the acceleration due to gravity ฀ = 10 m/s2) is _______.

3) An infinite number of bricks are placed one over the other as shown in the figure. Each
succeeding brick having half the length and breadth of its preceding brick and the mass of each
succeeding bricks being 1/4th of the preceding one, take ‘O’ as the origin, the x-coordinate of centre

of mass of the system of bricks is . Then the value of n is ___.

4) A material with uniform restively is formed in the shape of a wedge as shown. The resistance of
wedge across length L is Then find the value of

5) Two identical parallel plate capacitors are connected as shown in the figure. Initially both have
total charge q0 and separation between their plates x0. At an instant, plates of one capacitor begin to
move towards each other and plates of the other capacitor away from each other. If velocity of a
plate relative to the other in both the capacitors has the same magnitude v, find current (in A) in the

0 0

circuit. (Given : q = 1mC, x = 1mm, v = 8m/s)

6) A monochromatic light of wavelength λ0 and intensity I0 (on the screen from each slit) is incident
of YDSE experiment. The distance between slits S1S2 is ‘d’ (d << D). The angle made by parallel

beam light with the normal to the plane of slits is . Now if a transparent glass slab of

thicknes is kept infront of one of the slits, where ‘μ’ is refractive index of glass slab. Find
the intensity (in W/m2) at the geometrical centre ‘O’ of the screen. (Given, d = 1 mm, D = 2m, μ =

4/3, λ = 4000Å and I = 4.16 W/m2).

7) A square loop abcd of side ‘ℓ’ and resistance R is placed near an infinitely long wire carrying
constant current I. The side ab and cd are parallel to wire. The wire and loop are in same plane the
loop is rotated by 180° about axis parlel to long wire and passing through mid point of bc and da.

The total amount of charge which passes through any side during loop rotation is . Then α
is :

8) One end of a spring of natural length ℓ and spring constant k is fixed at the ground and the other
is fitted with a smooth ring of mass m which is allowed to slide on a horizontal rod fixed at a height ℓ
(figure). Initially, the spring makes an angle of θ with the vertical when the system is released from

rest. If the speed of the ring when the spring becomes vertical is (2ℓ / 3) m/s then the value of

angle θ (in degree) is :

SECTION-I (i)

1) The switch SW1 and SW2 is open. At t = 0, SW1, SW2 are closed simultaneously. Choose CORRECT

statement/s. (Take : e = 2.7)

(A) Current i1 = 2A at t = 1 sec.

(B) The current i2 at t = 1 sec is approximately 4.3 A.
(C) Potential difference across capacitor at 1sec is approximately is 10 V.
At t = 1 sec, both the switches are opened. The current in each inductor just after opening both
(D)
switches SW1 and SW2 is 1.9 A.

2) A helicopter of mass M = 10000 kg is lifting a cubical box of mass m = 1000 kg. The helicopter is
going down with an acceleration of a = 1.8 m/s2. The four strings are tied at mid points of the sides
of the square face PQRS of the box. The strings are identical and form a knot at K. Another string
KH connects the knot to the helicopter. Neglect mass of all strings and take g = 9.8 m/s2. Length of
each string AK, BK, CK and DK is equal to side length of the cube.

(A)
Tension T in string AK is .
(B) Tension T0 in string KH is 8000N.
Force (F) applied by the atmosphere on helicopter is 88000N (assume that the atmosphere
(C)
exerts a negligible force on the box).
(D) If the four strings are tied at P, Q, R and S instead of A, B, C & D, then T0 and F will not change.

3) An object comprises of a uniform ring of radius R and two small identical disc as shown. Which of

the following can not be the centre of mass of the object?

(A)

(B)

(C) (R, R)

(D)

4) The equivalent circuit of a real source of alternating voltage of frequency ω = 1.00 × 103 s–1
consists of an ideal voltage source with the amplitude U = 15.0 V, a resistor with the resistance r =
10Ω and a capacitor with the capacitance C = 100 µF. Different circuits of resistors, capacitors and
coils can be connected to the source as a load. A load circuit, which assures maximum heat
generated in the load itself is connected across the source terminals AB.

(A) The load is purely resistive in nature.

(B)
The power factor of the load is .
(C) The resistance of the load is equal to 10Ω.

(D)
The maximum heat generated in the load is W.

5) A charged particle of charge q and mass m is entering at origin with a velocity v in a uniform
magnetic field –B which is extended upto infinite at right of the line L. Select the correct option(s)

Given that = 1 meter, and v = 1 m/s.

Velocity of the particle makes an angle 60º with x-axis while it is coming out of the magnetic
(A)
field.

(B)
The co-ordinates of point of exit is

(C)
The co-ordinates of point of exit is

(D)
Time spent by the particle in the magnetic field is sec.

6) Two concentric spherical shells masses m1 and m2 and radii r1 and r2. Then

(A) outer shell will have no contribution in gravitational field at point P.

(B) force on P is directed towards O.

(C)
force on P is .

(D)
force on P is .

SECTION-I (ii)

1) One mole of an ideal monoatomic gas is taken round the cyclic process ABCA as shown in figure.

List-I List-II

(P) The work done by the gas during complete cycle (1)

(Q) Heat absorbed by the gas in the path AB (2)

The minimum temperature attained by the

(R) (3) P0V0
gas during the cycle.

The maximum temperature attained by the

(S) (4) 3P0V0
gas during the cycle.

(5) 2P0V0
(A) P → 1;Q → 2;R → 3;S → 4
(B) P → 3;Q → 4;R → 2;S → 1
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 1;Q → 2;R → 4;S → 3

2) A standing wave, formed in an organ pipe aligned along the x-axis, is given by
S = (5 × 10–6 m) sin(4πx) cos (1320πt)
Where x is in m and t is in seconds.

List-I List-II

(P) Magnitude of change in pressure is maximum (1)

(Q) Magnitude of change in pressure is minimum (2)

(R) Maximum amplitude of vibration (3) x = 1m

 (S) Minimum amplitude of vibration (4)

(5)

(A) P → 1,2,3;Q → 4,5;R → 4,5;S → 1,2,3

(B) P → 1,3;Q → 3,5;R → 2,3,4,5;S → 1,2,3,4,5
(C) P → 2,3;Q → 2,4;R → 2,3,5;S → 3,4,5
(D) P → 1,3,4;Q → 1,3;R → 2,3;S → 2,3,4,5

3) A light ray is incident on the surface of a sphere of refractive index ฀ at an angle of incidence θ0.
The ray partially refracts into the sphere with angle of refraction ϕ0 and then partly reflects from the
back surface. The reflected ray then emerges out of the sphere after a partial refraction. The total
angle of deviation of the emergent ray with respect to the incident ray is α. Match the quantities
mentioned in List-I with their values in List-II and choose the correct option.

List-I List-II

If n = 2 and α = 180°, then all

(P) (1) 30° and 0°
the possible values of θ0 will be

If n = and α = 180°, then all

(Q) (2) 60° and 0°
the possible values of θ0 will be

If n = and α = 180°, then all

(R) (3) 45° and 0°
the possible values of ϕ0 will be

If n = and θ0 = 45°, then all

(S) (4) 150°
the possible values of α will be

(5) 0°
(A) P → 5;Q → 2;R → 1;S → 4
(B) P → 5;Q → 1;R → 2;S → 4
(C) P → 3;Q → 2;R → 1;S → 4
(D) P → 3;Q → 1;R → 2;S → 5

4) A block 'A' of mass 10 kg is placed on rough horizontal plank 'B' (x-y plane) where gravity act
vertically downward. µs = 1.2, µk = 1. (All units are in SI). Forces acting on block A is due to plank
and earth only. For the situation in column-I match the appropriate description in column-II.

Column-I Column-II
 Direction of friction on A is +ve
(A) (P)
y-direction.

Direction of friction on A is +ve

(B) (Q)
x-direction.

Direction of acceleration of A is
(C) (R)
+ve y-direction.

(D) (S)

Friction force on A is neither in

(T) x-direction nor y-direction but
somewhere in between.
(A) A → P,Q;B → R,S;C → R,S;D → S,T
(B) A → P,R;B → S,T;C → R,S;D → S,T
(C) A → P,R;B → S,T;C → S,T;D → S,T
(D) A → P,Q;B → P,R;C → S,T;D → S,T

PART 2 : CHEMISTRY

SECTION-II

1) An octahedral complex of chromium contains NH3 and Cl ligands. The oxidation number of
chromium in the complex is +3. The complex shows one cis and one trans isomer(no fac or mer
isomers). Reaction of the complex with AgNO3 solution forms white precipitate. How much
precipitate in gram will be formed if one mole of the complex reacts with excess of AgNO3 solution ?

2) HA is a weak acid and NaA is it’s salt. An aqueous solution contains HA and NaA in the molar
ratio of 10 :1 respectively. The pH of this aqueous solution is 5.38. What is the pKa of the acid HA?

3) CaCO3(s) ⇋ CaO(s) + CO2(g)

If above reaction takes place in a 100 L container at 1000 K, 100 moles of CO2 is produced at
equilibrium. What is the equilibrium constant KP of the reaction in atm unit ?

4) The polymerization of the ethylene to linear polyethylene is represented by the reaction

n(H2C=CH2)→(CH2–CH2)n
Where n has a large integral value. Given that the average enthalpies of bond dissociation for C = C
and C – C at 298 K are +590 kJ/mol & +331 kJ/mol respectively. Calculate the magnitude of enthalpy
of polymerization in kJ per mole of ethylene at 298 K?

5) The sum of reaction number for which the major product is/are correctly mentioned is :
6) For the given sequence of reaction

How many products are obtained finally ?

7) Degree of unsaturation in the major product is

X then (X–2)

8) Consider the following complex compounds.

[CoCl2Br2]2⊝ , [Ni(en)3]2⊕ , [Ti(H2O)6]3⊕ , [Fe(NH3)6]2⊕ , [Co(H2O)3F3] , K3[Fe(CN)6]

If number of low spin complexes is "X" and number of high spin complexes is "Y" then is

SECTION-I (i)

1) 30 mL of CH3OH(d = 0.8 g/cc) is mixed with 60 mL of C2H5OH (d = 0.92 g/cc) at 25oC to form a
solution of density 0.88 g/cc.
Choose the correct statement(s) from the following.

(A) Molarity of the solution and percentage change in volume are 13.59 and zero respectively.
(B) The mole fraction of solute and molality are 0.385 and 13.59 respectively.
(C) The mole fraction of solvent and molality are 0.615 and 13.59 respectively.
(D) Molarity and molality of resulting solution are 6.33 and 13.59 respectively.

2) Which of the following statement(s) is/are correct for Na3[Co(ONO)6]?

(A) It’s aqueous solution is slightly basic in nature.

(B) It’s IUPAC name is sodium hexanitritocobaltate(III)
(C) It is called sodium cobaltinitrite
(D) One molecule of it forms three ions in water.

3) The total vapour pressure of a binary solution is given by

P = (80 XA + 240 XB) mm Hg
Where XA and XB are the mole fractions of components A and B. Choose the correct statement(s)
from the following:

(A) vapour pressure of solution is less than that of the pure B component.
(B) vapour pressure of solution is more than that of pure A component.
(C) vapour pressure of pure A is 80 mm of Hg and that of pure B is 240 mm Hg.
(D) the vapour pressure of pure A and B are 240 and 80 mm Hg respectively.

4) Which of the following cations will turn a borax bead blue in an oxidizing flame?

(A) Fe3+
(B) Fe2+
(C) Co2+
(D) Cu2+

5)

(A)
(B)

(C)

(D)

6)
Identify correct statement for (A) and (B) products.

(A)

(B)

(C)
(D)

SECTION-I (ii)

1)

List-II
List-I
Graph (A - Reactant in reaction,
(Order)
B - Product in reaction)

(P) Zero order (1)

(Q) First order (2)

(R) Second order (3)

 (S) Third order (4)

(5)

Select correct option :

(A) P → 5;Q → 2;R → 4;S → 1
(B) P → 1;Q → 2;R → 3;S → 5
(C) P → 1;Q → 5;R → 3;S → 1
(D) P → 5;Q → 2;R → 3;S → 1

2)

List-I List-II
(Orbitals) (Nodal graphs)

(P) 3s (1)

(Q) 4p (2)
 (R) 4d (3)

(S) 3p (4)

(5)

(A) P → 4;Q → 1;R → 3;S → 2

(B) P → 2;Q → 3;R → 2;S → 5
(C) P → 2;Q → 1;R → 3;S → 5
(D) P → 1;Q → 3;R → 4;S → 3

3)

Column-I Column-II

(P) Acetone + CHCl3 (A) ΔSmix > 0

(Q) Ethanol + Water (B) ΔVmix > 0

(R) C2H5Br + C2H5I (C) ΔHmix > 0

(S) Acetone + benzene (D) Maximum boiling point azeotrope

(E) Minimum boiling point azeotrone

(A) P → AD;Q → ABCE;R → A;S → ABE
(B) P → AD;Q → ABCE;R → A;S → ABCE
(C) P → AB;Q → ABCE;R → ABE;S → A
(D) P → AC;Q → A;R → BC;S → AB

4) Match each species in List-I with List-II and choose correct option :

List-I List-II
 (P) A carbohydrate which yields only glucose on hydrolysis (1) Sucrose

(Q) A carbohydrate which yields glucose and fructose on hydrolysis (2) Lactose

(R) A carbohydrate which yields glucose and galactose on hydrolysis (3) Amylose

(S) A carbohydrate which can reduce Fehling solution (4) Mannose

(5) Cellulose
(A) P → 3,5;Q → 2;R → 1;S → 2,4
(B) P → 5;Q → 1;R → 2;S → 2,3
(C) P → 3;Q → 1;R → 2;S → 2,5
(D) P → 3,5;Q → 1;R → 2;S → 2,4

PART 3 : MATHEMATICS

SECTION-II

1) If f(x) is twice differentiable function such that for all x ∈ [0, 9] and f(x) takes
maximum value at an interior point of the interval [0, 9], then find sum of square of digits of largest
value of is

2) is equal to

3) Let , for x ∈ ℝ. Then the number of real solutions of the equation

in the set is equal to

4) Let and are two non-zero, non-collinear vectors such that = 1 and and

represents two sides of a triangle. If area of the triangle is and V

be the volume of parallelepiped formed by coterminous edges and then value of is equal
to

5) Three circles C3, C2, C1 of radius 3, 6, 9 respectively touch as shown in the figure. A chord AB to
circle C1 touch circles C2 and C3.
The length of chord AB is and length of common tangent PQ is then number of divisors
of (3β–1 – 2α–1) is

6) If a1, a2,......., a10 are positive numbers in arithmetic progression such that

and

Then the sum of digits of is

7) Let Let A be a 2 × 2 symmetric matrix such that and the determinant of A be 1.

If A–1 = αA + βI, where I is an identity matrix of order 2 × 2, then α + β equals

8) Consider a triangle formed by the points and . Let A(z) be any

point on its incircle then AP2 + AQ2 + AR2 equals to

SECTION-I (i)

1) Let f be a continuous function satisfying and . If

then which of the following options is/are CORRECT?

(A)

(B)

(C) Number of points where g(x) is non-derivable is 3

(D) Number of points where g(x) is non-derivable is 5

2) Let f : [0, ∞) → be a continuous function such that for all x ∈[0, ∞).
Then, which of the following statement(s) is (are) TRUE?

(A) The curve y = f(x) passes through the point (1, 2)

(B) The curve y = f(x) passes through the point (2, –1)

The area of the region is

(C)

(D)
The area of the region is

3) Let and 0 < β1 < β2 < ........ < βm < 2π are values of α
and β respectively such that 2cos2α – 3 = 2cos(2α + β) – 2cosβ, then which of the following can be
true ?

(A) 2n > 3m
(B) n > m

(C)

(D)

4) The chord x+y=1 cuts the curve y2=12x in pomts Aand B. The normals at A and B intersect at C. A
third line from C cuts the y2=12x normally at D. Then which of the following is/are correct

(A) Sum of slopes of normals at A and B is 3

(B) Coordinates of D are (12,12)
(C) Tangent at D intersect y axis at (0,6)
(D) Coordinates of D are (12,-12)

5) 16 players P1, P2, ......... P16 play a knock out tournament. Assuming that the players are paired at
random in each round. If all the players are of equal strength, then the probability that P1 reaches

final under the condition P2 reaches semifinal but not in final is (where a and b are co-primes),
then which of the following is true?

(A)

(B)

(C) Number of divisors of a2b = 12

(D) Sum of all devisors of a2b = 24

6) Consider the equation , p, q ∈ R. Then which of the following is/are correct

(A) Equation has atmost 3 real solutions

(B) Equation has atleast 1 real solutions
(C) Equation has real solutions only if p2 – 4q ≥ 0
(D) Equation has 3 real solutions if p < 0 and q > 0.
 SECTION-I (ii)

1)

Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

one-one and onto

(P) ƒ : R → R such that , (1)
function
then ƒ(x) is
one-one and into
(Q) ƒ : [–1,∞) → [0,∞) such that ƒ(x) = |e–|x| + x|, then ƒ(x) is (2)
function
many-one and into
(R) (3)
ƒ : (∞, ∞) – {–9,9} → R such that , then ƒ(x) is function
many-one and onto
(S) (4)
ƒ : R – {1, –7} → R – {1} such that , then ƒ(x) is function
(A) P → 1;Q → 4;R → 3;S → 2
(B) P → 4;Q → 3;R → 1;S → 2
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 3;Q → 1;R → 4;S → 2

2) For any finite set S let n(s) denote the number of elements in S, suppose A and B are two subset
of {1, 2, 3, 4, 5, 6} that satisfy n(A) . n(B) = n(A ∩ B). n(A ∪ B) and P(E) is the probability of
occurrence of event E, then (where n(A) is number of elements in the set(A).

List - I List - II

(P) (1)

(Q) (2)

(R) (3)

(S) (4)

(5)

(A) P → 2;Q → 3;R → 1;S → 4

(B) P → 2;Q → 4;R → 5;S → 3
(C) P → 1;Q → 4;R → 5;S → 2
(D) P → 4;Q → 1;R → 5;S → 3

3) A point P moves such that sum of slopes of normals drawn from it to the hyperbola xy = 16 is
equal to sum of ordinates of feet of the normals. Let P lies on curve C, then
 List -
List - I
II

Area of equilateral triangle (in sq. units) inscribed in C, having one

(P) (1) 0
vertex at (0, 0) is λ then is

If intercept of normal drawn at (x, y) by curve C, subtend 90° at (0,

(Q) (2) 1
0) then is (where g.i.f.)

(R) (3) 2
If area bounded by latus rectum of C and curve C is λ, then is

If λ is minimum distance between curve C and x2 + y2 + 10y + 24 =

(S) (4) 3
0, then value of λ is

(5) 4
(A) P → 2;Q → 3;R → 2;S → 1
(B) P → 4;Q → 3;R → 2;S → 5
(C) P → 4;Q → 3;R → 5;S → 2
(D) P → 4;Q → 5;R → 3;S → 2

4) Let ℓ1 and ℓ2 be the lines and , respectively. Let X be the

set of all the planes H that contain the line ℓ1. For a plane H, let d(H) denote the smallest possible
distance between the points of ℓ2 and H. Let H0 be plane in X for which d(H0) is the maximum value
of d(H) as H varies over all planes in X.
Match each entry in List-I to the correct entries in List-II.

List-I List-II

(P) The value of d(H0) is (1) 0

(Q) The distance of the point (0,1,2) from H0 is (2)

(R) The distance of origin from H0 is (3)

The distance of origin from the point of

(S) (4)
intersection of planes y = z, x = 1 and H0 is

(5)

The correct option is :

(A) P → 2;Q → 4;R → 5;S → 3
(B) P → 5;Q → 4;R → 1;S → 3
(C) P → 2;Q → 3;R → 1;S → 2
(D) P → 5;Q → 3;R → 4;S → 2
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-II

Q. 1 2 3 4 5 6 7 8
A. 100.00 31.19 to 32.27 7.00 8.00 4.00 16.64 2.00 53.00

SECTION-I (i)

Q. 9 10 11 12 13 14
A. B,C,D A,B,C,D B,C,D B,C A,C,D A,B,D

SECTION-I (ii)

Q. 15 16 17 18
A. B A A C

PART 2 : CHEMISTRY

SECTION-II

Q. 19 20 21 22 23 24 25 26
A. 143.50 6.38 82.10 72.00 6.00 11.00 9.00 0.33 to 0.34

SECTION-I (i)

Q. 27 28 29 30 31 32
A. B,C A,B,C A,B,C C,D C,D A,D

SECTION-I (ii)

Q. 33 34 35 36
A. D C B D

PART 3 : MATHEMATICS

SECTION-II

Q. 37 38 39 40 41 42 43 44
A. 33.00 0.50 3.00 3.00 4.00 8.00 5.00 33.75

SECTION-I (i)

Q. 45 46 47 48 49 50
A. A,D B,C B,C B,C B,C A,B
 SECTION-I (ii)

Q. 51 52 53 54
A. A B B B
 SOLUTIONS

PART 1 : PHYSICS

1) Explain Question: We need to find final length of air column

Concept: Isothermal process equation
Solution:

P2V2 = P1V1
V1 = 20000cc.
P1 = 105 Pa
V2 = Ax

0
P2 = P +

⇒ 105 × 20000 × 10–6 = 10– 4 × 100x

⇒ 2000 = 1000 [x (1 + x)]
x2 + x – 2 = 0

x= =1m
x = 100 cm.
Final Answer: (100.00)

2) Explain Question: We need to find maximum variation in the frequency

Concept: Doppler effect
Solution:
 ......(i)
Here, v' = ℓΩmax
= ℓ·θ0·ω (ω = Angular frequency)

v' = 4
Put in equation (i)

Final Answer: (31.19-21.27)

3) Explain Question: We need to find CM of given system

Concept: Formula to calculate CM of system
Solution:
Centre of mass of each block will be at its mid point.

For mass

for mass ; and so on ...

Co-ordinate of com is given by

sum of are infinite G.P is given by

Final Answer: (7.00)

4) Explain Question: We need to find resistance of wedge shaped material

Concept: How to take element and basic formula of resistance
Solution:
Final Answer: (8.00)

5) Explain Question: We need to find current in circuit

Concept: Charge distribution and KVL
Solution:

so

Final Answer: (4)

6) Explain Question: We need to find intensity at "O" point in case of oblique incidence
Concept: Calculation of path difference
Solution:
d sin θ ± (m – 1)t = Δx

= Δx
Δx = 3λ
Hence maximum intensity will occur at ‘O’.
I = 4I0 = 16.64 W/m2.
Final Answer: (16.64)

7) Explain Question: We need to find total amount of charge which passes through any side
during loop rotation
Concept: Calculation of flux using element and
Solution:

Final Answer: (2.00)

8) Explain Question: We need to find speed of ring when it becomes vertical

Concept: Conservation of mechanical energy
Solution:

Final Answer: (53.00)

9) Explain Question: We need to find correct statement for R-L-C circuit with DC source.
Concept: Charging and discharging of capacitor and inductor and flux does not charge
suddenly through inductor
Solution:

i1 = = 5t = 5A
i2 = 5(1 – e–2t) = 5(1 – e–2) = 4.3 A
v = 10 (1 – e–1/RC) = 10V

10 – 4.3 = 3i ⇒ i =
Final Answer: (B,C,D)

10) Question Explanation:

The problem describes a helicopter of mass M = 10000 kg lifting a cubical box of mas m =
1000 kg. The system is moving downwards with an acceleration of a = 1.8 m/s2. We need to
analyze the system and choose correct options.

Concept:
This question is based on Newton/s law of motion.

Solution:
If force applied by atmosphere on helicopter is F then
(M + m)g – F = (M + m)a
F = (M + m) (g – a)
F = 11000 (8) = 88000N
Let tension in string HK is T0 and tension in string AK, BK, CK and DK all are T
then for helicopter Mg + T0 – F = Ma
solving this we get
T0 = 8000

at point K 4Tcosθ = T0

If string are connected to PQRS, θ will increase cosθ will decrease.

Hence T0 and F will remain unchanged while T will increase.

Final Answer:
The correct options are (1), (2), (3) & (4).

11) Explain Question: We need to find correct possible answers

Concept: CM will be in first quadrant and on symmetric line but can not be (R,R)
Solution:
COM will be on the line y = x
Final Answer: (B,C,D)

12) Explain Question: We need to find correct statement about load

Concept: Resonance in RLC series circuit with AC source.
Solution:
(1) In the source

xC = , r = 10Ω
z1 = r – xCj
(2) Let load has z2 = R + xj
z of existing ckt ⇒ z1 = r + (–xC)j
zeq = z1 + z2 ⇒ zeq = (R + r) + (x – xC)j
Pload = irms load vrms load cosϕload

for Pload to be maximum

x = xC = 10Ω

⇒R=r

⇒ (Pload)max =
Now R = r = 10Ω

εrms =

(Pload)max=

(Pload)max =
z2 = zload = 10 + 10j

P.f. = ϕ =
Final Answer: (B,C)

13) Explain Question: We need to select correct options

Concept: Circular motion in uniform magnetic field
Solution:

OP = 1m and time period

T= sec
Time spent by the particle in the magnetic field is

Final Answer: (A,C,D)

14) Explain Question: We need to find correct statement

Concept: Gravitational field and force for spherical shells
Solution:
Gravitational field intensity inside the spherical shell is zero.
Gravitational force is always directed towards the source mass.
Force on P act only due to m1 because point P is outside the spherical shell of mass m1.
So choice (A), (B) and (D) are correct.
∴ (A), (B) and (D)
Final Answer: (A,B,D)

15) Explain question : We are given a graph between pressure (P) and volume (v) for a one
mole of ideal monatomic gas. We have to match list-I with list-II.
Concept : This question is based on cyclic process graph in thermodynamic system.
Solution :

0 0 0 0
For (P) : W = (2P )(V ) = P V

0 0
For (Q) : QAB = nCV (TB–TA) = 1 × R = 3P V

For (R) : TA = , TB = = 3TA, TC = = 2TA

⇒ Minimum temperature : Tmin =

(OR Temperature will be minimum for a point which is nearest to origin)
Maximum temperature will be either on end points or in process BC.
For (S) : As for process BC :

= ⇒ P = 5P0 –

0 0
⇒ PV = 5P V – V2 But PV = RT. So RT = 5P V – V2

0
⇒ = 5P0 – (2V) = 0 ⇒ V = V

0
⇒ RTmax = 5P ⇒ Tmax =
Final answer : 2

16) Explain Question: We need to select a position that is correctly method about standing
wave in sound.
Concept: Relation between displacement and pressure wave equation

Solution: Displacement and pressure have phase difference of

 Final Answer: (A)

17) Explain Question: We need to find correct statement about angle of deviation
Concept: Angle of deviation and snell's law
Solution:

α = (θ0 – ϕ0) + (180 – 2 ϕ0) + (θ0 – 2ϕ0)

α = 180 + 2θ0 – 4ϕ0
(P) α = 180 + 2θ0 – 4ϕ0
180 = 180 + 2θ0 – 4ϕ0 ⇒ θ0 = 2ϕ0 ....(i)
sinθ0 = 2sinϕ0 ....(ii)
From (i) & (ii)

0 0
sinθ = 2sin(θ /2)
Final Answer: (A)

18) Explain Question: We need to match the situation of block to direction of friction and
acceleration
Concept: Direction of friction is opposite to relative velocity and direction of acceleration is
along net force
Solution:
(A) thus kinetic friction will act along positive y axis.
(B) since a < µsg
thus static friction acts in the direction of .
(C) Same as (B)
(D) Same as (B)
Final Answer: (C)

PART 2 : CHEMISTRY

19) Explain Question: Calculate how much precipitate in gram will be formed if one mole of
the complex reacts with excess of AgNO3 solution
Concept: Werner theory
Solution:
[Cr(NH3)4Cl2]Cl + AgNO3 → AgCl + [Cr(NH3)4Cl2]NO3
1 1
∴ Mole of AgCl formed = 1
Mass of AgCl = 143.50 g
Final Answer: (143.50)

20) Explain Question: Calculate the pKa of the acid HA

Concept: Henderson's equation
Solution:

pH = pKa + log

or, 5.38 = pKa + log

∴ pKa = 5.38 + 1 = 6.38
Final Answer: (6.38)

21) Explain Question: Calculate the equilibrium constant KP of the reaction in atm unit
Concept: Equilibrium constant
Solution:

Kp = 82.1
Final Answer: (82.10)

22) Explain Question: Calculate the magnitude of enthalpy of polymerization in kJ per mole
of ethylene at 298 K
Concept: Polymerization enthalpy using bond enthalpy
Solution:
n double bonds dissociate to form 2n single bond.
ΔH for polymerization of 1 mol of ethylene

=+590 – 2 × 331 = –72 kJ mol–1 = –72.00 kJ mol–1

Final Answer: (72.00)

23) Explain Question: Calculate sum of reaction number for which the major product is/are
correctly mentioned
Concept: Birch reduction.
Solution:
Final Answer: (6.00)

24) Explain Question: Calculate the number of products are obtained finally
Concept: Aldol condensation, ozonolysis, grignard, kucherov reaction.
Solution:
Final Answer: (11.00)

25) Explain Question: Calculate Degree of unsaturation in the major product is X

Concept: Dehydration of alcohol.
Solution:

Final Answer: (9.00)

26) Explain Question: Identify low and high spin complexes.

Concept: Crystal field theory.
Solution:
X = K3[Fe(CN)6] Y = [CoCl2Br2]2⊝ , [Fe(NH3)6]2⊕ , [Co(H2O)3F3]
Final Answer: (0.33-0.34)

27) Explain Question: Identify the correct statement(s) from the following
Concept: concentration terms.
Solution:
= 30 mL = 60 mL
d = 0.8 g/cc d = 0.92 g/cc
W = 0.8 × 30= 24 g W = 60 x 0.92 = 55.2 g

n= = 0.75
Total moles = 0.75 +1.2 = 1.95 Solute = CH3OH, Solvent = C2H5OH

Molarity = 0.75 ×

Molality = 0.75 ×

Mole fraction of solute (CH3OH) =

Mole fraction of solvent (C2H5OH) = 1 –0.385 = 0.615
Final Answer: (BC)

28) Explain Question: Identify which of the following statement(s) is/are correct for
Na3[Co(ONO)6]
Concept: Chemical and physical properties of given complex.
Solution:
Na3 [Co(ONO)6] 3Na+ + [Co(ONO)6]3–
[Co(ONO)6]3– + H2O H[Co(ONO)6]2– + OH–
The IUPAC name of the ligand is nitrito.
Final Answer: (ABC)

29) Explain Question: Identify the correct statement(s) from the following
Concept: Raoult's law
Solution:
For option (A)
P = 80XA + 240 XB
= 80 XA + 240 (1 – XA)
= 80 XA + 240 – 240 XA
= 240 + XA(80 – 240)
= 240 – 160 XA
∴ V.P of solution is less than 240 mm Hg which is V.P of pure(B)
For option (B)
P = 80XA + 240 XB
= 80(1 – XB) + 240 XB
= 80 – 80 XB + 240 XB
= 80 + (240 – 80)XB = 80 + 160 XB
∴ V.P of solution is more than 80 mm Hg which is the V.P of pure(A)
For option (C)
P = 80XA + 240XB
For pure (A), XA = 1 and XB = 0
V.P of pure (A) = 80 mm Hg
Similarly
∴ V.P of pure (B) = 240 mm Hg.
Final Answer: (ABC)

30) Explain Question: Identify which of the following cations will turn a borax bead blue in
an oxidizing flame
Concept: Borax bead test
Solution:
Co(BO2)2 and Cu(BO2)2 are blue substances.
Final Answer: (CD)

31) Explain Question: Identify the major product

Concept: Hydroboration oxidation.
Solution:

Final Answer: (CD)

32) Explain Question: Identify product A and B

Concept: Reaction of carbonyl compounds.
Solution:

Final Answer: (AD)

33) Explain Question: Identify the correct match of order

Concept: Rate law and order of reactions.
Solution:
(P) For zero order
[Ao] – [At] = Kt
[At] = [Ao] – Kt

(Q) For first order

ln[Ao] – ln[At] = Kt
ln[At] = ln[Ao] – Kt

(R) For second order

ln t1/2 = –ln [Ao] –lnK

(S) For third order

Final Answer: (D)

 34)

Question Explanation: Match the column

Concept: This question is based on Schrodinger's wave equation

Solution:
Radial nodes are calculated using the formula: n – ℓ – 1.

A. (P) 3s: nodes . Since it's an s-orbital, its starts at a non-zero value. Thus,
.
B. (Q) 4p: nodes . The RPD graph (1) shows 3 peaks, indicating 2 nodes. Thus,
.
C. (R) 4d: nodes . The graph (3) shows 1 radial node where the graph
touches the axis. Thus, .
D. (S) 3p: nodes . The RPD graph (5) shows 2 peaks, indicating 1 node. Thus,
.

Matching these results gives: P→2, Q→1, R→3, S→5.

Final Answer: Option (3)

35) Explain Question: Identify correct match with their properties,

Concept: Deviation from raoult's law
Solution:

(P)
⇒ More interaction in mixture.
⇒ Negative deviation from Roult’s law.
⇒
⇒ Maximum boiling point azeotrope
[P → A, D]

(Q)
⇒ A–A & B–B interaction > A–B interaction
⇒ Positive deviation from Roult’s law.
⇒ ΔSmix > 0 ; ΔVmix > 0 : ΔHmix > 0
⇒ Minimum boiling point azeotrope
⇒ [Q → A, B, C, E]

(R)
⇒ A–A & B–B interaction A–B interaction
⇒ shows ideal behaviour
 ⇒ ΔSmix > 0 ; ΔVmix = 0 ; ΔHmix = 0
[R → A]

(S)
⇒ Less interaction in mixture.
⇒ Positive deviation from Roult’s law.
⇒ ΔSmix > 0 ; ΔVmix > 0 ; ΔHmix > 0
⇒ Minimum boiling point azeotrope.
[S → A, B, C, E]
Final Answer: (B)

36) Explain Question: Identify the correct hydrolysis products.

Concept: Monomers of given di and polysaccharides.
Solution:
Sucrose
α-D-glucose + β-D-fructose
Lactose
β-D-glucose + β-D-galactose
Amylose
α-D-glucose + α-D-glucose + ...
Mannose cannot be hydrolysed.
Lactose and mannose can reduce Fehling’s solution due to presence of hemiacetal and
aldehyde group.
Final Answer: (D)

PART 3 : MATHEMATICS

37)

Explain Question: Given a twice differentiable function f(x) on [0,9] with a maximum at an
interior point and , find the sum of the squares of the digits of the maximum
possible value of .
Concept: Application of Derivatives, Lagrange’s Mean Value Theorem (LMVT), and properties
of differentiable functions involving second derivatives and extrema.
Solution:
Let f(x) takes its maximum value of α, where α ∈ (0, 9)
By, LMVT for

..... (1)
Similarly, ..... (2)
Largest value of
Sum of square of digits = 22 + 0 + 22 + 52 = 33
Final Answer: (33.00)

38)

Explain Question: Calculate the limit as n approaches infinity for the nth root of the product

of sine terms for k from 1 to n.

Concept: Limit of a Sum as an Integral, Logarithmic properties, and Definite Integration of
.
Solution:

ln l =

Tr = ;

sum =

∴ ln l = ln 2–1 ⇒ l = Ans
Final Answer: (0.50)

39)

40)

Explain Question: Given two vectors forming sides of a triangle with a specific area related
to a parallelepiped volume V, find the value of V/4.
Concept: Vector Algebra, Scalar Triple Product, Vector Cross Product, Area of Triangle, and
Volume of Parallelepiped.
Solution:
 ,
=0⇒
= =
=

=
=2 sin θ

Δ= ×3 sin θ × sin θ

Δ= sin2θ =

⇒ = =
⇒ sin2θ = 1 and =2
Now, V =
=

=
= 6 × (1) × (2) × (1) = 12

∴ =3
Final Answer: (3.00)

41)

Explain Question: Three mutually touching circles are given. A chord AB of the largest circle
touches the smaller two. Find the number of divisors of a specific expression derived from the
lengths of AB and tangent PQ.
Concept: Coordinate Geometry of Circles, Tangents, Power of a Point, and Number Theory
(Divisors).
Solution:

Also

Let equation of circle

In
D is mid-point of O2Q
Line O3D is parallel to PQ
⇒ O3 is mid-point of TO2
⇒ Co-ordinate of T = (–15, 0)

Any point on lie on circle C1

Clearly α = 4, β = 6
Hence N = 3β–1 – 2α–1 = 235 = 5 × 47
Number of divisors = 4
Final Answer: (4.00)

42)

Explain Question: For 10 positive numbers in Arithmetic Progression (AP) satisfying two
specific sum/product equations, calculate the sum of the digits of the expression

.
Concept: Arithmetic Progression (AP) properties, Reciprocal sums in AP, and Sum of Digits.
Solution:

Also

​Final Answer: (8.00)

43)

Explain Question: A 2 × 2 symmetric matrix A has determinant 1 and transforms vector [1,1]
to [3,7]. Find α + β if .
Concept: Matrix Algebra, Symmetric Matrices, Determinants, Matrix Inverse, and Cayley-
Hamilton Theorem.
Solution:

Let A =

, ad ⧿ b2 = 1
a + b = 3, b + d = 7, (3 – b) (7 – b) ⧿b2 = 1
21 – 10b = 1 → b = 2, a = 1, d = 5
A⧿1 = αA + βI

α = ⧿1, β = 6 → α + β = 5
Final Answer: (5.00)

44)

Explain Question: For an equilateral triangle formed by complex numbers on a circle of

radius 3, find the sum of squared distances from any point on its incircle to the vertices.
Concept: Complex Numbers, Geometry of Equilateral Triangles, Incenter/Incircle properties,
and Distance Formula in complex plane.
Solution:
Let , ,
Clearly the points lies on circle |z'| = 3 and form an equilateral triangle.

If a is side length of triangle and R' = 3 is radius of circle, then

in-radius of

Let A(z) be any point on the in-circle

⇒
Now,
Similarly
and
Now AP2 + AQ2 + AR2
=

Final Answer: (33.75)

45)

Explain Question: Analyze the continuity and differentiability of a function g(x) defined as the
minimum of a constant function f(x) and an absolute value function.
Concept: Continuity, Differentiability, Limits of periodic-like functions, and Non-derivable
points of "min" functions.
Solution:

Number of points where function is not differentiable = 5

Final Answer: (A, D)

46)

Explain Question: Solve an integral equation for f(x), then identify the point the resulting
curve passes through and the area it bounds with a circle in the first quadrant.
Concept: Integral Equations, Leibniz Rule, Linear Differential Equations, and Area Under
Curves (Integration).
Solution:

f(x) = ... (1)

f′(x) = (differentiating using leibnitz rule)

f′(x) = ... (2)

from equation (1) & (2)
f′(x) = –2 + f(x) – 1 + 2x + f(x)
f′(x) = 2f(x) + 2x – 3

= 2x – 3
IF =

ye–2x =

ye–2x =

ye–2x =

y=
y = 1 – x + cezx
Put x = 0 in equation (1)
⇒ f(0) = 1
1=1–0+c
⇒ c=0
y=1–x

Area =

=
Final Answer: (B,C)

47)

Explain Question: Solve a trigonometric equation involving α and β within specific ranges to
determine the number of possible values (n and m) and their sums.
Concept: Trigonometric Equations, Sum-to-Product Formulas, and Range/Domain analysis of
angles.
Solution:
2cos2α – 3 = 2cos(2α + b) – 2cosβ
2(cos2α + cosβ) = 3 + 2cos(2α + β)

and

case :

we get

Case : and ,

we get
we get 3 values of α and 2 values of β.
n = 3, m = 2
Final Answer: (B, C)

48)

Explain Question: A chord cuts a parabola; normals at intersection points meet at C. A third
normal from C meets the parabola at D. Identify the properties of D.
Concept: Parabola (Co-normal points), Properties of Normals and Tangents, and Slopes of
Normals.
Solution:
Coordinates of D are (12,12)
Tangent at D intersect y axis at (0,6)
Final Answer: (B, C)

49)

Explain Question: In a 16-player knockout tournament, find the conditional probability that
player P1 reaches the final given P2 reaches the semifinal but loses there.
Concept: Probability, Conditional Probability, Combinations, and Tournament Brackets.
Solution:
Required probability =

Final Answer: (B, C)

50)

Explain Question: Analyze the number of real solutions for the equation
based on different conditions for parameters p and q.
Concept: Quadratic Equations, Absolute Value Functions, and Analysis of Roots based on
Discriminants and Signs.
Solution:
x |x| + px + q = 0
if ... (1)
and if x < 0 ... (2)
i) If q = 0 both the equations have 0 as a common root
ii) If q < 0, (1) has a +ve and a -ve root but the -ve root must be rejected as
iii) If q > 0, (2) has a +ve and a -ve root but the +ve root must be rejected as x < 0
Hence both A and B are true
Taking p = q = 1 yields real roots for (2) but . Hence (C) is false
iv) Taking p = - 1 and q = 1 we see that (1) has no real roots while (2) has 2 real roots. Hence
(D) is false
Final Answer: (A, B)

51) ƒ'(x) = x2008 + x2006 + x2 + 2 + cosx – sinx > 0 ∀ x ∈ R

ƒ(x) is always increasing.
⇒ it is one-one
and range = R ⇒ onto

52)

Explain Question: For subsets A and B of a given set satisfying a specific cardinality relation,
match various probability scenarios involving n(A) and n(B).
Concept: Set Theory, Cardinality, Probability, and Counting (Combinatorics).
Solution:

Given, (p + q) (q + r) = q (p + q + r)
pq + pr + q2 + qr = pq + q2 + qr
pr = 0
p = 0 or r = 0
n(s) = 36 + 36 – 26
= 1394
(P) n(A) > n(B)
p+q>q+r
p>r
r=0
Favorable , 36 – 26
= 665

P(n(A)>n(B)) =
(Q) n(A) ≤ n(B)
p+q≤q+r
p≤r
p=0
Favorable, 36 = 729
p(n(A) ≤ n(B))

=
(R) n(A) ≥ n(B) → 36
Favorable = 26

Probability
(S) Favorable = 26
Probability =
Final Answer: B

53) Normal at is (x – 4t), passes through p(h1k)

⇒ 4t4 – ht3 + kt – 4 = 0
t1, t2, t3, t4 are roots

⇒ given =
2
⇒ locus of p(h1k) is x = 16y

(P)

tan 30° =

Now side of equilateral triangle OAB is 16α

⇒ area of ΔOAB =

(Q)

αβ = – 4 ....... (I)
Normal at A(3α, 4α2)

passes through B(8β, 4β2)

From (I)

or

Now,
(R)

(S) Minimum distance between C and x2 + y2 + 10y + 24 = 0 is 4

54)

Let system of planes are

ax + by + cz = 0 ..... (1)
∵ It contain L1
∴a+b+c=0 …. (2)
For largest possible distance between plane (1) and L2 the line L2 must be parallel to plane (1)
∴a+c=0 …. (3)

∴ Plane H0 :
Now d(H0) = ⊥ distance from point (0, 1, –1) on L2 to plane.

∴P→5

for 'Q' distance =

∴Q→4
∴ (0, 0, 0) lies on plane
∴R→3
for 'S' x = z ; y = z ; x = 1
∴ point of intersection p(1, 1, 1).
∴
∴S→2
∴ option [B] is correct