22-01-2025

1001CJM220125EVE JM

PART-1 : PHYSICS

SECTION-I

1) A symmetric thin biconvex lens is cut into four equal parts by two planes AB and CD as shown in
figure. If the power of original lens is 4D then the power of a part of the divided lens is

(A) 8D
(B) 4D
(C) D
(D) 2D

2) A small rigid spherical ball of mass M is dropped in a long vertical tube containing glycerine. The
velocity of the ball becomes constant after some time. If the density of glycerine is half of the density
of the ball, then the viscous force acting on the ball will be
(consider g as acceleration due to gravity)

(A)

(B)

(C) Mg
(D) 2 Mg

3) The maximum percentage error in the measurement of density of a wire is

[Given, mass of wire = (0.60 ± 0.003)g
radius of wire = (0.50 ± 0.01)cm
length of wire (10.00 ± 0.05)cm]

(A) 4
(B) 5
(C) 8
(D) 7
4) A series LCR circuit is connected to an alternating source of emf E. The current amplitude at
resonant frequency is I0. If the value of resistance R becomes twice of its initial value then amplitude
of current at resonance will be

(A) I0

(B)

(C)

(D) 2I0

5) For a short dipole placed at origin O, the dipole moment P is along x-axis, as shown in the figure.
If the electric potential and electric field at A are V0 and E0, respectively, then the correct
combination of the electric potential and electric field, respectively, at point B on the y-axis is given

by

(A)
and

(B)
zero and

(C)
zero and

(D) 0
V and

6) Which one of the following is the correct dimensional formula for the capacitance in F ? M, L, T
and C stand for unit of mass, length, time and charge,

(A) [F] = [C2M–2 L2 T2]

(B) [F] = [CM–2 L–2 T–2]
(C) [F] = [CM–1 L–2 T2]
(D) [F] = [C2M–1 L–2 T2]

7) An electron projected perpendicular to a uniform magnetic field B moves in a circle. If Bohr's

quantization is applicable, then the radius of the electronic orbit in the first excited state is :

(A)

(B)
(C)

(D)

8) For a diatomic gas, if for rigid molecules and for another diatomic
molecules, but also having vibrational modes. Then, which one of the following options is correct ?

(Cp and Cv are specific heats of the gas at constant pressure and volume)

(A) γ2 > γ1
(B) γ2 = γ1
(C) 2γ2 = γ1
(D) γ2 < γ1

9) A rectangular metallic loop is moving out of a uniform magnetic field region to a field free region
with a constant speed. When the loop is partially inside the magnate field, the plot of magnitude of
induced emf (ε) with time (t) is given by

(A)

(B)

(C)

(D)

10) A light source of wavelength λ illuminates a metal surface and electrons are ejected with

maximum kinetic energy of 2 eV. If the same surface is illuminated by a light source of wavelength
, then the maximum kinetic energy of ejected electrons will be (The work function of metal is 1 eV)

(A) 2 eV
(B) 6 eV
(C) 5 eV
(D) 3 eV

11) Given below are two statements. One is labelled as Assertion (A) and the other is labelled as
Reason (R).
Assertion (A) : A simple pendulum is taken to a planet of mass and radius, 4 times and 2 times,
respectively, than the Earth. The time period of the pendulum remains same on earth and the planet.
Reason (R) : The mass of the pendulum remains unchanged at Earth and the other planet.
In the light of the above statements, choose the correct answer from the options given below :

(A) Both (A) and (R) are true but (R) is NOT the correct explanation of (A)
(B) (A) is true but (R) is false
(C) (A) is false but (R) is true
(D) Both (A) and (R) are true and (R) is the correct explanation of (A)

12) The torque due to the force about the origin, acting on a particle whose position

vector is , would be

(A)
(B)
(C)
(D)

13)

To obtain the given truth table, following logic gate should be placed at G :

(A) NOR Gate

(B) AND Gate
(C) NAND Gate
(D) None of these

14) A force is applied on a particle and it undergoes a displacement . What

will be the value of b, if work done on the particle is zero.

(A) 0
(B)

(C)

(D) 2

15) Given below are two statements. On is labelled as Assertion (A) and the other is labelled as
Reason (R).
Assertion (A) : In Young’s double slit experiment, the fringes produced by red light are closer as
compared to those produced by blue light.
Reason (R) : The fringe width is directly proportional to the wavelength of light.
In the light of above statements, choose the correct answer from the options given below :

(A) Both (A) and (R) are true and (R) is the correct explanation of (A)
(B) (A) is false but (R) is true.
(C) Both (A) and (R) are true but (R) is NOT the correct explanation of (A).
(D) (A) is true but (R) is false.

16) A ball of mass 100 g is projected with velocity 20 m/s at 60° with horizontal. The decrease in
kinetic energy of the ball during the motion from point of projection to highest point is :

(A) 20 J
(B) 15 J
(C) zero
(D) 5 J

17) A transparent film of refractive index, 2.0 is coated on a glass slab of refractive index, 1.45.
What is the minimum thickness of transparent film to be coated for the maximum transmission of
Green light of wavelength 550 nm. [Assume that the light is incident nearly perpendicular to the
glass surface.]

(A) 94.8 nm
(B) 68.7 nm
(C) 137.5 nm
(D) 275 nm

18)
The tube of length L is shown in the figure. The radius of cross section at the point (1) is 2 cm and at
the point (2) is 1 cm, respectively. If the velocity of water entering at point (1) is 2 m/s, then velocity
of water leaving the point (2) will be :

(A) 2 m/s
(B) 4 m/s
(C) 6 m/s
(D) 8 m/s

19) Given are statements for certain thermodynamic variables,

(A) Internal energy, volume (V) and mass (M) are extensive variables.
(B) Pressure (P), temperature (T) and density (ρ) are intensive variables.
(C) Volume (V), temperature (T) and density (ρ) are intensive variables.
(D) Mass (M), temperature (T) and internal energy are extensive variables.
Choose the correct answer from the points given below :

(A) (C) and (D) only

(B) (D) and (A) only
(C) (A) and (B) only
(D) (B) and (C) only

20) A body of mass 100 g is moving in circular path of radius 2 m on vertical plane as shown in
figure. The velocity of the body at point A is 10 m/s. The ratio of its kinetic energies at point B and C

is : (Take acceleration due to gravity as 10 m/s2)

(A)

(B)

(C)

(D)

SECTION-II

1) A proton is moving undeflected in a region of crossed electric and magnetic fields at a constant
speed of 2 × 105 ms–1. When the electric field is switched off, the proton moves along a circular path
of radius 2 cm. The magnitude of electric field is x × 104 N/C. the value of x is _____.
Take the mass of the proton = 1.6 × 10–27 kg.

2) Two long parallel wires X and Y, separated by a distance of 6 cm, carry currents of 5A and 4A,
respectively, in opposite directions as shown in the figure. Magnitude of the resultant magnetic field
at point P at a distance of 4 cm from wire Y is x × 10–5 T. The value of x is ________. Take permeability
 0

of free space as μ = 4π × 10–7 SI units.

3) A parallel plate capacitor of area A = 16 cm2 and separation between the plates 10 cm, is charged
by a DC current. Consider a hypothetical plane surface of area A0 = 3.2 cm2 inside the capacitor and
parallel to the plates. At an instant, the current through the circuit is 6A. At the same instant the
displacement current through A0 is ________ mA.

4) A tube of length 1m is filled completely with an ideal liquid of mass 2M, and closed at both
[Link] tube is rotated uniformly in horizontal plane about one of its ends. If the force exerted by

the liquid at the other end is F then angular velocity of the tube is in SI unit. The value of α is
______.

5) The net current flowing in the given circuit is _______ A.

PART-2 : CHEMISTRY

SECTION-I

1) Arrange the following compounds in increasing order of their dipole moment : HBr, H2S, NF3 and
CHCl3

(A) NF3 < HBr < H2S < CHCl3

(B) HBr < H2S < NF3 < CHCl3
(C) H2S < HBr < NF3 < CHCl3
(D) CHCl3 < NF3 < HBr < H2S

2) Identify the number of structure/s from the following which can be correlated to D-

glyceraldehyde.
(A) three
(B) two
(C) four
(D) one

3) The maximum covalency of a non-metallic group 15 element 'E' with weakest E–E bond is :

(A) 5
(B) 3
(C) 6
(D) 4

4) Consider the given figure and choose the correct option :

(A) Activation energy of backward reaction is E1 and product is more stable than reactant.
(B) Activation energy of forward reaction is E1 + E2 and product is more stable than reactant.
(C) Activation energy of forward reaction is E1 + E2 and product is less stable than reactant.
Activation energy of both forward and backward reaction is E1 + E2 and reactant is more stable
(D)
than product.

5) When sec-butylcyclohexane reacts with bromine in the presence of sunlight, the major product is :

(A)

(B)

(C)

(D)

6) The species which does not undergo disproportionation reaction is :

(A)
(B)
(C) ClO–
(D)

7) Match the Compounds (List-I) with the appropriate Catalyst/Reagents (List-II) for their
reduction into corresponding amines.

List-I(Compounds) List-II(Catalyst/Reagents)

(A) (I) NaOH (aqueous)

(B) (II) H2/Ni

(C) R–C≡N (III) LiAlH4, H2O

(D) (IV) Sn, HCl

Choose the correct answer from the options given below :

(A) (A)-(III), (B)-(II), (C)-(IV), (D)-(I)
(B) (A)-(II), (B)-(IV), (C)-(III), (D)-(I)
(C) (A)-(II), (B)-(I), (C)-(III), (D)-(IV)
(D) (A)-(III), (B)-(IV), (C)-(II), (D)-(I)

8)
The maximum number of RBr producing 2-methylbutane by above sequence of reactions is _____.
(Consider the structural isomers only)

(A) 4
(B) 5
(C) 3
(D) 1

9) Match List-I with List-II.

List-I List-II
(Partial (Thermodynamic
Derivatives) Quantity)

(A) (I) CP
 (B) (II) –S

(C) (III) CV

(D) (IV) V

Choose the correct answer from the options given below :

(A) (A)-(II), (B)-(I), (C)-(III), (D)-(IV)
(B) (A)-(II), (B)-(I), (C)-(IV), (D)-(III)
(C) (A)-(I), (B)-(II), (C)-(IV), (D)-(III)
(D) (A)-(II), (B)-(III), (C)-(I), (D)-(IV)

10)

The correct order of the following complexes in terms of their crystal field stabilization energies is :

2+ 2+ 3+ 3+
(A) [Co(NH3)4] <[Co(NH3)6] <[Co(en)3] <[Co(NH3)6]
2+ 2+ 3+ 3+
(B) [Co(NH3)4] <[Co(NH3)6] <[Co(NH3)6] <[Co(en)3]
2+ 3+ 2+ 3+
(C) [Co(NH3)6] <[Co(NH3)6] <[Co(NH3)4] <[Co(en)3]
3+ 3+ 2+ 2+
(D) [Co(en)3] <[Co(NH3)6] <[Co(NH3)6] <[Co(NH3)4]

11)

Density of 3 M NaCl solution is 1.25 g/mL. The molality of the solution is :

(A) 1.79 m
(B) 2 m
(C) 3 m
(D) 2.79 m

12)

The molar solubility(s) of zirconium phosphate with molecular formula (Zr4+)3 is given by
relation :

(A)

(B)

(C)

(D)
13)

The most stable carbocation from the following is :

(A)

(B)

(C)

(D)

14)

Given below are two statements :

Statement (I) : An element in the extreme left of the periodic table forms acidic oxides.

Statement (II) : Acid is formed during the reaction between water and oxide of a reactive element
present in the extreme right of the periodic table.
In the light of the above statements, choose the correct answer from the options given below :
(A) Statement-I is false but Statement-II is true.
(B) Both Statement-I and Statement-II are false.
(C) Statement-I is true but Statement-II is false.
(D) Both Statement-I and Statement-II are true.

15)

Given below are two statements :

Statement (I) : A spectral line will be observed for a 2px → 2py transition.

Statement (II) : 2px and 2py are degenerate orbitals.

In the light of the above statements, choose the correct answer from the options given below :
(A) Both Statement-I and Statement-II are true.
(B) Both Statement-I and Statement-II are false.
(C) Statement-I is true but Statement-II is false.
(D) Statement-I is false but Statement-II is true.

16)

Given below are two statement :

Statement (I) : Nitrogen, sulphur, halogen and phosphorus present in an organic compound are
detected by Lassaigne’s Test.
Statement (II) : The elements present in the compound are converted from covalent form into ionic
form by fusing the compound with Magnesium in Lassaigne’s test.
In the light of the above statements, choose the correct answer from the options given below :
(A) Both Statement I and Statement II are true
(B) Both Statement I and Statement II are false
(C) Statement I is true but Statement II is false
(D) Statement I is false but Statement II is true

17)

Identify the homoleptic complex(es) that is/are low spin.

(A) [Fe(CN)5NO]2– (B) [CoF6]3–
(C) [Fe(CN)6]4– (D) [Co(NH3)6]3+
(E) [Cr(H2O)6]2+
Choose the correct answer from the options given below :

(A) (B) and (E) only

(B) (A) and (C) only
(C) (C) and (D) only
(D) (C) only

18)
Residue (A) + HCl (dil.) → Compound (B)

Formed respectively is :

(A)

(A) (B)

(A) (B)
(B)

(C)
(A) (B)

(D)
(A) (B)

19)
Given below are two statements :

Statement (I) : Corrosion is an electrochemical phenomenon in which pure metal acts as an anode
and impure metal as a cathode. Statement (II) : The rate of corrosion is more in alkaline medium
than in acidic medium.
In the light of the above statements, choose the correct answer from the options given below :
(A) Both Statement I and Statement II are false
(B) Statement I is false but Statement II is true
(C) Both Statement I and Statement II are true
(D) Statement I is true but Statement II is false

20)

The alkane from below having two secondary hydrogens is :

(A) 4-Ethyl-3,4-dimethyloctane
(B) 2,2,4,4-Tetramethylhexane
(C) 2,2,3,3-Tetramethylpentane
(D) 2,2,4,5-Tetramethylheptane

SECTION-II

1) The compound with molecular formula C6H6, which gives only one monobromo derivative and
takes up four moles of hydrogen per mole for complete hydrogenation has _______ π electrons.

2)

Niobium (Nb) and ruthenium (Ru) have “x” and “y” number of electrons in their respective 4d
orbitals. The value of x + y is _______

3)

The complex of Ni2+ ion and dimethyl glyoxime contains ______ number of Hydrogen (H) atoms.

4)

Consider the following cases of standard enthalpy of reaction

The magnitude of is ______ kJ mol–1 (Nearest integer).

5) 20 mL of 2 M NaOH solution is added to 400 mL of 0.5 M NaOH solution. The final concentration
of the solution is ______ × 10–2 M. (Nearest integer).
 PART-3 : MATHEMATICS

SECTION-I

1) Let α, β, γ and δ be the coefficients of x7, x5, x3 and x respectively in the expansion of

, x > 1. If u and v satisfy the equations αu + βv = 18, γu + δv =

20,
then u + v equals :

(A) 5
(B) 4
(C) 3
(D) 8

2) In a group of 3 girls and 4 boys, there are two boys B1 and B2. The number of ways, in which these
girls and boys can stand in a queue such that all the girls stand together, all the boys stand together,
but B1 and B2 are not adjacent to each other, is :

(A) 144
(B) 72
(C) 96
(D) 120

3) Let P be a point on the parabola y2 = 4ax and PQ be a focal chord of the parabola. If M
and N are the foot of perpendiculars drawn from P and Q respectively on the directrix of the
parabola, then the area of the quadrilateral PQMN is equal to:

(A)

(B)

(C)

(D)

4) For a 3 × 3 matrix M, let trace (M) denote the sum of all the diagonal elements of M. Let A be a 3

× 3 matrix such that |A| = and trace (A) = 3. If B = adj(adj(2A)), then the value of |B| + trace (B)
equals:

(A) 56
(B) 132
(C) 174
(D) 280
5) Suppose that the number of terms in an A.P. is 2k, k∈N. If the sum of all odd terms of the A.P. is
40, the sum of all even terms is 55 and the last term of the A.P. exceeds the first term by 27, then k
is equal to

(A) 5
(B) 8
(C) 6
(D) 4

6) Let a line pass through two distinct points P(–2, –1, 3) and Q, and be parallel to the vector
. If the distance of the point Q from the point R(1, 3, 3) is 5, then the square of the area of
ΔPQR is equal to:

(A) 136
(B) 140
(C) 144
(D) 148

7) If = α, then the value of equals

(A) e
(B) e–2
(C) e2
(D) e–1

8) Let f(x) = dt, x ∈ R. Then the numbers of local maximum and local minimum points
of f, respectively, are :

(A) 2 and 3
(B) 3 and 2
(C) 1 and 3
(D) 2 and 2

9) The perpendicular distance, of the line from the point P(2, –10,1), is:

(A) 6
(B)
(C)
(D)

10) If x = f(y) is the solution of the differential equation (1 + y2) + = 0, y ∈

 with f(0) = 1, then f is equal to :

(A) eπ/4
(B) eπ/12
(C) eπ/3
(D) eπ/6

11) If dx = g(x) + C, where C is the constant of integration,

then equals :

(A)

(B)

(C)

(D)

12) Let αθ and βθ be the distinct roots of 2x2 + (cosθ)x –1 = 0, θ ∈ (0, 2π). If m and M are the
minimum and the maximum values of , then 16(M + m) equals :

(A) 24
(B) 25
(C) 27
(D) 17

13) Let A = {1, 2, 3, 4} and B = {1, 4, 9, 16}. Then the number of many-one functions f : A → B such
that 1 ∈ f(A) is equal to :

(A) 127
(B) 151
(C) 163
(D) 139

14) If the system of linear equations :

x + y + 2z = 6,
2x + 3y + az = a + 1,
–x – 3y + bz = 2b,
where a, b ∈ R, has infinitely many solutions, then 7a + 3b is equal to :

(A) 9
(B) 12
(C) 16
(D) 22

15) Let and be two unit vectors such that the angle between them is . If and
are perpendicular to each other, then the number of values of λ in [–1, 3] is :

(A) 3
(B) 2
(C) 1
(D) 0

16) Let E : = 1, a > b and H : = 1. Let the distance between the foci of E and the

foci of H be . If a – A = 2, and the ratio of the eccentricities of E and H is , then the sum of the
lengths of their latus rectums is equal to :

(A) 10
(B) 7
(C) 8
(D) 9

17) If A and B are two events such that = 0.1, and and are the roots of the

equation 12x2 – 7x + 1 = 0, then the value of is:

(A)

(B)

(C)

(D)

18) The sum of all values of θ ∈ [0, 2π] satisfying 2sin2θ = cos2θ and 2cos2θ = 3sinθ is

(A)

(B) 4π

(C)

(D) π

19) Let the curve z(1 + i) + = 4, z ∈ C, divide the region |z – 3| ≤ 1 into two parts of areas α
and β. Then |α – β| equals :

(A)

(B)

(C)

(D)

20) The area of the region enclosed by the curves y = x2 – 4x + 4 and y2 = 16 – 8x is :

(A)

(B)

(C) 5
(D) 8

SECTION-II

1) Let y = f(x) be the solution of the differential equation , –1 < x < 1 such

that f(0) = 0. If 6 then α2 is equal to __________.

2)

Let A(6, 8), B(10 cosα, –10 sinα) and C (–10 sinα, 10 cosα), be the vertices of a triangle. If L(a, 9) and
G(h, k) be its orthocenter and centroid respectively, then (5a – 3h + 6k + 100 sin2α) is equal
to___________

3) Let the distance between two parallel lines be 5 units and a point P lie between the lines at a unit
distance from one of them. An equilateral triangle PQR is formed such that Q lies on one of the
parallel lines, while R lies on the other. Then (QR)2 is equal to ________.

4) If = a × 229, then α is equal to ______.

5) Let A = {1, 2, 3}. The number of relations on A, containing (1, 2) and (2, 3), which are reflexive
and transitive but not symmetric, is ______.
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D B B B C D D D D C A C D B B B C D C C

SECTION-II

Q. 21 22 23 24 25
A. 2 1 1200 1 1

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A A D C D B D A B B D A A A D C C D D C

SECTION-II

Q. 46 47 48 49 50
A. 8 11 14 95 57

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A A C D A A A A C D C B B C D C C D A A

SECTION-II

Q. 71 72 73 74 75
A. 27 145 28 465 3
 SOLUTIONS

PART-1 : PHYSICS

1)

2)
mg – FB – f = 0

⇒ mg – –f=0

∴f=

3) ⇒ ⇒

4) Initially,

Finally,

5) & VA =

EB = &

6) =

7) r = & mvr = ⇒ (eBr)r =

⇒

first excited state : n = 2 ∴ r =

8)

without vibration : f = 5 : γ1 = 1. 4

without vibration : f = 7 : γ2 = 1.14

∴ γ2 < γ1

9)
Motional emf : ε = Bℓv = constant

10) ⇒ ......(1)

∴ kmax = 5eV

11)

A is correct, R is correct ; but since T =

doesn't depend on mass ; R doesn't explain A.

12)

13) Dropped by NTA

For NOR gate :

∴ Truth table
∴ Bonus

14) WD =

∴b=

15) &
∴

16)

17)
For transmitted green light to be maxima, reflected green should be minima.

⇒ ∴

18)
 ⇒
∴ V2 = 8 m/s

19) Extensive variables depends on size or mass of system ex : internal energy, volume, mass

20)

+ mg

100 =

[Link] =

100 = VC2 = 60
VC2 = 40

[Link] =

[Link] = =

21) For uniform speed V =

R= =

⇒E=

=
= 2 × 104 N/C.
 22)

B=

=–
= – 100 × 10–7
= –1 × 10–5 T

23) Jd =

∴ I through small area = Jd × A’ = × 3.2 = 1.2A =1200 mA

24)

F = 2Mω2 = Mw2ℓ

ω=

25)
Req = 2Ω

I= = 1A

PART-2 : CHEMISTRY

26) Increasing order of Dipole moment

NF3 < HBr < H2S < CHCl3
μ = 0.24D 0.79D 0.95D 1.04D
It is NCERT Data Based
27)

28)

N – N < P – P : single (σ) bond strength

Due to L.P.-L.P. replusion

and maximum possible covalency of nitrogen is 4.

29)

Activation energy of forward reaction = E1 + E2

Energy of product > Energy of reactant

Stability

Reactant > Product

30)

31) → x + {(–2) × 4} = – 1 ⇒ x = +7
Chlorine is in its maximum oxidation state, so disproportionation not possible in .

32) (A)

(B)
(C)

(D)

33)

34) (A) dG = VdP – SdT

Constant pressure
dG = – SdT

= –S
(B) dH = (dq)P = nCpdT

(C) dG = VdP – SdT

At constant temperature
dG = VdP

(D) dU = nCVdT = (q)V

35) Order of CFSE

SFL : NH3 < en

36) 3M NaCl, dsol = 1.25 gm/mol

Molality =

= = 2.79

37) Zr3(PO4)4(s) 3Zr+4(aq) + 4PO4–3(aq)

 – 3s 4s
Ksp = (3s)3 (4s)4 = 6912 s7

s=

38)
Due to +M effect of –OMe at para position

39) Statement-I : False but Statement-II is true.

On moving left to right in periodic table non-metallic character increases and we know that
non-metal oxides are acidic in nature.
Non metallic character ↑ Acidic strength of oxide ↑

40) No spectral line will be observed for a 2px → 2py transition because 2px and 2py orbitals are
degenerate orbitals.

41) The elements present in the compound are converted from covalent form into ionic form by
fusing the compound with sodium in Lassigne’s test

0
42) (A) [Fe(CN)5NO]–2 → Heteroleptic, Fe+2, 3d6, t2g6eg , d2sp3, Low spin (3d series + SFL)
(B) [CoF6]–3 → Homoleptic, sp3d2, High spin, Co+3, 3d6 (3d series + WFL)
0
(C) [Fe(CN)6]–4 → Homoleptic, Fe+2, 3d6, d2sp3, t2g6 eg , Low spin (3d series + SFL)
0
(D) [Co(NH3)6]+3 → Homoleptic, Co+3 3d6, d2sp3, t2g6 eg , Low spin (3d series + SFL)
(E) [Cr(H2O)6]+2 → Homoleptic, Cr+2 3d4, d2sp3, High spin t2g3 eg1 (3d series + WFL)

43)

44) Statement I : Corrosion is an example of electrochemical phenomenon.

In which pure metal act as anode and impure metal (rusted metal) act as cathode.
Statement II : Corrosion is more favourable in acid medium than alkaline so rate of corrosion
is high is acid medium then alkaline.

45)

46)

47) Z = 41 → Nb (Niobium) : [Kr]36 4d4 5s1

Number of electron in 4d = 4 = x
Z = 44 → Ru (Ruthenium) [Kr]36 4d7 5s1
Number of electron in 4d = 7 = y
x + y = 11

48) [Ni(dmg)2]

Number of H-atom = 14

49) 2C(graphite) + 3H2(g) → C2H6(g) ΔHf = ?

C2H6(g) + O2(g) → 2CO2(g) + 3H2O(l)ΔH1 = – 1550

C(graphite) + O2(g) → CO2(g) ΔH2 = – 393.5

H2(g) + O2(g) → H2O(/) ΔH3 = – 286

ΔHf = 2ΔH2 + 3ΔH3 – ΔH1
 = 95 kJ/mole

50) MF =

= 0.571 M
–2
= 57.1 × 10 M
= 57

PART-3 : MATHEMATICS

51)
= 2{5C0.x5 + 5C2.x3(x3 – 1) + 5C4.x(x3 – 1)2}
= 2{5x7 + 10x6 + x5 – 10x4 – 10x3 + 5x}
⇒ α = 10, β = 2, γ = –20, δ = 10
Now, 10u + 2v = 18
–20u + 10v = 20
⇒ u = 1, v = 4
u+v=5

52) Total – when B1 and B2 are together

= 2!(3! 4!) – 2! (3!(3! 2!)) = 144

53)
(4, 4 )lies on y2 = 4ax
⇒ 48 = 4a.4
4a = 12
⇒ y2 = 12x is equation of parabola

Now, parameter of P is t1 = ⇒ Parameters of Q

is t2 = ⇒Q
Area of trapezium PQNM

= MN.(PM + QN)

= MN.(PS + QS)
= MN. PQ

= =3

54) |A|= , trace(A) = 3, B = adj(adj(2A))=|2A|n–2(2A)

n = 3, B = |2A|(2A) = 23.|A|(2A) = 8A
|B| = |8A| = 83.|A| = 28 = 256
trace(B) = 8 trace(A) = 24
|B| + trace(B) = 280

55) a1, a2, a3,……, a2k →A.P.

, , a2k – a1 = 27

[2a1 + (k – 1)2d] = 40, [2a2 + (k – 1)2d] = 55,

d=

a1 = – (k – 1)d = – kd

d= ⇒ = ⇒ 9k = 10k – 5
∴k=5

56) parallel to , R(1, 3, 3)

⇒ Q(3λ – 2, 2λ – 1, 2λ + 3), λ ∈ R – {0}

=5=
∴ 17λ2 – 34λ + 25 = 25 ⇒ λ = 2(∴ λ ≠ 0)
∴ Q(4, 3, 7), P(–2, –1, 3), R(1, 3, 3)

Area of ΔPQR = [PQR] =

[PQR] =
[PQR] =
∴ [PQR]2 = 136

57) α = (1∞ form)

∴ α = eL

Where L =
⇒L=

⇒L=

⇒L=

⇒L=

⇒L=

∴α= ⇒ logα =

∴ Required value = =e

58) f ′(x) =

Maxima at x ∈ { }
Minima at x ∈ { }
2 points of maxima and 3 points of minima.

59)

(2λ + 1, –λ – 2, 2λ – 3)
∴
⇒ (2λ – 1)2 + (–λ + 8)(–1) + (2λ – 4)2 = 0
⇒ 4λ – 2 + λ – 8 + 4λ – 8 = 0
⇒ 9λ – 18 = 0 ⇒ λ = 2
∴ A(5, –4, 1)
∴ AP = = =

60)
I.F. =

Put tan–1y = t,

∴ y = 0, x = 1
1=1+c⇒c=0

y= , x = eπ/6

61) ∵

⇒ = g(x) + C

Note : assuming g(x) =

g(1/2) = =
Comment : In this question we will not get a unique function g(x), but in order to match the

answer we will have to assume g(x) = .

62) (α2 + β2)2 – 2 α2β2

[(α + β)2 – 2αβ]2 – 2(αβ)2

, 16(M + m) = 25

63)

Total = 44
One-one = 4!
Many-one = 256 – 24 = 232
Many-one which 1 ∉ f(A)
= [Link] = 81
232 – 81 = 151

64) Δ = =0
⇒ 2a + b – 6 = 0 …….(1)

Δ1 = =0
⇒a+b–8=0 …….(2)
Solving (1) + (2)
a = –2, b = 10
⇒ 7a + 3b = 16

65)

Now

λ2 – 2λ – 6 = 0
λ=
⇒ number of values = 0

66) foci are (ae, 0) and (–ae, 0)

foci are (Ae′, 0) and (–Ae′, 0)

⇒ 2ae = ⇒ ae =
and 2Ae′ = ⇒ Ae′ =

⇒ ae = Ae′ ⇒

⇒ ⇒ a = 3A

Now a – A = 2 ⇒ a – – 2 ⇒ a = 3 and A = 1

Ae = ⇒e= and e′ =
2 2 2
b = a (1 – e )
b2 = 6
and B2 = A2((e′)2 – 1) = (2) ⇒ B2 = 2
sum of LR = =8

67) 12x2 – 7x + 1 = 0 x =

Let &

&
⇒ P(B) = 0.3
& P(A) = 0.4
P(A ∪ B) = P(A) + P(B) – P(A ∩ B)
= 0.3 + 0.4 – 0.1 = 0.6

Now =

= = =

68) 2sin2θ = cos2θ

2sin2θ = 1 – 2sin2θ
4sin2θ = 1

sin2θ =

sinθ = ±
2cos2θ = 3sinθ
2 – 2sin2θ + 3sinθ – 2 = 0
(2sinθ – 1)(2sinθ – 2) = 0

sinθ =

so common equation which satisfy both equations is sinθ =

(θ ∈ [0, 2π])
Sum = π

69)
Let z = x + iy
(x + iy)(1 + i) + (x – iy)(1 – i) = 4
x + ix + iy – y + x – ix – iy – y = 4
2x – 2y = 4
x–y=2
|z – 3| ≤ 1
(x – 3)2 + y2 ≤ 1

Area of shaded region = =

Area of unshaded region inside the circle

= =

∴ difference of area =

70)
y = (x –2)2, y2 = 8(x – 2)
y = x2 , y2 = – 8x

71) I.F.

Given y(0) = 0 ⇒ c = 0

Now,

Put x = sinθ
dx = cosθ dθ
=
=

72)

All the three points A, B, C lie on the circle x2 + y2 = 100 so circumcentre is (0, 0)

and ⇒k=3

also centroid
⇒ 10(cosα– sinα) = 3h – 6 ….(i)

and
⇒ 10(cosα – sinα) = 3k – 8 = 9 – 8 = 1 ….(ii)
on squaring 100(1 – sin2α) = 1
⇒ 100sin2α = 99

from equ. (i) and (ii) we get h =

Now 5a – 3h + 6k + 100 sin2α
= 15h – 3h + 6k + 100 sin2α

= 12 × + 18 + 99
= 145

73)
PR = cosecθ, PQ = 4sec(30 + θ)
For equilateral
d = PR = PQ
⇒ cos(θ + 30°) = 4sinθ

⇒
⇒
QR2 = d2 = cosec2θ = 28

74)

=
= 30(29 × 228 + 229) = 30(29 + 2)228
= 15 × 31 × 229
= 465(229)
α = 465

75)

Transitivity
(1, 2) ∈ R, (2, 3) ∈ R ⇒ (1, 3) ∈ R
For reflexive (1, 1), (2, 2) (3, 3) ∈ R
Now (2, 1), (3, 2), (3, 1)
(3, 1) cannot be taken
(1) (2, 1) taken and (3, 2) not taken
(2) (3, 2) taken and (2, 1) not taken
(3) Both not taken
therefore 3 relations are possible.